WO1996038516A1 - Internal combustion gas generator - Google Patents

Internal combustion gas generator Download PDF

Info

Publication number
WO1996038516A1
WO1996038516A1 PCT/US1995/006949 US9506949W WO9638516A1 WO 1996038516 A1 WO1996038516 A1 WO 1996038516A1 US 9506949 W US9506949 W US 9506949W WO 9638516 A1 WO9638516 A1 WO 9638516A1
Authority
WO
WIPO (PCT)
Prior art keywords
chamber
air
fuel
burner
pair
Prior art date
Application number
PCT/US1995/006949
Other languages
French (fr)
Inventor
David M. Moard
Leonard Greiner
Original Assignee
Hydrogen Burner Technology, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US08/148,472 priority Critical patent/US5441546A/en
Priority to US08/309,041 priority patent/US5437123A/en
Priority to US08/440,698 priority patent/US5529484A/en
Application filed by Hydrogen Burner Technology, Inc. filed Critical Hydrogen Burner Technology, Inc.
Priority to JP51556496A priority patent/JP3145123B2/en
Priority to CA002221594A priority patent/CA2221594A1/en
Priority to EP95922930A priority patent/EP0828804A4/en
Priority to KR1019970708658A priority patent/KR100255335B1/en
Priority to PCT/US1995/006949 priority patent/WO1996038516A1/en
Publication of WO1996038516A1 publication Critical patent/WO1996038516A1/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C6/00Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion
    • F23C6/04Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B47/00Methods of operating engines involving adding non-fuel substances or anti-knock agents to combustion air, fuel, or fuel-air mixtures of engines
    • F02B47/02Methods of operating engines involving adding non-fuel substances or anti-knock agents to combustion air, fuel, or fuel-air mixtures of engines the substances being water or steam
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M25/00Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
    • F02M25/022Adding fuel and water emulsion, water or steam
    • F02M25/0221Details of the water supply system, e.g. pumps or arrangement of valves
    • F02M25/0225Water atomisers or mixers, e.g. using ultrasonic waves
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M25/00Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
    • F02M25/10Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture adding acetylene, non-waterborne hydrogen, non-airborne oxygen, or ozone
    • F02M25/12Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture adding acetylene, non-waterborne hydrogen, non-airborne oxygen, or ozone the apparatus having means for generating such gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M53/00Fuel-injection apparatus characterised by having heating, cooling or thermally-insulating means
    • F02M53/02Fuel-injection apparatus characterised by having heating, cooling or thermally-insulating means with fuel-heating means, e.g. for vaporising
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D14/00Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/20Non-premix gas burners, i.e. in which gaseous fuel is mixed with combustion air on arrival at the combustion zone
    • F23D14/22Non-premix gas burners, i.e. in which gaseous fuel is mixed with combustion air on arrival at the combustion zone with separate air and gas feed ducts, e.g. with ducts running parallel or crossing each other
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D14/00Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/46Details, e.g. noise reduction means
    • F23D14/66Preheating the combustion air or gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L7/00Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
    • F23L7/002Supplying water
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00Engines characterised by air compression and subsequent fuel addition
    • F02B3/06Engines characterised by air compression and subsequent fuel addition with compression ignition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Definitions

