WO2000005010A1 - Coating compositions - Google Patents

Coating compositions Download PDF

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Publication number
WO2000005010A1
WO2000005010A1 PCT/GB1999/002151 GB9902151W WO0005010A1 WO 2000005010 A1 WO2000005010 A1 WO 2000005010A1 GB 9902151 W GB9902151 W GB 9902151W WO 0005010 A1 WO0005010 A1 WO 0005010A1
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WO
WIPO (PCT)
Prior art keywords
water
composition
coating
esters
binder
Prior art date
Application number
PCT/GB1999/002151
Other languages
French (fr)
Inventor
Reinhard Stoetzel
Helmut Stuhr
Original Assignee
Foseco International Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foseco International Limited filed Critical Foseco International Limited
Priority to PL99345586A priority Critical patent/PL345586A1/en
Priority to KR1020017000949A priority patent/KR20010071014A/en
Priority to AT99934828T priority patent/ATE255973T1/en
Priority to DE69913539T priority patent/DE69913539T2/en
Priority to CA002338197A priority patent/CA2338197A1/en
Priority to BR9912379-7A priority patent/BR9912379A/en
Priority to EP99934828A priority patent/EP1113890B1/en
Priority to AU50475/99A priority patent/AU5047599A/en
Publication of WO2000005010A1 publication Critical patent/WO2000005010A1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22C—FOUNDRY MOULDING
    • B22C3/00—Selection of compositions for coating the surfaces of moulds, cores, or patterns
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02—Emulsion paints including aerosols
    • C09D5/024—Emulsion paints including aerosols characterised by the additives

