WO1999021432A1 - Flavouring materials for use in tea containing beverages - Google Patents
Flavouring materials for use in tea containing beverages Download PDFInfo
- Publication number
- WO1999021432A1 WO1999021432A1 PCT/EP1998/006637 EP9806637W WO9921432A1 WO 1999021432 A1 WO1999021432 A1 WO 1999021432A1 EP 9806637 W EP9806637 W EP 9806637W WO 9921432 A1 WO9921432 A1 WO 9921432A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- beverage
- ppm
- compound
- tea
- antimicrobial
- Prior art date
Links
- 0 C*=*c(cc1)ccc1O Chemical compound C*=*c(cc1)ccc1O 0.000 description 2
- PETRWTHZSKVLRE-UHFFFAOYSA-N Cc(cc1OC)ccc1O Chemical compound Cc(cc1OC)ccc1O PETRWTHZSKVLRE-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23F—COFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
- A23F3/00—Tea; Tea substitutes; Preparations thereof
- A23F3/40—Tea flavour; Tea oil; Flavouring of tea or tea extract
- A23F3/405—Flavouring with flavours other than natural tea flavour or tea oil
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23F—COFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
- A23F3/00—Tea; Tea substitutes; Preparations thereof
- A23F3/16—Tea extraction; Tea extracts; Treating tea extract; Making instant tea
- A23F3/163—Liquid or semi-liquid tea extract preparations, e.g. gels, liquid extracts in solid capsules
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/20—Synthetic spices, flavouring agents or condiments
- A23L27/204—Aromatic compounds
Definitions
- the present invention relates to the use of natural and synthetically prepared flagrant materials which also act as antimicrobials in aqueous based beverages containing tea solids. These materials are selected substituted phenyl compounds.
- Acidified and native pH ready-to-drink (RTD) tea beverages in the 2.5-6.5 pH range regardless of packaging are known to be susceptible to spoilage.
- tea beverages packaged in glass and plastic bottles (because of increased 02 ingress) as well as tea beverages at the higher range of the pH spectrum, are even more sensitive to yeast and mould spoilage than canned teas.
- RTD ready-to-drink
- the bottles can all be sterilised and the tea beverage first pasteurised and then bottled at high temperature.
- Each of these high temperature treatments requires a large capital investment for equipment and if there were many different bottling plants the costs of equipping each of these multiple plants with such high temperature equipment would be prohibitive if not impossible to justify.
- Further all of these high temperature expedients are relatively inefficient and require a very high use of energy and excessive costs in addition to the original equipment costs. It is thus seen to be desirable to be able to prepare and bottle RTD teas without using such cost ineffective, energy intensive methods which also require a large initial investment in equipment.
- the steps include employing water having a very low water hardness; using a pH of about 2.5 to 4.0; using selected sequestrants with the pH and water adjustments; using selected polyphospates in combination with the pH water and sequestrants; and using selected well known preservatives such as nisin, natamycin, sorbic acid and sorbates and benzoic acid and benzoates together with the low water hardness, the pH adjustment, sequestrants and polyphosphates . Together these steps contribute to the antimicrobial effect and thus individually each is incrementally antimicrobially effective.
- a method and composition for imparting a pleasant flavour to tea beverages while simultaneously contributing to the control of microbial growth in ready- to-drink still and carbonated tea beverages, for distribution and sale at ambient or chilled temperatures .
- a method and composition incorporating a stepwise or "hurdle” approach described above is disclosed.
- the beverages include herbal teas, both "still” and carbonated as well as black, oolong and green tea.
- the method uses selected compounds in optional combination with the hurdle or step approach. These natural compounds may be obtained naturally or synthesised.
- the method which also contributes to the stability of tea beverages employs a class of chemical compounds characterised by a structure containing an aromatic base, preferably an aromatic acid such as phenylbutenoic or phenylhexenoic acid and selected derivatives.
- aromatic base preferably an aromatic acid such as phenylbutenoic or phenylhexenoic acid and selected derivatives.
