WO1998041340A1 - Making heat-exchanging cast metal forming tool - Google Patents
Making heat-exchanging cast metal forming tool Download PDFInfo
- Publication number
- WO1998041340A1 WO1998041340A1 PCT/US1998/005294 US9805294W WO9841340A1 WO 1998041340 A1 WO1998041340 A1 WO 1998041340A1 US 9805294 W US9805294 W US 9805294W WO 9841340 A1 WO9841340 A1 WO 9841340A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- insert
- metal
- porous
- forming tool
- casting
- Prior art date
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C7/00—Patterns; Manufacture thereof so far as not provided for in other classes
- B22C7/02—Lost patterns
- B22C7/023—Patterns made from expanded plastic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D18/00—Pressure casting; Vacuum casting
- B22D18/04—Low pressure casting, i.e. making use of pressures up to a few bars to fill the mould
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
Definitions
- This invention relates to the construction and manufacture of shape-imparting forming tools such as molds and dies having heat-exchanging characteristics .
- Forming tools such as metal molds and dies are employed in many processes to impart a desired shape to an article of manufacture.
- metal molds and dies are used to produce cast articles, of metal, plastics, glass, rubber, etc., having the shape of the casting cavity of the tool .
- Metal dies are also used in other forming operations such as stamping, pressing, coining, drawing, extruding, forging, etc., to impart a desired shape to a metal sheet or billet .
- metal dies are used to mold or shape various plastics, resins, composites, and glass to produce various shaped articles from these materials.
- a metal forming tool it is quite common when making a metal forming tool to begin with a solid block of metal into which a shaping surface is machined having a contour corresponding to that of the shape of the article to be formed by the tool . It is also common to bore fluid passages into the block beneath the shaping surface through which a heat transferring fluid may be circulated to draw heat from or conduct heat to the mold tool and hence the article being formed. Drilling such fluid passages, however, has its limitations since shaping surfaces are often of a complex contour making it difficult if not impossible to uniformally extend the passages into all areas of the tool where they are required to achieve the desired cooling or heating characteristics of the forming tool and to achieve optimum heat transfer efficiency.
- the open metal network of the porous body draws heat from the shaping surface and the network of open pores defines a tortuous flow path for a heat transfer fluid to pass to provide rapid, uniform cooling or heating of the shaping surface and thus the article being formed by the tool .
- the porous body forming tool described in the previous paragraph is considered to be a tremendous advancement over traditional solid block forming tools, machining the shaping surface into the porous metal body is a costly, time- consuming process. Thermal spraying is also costly and requires specialized equipment and skilled operators .
- a principal object of the present invention is to improve on these early developments in heat-exchanging forming tools by simplifying the construction and method of making high efficient heat-exchanging forming tools.
- the invention provides a method of casting a forming tool in a way that produces a one-piece monolithic structure having a non-porous shaping portion backed by a porous heat- exchanging support body that would be difficult if not impossible to produce by conventional machining practices.
- the porous body forms an extended heat transfer surface of the shaping portion and provides a tortuous flow path through the body that generates turbulent flow of a heat transfer fluid at low fluid flow rates.
- the porous body further provides the tool with the structural integrity required to withstand compressive molding forces and hydrokinetic tensile forces exerted by the fluid flowing through the tool during operation.
- a porous insert is prepared from an open network of expendable material, such as ceramics or salts, patterned after a corresponding network of open interconnected pores and passages.
- the insert is suspended within a cavity of a casting mold such that a first surface of the insert is spaced above an opposing contoured surface of the cavity having a shape corresponding inversely to the shaping surface to be made.
- Molten metal is cast into the cavity and surrounds the insert and infiltrates the network of pores and passages resulting in a monolithic structure having a non-porous shaping surface portion formed between the insert and contoured cavity surface and a porous metal network portion occupying the pores of the insert .
- the original porous insert is extracted from the tool following casting leaving behind a corresponding network of interconnected pores and passages throughout the metal network in communication with one another and the non-porous shaping surface providing a tortuous flow path through the support body for efficient, uniform cooling or heating of the shaping surface. Casting the tool enables all exterior surfaces to be as-formed to near net shape.
- the invention has several advantages over conventional forming tools described above and the early heat-exchanging forming tools disclosed in the aforementioned published application. Rather than machining the forming tool from a block of metal, the tool of the present invention is formed from the inside out beginning with an extractable insert around which the forming tool and its shaping surface is cast to shape. This greatly simplifies the manufacturing process and provides a rugged, near net shape construction in which the non-porous shaping surface, the remaining exterior mold surfaces, and the porous support body are formed as one whole piece.
