WO1997023760A1

WO1997023760A1 - A method of manufacturing iron shot for hunting cartridges

Info

Publication number: WO1997023760A1
Application number: PCT/DK1996/000525
Authority: WO
Inventors: Ole Kraemer; Marianne Schmidt
Original assignee: Dansk Teknologisk Institut
Priority date: 1995-12-22
Filing date: 1996-12-12
Publication date: 1997-07-03
Also published as: AU1365697A

Abstract

A method of manufacturing iron shot, wherein essentially carbon free iron powder is compacted so as to form small bodies, and the small bodies formed are heated for a sufficient period to obtain partial sintering of the iron particles.

Description

3760

A method of manufacturing iron shot for hunting cartridges

The present invention relates to a method of manufactur¬ ing iron shot for hunting cartridges.

It has been known for long to use lead shot in hunting cartridges. Such lead shot are typically spherical and have a diameter which varies dependent on the type of game to be hunted. For example for hunting pheasants and other gamebirds, use is made of lead shot having a diameter of about 3 mm.

The known lead shot typically has a density of about 11.3 g/cm³.

Since lead is toxic to animals and human beings, and since, as a result of hunting, large quantities of shot are scattered annually throughout the countryside, steps have been taken during recent years to limit, and on a longer view, stop the use of lead shot.

Attempts have been made to replace lead shot by shot made from various lead-containing mixtures.

Thus, it is known from US patent specification No. 3,900,317 to replace lead shot by composite shot made from mixtures of particles of lead, iron, tin and zinc, which after agglomeration so as to form spherical bodies are sintered at a temperature of about 940 °C.

US 3,987,730 also describes composite shot consisting of iron, lead, tin and zinc. These known shot consist of an iron phase which may be in the form of a porous matrix, the voids of which are filled with lead or a lead- containing alloy which imparts a density of as much as 11 g/cm³ to the shot. DE-OS-2, 453,881 describes a method of manufacturing iron shot having sufficiently high strength to be used for hunting purposes, and which do not cause undue wear on the gun barrel. According to the method conventionally manufactured iron shot are subjected to a heat treatment at a temperature of 593-982 °C in a reducing atmosphere in order to remove carbon from the surface of the iron shot.

US-A-2,284,638 describes a method of manufacturing hardenable metal bodies by compacting a mixture of iron powder and iron carbide powder so as to form a coherent body, this body subsequently being heated in a non- oxidizing atmosphere for a sufficient period to obtain sintering of the iron powder particles and diffusion of iron carbide into the mass thus formed, whereby the latter becomes hardenable.

It has also been suggested to use steel shot as a substitute for lead shot. Such steel shot have a comparatively high degree of hardness, which causes considerable problems.

In case of woodland hunting, some of the shot end up in tree trunks, and when these trunks are subsequently cut, e.g. into veneer, the hard steel shot may cause damage to or destruction of the knives used for the cutting. This is an essential reason why although it is desired to abolish lead shot, it is still allowed to use lead shot for woodland hunting.

The object of the present invention is to provide non- toxic iron shot which do not destroy the tools used for wood-working, and which at the same time have satisfac¬ tory strength and penetration power to kill the game. This object is achieved by the method according to the invention, which method is characterized in that essentially carbon free iron powder is compacted so as to form small bodies, and that the small bodies formed are heated for a sufficient period to obtain partial sinter¬ ing of the iron particles.

The iron shot prepared by the method according to the invention have sufficiently high strength to kill the game without fracturing, and at the same time such brittleness that they disintegrate upon contact with hard objects or surfaces. Such disintegration thus occurs if, having penetrated into wood which is to be cut, they are hit by a veneer knife. The same applies if the shot strike hard road surfaces, ice-covered surfaces, or the like. Hereby the problems of ricocheting, which may arise when using conventional steel shot, are reduced.

The iron powder used in the method according to the invention preferably has a high degree of purity and contains only very small amounts of iron oxides. The particle size is preferably within the range 0.01-0.5 mm.

In connection with the compacting of the iron powder it is preferably admixed with lubricant in order to reduce the friction between the powder particles and the tool. Hereby also good green strength is obtained.

According to a preferred embodiment of the method accord¬ ing to the invention, the iron powder is compacted so as to form small bodies having larger dimensions than the desired shot, and the small bodies are abraded either before or after the sintering so as to obtain shot having a desired form and size.

The compacting is expediently performed by means of such matrices that oblong bodies with rounded ends and circular cross-section are formed. When manufacturing approximately spherical shot having a diameter of 3 mm, the said oblong bodies preferably have a length of about 3.5 mm and a diameter of about 3.2 mm.

The compacting of the iron powder is typically performed using pressures between 200 and 600 MPa and results in a deformation of the iron powder particles.

As appears from the drawing, which shows an enlarged cross-sectional view of an iron shot manufactured by the method according to the invention, the compacting of the iron particles has resulted in their surfaces having adapted themselves to one another, whereby the void between the particles has been reduced to a minimum.

By using powder of essentially pure iron, the partial sintering of the iron particles is preferably performed at a temperature of 700-810 °C, and particularly expediently at a temperature of about 790 °C. The sinter¬ ing is preferably performed in a reducing atmosphere, e.g. hydrogen-containing atmosphere, in order to obtain a reduction of any iron oxides. The partial sintering serves to establish punctiform bonds between the deformed iron particles.

These punctiform bonds have limited strength, which contributes to the shot, when exposed to strong mechanical impacts, fracturing at the interfaces between the deformed iron particles.

The above temperature is typically maintained for 20-30 minutes, whereafter the compacted small bodies have obtained suitably high strength following cooling to room temperature. During the heating to a temperature within the above range, any lubricating and/or binding agents will evaporate or decompose, so that the sintered bodies obtained essentially consist only of iron.