- aromatic based compounds are as follows:
- Rj_ is an unsaturated, non-halogenated side chain having up to about 9 carbons, one of which is preferably a carboxyl group, which may or may not be esterified, and the side chain has at least one double bond.
- the Ri side chain preferably has up to about 6 carbon atoms.
- the R x side chain may contain unsaturated molecular components from the ester, alcohol, ketone or acid families.
- the compounds contain, as well, additional R 2 _ 6 groups occupying the other sites on the benzene ring
- R 2 _ 6 may be the same or diff-erent and may be hydrogen or a low molecular weight non-halogenated neutral or electronegative group such as O, COOH, OH, OCH 3 0C 2 H 5 , CH 3 and C 2 H 5 among others but at least one of R 2 - 6 must be a low molecular weight group.
- Examples of such compounds include the naturally occurring sinapic, caffeic, coumaric, chlorogenic and ferulic acids as well as eugenol, and anethole among others. These compounds, impart pleasant or unique desirable and distinctive flavour to tea beverages when properly combined.
- acidified and native pH based tea beverages including juice flavoured and juice containing tea beverages in the 2.5-7.0 pH range are known to be susceptible to spoilage by yeast, mould, acid tolerant bacteria (e.g. Lactobacillus sp, Gluconobacter/Acetobacter sp . ) and/or mesophilic or thermophilic spore forming (e.g. B . coagulans and the Alicyclobacillus sp .
- acid tolerant bacteria e.g. Lactobacillus sp, Gluconobacter/Acetobacter sp .
- mesophilic or thermophilic spore forming e.g. B . coagulans and the Alicyclobacillus sp .
- the compounds of the invention such as 3 , 4-dihydroxycinnamic acids (i.e. caffeic acid), 4- hydroxy-3-methoxycinnamic acid (i.e. ferulic acid) and 3- caffeoylquinic acid (i . e . chlorogenic acid) alone, when formulated in combination with low levels of sorbic or benzoic acid and mixtures of these as well as other flavour components contribute to a pleasant unique, desirable and distinctive flavoured tea while adding the benefit of their antimicrobial activity.
- the compounds may be used at individual concentrations of preferably from about 25 to about 600 ppm and while used primarily as a flavourant have been found to be extremely effective antimicrobials .
- the compounds are effective against yeast, mould, and other acid tolerant and non-acid tolerant spore-forming and non-spore-forming spoilage bacteria in ready-to-drink tea beverages and tea beverages containing juice, fruit or vegetable extracts and/or additional flavours.
- the small size of the attached groups facilitates passage through the cell membrane and concentrates the energy of reaction once inside the cell.
- These combinations include H, OH, CH 3 , NH 2 , 0CH 3 as "activating" (electron releasing) groups, and COOH, COCH 3 , CHO, N0 2 alone or attached to short unsaturated carbon chains, as electron withdrawing groups that become released as highly reactive charged or free radical species.
- the use of the disclosed class of compounds provides a portfolio of antimicrobial compounds that may be used to formulate beverages which are "all-natural", by the current definition of the term.
- pleasantly flavoured, ready-to-drink still and carbonated tea beverages that are stable and safe at ambient temperatures and/or that have an extended shelf life at chill temperatures are thus enabled.
- the flexibility of the class of compounds affords a broad selection of agents suited to complement enhance and/or contribute of unique, desirable and distinctive flavour to the flavour profile of the tea beverage system
- the antimicrobial material operates as follows : Essentially the organism will typically passively transport the compound class described, in its non-dissociated (unchanged) state. Once the compound is in the cell it begins to dissociate, essentially upsetting the pH balance internal to the cell.
- An organism such as Z. bailii , one of the yeast species that poses a serious spoilage problem in beverages is reported to possess an ability to pump a preservative such as benzoic acid out quite readily thus, leading to Z . baiiii 's reputation as being somewhat preservative resistant.
- the compounds of the present invention are less likely to succumb to the preservative pump because of added high reactivity of the unsaturated side chain. It is believed that for this reason compounds of the type disclosed are effective .
- flavourant/antimicrobial compounds of the invention provide improved stability in tea beverages when the magnesium and calcium ions common to tap water are kept to a minimum of no more than about 300 ppm as CaC0 3 .