  • the present invention relates to the field of reducing nitrogen oxide emission from internal combustion engines and turbines, and more particularly to a novel means and method for conducting a feed mixture flow from a preheater assembly to a fully insulated burner having an insulated inner burner supplying gases from a portion or part of the main engine fuel whether it be gaseous or liquid to an insulated outer burner.
  • N0 X nitrogen oxides
  • the present invention teaches the use of an underoxidized burner using the main fuel to obtain hydrogen .
  • the first stage includes regions with air-fuel ratios near stoichiometric wherein high temperatures occur that induce initiating undesired chemical reaction with the fuel. Such temperatures result in elevated concentrations of N0 ⁇ .
  • a second stage operates air rich to achieve final overall air- fuel ratio. Its temperature is lower but not sufficiently low that N0 X cannot form, and this stage generally does not remove N0 ⁇ which has been formed in the first stage. The overall result is that N0 ⁇ formed in both stages appears in the burner exhaust.
  • the present invention provides a novel means and method utilizing a fully insulated burner for combusting air and hydrocarbons at fuel-rich stoichiometric air/fuel ratios from 0.3 to 1, which includes a first stage burner having a combustion chamber properly coupled to a main source of fuel which includes means for diverting a portion of the main fuel into the burner along with a portion or all of the main air so that the fuel portion and air portion impinge against a first baffle arrangement whereby impingement thoroughly mixes the fuel/air combination preparatory for ignition in the combustion chamber.
  • Means are provided for exhausting the burned gases from the first stage burner into the combustion chamber of a second stage burner via a second baffle arrangement and then into exhaust. The excellent mixing provided by said impingements results in close to theoretical equilibration of the fuel-rich reaction, despite the low reactivity of the original excess fuel.
  • Yet another object is to provide a novel burner apparatus means and method which is a very simple, non-catalytic burner means and method for producing hydrogen from a portion or all of the main engine fuel for injection into the main engine combustor with the remainder of the fuel or full fuel flow to attain high air/fuel ratios leading to minimal or zero nitrogen oxide formation.
  • a still further object of the present invention is to provide a hydrogen generator for use in connection with reducing nitrogen oxide in an engine emission which does not require additives that degrade fuel performance and which burner contributes little to engine complexity.
  • Yet another object of the present invention is to provide a novel means and apparatus and method utilizing a two-stage fully insulated burner to reduce nitrogen oxides from internal combustion engines and turbines by utilization of a simple hydrogen generator fed by a small portion or all of main engine fuel whereby the resultant hydrogen produced is to be co- fired or flowed in the engine with the remainder of the main fuel, or as the fuel.
  • a further object resides in the provision of an air/fuel mixture pre-heating means and methodology so as to provide a higher combustion temperature to assist the equilibration process.
  • Another object resides in employment of an insulated burner with preferably two fuel-air mixing chambers to insure vaporization of liquid fuel with increased hydrogen output.
  • FIGURE 1 is a chart of theoretical equilibrium calculations for methane-air combinations
  • FIGURE 2 is an enlarged longitudinal diagrammatic view, in section, illustrating the novel two-stage no-NO x burner means employed in an engine for hydrogen generation;
  • FIGURE 3 is a chart illustrating theoretical temperatures and diagrammatic sectional views of the hydrogen generator for fuel/air feed (designated "normal") before and after (designated VOB) heating to 1000°F employing a pre-heater means using heat exchange principles;
  • FIGURE 4 is a diagrammatic longitudinal cross- sectional view of a prior art single-stage burner;
  • FIGURE 5 is a diagrammatic sectional view of another version of a two-stage burner having separate and individually insulated heat exchanger combustion chambers;
  • FIGURE 6 is a view similar to the burner shown in FIGURE 5 showing a modified heat exchanger
  • FIGURE 7 is a transverse cross-sectional view of the burner shown in FIGURE 5 as taken in the direction of arrows 7-7 thereof;
  • FIGURE 8 is a transverse sectional view taken in the direction of arrows 8-8 in FIGURE 6;
  • FIGURE 9 is a view similar to the burner shown in FIGURE 6 showing a preferred modified heat exchanger and also illustrating a ceramic or cement insulation ring between heat exchanger and burner rear.
  • FIGURE 10 is a side elevational view of the ceramic ring disassembled from the burner shown in FIGURE 9. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
  • ratios of air (formula, 0 2 + 3.76 N 2 ) to fuel are set with more than sufficient oxygen (0 2 ) to react all carbon (C) atoms to carbon dioxide (C0 2 ) and all hydrogen (H) to water (H 2 0) .
  • methane (CH 4 ) as fuel, this is represented by the equation,
  • the technology of the co-patents can result in an underoxidized burner replacing the customary near- stoichiometric regions in the first stage of a burner. While the latter produces N0 X that eventually appears in the exhaust, N0 X cannot form in the very fuel rich underoxidized burner. It equilibrates instead to easily combustible CO and H 2 , and very minor amounts of undecomposed fuel. As a consequence, injecting a mix of such products and the air needed to attain the desired overall air-fuel ration into a second stage burner which incorporates means to achieve the same rapid flow reversals taught by the co-patents, results in rapid chemical equilibration. These factors, aided by the relatively high concentration of H 2 , permits stable combustion at extraordinarily lean air/fuel ratios with relatively low temperature where N0 X does not form.
  • FIGURE 2 is an example of a no-NO x burner incorporating the present invention and is illustrated in the general direction of arrow 10.
  • a burner enclosure 11 is internally covered with an insulation material 12.
  • Air is introduced via an inlet 13 with flow being controlled by a valve 14.
  • a portion of the air controlled by valve 14A passes into a heat exchanger 15 in heat exchange relationship with hot gases 16 within a first stage burner 17.
  • Fuel is introduced to the heat exchanger through an inlet 18 and is passed through a valve 19 into the heat exchanger 15.
  • the pre-heated air/fuel mixture leaves the heat exchanger via a hole 20 and enters an annulus 21 enclosed by a tube 22.
  • the gases pass through the annulus and impinge on the cover of a thimble 23 causing a 90° turn to be taken and eventually, the gases leave the thimble 9 via an orifice 24.
  • the gases then impinge on the insulated rear wall 25 where another 90° turn takes place.
  • the gases are again turned 90° at outward wall 26 and are ignited by a spark plug 27.
  • the burning mixture then moves through the first stage burner 17 to a firewall 30 and exits the first stage chamber via a tube 21.
  • Remaining air from valve 14 moves into a flat tubular heat exchanger 31 in heat exchange relationship with gases 24 and the heated air leaves the exchanger 31 and enters tube 32 via entrance 33. This exchanger may be substituted by a straight tube leading into tube 21.
  • the mixed air and burner products leave the tube 32 via a hole 34 and move into a second annulus 35.
  • the gases now impinge onto the closed end of a thimble 37 where the gases are now turned 90° and leave the thimble via an exit opening 38 to impinge on the firewall where flow is again turned 90°.
  • the gases then move to the cylinder wall 26 in the second chamber or second stage burner 40.
  • the gases finally exit the burner through an orifice 41.
  • Acceptable formulations for the first and second stage burners can be deduced from FIGURE 1.
  • S should be above 0.3 to prevent formulation of solid carbon that would interfere with operation of the burner or methane that might be difficult to burn in the second stage and below about 0.6 to prevent formation of NO x .
  • S should be up to 3, preferably at 3 to prevent formation of NO ⁇ .
  • the latter ratio includes total air and feed flows to both stages.
  • FIGURE 3 includes theoretical temperatures for fuel-air feed before and after heating to 1000°F, with increases in the latter case of 600° to 800°F. As indicated in a previous application, the higher temperature greatly increases the likelihood of attaining the theoretical equilibrium needed to provide hydrogen. Attaining such temperatures, however, requires decreasing thermal losses.
  • a methane burner operating at stoichiometric ratio over unity with C0 2 and H 2 0 as major products provides about 22,000 Btu/lb of methane, with the result that thermal losses in the range of 1000 Btu/lb or more are relatively unimportant and so its combustion temperature can approach its theoretical of 3300°F where chemical equilibration is likely.
  • much less energy is liberated on reaction of the underoxidized burner because its ideal products are hydrogen and carbon monoxide.
  • the curve labeled "Btu/lb" in FIGURE 3 relates to theoretical heat outputs for methane-air reaction at underoxidized stoichiometric ratios from .25 to .75. It shows energy output as low as about 500 Btu at the lowest practical ratio of about 0.3 and about 7500 at the upper ratio of about .5. At such low energy outputs minor thermal losses become significant.
  • the curve labeled "normal" in FIGURE 3 relates theoretical temperature for feed of 78°F of underoxidized burners to stoichiometric ratios from .25 to .75. At the low practical ratio of .3, the heat output is easily overshadowed by heat losses, so theoretical temperature is virtually impossible to achieve. Even at the high practical ratio of 0.5, the theoretical temperature of 2300°F is hard to achieve unless thermal losses are severely decreased.
  • the burner wall 45 is always composed of material which is insulative to some degree; however, this burner wall still results in heat losses since thermal conductivity is proportional to temperature difference and the insulation contacts the highest temperature of the burner on one side and the lowest external temperature on the other side. Also, the thermal conductivity of most insulation increases with temperature, as indicated in the following Table from Carborundum for Fibrefax Felt.
  • the prior art burner is indicated by numeral 45 having a housing 46 with an internal combustion chamber 47.
  • the heat exchanger 48 accepts fuel via inlet 48 and air via inlet 50 with a portion of fuel being introduced via inlet 51.
  • the fuel/air is initially combined in a tube 52 which is open-ended so that the combined fuel/air is directed towards a baffle 53, as indicated by the flow of arrows such that the flow is reversed upon itself and exists through the tube 52 inside a cup 53 where the streams impinge on the baffle 53.
  • Flow direction is changed 90 degrees radially outwardly and then 90 degrees to an opening 54 in a plate 55 into the combustion chamber 47 for exiting via duct 56. Additional disclosure is found in the previously noted co-pending applications.
  • Heat loss can be decreased by locating a burner section with the feed heat exchanger, as indicated FIGURE 5, which tends to "fold" the burner onto itself, to more closely resemble a sphere.
  • FIGURE 5 employs a thicker and more efficient insulation than the prior art
  • FIGURES 5 and 7 version as shown in the direction of arrow 60, is more efficient.
  • the burner 60 has an outer section 61 with heavy insulation 62 surrounding an inner section 63 which is hollow and open ended at number 64 and closed at a wall 65.
  • a first chamber 66 is defined between the heavily insulated inner section 63 and the outer section 61 while number 67 indicates a second chamber within inner section 63.
  • a spiral heat exchanger 68 containing the feed mixture is disposed in the first chamber 66 and having an inlet 70 and an outlet 71 discharging into the second chamber 64.
  • the air/fuel mixture enters into heat exchanger 68 via an entry coil 72 and passes to an existing coil 73 via an intermediate coil 74 that surrounds the inner section 63. Ignition is achieved by spark plug 73 within second chamber 67 as the preheated air/fuel mixture is discharged from the outlet 71 when the gases impinge against wall 65 and reverse flow direction. Gases then flow from the second chamber 67 through opening 64 into the outer or first chamber 66 for exhaust discharge through exhaust outlet 75.
  • the spiral heat exchanger 68 containing the feed mixture is surrounded by high temperature gases from the burner chamber 67. These hot gases contact the inner surface of the insulating wall of the outer section 61 while the outer surface is in contact with the cool exterior. As a result, the temperature drop across the insulation is high which causes a considerable swing in heat flux values.
  • FIGURES 6 and 8 discloses a heat exchanger section which greatly reduces or decreases the heat flux swing values.
  • the burner device is illustrated in the direction of arrow 80 which includes an outer section 81 and an inner section 82, both of which are composed of insulated walls and arranged in coaxial spaced apart relationship defining a first chamber 83 and internal burner chamber 84 which is open at end 85.
  • An inlet 86 brings air/fuel supply to a heat exchanger 87 consisting of a plurality of spaced apart parallel tubes coaxial with the burner and having opposites joined in annular tubes 88 and 89.
  • Tubular spokes 90-94 connect the heat exchanger parallel tubes with inlet 86 while similar tubular spokes 103 connect the other end of the parallel tubes with a feed tube 95.
  • the end of the tube 95 supports a baffle or cup 96 having an end wall against the feed mixture impinges which reverses the flow and then exits into the burner chamber 84.
  • the flow impacts against end wall 98 which causes another directional flow reversal. Ignition is achieved by spark plug 100 and the exhaust flow exits through opening 85 into the first chamber 83 partially occupied by the heat exchanger 87. Discharge of the gases is via exhaust exit 102 connected to the first chamber after the gases flow past the heat exchanger.
  • the heat exchanger forms an outer and an inner annulus.
  • the outer contains the cooled feed mixture and is located adjacent to the outer wall of insulation.
  • FIGURE 9 another burner version is illustrated in the general direction of arrow 110 which, as previously described, includes an insulated outer wall 111 coaxially disposed with respect to an inner section 112 having an opening 113 in fluid communication with a closed inner chamber 114. An outer chamber 115 is separated therefrom by a "can" like metal separator 116.
  • the outer chamber is in communication with an inlet 117 for conducting air/fuel mixture to a fully insulated injector-mixer 118 which includes a baffle plate or cup 120 for effecting feed mixture flow reversal as previously described.
  • a wall 121 of the inner section 112 causes another flow reversal.
  • Spark plug 122 ignites the gases in a burner chamber 123 for exiting through inner chamber 114 to an exhaust outlet 124.
  • the gases move against the insulated wall with 111 within the annulus and the pass radially inward along the chamber 115 to the injector-mixer 118.
  • the hot gases formed in the burner chamber 123 impinge on the inner surface of the separator 116 and then pass radially outward to an annulus bounded by the separator and the insulated inner section 112. Finally the gases exit at outlet 124.
  • the separator is the exchanger surface between burner gas and feed gases. Its area is sufficiently large so that there is no requirement for any "extended” surfaces. Flows are parallel, instead of counter flow, to limit heat exchange and prevent uncontrolled temperature caused by any conventional "boot strap” process. This is not a requirement and counter flow may also be used.
  • the inventive burner concept may be employed with diesel fuel in diesel-type engines.
  • a major problem with such engines are particulates (smoke) ejected from the tail pipe, which include toxic material and provide a visual and auditory nuisance.
  • particulates could be eliminated by using the first section of the inventive burner to gasify all the diesel fuel prior to injection into the engine, along with the further air necessary to get the final air fuel ratio. By doing so, the diesel fuel cannot produce particulates.
  • the process would also result in the ability of the engine burner to operate at low air/fuel ratios where N0 X does not form.
  • the several impingements of the air/fuel mixture result in an intimate mixture that readily ignites and burns to completion in a certain volume.
  • This volume may be decreased by about 25% by placing a preferably ceramic ring 125 within the burner below the location where the fuel stream leaves the mixer, as shown in FIGURE 9. Apparently the ring causes the burning gases to move from the sides of the burner and into its center, after which a portion spontaneously moves back to the wall, and so results in more complete utilization of the burner volume.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Water Supply & Treatment (AREA)