Definitions

  • This invention relates to coating compositions for use on sand cores and moulds in foundries.
  • the coatings are usually applied in the form of a dispersion of the particulate refractory material in a liquid medium, which also contains a binder for the refractory particles.
  • the liquid medium is usually water or an organic liquid such as isopropanol.
  • binders which are used to make foundry sand cores and moulds is an aqueous solution of sodium silicate, which is reacted with carbon dioxide gas passed through the cores or moulds so as to cure the silicate and bond the sand grains together.
  • Cores and moulds which have been bonded with sodium silicate suffer from the disadvantage that when a water based coating is applied to the cores and moulds their surface is disintegrated and they are softened, thus reducing their strength appreciably, due to dissolution of the sodium silicate bond by the water.
  • a coating composition comprising particulate refractory material having a particle size of predominantly less than 150 microns, a binder, water and a water soluble or water miscible additive selected from esters of polyhydric alcohols, carbonate esters and lactones.
  • the invention provides a coating system comprising two or more separate parts to be mixed together to form a coating composition, the coating system comprising:
  • a water soluble or water miscible additive selected from esters of polyhydric alcohols, carbonate esters and lactones.
  • the separate parts of the coating system are preferably mixed together substantially immediately before coating is to be carried out.
  • Water is preferably added to the coating system, for example at the same time as the separate parts are mixed together.
  • the invention provides a method of forming a coating composition, comprising mixing together: (a) particulate refractory material having a particle size of predominantly less than 150 microns, and a binder; (b) a water soluble or water miscible additive selected from esters of polyhydric alcohols, carbonate esters and lactones; and
  • the particulate refractory material may be for example, one or more of zircon, alumina, chromite, silica, talc, olivine, graphite, an aluminosilicate such as calcined clay, pyrophyllite and mica.
  • the binder may be for example solution or dispersion of a polyacrylate, a solution or dispersion of polyvinyl alcohol, dextrin, starch.
  • the binder should be one which will not react with the polyhydric alcohol ester, carbonate ester or lactone. Binders which should not be used because they would react with the polyhydric alcohol ester, carbonate ester or lactone include alkali metal silicates and alkaline resol phenol-formaldehyde resins.
  • the water soluble or water miscible additive may be for example diacetin, triacetin, butylene glycol diacetate, propylene carbonate, or gamma-butyrolactone.
  • Industrial grade diacetin glycerol diacetate is preferred.
  • the coating composition may also contain other components, for example, a suspension agent to prevent settling of the particulate refractory material, for example a clay such as attapulgite or bentonite or a rheological agent to improve the application properties of coating composition such as a cellulose derivative, a flocculant or a dispersant.
  • a suspension agent to prevent settling of the particulate refractory material
  • a clay such as attapulgite or bentonite
  • a rheological agent to improve the application properties of coating composition
  • a cellulose derivative such as attapulgite or bentonite
  • a rheological agent to improve the application properties of coating composition
  • the coating composition (and when formed from the coating system, the water diluted coating composition) will usually contain at least 0.5%, preferably at least 1.0%, more preferably at least 2.0% especially at least 4.0% by weight of the water soluble or water miscible additive.
  • the composition contains no more than 20.0%, more preferably no more than 15.0%, especially no more than 10.0% by weight of the water soluble or water miscible additive.
  • the actual amount of the additive used may depend on the method of application of the coating composition to the cores or moulds.
  • the coating composition may be applied by any of the usual methods used in foundries, for example by brushing, dipping, spraying or overpouring.
  • the solids content of the coating composition will depend on the method of application, but will usually be a maximum of 75% by weight.
  • the coating compositions of the invention are particularly advantageous when used on carbon dioxide gassed sodium silicate bonded sands. However they can also be used beneficially on other types of bonded sand which may have a tendency to soften and disintegrate when conventional water based coating compositions are applied to them. These sands include carbon dioxide gassed alkaline resol phenol-formaldehyde resin bonded sand, ester hardened sodium silicate bonded sand, and ester cured alkaline resol phenol-formaldehyde resin bonded sand.
  • Standard transverse strength test cores were produced from H 32 silica sand containing 3.5 % by weight of a proprietary sodium silicate binder, NUCLEOPON 20, available from Foseco (silica to soda molar ratio 2.4 : 1 and solids content 49 % by weight).
  • composition 1 Three proprietary water based coating compositions available from Foseco, TERRAPAINT EP 9828 AT (composition 1), RHEOTEC 463 BW (composition 2) and HOLCOTE 90 (composition 3), were diluted to a dipping consistency with water, and 5 % by weight of commercial diacetin based on the weight of the diluted coated composition were added to produce coating compositions according to the invention.
  • the coating compositions were applied to the standard transverse strength test cores by dipping, and transverse strengths were measured immediately after application of the coating (while wet), one hour after drying at 120 °C for 30 minutes, and after 24 hours.
  • silica sand 120 kg were mixed with 3.6% by weight based on the weight of the sand of SOLOSIL 433, a proprietary sodium silicate based binder available from Foseco of the type described in European Patent No. 0024392.
  • Housing cores were made from the sand-binder mixture by core-shooting at a pressure 6 bars and by gassing the formed cores with carbon dioxide gas at a pressure of 5 bars for 15 seconds.
  • the diluted coating composition had a density of 42° Baume and a viscosity of 13.5 seconds as measured on a Ford Cup No. 4.
  • the housing cores were dipped into the coating composition so as to produce a wet coating thickness of approximately 175 microns.
  • the coated cores were held for a maximum of 15 minutes dried in a microwave drying unit. After drying for 10 minutes the cores were still wet and had a surface temperature of 55° to 60° C. The cores were the dried for a further 15 minutes after which time they were almost completely dry and had a surface temperature of 60° to 70° C. The cores were then inspected, and they showed no signs of having been affected adversely by the water based coating.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Mold Materials And Core Materials (AREA)

Abstract

A coating composition for use on sand cores and moulds in foundries is disclosed. The coating composition comprises particulate refractory material having a particle size of predominantly less than 150 microns, a binder, water and a water soluble or water miscible additive selected from esters of polyhydric alcohols, carbonate esters and lactones. Also disclosed is a coating system comprising two or more separate parts to be mixed together to form a coating composition, the coating system comprising: (a) particulate refractory material having a particle size of predominantly less than 150 microns, and a binder; and, separately, (b) a water soluble or water miscible additive selected from esters of polyhydric alcohols, carbonate esters and lactones. The water soluble or water miscible additive may comprise one or more of: diacetin, triacetin, butylene glycol diacetate, propylene carbonate, gamma-butyrolactone, for example.

