WO1999058243A3 - Ion exchange materials - Google Patents

Ion exchange materials Download PDF

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Publication number
WO1999058243A3
WO1999058243A3 PCT/GB1999/001517 GB9901517W WO9958243A3 WO 1999058243 A3 WO1999058243 A3 WO 1999058243A3 GB 9901517 W GB9901517 W GB 9901517W WO 9958243 A3 WO9958243 A3 WO 9958243A3
Authority
WO
WIPO (PCT)
Prior art keywords
ion exchange
materials
metal cation
cations
ordination
Prior art date
Application number
PCT/GB1999/001517
Other languages
French (fr)
Other versions
WO1999058243A2 (en
Inventor
Alan Dyer
Martyn Pillinger
Jonathan Andrew Newton
Risto Olavi Harjula
Johanna Teresia Moller
Esko Heikki Tusa
Amin Suheel
Maurice Webb
Original Assignee
British Nuclear Fuels Plc
Alan Dyer
Martyn Pillinger
Jonathan Andrew Newton
Risto Olavi Harjula
Johanna Teresia Moller
Esko Heikki Tusa
Amin Suheel
Maurice Webb
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Nuclear Fuels Plc, Alan Dyer, Martyn Pillinger, Jonathan Andrew Newton, Risto Olavi Harjula, Johanna Teresia Moller, Esko Heikki Tusa, Amin Suheel, Maurice Webb filed Critical British Nuclear Fuels Plc
Priority to AU39407/99A priority Critical patent/AU3940799A/en
Publication of WO1999058243A2 publication Critical patent/WO1999058243A2/en
Publication of WO1999058243A3 publication Critical patent/WO1999058243A3/en

Links

Classifications

    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • G21F9/06—Processing
    • G21F9/12—Processing by absorption; by adsorption; by ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/02—Processes using inorganic exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/10—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/12—Compounds containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/14—Base exchange silicates, e.g. zeolites

Abstract

A method of selectively removing a target metal cation from a liquid medium containing at least one other metal cation involves the use of an ion exchange material selected from four groups: 1) crystalline materials synthesised from octahedral/tetrahedral co-ordination polyhedra; 2) layered oxide materials, including those with inorganic pillars incorporated between the layers; 3) high silica materials, including those with large mesoporosity; and 4) microporous materials with interstitial cations other than Si or Al in tetrahedral co-ordination. At least one of the pore size, the layer charge density, the interlayer cations and the doping metal cations are controlled to render the ion exchange material selective towards the target metal cation.
PCT/GB1999/001517 1998-05-14 1999-05-13 Ion exchange materials WO1999058243A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU39407/99A AU3940799A (en) 1998-05-14 1999-05-13 Ion exchange materials

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9810271.8 1998-05-14
GBGB9810271.8A GB9810271D0 (en) 1998-05-14 1998-05-14 Ion exchange materials

Publications (2)

Publication Number Publication Date
WO1999058243A2 WO1999058243A2 (en) 1999-11-18
WO1999058243A3 true WO1999058243A3 (en) 2000-04-20

Family

ID=10831988

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1999/001517 WO1999058243A2 (en) 1998-05-14 1999-05-13 Ion exchange materials

Country Status (3)

Country Link
AU (1) AU3940799A (en)
GB (1) GB9810271D0 (en)
WO (1) WO1999058243A2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8759597B2 (en) 2012-04-18 2014-06-24 Uop Llc Methods for producing zeolite catalysts and methods for producing alkylated aromatic compounds using the zeolite catalysts
GB201317553D0 (en) * 2013-10-03 2013-11-20 Univ Central Lancashire Chromatographic Separation of Nuclear Waste
JP5696244B1 (en) * 2014-03-27 2015-04-08 日本化学工業株式会社 Adsorbent
WO2017086056A1 (en) * 2015-11-18 2017-05-26 国立大学法人香川大学 Strontium ion adsorbent and method for producing same
JP6610978B2 (en) * 2016-12-13 2019-11-27 国立大学法人 香川大学 Strontium ion adsorbent and method for producing the same
WO2018109823A1 (en) * 2016-12-13 2018-06-21 国立大学法人香川大学 Strontium ion adsorbent and production method therefor
CN114700031A (en) * 2022-06-07 2022-07-05 天津科技大学 Adsorbing material for extracting rubidium and cesium from liquid rubidium-cesium ore and preparation method thereof

Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1393546A (en) * 1964-02-13 1965-03-26 Commissariat Energie Atomique Improvements made to ion exchangers and their manufacturing processes
FR1399711A (en) * 1964-04-09 1965-05-21 Kuhlmann Ets Decontamination process for a radioactive solution
FR2310616A1 (en) * 1975-05-07 1976-12-03 Shin Tohoku Chemical Ind Co Lt RADIO-ACTIVE WASTE WATER TREATMENT PROCESS
US4059679A (en) * 1971-04-08 1977-11-22 Ohio University Modified zirconium phosphates
EP0051999A1 (en) * 1980-11-10 1982-05-19 Exxon Research And Engineering Company Intercalated layered mixed oxides
US4623527A (en) * 1983-12-19 1986-11-18 Mobil Oil Corporation Crystalline silicophosphoaluminate (MCM-10)
US4808318A (en) * 1988-04-25 1989-02-28 The United States Of America As Represented By The United States Department Of Energy Process for cesium decontamination and immobilization
EP0405978A1 (en) * 1989-06-29 1991-01-02 Engelhard Corporation Large-pored molecular sieves and their use as catalysts and ion exchangers
WO1991018833A1 (en) * 1990-05-28 1991-12-12 Engelhard Corporation Large-pored molecular sieves containing at least one octahedral site and tetrahedral sites of at least one type
FR2666591A1 (en) * 1990-09-06 1992-03-13 Centre Nat Rech Scient Process and device for selective recovery of silver ions in solution, eluent compositions for recovery and use of the composition
US5137706A (en) * 1991-02-12 1992-08-11 Mobil Oil Corporation Crystalline compositions
US5223022A (en) * 1988-09-08 1993-06-29 Engelhard Corporation Ion-exchange agent and use thereof in extracting heavy metals from aqueous solutions
WO1995000441A1 (en) * 1993-06-17 1995-01-05 The University Of Queensland Kaolin derivatives
WO1997014652A1 (en) * 1995-10-20 1997-04-24 Alliedsignal Inc. Partially crystalline layered sodium titanate
WO1999003576A1 (en) * 1997-07-15 1999-01-28 Alliedsignal Inc. Chemically modified micas for removal of cesium salts from aqueous solution
US5888472A (en) * 1997-04-08 1999-03-30 Uop Llc Zirconium silicate molecular sieves and process using the same

Patent Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1393546A (en) * 1964-02-13 1965-03-26 Commissariat Energie Atomique Improvements made to ion exchangers and their manufacturing processes
FR1399711A (en) * 1964-04-09 1965-05-21 Kuhlmann Ets Decontamination process for a radioactive solution
US4059679A (en) * 1971-04-08 1977-11-22 Ohio University Modified zirconium phosphates
FR2310616A1 (en) * 1975-05-07 1976-12-03 Shin Tohoku Chemical Ind Co Lt RADIO-ACTIVE WASTE WATER TREATMENT PROCESS
EP0051999A1 (en) * 1980-11-10 1982-05-19 Exxon Research And Engineering Company Intercalated layered mixed oxides
US4623527A (en) * 1983-12-19 1986-11-18 Mobil Oil Corporation Crystalline silicophosphoaluminate (MCM-10)
US4808318A (en) * 1988-04-25 1989-02-28 The United States Of America As Represented By The United States Department Of Energy Process for cesium decontamination and immobilization
US5223022A (en) * 1988-09-08 1993-06-29 Engelhard Corporation Ion-exchange agent and use thereof in extracting heavy metals from aqueous solutions
EP0405978A1 (en) * 1989-06-29 1991-01-02 Engelhard Corporation Large-pored molecular sieves and their use as catalysts and ion exchangers
WO1991018833A1 (en) * 1990-05-28 1991-12-12 Engelhard Corporation Large-pored molecular sieves containing at least one octahedral site and tetrahedral sites of at least one type
FR2666591A1 (en) * 1990-09-06 1992-03-13 Centre Nat Rech Scient Process and device for selective recovery of silver ions in solution, eluent compositions for recovery and use of the composition
US5137706A (en) * 1991-02-12 1992-08-11 Mobil Oil Corporation Crystalline compositions
WO1995000441A1 (en) * 1993-06-17 1995-01-05 The University Of Queensland Kaolin derivatives
WO1997014652A1 (en) * 1995-10-20 1997-04-24 Alliedsignal Inc. Partially crystalline layered sodium titanate
US5888472A (en) * 1997-04-08 1999-03-30 Uop Llc Zirconium silicate molecular sieves and process using the same
WO1999003576A1 (en) * 1997-07-15 1999-01-28 Alliedsignal Inc. Chemically modified micas for removal of cesium salts from aqueous solution

