WO1997040197A1

WO1997040197A1 - Metal containing compound reduction and melting process

Info

Publication number: WO1997040197A1
Application number: PCT/EP1997/001999
Authority: WO
Inventors: Louis Johannes Fourie
Original assignee: Ipcor N.V.
Priority date: 1996-04-19
Filing date: 1997-04-17
Publication date: 1997-10-30
Also published as: JP2000508714A; DK0904420T3; ATE206478T1; TR199802101T2; IN192927B; SI0904420T1; US6146437A; CZ336798A3; PT904420E; JP3657274B2; CZ288946B6; EP0904420B1; SK143698A3; BR9708694A; DE69707128T2; EP0904420A1; PL188820B1; BG63264B1; ES2165051T3; CN1067112C

Abstract

A metal containing compound reduction and melting process which entails feeding a burden (15) comprising a mixture of the metal containing compound and a suitable reductant in particulate form into an electrically heatable vessel (11) which contains a bath (18) of the said metal in liquid form so that a reaction zone is formed in the burden (15) in which the metal containing compound (15) is reduced and a malting zone (23) is formed below the reaction zone in which the reduced metal is melted; and controlling such process in such a manner that substantially all of the reduction of the said metal containing compound takes place in the solid phase. Apparatus for carrying the said process into operation comprises a single compartment (11) channel type induction furnace (10) in which the said reduction and melting are carried out, the compartment (11) being provided with at least one feeding port (13, 14) for the burden (15); at least one exit port for the liquid metal product; and at least one exit port for any slag formed in the reaction.

Description

Metal containing compound reduction and melting process

THIS invention relates to a metal containing compound reduction and melting

process.

Most conventional metal containing compound reduction processes involve the

heating of the metal containing compound (usually the metal oxide) in the

presence of a reductant such as a suitable carbon containing compound or the

like. The metal containing compound and reductant are usually collectively

referred to as the burden.

In the aforesaid known processes, the rate at which such heating takes place

is usually so rapid that at least a substantial part of the burden is melted

before the reduction reactions are completed. A substantial amount of the

reduction accordingly takes place in the liquid phase.

On such melting of the burden, a slag is formed which, apart from the oxides

of the said metal containing compound, also contains the oxides of other metals which may be present in the burden.

In order to recover the said metal containing compound from its oxide in the

slag, a further amount of the reductant is required in the reaction which can accordingly give rise to a metal product with an unwanted high carbon content. Such high carbon in the product is usually subsequently reduced by oxidation,

either by adding to the product oxygen as gaseous oxygen or air, or by utilising

a suitable metal oxide present in the reaction medium. Such oxidation reaction

accordingly also takes place in the liquid phase.

It will be appreciated that apart from requiring an initial excess of reductant,

the subsequent oxidation of such excess entails a further step in the process.

As a result of both the aforesaid reduction and oxidation reactions, relatively

large volumes of unwanted gas are formed below the surface of the liquid metal and slag which then escape in the form of bubbles from the liquid metal

and slag.

It is accordingly an object of this invention to provide a metal reduction and melting process with which the aforesaid problems can be overcome or at least

minimised.

According to the invention a metal containing compound reduction and melting

process entails feeding a burden comprising a mixture of the metal containing

compound and a suitable reductant in particulate form into an electrically heatable vessel which contains a bath of the said metal in liquid form so that a reaction zone is formed in the burden in which the metal containing

compound is reduced and a melting zone is formed below the reaction zone in

which the reduced metal is melted; and controlling such process in such a

manner that substantially all of the reduction of the said metal containing compound take place in the solid phase.

It will be appreciated that because substantially no liquid phase reactions take

place during the process according to the invention, the aforesaid unwanted gas evolution is practically eliminated, and in practice the substantial absence of

bubble formation in the liquid metal bath and slag which is formed is used as an indication that the process is being controlled correctly.

It will be appreciated further that because the process can be carried out in

such a manner that there is substantially no need for the subsequently removal

of any excess reductant, the number of steps in the process is reduced relative to what the case is in the aforesaid known processes.

Further according to the invention the said control of the process is effected

by controlling at least one of the following parameters: (1 ) the manner in, and rate at, which the burden is fed into the vessel;

(2) the particle size of the burden;

(3) the degree of mixing of the burden;

(4) the rate at which heat is supplied to the vessel.

Further according to the invention the burden is fed into the vessel in such a

manner and rate that the burden extends over substantially the whole of the

liquid bath and any slag which may be present.

Such an arrangement will accordingly prevent any unreacted burden from

coming directly into contact with the liquid metal and slag. Such 'short circuiting', which could give rise to at least some of the reactions taking place in the fluid phase, is accordingly substantially eliminated.

Where the burden is, for example, fed into the vessel through spaced apart

feeding ports to form adjacently located heaps of burden inside the vessel, the process includes the step of ensuring that such feeding is effected in such a

manner that the bottoms of the heaps merge to define a continuous layer of

burden which extends in the manner of a bridge over the liquid bath and slag. Such bridge accordingly prevents burden material falling from the heaps from

coming directly into contact with the liquid metal or slag.