Description

COATING COMPOSITIONS
This invention relates to coating compositions for use on sand cores and moulds in foundries.
It is common practice in foundries to coat sand cores and moulds with a coating of fine particle size refractory material, in order to prevent penetration of molten metal into the surface of the core or mould between the sand grains, and in the case of silica sand cores and moulds used for casting iron, to prevent reaction between the silica and iron oxide and adhesion between the sand and the cast metal, and thereby to improve the surface finish of metal cast against the cores or moulds. The coatings are usually applied in the form of a dispersion of the particulate refractory material in a liquid medium, which also contains a binder for the refractory particles. The liquid medium is usually water or an organic liquid such as isopropanol.
One of the numerous binders which are used to make foundry sand cores and moulds is an aqueous solution of sodium silicate, which is reacted with carbon dioxide gas passed through the cores or moulds so as to cure the silicate and bond the sand grains together. Cores and moulds which have been bonded with sodium silicate suffer from the disadvantage that when a water based coating is applied to the cores and moulds their surface is disintegrated and they are softened, thus reducing their strength appreciably, due to dissolution of the sodium silicate bond by the water. In some instance it is possible to use a water based coating on sodium silicate bonded cores provided the coating is dried immediately after it has been applied, but this usually involves installing a continuous drying oven in the foundry. However, in most foundries making sodium silicate bonded cores and moulds it is normal practice to coat the cores and moulds with an alcohol based coating. For safety and for environmental reasons it is desirable to replace the alcohol based coatings with water based coatings, but without the need to provide means for drying the coatings as soon as they have been applied.
It has now been found that a water based coating can be used successfully on carbon dioxide gassed sodium silicate bonded cores and moulds if the coating composition used contains a water soluble or water miscible additive selected from esters of polyhydric alcohols, carbonate esters and lactones.
According to a first aspect of the present invention there is provided a coating composition comprising particulate refractory material having a particle size of predominantly less than 150 microns, a binder, water and a water soluble or water miscible additive selected from esters of polyhydric alcohols, carbonate esters and lactones.
According to a second aspect, the invention provides a coating system comprising two or more separate parts to be mixed together to form a coating composition, the coating system comprising:
(a) particulate refractory material having a particle size of predominantly less than 150 microns, and a binder; and, separately,
(b) a water soluble or water miscible additive selected from esters of polyhydric alcohols, carbonate esters and lactones.
The separate parts of the coating system are preferably mixed together substantially immediately before coating is to be carried out. Water is preferably added to the coating system, for example at the same time as the separate parts are mixed together.
According to a third aspect, the invention provides a method of forming a coating composition, comprising mixing together: (a) particulate refractory material having a particle size of predominantly less than 150 microns, and a binder; (b) a water soluble or water miscible additive selected from esters of polyhydric alcohols, carbonate esters and lactones; and
(c) water.
The particulate refractory material may be for example, one or more of zircon, alumina, chromite, silica, talc, olivine, graphite, an aluminosilicate such as calcined clay, pyrophyllite and mica.
The binder may be for example solution or dispersion of a polyacrylate, a solution or dispersion of polyvinyl alcohol, dextrin, starch. The binder should be one which will not react with the polyhydric alcohol ester, carbonate ester or lactone. Binders which should not be used because they would react with the polyhydric alcohol ester, carbonate ester or lactone include alkali metal silicates and alkaline resol phenol-formaldehyde resins.
The water soluble or water miscible additive may be for example diacetin, triacetin, butylene glycol diacetate, propylene carbonate, or gamma-butyrolactone. Industrial grade diacetin (glycerol diacetate) is preferred.
The coating composition may also contain other components, for example, a suspension agent to prevent settling of the particulate refractory material, for example a clay such as attapulgite or bentonite or a rheological agent to improve the application properties of coating composition such as a cellulose derivative, a flocculant or a dispersant.
