WO1998046651A3 - Living olefin polymerization processes - Google Patents

Living olefin polymerization processes Download PDF

Info

Publication number
WO1998046651A3
WO1998046651A3 PCT/US1998/007466 US9807466W WO9846651A3 WO 1998046651 A3 WO1998046651 A3 WO 1998046651A3 US 9807466 W US9807466 W US 9807466W WO 9846651 A3 WO9846651 A3 WO 9846651A3
Authority
WO
Grant status
Application
Patent type
Prior art keywords
processes
group
ligand
atoms
initiators
Prior art date
Application number
PCT/US1998/007466
Other languages
French (fr)
Other versions
WO1998046651A2 (en )
Inventor
Richard R Schrock
Robert Baumann
Original Assignee
Massachusetts Inst Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/28Titanium compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/02Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C217/04Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C217/06Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one etherified hydroxy group and one amino group bound to the carbon skeleton, which is not further substituted
    • C07C217/08Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one etherified hydroxy group and one amino group bound to the carbon skeleton, which is not further substituted the oxygen atom of the etherified hydroxy group being further bound to an acyclic carbon atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/78Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
    • C07C217/80Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings
    • C07C217/82Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring
    • C07C217/90Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring the oxygen atom of at least one of the etherified hydroxy groups being further bound to a carbon atom of a six-membered aromatic ring, e.g. amino-diphenylethers
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/003Compounds containing elements of Groups 4 or 14 of the Periodic System without C-Metal linkages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/903Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity

Abstract

Processes for the living polymerization of olefin monomers with terminal carbon-carbon double bonds are disclosed. The processes employ initiators that include a metal atom and a ligand having two group 15 atoms and a group 16 atom or three group 15 atoms. The ligand is bonded to the metal atom through two anionic or covalent bonds and a dative bond. The initiators are particularly stable under reaction conditions in the absence of olefin monomer. The processes provide polymers having low polydispersities, especially block copolymers having low polydispersities. It is an additional advantage of these processes that, during block copolymer synthesis, a relatively small amount of homopolymer is formed.
PCT/US1998/007466 1997-04-11 1998-04-09 Living olefin polymerization processes WO1998046651A3 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US08/843,161 1997-04-11
US08843161 US5889128A (en) 1997-04-11 1997-04-11 Living olefin polymerization processes

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CA 2285964 CA2285964C (en) 1997-04-11 1998-04-09 Living olefin polymerization processes
DE1998610605 DE69810605D1 (en) 1997-04-11 1998-04-09 living olefin polymerization
JP54419898A JP2001520696A (en) 1997-04-11 1998-04-09 Living olefin polymerization process
DE1998610605 DE69810605T2 (en) 1997-04-11 1998-04-09 living olefin polymerization
EP19980915559 EP0975579B1 (en) 1997-04-11 1998-04-09 Living olefin polymerization processes

Publications (2)

Publication Number Publication Date
WO1998046651A2 true WO1998046651A2 (en) 1998-10-22
WO1998046651A3 true true WO1998046651A3 (en) 1999-03-25

Family

ID=25289222

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1998/007466 WO1998046651A3 (en) 1997-04-11 1998-04-09 Living olefin polymerization processes

Country Status (6)

Country Link
US (5) US5889128A (en)
EP (1) EP0975579B1 (en)
JP (1) JP2001520696A (en)
CA (1) CA2285964C (en)
DE (2) DE69810605T2 (en)
WO (1) WO1998046651A3 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE41897E1 (en) 1999-10-22 2010-10-26 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US9234060B2 (en) 2011-11-08 2016-01-12 Univation Technologies, Llc Methods of preparing a catalyst system