The iron powder used can be admixed with small amounts of one or more additives, such as ferrophosphorus, manganese sulphide, tin and graphite, with a view to changing its sintering temperature, workability etc. In this case it may be a possibility to perform the partial sintering within a temperature range outside the range stated above. Any additives are preferably used in an amount of maximally 5 weight-%.

The abrasion of the small bodies formed at the sintering, so as to obtain shot having a desired form and size, is expediently performed by placing the small bodies in a container equipped with a paddle-wheel agitator and containing a suspension of an abrasive, such as aluminium oxide or silicon carbide. During the movement caused by such an agitator, e.g. oblong small bodies or irregularly shaped small bodies will in time become essentially spherical.

The density of the shot prepared by the method according to the invention is about 7 g/cm³, which density combined with the strength of the shot has been found to give satisfactory penetration power.

Following prolonged stay in live wood, the shot manufac¬ tured by the method according to the invention may tend to discolour the wood. In order to counteract or eliminate such tendency to discoloration, the shot are preferably subjected to a surface treatment so as to provide a surface coating on the shot. The surface treatment may e.g. be hot-dip galvanization, zinc electroplating, tinning, or another kind of environment¬ ally acceptable surface treatment.

The invention is described in more detail below, refer¬ ence being made to the following examples.

Example 1

As starting material use is made of commercially avail¬ able iron powder having good flow properties and a grain size of about 0.2 mm. About 0.5 weight-% of a lubricant consisting of 70 % zinc stearate and 30 % wax was added to the powder.

The iron powder and the lubricant were mixed in a V-mixer with internal rotor. The mixing time was about 25 minutes for a batch of 4 kg.

The powder was cooled to room temperature, whereafter it was ready for compacting.

The compacting was performed using a press comprising a top and a bottom piston at a pressure of about 500 MPa.

The bodies formed at the compacting had the shape of cylinders with rounded ends. The diameter of the cylinder-shaped portion of the compacted bodies was about 3.2 mm, and the length of the bodies was about 3.5 mm.

The compacted bodies, which had a density of about 7.3 g/cm³, were subsequently abraded so as to obtain essentially spherical shot having a diameter of about 3 mm by making them roll against each other in a container equipped with an agitator and containing an aqueous suspension of fine-grained aluminium oxide. The container had a volume of 5 litres, and the quantity of compacted bodies was about 300 g per portion, which were treated for about 20 minutes. After the abrasion the bodies were cleaned with soap and water, and subsequently dried.

The bodies were subjected to a heat treatment in order to effect partial sintering of the iron powder particles. The heat treatment took place in a throughflow furnace, in which the temperature at the inlet was 500 °C, and in which the highest temperature was 790 °C. The bodies were kept at a temperature of about 500 °C for 30 minutes, and subsequently at a temperature of 790 °C for another 30 minutes. The sintering process was performed in a hydrogen atmosphere. The sintered bodies were subsequent¬ ly cooled to room temperature for about 30 minutes.

The iron shot prepared had a density of about 7.3 g/cm³ and caused no damage to veneer knives when cutting. The shot remained intact after shooting against hard wood fibreboards and bones.

Example 2

The method according to example 1 was repeated, but using a compression pressure of 400 MPa.

The shot thus prepared had a density of 6.8-7.0 g/cm³ and were more brittle than the iron shot prepared according to example 1. This manifested itself in that in shooting tests they disintegrated on impact with bones cast in a muscle-like gel.

Comparative example

The method according to example 1 was repeated, but using a maximum temperature of 850 °C. The iron shot hereby obtained, which had a density of 7.3 g/cm³, were so hard that when cutting the shot with veneer knives, the knives suffered damage.

Claims

C l a i m s ;

1. A method of manufacturing iron shot, c h a r a c ¬ t e r i z e d in that essentially carbon free iron powder is compacted so as to form small bodies, and that the small bodies formed are heated for a sufficient period to obtain partial sintering of the iron particles.

2. A method according to claim 1, c h a r a c t e r ¬ i z e d in using iron powder having a particle size of 0.01-0.5 mm.

3. A method according to claim 1 or 2, c h a r a c ¬ t e r i z e d in that the compacting is performed at a pressure of 200-600 MPa.

4. A method according to any of the preceding claims, c h a r a c t e r i z e d in that the iron powder is compacted into small bodies having larger dimensions than the shot desired, and that the small bodies either before or after the sintering are abraded so as to obtain shot having a desired shape and size.

5. A method according to any of the preceding claims, c h a r a c t e r i z e d in that oblong small bodies with rounded ends and circular cross-section are formed at the compacting.

6. A method according to any of the preceding claims, comprising using a powder of essentially pure iron, c h a r a c t e r i z e d in that the sintering is performed at a temperature of 700 °C - 810 °C.

7. A method according to any of the preceding claims, c h a r a c t e r i z e d in that the iron powder is admixed with one or more additives before the compacting.

8. A method according to any of the preceding claims, c h a r a c t e r i z e d in that the sintering tempera¬ ture is maintained for 20-30 minutes.

9. A method according to any of the preceding claims, c h a r a c t e r i z e d in that the sintering is performed in a reducing atmosphere.

10. A method according to any of the preceding claims, c h a r a c t e r i z e d in that the abrading of the small bodies is performed in a container equipped with an agitator and containing a suspension of a particle shaped abrasive agent.

11. A method according to claim 10, c h a r a c t e r ¬ i z e d in using aluminium oxide or silicon carbide as abrasive agent.

12. A method according to any of the preceding claims, c h a r a c t e r i z e d in that the finished shot are subjected to a surface treatment so as to provide a surface coating on the shot.

13. Iron shot manufactured by the method according to any of the claims 1-12.