The coating composition (and when formed from the coating system, the water diluted coating composition) will usually contain at least 0.5%, preferably at least 1.0%, more preferably at least 2.0% especially at least 4.0% by weight of the water soluble or water miscible additive. Preferably the composition contains no more than 20.0%, more preferably no more than 15.0%, especially no more than 10.0% by weight of the water soluble or water miscible additive. The actual amount of the additive used may depend on the method of application of the coating composition to the cores or moulds.
The coating composition may be applied by any of the usual methods used in foundries, for example by brushing, dipping, spraying or overpouring. The solids content of the coating composition will depend on the method of application, but will usually be a maximum of 75% by weight.
The coating compositions of the invention are particularly advantageous when used on carbon dioxide gassed sodium silicate bonded sands. However they can also be used beneficially on other types of bonded sand which may have a tendency to soften and disintegrate when conventional water based coating compositions are applied to them. These sands include carbon dioxide gassed alkaline resol phenol-formaldehyde resin bonded sand, ester hardened sodium silicate bonded sand, and ester cured alkaline resol phenol-formaldehyde resin bonded sand.
The following Examples will serve to illustrate the invention :-
EXAMPLE 1
Standard transverse strength test cores were produced from H 32 silica sand containing 3.5 % by weight of a proprietary sodium silicate binder, NUCLEOPON 20, available from Foseco (silica to soda molar ratio 2.4 : 1 and solids content 49 % by weight).
Three proprietary water based coating compositions available from Foseco, TERRAPAINT EP 9828 AT (composition 1), RHEOTEC 463 BW (composition 2) and HOLCOTE 90 (composition 3), were diluted to a dipping consistency with water, and 5 % by weight of commercial diacetin based on the weight of the diluted coated composition were added to produce coating compositions according to the invention.
The coating compositions were applied to the standard transverse strength test cores by dipping, and transverse strengths were measured immediately after application of the coating (while wet), one hour after drying at 120 °C for 30 minutes, and after 24 hours.
Similar tests were done on specimens which had been coated with coating composition 4, a proprietary alcohol based coating, MOLCO 6, available from Foseco.
The results obtained are shown in the table below.
Figure imgf000008_0001
The results show that the strength of the cores after immediately coating with each of the three compositions according to the invention was comparable to that of cores which had been coated with the alcohol based coating which is of the type normally used for coating sodium silicate bonded cores. After drying for 1 hour the strength of the cores coated with the compositions according to the invention was appreciably higher than both the strength immediately after application, and the strength of the cores coated with the alcohol based coating. After 24 hours the appreciable improvement was maintained.
EXAMPLE 2
120 kg of silica sand were mixed with 3.6% by weight based on the weight of the sand of SOLOSIL 433, a proprietary sodium silicate based binder available from Foseco of the type described in European Patent No. 0024392. Housing cores were made from the sand-binder mixture by core-shooting at a pressure 6 bars and by gassing the formed cores with carbon dioxide gas at a pressure of 5 bars for 15 seconds. A proprietary water-based coating zircon composition RHEOTEC 300 available from Foseco containing an addition of 10% by weight of diacetin based on the weight of the composition as supplied, and having a density of 70° Baume, was diluted with water in the proportions 150 kg of the coating composition containing the diacetin additive and 40 kg water. The diluted coating composition had a density of 42° Baume and a viscosity of 13.5 seconds as measured on a Ford Cup No. 4.
The housing cores were dipped into the coating composition so as to produce a wet coating thickness of approximately 175 microns. The coated cores were held for a maximum of 15 minutes dried in a microwave drying unit. After drying for 10 minutes the cores were still wet and had a surface temperature of 55° to 60° C. The cores were the dried for a further 15 minutes after which time they were almost completely dry and had a surface temperature of 60° to 70° C. The cores were then inspected, and they showed no signs of having been affected adversely by the water based coating.
In contrast, in a comparison test using similar cores coated with a water-based aluminosilicate coating ARCOPAL 6423 (available from Hϋttenes-Albertus) the coated cores had started to disintegrate.