Families Citing this family (98)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5889128A (en) 1997-04-11 1999-03-30 Massachusetts Institute Of Technology Living olefin polymerization processes
US6271325B1 (en) * 1999-05-17 2001-08-07 Univation Technologies, Llc Method of polymerization
US6271315B1 (en) 1999-06-17 2001-08-07 Wisconsin Alumni Research Foundation Methods for making multivalent arrays
US6291616B1 (en) 1999-06-17 2001-09-18 Wisconsin Alumni Research Foundation Methods and reagents for capping ruthenium or osmium carbene-catalyzed ROMP products
US6333423B1 (en) * 1999-09-10 2001-12-25 Ramot University Authority For Applied Research And Industrial Development Ltd. Ultra-high activity non-metallocene pre-catalyst and method for catalytic polymerization of alpha-olefin monomers
DE10002075C2 (en) 1999-09-20 2002-10-17 Solarlux Aluminium Sys Gmbh profile frame
JP2003511427A (en) * 1999-10-12 2003-03-25 ダウ グローバル テクノロジーズ インコーポレーテッド Dicationic nonmetallocene Group 4 metal complex
US6624107B2 (en) 1999-10-22 2003-09-23 Univation Technologies, Llc Transition metal catalyst compounds having deuterium substituted ligand and catalyst systems thereof
US6300438B1 (en) * 1999-10-22 2001-10-09 Univation Technolgies, Llc Hafnium transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6271323B1 (en) * 1999-10-28 2001-08-07 Univation Technologies, Llc Mixed catalyst compounds, catalyst systems and their use in a polymerization process
US6300439B1 (en) 1999-11-08 2001-10-09 Univation Technologies, Llc Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6417304B1 (en) 1999-11-18 2002-07-09 Univation Technologies, Llc Method of polymerization and polymer produced therefrom
US6265505B1 (en) * 1999-11-18 2001-07-24 Univation Technologies, Llc Catalyst system and its use in a polymerization process
US6380328B1 (en) 1999-12-10 2002-04-30 Univation Technologies, Llc Catalyst systems and their use in a polymerization process
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
EP1334118A4 (en) * 2000-03-21 2005-10-05 Wisconsin Alumni Res Found Methods and reagents for regulation of cellular responses in biological systems
US20040248801A1 (en) * 2000-03-21 2004-12-09 Kiessling Laura L. Methods and reagents for regulation of cellular responses in biological systems
KR100814980B1 (en) 2000-09-28 2008-03-18 프레지던트 앤드 펠로우즈 오브 하바드 칼리지 Vapor deposition of oxides, silicates, and phosphates
US6686490B1 (en) * 2000-11-06 2004-02-03 Ramot University Authority For Applied Research & Industrial Development Ltd. Active non-metallocene pre-catalyst and method for tactic catalytic polymerization of alpha-olefin monomers
JP2002206007A (en) * 2000-11-08 2002-07-26 Kanegafuchi Chem Ind Co Ltd Method for manufacturing olefinic block copolymer
US6656866B2 (en) * 2000-12-04 2003-12-02 Univation Technologies, Llc Catalyst preparation method
US6518444B1 (en) 2000-12-18 2003-02-11 Univation Technologies, Llc Preparation of polymerization catalysts
GB2374771B (en) * 2000-12-29 2004-07-07 Vtech Communications Ltd Frame structure with diversity
GB0102440D0 (en) 2001-01-31 2001-03-14 Borealis Tech Oy Catalyst
US20020119890A1 (en) * 2001-02-26 2002-08-29 Wenzel Timothy T. Catalyst preparation method
CA2447073A1 (en) * 2001-05-10 2002-11-14 Jessica A. Cook Olefin polymerization catalysts containing a pyrrole bisimine ligand
US7002049B2 (en) * 2002-08-19 2006-02-21 Eastman Chemical Company Process for α,β-dihydroxyalkenes and derivatives
WO2005108442A1 (en) 2002-10-15 2005-11-17 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
WO2005014674A3 (en) * 2003-08-04 2005-11-17 Dsm Ip Assets Bv Process for the preparation of a polyolefin
US7285606B2 (en) * 2003-08-04 2007-10-23 Dsm Ip Assets B.V. Process for the preparation of a polyolefin
EP1506974A1 (en) 2003-08-04 2005-02-16 DSM IP Assets B.V. Process for the preparation of a metalloorganic compound comprising at least one imine ligand
US7250523B2 (en) * 2003-10-22 2007-07-31 Board Of Trustees Of Michigan State University Imido-tethered carbenes of molybdenum for ring-opening metathesis polymerization and ring-closing metathesis
