WO1996038516A1 - Internal combustion gas generator - Google Patents
Internal combustion gas generator Download PDFInfo
- Publication number
- WO1996038516A1 WO1996038516A1 PCT/US1995/006949 US9506949W WO9638516A1 WO 1996038516 A1 WO1996038516 A1 WO 1996038516A1 US 9506949 W US9506949 W US 9506949W WO 9638516 A1 WO9638516 A1 WO 9638516A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- chamber
- air
- fuel
- burner
- pair
- Prior art date
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C6/00—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion
- F23C6/04—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B47/00—Methods of operating engines involving adding non-fuel substances or anti-knock agents to combustion air, fuel, or fuel-air mixtures of engines
- F02B47/02—Methods of operating engines involving adding non-fuel substances or anti-knock agents to combustion air, fuel, or fuel-air mixtures of engines the substances being water or steam
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M25/00—Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
- F02M25/022—Adding fuel and water emulsion, water or steam
- F02M25/0221—Details of the water supply system, e.g. pumps or arrangement of valves
- F02M25/0225—Water atomisers or mixers, e.g. using ultrasonic waves
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M25/00—Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
- F02M25/10—Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture adding acetylene, non-waterborne hydrogen, non-airborne oxygen, or ozone
- F02M25/12—Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture adding acetylene, non-waterborne hydrogen, non-airborne oxygen, or ozone the apparatus having means for generating such gases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M53/00—Fuel-injection apparatus characterised by having heating, cooling or thermally-insulating means
- F02M53/02—Fuel-injection apparatus characterised by having heating, cooling or thermally-insulating means with fuel-heating means, e.g. for vaporising
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
- F23D14/20—Non-premix gas burners, i.e. in which gaseous fuel is mixed with combustion air on arrival at the combustion zone
- F23D14/22—Non-premix gas burners, i.e. in which gaseous fuel is mixed with combustion air on arrival at the combustion zone with separate air and gas feed ducts, e.g. with ducts running parallel or crossing each other
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
- F23D14/46—Details, e.g. noise reduction means
- F23D14/66—Preheating the combustion air or gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
- F23L7/002—Supplying water
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B3/00—Engines characterised by air compression and subsequent fuel addition
- F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Definitions
- the present invention relates to the field of reducing nitrogen oxide emission from internal combustion engines and turbines, and more particularly to a novel means and method for conducting a feed mixture flow from a preheater assembly to a fully insulated burner having an insulated inner burner supplying gases from a portion or part of the main engine fuel whether it be gaseous or liquid to an insulated outer burner.
- N0 X nitrogen oxides
- the present invention teaches the use of an underoxidized burner using the main fuel to obtain hydrogen .
- the first stage includes regions with air-fuel ratios near stoichiometric wherein high temperatures occur that induce initiating undesired chemical reaction with the fuel. Such temperatures result in elevated concentrations of N0 ⁇ .
- a second stage operates air rich to achieve final overall air- fuel ratio. Its temperature is lower but not sufficiently low that N0 X cannot form, and this stage generally does not remove N0 ⁇ which has been formed in the first stage. The overall result is that N0 ⁇ formed in both stages appears in the burner exhaust.
- the present invention provides a novel means and method utilizing a fully insulated burner for combusting air and hydrocarbons at fuel-rich stoichiometric air/fuel ratios from 0.3 to 1, which includes a first stage burner having a combustion chamber properly coupled to a main source of fuel which includes means for diverting a portion of the main fuel into the burner along with a portion or all of the main air so that the fuel portion and air portion impinge against a first baffle arrangement whereby impingement thoroughly mixes the fuel/air combination preparatory for ignition in the combustion chamber.
- Means are provided for exhausting the burned gases from the first stage burner into the combustion chamber of a second stage burner via a second baffle arrangement and then into exhaust. The excellent mixing provided by said impingements results in close to theoretical equilibration of the fuel-rich reaction, despite the low reactivity of the original excess fuel.
- Yet another object is to provide a novel burner apparatus means and method which is a very simple, non-catalytic burner means and method for producing hydrogen from a portion or all of the main engine fuel for injection into the main engine combustor with the remainder of the fuel or full fuel flow to attain high air/fuel ratios leading to minimal or zero nitrogen oxide formation.