- the casting of the forming tool further simplifies the manufacturing process by eliminating the extensive machining and thermal spraying of the early heat-exchanging forming tools mentioned above, thus reducing the time and cost involved in manufacturing forming tools.
- the extractable insert may be pre- infiltrated with metal.
- the metal of the insert bonds mechanically and metallurgically with the molten cast metal, resulting in a similar one-piece monolithic structure like the one-piece cast structure described above.
- the extractable material is withdrawn as before leaving behind an internal network of interconnected pores and passages through which heat transfer fluid may be passed.
- Figure 1 is a schematic cross-sectional schematic view of a forming tool constructed in accordance with a first embodiment of the invention
- Figure 1A is an enlarged schematic sectional view of the encircled region 1A of Figure 1
- Figure 2 is a schematic cross-sectional elevation view of an extractable insert shown supported within a cavity of a casting mold.
- Figure 3 is a view like Figure 2 but showing molten metal cast into the mold and about the insert ;
- Figure 4 is a cross-sectional schematic view of the resultant cast forming tool blank prior to extracting the insert;
- Figure 4A is an enlarged schematic sectional view of the encircled region 4A of Figure 4;
- Figure 5 is a cross-sectional view of a forming tool constructed in accordance with a second embodiment of the invention.
- Figure 6 is a schematic cross-sectional view of an insert prepared according to the second embodiment of the invention shown supported in the mold;
- Figure 7 is a cross-sectional schematic view of the resultant cast forming tool of the second embodiment prior to withdrawing the extractable insert material;
- Figure 7A is an enlarged schematic sectional view of the encircled region 7A of Figure 7;
- Figure 8 is a cross-sectional schematic view of an alternative forming tool construction;
- Figure 9 is a cross-sectional schematic view of a forming tool having a built-in flow control system
- Figure 10 is a cross-sectional schematic view of a forming tool having a built-in vacuum system.
- Figure 11 is a cross-sectional schematic view of a forming tool constructed according to another embodiment of the invention.
- the invention is broadly related to forming tools used for shaping any of a variety of shapable materials such as, for example, metal, plastics, thermoplastics, thermosets, elastomers, rubbers, foams, resins, glass, composites, etc., according to any of a variety of manufacturing processes.
- shapable materials such as, for example, metal, plastics, thermoplastics, thermosets, elastomers, rubbers, foams, resins, glass, composites, etc.
- Such processes include, for example metal casting, stamping, extruding, forging, drawing, rolling; plastic fabrication processes including injection molding, blow molding, compressing molding, foam molding, reaction injection molding, thermoforming, thermoform/ thermoset molding, rotational molding; and in the glass making industry, molding or shaping glass; and other applications ' where a tool is employed to impart a shape to a shapable material in the manufacture of an article including those tools and processes disclosed in the aforementioned International Published Application No. WO- 96/17716, the disclosure of which is incorporated herein by reference.
- the invention is concerned more specifically with the manufacture of heat-exchanging forming tools employing a casting process built around an expendable porous insert that results in an all-in-one cast and shaped forming tool that is rugged, cost effective and has desirable heat- exchanging characteristics.
- FIG. 1 Such a forming tool constructed in accordance with a first embodiment of the invention is illustrated schematically in Figure 1 and designated generally by the reference numeral 10.
- the tool 10 is of a one-piece monolithic cast metal structure having a non-porous shaping surface portion 12 in the form of a generally uniform thickness skin or shell presenting an outer contoured shaping surface of predetermined configuration corresponding to that of the article to be shaped by the tool 10.
- the shaping surface portion 12 is backed by a porous heat-exchanging support body 16.
- the body 16 includes a non-porous outer shell portion 18 that is as-cast to near net or final shape and has four upstanding shaped side walls 20 integrated at their upper ends to the shaping surface portion 12 and at their opposite lower ends to a shaped bottom wall 22 of the shell 18 defining an internal chamber 24 within the cast structure.
- At least one and preferably at least a pair of access openings 26, 28 are provided in the shell 18 for circulating a heat- transferring fluids through the chamber 24 in order to transfer heat to or from the shaping surface portion 12 during operation of the tool.