US6967184B2 (en) * 2004-02-17 2005-11-22 Univation Technologies, Llc Fluoroalcohol leaving group for non-metallocene olefin polymerization catalysts
US7193017B2 (en) * 2004-08-13 2007-03-20 Univation Technologies, Llc High strength biomodal polyethylene compositions
US8202940B2 (en) 2004-08-19 2012-06-19 Univation Technologies, Llc Bimodal polyethylene compositions for blow molding applications
US7399874B2 (en) * 2004-10-29 2008-07-15 Exxonmobil Chemical Patents Inc. Catalyst compound containing divalent tridentate ligand
US6987152B1 (en) 2005-01-11 2006-01-17 Univation Technologies, Llc Feed purification at ambient temperature
WO2006078021A1 (en) * 2005-01-21 2006-07-27 Riken Metal complex containing tridentate ligand, and polymerization catalyst comprising the same
US7312279B2 (en) * 2005-02-07 2007-12-25 Univation Technologies, Llc Polyethylene blend compositions
US7858702B2 (en) * 2005-06-14 2010-12-28 Univation Technologies, Llc Enhanced ESCR bimodal HDPE for blow molding applications
US7432328B2 (en) * 2005-06-14 2008-10-07 Univation Technologies, Llc Enhanced ESCR bimodal HDPE for blow molding applications
US7868092B2 (en) * 2005-06-14 2011-01-11 Univation Technologies, Llc Bimodal polyethylene compositions for blow molding applications
US7947797B2 (en) 2005-09-14 2011-05-24 Univation Technologies, Llc Method for operating a gas-phase reactor at or near maximum production rates while controlling polymer stickiness
US20070109911A1 (en) * 2005-11-16 2007-05-17 Neubauer Anthony C High speed and direct driven rotating equipment for polyolefin manufacturing
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
US20070203504A1 (en) * 2006-02-27 2007-08-30 Blair Denny Skin-marking devices and their use
WO2008042078A1 (en) * 2006-10-03 2008-04-10 Univation Technologies, Llc Effervescent nozzle for catalyst injection
US7932397B2 (en) * 2006-11-22 2011-04-26 Massachusetts Institute Of Technology Olefin metathesis catalysts and related methods
US9133081B2 (en) * 2007-11-15 2015-09-15 Univation Technologies, Llc Methods for the removal of impurities from polymerization feed streams
US8586497B2 (en) 2007-11-15 2013-11-19 Univation Technologies, Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
CA2712503C (en) * 2008-01-25 2017-04-18 Massachusetts Institute Of Technology Catalysts for metathesis reactions including enantioselective olefin metathesis, and related methods
US7910760B2 (en) * 2008-04-15 2011-03-22 Exxonmobil Chemical Patents Inc. Semi-rigid linked diamines, precursors therefor, and transition metal diamido complexes as catalysts for olefin polymerization processes
EP2112175A1 (en) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Activator for metallocenes comprising one or more halogen substituted heterocyclic heteroatom containing ligand coordinated to an alumoxane
RU2515900C2 (en) 2008-12-18 2014-05-20 Юнивейшн Текнолоджиз, Ллк Method of processing nucleating layer of polymerisation reaction
US8222469B2 (en) * 2009-07-15 2012-07-17 Massachusetts Institute Of Technology Catalysts and processes for the formation of terminal olefins by ethenolysis
US8158733B2 (en) * 2009-07-22 2012-04-17 Equistar Chemicals, Lp Catalysts based on 2-(2-aryloxy)quinoline or 2-(2-aryloxy)dihydroquinoline ligands
US8153544B2 (en) * 2009-07-22 2012-04-10 Equistar Chemicals, Lp Method for preparing non-metallocene catalysts
US7858718B1 (en) 2009-07-22 2010-12-28 Equistar Chemicals, Lp Catalysts based on 2-aryl-8-anilinoquinoline ligands
US8586685B2 (en) 2009-07-23 2013-11-19 Univation Technologies, Llc Polymerization reaction system
US8362311B2 (en) 2009-09-30 2013-01-29 Massachusetts Institute Of Technology Highly Z-selective olefins metathesis
WO2011078923A1 (en) 2009-12-23 2011-06-30 Univation Technologies, Llc Methods for producing catalyst systems
US8598400B2 (en) 2010-02-08 2013-12-03 Massachusetts Institute Of Technology Efficient methods for Z- or cis-selective cross-metathesis
CN102803308B (en) 2010-02-18 2015-04-01 尤尼威蒂恩技术有限公司 Methods for operating a polymerization reactor
CA2789687C (en) 2010-02-22 2018-03-06 Univation Technologies, Llc Catalyst systems and methods for using same to produce polyolefin products
