WO2000004591A1

WO2000004591A1 - Low resistance magnetic tunneling junction

Info

Publication number: WO2000004591A1
Application number: PCT/US1999/016195
Authority: WO
Inventors: Eugene Chen; Jon Slaughter; Renu Whig
Original assignee: Motorola, Inc.
Priority date: 1998-07-20
Filing date: 1999-07-15
Publication date: 2000-01-27
Also published as: TW432482B; US6183859B1; US6261646B1; JP2002520883A; EP1038324A1

Abstract

A low resistance magnetic tunnel junction with low resistance barrier layer and method of fabrication is disclosed. A first magnetic layer of material with a surface is provided and a continuous layer of material, e.g. aluminum, is formed on the surface of the first magnetic layer. The continuous layer of material is treated to produce a low resistance barrier layer of oxynitride material and a second magnetic layer is formed on the barrier layer of oxynitride material to complete the low resistance magnetic tunnel junction.

Description

LOW RESISTANCE MAGNETIC TUNNELING JUNCTION

Field of the Invent.inn

The present invention pertains to methods of fabricating magnetic tunneling junctions for memory cells and more specifically to methods of manufacturing magnetic tunneling junctions with low resistance barrier layers.

Background of the Invention

A magnetic random access memory (MRAM) is a nonvolatile memory which basically includes a magnetoresistive (MR) material, a sense line, and a word line. The MRAM employs the magnetic vectors to store memory states. Magnetic vectors in one or all of the layers of MR material are switched very quickly from one direction to an opposite direction when a magnetic field is applied to the MR material over a certain threshold.

According to the direction of the magnetic vectors in the MR material, states are stored, for example, one direction can be defined as a logic "0", and another direction can be defined as a logic "1". The MR material maintains these states even without a magnetic field being applied. The states stored in the MR material can be read by passing a sense current through the cell in a sense line because of the difference between the magnetic resistances of the two states.

Magnetic tunneling junction (MTJ) structure or cells include at least a pair of magnetic layers with a non- magnetic, non-conducting tunnel layer (commonly referred to as the barrier layer) sandwiched therebetween. When a sense voltage is applied between the pair of magnetic layers, electrical carriers travel between the pair of magnetic layers by tunneling through the non-magnetic, non-conducting tunnel layer sandwiched between the magnetic layers. The resistance to the sense current is a maximum when the magnetic vectors of the pair of magnetic layers are anti-parallel and minimum when the magnetic vectors of the pair of magnetic layers are parallel. The difference between the maximum and minimum resistance is commonly referred to as the magnetoresistance (MR) ratio.

The minimum resistance of the MTJ cell (commonly referred to as the areal resistance) is determined by the construction and materials of the MTJ cell. Clearly, in an ideal MTJ cell the areal resistance would be very low or zero and the maximum resistance would be very high or infinite, similar to an ideal switch. In the prior art, the primary method used to reduce the resistance of an MTJ cell is to make the barrier layer thinner. The cell resistance problem is further aggravated by the fact that in very high density arrays of magnetic memory cells the size of individual cells becomes very small (submicron) if the array is constructed small enough to be useful in present day electronic devices. Thus, to make the barrier layers "thinner", they must become ultra thin, or in a range of a few angstroms thick.

Attempts to reduce the barrier layer to ultra thin dimensions have not been successful because ultra thin layers are usually not continuous, i.e. contain pin holes and the like. For example, one prior art attempt to reduce the areal resistance includes depositing a layer of pure aluminum on the lower magnetic layer of the MTJ and then oxidizing the aluminum layer in oxygen plasma. A problem with this procedure is that as the aluminum layer is deposited, pinholes tend to form, especially if the layer is thin. As the aluminum is oxidized, some of the pinholes tend to remain and produce shorts in the MTJ cell when the second magnetic layer is deposited on the aluminum oxide layer. To overcome the pinhole problem, one possible solution suggested by the prior art is to deposit the aluminum layer at low temperatures (e.g. the temperature of liquid nitrogen) , thereby, reducing the size of the grains. Some of the problems with this method are that it involves extensive heating and cooling cycles, takes a long time, costs more and hence is not a method which can be used in manufacturing.