Abstract

Apparatus is disclosed herein for reducing engine nitrogen oxide emissions by mixing hydrogen prepared from a portion or all of engine fuel within a simple burner. The apparatus includes an insulated burner (10) having an internal combustion chamber (17, 40) for receiving either a portion of or all the gaseous fuel or liquid fuel for mixture with air and subsequent ignition by a spark plug (27). The chamber is within a feed preheater assembly. A mixing chamber (17, 40) is included having a series of baffles (22, 23, 32, 37) against which injected air and fuel vapor impinge causing thorough and complete air/fuel blending into a mixture subsequently ignited and burned, and then discharged into the combustion chamber of the engine itself. The pre-heating assembly (15, 31) raises the temperature of the incoming air/fuel mixture via a heat exchanging process with post combusted gases from the combustion chamber. The apparatus improves operability and performs by conserving energy by insulating the total burner, placing the burner section within the feed preheater assembly, and locating the feed mixture flow of the preheater adjacent to the outer insulation (12); and hydrogen output may be increased by reaction between carbon monoxide and water produced by the main reaction or added separately.

Description

INTERNAL COMBUSTION GAS GENERATOR
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to the field of reducing nitrogen oxide emission from internal combustion engines and turbines, and more particularly to a novel means and method for conducting a feed mixture flow from a preheater assembly to a fully insulated burner having an insulated inner burner supplying gases from a portion or part of the main engine fuel whether it be gaseous or liquid to an insulated outer burner.
2. Brief Description of the Prior Art
It is well known that nitrogen oxides (N0X) form at the high temperatures normally associated with combustion processes and that operating an engine at lean conditions with excess air lowers temperature and, therefore, decreases N0X. However, decades of engine and turbine studies have shown that lean combustion limits are above those where N0X emissions are below specified goals. Natural gas and gasoline are examples where lean combustion has been pushed to its limit and where it has been found that hydrogen addition increases this limit to where N0X output is acceptably low. However, means to obtain hydrogen for this purpose are beset with problems.
Problems and difficulties have been encountered when the supply of hydrogen is provided by materials carried in a separate tank which can be extremely heavy and requires pressurization. As examples, methanol, hydrogen or ammonium nitrate can provide or produce hydrogen when added to an engine combustor. However, these take the place of the fuel and so reduce the volumetric storage capacity which lowers overall performance, and results in complications through use of secondary materials. Hydrogen stored in the pressurized container which holds methane (Hythane) can also be used, but this causes about .75 percent reduced engine range for each percent hydrogen used because of its very low energy content on a volumetric basis, and also requires special means to enable safe storage of hydrogen.
The present invention teaches the use of an underoxidized burner using the main fuel to obtain hydrogen .
Previous attempts have been made to improve the underoxidized burner disclosed in the applicants' two previous patent applications by pre- ixing fuel and air, pre-heating the fuel-air feed by heat exchange with the burner products, and affecting circulation of the burning products. Such prior attempts have been successful in reducing nitrogen oxide emission. Thus, the two stage burner described in the first disclosure utilizes technology to effect chemical equilibration with air-fuel formulations containing a great excess of fuel and a second stage in the prior disclosures utilizes related technology to attempt equilibration between the products of the first stage and excess air.
Conventional burners operate air rich and react in roughly two stages. The first stage includes regions with air-fuel ratios near stoichiometric wherein high temperatures occur that induce initiating undesired chemical reaction with the fuel. Such temperatures result in elevated concentrations of N0χ. A second stage operates air rich to achieve final overall air- fuel ratio. Its temperature is lower but not sufficiently low that N0X cannot form, and this stage generally does not remove N0χ which has been formed in the first stage. The overall result is that N0χ formed in both stages appears in the burner exhaust.
In the second previous patent application mentioned above, technology is disclosed for attaining chemical equilibration between air and a large excess of fuel in an underoxidized burner through a process whereby the air-fuel mixture undergoes certain rapid flow reversals. This technology results in equilibration at a reasonably high temperature without resulting in formation of N0χ since its excessive fuel concentration preferentially causes reaction between air and fuel instead of air and N3 to form N02.
It has been found that the technology of co-patents nos. 07-858,840 and 07-997,450 results in products that are easily combusted with further air. As a consequence, a combustor with excess air for powering engines which produces virtually zero N0X can be achieved by a related two-stage process. The first stage comprises a fuel-rich burner of the type taught in these co-patents. The second stages uses similar technology but operates air rich. Products from the first stage and the excess air needed to attain the final air-fuel mixture are introduced into the second stage. In this stage, a mixture of the latter air and latter products undergoes the same rapid flow reversals taught by the technology of the co-patents, which result in their rapid chemical equilibration. In view of the improved reactivity of the fuel products obtained from the underoxidized burner, the induced flow reversals, and the relatively high concentration of hydrogen, equilibration can be induced in the second stage at a higher ration of air-fuel than normally used. This results in very low temperatures where N0X formation is very low.
The technology of the co-patents results in an underoxidized burner replacing the customary near- stoichiometric regions in the first stage of a burner. While the latter produces N0χ that eventually appears in the exhaust, N0X cannot form in the very fuel rich underoxidized burner. It equilibrates instead to easily combustible CO and H2, and very minor amounts of undecomposed fuel. As a consequence, injecting a mix of such products and the air needed to attain the desired overall air-fuel ration into a second stage burner which incorporates means to achieve the same rapid flow reversals taught by the co-patents, results in rapid chemical equilibration. These factors, aided by the relatively high concentration of H2, permits stable combustion at extraordinarily lean air/fuel ration with relatively low temperature where N0χ does not form.
Therefore, a long-standing need has existed to provide novel means and methods for accomplishing a technology breakthrough for a simple means of producing hydrogen from fuel in a simple fully insulated burner without the catalyst and without a special pressurized hydrogen or related storage means heretofore normally considered required and whereby improved results are gained employing first and second stages which are virtually N0χ free, as in the overall combustor, leading to a no-NOx burner.
SinVLMARY OF THE INVENTION
Accordingly, the above problems and difficulties are avoided by the present invention which provides a novel means and method utilizing a fully insulated burner for combusting air and hydrocarbons at fuel-rich stoichiometric air/fuel ratios from 0.3 to 1, which includes a first stage burner having a combustion chamber properly coupled to a main source of fuel which includes means for diverting a portion of the main fuel into the burner along with a portion or all of the main air so that the fuel portion and air portion impinge against a first baffle arrangement whereby impingement thoroughly mixes the fuel/air combination preparatory for ignition in the combustion chamber. Means are provided for exhausting the burned gases from the first stage burner into the combustion chamber of a second stage burner via a second baffle arrangement and then into exhaust. The excellent mixing provided by said impingements results in close to theoretical equilibration of the fuel-rich reaction, despite the low reactivity of the original excess fuel.
Therefore, it is a primary object of the present invention to provide a novel fully insulated burner means having means for intimate pre-mixing of fuel and a deficiency of air which is achieved by bringing the air and fuel together in a first separate chamber and then to a second chamber where the flow is induced to move back and forth via a series of baffle assemblies in each of the chambers preparatory for entering the combustion chamber where ignition of the mixture occurs.
Yet another object is to provide a novel burner apparatus means and method which is a very simple, non-catalytic burner means and method for producing hydrogen from a portion or all of the main engine fuel for injection into the main engine combustor with the remainder of the fuel or full fuel flow to attain high air/fuel ratios leading to minimal or zero nitrogen oxide formation.
A still further object of the present invention is to provide a hydrogen generator for use in connection with reducing nitrogen oxide in an engine emission which does not require additives that degrade fuel performance and which burner contributes little to engine complexity.