WO2011129956A1 (en) 2010-04-13 2011-10-20 Univation Technologies, Llc Polymer blends and films made therefrom
US20120016092A1 (en) 2010-07-14 2012-01-19 Sandor Nagy Catalysts based on quinoline precursors
WO2012009216A1 (en) 2010-07-16 2012-01-19 Univation Technologies, Llc Systems and methods for measuring particle accumulation on reactor surfaces
WO2012009215A1 (en) 2010-07-16 2012-01-19 Univation Technologies, Llc Systems and methods for measuring static charge on particulates
WO2012015898A1 (en) 2010-07-28 2012-02-02 Univation Technologies, Llc Systems and methods for measuring velocity of a particle/fluid mixture
EP2646481B1 (en) 2010-11-30 2015-04-22 Univation Technologies, LLC Catalyst composition having improved flow characteristics and methods of making and using the same
WO2012074709A8 (en) 2010-11-30 2012-07-05 Univation Technologies, Llc Processes for the polymerization of olefins with extracted metal carboxylate salts
EP2651982B1 (en) 2010-12-17 2018-04-11 Univation Technologies, LLC Systems and methods for recovering hydrocarbons from a polyolefin purge gas product
ES2641112T3 (en) 2011-05-13 2017-11-07 Univation Technologies, Llc Catalyst compositions and spray dried polymerization processes that use
US8546500B2 (en) 2011-05-27 2013-10-01 Massachusetts Institute Of Technology Complexes for use in metathesis reactions
JP6266509B2 (en) 2011-06-03 2018-01-24 マサチューセッツ インスティテュート オブ テクノロジー Z-selective ring-closing metathesis reaction
WO2013028283A8 (en) 2011-08-19 2013-08-22 Univation Technologies, Llc Catalyst systems and methods for using same to produce polyolefin products
WO2013070602A1 (en) 2011-11-08 2013-05-16 Univation Technologies, Llc Methods for producing polyolefins with catalyst systems
WO2014106143A1 (en) 2012-12-28 2014-07-03 Univation Technologies, Llc Supported catalyst with improved flowability
CN104918947A (en) 2012-12-28 2015-09-16 尤尼威蒂恩技术有限责任公司 Methods for integrating aluminoxane production into catalyst production
CA2897456A1 (en) 2013-01-14 2014-07-17 Univation Technologies, Llc Methods for preparing catalyst systems with increased productivity
CN105189566A (en) 2013-01-30 2015-12-23 尤尼威蒂恩技术有限责任公司 Processes for making catalyst compositions having improved flow
JP6359034B2 (en) 2013-02-07 2018-07-18 ユニベーション・テクノロジーズ・エルエルシー Preparation of polyolefin
CN105143280B (en) 2013-03-15 2017-06-13 尤尼威蒂恩技术有限责任公司 Ligand catalyst
US9714305B2 (en) * 2013-03-15 2017-07-25 Univation Technologies, Llc Multiple catalyst system comprising metallocenes and tridentate nitrogen based ligand complexes for olefin polymerisation
US9644053B2 (en) 2013-03-15 2017-05-09 Univation Technologies, Llc Tridentate nitrogen based ligands for olefin polymerisation catalysts
WO2014197169A1 (en) 2013-06-05 2014-12-11 Univation Technologies, Llc Protecting phenol groups
CN103408577B (en) * 2013-08-13 2016-02-24 中国科学院化学研究所 Aminosilane compound and a preparation method based on aromatic diamine
WO2015153082A1 (en) 2014-04-02 2015-10-08 Univation Technologies, Llc Continuity compositions and methods of making and using the same
CN106459284A (en) 2014-06-16 2017-02-22 尤尼威蒂恩技术有限责任公司 Polyethylene resins
WO2016094870A1 (en) 2014-12-12 2016-06-16 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system comprising mesoporous organosilica support
CA2978925A1 (en) 2015-03-10 2016-09-15 Univation Technologies, Llc Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes
US20180100031A1 (en) 2015-04-17 2018-04-12 Univation Technologies, Llc Methods and systems for olefin polymerization
EP3286228A1 (en) 2015-04-24 2018-02-28 Univation Technologies, LLC Methods for operating a polymerization reactor
EP3288984A1 (en) 2015-04-27 2018-03-07 Univation Technologies, LLC Supported catalyst compositions having improved flow properties and preparation thereof
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
WO2018048472A1 (en) 2016-09-09 2018-03-15 Exxonmobil Chemical Patents Inc. Pilot plant scale semi-condensing operation
WO2018075243A1 (en) 2016-10-19 2018-04-26 Exxonmobil Chemical Patents Inc. Supported catalyst systems and methods of using same