Claims

Claims
1. A coating composition, comprising particulate refractory material having a particle size of predominantly less than 150 microns, a binder, water and a water soluble or water miscible additive selected from esters of polyhydric alcohols, carbonate esters and lactones.
2. A coating system comprising two or more separate parts to be mixed together to form a coating composition, the coating system comprising:
(a) particulate refractory material having a particle size of predominantly less than 150 microns, and a binder; and, separately,
(b) a water soluble or water miscible additive selected from esters of polyhydric alcohols, carbonate esters and lactones.
3. A coating system according to Claim 2, further comprising water.
4. A method of forming a coating composition, comprising mixing together:
(a) particulate refractory material having a particle size of predominantly less than 150 microns, and a binder;
(b) a water soluble or water miscible additive selected from esters of polyhydric alcohols, carbonate esters and lactones; and
(c) water.
5. A composition, system or method according to any preceding claim, in which the particulate refractory material comprises one or more of: zircon, alumina, chromite, silica, talc, olivine, graphite, an aluminosilicate.
6. A composition, system or method according to any preceding claim, in which the binder comprises a solution or dispersion of a polyacrylate.
7. A composition, system or method according to any preceding claim, in which the binder comprises polyvinyl alcohol.
8. A composition, system or method according to any preceding claim, in which the binder comprises dextrin and/or starch.
9. A composition, system or method according to any preceding claim, in which the water soluble or water miscible additive comprises one or more of: diacetin, triacetin, butylene glycol diacetate, propylene carbonate, gamma-butyrolactone.
10. A composition, system or method according to any preceding claim, in which the ready for use coating composition contains at least 0.5%, preferably at least 1.0%, more preferably at least 2.0% especially at least 4.0% by weight of the water soluble or water miscible additive.
11. A composition, system or method according to any preceding claim, in which the ready for use coating composition contains no more than 20.0%, more preferably no more than 15.0%, especially no more than 10.0% by weight of the water soluble or water miscible additive.
PCT/GB1999/002151 1998-07-24 1999-07-16 Coating compositions WO2000005010A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
PL99345586A PL345586A1 (en) 1998-07-24 1999-07-16 Coating compositions
KR1020017000949A KR20010071014A (en) 1998-07-24 1999-07-16 Coating compositions
AT99934828T ATE255973T1 (en) 1998-07-24 1999-07-16 COATING COMPOSITIONS
DE69913539T DE69913539T2 (en) 1998-07-24 1999-07-16 COATING COMPOSITIONS
CA002338197A CA2338197A1 (en) 1998-07-24 1999-07-16 Coating compositions
BR9912379-7A BR9912379A (en) 1998-07-24 1999-07-16 Coating composition, coating system, and process of forming a coating composition
EP99934828A EP1113890B1 (en) 1998-07-24 1999-07-16 Coating compositions
AU50475/99A AU5047599A (en) 1998-07-24 1999-07-16 Coating compositions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9816080.7A GB9816080D0 (en) 1998-07-24 1998-07-24 Coating compositions
GB9816080.7 1998-07-24

Publications (1)

Publication Number Publication Date
WO2000005010A1 true WO2000005010A1 (en) 2000-02-03

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Country Status (12)

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EP (1) EP1113890B1 (en)
KR (1) KR20010071014A (en)
AT (1) ATE255973T1 (en)
AU (1) AU5047599A (en)
BR (1) BR9912379A (en)
CA (1) CA2338197A1 (en)
DE (1) DE69913539T2 (en)
ES (1) ES2211128T3 (en)
GB (1) GB9816080D0 (en)
PL (1) PL345586A1 (en)
TR (1) TR200100223T2 (en)
WO (1) WO2000005010A1 (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100418666C (en) * 2006-11-24 2008-09-17 费长正 Alcohol zircon flour coating for heavy castings and its production method
CN101985157A (en) * 2010-10-29 2011-03-16 内蒙古第一机械制造（集团）有限公司 Core making method for diphasic sand mould core hardened by CO2 gas
US8029614B2 (en) 2002-11-08 2011-10-04 Sintokogio, Ltd. Dry mixture of an aggregate material, a molding process using the same, and a core mold
WO2012081925A2 (en) * 2010-12-17 2012-06-21 Sk Innovation Co., Ltd. Polypropylene carbonate paint composition
US20170036263A1 (en) * 2015-03-09 2017-02-09 Technology Research Association For Future Additiv Manufacturing Granular material, three-dimensional lamination-shaped mold manufacturing apparatus, and three-dimensional lamination-shaped mold manufacturing method
DE102017107655A1 (en) 2017-01-04 2018-07-05 HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung Use of an acid-containing sizing composition in the foundry industry
DE102017107658A1 (en) 2017-01-04 2018-07-05 HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung A sizing composition for the foundry industry containing particulate amorphous silica and acid
DE102017107657A1 (en) 2017-01-04 2018-07-05 HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung A sizing composition comprising organic ester compounds and particulate amorphous silica for use in the foundry industry