The fact that such a bridge is being formed can be established in any suitable

manner such as, for example, visually, and/or by means of image recording

apparatus, such as cameras, etc.

In practice, such visual recording may be effected by inserting a rigid element

in the manner of a 'dip stick' from the top of the vessel into the burden.

The formation of the said bridge may be effected in any suitable manner.

Thus, for example, it may be done by controlling the size of the burden heaps inside the vessel.

Alternatively, and/or additionally, it may be done by the strategic location of

the ports through which the burden is fed into the vessel and/or by controlling

the number of such ports and the rate at which the burden is fed through them. Further according to the invention the particle size of the burden is so chosen

that it can pass through a 10 mm, preferably 6 mm, more preferably 3 mm,

sieve.

Applicant has found that when a burden of such small particle size is employed,

substantially the whole of each particle is reduced to the particular metal in

the reaction zone and accordingly remains solid before the temperature of the particle is elevated to that required for the melting of unreduced oxides which

may be present in the particle.

There is accordingly very little tendency for any liquid metal in the form of the metal oxide melting at a lower temperature than the metal, to escape from

such a particle into the slag.

Thus, for example, in the case of iron, the nucleus of the particle usually

comprises FeO, which melts at a temperature of 1378 C, while the crust of the

particle comprises Fe which only melts at 1535 C. Accordingly, if larger

particles than those stipulated above are employed, the temperature of the

nucleus of such a particle could be raised to the aforesaid temperature of

1378 C before all the Fe or FeO in the particle is reduced, which may lead to

the liquid FeO escaping from the nucleus. It will be appreciated that because the said solid phase reactions are diffusion

controlled, the maximum rate of heat input which will be required will be a

function of the particle size and degree of mixing of the components of the burden, such degree of mixing preferably being such that the burden comprises

a homogeneous mixture.

Further according to the invention the process may include the step of burning

above the burden the CO which is formed during the reduction of the metal

containing compound, and which permeates through the burden.

Such burning may, for example, be effected by suitable oxygen and/or air

burners located in the vessel above the burden.

It will be appreciated that the heat so produced will also serve to increase the

temperature inside the vessel, mainly through radiation from the roof of the

vessel.

Preferably the reaction vessel comprises the heating compartment of a channel type induction furnace. Applicant has found such an arrangement particularly suited because of the

ease with which the rate of heating can be controlled in such a furnace.

Further according to the invention apparatus for carrying the aforesaid process into operation comprises a single compartment channel type induction furnace

which is provided with at least one feeding port for the burden; at least one

exit port for the liquid metal product; and at least one exit port for the slag

formed in the reaction.

In a preferred form of the invention, the metal containing compound preferably

comprises or includes an iron containing compound.

In other forms of the invention the metal of the metal containing compound

may comprise or include any other suitable one such as chromium and/or

manganese and/or copper and/or zinc and/or lead, etc.

One embodiment of the invention will now be described by way of example

with reference to the enclosed drawing, which is a diagrammatic cross

sectional view through a furnace according to the invention. In this embodiment of the invention a channel type induction furnace 10 is

utilised which comprises an elongated tubular compartment 11 of circular configuration in cross section which is provided along its bottom with two rows

of electrically operated inductors 12, each row comprising five such inductors of a capacity in the order of 2,2 MW each.

Compartment 11 includes two parallel extending rows of feeding ports of which

only two, 13 and 14, are shown, which extend along opposite longitudinal sides of compartment 11. These ports are utilised for introducing a burden 15 to furnace 10 to form two longitudinally extending heaps 16 and 17 which float

on a liquid metal bath 18. If required, the latter can initially be introduced to

vessel 11 through a feeding port, not shown.

Burden 15 comprises a homogeneous mixture in particulate form of a carbon

containing compound such as coal, for example, and iron oxide; the carbon containing compound being present in a concentration slightly less than that

representing the stoichiometric amount of carbon necessary for reducing the

ore; and the particle size of burden 15 being such that it can pass through a 3

mm sieve. Burden 15 is introduced to vessel 1 1 in such a manner and at such a rate that

the bottoms of heaps 16 and 17 merge with each other to form a bridge 19 of burden material which extends over liquid bath 18.

The fact that the bridge 19 is being formed can, for example, be established

visually by means of a 'dip stick' which is inserted from above into vessel 11, or by means of a suitable inspection window (not shown) in the wall of vessel

1 1. It may also be established by means of a suitable image recording apparatus (also not shown) located inside vessel 11.

Vessel 11 is also provided along its upper end with a plurality of oxygen burners of which only two, 20 and 21, are shown, by means of which the CO formed in

the reaction, and which permeates through the upper layer of burden 15, can

be burnt.