- Suitable heat transfer fluids include liquids such as hot or cold water and gases such as steam or steam under vacuum to achieve heat transfer temperatures from room temperature to about 350°.
- a heat-conducting porous metal network structure 30 which, in the first embodiment, is as-cast as an integral, monolithic portion of the casting from the same cast metal material as that of the rest of the casting.
- all portions of the forming tool, including the shaping surface 12, shell 18, and porous metal network 30 are as-cast from the same materials as a single, whole unit.
- the metal network 30 is open and porous and as such provides a corresponding network of open interconnected pores and passages 32 throughout the metal network 30.
- the open porous structure of the network 30 functions as an extended heat transfer surface of the shaping portion 12 by exposing a large surface area of the metal casting material to the heat transferring fluid as it passes through the network of pores 32 of the chamber 24 to quickly and efficiently transfer heat between the tool 10 and fluid.
- the metal network 30 also functions to provide needed structural support and integrity to the tool 10 to withstand compressive external molding forces that the tool may be subjected to during a forming operation, as well as internal hydrokinetic tensile forces that may be exerted by the heat transfer fluid as it flows under pressure through the body 16.
- the network of pores 32 defines a tortuous 'flow path for the heat transfer fluid causing it to flow turbulently through the body 16 at low flow rates, further enhancing the rate at which heat can be transferred to or from the shaping surface portion 12 and thus the material being shaped.
- the metal and porous networks 30, 32 can be formed in various patterns, sizes, shapes, and relative distributions to control the rate of heat transfer across the shaping surface 12. In many cases, it is desirable that all regions of the shaping surface 12 be heated or cooled uniformly, whereas at other times it may be desirable to heat or cool one region more than others. In each case, the metal network structure 30 may be engineered to have whatever porosity and distribution needed to achieve the desired heat transfer characteristics.
- metal materials or alloys thereof may be used to fabricate the forming tool 10.
- the materials include, but are not limited to, aluminum, zinc, tin, magnesium, copper, iron, nickel, steel, titanium, cobalt and alloys thereof and inter- metallic alloys such as nickel-aluminide, to name a few.
- the selection of the metal material for the forming tool 10 will depend in large part on the particular end used of the forming tool 10 and the term "metal material" is intended to embrace all etallics including pure metals and alloys thereof as well as composites and intermetallics .
- Figures 2-4 illustrate a preferred casting method in accordance with the first embodiment of the invention for casting the forming tool 10 of Figure 1.
- an expendable preform insert or pattern 34 which, as illustrated in Figure 2, may be configured to the general shape and contour of the forming tool 10 but smaller in size by an amount equal to the thickness of the non-porous shaping surface portion 12 and outer shell portion 18. Included among the contours is a first surface 36 of the insert 34 corresponding substantially in configuration to that of the predetermined shaping surface portion 14 of the forming tool 10 to be made.
- the expendable insert 34 is a temporary structure that is patterned to conform in size and shape to that of the porous network of pores and passages 32 to be formed in the tool 10.
- the insert 34 When the insert 34 is cast-in-place within the forming tool 10, it preserves a space within the casting devoid of the cast metal material such that upon its removal the corresponding network of the open interconnected pores and passages 32 is left behind.
- the material selected for the insert 34 is one that is sufficiently strong, thermodynamically stable, chemically resistant and heat-resistant to withstand having molten metal cast about it while retaining its expendability that enables it to be withdrawn from the forming tool following casting to provide the network of pores 32.
- Candidate materials for the insert 34 include ceramics and soluble salt materials of the type conventionally used as core materials in metal casting applications. Inorganic salts and particularly carbonate slats may be utilized as the expendable insert material . Included among the
- suitable carbonate salt compositions are those listed in Table 1 below:
- Carbonate Salts The family of carbonate salts listed in Table 1 may be readily formed or cast into various shapes including shaped, open cell, porous structures in the interstices of which metal may be cast.
- the candidate casting metals for use with these salts include aluminum, magnesium, zinc, tin, copper, iron, nickel, some intermetallics such as Ni 3 Al, cobalt, gold, silver, and alloys thereof.
- a mild acidic solution such as HC1, HN0 3 , acetic acid, H 2 S0 4 , etc.
- the insert 34 comprises an open porous network of the expendable material defining a corresponding network of interconnected pores generally uniformly distributed throughout the insert.