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US9315426B2 (en) 2010-05-20 2016-04-19 Comanche Tecnologies, LLC Coatings for refractory substrates
CN110997179B (en) 2017-07-18 2022-03-29 Ha国际有限责任公司 Composition and method for fire resistant coatings with ester carriers
WO2022083875A1 (en) * 2020-10-23 2022-04-28 Foseco International Limited Water-soluble core for casting and moulding processes

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SU1324743A1 (en) * 1985-07-17 1987-07-23 Калужский Машиностроительный Завод Composition for self-hardening anti-stick coat in moulds and cores

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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8029614B2 (en) 2002-11-08 2011-10-04 Sintokogio, Ltd. Dry mixture of an aggregate material, a molding process using the same, and a core mold
US8034265B2 (en) 2002-11-08 2011-10-11 Sintokogio, Ltd. Dry mixture of an aggregate material, a molding process using the same, and a core mold
CN100418666C (en) * 2006-11-24 2008-09-17 费长正 Alcohol zircon flour coating for heavy castings and its production method
CN101985157B (en) * 2010-10-29 2012-07-25 内蒙古第一机械制造（集团）有限公司 Core making method for ''diphase'' sand mould core hardened by CO2 gas
CN101985157A (en) * 2010-10-29 2011-03-16 内蒙古第一机械制造（集团）有限公司 Core making method for diphasic sand mould core hardened by CO2 gas
KR101385933B1 (en) 2010-12-17 2014-04-21 에스케이이노베이션 주식회사 Polypropylene Carbonate Dye Composition
WO2012081925A3 (en) * 2010-12-17 2012-10-04 Sk Innovation Co., Ltd. Polypropylene carbonate paint composition
CN103261346A (en) * 2010-12-17 2013-08-21 Sk新技术 Polypropylene carbonate paint composition
WO2012081925A2 (en) * 2010-12-17 2012-06-21 Sk Innovation Co., Ltd. Polypropylene carbonate paint composition
CN103261346B (en) * 2010-12-17 2016-08-03 Sk新技术株式会社 Polypropylene carbonate paint composition
US20170036263A1 (en) * 2015-03-09 2017-02-09 Technology Research Association For Future Additiv Manufacturing Granular material, three-dimensional lamination-shaped mold manufacturing apparatus, and three-dimensional lamination-shaped mold manufacturing method
DE102017107658A1 (en) 2017-01-04 2018-07-05 HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung A sizing composition for the foundry industry containing particulate amorphous silica and acid
DE102017107655A1 (en) 2017-01-04 2018-07-05 HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung Use of an acid-containing sizing composition in the foundry industry
DE102017107657A1 (en) 2017-01-04 2018-07-05 HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung A sizing composition comprising organic ester compounds and particulate amorphous silica for use in the foundry industry
WO2018127415A1 (en) 2017-01-04 2018-07-12 HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung Use of a size composition containing an acid in the foundry industry
WO2018127399A1 (en) 2017-01-04 2018-07-12 HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung Size composition, comprising organic ester compounds and particulate, amorphous silicon dioxide, for use in the foundry industry
WO2018127413A1 (en) 2017-01-04 2018-07-12 HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung Sizing composition for the foundry industry, containing particulate, amorphous silicone dioxide and acid
CN110446563A (en) * 2017-01-04 2019-11-12 胡坦斯·阿尔伯图斯化学厂有限公司 The coating composition comprising granular, amorphous silica and acid for foundary industry
US11529673B2 (en) 2017-01-04 2022-12-20 HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung Coating composition for the foundry industry, containing particulate, amorphous silicon dioxide and acid

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Publication number Publication date
PL345586A1 (en) 2001-12-17
DE69913539T2 (en) 2004-11-11
KR20010071014A (en) 2001-07-28
EP1113890A1 (en) 2001-07-11
ATE255973T1 (en) 2003-12-15
ES2211128T3 (en) 2004-07-01
CA2338197A1 (en) 2000-02-03
AU5047599A (en) 2000-02-14
GB9816080D0 (en) 1998-09-23
TR200100223T2 (en) 2001-05-21
BR9912379A (en) 2001-10-02
DE69913539D1 (en) 2004-01-22
EP1113890B1 (en) 2003-12-10

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