Non-Patent Citations (10)

* Cited by examiner, † Cited by third party
Title
ALBERTI G ET AL: "ION-EXCHANGE PROPERTIES OF ZIRCONIUM PHOSPHATE-PHOSPHITE, A LAYERED COMPOUND WITH ASYMMETRICAL LAYERS", REACTIVE POLYMERS, ION EXCHANGERS, SORBENTS,NL,ELSEVIER SCIENCE PUBLISHERS, AMSTERDAM, vol. 9, no. 3, + INDEX, 1 December 1988 (1988-12-01), pages 267 - 276, XP000004403 *
ALBERTI G. ET AL.: "CRYSTALLINE INSOLUBLE ACID SALTS OF TETRAVALENT METALS--XIX; Na+-CATALYSED H+-Mg2+ AND H+-Cs+ ION EXCHANGES ON alpha-ZIRCONIUM PHOSPHATE", JOURNAL OF INORGANIC AND NUCLEAR CHEMISTRY., vol. 36, no. 9, September 1974 (1974-09-01), PERGAMON PRESS LTD. OXFORD., GB, pages 2109 - 2114, XP000874268 *
BAETSLE, LEO H. ET AL: "Ion-exchange properties of zirconium and titanium phosphates and their use in the separation of nuclear reaction products", ION EXCH. PROCESS IND., PAP. CONF. (1970), MEETING DATE 1969, 209-15 PUBLISHER: SOC. CHEM. IND, LONDON, ENGL., 1970, XP000874517 *
Eleventh Toyota Conference on Nanostructured Materials in biological and Artificial Systems 5-8 November 1997 Japan *
G.T. DESAI ET AL.: "Ion-Exchange Properties of Titanium Silicates", INDIAN JOURNAL OF TECHNOLOGY., vol. 16, May 1978 (1978-05-01), COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEARCH, NEW DEHLI., IN, pages 204 - 206, XP002114761, ISSN: 0019-5669 *
MINTOVA S ET AL: "Kinetic investigation of the effect of Na, K, Li and Ca on the crystallization of titanium silicate ETS-4", ZEOLITES, vol. 18, no. 4, 1 April 1997 (1997-04-01), pages 269-273, XP004082859, ISSN: 0144-2449 *
SMIRNOV G I ET AL: "SYNTHESIS AND ION-EXCHANGE PROPERTIES OF TIN PHOSPHATE FOR EXHAUSTIVE REMOVAL OF POTASSIUM FROM SODIUM SALTS", RUSSIAN JOURNAL OF APPLIED CHEMISTRY,US,CONSULTANTS BUREAU, vol. 62, no. 11 PART 01, 1 November 1989 (1989-11-01), pages 2252 - 2256, XP000141277, ISSN: 1070-4272 *
TANEV, PETER T. ET AL: "Biomimetic assembly of porous lamellar silica molecular sieves with a vesicular particle architecture", SUPRAMOL. SCI. (1998), 5(3-4), 399-404, 1998, XP000874514 *
V.V. VOL'KIN ET AL.: "SOME WAYS OF MODIFYING ION-EXCHANGERS BASED ON THE DIOXIDES OF MANGANESE AND TITANIUM", JOURNAL OF APPLIED CHEMISTRY OF USSR., vol. 50, no. 4, April 1977 (1977-04-01), CONSULTANTS BUREAU. NEW YORK. 481975 11, US, pages 719 - 722, XP002114762 *
VALTCHEV V ET AL: "Comparison of physicochemical properties of zorite and ETS-4", MATERIALS RESEARCH BULLETIN, vol. 31, no. 2, 1 February 1996 (1996-02-01), pages 163-169, XP004075955, ISSN: 0025-5408 *

Also Published As

Publication number Publication date
WO1999058243A2 (en) 1999-11-18
GB9810271D0 (en) 1998-07-15
AU3940799A (en) 1999-11-29

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