In operation, a reaction zone is created in burden 15 of heaps 16 and 17 which

extends virtually from the bottoms of the heaps to their upper ends. At the

same time a melting zone 22 is formed which extends between the bottoms of heaps 16 and 17 and the upper surface of liquid bath 18. During the reaction

the reduced burden 15 moves under the influence of gravity from the reaction

zone towards melting zone 22. The slag which is formed during such melting floats on top of bath 18 in a

tunnel 23 which also extends below melting zone 22. Tunnel 23 leads to a slag

exit port (not shown) in vessel 11, and burden feed ports 13 and 14 are so

arranged relative to such slag exit port that the slag in tunnel 23 is directed towards it.

During the operation of the process, bridge 19 serves to prevent any burden

material 15 from falling directly from heaps 16 and 17 into the slag in tunnel 23, or into the liquid metal in bath 18, thus preventing any 'short circuiting'.

The heat supplied to bath 18 through inductors 12 diffuses into burden 15 in

heaps 16 and 17 and this, together with the heat from the CO being burnt by burners 20 and 21 , causes the iron oxide and carbon of burden 15 to react, which results in the reduction of the iron oxide. Almost all of such reduction,

which accordingly takes place in the solid phase, takes place in the uppermost

20 mm layer of heaps 16 and 17, mainly due to the heat being supplied to such layer from the burning of the CO by burners 20 and 21. At the same time the

solid reduced iron is melted in zone 22, from where it passes under gravity into

bath 18. It will be appreciated that apart from overcoming the problems referred to in

the preamble of this specification as being encountered with the known arrangements, a further advantage of the process according to the invention

is that because it can operate with a burden of such small particle size,

burdens can be used which normally would not be usable otherwise than through prior pelletization and/or sintering.

It will appreciated further that there are no doubt many variations in detail

possible with a metal containing compound reduction and melting process according to the invention, and apparatus utilised for carrying out such process,

without departing from the spirit and/or scope of the appended claims

Claims

CLAIMS Claim 1 A metal containing compound reduction and melting process which entails feeding a burden comprising a mixture of the metal containing compound and a suitable reductant in particulate form into an electrically heatable vessel which contains a bath of the said metal in liquid form so that a reaction zone is formed in the burden in which the metal containing compound is reduced and a melting zone is formed below the reaction zone in which the reduced metal is melted; and controlling such process in such a manner that substantially all of the reduction of the said metal containing compound takes place in the solid phase. Claim 2 The process of claim 1 wherein the said control of the process is effected by controlling at least one of the following parameters:

(1) the manner in, and rate at, which the burden is fed into the vessel;

(2) the particle size of the burden;

(3) the degree of mixing of the burden; Claim 3 The method of claims 1 or 2 wherein said control is so

exercised that substantially no gas bubbles are formed in the liquid bath or slag which may be formed, which

absence of bubbles is used as an indication that

substantially all the reactions are taking place in the solid

phase.

Claim 4 The process of any one of claims 1 to 3 wherein the

burden is fed into the vessel in such a manner and rate that it extends over substantially the whole of the liquid

bath and slag which may be present.

Claim 5 The process of any one of claims 1 to 4 wherein the burden is fed into the vessel through spaced apart feeding

ports to form adjacently located heaps of burden inside

the vessel, and the process includes the step of ensuring

that such feeding is effected in such a manner that the

bottoms of the heaps merge to define a continuous layer of burden which extends in the manner of a bridge over

the liquid bath and any slag which may be present. Claim 6 The process of claim 5 wherein the formation of the

bridge is effected by controlling the size of the burden

heaps inside the vessel.

Claim 7 The process of claims 5 or 6 wherein the formation of the bridge is effected by the strategic location of ports

through which the burden is fed into the vessel and/ or by

controlling the number of such ports and the rate at which the burden is fed through them and/or by

controlling the level of the liquid metal in the vessel.

Claim 8 The process of any one of the preceding claims wherein the particle size of the burden is such that it can pass

through a 10 mm, preferably 6 mm, more preferably 3

mm, sieve.

Claim 9 The process of any one of the preceding claims which includes the steps of burning any CO which is formed

during the reduction of the metal containing compound,

and which permeates through the burden, above the

burden, and utilising the heat so produced in the reaction. Claim 10 The process of claim 9 wherein such burning is effected

by oxygen and/or air burners located in the vessel above the burden.

Claim 11 The process of any one of the preceding claims wherein

the reaction vessel comprises the heating compartment of a channel type induction furnace.

Claim 12 The process of any one of the preceding claims in which

the metal containing compound comprises or includes an iron containing compound.

Claim 13 The process of any one of claims 1 to 11 wherein the

metal of the metal containing compound comprises or includes any one or more of the following: iron,

chromium, manganese, copper, zinc, lead.

Claim 14 Apparatus for carrying out the process of any one of

claims 1-13 which comprises a single compartment

channel type induction furnace in which the said reduction

and melting are carried out, the compartment being provided with at least one feeding port for the burden; at

least one exit port for the liquid metal product; and at

least one exit port for any slag formed in the reaction.

Claim 15 A metal containing compound reduction and melting

process substantially as herein described with reference

to the drawing.

Claim 16 Apparatus for carrying out a metal containing compound

reduction and melting process substantially as herein

described and as illustrated in the drawing.