WO1999065989A1 - High barrier polyester / phenylenedi (oxyacetic acid) polyester blends - Google Patents
High barrier polyester / phenylenedi (oxyacetic acid) polyester blends Download PDFInfo
- Publication number
- WO1999065989A1 WO1999065989A1 PCT/US1999/013371 US9913371W WO9965989A1 WO 1999065989 A1 WO1999065989 A1 WO 1999065989A1 US 9913371 W US9913371 W US 9913371W WO 9965989 A1 WO9965989 A1 WO 9965989A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- poly
- polyester
- acid
- phenylenedi
- article
- Prior art date
Links
- 0 CC(C1)(CC(*)C2)[C@@](*)C3C1(*)CCC1(*)*3C2(*)C1* Chemical compound CC(C1)(CC(*)C2)[C@@](*)C3C1(*)CCC1(*)*3C2(*)C1* 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C08L67/025—Polyesters derived from dicarboxylic acids and dihydroxy compounds containing polyether sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1397—Single layer [continuous layer]
Definitions
- a polyester hollow molded product of the present invention is produced by stretching and blowing the preform produced from a polyester blend composition of the present invention. It is, therefore, possible to use an apparatus conventionally used in. the blow molding of poly(ethylene terephthalate). More specifically, a blow molding method such as a hot parison process or a cold parison process is adopted in which a preform is first produced by ordinary extrusion blow molding, injection blow molding, injection molding or extrusion molding, and the thus obtained preform is reheated and biaxially stretched.
- the stretching temperature is 70° to 120° C, preferably 80° to 110° C, and the stretching ratio is 1.5 to 3.5 times in the machine direction and 2 to 5 times in the hoop direction.
- the polyester of the polyester layer in the present invention may be poiy(ethylene terephthalate), poly(ethylene naphthalate), poly(ethylene naphthalate) modified with from greater than 0 to about 20 mole % of terephthalic acid or polycarbonate.
- the polyester of the polyester layer in the present invention is a poly(ethylene terephthalate).
- Poly(ethylene 1 ,4-phenylenedi(oxyacetate)) was made as follows. A reaction vessel was charged with 22.42 grams of 1 ,4-phenylenedi(oxyacetic acid), 24.60 grams of ethylene glycol and 100 ppm of titanium from titanium tetraisopropoxide. The reaction mixture was heated and stirred under nitrogen at 210°C for 60 minutes. The temperature was then increased to 220°C for 120 minutes until all of the water had distilled out of the reaction mixture. The temperature was then raised to 260°C; the nitrogen was evacuated from the reaction system, and a vacuum was applied. The melt condensation was continued at 260°C for 75 minutes under 0.5 mm Hg pressure. The heating was discontinued, the reaction mixture was brought to atmospheric pressure with nitrogen, and the polymer was collected. The polymer had an inherent viscosity of 0.88 dl/g.
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000554801A JP2002518537A (en) | 1998-06-15 | 1999-06-14 | High barrier polyester / phenylene (oxyacetic acid) polyester blend |
BR9911256-6A BR9911256A (en) | 1998-06-15 | 1999-06-14 | Composition of polyester blend, article, and, process for producing a polyester blend |
CA002334464A CA2334464A1 (en) | 1998-06-15 | 1999-06-14 | High barrier polyester / phenylenedi (oxyacetic acid) polyester blends |
EP99928636A EP1088034A1 (en) | 1998-06-15 | 1999-06-14 | High barrier polyester/phenylendedi(oxyacetic acid) polyester blends |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US8922098P | 1998-06-15 | 1998-06-15 | |
US8922198P | 1998-06-15 | 1998-06-15 | |
US8939198P | 1998-06-15 | 1998-06-15 | |