Some additional problems which arise with attempts to produce thinner layers are that the thinner layers are hard to make reproducibly , and they possibly have issues of thermal stability and electrical breakdown. Accordingly, it is highly desirable to provide magnetic tunneling junctions for magnetic random access memories which include barrier layers with reduced resistance . It is a purpose of the present invention to provide new and improved MTJ cells with reduced resistance and methods of fabrication.

It is another purpose of the present invention to provide new and improved MTJ cells and a method of fabrication with high quality barriers or tunnel layers.

It is still another purpose of the present invention to provide new and improved MTJ cells with a high magnetoresistance (MR) ratio.

It is a further purpose of the present invention to provide a new and improved method of fabricating MTJ cells which is easily adaptable to manufacturing.

Summary of the Invention

The above problems and others are at least partially solved and the above purposes and others are realized in a low resistance magnetic tunnel junction with low resistance barrier layer and method of fabrication. In the novel method, a first magnetic layer of material with a surface is provided and a continuous layer of material, e.g. aluminum, is formed on the surface of the first magnetic layer. The continuous layer of material is treated to produce a low resistance, nonconductive barrier layer of oxynitride material and a second magnetic layer is formed on the barrier layer of oxynitride material to complete the low resistance magnetic tunnel junction.

Brief Description of the Drawings

Referring to the drawings: FIG. 1 through FIG. 4 are simplified and enlarged sectional views illustrating various intermediate structures in accordance with the present invention.

Description of the Preferred Embodiment

Turning now to the drawings in which like characters are designated with similar numbers throughout, FIG. 1 illustrates a structure including a supporting substrate 10 with a magnetic layer 11 formed thereon. While supporting substrate 10 is illustrated as a single layer for simplicity, it will be understood by those skilled in the art that it may include additional layers for various purposes, such as buffer layers, insulating or conducting layers, etc., and all such layers are considered as included in supporting substrate 10. Magnetic layer 11 has an upper surface 12 which is formed as smooth as possible for the deposition cf further layers thereon. Magnetic layer 11 is formed of any of the various materials, or multiple layers of materials, well known in the art and will not be described in great detail herein. While the magnetic cell or cells described herein are illustrated in sectional views for convenience, it should be understood that the figures represent a portion of a cell or an array of cells and each cell can be rectangularly shaped or circular, square or diamond shaped, or elliptical, if desired. As is known in the art, cells that are rectangularly shaped have magnetization vectors that are positioned substantially along the length of the cell and maintained parallel to the length by the physical anisotropy. To achieve this, the width of the cell is formed to be smaller than the width of the magnetic domain walls or transition width within the magnetic layers. Typically, widths of less than 1.0 to 1.2 microns result in such a constraint. Generally, to achieve high density the width is less than one micron and is as small as can be made by manufacturing technology, and the length is greater than the width.

Also, thicknesses of the magnetic layers, e.g. layer 11, are approximately three to ten nanometers and may be different for each magnetic layer in some embodiments. The difference in thicknesses affect the switching points and are utilized in some structures for reading and writing cells.

When the aspect ratio (length to width) of a single magnetic layer is close to one, such as for circular, square or diamond shaped, or elliptical shaped cells, the switching field from shape anisotropy is minimum. In the case of circularly shaped cells, for example, the preferred magnetization direction is determined by uniaxial crystal field anisotropy (or magnetic crystalline anisotropy) . This preferred magnetization direction is set during film deposition by a bias field or by annealing the film after deposition in a high magnetic field (e.g. several kOe) at elevated temperatures (e.g. 200°C to 300°C) . In the case of a square or diamond shape, for example, the uniaxial crystal anisotropy is set along a diagonal direction of the square. In the case of an elliptically shaped cell, the uniaxial crystal anisotropy is set along the long axis of the cell. The main idea is to minimize the shape effect, which contributes to the rise in required switching fields at narrow cell widths, and to utilize crystal field anisotropy to set the preferred magnetization direction needed by a memory cell. Referring now to FIG. 2, a continuous layer 15 of metal is formed on surface 12 of magnetic layer 11. For purposes of this disclosure the term "continuous" refers to a layer of material which is approximately coextensive with magnetic layer 11 and which does not include any pinholes or the like. It should be understood that layer 15 can be formed of a pure material or element, such as aluminum, which can be easily oxidized and nitridized to produce a nonconductive low resistance material for the barrier layer in a MTJ. In a preferred embodiment, layer 15 includes a dominant material or element, which can be easily oxidized and nitridized, and traces of one or more other materials or elements having atoms that are different from the atoms of the dominant metal. Generally, the amount of the dominant element will be greater than 90% including only an amount sufficient to produce grains in layer 15 which are smaller than grains of the dominant element alone so as to produce a continuous layer. In a preferred embodiment, the dominant element is aluminum and the trace materials can be any or all of Cu, Si, Ta, Ti, or the like.