- the selected porosity of the insert 34 will depend in part on the desired porosity of the forming tool 10 to be produced, with there being an inverse relationship between the two. For example, providing an insert 34 having 60% porosity by volume will produce a metal network structure 30 that is
- the preferred porosity range of the tool is on the order of 30-70% volumetric porosity, but the invention contemplates a much wider range of about 5-95% volumetric prorsity, depending upon the design criteria and molding requirements of a particular application..
- Figure 3 schematically shows a casting apparatus 38 which may be used for casting the forming tool 10. While the apparatus shown and preferred is a low pressure casting apparatus, the invention fully contemplates that any of various other known casting processes may be used to produce the monolithic cast tool of the invention.
- the processes include but are not limited to sand casting, die casting, vacuum casting, squeeze casting, injection molding, permanent mold casting and other standard casting techniques.
- the preferred low pressure casting apparatus 38 includes a casting mold 40 arranged above a ladle 42 of molten metal M contained within a sealed chamber 44 of a holding vessel 46.
- the mold 40 is formed with a cavity 48 whose walls correspond in size and shape to the forming tool 10 to be made.
- a bottom inlet 50 of the mold 40 is coupled to a vertical fill tube 52 whose lower free end is submerged in the molten metal M within the ladle 42.
- Low pressure casting involves delivering molten metal into a mold cavity under low pressure from below to slowly fill the mold cavity from the bottom up under precisely regulated low pressure and flow rate conditions (typically in the range of about 5-20 psi) to minimize turbulence and assure complete filling of the mold cavity including thin sections. However, higher pressures of up to 200 psi or more may be employed.
- Various mold types are used in low pressure casting applications including sand mold and permanent metal molds.
- the preferred construction of the mold 40 for use in making the forming tool 10 includes a lower part 54 comprising a shaped, ceramic block 56 mounted on a base plate 58 contoured inversely to that of the shaping surface 14 of the forming tool 10.
- a separable upper part 60 in the preferred form of an open- bottomed metal box-like structure is also provided having sides 62 closely surrounding the sides of the ceramic block 56 and sealed at their lower ends against the base plate 58.
- a top wall 64 of upper part 60 is secured to the upper ends of the sides 62 above an upper surface 66 of the block 56. All mold surfaces are contoured inversely to that of the desired shape of the exterior of the tool 10.
- the insert 34 is inverted within the cavity 48 of the mold 40 with its shaped surface 36 suspended above the surface 66 of the block 56 to provide a gap therebetween corresponding in shape and dimension to the shaping surface portion 12 of the forming tool 10 to be made.
- the remaining sides of the insert 34 are likewise spaced from the adjacent sides 62 and top wall 64 of the mold 40 by a distance corresponding to the non-porous shell portion 18 of the forming tool 10.
- Support for the insert 34 may be provided by means of releasable connectors or mounts 68 fixed to the insert 34 and mounted releasably to the upper part 60 of the mold 40.
- the connectors 68 may be constructed of metal or other material that becomes a permanent integrated cast-in-place part of the forming tool 10 or may be fabricated of an extractable material such as that used for the insert 34, which would result in openings being cast in the shell 18 that could serve the purpose of the openings 26, 28 described above.
- the molten casting metal M is low pressure cast into the cavity 48 via the fill tube or quill 52 and bottom inlet 50 to fill the cavity 48 from the bottom up, as illustrated schematically in Figure 3.
- computer process control of the differential pressure may be employed to control the flow of the metal into the cavity 48.
- One way of achieving the differential pressure is to admit compressed air into the chamber 44 thereby displacing the molten metal M in the ladle causing it to travel up the fill tube 52 and into the cavity 48.
- the cavity 48 may be evacuated to draw the metal from the ladle 42 into the cavity 48.
- Suitable valves 70, 72 may be fitted to the vessel 46 and mold part 60 to control the relative pressure between the chamber 44 and cavity 48. Low pressure filling of the cavity 48 is preferred over other casting techniques such as gravity casting since it enables the molten metal M to fully penetrate and fill the pores of the insert 34 and form a sound, pore-free casting about the insert 34.
- the molten metal M is allowed to cool and solidify, after which the resultant cast forming tool blank is removed from the mold 40.
- the insert 34 is encapsulated by the non-porous shaping surface portion 12 and shell portion 18 and its porous network completely filled with cast metal.
- the insert 34 is extracted from the casting through the openings 26, 28. These openings may either be cast in place as mentioned or else bored through the shell 18 in a post-casting operation. Where the insert 34 is constructed of ceramic material, it may be chemically leached from the casting using a suitable acid of the types well known in the art for extracting such materials from metal castings.