US60/089,391 | 1998-06-15 | ||
US60/089,221 | 1998-06-15 | ||
US60/089,220 | 1998-06-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999065989A1 true WO1999065989A1 (en) | 1999-12-23 |
Family
ID=27376251
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1999/013371 WO1999065989A1 (en) | 1998-06-15 | 1999-06-14 | High barrier polyester / phenylenedi (oxyacetic acid) polyester blends |
PCT/US1999/013352 WO1999065967A1 (en) | 1998-06-15 | 1999-06-14 | Multi-layered polyester articles containing a residue of phenylenedi(oxyacetic acid) and having good barrier to gas permeation |
PCT/US1999/013351 WO1999065988A1 (en) | 1998-06-15 | 1999-06-14 | Polyester / phenylenedi (oxyacetic acid) copolyester blends having improved gas barrier properties |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1999/013352 WO1999065967A1 (en) | 1998-06-15 | 1999-06-14 | Multi-layered polyester articles containing a residue of phenylenedi(oxyacetic acid) and having good barrier to gas permeation |
PCT/US1999/013351 WO1999065988A1 (en) | 1998-06-15 | 1999-06-14 | Polyester / phenylenedi (oxyacetic acid) copolyester blends having improved gas barrier properties |
Country Status (8)
Country | Link |
---|---|
US (1) | US6254950B1 (en) |
EP (3) | EP1088033A1 (en) |
JP (3) | JP2002518536A (en) |
CN (3) | CN1305511A (en) |
AR (3) | AR017749A1 (en) |
BR (3) | BR9911262A (en) |
CA (3) | CA2332519A1 (en) |
WO (3) | WO1999065989A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1038905A2 (en) * | 1999-03-26 | 2000-09-27 | Mitsubishi Polyester Film GmbH | Transparent, UV-stabilised film from a crystallisable thermoplastic material |
WO2013029042A2 (en) | 2011-08-25 | 2013-02-28 | Plastipak Packaging, Inc. | Extruded pet parison, container, and method |
EP2807082A4 (en) * | 2012-01-25 | 2016-10-12 | Plastipak Packaging Inc | Extruded pet parison, container, and method |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AUPR005000A0 (en) * | 2000-09-12 | 2000-10-05 | Polymers Australia Pty Limited | Polyster resins with improved properties |
US20040024102A1 (en) * | 2002-07-30 | 2004-02-05 | Hayes Richard Allen | Sulfonated aliphatic-aromatic polyetherester films, coatings, and laminates |
US7482397B2 (en) * | 2003-01-13 | 2009-01-27 | Eastman Chemical Company | Polycarbonate compositions |
US7297735B2 (en) * | 2003-03-05 | 2007-11-20 | Eastman Chemical Company | Polycarbonate compositions |
US20040143041A1 (en) * | 2003-01-13 | 2004-07-22 | Pearson Jason Clay | Polyester compositions |
US20040192813A1 (en) * | 2003-03-20 | 2004-09-30 | Pearson Jason Clay | Polymer compositions containing an ultraviolet light absorbing compound |
US20040180994A1 (en) * | 2003-03-05 | 2004-09-16 | Pearson Jason Clay | Polyolefin compositions |
US20050277713A1 (en) * | 2003-03-05 | 2005-12-15 | Pearson Jason C | Polymer blends |
CN100594220C (en) * | 2003-03-05 | 2010-03-17 | 伊士曼化工公司 | Polymer blends |
KR101158123B1 (en) * | 2003-03-05 | 2012-06-19 | 이스트만 케미칼 컴파니 | Polymer compositions containing an ultraviolet light absorbing compound |
US20040183053A1 (en) * | 2003-03-20 | 2004-09-23 | Pearson Jason Clay | Process for the preparation of a hindered amine light stabilizer salt |
US7338992B2 (en) * | 2003-03-05 | 2008-03-04 | Eastman Chemical Company | Polyolefin compositions |
JP2006118392A (en) * | 2004-10-20 | 2006-05-11 | Nissan Motor Co Ltd | Multilayered resin pipe and multilayered resin vessel |
EP2270065A3 (en) * | 2004-12-21 | 2011-03-09 | E. I. du Pont de Nemours and Company | Poly(trimethylene terephthalate) composition and shaped articles prepared therefrom |