- the hardness is less than about 100 ppm and most preferably less than about 50 ppm or even lower such as 25 ppm or less. This can be achieved by deionization reverse osmosis or ion exchange in appropriate manner .
- selected phosphates also contribute to stability and flavour and thus about 100 ppm to about 1000 ppm or higher and preferably about 250 to 500 ppm of a polyphosphate having the formula:
- m averages about 3 to 100 and M may be sodium or potassium.
- preservatives such as sorbic acid or sorbate and benzoic acid or benzoates or parabens used alone or in combination at levels of about 50 to 1000 ppm provide a benefit without effecting flavour.
- Additional sequestrants such as EDTA, NTA and the like have also been found to be useful in amounts of about 20 ppm up to about 1 000 ppm and preferably about 30 ppm to about 1000 ppm. When EDTA is used the lower levels are preferred.
- tea concentrate refers to a product derived from concentrated tea extract which is diluted with water to form a drinkable tea beverage.
- the method of extraction is not significant and any method known in the art may be used.
- tea beverage refers to a drinkable beverage prepared from tea concentrates, extracts or powder. Usually the beverage is prepared by mixing with water. Various other flavouring agents and/or juices may also be included in the tea beverage such as fruit juices, vegetable juices and the like. If a concentrate or powder is used then the concentrate or powder is generally diluted with sufficient water to provide the tea beverage. Preferred tea concentrates or powders are typically diluted to about 0.06 to 0.4% tea solids and preferably about 0.08 to 0.2% tea solids to provide a drinkable tea beverage but this depends on the flavour profile sought and amounts of 0.01 to 0.5% or higher may be used.
- tea solids refers to those solids normally present in a tea extract including normal tea antioxidants .
- Polyphenolic compounds are normally the primary component of tea solids when prepared from an extract of Camellia sinensis .
- tea solids can also include caffeine, proteins, amino acids, minerals and carbohydrates.
- sequestrants including EDTA; 4. polyphosphate;
- a ready to drink (RTD) tea composition containing about
- 0.08% tea solids was prepared having the following general composition.
- Water hardness measured as Ca(C0 3 ) in the presence and absence of 30 pp of EDTA was studied at different water hardness levels including 28 ppm; 36 ppm; 72 ppm and 138 ppm.
- the RTD beverage was prepared as above at several water hardness levels and inoculated with Z bailii , preservative resistant spoilage yeast at a level of 10 colony forming units (CFU) per ml of beverage.
- CFU colony forming units
- the beverage was then bottled and observed for failure such as a plate count with at least a 2 log increase; or "Frank Spoilage" such as for example C0 2 production or sediment or the like.
- Example 1 A study was done to determine the impact of hexametaphosphate at a level of about 500 ppm at a pH of 2. and 3.2.
- An RTD beverage was prepared and bottled as in Example 1 except it contained 30 ppm EDTA and the water hardness was 50 ppm.
- the beverage was inoculated with Z bailii at 1 CFU and 10 CFU. Hexametaphosphate was either present or absent.
- the tea beverage was prepared from tea extracted with hot water and containing about 0.12% tea solids.
- the tea extract was sweetened with high fructose corn syrup and flavoured with lemon flavour and citric acid to form the beverage.
- the pH was 2.8.
- a sorbate/benzoate control (Control A) was prepared from the above beverage by adding 200 ppm benzoic acid and 300 ppm sorbic acid.
- An unpreserved control (control B) , prepared from the same beverage but having no sorbate or benzoate was also included.
- test formulations were prepared by adding to the above beverage test compounds as follows :
- caffeic acid 220 ppm The tests were run in triplicate in 10 ml. culture tubes Each tube was inoculated with 1 CFU/ml of beverage of Z bailii preservative resistant yeast. The results are reported as follows:
- the compounds could be ranked relative to the benzoic acid/sorbic acid system.
- coumaric acid began gassing the same day as the benzoic/sorbic system which would give a coefficient of 1.
- Ferulic acid would have a coefficient of about 1.3.