- a still further object of the present invention is to provide a hydrogen generator for use in connection with reducing nitrogen oxide in an engine emission which does not require additives that degrade fuel performance and which burner contributes little to engine complexity.
- Yet another object of the present invention is to provide a novel means and apparatus and method utilizing a two-stage fully insulated burner to reduce nitrogen oxides from internal combustion engines and turbines by utilization of a simple hydrogen generator fed by a small portion or all of main engine fuel whereby the resultant hydrogen produced is to be co- fired or flowed in the engine with the remainder of the main fuel, or as the fuel.
- a further object resides in the provision of an air/fuel mixture pre-heating means and methodology so as to provide a higher combustion temperature to assist the equilibration process.
- Another object resides in employment of an insulated burner with preferably two fuel-air mixing chambers to insure vaporization of liquid fuel with increased hydrogen output.
- FIGURE 1 is a chart of theoretical equilibrium calculations for methane-air combinations
- FIGURE 2 is an enlarged longitudinal diagrammatic view, in section, illustrating the novel two-stage no-NO x burner means employed in an engine for hydrogen generation;
- FIGURE 3 is a chart illustrating theoretical temperatures and diagrammatic sectional views of the hydrogen generator for fuel/air feed (designated "normal") before and after (designated VOB) heating to 1000°F employing a pre-heater means using heat exchange principles;
- FIGURE 4 is a diagrammatic longitudinal cross- sectional view of a prior art single-stage burner;
- FIGURE 5 is a diagrammatic sectional view of another version of a two-stage burner having separate and individually insulated heat exchanger combustion chambers;
- FIGURE 6 is a view similar to the burner shown in FIGURE 5 showing a modified heat exchanger
- FIGURE 7 is a transverse cross-sectional view of the burner shown in FIGURE 5 as taken in the direction of arrows 7-7 thereof;
- FIGURE 8 is a transverse sectional view taken in the direction of arrows 8-8 in FIGURE 6;
- FIGURE 9 is a view similar to the burner shown in FIGURE 6 showing a preferred modified heat exchanger and also illustrating a ceramic or cement insulation ring between heat exchanger and burner rear.
- FIGURE 10 is a side elevational view of the ceramic ring disassembled from the burner shown in FIGURE 9. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
- ratios of air (formula, 0 2 + 3.76 N 2 ) to fuel are set with more than sufficient oxygen (0 2 ) to react all carbon (C) atoms to carbon dioxide (C0 2 ) and all hydrogen (H) to water (H 2 0) .
- methane (CH 4 ) as fuel, this is represented by the equation,
- the technology of the co-patents can result in an underoxidized burner replacing the customary near- stoichiometric regions in the first stage of a burner. While the latter produces N0 X that eventually appears in the exhaust, N0 X cannot form in the very fuel rich underoxidized burner. It equilibrates instead to easily combustible CO and H 2 , and very minor amounts of undecomposed fuel. As a consequence, injecting a mix of such products and the air needed to attain the desired overall air-fuel ration into a second stage burner which incorporates means to achieve the same rapid flow reversals taught by the co-patents, results in rapid chemical equilibration. These factors, aided by the relatively high concentration of H 2 , permits stable combustion at extraordinarily lean air/fuel ratios with relatively low temperature where N0 X does not form.
- FIGURE 2 is an example of a no-NO x burner incorporating the present invention and is illustrated in the general direction of arrow 10.
- a burner enclosure 11 is internally covered with an insulation material 12.
- Air is introduced via an inlet 13 with flow being controlled by a valve 14.
- a portion of the air controlled by valve 14A passes into a heat exchanger 15 in heat exchange relationship with hot gases 16 within a first stage burner 17.
- Fuel is introduced to the heat exchanger through an inlet 18 and is passed through a valve 19 into the heat exchanger 15.
- the pre-heated air/fuel mixture leaves the heat exchanger via a hole 20 and enters an annulus 21 enclosed by a tube 22.