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991012285A1 (en) * 1990-02-09 1991-08-22 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
WO1994021700A1 (en) * 1993-03-22 1994-09-29 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
JPH0881415A (en) * 1994-07-12 1996-03-26 Ube Ind Ltd Production of alkenecarboxylic acid ester
WO1997042197A1 (en) * 1996-05-02 1997-11-13 Societe De Conseils De Recherches Et D'applications Scientifiques (S.C.R.A.S.) New compounds having one group 13 element, bound with one mono- or di-anionic trident ligand, a method of preparation and application thereof as polymerisation catalysts

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4959436A (en) 1983-06-15 1990-09-25 Exxon Research And Engineering Co. Narrow MWD alpha-olefin copolymers
US4882406A (en) * 1983-06-15 1989-11-21 Exxon Research & Engineering Company Nodular copolymers formed of alpha-olefin copolymers coupled by non-conjugated dienes
US4480075A (en) * 1983-06-24 1984-10-30 Shell Oil Company Block copolymers of Ziegler-Natta polymerized and anionically polymerized monomers
JPH0612089B2 (en) * 1984-10-15 1994-02-16 本田技研工業株式会社 Idle speed feedback control method for an internal combustion engine
US4681956A (en) 1985-09-25 1987-07-21 Massachusetts Institute Of Technology Catalyst composition for effecting metathesis of olefins
US4752597A (en) 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
US4791180A (en) 1985-12-12 1988-12-13 Exxon Chemical Patents Inc. New polymerization catalyst
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5621126A (en) 1987-01-30 1997-04-15 Exxon Chemical Patents Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US5196491A (en) * 1988-11-25 1993-03-23 E. I. Du Pont De Nemours And Company Living cationic polymerization of alkyl vinyl ethers
US5026798A (en) 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5504169A (en) 1989-09-13 1996-04-02 Exxon Chemical Patents Inc. Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5079205A (en) 1990-07-13 1992-01-07 Exxon Chemical Patents Inc. Group ivb, vb and vib metal hydrocarbyloxides, with alumoxane for olefin polymerization
ES2085000T3 (en) * 1990-12-27 1996-05-16 Exxon Chemical Patents Inc A compound amido transition metal and a catalyst system for the production of isotactic polypropylene.
EP0501370B1 (en) * 1991-02-27 1998-11-25 Ticona GmbH Process for preparing cyclo-olefinic(co)polymers with a narrow molecular weigth distribution
US5399626A (en) * 1991-04-29 1995-03-21 Shell Oil Company Viscous conjugated diene block copolymers
JP3273944B2 (en) * 1991-11-25 2002-04-15 エクソンモービル・ケミカル・パテンツ・インク Polyanionic transition metal catalyst compositions
WO1993012151A1 (en) 1991-12-13 1993-06-24 Exxon Chemical Patents Inc. Ethylene/longer alpha-olefin copolymers
US5281368A (en) * 1992-03-31 1994-01-25 Exxon Chemical Patents Inc. Norbornene polymerization initiators and process for preparing same
DE69322082T2 (en) 1992-04-20 1999-06-17 Exxon Chemical Patents Inc Copolymers of ethylene with branched olefins
WO1994001471A1 (en) 1992-07-01 1994-01-20 Exxon Chemical Patents Inc. Transition metal olefin polymerization catalysts
US5635573A (en) 1992-12-01 1997-06-03 Exxon Chemical Patents Inc. Method for preparing alpha-olefin/cycloolefin copolymers
EP0610851B1 (en) * 1993-02-12 1997-05-07 Hoechst Aktiengesellschaft Process for preparing cyclo-olefin copolymers
US5438102A (en) * 1993-06-24 1995-08-01 Mobil Oil Corporation Solid elastomeric block copolymers
ES2154664T3 (en) * 1993-11-24 2001-04-16 Targor Gmbh Metallocenes, procedures for their preparation and their use as catalysts.
DE4344689A1 (en) * 1993-12-27 1995-06-29 Hoechst Ag metallocene
DE4344688A1 (en) * 1993-12-27 1995-06-29 Hoechst Ag metallocene
US5489651A (en) * 1994-02-14 1996-02-06 The Regents Of The University Of California Polymerization using bimetallic bis-lanthanoid initiators
DE4422157A1 (en) * 1994-06-24 1996-01-04 Hoechst Ag A process for the preparation of cycloolefin copolymers
US5476915A (en) * 1994-06-29 1995-12-19 The Regents Of The University Of California Method for controlled synthesis of polymers
DE4425408A1 (en) * 1994-07-13 1996-01-18 Hoechst Ag cycloolefin
US5621428A (en) * 1994-12-12 1997-04-15 Auravision Corporation Automatic alignment of video window on a multimedia screen
KR100359370B1 (en) 1995-02-07 2003-02-11 미쓰이 가가쿠 가부시키가이샤 Method for producing an olefin polymer
US5789474A (en) * 1995-09-28 1998-08-04 Arizona Chemical Company Additive composition and method for increasing the upper service temperature of adhesives
US5763556A (en) 1996-05-21 1998-06-09 Exxon Chemical Patents Inc. Copolymers of ethylene and geminally disubstituted olefins
US6255419B1 (en) 1997-02-07 2001-07-03 Mitsui Chemicals, Inc. Olefin polymerization catalyst and process for producing olefin polymers
EP0893454A4 (en) 1997-02-07 2001-01-24 Mitsui Chemicals Inc Olefin polymerization catalyst and process for the production of olefin polymers
US5889128A (en) 1997-04-11 1999-03-30 Massachusetts Institute Of Technology Living olefin polymerization processes
US6271325B1 (en) 1999-05-17 2001-08-07 Univation Technologies, Llc Method of polymerization