Yet another object of the present invention is to provide a novel means and apparatus and method utilizing a two-stage fully insulated burner to reduce nitrogen oxides from internal combustion engines and turbines by utilization of a simple hydrogen generator fed by a small portion or all of main engine fuel whereby the resultant hydrogen produced is to be co- fired or flowed in the engine with the remainder of the main fuel, or as the fuel.
A further object resides in the provision of an air/fuel mixture pre-heating means and methodology so as to provide a higher combustion temperature to assist the equilibration process.
Another object resides in employment of an insulated burner with preferably two fuel-air mixing chambers to insure vaporization of liquid fuel with increased hydrogen output.
BRIEF DESCRIPTION OF THE DRAWINGS
The features of the present invention which are believed to be novel are set forth with particularity in the appended claims. The present invention, both as to its organization and manner of operation, together with further objects and advantages thereof, may best be understood with reference to the following description, taken in connection with the accompanying drawings in which:
FIGURE 1 is a chart of theoretical equilibrium calculations for methane-air combinations;
FIGURE 2 is an enlarged longitudinal diagrammatic view, in section, illustrating the novel two-stage no-NOx burner means employed in an engine for hydrogen generation;
FIGURE 3 is a chart illustrating theoretical temperatures and diagrammatic sectional views of the hydrogen generator for fuel/air feed (designated "normal") before and after (designated VOB) heating to 1000°F employing a pre-heater means using heat exchange principles; FIGURE 4 is a diagrammatic longitudinal cross- sectional view of a prior art single-stage burner;
FIGURE 5 is a diagrammatic sectional view of another version of a two-stage burner having separate and individually insulated heat exchanger combustion chambers;
FIGURE 6 is a view similar to the burner shown in FIGURE 5 showing a modified heat exchanger;
FIGURE 7 is a transverse cross-sectional view of the burner shown in FIGURE 5 as taken in the direction of arrows 7-7 thereof;
FIGURE 8 is a transverse sectional view taken in the direction of arrows 8-8 in FIGURE 6; and
FIGURE 9 is a view similar to the burner shown in FIGURE 6 showing a preferred modified heat exchanger and also illustrating a ceramic or cement insulation ring between heat exchanger and burner rear.
FIGURE 10 is a side elevational view of the ceramic ring disassembled from the burner shown in FIGURE 9. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
In conventional burners, as shown in FIGURE 1, ratios of air (formula, 02 + 3.76 N2) to fuel are set with more than sufficient oxygen (02) to react all carbon (C) atoms to carbon dioxide (C02) and all hydrogen (H) to water (H20) . With methane (CH4 ) as fuel, this is represented by the equation,
(1) CH4 + S X 2 (02 + 3.76 N2) =
C02 + 2 H2 + S X 2 x 3.76 N2 + 2 X (S - 1) 02,
where S, the air/fuel "stoichiometric ratio", is unity when there are just sufficient oxygen atoms to reach with all fuel atoms. State-of-the-art burners used, for example, with engines normally operate with S greater than one, with excess air molecules (02 and N2) emerging relatively unchanged, except that at high temperatures excessive concentrations of N0χ form which are difficult to dissociate to elements. This is undesirable pollutant.
Results of theoretical equilibrium calculations for methane-air combinations are assembled in FIGURE 1 for air/fuel S from 0.1 to 3.0, reaction at one atmosphere, and feed at 78°F. Species are given as moles of product per mole of methane feed vs. S, except N0X is volume percent times 10. Temperature is in deg F divided by 1000. Virtually all potential products are included in the calculations. However, N2 is excluded because it exceeds the orinate; it can be calculated from S x 2 x 3.76.
As shown, N0χ is 0.19 to 0.34% near S = 1 where temperature is high. These are excessive values. Because excess air lowers temperature, N0χ is .08% at S = 2 and only 0.01% at S = 3. At the latter conditions, reaction between N2 and 02 is slow, so actual NOx concentration is even less. However, normal burners do not operate stablely at such very lean conditions.
The technology of the co-patents can result in an underoxidized burner replacing the customary near- stoichiometric regions in the first stage of a burner. While the latter produces N0X that eventually appears in the exhaust, N0X cannot form in the very fuel rich underoxidized burner. It equilibrates instead to easily combustible CO and H2, and very minor amounts of undecomposed fuel. As a consequence, injecting a mix of such products and the air needed to attain the desired overall air-fuel ration into a second stage burner which incorporates means to achieve the same rapid flow reversals taught by the co-patents, results in rapid chemical equilibration. These factors, aided by the relatively high concentration of H2, permits stable combustion at extraordinarily lean air/fuel ratios with relatively low temperature where N0X does not form.
The results are first and second stages which are virtually NOχ-free, as is the overall combustor, leading to a no-NOχ burner.
FIGURE 2 is an example of a no-NOx burner incorporating the present invention and is illustrated in the general direction of arrow 10. A burner enclosure 11 is internally covered with an insulation material 12. Air is introduced via an inlet 13 with flow being controlled by a valve 14. A portion of the air controlled by valve 14A passes into a heat exchanger 15 in heat exchange relationship with hot gases 16 within a first stage burner 17. Fuel is introduced to the heat exchanger through an inlet 18 and is passed through a valve 19 into the heat exchanger 15. The pre-heated air/fuel mixture leaves the heat exchanger via a hole 20 and enters an annulus 21 enclosed by a tube 22. The gases pass through the annulus and impinge on the cover of a thimble 23 causing a 90° turn to be taken and eventually, the gases leave the thimble 9 via an orifice 24. The gases then impinge on the insulated rear wall 25 where another 90° turn takes place. The gases are again turned 90° at outward wall 26 and are ignited by a spark plug 27. The burning mixture then moves through the first stage burner 17 to a firewall 30 and exits the first stage chamber via a tube 21. Remaining air from valve 14 moves into a flat tubular heat exchanger 31 in heat exchange relationship with gases 24 and the heated air leaves the exchanger 31 and enters tube 32 via entrance 33. This exchanger may be substituted by a straight tube leading into tube 21. The mixed air and burner products leave the tube 32 via a hole 34 and move into a second annulus 35. The gases now impinge onto the closed end of a thimble 37 where the gases are now turned 90° and leave the thimble via an exit opening 38 to impinge on the firewall where flow is again turned 90°. The gases then move to the cylinder wall 26 in the second chamber or second stage burner 40. The gases finally exit the burner through an orifice 41.
Acceptable formulations for the first and second stage burners can be deduced from FIGURE 1. Thus, for the first stage underoxidized burner, S should be above 0.3 to prevent formulation of solid carbon that would interfere with operation of the burner or methane that might be difficult to burn in the second stage and below about 0.6 to prevent formation of NOx. For the second stage, S should be up to 3, preferably at 3 to prevent formation of NOχ. The latter ratio includes total air and feed flows to both stages.
Further means are disclosed to improve the operability and performance of the underoxidized burner while conserving energy through insulating the overall burner, placing the burner section within the feed preheater assembly, locating the feed-mixture flow of the preheater adjacent to the outer insulation and by increasing hydrogen output by effecting reaction between carbon monoxide and water produced by the main reaction or added separately. The previous co-pending disclosures noted above reveal means to improve the underoxidized burner by pre-mixing fuel and air, preheating the fuel/air feed by heat exchange with the burner products, and effecting circulation of the burning products. Additional means for improvement are discussed as follows:
FIGURE 3 includes theoretical temperatures for fuel-air feed before and after heating to 1000°F, with increases in the latter case of 600° to 800°F. As indicated in a previous application, the higher temperature greatly increases the likelihood of attaining the theoretical equilibrium needed to provide hydrogen. Attaining such temperatures, however, requires decreasing thermal losses.
A methane burner operating at stoichiometric ratio over unity with C02 and H20 as major products provides about 22,000 Btu/lb of methane, with the result that thermal losses in the range of 1000 Btu/lb or more are relatively unimportant and so its combustion temperature can approach its theoretical of 3300°F where chemical equilibration is likely. On the other hand, much less energy is liberated on reaction of the underoxidized burner because its ideal products are hydrogen and carbon monoxide. Thus, the curve labeled "Btu/lb" in FIGURE 3 relates to theoretical heat outputs for methane-air reaction at underoxidized stoichiometric ratios from .25 to .75. It shows energy output as low as about 500 Btu at the lowest practical ratio of about 0.3 and about 7500 at the upper ratio of about .5. At such low energy outputs minor thermal losses become significant.
The curve labeled "normal" in FIGURE 3 relates theoretical temperature for feed of 78°F of underoxidized burners to stoichiometric ratios from .25 to .75. At the low practical ratio of .3, the heat output is easily overshadowed by heat losses, so theoretical temperature is virtually impossible to achieve. Even at the high practical ratio of 0.5, the theoretical temperature of 2300°F is hard to achieve unless thermal losses are severely decreased.