US7396896B2 (en) * | 2004-12-21 | 2008-07-08 | E.I. Dupont De Nemours And Company | Poly(trimethylene terephthalate) composition and shaped articles prepared therefrom |
DE602006009691D1 (en) * | 2005-10-28 | 2009-11-19 | Eastman Chem Co | MADE OF 2,2,4,4-TETRAMETHYL-1,3-CYCLOBUTANDIOL AND 1,4-CYCLOHEXANDIMETHANOL MIXED POLYESTER COMPOSITIONS COMPREHENSIVE RESTAURANT GLASS |
CN101100504B (en) * | 2006-07-07 | 2010-04-21 | 新疆屯河聚酯有限责任公司 | Low pressure resistant polyethylene terephthalate resin and producing method thereof |
JP5449652B2 (en) * | 2007-03-22 | 2014-03-19 | 株式会社クレハ | Aromatic polyester resin multilayer stretched molded product |
US20100044928A1 (en) * | 2008-08-22 | 2010-02-25 | E. I. Du Pont De Nemours And Company | Process for Shaped Articles from Polyester Blends |
WO2013149157A1 (en) * | 2012-03-30 | 2013-10-03 | E. I. Du Pont De Nemours And Company | Polyesters and fibers made therefrom |
MY185768A (en) * | 2015-04-24 | 2021-06-06 | Toyo Boseki | Biaxially stretched polyester film, and production method therefor |
EP3241865A1 (en) * | 2016-05-04 | 2017-11-08 | Clariant Plastics & Coatings Ltd | Composition for polyester hydrolytic stabilization |
TW202024229A (en) * | 2018-12-22 | 2020-07-01 | 遠東新世紀股份有限公司 | Polyester composition with gas barrier properties |
CN116285257B (en) * | 2023-05-18 | 2023-07-18 | 广东永鑫华新型材料有限公司 | Preparation method of high-temperature-resistant super-tough modified PBT-PET composite material |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4440922A (en) * | 1983-04-13 | 1984-04-03 | Eastman Kodak Co. | Polyester containers having improved gas barrier properties |
EP0335594A2 (en) * | 1988-03-26 | 1989-10-04 | Mitsubishi Chemical Corporation | Copolymerized polymer |
JPH05295241A (en) * | 1992-04-21 | 1993-11-09 | Denki Kagaku Kogyo Kk | Polyester resin composition |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2851788A1 (en) | 1978-11-30 | 1980-06-12 | Bayer Ag | METHOD FOR THE PRODUCTION OF ARYLOXIC ACID |
US4501879A (en) * | 1984-03-26 | 1985-02-26 | Eastman Kodak Company | Polyesteramides and containers having improved gas barrier properties formed therefrom |
US4663426A (en) * | 1985-03-29 | 1987-05-05 | Eastman Kodak Company | Polyester resins capable of forming containers having improved gas barrier properties |
US4552948A (en) | 1985-03-29 | 1985-11-12 | Eastman Kodak Company | Polyester resins capable of forming containers having improved gas barrier properties |
US4935540A (en) | 1988-12-12 | 1990-06-19 | Sumner Jr Charles E | Process for the preparation of aryloxyacetic acid |
JP2767944B2 (en) | 1989-12-28 | 1998-06-25 | 三菱化学株式会社 | Method for producing 1,3-phenylenedioxydiacetic acid |
JP2870151B2 (en) | 1990-08-02 | 1999-03-10 | 三菱化学株式会社 | Process for producing 1,3-phenylenedioxydiacetic acid |
JP2917498B2 (en) | 1990-11-07 | 1999-07-12 | 三菱化学株式会社 | Process for producing 1,3-phenylenedioxydiacetic acid |
US5239045A (en) | 1990-12-27 | 1993-08-24 | Mitsubishi Kasei Corporation | Copolyester and hollow container and oriented film comprising the copolyester |
-
1999
- 1999-06-11 AR ARP990102816A patent/AR017749A1/en unknown
- 1999-06-11 AR ARP990102817A patent/AR019660A1/en unknown
- 1999-06-11 AR ARP990102818A patent/AR018672A1/en unknown
- 1999-06-14 CA CA002332519A patent/CA2332519A1/en not_active Abandoned
- 1999-06-14 BR BR9911262-0A patent/BR9911262A/en not_active Application Discontinuation
- 1999-06-14 JP JP2000554800A patent/JP2002518536A/en active Pending
- 1999-06-14 EP EP99928623A patent/EP1088033A1/en not_active Withdrawn
- 1999-06-14 CA CA002334828A patent/CA2334828A1/en not_active Abandoned
- 1999-06-14 BR BR9911254-0A patent/BR9911254A/en not_active Application Discontinuation