In one specific technique a dominant metal and a trace metal or metals are deposited simultaneously so as to arrive at a mixture that results in the smaller grains and, thus, the continuous layer. In a second technique, seed material is deposited on surface 12 of magnetic layer 11 by any convenient method. The seed material may or may not be a continuous layer. The dominant material is then formed with the use of the seed material, the presence of the seed material insuring a substantially thinner continuous layer of the dominant material . In a preferred embodiment, the seed material includes one or more of Cu, Si, Ta, Ti, or the like and the dominant material includes aluminum. In either of the above techniques, layer 15 is continuous with no pinholes or the like and with a thickness in a range of approximately 0.3 nm to 3 nm and preferably approximately 1.5 nm. It has been found, for example, that the minimum thickness of a continuous aluminum layer 15 for producing a quality barrier layer is approximately 1.5 nm, with thinner continuous aluminum layers resulting in a reduced MR ratio. However, in instances where a dominant material other than aluminum is used, the thinnest continuous layer possible without a reduction in the MR ratio may be different. The addition of a trace material in aluminum can also lower its tunneling energy barrier and, hence, lower the resistance of the MTJ. Also, because layer 15 is converted to an oxynitride with a lower resistance, as explained below, it does not have to be formed as thin as is required for prior art oxides to produce the same results as the prior art oxides. Once continuous layer 15 is in place, whether formed of a pure material or a dominant material and trace materials, a treating step is performed to produce a barrier or tunnel layer 16, as illustrated in FIG. 3, of treated non-conductive material. In a preferred embodiment, the treatment includes generating a plasma from a mixture of oxygen and nitrogen and converting continuous layer 15, by a technique similar to plasma oxidation, to an oxynitride. Depending upon the material utilized to form the oxynitride the plasma mixture of oxygen and nitrogen can be varied to provide optimum results. For example, if the material utilized is aluminum, either pure or with trace materials intermixed, the plasma treatment results in a layer of A10_xN_y, where x and y are the components of oxide and nitride in the aluminum oxynitride. Generally, continuous layer 15 can be made very thin while still maintaining its integrity, which results in a very thin barrier or tunnel layer 16 with low energy barrier height and, consequently, a substantially reduced areal resistance. Also, the fact that layer 15 is continuous substantially improves the quality an reliability of barrier or tunnel layer 16.

Further, by converting layer 15 to oxynitride barrier layer 16, the MTJ has a much lower resistance.

Referring to FIG. 4, a magnetic layer 18 is deposited over barrier or tunnel layer 16 and any electrical connections, passivation, etc. (not shown) are performed to provide a complete cell 20 and/or an array of cells. Generally, the thicknesses of magnetic layer 18 is approximately three to ten nanometers and may be different than or the same as magnetic layer 11 in different embodiments. As explained above, the difference in thicknesses of the magnetic layers affect the switching points and are utilized in some structures for the functions of reading and writing the cells. While barrier layer 16 is described and illustrated as abutting both magnetic layers 11 and 18, it should be understood that in some specific applications it may be desirable to include an additional layer of material (e.g. a thin conducting later) between barrier layer 16 and one or both of magnetic layers 11 and 18. To include such additional layers in cell 20, the lower layers (i.e. substrate 10, magnetic layer 11 and any additional layers which may be present) are defined generally as a support structure and magnetic layer 18 and any additional layers which may be present are defined as a cover structure.