One means to decrease normal thermal losses is with insulation. As disclosed in the co-pending applications and as shown in FIGURE 4, the burner wall 45 is always composed of material which is insulative to some degree; however, this burner wall still results in heat losses since thermal conductivity is proportional to temperature difference and the insulation contacts the highest temperature of the burner on one side and the lowest external temperature on the other side. Also, the thermal conductivity of most insulation increases with temperature, as indicated in the following Table from Carborundum for Fibrefax Felt.
Temperature Conductivity
°F Btu-in/hr-ft2-°F
500 .394
1000 .643
1500 1.041
2000 1.504
2500 2.572
3000 6.300
FIGURE 3 also shows theoretical hydrogen formed vs. stoichiometric ratio. Due to formation of water at the lower ratios, hydrogen decreases with increased ratio from a maximum of almost 2 moles/mole of methane. FIGURE 3 also shown a more-or-less constant 1 mole of CO per mole of methane is also formed. At low temperature, CO readily reacts with water in a down stream shift reaction to re-form hydrogen through the reaction, CO + H20 = H2 + C02, until stoichiometric ratio of .5 when all the CO is converted with the result that total hydrogen remains about 2 moles per mole of methane. At the very low ratios, further hydrogen can be formed by adding excess water, as shown in the FIGURE. Such "shift" reactions require cooling, perhaps in a cylinder located downstream from the burner, cooled as by a spiral heat exchanger with air flowing therethrough.
In addition, heat loss is proportional to external areas, and the configure of FIGURE 4 does not minimize this area. The prior art burner is indicated by numeral 45 having a housing 46 with an internal combustion chamber 47. The heat exchanger 48 accepts fuel via inlet 48 and air via inlet 50 with a portion of fuel being introduced via inlet 51. The fuel/air is initially combined in a tube 52 which is open-ended so that the combined fuel/air is directed towards a baffle 53, as indicated by the flow of arrows such that the flow is reversed upon itself and exists through the tube 52 inside a cup 53 where the streams impinge on the baffle 53. Flow direction is changed 90 degrees radially outwardly and then 90 degrees to an opening 54 in a plate 55 into the combustion chamber 47 for exiting via duct 56. Additional disclosure is found in the previously noted co-pending applications.
Heat loss can be decreased by locating a burner section with the feed heat exchanger, as indicated FIGURE 5, which tends to "fold" the burner onto itself, to more closely resemble a sphere. Although the embodiment shown in FIGURE 2 employs a thicker and more efficient insulation than the prior art, the FIGURES 5 and 7 version as shown in the direction of arrow 60, is more efficient. The burner 60 has an outer section 61 with heavy insulation 62 surrounding an inner section 63 which is hollow and open ended at number 64 and closed at a wall 65. A first chamber 66 is defined between the heavily insulated inner section 63 and the outer section 61 while number 67 indicates a second chamber within inner section 63. A spiral heat exchanger 68 containing the feed mixture is disposed in the first chamber 66 and having an inlet 70 and an outlet 71 discharging into the second chamber 64. The air/fuel mixture enters into heat exchanger 68 via an entry coil 72 and passes to an existing coil 73 via an intermediate coil 74 that surrounds the inner section 63. Ignition is achieved by spark plug 73 within second chamber 67 as the preheated air/fuel mixture is discharged from the outlet 71 when the gases impinge against wall 65 and reverse flow direction. Gases then flow from the second chamber 67 through opening 64 into the outer or first chamber 66 for exhaust discharge through exhaust outlet 75.
Therefore, the spiral heat exchanger 68 containing the feed mixture is surrounded by high temperature gases from the burner chamber 67. These hot gases contact the inner surface of the insulating wall of the outer section 61 while the outer surface is in contact with the cool exterior. As a result, the temperature drop across the insulation is high which causes a considerable swing in heat flux values.
The embodiment of FIGURES 6 and 8 discloses a heat exchanger section which greatly reduces or decreases the heat flux swing values. The burner device is illustrated in the direction of arrow 80 which includes an outer section 81 and an inner section 82, both of which are composed of insulated walls and arranged in coaxial spaced apart relationship defining a first chamber 83 and internal burner chamber 84 which is open at end 85. An inlet 86 brings air/fuel supply to a heat exchanger 87 consisting of a plurality of spaced apart parallel tubes coaxial with the burner and having opposites joined in annular tubes 88 and 89. Tubular spokes 90-94 connect the heat exchanger parallel tubes with inlet 86 while similar tubular spokes 103 connect the other end of the parallel tubes with a feed tube 95. The end of the tube 95 supports a baffle or cup 96 having an end wall against the feed mixture impinges which reverses the flow and then exits into the burner chamber 84. The flow impacts against end wall 98 which causes another directional flow reversal. Ignition is achieved by spark plug 100 and the exhaust flow exits through opening 85 into the first chamber 83 partially occupied by the heat exchanger 87. Discharge of the gases is via exhaust exit 102 connected to the first chamber after the gases flow past the heat exchanger. The heat exchanger forms an outer and an inner annulus. The outer contains the cooled feed mixture and is located adjacent to the outer wall of insulation. Then, the overall heat loss from one burner proportions to the difference between the feed mixture and environment temperature, instead of the much larger difference between the burner output gases and the environment. Also, as noted above, because the conductivity of normal high temperature insulations increases with temperature, the heat loss to the environment is less than it would be if higher temperature burner gases were adjacent to the external insulation.
For thermal passage through cylindrical insulation surrounding the burner with conductivity as given in the above table with ID of 7 inches, OD of 10 inches and height of 7 inches and burner gases averaging 2100 degrees F, feed gases 900 degrees F, and ambient at 78 degrees F, the heat flux is 790 Btu/hr for a normal heat exchanger and only a heat flux of 136 with the inventive burner, which is a reduction to 30%. Referring now to FIGURE 9, another burner version is illustrated in the general direction of arrow 110 which, as previously described, includes an insulated outer wall 111 coaxially disposed with respect to an inner section 112 having an opening 113 in fluid communication with a closed inner chamber 114. An outer chamber 115 is separated therefrom by a "can" like metal separator 116. The outer chamber is in communication with an inlet 117 for conducting air/fuel mixture to a fully insulated injector-mixer 118 which includes a baffle plate or cup 120 for effecting feed mixture flow reversal as previously described. A wall 121 of the inner section 112 causes another flow reversal. Spark plug 122 ignites the gases in a burner chamber 123 for exiting through inner chamber 114 to an exhaust outlet 124.
Feed gases enter the burner 110 through inlet 117 and move radially through space or outer chamber 115. The gases move against the insulated wall with 111 within the annulus and the pass radially inward along the chamber 115 to the injector-mixer 118. The hot gases formed in the burner chamber 123 impinge on the inner surface of the separator 116 and then pass radially outward to an annulus bounded by the separator and the insulated inner section 112. Finally the gases exit at outlet 124.
The separator is the exchanger surface between burner gas and feed gases. Its area is sufficiently large so that there is no requirement for any "extended" surfaces. Flows are parallel, instead of counter flow, to limit heat exchange and prevent uncontrolled temperature caused by any conventional "boot strap" process. This is not a requirement and counter flow may also be used.
The inventive burner concept may be employed with diesel fuel in diesel-type engines.
A major problem with such engines are particulates (smoke) ejected from the tail pipe, which include toxic material and provide a visual and auditory nuisance. Such particulates could be eliminated by using the first section of the inventive burner to gasify all the diesel fuel prior to injection into the engine, along with the further air necessary to get the final air fuel ratio. By doing so, the diesel fuel cannot produce particulates. The process would also result in the ability of the engine burner to operate at low air/fuel ratios where N0X does not form. The several impingements of the air/fuel mixture result in an intimate mixture that readily ignites and burns to completion in a certain volume. This volume may be decreased by about 25% by placing a preferably ceramic ring 125 within the burner below the location where the fuel stream leaves the mixer, as shown in FIGURE 9. Apparently the ring causes the burning gases to move from the sides of the burner and into its center, after which a portion spontaneously moves back to the wall, and so results in more complete utilization of the burner volume.
While particular embodiments of the present invention have been shown and described, it will be obvious to those skilled in the art that changes and modifications may be made without departing from this invention in its broader aspects and, therefore, the aim in the appended claims is to cover all such changes and modifications as fall within the true spirit and scope of this invention.

