WO1998042800A1 - Decorative material and method of its fabrication - Google Patents
Decorative material and method of its fabrication Download PDFInfo
- Publication number
- WO1998042800A1 WO1998042800A1 PCT/US1998/005394 US9805394W WO9842800A1 WO 1998042800 A1 WO1998042800 A1 WO 1998042800A1 US 9805394 W US9805394 W US 9805394W WO 9842800 A1 WO9842800 A1 WO 9842800A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- polarizers
- mosaic
- distinguished
- film
- decorative
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F1/00—Designs or pictures characterised by special or unusual light effects
- B44F1/06—Designs or pictures characterised by special or unusual light effects produced by transmitted light, e.g. transparencies, imitations of glass paintings
- B44F1/063—Imitation of leaded light
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3083—Birefringent or phase retarding elements
Definitions
- the invention refers to the field of fabrication of decorative materials and stained-glass windows on the basis of optical effects in polarized light and can be used in decorative art, advertising, and for the production of show windows, decorative screens, etc.
- the polarized light is capable of producing a number of optical effects that can be used for various purposes.
- a polarizer is able to modify the intensity of transmitted polarized light depending on the mutual orientation of the polarization plane of light and the polarization axis. This ability is used for the formation of images in indicators and other information display devices based on liquid crystals .
- Another optical effect which appears when an anisotropic nonabsorbing film is placed between crossed polarizers, can be used for the obtaining of iridescent colors. In this case, a nontransparent state of the polarizers is changed for clarification and the system acquires interference colors depending on the orientation of the anisotropic film and the viewing angle. This phenomenon can be used for the production of decorative images and stained glass windows.
- invention [1] offered a decorative color material having a sandwich structure, including a glass substrate, an optically transparent film, and a phase- shifting plate or a polarizing plate on which fragments of the phase-shifting plate (having properly selected colors and cut according to a designed pattern) are glued to form a mosaic.
- This sandwich structure is confined between layers of polarizing plates.
- each element of the mosaic acquires certain color depending on the viewing angle. Rotation of the polarizers or variation of the viewing angle will change the color of each element in the mosaic .
- a disadvantage of the known material is that it consists of separate elements cut from an optically anisotropic transparent film so as to have certain orientations. This implies considerable difficulties in the production of this material, since the process of cutting, assembling, and fixing the elements of mosaic involves manual low-productivity operations significantly increasing the costs of such decorative glasses .
- the purpose of the present invention was to create a decorative material comprising a continuous optically anisotropic film and to simplify the production technology so as to exclude the labor- consuming stages of the decorative glass fabrication involving cutting individual elements for a mosaic from an optically anisotropic material, assembling the pattern, and fixing the mosaic on a substrate.
- This task was solved by forming a mosaic structure of the decorative material either by inducing local changes in the optical properties of an initially homogeneous anisotropic or isotropic film or by depositing a polarization coating onto an optically homogeneous anisotropic transparent film.
- the polarization axis of the coating varies in a preset manner so as to form the required mosaic pattern.
- the interference phenomena in the polarizer-- birefringent transparent film- -polarizer system appear because the light beam in the birefringent plate splits into ordinary and extraordinary rays that interfere with each other upon exit from the film to form an elliptically polarized beam.
- the shape of the polarization ellipse and the orientation of its axes depend on the optical phase shift between ordinary and extraordinary rays at the exit from the birefringent film and on the orientation of the polarization plane of the incident light beam relative to the principal directions (axes) of the refractive index of the film.
- the orientation of the polarization plane is determined by angles between the axes of the refractive index ellipsoid and the polarization axis.
- ⁇ ⁇
- the polarization plane orientation will remain unchanged and the light will be blocked by the second polarizer.
- the light with elliptic polarization will be partly transmitted through the second crossed polarizer.
- a mosaic pattern can be formed by changing one of the parameters determining the shape or orientation of the polarization ellipse of the transmitted light wave: n e , n 0 , d, ⁇ .
- the decorative material is based on either an anisotropic film with varying optical properties, placed between two polarizers, or an anisotropic film with homogeneous optical properties, onto which a polarization coating with variable polarization axis orientation is deposited from one or both sides
- Anisotropic films with variable optical properties are formed by embossment or a local thermal treatment of the initially anisotropic film.
- Another method consists in covering a substrate with a thin film of a substance in which molecules, having no principal absorption bands in the visible range, can acquire a preset orientational order.