In a specific example, layer 11 is formed of cobalt (Co) approximately 100 A thick (generally in a range of lOA to 200A) , layer 16 is formed of aluminum oxynitride (A10_xN_y) approximately 25 A thick (generally in a range of lOA to lOOA) , and magnetic layer 18 is formed of nickel iron (NiFe) approximately 100 A thick (generally in a range of lOA to 200A) . The change of resistance versus the resistance (ΔR/R) is generally in a range of 10% to 30%. Thus, the state of magnetic cell 20 is relatively easily sensed by passing a sense current therethrough from magnetic layer 11 to magnetic layer 18 (or vice versa) . The change of resistance in cell 20 is easily read as a change in voltage drop across cell 20 which can conveniently be used in conjunction with memory arrays and the like.

Thus, a new and improved method of fabricating low resistance barrier layers for MTJ cells with reduced areal resistance has been disclosed. The new and improved method provides the fabrication of MTJ cells with high quality barriers or tunnel layers and with high magnetoresistance ratios. The new and improved method provides for the fabrication of continuous layers of material which are then treated to produce low resistance oxynitride layers for the formation of the barrier or tunnel layer in MTJ cells. The treatment to produce the low resistance oxynitride layers is easily adaptable to manufacturing processes. While we have shown and described specific embodiments of the present invention, further modifications and improvements will occur to those skilled in the art. We desire it to be understood, therefore, that this invention is not limited to the particular forms shown and we intend in the appended claims to cover all modifications that do not depart from the spirit and scope of this invention.

Claims

What is claimed is:

1. A method of fabricating a magnetic tunnel junction with low resistance barrier layer comprising the steps of: providing a support structure including a first magnetic layer of material; forming a continuous layer of material on the support structure parallel with the first magnetic layer; treating the continuous layer of material to produce a barrier layer of oxynitride material; and forming a cover structure including a second magnetic layer on the barrier layer of oxynitride material, the second magnetic layer being positioned parallel with the first magnetic layer so as to form a magnetic tunnel junction with the barrier layer and the first magnetic layer.

2. A method of fabricating a magnetic tunnel junction as claimed in claim 1 wherein the step of forming the continuous layer of material includes forming a continuous layer of aluminum.

3. A method of fabricating a magnetic tunnel junction as claimed in claim 2 wherein the step of treating the continuous layer of material includes generating a plasma of oxygen and nitrogen and subjecting the continuous layer of aluminum to the plasma to produce a layer of aluminum oxynitride .

4. A method of fabricating a magnetic tunnel junction as claimed in claim 2 wherein the step of forming the continuous layer of material includes forming a continuous layer of aluminum having traces of materials having atoms that are different from atoms of the aluminum.

5. A method of fabricating a magnetic tunnel junction as claimed in claim 4 wherein the step of forming the continuous layer of material including traces of materials includes forming a continuous layer of aluminum with traces of one of Cu, Si, Ta, or Ti .

6. A method of fabricating a magnetic tunnel junction comprising the steps of: providing a support structure including a first magnetic layer of material; forming a continuous layer of aluminum alloy on the support structure parallel with the first magnetic layer with a thickness in a range of 1 nm to 3 nm, the layer of aluminum alloy including greater than 90% aluminum having atoms and traces of materials having atoms that are different from the atoms of the aluminum to produce grains which are different than grains of the aluminum alone; generating a plasma of oxygen and nitrogen and subjecting the continuous layer of aluminum alloy to the plasma to produce a layer of aluminum oxynitride; and forming a cover structure including a second magnetic layer on the layer of aluminum oxynitride so as to produce a magnetic tunnel junction with the layer of aluminum oxynitride and the first magnetic layer.

7. A method of fabricating a magnetic tunnel junction as claimed in claim 6 wherein the step of forming the continuous layer of metal including traces of materials includes forming a continuous layer of aluminum with traces of one of Cu, Si, Ta, or Ti .

8. A magnetic tunnel junction comprising: a support structure including a first magnetic layer of material; a continuous layer of metal oxynitride positioned on the support structure parallel with the first magnetic layer; and a cover structure including a second magnetic layer formed on the continuous layer so as to produce a magnetic tunnel junction with the layer of metal oxynitride and the first magnetic layer.

9. A magnetic tunnel junction as claimed in claim 8 wherein the continuous layer includes a dominant metal having atoms and traces of materials having atoms that are different from the atoms of the dominant metal.

10. A magnetic tunnel junction as claimed in claim 8 wherein the continuous layer includes aluminum having atoms and traces of materials having atoms that are different from the atoms of the dominant metal .