Claims

WHAT IS CLAIMED IS:
1. In an internal combustion apparatus, the improvement which comprises:
a burner means having a pair of combustion chambers for combusting air and hydrocarbons at fuel-rich stoichiometric air/fuel ratios from 0.3 to 1.0 to provide air/fuel vapors;
each combustion chamber includes a mixer means intimately combining said air/fuel vapors for injection into said internal combustion apparatus;
said burner means having an inlet means communicating with each combustion chamber of said pair for receiving a supply of fuel and air;
a pre-heater means connected with each of said inlet means for heating the supply of fuel and air;
said mixer means in each of said burner means combustion chambers includes a baffle wall disposed in each of said combustion chambers for receiving said pre-heated and combined air/fuel supply from said inlet means in forced impingement relationship to create a mixed vapor; and
said baffle wall receiving and re¬ directing said pre-heated and combined air/fuel mixture within said combustion chamber to further blend said air/fuel mixture.
2. The invention as defined in Claim l wherein:
each of said mixture means includes a tubular coil for receiving and mixing said air/fuel supply; and
said pre-heater means constitutes a heat exchanger employing combusted gases in said combustion chambers to be conducted adjacent said tubular coil in each combustion chamber to raise the temperature of said air/fuel mixtures preparatory to entering the internal combustion apparatus.
3. The invention as defined in Claim 2 wherein:
each coil terminates in an exit tube opening immediately adjacent to said baffle wall.
4. The invention as defined in Claim 3 wherein:
each coil is of sufficient length so that the internal air/fuel mixture is heated within the range Of 500° to 1000°F.
5. The invention as defined in Claim 4 wherein:
said pair of combustion chambers are disposed with respect to each other lying along a common longitudinal axis in end-to-end relationship.
6. The invention as defined in Claim 1 including:
each of said combustion chambers enclosed by an insulated layer separating said combustion chambers from ambient atmosphere.
7. The invention as defined in Claim 6 wherein: said combustion chambers are arranged in end-to-end relationship and separated by a firewall.
8. The invention as defined in Claim 1 wherein:
said pair of combustion chambers are arranged with a first chamber of said pair enclosed by a second chamber of said pair in coaxial spaced-apart relationship;
said pre-heater associated with said second chamber disposed between said second chamber and said first chamber with said pre-heater associated with said first chamber disposed within said first chamber.
9. The invention as defined in Claim 8 wherein:
each of said combustion chambers are fixed by a thickened insulative wall.
10. The invention as defined in Claim 9 wherein:
said first chamber is open-ended to be in fluid communication with said second chamber.
11. In an internal combustion apparatus, the improvement which comprises:
a burner means for combusting air and hydrocarbons to provide air/fuel vapors at fuel-rich ratios of 0.3 to 1.0 times the stoichiometric ratio;
said burner means includes a pair of chambers having a mixer means in a first chamber of said pair intimately combining said air/fuel vapors for injection into said internal combustion apparatus;
said burner means includes an inlet means in a second chamber of said pair for receiving a supply of fuel and air; and
a pre-heater means in said second chamber for heating the supply of fuel and air and which constitutes a heat exchanger employing combusted gases in said first chamber to be conducted adjacent said tubular coil in said second chamber to raise the temperature of said air/fuel mixture preparatory to entering said first chamber.
12. The invention as defined in Claim 11 wherein:
said pair of chambers are each enclosed by an insulative layer to retain heat within said chambers.
13. The invention as defined in Claim 12 wherein:
said chambers are coaxially disposed with respect to each other;
said first chamber constituting an inner chamber enclosed by said second chamber constituting an outer chamber in spaced relationship; and
said first chamber being open-ended in fluid communication with said second chamber.
14. The invention as defined in Claim 13 including:
a separator plate disposed in said spatial area between said first chamber and said second chamber defining an intake channel leading to said mixing means of said first chamber and an outlet channel leading from said first chamber to said internal combustion apparatus.
15. The invention as defined in Claim 11 including:
an ignition means operably disposed in said first chamber for igniting said air/fuel vapors.
16. An internal combustion apparatus, the improvement which comprises:
a burner means for combusting air and hydrocarbons to provide air/fuel vapors;
said burner means having a first chamber surrounded by a second chamber in fixed spaced-apart relationship;
each of said chambers defined by an insulative wall;
pre-heater means carried on said burner means surrounding said second chamber; and ignition means disposed in said second chamber for igniting said air/fuel vapors.
17. The invention as defined in Claim 16 including:
a mixer means in said second chamber intimately combining said air/fuel vapors in said second chamber.
18. The invention as defined in Claim 17 including:
a heat exchanger coil disposed between said first and said second chambers.
19. The invention as defined in Claim 18 wherein:
said heat exchanger is a spiral coil.
20. The invention as defined in Claim 18 wherein:
said heat exchanger is a helix.
21. The invention as defined in Claim 18 including:
a separator plate disposed in said first chamber defining a pair of flow ducts with a selected one of said ducts in fluid communication with said second chamber and said other duct in fluid communication with the internal combustion apparatus.
22. The invention as defined in Claim 21 wherein:
said first chamber is coupled to an air/fuel intake and said mixer means with said selected duct in fluid communication with said internal combustion apparatus.
23. The invention as defined in Claim 22 including:
a ceramic ring disposed in said second chamber coaxially disposed with respect to said mixing means, to cause the flow of hot gases toward the center of the chamber.
24. An internal combustion apparatus, the improvement which comprises:
a burner means for combusting air and hydrocarbons to provide air/fuel vapors at fuel-rich ratios 0.3 to 1.0 times the stoichiometric ratio;
said burner means includes a pair of fully insulated chambers having a mixer means in a first chamber of said pair intimately combining said air/fuel vapors for injection into said internal combustion apparatus;
said burner means includes an inlet means in a second chamber of said pair for receiving a supply of fuel and air;
a pre-heater means in said second chamber for heating the supply of fuel and air;
said mixer means includes a baffle wall disposed in said first chamber for receiving said pre¬ heated and combined air/fuel supply in forced impingement relationship to create a mixed vapor;
said baffle wall receiving and re¬ directing said pre-heated and combine air/fuel mixture within said first chamber to further blend air/fuel mixture;
said mixer means includes a tubular coil for receiving and mixing said air/fuel supply; and
said pre-heater means constitutes a heat exchanger employing combusted gases in said first chamber to be conducted adjacent said tubular coil in said second chamber to raise the temperature of said air/fuel mixture preparatory to entering said first chamber.
PCT/US1995/006949 1993-11-08 1995-06-02 Internal combustion gas generator WO1996038516A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
US08/148,472 US5441546A (en) 1993-11-08 1993-11-08 Apparatus and method for decreasing nitrogen oxide emissions from internal combustion power sources
US08/309,041 US5437123A (en) 1993-11-08 1994-09-20 Underoxidized burner utilizing improved injectors
US08/440,698 US5529484A (en) 1993-11-08 1995-05-15 Apparatus and method for decreasing nitrogen oxide emissions from internal combustion power sources
JP51556496A JP3145123B2 (en) 1993-11-08 1995-06-02 Internal combustion gas generator
CA002221594A CA2221594A1 (en) 1993-11-08 1995-06-02 Internal combustion gas generator
EP95922930A EP0828804A4 (en) 1993-11-08 1995-06-02 Internal combustion gas generator
KR1019970708658A KR100255335B1 (en) 1995-06-02 1995-06-02 Internal combustion gas generator
PCT/US1995/006949 WO1996038516A1 (en) 1993-11-08 1995-06-02 Internal combustion gas generator