- the gases pass through the annulus and impinge on the cover of a thimble 23 causing a 90° turn to be taken and eventually, the gases leave the thimble 9 via an orifice 24.
- the gases then impinge on the insulated rear wall 25 where another 90° turn takes place.
- the gases are again turned 90° at outward wall 26 and are ignited by a spark plug 27.
- the burning mixture then moves through the first stage burner 17 to a firewall 30 and exits the first stage chamber via a tube 21.
- Remaining air from valve 14 moves into a flat tubular heat exchanger 31 in heat exchange relationship with gases 24 and the heated air leaves the exchanger 31 and enters tube 32 via entrance 33. This exchanger may be substituted by a straight tube leading into tube 21.
- the mixed air and burner products leave the tube 32 via a hole 34 and move into a second annulus 35.
- the gases now impinge onto the closed end of a thimble 37 where the gases are now turned 90° and leave the thimble via an exit opening 38 to impinge on the firewall where flow is again turned 90°.
- the gases then move to the cylinder wall 26 in the second chamber or second stage burner 40.
- the gases finally exit the burner through an orifice 41.
- Acceptable formulations for the first and second stage burners can be deduced from FIGURE 1.
- S should be above 0.3 to prevent formulation of solid carbon that would interfere with operation of the burner or methane that might be difficult to burn in the second stage and below about 0.6 to prevent formation of NO x .
- S should be up to 3, preferably at 3 to prevent formation of NO ⁇ .
- the latter ratio includes total air and feed flows to both stages.
- FIGURE 3 includes theoretical temperatures for fuel-air feed before and after heating to 1000°F, with increases in the latter case of 600° to 800°F. As indicated in a previous application, the higher temperature greatly increases the likelihood of attaining the theoretical equilibrium needed to provide hydrogen. Attaining such temperatures, however, requires decreasing thermal losses.
- a methane burner operating at stoichiometric ratio over unity with C0 2 and H 2 0 as major products provides about 22,000 Btu/lb of methane, with the result that thermal losses in the range of 1000 Btu/lb or more are relatively unimportant and so its combustion temperature can approach its theoretical of 3300°F where chemical equilibration is likely.
- much less energy is liberated on reaction of the underoxidized burner because its ideal products are hydrogen and carbon monoxide.
- the curve labeled "Btu/lb" in FIGURE 3 relates to theoretical heat outputs for methane-air reaction at underoxidized stoichiometric ratios from .25 to .75. It shows energy output as low as about 500 Btu at the lowest practical ratio of about 0.3 and about 7500 at the upper ratio of about .5. At such low energy outputs minor thermal losses become significant.
- the curve labeled "normal" in FIGURE 3 relates theoretical temperature for feed of 78°F of underoxidized burners to stoichiometric ratios from .25 to .75. At the low practical ratio of .3, the heat output is easily overshadowed by heat losses, so theoretical temperature is virtually impossible to achieve. Even at the high practical ratio of 0.5, the theoretical temperature of 2300°F is hard to achieve unless thermal losses are severely decreased.
- the burner wall 45 is always composed of material which is insulative to some degree; however, this burner wall still results in heat losses since thermal conductivity is proportional to temperature difference and the insulation contacts the highest temperature of the burner on one side and the lowest external temperature on the other side. Also, the thermal conductivity of most insulation increases with temperature, as indicated in the following Table from Carborundum for Fibrefax Felt.
- the prior art burner is indicated by numeral 45 having a housing 46 with an internal combustion chamber 47.
- the heat exchanger 48 accepts fuel via inlet 48 and air via inlet 50 with a portion of fuel being introduced via inlet 51.
- the fuel/air is initially combined in a tube 52 which is open-ended so that the combined fuel/air is directed towards a baffle 53, as indicated by the flow of arrows such that the flow is reversed upon itself and exists through the tube 52 inside a cup 53 where the streams impinge on the baffle 53.
- Flow direction is changed 90 degrees radially outwardly and then 90 degrees to an opening 54 in a plate 55 into the combustion chamber 47 for exiting via duct 56. Additional disclosure is found in the previously noted co-pending applications.
- Heat loss can be decreased by locating a burner section with the feed heat exchanger, as indicated FIGURE 5, which tends to "fold" the burner onto itself, to more closely resemble a sphere.