- FIG 5 illustrates a forming tool constructed in accordance with a second embodiment of a invention, wherein like reference numerals are used to indicate like features with respect to the forming tool 10 of Figures 1-4A of the first embodiment, but are offset by 100.
- the tool 110 is the same except that the porous metal network 130 is prefabricated prior to casting and united mechanically and metallurgically with the shaping surface portion 112 and shell portion 118 of the tool 110 during casting.
- Figures 6 and 7 illustrates the manner in which the forming tool 110 of the second embodiment is made.
- the process begins with an insert 134 like that of the first embodiment 34 except that the interconnected pores and passages of the insert 134 are infiltrated with metal to provide what ultimately becomes the porous metal network 130 in the final tool 110.
- the metal occupying the pores of the insert 134 is selected to be identical to or metallurgically compatible with the casting metal of the forming tool 110 such that the two are mechanically and metallurgically united during casting to provide a one-piece monolithic structure .
- the metal infiltrated insert 134 is suspended within the mold cavity 48 in the same manner as described above for the insert 34.
- Molten metal M is then cast under low pressure into the cavity 48 and surrounds the insert 134, filling the space between the insert 134 and the walls of the cavity 48.
- the outer surface regions of the insert metal are exposed and suitably treated to remove any oxides, contaminants, or other impurities that would inhibit the insert metal from bonding metallurgically with the molten casting metal M, as illustrated schematically in Figure 7A.
- the extractable portion of the insert 134 is withdrawn from the forming tool 110 in the same manner to leave behind the internal network of interconnected pores 132 within the tool 110 like that of the tool of Figure 1.
- the extractable porous insert 34 of the first embodiment may be made in any of a number of ways including lost foam or lost wax processes, which are well known to those skilled in the art.
- the infiltration of the metal 130 into the insert 134 may be carried out by a similar low pressure casting process described above except using a mold cavity that is the same size and shape as the insert 134.
- Figure 8 illustrates another embodiment of the invention, wherein like reference numbers are used to indicate like features with respect to the forming tool 10 of Figures l-4a of the first embodiment, but are offset by 200.
- the tool 210 is the same except that the porous metal network 230 occupies only a portion of the chamber 224 directly beneath the shaping portion 212 and in communication with the inlet and outlet openings 226, 228. The remainder of the chamber 224 is occupied by a cast in place insulated support structure 80 which may a ceramic block or the like.
- the Figure 8 tool 210 thus provides a porous envelope behind the forming surface 212, but with a limited volume.
- the porous region has a thickness, for example, of about an inch - much less than the overall thickness of the tool 210.
- Such a structure provides advantageous heating and cooling characteristics described above with respect to the other tool configuration, but with less of the mold tool dedicated to the porous metal structure 230.
- the overall weight of the tool 210 is substantially less than it would be if the same space were occupied by a solid mass of the cast metal .
- Figure 9 illustrates still a further embodiment of the invention in which a monolithic forming tool 310 like any of the preceding constructions is fitted with a distribution an collection system 82 to control the flow of the heat transfer fluid through the metal network structure 330 of the tool.
- the system 82 may comprise one or more or a series of branched inlet and outlet flow tubes 84, 86 that extend throughout the metal porous structure 330. Holes 88 are provided at strategic locations along the tubes to distribute and collect a transfer fluid in a designed pattern to achieve the desired heat transfer properties across the shaping surface portion 312.
- heat transfer fluid introduced to the inlet flow tube 84 would exit through holes 88, circulate through the porous metal network structure 330 in a prescribed region, and then be drawn by low pressure into the outlet tube 86 through associated hole or holes 90 therein.
- Such a distribution and collection system 82 can be designed to achieve for example, uniform pressure drop and thus even flow of the heat transfer fluid throughout the porous metal structure 330.
- the tubes 84, 86 may be embedded in situ within the porous insert 334 and thereafter cast in place in the metallic tool 310.
- the holes 88, 90 in such case would be covered by the insert material
- the insert 334 may be extracted through the tubes 84, 86 using the techniques described above.
- Figure 10 illustrates yet another embodiment of the invention in which the tool 410 illustrated is like the other embodiments described above except that in includes the provision of a built-in vacuum suction system having lines 92 which are cast in place in the same manner as the flow tubes 84, 86 described above expect that the lines 92 communicate by branched lines 94 with the shaping surface 412.