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US08/148,472 US5441546A (en) 1993-11-08 1993-11-08 Apparatus and method for decreasing nitrogen oxide emissions from internal combustion power sources
US08/309,041 US5437123A (en) 1993-11-08 1994-09-20 Underoxidized burner utilizing improved injectors
US08/440,698 US5529484A (en) 1993-11-08 1995-05-15 Apparatus and method for decreasing nitrogen oxide emissions from internal combustion power sources
CA002221594A CA2221594A1 (en) 1993-11-08 1995-06-02 Internal combustion gas generator
PCT/US1995/006949 WO1996038516A1 (en) 1993-11-08 1995-06-02 Internal combustion gas generator

Publications (1)

Publication Number Publication Date
WO1996038516A1 true WO1996038516A1 (en) 1996-12-05

Family

ID=27508641

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1995/006949 WO1996038516A1 (en) 1993-11-08 1995-06-02 Internal combustion gas generator

Country Status (5)

Country Link
US (3) US5441546A (en)
EP (1) EP0828804A4 (en)
JP (1) JP3145123B2 (en)
CA (1) CA2221594A1 (en)
WO (1) WO1996038516A1 (en)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4417539A1 (en) * 1994-05-19 1995-11-23 Abb Research Ltd Process for air-blown gasification of fuels containing carbon
US5728183A (en) * 1995-06-06 1998-03-17 Hydrogen Burner Tech., Inc. Shift reactor for use with an underoxidized burner
DE19633674C2 (en) * 1996-08-21 1998-07-16 Hamburger Gaswerke Gmbh In-line gas preheating
US6126908A (en) 1996-08-26 2000-10-03 Arthur D. Little, Inc. Method and apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide
US6245303B1 (en) 1998-01-14 2001-06-12 Arthur D. Little, Inc. Reactor for producing hydrogen from hydrocarbon fuels
US5944510A (en) 1996-11-01 1999-08-31 Greiner; Leonard Dynamic fluid injector
US6033793A (en) * 1996-11-01 2000-03-07 Hydrogen Burner Technology, Inc. Integrated power module
US5975887A (en) * 1997-01-24 1999-11-02 Gordon-Piatt Energy Group, Inc. Compact hi-spin gas burner assembly
US5938800A (en) * 1997-11-13 1999-08-17 Mcdermott Technology, Inc. Compact multi-fuel steam reformer
US6089859A (en) * 1998-06-19 2000-07-18 Hydrogen Burner Technology, Inc. Reduced carbon from under oxidized burner
TW493058B (en) * 1998-07-02 2002-07-01 Showa Denko Kk The remains of non condensing gas in heat pipe, the detecting method of non-remains, and the manufacturing method of pipes
US6641625B1 (en) 1999-05-03 2003-11-04 Nuvera Fuel Cells, Inc. Integrated hydrocarbon reforming system and controls
US6887436B1 (en) * 2000-06-27 2005-05-03 Delphi Technologies, Inc. Fast light-off catalytic reformer
US20030066239A1 (en) * 2001-10-05 2003-04-10 Iraj Parchamazad Portable cogeneration fuel-cell power generator with high-yield, low pressure reformer for recreational vehicles
FR2850372B1 (en) * 2003-01-23 2006-06-09 Inst Francais Du Petrole NEW PARTIAL OXIDATION REACTOR
JP4618705B2 (en) 2003-09-18 2011-01-26 大日本スクリーン製造株式会社 Heat treatment equipment
US7086853B2 (en) * 2003-12-12 2006-08-08 Nissan Motor Co., Ltd. Startup combustor for a fuel cell
FR2872887B1 (en) * 2004-07-07 2006-09-08 Inst Francais Du Petrole HOMOGENEOUS COMBUSTION METHOD AND THERMAL GENERATOR USING SUCH A METHOD
US7316563B2 (en) * 2004-07-30 2008-01-08 Marshall Daniel S Combustor with integrated counter-flow heat exchanger
US7740031B2 (en) * 2005-04-26 2010-06-22 Eden Innovations Ltd. System for blending and compressing gases
US7547385B2 (en) * 2005-11-14 2009-06-16 Eden Innovations Ltd. Method and system for producing a supercritical cryogenic fuel (SCCF)
US7497191B2 (en) 2006-02-06 2009-03-03 Eden Innovations Ltd. System and method for producing, dispensing, using and monitoring a hydrogen enriched fuel
US20070277438A1 (en) * 2006-05-30 2007-12-06 Brehon Energy Plc System and method for producing a hydrogen enriched fuel
US20080034659A1 (en) * 2006-08-09 2008-02-14 Ming-Fu Liu Portable flammable gas generating device
CN1971134B (en) * 2006-12-05 2013-05-01 白玉林 Liquid fuel and oxyhydrogen gas mixed-combustion single-injection device
US8747496B2 (en) * 2007-05-01 2014-06-10 Westport Power Inc. Compact fuel processor
US8105076B2 (en) * 2007-08-06 2012-01-31 Thomas & Betts International, Inc. High efficiency radiant heater
TW200946838A (en) * 2008-03-04 2009-11-16 Ihi Corp Heating apparatus
US7959431B2 (en) * 2008-04-21 2011-06-14 Fives North American Combustion, Inc. Radiant tube with recirculation
WO2010004009A2 (en) * 2008-07-11 2010-01-14 Rheinkalk Gmbh Burner unit and burner arrangement for powdered solid fuel
US8370126B2 (en) * 2009-01-30 2013-02-05 Facebook, Inc. Incorporation of variables into textual content
KR101152586B1 (en) * 2010-03-04 2012-06-01 삼성에스디아이 주식회사 fuel reformer
US8888872B2 (en) * 2010-07-06 2014-11-18 General Electric Company Gasifier cooling system
US9027332B2 (en) 2013-02-27 2015-05-12 Tenneco Automotive Operating Company Inc. Ion sensor with decoking heater
US9027331B2 (en) 2013-02-27 2015-05-12 Tenneco Automotive Operating Company Inc. Exhaust aftertreatment burner with preheated combustion air
US8959902B2 (en) 2013-02-27 2015-02-24 Tenneco Automotive Operating Company Inc. Exhaust treatment burner and mixer system
US8991163B2 (en) * 2013-02-27 2015-03-31 Tenneco Automotive Operating Company Inc. Burner with air-assisted fuel nozzle and vaporizing ignition system
US9595726B2 (en) 2014-01-07 2017-03-14 Advanced Cooling Technologies, Inc. Fuel reforming system and process
WO2016016919A1 (en) * 2014-07-28 2016-02-04 大阪瓦斯株式会社 Heating furnace
US9534525B2 (en) 2015-05-27 2017-01-03 Tenneco Automotive Operating Company Inc. Mixer assembly for exhaust aftertreatment system
JP6242453B1 (en) * 2016-08-25 2017-12-06 中外炉工業株式会社 Heating furnace cooling system
US10557391B1 (en) 2017-05-18 2020-02-11 Advanced Cooling Technologies, Inc. Incineration system and process
EP3492718B1 (en) 2017-11-30 2020-06-10 Katcon Global S.A. Exhaust line for a vehicle
KR20240010530A (en) * 2018-11-16 2024-01-23 버킨 에너지 엘엘씨 Thermal lensing electrode in thermoelectric generators for improved performance