- a polarization coating with variable orientation of the polarization axis can be formed by known methods described in patents [2--4] .
- Embossing of a homogeneous anisotropic film creates regions with different thicknesses that provide a differential phase shift and, hence, various coloration of these regions.
- the film thicknesses in these regions must differ by 1--3 ⁇ m.
- the embossing technology is based on pressing a polymeric film between two surfaces of a press mold, one or both bearing a desired pattern engraved on the surface.
- Another method of embossing consists in rolling a polymeric film between two cylinders. The desired pattern is engraved on the surface of one or both rollers.
- the mold or roller engraving consists in creating a depression (0.1 to 10 ⁇ m deep) along the periphery of the pattern, which can be produced by chemical or electrochemical etching, depositing a metal film, mechanical engraving, or by any other known method.
- the patterns are made on both surfaces of the press mold or rollers, the contours may either coincide or not.
- both patterns can represent protruding or recessing elements; it is also possible that elements on one surface are made as protrusions, while the opposite mold surface has the same elements in the form of recessions, whereby the two surfaces are fitting one another in the course of embossing to form different gaps in the neighboring regions.
- the rollers In order to facilitate the process of embossing, the rollers (or the press mold) are heated to a softening temperature of the polymeric film. In order to level the film surface after the process and to restore a uniform film thickness, while retaining local changes in the optical path length, the surface of the anisotropic film is coated with an isotropic layer of a lacquer or polymer.
- Variation of the optical properties of an anisotropic film by local heating can be performed by directly or indirectly touching the surface with a tool heated to the required temperature, or by treating the surface with a torch flame, or by blowing it with a hot gas stream.
- Anisotropic optically transparent layers with homogeneous or variable optical properties are obtained by depositing thin films of molecularly oriented substances onto an isotropic substrate, for this purpose we may use compounds or their solutions that can occur in a liquid-crystalline (LC) state, such as low-molecular- mass liquid crystals having melting points above the ambient temperature, LC polymers [5] , or some other low-molecular-mass substances capable of forming elongated molecular aggregates in solution [2] .
- LC liquid-crystalline
- the anisotropic layers transparent to visible light can be obtained using aqueous or aqueous-organic solutions of aromatic compounds absorbing in the spectral range below 400 nm, which can be selected among organic and inorganic salts of alkylbenzene sulfonates, sulfonic acids of the naphthalene series, mono- and polysulfonic acids of the derivatives of benzoimidazole and benzothiazole, anthraquinone , phenanthrene , amino-, hydroxy- , halido-, nitro-, and alkylanthraquinones, benzanthrone, 3- bromobenzanthrone, and water-soluble organic belofores and bleaching agents.
- aromatic compounds absorbing in the spectral range below 400 nm, which can be selected among organic and inorganic salts of alkylbenzene sulfonates, sulfonic acids of the naphthalene series, mono- and polysulf
- the LC films are deposited by known methods described in detail in patents [2, 3], based on the squeegee, die, and roller techniques.
- the process of LC solution deposition is accompanied by orientation of the molecules under the action of viscous forces developed in the course of deposition due to stretching of the liquid layer, shifting one layer relative to another, or specially treating the surface to render it anisotropic.
- the compounds are preliminarily transformed into an LC state by heating to the melting temperature. All these techniques can be used to obtain elements with different thicknesses.
- a stepped, wedge-shaped, or other relief with depth variations within 1--15 ⁇ m is formed on the surface of the application device.
- the application device die or squeegee
- the application device must perform reciprocating motions in the direction perpendicular to the direction of motion of the base to which the anisotropic film is applied.
- this is achieved by producing a relief of elongated grooves, making certain angle with the cylinder generating line, on the surface of rollers. These grooves render the roller surface anisotropic and provide the orientation of molecules in a desired direction.
- An alternative method of obtaining anisotropic films with variable direction of optical axes and differential refractive indices is based on the known method of inducing the optical anisotropy by directional photopolymerization or simply irradiating a polymeric film on a substrate with polarized light [6] .
- a decorative material with interference-colored mosaic structure can be also obtained using a single polarizer.
- the rear polarizer is replaced by a mirror- or diffuse-reflecting surface layer. This layer is obtained by depositing a film of aluminum or some other high-reflectance material or by gluing a reflecting metal foil, mirror, or some other reflecting film.
- a polarizer is fastened on the opposite side of the structure .
- the anisotropic film can be given a certain shape and fastened on a transparent object having a preset density. All this system is placed inside a closed volume filled with a transparent liquid, e.g., water or an organic solvent, so that the anisotropic film and the base object would be immersed in the liquid.