- Example 4 A study was run to more precisely define the inhibitory effects of one of the flavouring components from Example 4. This study contained a tea beverage model containing the following components.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Tea And Coffee (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Non-Alcoholic Beverages (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR9813286-5A BR9813286A (en) | 1997-10-28 | 1998-10-09 | Tea drink, water-based drink, and processes for flavoring / preserving a tea drink and for improving the microbial stability of a tea drink |
JP2000517607A JP2001520866A (en) | 1997-10-28 | 1998-10-09 | Flavoring substances used in beverages containing tea |
EP98954434A EP1026955A1 (en) | 1997-10-28 | 1998-10-09 | Flavouring materials for use in tea containing beverages |
PL98340820A PL340820A1 (en) | 1997-10-28 | 1998-10-09 | Taste- and fragrance-giving materials as additives to tea-based beverages |
AU11548/99A AU732042B2 (en) | 1997-10-28 | 1998-10-09 | Flavouring materials for use in tea containing beverages |
CA002307871A CA2307871A1 (en) | 1997-10-28 | 1998-10-09 | Flavouring materials for use in tea containing beverages |
HU0100173A HUP0100173A3 (en) | 1997-10-28 | 1998-10-09 | Flavouring materials for use in tea containing beverages |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/958,959 US6022576A (en) | 1997-10-28 | 1997-10-28 | Flavoring materials for use in tea containing beverages |
US08/958,959 | 1997-10-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999021432A1 true WO1999021432A1 (en) | 1999-05-06 |
Family
ID=25501491
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1998/006637 WO1999021432A1 (en) | 1997-10-28 | 1998-10-09 | Flavouring materials for use in tea containing beverages |
Country Status (13)
Country | Link |
---|---|
US (1) | US6022576A (en) |
EP (1) | EP1026955A1 (en) |
JP (1) | JP2001520866A (en) |
CN (1) | CN1278142A (en) |
AU (1) | AU732042B2 (en) |
BR (1) | BR9813286A (en) |
CA (1) | CA2307871A1 (en) |
HU (1) | HUP0100173A3 (en) |
ID (1) | ID29935A (en) |
IN (1) | IN185397B (en) |
PL (1) | PL340820A1 (en) |
TR (1) | TR200001152T2 (en) |
WO (1) | WO1999021432A1 (en) |
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WO2000053036A1 (en) * | 1999-03-08 | 2000-09-14 | The Procter & Gamble Company | Beverage products having superior vitamin stability |
WO2001052796A2 (en) * | 2000-01-21 | 2001-07-26 | The Procter & Gamble Company | Methods of using a beverage composition for treating dental erosion |
JP2003038144A (en) * | 2001-07-26 | 2003-02-12 | Taiyo Kagaku Co Ltd | Flavor ingredient deterioration-preventing agent |
JP2003533201A (en) * | 2000-05-15 | 2003-11-11 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Environmentally stable beverage |
US6719963B2 (en) | 1996-02-20 | 2004-04-13 | Smithkline Beecham P.L.C. | Liquid oral compositions comprising a calcium compound and an acidulant |
US6984376B2 (en) | 2000-01-21 | 2006-01-10 | Procter & Gamble | Methods of inhibiting dental erosion/discoloration using a beverage composition comprising a long chain polyphosphate |
US7279152B2 (en) | 2000-03-27 | 2007-10-09 | Smithkline Beecham P.L.C. | Use of polyphosphate as a tooth erosion inhibitors in acidic compositions |
WO2010026003A1 (en) * | 2008-09-05 | 2010-03-11 | Unilever Plc | Flavan-3-ol containing foodstuffs |
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GB9819530D0 (en) | 1998-09-09 | 1998-10-28 | Smithkline Beecham Plc | Novel compositions and use |