- 1999-06-14 WO PCT/US1999/013371 patent/WO1999065989A1/en not_active Application Discontinuation
- 1999-06-14 WO PCT/US1999/013352 patent/WO1999065967A1/en not_active Application Discontinuation
- 1999-06-14 CA CA002334464A patent/CA2334464A1/en not_active Abandoned
- 1999-06-14 CN CN99807462A patent/CN1305511A/en active Pending
- 1999-06-14 CN CN99809656A patent/CN1312837A/en active Pending
- 1999-06-14 JP JP2000554801A patent/JP2002518537A/en active Pending
- 1999-06-14 CN CN99807369A patent/CN1305503A/en active Pending
- 1999-06-14 BR BR9911256-6A patent/BR9911256A/en not_active Application Discontinuation
- 1999-06-14 EP EP99928624A patent/EP1095093A1/en not_active Withdrawn
- 1999-06-14 JP JP2000554785A patent/JP2002518218A/en active Pending
- 1999-06-14 WO PCT/US1999/013351 patent/WO1999065988A1/en not_active Application Discontinuation
- 1999-06-14 EP EP99928636A patent/EP1088034A1/en not_active Withdrawn
- 1999-06-14 US US09/332,829 patent/US6254950B1/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4440922A (en) * | 1983-04-13 | 1984-04-03 | Eastman Kodak Co. | Polyester containers having improved gas barrier properties |
EP0139726A1 (en) * | 1983-04-13 | 1985-05-08 | Eastman Kodak Co | Container having improved gas barrier properties. |
EP0335594A2 (en) * | 1988-03-26 | 1989-10-04 | Mitsubishi Chemical Corporation | Copolymerized polymer |
US4959421A (en) * | 1988-03-26 | 1990-09-25 | Mitsubishi Kasei Corporation | Copolymerized polyester having excellent transparency and gas barrier properties |
JPH05295241A (en) * | 1992-04-21 | 1993-11-09 | Denki Kagaku Kogyo Kk | Polyester resin composition |
Non-Patent Citations (1)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 018, no. 097 (C - 1167) 17 February 1994 (1994-02-17) * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1038905A2 (en) * | 1999-03-26 | 2000-09-27 | Mitsubishi Polyester Film GmbH | Transparent, UV-stabilised film from a crystallisable thermoplastic material |
EP1038905A3 (en) * | 1999-03-26 | 2001-01-31 | Mitsubishi Polyester Film GmbH | Transparent, UV-stabilised film from a crystallisable thermoplastic material |
US6855435B2 (en) | 1999-03-26 | 2005-02-15 | Mitsubishi Polyester Film Gmbh | Transparent, UV-stabilized film made from a crystallizable thermoplastic |
WO2013029042A2 (en) | 2011-08-25 | 2013-02-28 | Plastipak Packaging, Inc. | Extruded pet parison, container, and method |
JP2014527924A (en) * | 2011-08-25 | 2014-10-23 | プラスチパック パッケージング,インコーポレイテッド | Extruded PET parison, container, and method |
EP2747981A4 (en) * | 2011-08-25 | 2015-09-30 | Plastipak Packaging Inc | Extruded pet parison, container, and method |
AU2012298664B2 (en) * | 2011-08-25 | 2017-07-20 | Plastipak Packaging, Inc. | Extruded PET parison, container, and method |
EP2807082A4 (en) * | 2012-01-25 | 2016-10-12 | Plastipak Packaging Inc | Extruded pet parison, container, and method |
Also Published As
Publication number | Publication date |
---|---|
AR019660A1 (en) | 2002-03-13 |
CA2332519A1 (en) | 1999-12-23 |
AR018672A1 (en) | 2001-11-28 |
CN1312837A (en) | 2001-09-12 |
CA2334464A1 (en) | 1999-12-23 |
JP2002518218A (en) | 2002-06-25 |
US6254950B1 (en) | 2001-07-03 |
CA2334828A1 (en) | 1999-12-23 |
CN1305503A (en) | 2001-07-25 |
WO1999065967A1 (en) | 1999-12-23 |
EP1095093A1 (en) | 2001-05-02 |
WO1999065988A1 (en) | 1999-12-23 |
BR9911254A (en) | 2001-03-13 |
EP1088034A1 (en) | 2001-04-04 |
JP2002518537A (en) | 2002-06-25 |
BR9911262A (en) | 2001-03-13 |
CN1305511A (en) | 2001-07-25 |
EP1088033A1 (en) | 2001-04-04 |
JP2002518536A (en) | 2002-06-25 |
AR017749A1 (en) | 2001-10-24 |
BR9911256A (en) | 2001-03-13 |
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