- the polarizers are glued onto the outer surface of the vessel . .When viewed through the walls of the vessel with glued polarizers, motions of the object carrying the anisotropic film will produce an interplay of colors.
- the base with preset density can be a hollow object made of glass, plastic, or some other transparent material .
- Figs. 1--4 The structure of the decorative material is depicted in more detail in Figs. 1--4, and the methods of its fabrication are illustrated in Fig. 5.
- Figure 1 shows a decorative material in which the mosaic effect is due to the differential thickness of neighboring regions in an anisotropic film 1.
- the anisotropic film is placed between two polarizers 2 whose polarization axes can be oriented at an arbitrary angle, although the most pronounced effect is achieved for 90°.
- one or both polarizers can be glued onto the anisotropic film 1.
- the structure is protected from the action of ambient factors by glass plates 3 or by some other rigid transparent material 4, mechanically fastened or glued on one or both sides.
- the durability of polarizers and anisotropic film can be further increased by application of a film 5 absorbing in the UN and IR spectral ranges .
- Figure 2 shows a decorative material in which the anisotropic film is represented by a molecularly ordered layer 1 of a compound, transparent in the visible range, deposited onto an isotropic substrate 6.
- the mosaic effect is ensured by differential orientation of optical axes of the neighboring elements. All other parts of the structure are the same as in Fig. 1.
- Figure 3 shows a decorative material in which the optically anisotropic film has otherwise homogeneous properties and the mosaic effect is achieved by placing polarization coatings 2 onto both sides of the anisotropic film. One or both of these coatings have different directions of the polarization axes in the neighboring mosaic elements.
- Figure 4 shows a decorative material with a reflecting layer 3 replacing one of the polarizers.
- Figure 5 illustrates the method of embossing used for the obtaining of an optically anisotropic film.
- Anisotropic film 1 with uniform thickness is rolled between rotating cylinders 2 and 3 whose surfaces contain recessions 4 and protrusions 5 forming the regions of differential thickness.
- the rollers are heated to a temperature close to the melting temperature of the polymer.
- the interaction of a decorative element with transmitted light is illustrated as follows.
- the light beam 1 (Fig. 1) passes through polarizer 2 and strikes the phase-shifting plate 3.
- Each element of the mosaic pattern splits the incident light into ordinary and extraordinary rays propagating with different velocities.
- the mosaic elements have different thicknesses, each of them produces its own phase shift between the ordinary and extraordinary rays
- all beams at the exit from the phase-shifting plate will have different ellipticity that accounts for the differential light transmission through the second polarizer. For a nonmonochromatic light, this will also lead to different colors of the mosaic elements.
- a mosaic characterized by different orientations of optical axes in the neighboring elements (Fig. 1)
- the polarized light beams passing through the neighboring elements will have different orientations of the axes of polarization ellipse, which will also result in a different attenuation of the light flux transmitted through the second polarizer.
- the mosaic effect is produced by a mosaic distribution of polarization axes in one of the polarizers (Fig. 3) , a homogeneously polarized light passing through polarizer 2 strikes the phase-shifting plate 1 and homogeneously changes its polarization over the entire area of the decorative plate, when the light passes through the second polarizer 3, in which the neighboring mosaic elements have different directions of the polarization axes, the beam will be differently attenuated in each element, thus acquiring different colors.
- a decorative material with reflecting layer acts similarly to the system with two polarizers.
- the light passes through the polarizer and is doubly transmitted through the anisotropic medium, being reflected from the rear surface.
- the light beam passing through each mosaic element acquires the corresponding phase shift and leaves the system through the same polarizer, which acts as the second polarizer upon the output light beam.
- the proposed solution allows us to obtain a decorative material comprising a continuous optically transparent material, rather than separately cut mosaic elements, which markedly simplifies the production technology.