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991012285A1 (en) * 1990-02-09 1991-08-22 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
WO1994021700A1 (en) * 1993-03-22 1994-09-29 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
JPH0881415A (en) * 1994-07-12 1996-03-26 Ube Ind Ltd Production of alkenecarboxylic acid ester
WO1997042197A1 (en) * 1996-05-02 1997-11-13 Societe De Conseils De Recherches Et D'applications Scientifiques (S.C.R.A.S.) New compounds having one group 13 element, bound with one mono- or di-anionic trident ligand, a method of preparation and application thereof as polymerisation catalysts

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
BAUMANN R ET AL: "SYNTHESIS OF TITANIUM AND ZIRCONIUM COMPLEXES THAT CONTAIN THE TRIDENTATE DIAMIDO LIGAND, ((T-BU-D6)N-O-C6H4)2O2- ( NON2-) AND THE LIVING POLYMERIZATION OF 1-HEXENE BY ACTIVATED NONZRME2", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 119, 2 June 1997 (1997-06-02), pages 3830/3831, XP002072608 *
CLARK H C S ET AL: "Titanium(IV) complexes incorporating the aminodiamide ligand [(SiMe3) N{CH2CH2N(SiMe3)}2](L);the X-ray crystal structures of [TiMe2(L)] and [TiCl{CH(SiMe3)2}(L)]", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 501, no. 1, 4 October 1995 (1995-10-04), pages 333-340, XP004023769 *
CLOKE F G N ET AL: "ZIRCONIUM COMPLEXES INCORPORATING THE NEW TRIDENTATE DIAMIDE LIGAND (ME3SI)N CH2CH2N(SIME3)22-(L);THE CRYSTAL STRUCTURES OF ZR(BH4)2L AND ZRCI CH(SIME3)2L", JOURNAL OF THE CHEMICAL SOCIETY, DALTON TRANSACTIONS, no. 1, 7 January 1995 (1995-01-07), pages 25 - 30, XP002048801 *
HORTON ANDREW D: "Cationic alkylzirconium complexes based on a tridentate diamide ligand: new alkene polymerization catalysts", ORGANOMETALLICS, vol. 15, 1996, pages 2672 - 2674, XP002072479 *
PATENT ABSTRACTS OF JAPAN vol. 096, no. 007 31 July 1996 (1996-07-31) *
SILVESTRO DI G ET AL: "POLYMERIZATION OF PROPENE WITH ENANTIOMORPHIC SITE CATALYSTS, 1 A STATISTICAL ANALYSIS", MACROMOLECULAR CHEMISTRY AND PHYSICS, vol. 197, no. 10, October 1996 (1996-10-01), pages 3209 - 3228, XP000634281 *
ST@?VNENG J A ET AL: "Influence of rotation between agostic structures on ethene interaction with a zirconocene polymerization site", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 519, no. 1, 26 July 1996 (1996-07-26), pages 205-208, XP004035900 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE41897E1 (en) 1999-10-22 2010-10-26 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US9234060B2 (en) 2011-11-08 2016-01-12 Univation Technologies, Llc Methods of preparing a catalyst system