- FIGURE 5 employs a thicker and more efficient insulation than the prior art
- FIGURES 5 and 7 version as shown in the direction of arrow 60, is more efficient.
- the burner 60 has an outer section 61 with heavy insulation 62 surrounding an inner section 63 which is hollow and open ended at number 64 and closed at a wall 65.
- a first chamber 66 is defined between the heavily insulated inner section 63 and the outer section 61 while number 67 indicates a second chamber within inner section 63.
- a spiral heat exchanger 68 containing the feed mixture is disposed in the first chamber 66 and having an inlet 70 and an outlet 71 discharging into the second chamber 64.
- the air/fuel mixture enters into heat exchanger 68 via an entry coil 72 and passes to an existing coil 73 via an intermediate coil 74 that surrounds the inner section 63. Ignition is achieved by spark plug 73 within second chamber 67 as the preheated air/fuel mixture is discharged from the outlet 71 when the gases impinge against wall 65 and reverse flow direction. Gases then flow from the second chamber 67 through opening 64 into the outer or first chamber 66 for exhaust discharge through exhaust outlet 75.
- the spiral heat exchanger 68 containing the feed mixture is surrounded by high temperature gases from the burner chamber 67. These hot gases contact the inner surface of the insulating wall of the outer section 61 while the outer surface is in contact with the cool exterior. As a result, the temperature drop across the insulation is high which causes a considerable swing in heat flux values.
- FIGURES 6 and 8 discloses a heat exchanger section which greatly reduces or decreases the heat flux swing values.
- the burner device is illustrated in the direction of arrow 80 which includes an outer section 81 and an inner section 82, both of which are composed of insulated walls and arranged in coaxial spaced apart relationship defining a first chamber 83 and internal burner chamber 84 which is open at end 85.
- An inlet 86 brings air/fuel supply to a heat exchanger 87 consisting of a plurality of spaced apart parallel tubes coaxial with the burner and having opposites joined in annular tubes 88 and 89.
- Tubular spokes 90-94 connect the heat exchanger parallel tubes with inlet 86 while similar tubular spokes 103 connect the other end of the parallel tubes with a feed tube 95.
- the end of the tube 95 supports a baffle or cup 96 having an end wall against the feed mixture impinges which reverses the flow and then exits into the burner chamber 84.
- the flow impacts against end wall 98 which causes another directional flow reversal. Ignition is achieved by spark plug 100 and the exhaust flow exits through opening 85 into the first chamber 83 partially occupied by the heat exchanger 87. Discharge of the gases is via exhaust exit 102 connected to the first chamber after the gases flow past the heat exchanger.
- the heat exchanger forms an outer and an inner annulus.
- the outer contains the cooled feed mixture and is located adjacent to the outer wall of insulation.
- FIGURE 9 another burner version is illustrated in the general direction of arrow 110 which, as previously described, includes an insulated outer wall 111 coaxially disposed with respect to an inner section 112 having an opening 113 in fluid communication with a closed inner chamber 114. An outer chamber 115 is separated therefrom by a "can" like metal separator 116.
- the outer chamber is in communication with an inlet 117 for conducting air/fuel mixture to a fully insulated injector-mixer 118 which includes a baffle plate or cup 120 for effecting feed mixture flow reversal as previously described.
- a wall 121 of the inner section 112 causes another flow reversal.
- Spark plug 122 ignites the gases in a burner chamber 123 for exiting through inner chamber 114 to an exhaust outlet 124.
- the gases move against the insulated wall with 111 within the annulus and the pass radially inward along the chamber 115 to the injector-mixer 118.
- the hot gases formed in the burner chamber 123 impinge on the inner surface of the separator 116 and then pass radially outward to an annulus bounded by the separator and the insulated inner section 112. Finally the gases exit at outlet 124.
- the separator is the exchanger surface between burner gas and feed gases. Its area is sufficiently large so that there is no requirement for any "extended” surfaces. Flows are parallel, instead of counter flow, to limit heat exchange and prevent uncontrolled temperature caused by any conventional "boot strap” process. This is not a requirement and counter flow may also be used.