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- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Polarising Elements (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP54580098A JP4113983B2 (en) | 1997-03-26 | 1998-03-25 | Decorative material and method for producing the same |
EP98911820A EP0980411B1 (en) | 1997-03-26 | 1998-03-25 | Decorative material and method of its fabrication |
AU65688/98A AU6568898A (en) | 1997-03-26 | 1998-03-25 | Decorative material and method of its fabrication |
DE69828598T DE69828598D1 (en) | 1997-03-26 | 1998-03-25 | DECORATIVE MATERIAL AND METHOD OF MANUFACTURING |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RU97105079A RU2123430C1 (en) | 1997-03-26 | 1997-03-26 | Decorative material and method for manufacture of decorative material |
RU97105079 | 1997-03-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998042800A1 true WO1998042800A1 (en) | 1998-10-01 |
Family
ID=20191424
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1998/005394 WO1998042800A1 (en) | 1997-03-26 | 1998-03-25 | Decorative material and method of its fabrication |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0980411B1 (en) |
JP (1) | JP4113983B2 (en) |
AU (1) | AU6568898A (en) |
DE (1) | DE69828598D1 (en) |
RU (1) | RU2123430C1 (en) |
WO (1) | WO1998042800A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6520275B2 (en) * | 2015-03-23 | 2019-05-29 | 大日本印刷株式会社 | Cosmetic material |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5438421A (en) * | 1991-04-24 | 1995-08-01 | Alps Electric Co., Ltd. | Orientation film of liquid crystal having bilaterally asymmetric ridges separated by grooves |
US5534209A (en) * | 1994-03-15 | 1996-07-09 | Japan Gore-Tex, Inc. | Method for manufacturing a liquid crystal polymer film and a liquid crystal polymer film made thereby |
US5607732A (en) * | 1994-09-30 | 1997-03-04 | Nissan Chemical Industries, Ltd. | Treating method for aligning liquid crystal molecules and liquid crystal display device |
US5738918A (en) * | 1996-06-14 | 1998-04-14 | Hoechst Celanese Corp | Laminates of liquid crystalline polymeric films for polarizer applications |
US5747121A (en) * | 1995-02-08 | 1998-05-05 | Fuji Photo Film Co., Ltd. | Optical compensatory sheet |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4110004A (en) * | 1977-01-12 | 1978-08-29 | The United States Of America As Represented By The Secretary Of The Navy | Complex photodichroic spatial filter |
CA2013776C (en) * | 1990-04-04 | 1992-10-20 | David M. Makow | Electro-optic cell for animated displays and indicators |
DE4339395B4 (en) * | 1992-11-18 | 2007-11-29 | Fujifilm Corp. | Optically anisotropic element and method of making the same |
DE69633546T2 (en) * | 1995-02-23 | 2005-10-13 | Koninklijke Philips Electronics N.V. | LIQUID CRYSTAL DISPLAY DEVICE AND DELAYING FILM |
-
1997
- 1997-03-26 RU RU97105079A patent/RU2123430C1/en not_active IP Right Cessation
-
1998
- 1998-03-25 EP EP98911820A patent/EP0980411B1/en not_active Expired - Lifetime
- 1998-03-25 DE DE69828598T patent/DE69828598D1/en not_active Expired - Fee Related
- 1998-03-25 AU AU65688/98A patent/AU6568898A/en not_active Abandoned
- 1998-03-25 WO PCT/US1998/005394 patent/WO1998042800A1/en active IP Right Grant
- 1998-03-25 JP JP54580098A patent/JP4113983B2/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5438421A (en) * | 1991-04-24 | 1995-08-01 | Alps Electric Co., Ltd. | Orientation film of liquid crystal having bilaterally asymmetric ridges separated by grooves |
US5534209A (en) * | 1994-03-15 | 1996-07-09 | Japan Gore-Tex, Inc. | Method for manufacturing a liquid crystal polymer film and a liquid crystal polymer film made thereby |
US5607732A (en) * | 1994-09-30 | 1997-03-04 | Nissan Chemical Industries, Ltd. | Treating method for aligning liquid crystal molecules and liquid crystal display device |
US5747121A (en) * | 1995-02-08 | 1998-05-05 | Fuji Photo Film Co., Ltd. | Optical compensatory sheet |
US5738918A (en) * | 1996-06-14 | 1998-04-14 | Hoechst Celanese Corp | Laminates of liquid crystalline polymeric films for polarizer applications |
Non-Patent Citations (1)
Title |
---|
See also references of EP0980411A4 * |
Also Published As
Publication number | Publication date |
---|---|
DE69828598D1 (en) | 2005-02-17 |
EP0980411A1 (en) | 2000-02-23 |
JP2001521647A (en) | 2001-11-06 |
JP4113983B2 (en) | 2008-07-09 |
RU2123430C1 (en) | 1998-12-20 |
EP0980411B1 (en) | 2005-01-12 |
EP0980411A4 (en) | 2000-06-28 |
AU6568898A (en) | 1998-10-20 |
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