Also Published As

Publication number Publication date Type
US20040138324A1 (en) 2004-07-15 application
WO1998046651A2 (en) 1998-10-22 application
CA2285964C (en) 2008-02-12 grant
DE69810605T2 (en) 2003-05-08 grant
US6610806B2 (en) 2003-08-26 grant
US7135544B2 (en) 2006-11-14 grant
CA2285964A1 (en) 1998-10-22 application
US6316555B1 (en) 2001-11-13 grant
US5889128A (en) 1999-03-30 grant
US20050187345A1 (en) 2005-08-25 application
JP2001520696A (en) 2001-10-30 application
DE69810605D1 (en) 2003-02-13 grant
EP0975579A2 (en) 2000-02-02 application
US20020111442A1 (en) 2002-08-15 application
EP0975579B1 (en) 2003-01-08 grant

Similar Documents

Publication Publication Date Title
Wayland et al. Living radical polymerization of acrylates by organocobalt porphyrin complexes
Wang et al. Controlled/" living" radical polymerization. Atom transfer radical polymerization in the presence of transition-metal complexes
Lutz et al. Preparation and characterization of graft terpolymers with controlled molecular structure
WO1991002012A1 (en) Very high molecular weight polyethylene
US5563219A (en) Process for Preparing block copolymer of monoolefin
WO1994013709A2 (en) Polymers functionalised by koch reaction and derivatives thereof
SCHELLEKENS et al. Synthesis of polyolefin block and graft copolymers
Quinn et al. Living Free Radical Polymerisation Under a Constant Source of Gamma Radiation–An Example of Reversible Addition‐Fragmentation Chain Transfer or Reversible Termination?
JPH03115313A (en) Production of water-absorptive resin
JPH0284404A (en) Polymerization of olefin and catalyst therefor
JPH02300210A (en) Production of highly water-absorptive polymer
JPH04218508A (en) Production of alpha-olefinic polymer
JPS58201816A (en) Propylene-ethylene block copolymer for molded article having high rigidity and its preparation
Sernetz et al. Metallocene‐catalyzed ethene/styrene co‐and terpolymerization with olefinic termonomers
JPS5610506A (en) Production of ethylene polymer composition
Zhu et al. New ligands for atom‐transfer radical polymerization
Baethge et al. Rate enhancement of the N‐oxyl‐controlled free radical copolymerization of styrene with N‐vinylcarbazole
Bergemann et al. Copolymerization of ethylene and linear 1-olefins with a metallocene catalyst system under high pressure. Part II. Comparison of propene, 1-butene, 1-hexene and 1-decene1
JPS59179508A (en) Preparation of ethylene copolymer
Corradini et al. New model of the origin of the stereospecificity in the synthesis of syndiotactic polypropylene
CA2256343A1 (en) A thermoplastic compound
Matyjaszewski et al. Synthesis of polypropylene-poly (meth) acrylate block copolymers using metallocene catalyzed processes and subsequent atom transfer radical polymerization
Read et al. Low temperature RAFT/MADIX gel polymerisation: access to controlled ultra-high molar mass polyacrylamides
Stoeckel et al. New syntheses of graft copolymers using the DPE-technique: ATRP graft copolymerization
JPS5622304A (en) Polymerization of olefin

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AU CA JP

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
AK Designated states

Kind code of ref document: A3

Designated state(s): AU CA JP

AL Designated countries for regional patents

Kind code of ref document: A3

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE

ENP Entry into the national phase in:

Ref country code: CA

Ref document number: 2285964

Kind code of ref document: A

Format of ref document f/p: F

Ref document number: 2285964

Country of ref document: CA

ENP Entry into the national phase in:

Ref country code: JP

Ref document number: 1998 544198

Kind code of ref document: A

Format of ref document f/p: F

WWE Wipo information: entry into national phase

Ref document number: 1998915559

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1998915559

Country of ref document: EP

WWG Wipo information: grant in national office

Ref document number: 1998915559

Country of ref document: EP