- the inventive burner concept may be employed with diesel fuel in diesel-type engines.
- a major problem with such engines are particulates (smoke) ejected from the tail pipe, which include toxic material and provide a visual and auditory nuisance.
- particulates could be eliminated by using the first section of the inventive burner to gasify all the diesel fuel prior to injection into the engine, along with the further air necessary to get the final air fuel ratio. By doing so, the diesel fuel cannot produce particulates.
- the process would also result in the ability of the engine burner to operate at low air/fuel ratios where N0 X does not form.
- the several impingements of the air/fuel mixture result in an intimate mixture that readily ignites and burns to completion in a certain volume.
- This volume may be decreased by about 25% by placing a preferably ceramic ring 125 within the burner below the location where the fuel stream leaves the mixer, as shown in FIGURE 9. Apparently the ring causes the burning gases to move from the sides of the burner and into its center, after which a portion spontaneously moves back to the wall, and so results in more complete utilization of the burner volume.
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Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/148,472 US5441546A (en) | 1993-11-08 | 1993-11-08 | Apparatus and method for decreasing nitrogen oxide emissions from internal combustion power sources |
US08/309,041 US5437123A (en) | 1993-11-08 | 1994-09-20 | Underoxidized burner utilizing improved injectors |
US08/440,698 US5529484A (en) | 1993-11-08 | 1995-05-15 | Apparatus and method for decreasing nitrogen oxide emissions from internal combustion power sources |
JP51556496A JP3145123B2 (en) | 1993-11-08 | 1995-06-02 | Internal combustion gas generator |
CA002221594A CA2221594A1 (en) | 1993-11-08 | 1995-06-02 | Internal combustion gas generator |
EP95922930A EP0828804A4 (en) | 1993-11-08 | 1995-06-02 | Internal combustion gas generator |
KR1019970708658A KR100255335B1 (en) | 1995-06-02 | 1995-06-02 | Internal combustion gas generator |
PCT/US1995/006949 WO1996038516A1 (en) | 1993-11-08 | 1995-06-02 | Internal combustion gas generator |
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/148,472 US5441546A (en) | 1993-11-08 | 1993-11-08 | Apparatus and method for decreasing nitrogen oxide emissions from internal combustion power sources |
US08/309,041 US5437123A (en) | 1993-11-08 | 1994-09-20 | Underoxidized burner utilizing improved injectors |
US08/440,698 US5529484A (en) | 1993-11-08 | 1995-05-15 | Apparatus and method for decreasing nitrogen oxide emissions from internal combustion power sources |
CA002221594A CA2221594A1 (en) | 1993-11-08 | 1995-06-02 | Internal combustion gas generator |
PCT/US1995/006949 WO1996038516A1 (en) | 1993-11-08 | 1995-06-02 | Internal combustion gas generator |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996038516A1 true WO1996038516A1 (en) | 1996-12-05 |
Family
ID=27508641
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1995/006949 WO1996038516A1 (en) | 1993-11-08 | 1995-06-02 | Internal combustion gas generator |
Country Status (5)
Country | Link |
---|---|
US (3) | US5441546A (en) |
EP (1) | EP0828804A4 (en) |
JP (1) | JP3145123B2 (en) |
CA (1) | CA2221594A1 (en) |
WO (1) | WO1996038516A1 (en) |
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1995
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- 1995-06-02 CA CA002221594A patent/CA2221594A1/en not_active Abandoned
- 1995-06-02 EP EP95922930A patent/EP0828804A4/en not_active Ceased
- 1995-06-02 WO PCT/US1995/006949 patent/WO1996038516A1/en not_active Application Discontinuation
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Also Published As
Publication number | Publication date |
---|---|
US5529484A (en) | 1996-06-25 |
US5437123A (en) | 1995-08-01 |
EP0828804A4 (en) | 1999-05-19 |
US5441546A (en) | 1995-08-15 |
EP0828804A1 (en) | 1998-03-18 |
CA2221594A1 (en) | 1996-12-05 |
JP3145123B2 (en) | 2001-03-12 |
JPH10511448A (en) | 1998-11-04 |
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