US6586033B1 (en) | 1999-05-21 | 2003-07-01 | Lipton, Division Of Conopco, Inc. | Ionic stable emulsion sauce |
US6596336B1 (en) | 1999-05-21 | 2003-07-22 | Lipton, Division Of Conopco, Inc. | Microbiologically stable sauce emulsion |
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US8642051B2 (en) | 2000-03-21 | 2014-02-04 | Suzanne Jaffe Stillman | Method of hydration; infusion packet system(s), support member(s), delivery system(s), and method(s); with business model(s) and Method(s) |
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US8420141B2 (en) * | 2002-07-30 | 2013-04-16 | Pepsico, Inc. | Prevention of synthetic color fading in beverages using botanically derived color stabilizers |
AU2002348809A1 (en) * | 2002-12-16 | 2004-07-09 | Council Of Scientific And Industrial Research | A process for preparation of spiced tea concentrate and products thereof |
US7141264B2 (en) * | 2003-06-02 | 2006-11-28 | Unilever Bestfoods, North America, Division Of Conopco, Inc. | Functional water |
US20080213450A1 (en) * | 2007-03-02 | 2008-09-04 | F.B.C. Industries, Inc. | Antimicrobials Useful for Beverages |
EP2131665A1 (en) * | 2007-03-15 | 2009-12-16 | The Coca-Cola Company | Methods for inhibiting benzene formation in beverages and beverages produced thereby |
US8445044B2 (en) * | 2007-05-07 | 2013-05-21 | Kent Precision Foods Group, Inc. | Food thickening agent, method for producing food thickening agent |
US20090246344A1 (en) * | 2008-03-31 | 2009-10-01 | Sasaki Tea Manufacturing Co., Ltd. | Antioxidant Agent and Beverage Using Same |
US20100151104A1 (en) * | 2008-10-27 | 2010-06-17 | Pepsico, Inc. | Preservative System For Beverages Based On Combinations Of Trans-Cinnamic Acid, Lauric Arginate, And Dimethyl Dicarbonate |
US8628812B2 (en) * | 2008-12-30 | 2014-01-14 | Pepsico, Inc. | Preservative system for acidic beverages based on sequestrants |
JP5493987B2 (en) * | 2010-02-24 | 2014-05-14 | 栗田工業株式会社 | Reagent for hardness measurement |
JP5871491B2 (en) * | 2011-06-14 | 2016-03-01 | 花王株式会社 | Bitter taste inhibitor |
WO2013087401A1 (en) * | 2011-12-13 | 2013-06-20 | Firmenich Sa | Antifungal flavoring compositions |
US20140272000A1 (en) * | 2013-03-14 | 2014-09-18 | Metabolic Technologies, Inc. | Liquids and Foodstuffs Containing beta-hydroxy-beta-methylbutyrate (HMB) in the Free Acid Form and Methods of Manufacturing or Producing the Same |
US9101156B2 (en) | 2013-03-15 | 2015-08-11 | Kent Precision Foods Group, Inc. | Thickener composition, thickened nutritive products, methods for preparing thickened nutritive products, and methods for providing nutrition |
US9392814B2 (en) | 2014-06-06 | 2016-07-19 | Nicholas J. Singer | Delivery system for drinks |
USD773313S1 (en) | 2015-06-23 | 2016-12-06 | Nicholas J. Singer | Package |
CA3078234A1 (en) | 2017-10-06 | 2019-04-11 | Cargill, Incorporated | Readily dissolvable steviol glycoside compositions |
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US11751594B2 (en) | 2020-10-22 | 2023-09-12 | Grain Processing Corporation | Food thickener composition and method |
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JPS61195646A (en) * | 1985-02-27 | 1986-08-29 | Anan Koryo Sangyo Kk | Instant caffeic drink |
US4748033A (en) * | 1986-05-07 | 1988-05-31 | The Procter & Gamble Company | Tea concentrate having freeze thaw stability and enhanced cold water solubility |
JPH0427374A (en) * | 1990-05-23 | 1992-01-30 | T Hasegawa Co Ltd | Prevention of deterioration of flavor of food and drink |
CN1088739A (en) * | 1992-12-29 | 1994-07-06 | 王树力 | Honeysuckle tea preparation |