- the shaping surface 412 will be formed with a plurality of minute openings 96 across its surface in communication with the lines 92 for purposes of drawing a vacuum across the shaping surface 412 of the tool 410.
- the openings 96 may be drilled into the surface 412 to connect with the branch lines 94 in a post casting operation or, may be cast in place by means of suitable cores or pull-back pins communicating with the branch lines 94 or by locating the openings of the branch lines 94 at the shaping surface 412 during casting. But for the vacuum openings 96, the shaping surface 412 remains substantially non-porous and as such the tool 410 retains the desired heat transfer characteristics of the mold tools described previously.
- the tool 410 may be used, for example, to vacuum form a plastic sheet wherein the heat transfer fluid may be employed to heat the sheet to its forming temperature and the built-in vacuum system 92 employed to draw the hot sheet into conformity against the shaping surface 412.
- Figure 11 illustrates a mold construction for injection molding and other higher pressure molding conditions (such as for the molding of glass filled compounds in powder or sheet form) , where the forming pressures on the mold face may range between 500 psi and 5000 psi and even upwards of 15,000 psi. Further, under these 2o
- the mold 510 of Figure 11 is like that of Figure 8 except that the porous media is in the form of metallic posts or pillars 98 which are placed throughout the porous cavity or chamber 524 and connect the non-porous molding face 512 with an inert body 580 which may be in the nature of the support structure 80 of Figure 8.
- the posts 98 serve the same purpose and function as the porous metal network structure 30 above, with openings 100 between the posts 98 serving to provide a tortuous flow path for heat transfer fluid.
- the density and position of these pillars or posts is a matter of structural calculation as to the pressures and temperatures involved.
- heating of the mold and the molding surface can take place using steam and/or other heat transfer fluid systems where condensation of the vapor to liquid occurs within the porous cavity, thus providing for heating and/or cooling of the molding surface.
- the tortuous path requirements within the porous media are eased in the condensation or vaporization of heat transfer fluid and thus the heat transfer affected with occur evenly throughout the porous cavity thus providing an isothermal molding surface in keeping with the principles of the invention.
- the disclosed embodiments are representative of presently preferred forms of the invention, and are intended to be illustrative rather than definitive thereof. The invention is defined in the claims.
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- Engineering & Computer Science (AREA)
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- Moulds For Moulding Plastics Or The Like (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
Abstract
Description
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Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP54074998A JP2002515831A (en) | 1997-03-19 | 1998-03-13 | Process for the production of cast metal forming tools with heat exchange properties. |
CA002284609A CA2284609A1 (en) | 1997-03-19 | 1998-03-13 | Making heat-exchanging cast metal forming tool |
EP98910478A EP0973621A1 (en) | 1997-03-19 | 1998-03-13 | Making heat-exchanging cast metal forming tool |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/328,038 | 1994-10-24 | ||
US32803897A | 1997-03-19 | 1997-03-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998041340A1 true WO1998041340A1 (en) | 1998-09-24 |
Family
ID=23279233
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1998/005294 WO1998041340A1 (en) | 1997-03-19 | 1998-03-13 | Making heat-exchanging cast metal forming tool |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0973621A1 (en) |
JP (1) | JP2002515831A (en) |
CA (1) | CA2284609A1 (en) |
WO (1) | WO1998041340A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102006002227A1 (en) * | 2006-01-16 | 2007-07-19 | Bernd Kuhs | Process for producing open-pored components made of metal, plastic or ceramic |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996017716A1 (en) * | 1994-12-05 | 1996-06-13 | Metallamics | Molds, dies or forming tools formed by thermal spraying |
-
1998
- 1998-03-13 EP EP98910478A patent/EP0973621A1/en not_active Withdrawn
- 1998-03-13 CA CA002284609A patent/CA2284609A1/en not_active Abandoned
- 1998-03-13 JP JP54074998A patent/JP2002515831A/en active Pending
- 1998-03-13 WO PCT/US1998/005294 patent/WO1998041340A1/en not_active Application Discontinuation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996017716A1 (en) * | 1994-12-05 | 1996-06-13 | Metallamics | Molds, dies or forming tools formed by thermal spraying |
Also Published As
Publication number | Publication date |
---|---|
CA2284609A1 (en) | 1998-09-24 |
JP2002515831A (en) | 2002-05-28 |
EP0973621A1 (en) | 2000-01-26 |
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