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3516807A (en) * 1966-04-06 1970-06-23 Texas Instruments Inc Apparatus for producing hydrogen gas by the partial oxidation of a carbonaceous fuel containing hydrogen
US3685977A (en) * 1969-04-16 1972-08-22 Texas Instruments Inc Partial oxidation of hydrocarbons
US5002481A (en) * 1986-08-08 1991-03-26 Forschungszentrum Julich Gmbh Apparatus for generating a combustible gaseous mixture
US5207185A (en) 1992-03-27 1993-05-04 Leonard Greiner Emissions reduction system for internal combustion engines
US5299536A (en) 1992-03-27 1994-04-05 David Moard Apparatus and method for decreasing nitrogen oxide emissions from internal combustion power sources

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1543776A (en) * 1925-06-30 Setts
US2097153A (en) * 1933-08-19 1937-10-26 John E Greenawalt Down draft furnace
US2220603A (en) * 1938-05-31 1940-11-05 Syncromatic Air Conditioning C Hydrocarbon burner
US4701123A (en) * 1986-12-24 1987-10-20 The Scott & Fetzer Company Gas fuel burner

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3516807A (en) * 1966-04-06 1970-06-23 Texas Instruments Inc Apparatus for producing hydrogen gas by the partial oxidation of a carbonaceous fuel containing hydrogen
US3685977A (en) * 1969-04-16 1972-08-22 Texas Instruments Inc Partial oxidation of hydrocarbons
US5002481A (en) * 1986-08-08 1991-03-26 Forschungszentrum Julich Gmbh Apparatus for generating a combustible gaseous mixture
US5207185A (en) 1992-03-27 1993-05-04 Leonard Greiner Emissions reduction system for internal combustion engines
US5299536A (en) 1992-03-27 1994-04-05 David Moard Apparatus and method for decreasing nitrogen oxide emissions from internal combustion power sources

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0828804A4 *

Also Published As

Publication number Publication date
US5529484A (en) 1996-06-25
US5437123A (en) 1995-08-01
EP0828804A4 (en) 1999-05-19
US5441546A (en) 1995-08-15
EP0828804A1 (en) 1998-03-18
CA2221594A1 (en) 1996-12-05
JP3145123B2 (en) 2001-03-12
JPH10511448A (en) 1998-11-04

Similar Documents

Publication Publication Date Title
US5529484A (en) Apparatus and method for decreasing nitrogen oxide emissions from internal combustion power sources
US5207185A (en) Emissions reduction system for internal combustion engines
US5546701A (en) Underoxidized burner utilizing improved injectors
US5542840A (en) Burner for combusting gas and/or liquid fuel with low NOx production
US6616442B2 (en) Low NOx premix burner apparatus and methods
US7469544B2 (en) Method and apparatus for injecting a fuel into a combustor assembly
US4040252A (en) Catalytic premixing combustor
US5458481A (en) Burner for combusting gas with low NOx production
US5299536A (en) Apparatus and method for decreasing nitrogen oxide emissions from internal combustion power sources
US5158445A (en) Ultra-low pollutant emission combustion method and apparatus
EP0677707B1 (en) Catalytic gas turbine combustor
CA2574091A1 (en) Stagnation point reverse flow combustor for a combustion system
US20050188702A1 (en) Non-catalytic combustor for reducing nox emissions
CA2200479A1 (en) Ultra low nox burner
US4088741A (en) Carbon black process
CA2046083C (en) Apparatus and method for reducing nitrogen oxide emissions from gas turbines
US7117674B2 (en) Catalytic combustor and method for substantially eliminating various emissions
JPH0210348B2 (en)
WO1996036836A1 (en) Combustor for generating gases
KR100255335B1 (en) Internal combustion gas generator
KR100294307B1 (en) Low oxidation burner with improved injector
CN1185171A (en) Internal combustion gas generator
MXPA97009200A (en) Inte combustion gas generator
CN108105801A (en) A kind of soft combustion method of new catalysis
Bulysova et al. Parametric Computational Studies of NO x Emission Reduction in Staged Combustion of Ideal Fuel-Air Mixtures1

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 95197879.9

Country of ref document: CN

AK Designated states

Kind code of ref document: A1

Designated state(s): CA CN JP KR MX

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
LE32 Later election for international application filed prior to expiration of 19th month from priority date or according to rule 32.2 (b)

Free format text: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application
NENP Non-entry into the national phase

Ref country code: CA

ENP Entry into the national phase

Ref document number: 2221594

Country of ref document: CA

Ref document number: 2221594

Country of ref document: CA

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: PA/a/1997/009200

Country of ref document: MX

WWE Wipo information: entry into national phase

Ref document number: 1995922930

Country of ref document: EP

Ref document number: 1019970708658

Country of ref document: KR

WWP Wipo information: published in national office

Ref document number: 1995922930

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1019970708658

Country of ref document: KR

WWG Wipo information: grant in national office

Ref document number: 1019970708658

Country of ref document: KR

WWR Wipo information: refused in national office

Ref document number: 1995922930

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 1995922930

Country of ref document: EP