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1997
- 1997-10-28 US US08/958,959 patent/US6022576A/en not_active Expired - Fee Related
-
1998
- 1998-10-09 CA CA002307871A patent/CA2307871A1/en not_active Abandoned
- 1998-10-09 HU HU0100173A patent/HUP0100173A3/en unknown
- 1998-10-09 BR BR9813286-5A patent/BR9813286A/en not_active IP Right Cessation
- 1998-10-09 AU AU11548/99A patent/AU732042B2/en not_active Ceased
- 1998-10-09 CN CN98810617A patent/CN1278142A/en active Pending
- 1998-10-09 EP EP98954434A patent/EP1026955A1/en not_active Withdrawn
- 1998-10-09 WO PCT/EP1998/006637 patent/WO1999021432A1/en not_active Application Discontinuation
- 1998-10-09 PL PL98340820A patent/PL340820A1/en unknown
- 1998-10-09 TR TR2000/01152T patent/TR200001152T2/en unknown
- 1998-10-09 ID IDW20000774D patent/ID29935A/en unknown
- 1998-10-09 JP JP2000517607A patent/JP2001520866A/en not_active Withdrawn
- 1998-10-23 IN IN681BO1998 patent/IN185397B/en unknown
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US6719963B2 (en) | 1996-02-20 | 2004-04-13 | Smithkline Beecham P.L.C. | Liquid oral compositions comprising a calcium compound and an acidulant |
US6908909B2 (en) | 1996-02-20 | 2005-06-21 | Smithkline Beecham Plc | Liquid oral compositions comprising a calcium compound and an acidulant |
WO2000053036A1 (en) * | 1999-03-08 | 2000-09-14 | The Procter & Gamble Company | Beverage products having superior vitamin stability |
US6984376B2 (en) | 2000-01-21 | 2006-01-10 | Procter & Gamble | Methods of inhibiting dental erosion/discoloration using a beverage composition comprising a long chain polyphosphate |
WO2001052796A2 (en) * | 2000-01-21 | 2001-07-26 | The Procter & Gamble Company | Methods of using a beverage composition for treating dental erosion |
WO2001052796A3 (en) * | 2000-01-21 | 2001-12-20 | Procter & Gamble | Methods of using a beverage composition for treating dental erosion |
US9585827B2 (en) | 2000-01-21 | 2017-03-07 | The Procter & Gamble Company | Kits comprising a beverage composition and information for use |
JP2003520040A (en) * | 2000-01-21 | 2003-07-02 | ザ プロクター アンド ギャンブル カンパニー | Method of using a beverage composition for treating tooth erosion |
US7279152B2 (en) | 2000-03-27 | 2007-10-09 | Smithkline Beecham P.L.C. | Use of polyphosphate as a tooth erosion inhibitors in acidic compositions |
JP2003533201A (en) * | 2000-05-15 | 2003-11-11 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Environmentally stable beverage |
JP4605949B2 (en) * | 2001-07-26 | 2011-01-05 | 太陽化学株式会社 | Degradation preventive agent for flavor components |
JP2003038144A (en) * | 2001-07-26 | 2003-02-12 | Taiyo Kagaku Co Ltd | Flavor ingredient deterioration-preventing agent |
WO2010026003A1 (en) * | 2008-09-05 | 2010-03-11 | Unilever Plc | Flavan-3-ol containing foodstuffs |
EA018270B1 (en) * | 2008-09-05 | 2013-06-28 | Унилевер Н.В. | Compounds and compositions for reduction or elimination of bitterness caused by flavan-3-ols |
Also Published As
Publication number | Publication date |
---|---|
CA2307871A1 (en) | 1999-05-06 |
EP1026955A1 (en) | 2000-08-16 |
AU732042B2 (en) | 2001-04-12 |
AU1154899A (en) | 1999-05-17 |
CN1278142A (en) | 2000-12-27 |
ID29935A (en) | 2001-10-25 |
IN185397B (en) | 2001-01-13 |
PL340820A1 (en) | 2001-02-26 |
JP2001520866A (en) | 2001-11-06 |
US6022576A (en) | 2000-02-08 |
BR9813286A (en) | 2000-08-22 |
HUP0100173A2 (en) | 2001-05-28 |
HUP0100173A3 (en) | 2001-11-28 |
TR200001152T2 (en) | 2000-09-21 |
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