WO1996025902A1 - Method for producing a continuous thermoplastic coating and articles constructed therefrom - Google Patents
Method for producing a continuous thermoplastic coating and articles constructed therefrom Download PDFInfo
- Publication number
- WO1996025902A1 WO1996025902A1 PCT/EP1996/000377 EP9600377W WO9625902A1 WO 1996025902 A1 WO1996025902 A1 WO 1996025902A1 EP 9600377 W EP9600377 W EP 9600377W WO 9625902 A1 WO9625902 A1 WO 9625902A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- coating
- substrate
- thermoplastic composition
- barrier layer
- less
- Prior art date
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 118
- 239000011248 coating agent Substances 0.000 title claims abstract description 101
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 43
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 39
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 50
- 239000000203 mixture Substances 0.000 claims abstract description 44
- 230000004888 barrier function Effects 0.000 claims abstract description 42
- 239000004753 textile Substances 0.000 claims abstract description 29
- 210000001124 body fluid Anatomy 0.000 claims abstract description 15
- 239000010839 body fluid Substances 0.000 claims abstract description 15
- 239000000758 substrate Substances 0.000 claims description 77
- 238000000034 method Methods 0.000 claims description 27
- 239000012943 hotmelt Substances 0.000 claims description 24
- 239000004831 Hot glue Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 230000002745 absorbent Effects 0.000 claims description 8
- 239000002250 absorbent Substances 0.000 claims description 8
- 230000009969 flowable effect Effects 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 32
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- -1 polyethylene Polymers 0.000 description 7
- 229920000098 polyolefin Polymers 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 239000003921 oil Substances 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000004014 plasticizer Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000012815 thermoplastic material Substances 0.000 description 4
- 239000013032 Hydrocarbon resin Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 229920006270 hydrocarbon resin Polymers 0.000 description 3
- 239000004745 nonwoven fabric Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 238000007757 hot melt coating Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920000247 superabsorbent polymer Polymers 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 239000005061 synthetic rubber Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920002633 Kraton (polymer) Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229920013623 Solprene Polymers 0.000 description 1
- 206010042618 Surgical procedure repeated Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012956 testing procedure Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/00987—Apparatus or processes for manufacturing non-adhesive dressings or bandages
- A61F13/00991—Apparatus or processes for manufacturing non-adhesive dressings or bandages for treating webs, e.g. for moisturising, coating, impregnating or applying powder
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15577—Apparatus or processes for manufacturing
- A61F13/15699—Forming webs by bringing together several webs, e.g. by laminating or folding several webs, with or without additional treatment of the webs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/514—Backsheet, i.e. the impermeable cover or layer furthest from the skin
- A61F13/51401—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material
- A61F2013/51441—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material being a fibrous material
- A61F2013/5145—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material being a fibrous material being treated materials
Definitions
- This invention relates to a non-contact coating method for producing a continuous coating and articles constructed
- This invention further relates to a method for producing a textile material with a moisture-impermeable barrier layer and to a method for producing a moisture-absorbing article of hygiene which has such a barrier layer.
- This invention particularly relates to a textile material and hygienic
- disposable articles comprising a body fluid impermeable barrier layer which can be produced from said coating method.
- thermoplastic composition used in the coating method for producing the barrier layer exhibits certain properties
- materials are required which are impermeable to liquids such as water and body fluids, but at the same time have a textile character which is as close as possible to materials without the impermeability characteristics.
- hygienic articles such as
- Such hygienic articles often have a substantial absorption capacity.
- Such hygienic articles customarily have a continuous layer of a body fluid impermeable film on their garment facing side. Since touching this film material is an unwelcome sensation for a number of users, it has been suggested to cover the outward side of the film with a thin layer of textile material so that the article has a textile feel also on its exterior surface.
- EP-A-O 187 728 teaches a disposable diaper with a barrier layer in the form of a plastics material film, typically consisting of a polyolefin, a polyacrylate, of PVC, nylon or other
- thermoplastic material The barrier film is laminated, adhered or welded onto a thin nonwoven layer, which makes it necessary to prepare the film laminate off-line.
- the plastics material of the film is to be extrusion coated onto the nonwoven.
- the laminate, thus formed, is then used as the outermost material layer in such a way that the film layer is on the inside, so that the outer nonwoven layer provides the desired exterior texture.
- This production method is rather expensive.
- Highly polymeric plastic materials such as polyethylene, polypropylene, polyacrylate and so on, have low melt flow indices and can (if at all) only be processed into impermeable films on very sophisticated machinery. This would also be true for the suggested direct extrusion coating which does not appear to have been reduced to practice yet. Separately producing the film, with subsequent laminating onto the nonwoven, is even more inefficacious in view of the additional production step required.
- US patents 4,692,161 and 4,627,847 teach a leakage waist barrier for the edge of an absorbent hygienic article provided by coating a hotmelt adhesive onto the edge area of a nonwoven sheet material.
- this hotmelt adhesive can also serve a constructive function, in combination with its function as a barrier, in that it can adhere the nonwoven to other materials of the hygienic article.
- the hotmelt is to be coated in a conventional manner by slot nozzle coating, transfer coating, spray coating or other such methods.
- the hotmelt coating must have a minimum thickness of 25 ⁇ m, preferably at least 75 ⁇ m, so that a continuous closed barrier layer is achieved.
- the applicants have found a coating method that overcomes the aforementioned problems.
- the coating method employs a noncontact application wherein a thermoplastic composition is thermally made flowable and released from a coating device onto a substrate.
- the thermoplastic composition is thus coated onto the substrate without contact between said coating device and said substrate.
- a liquid-impermeable, especially a body fluid impermeable, barrier wherein the textile character is not substantially impaired is produced. Since the method employs low coating weights of the thermoplastic composition, it eliminates the economic disadvantages of current methods as well as improves the tactile quality of the resulting article. Additionally, the method is suitable for coating a variety of heat sensitive materials.
- the substrate is a "textile material" which in the context of this invention means not only a woven material made of yarn, but also any material made from fibers such as nonwoven, as well as nonwoven composites and the like, which materials play a major role in the area of hygienic article production. Since the coating device and substrate do not contact each other, the mechanical stresses on the substrate are much less than prior art methods.
- thermoplastic composition is preferably coated at temperatures of less than 125°C, even more preferably less than 110°C, to reduce the heat-induced stresses on the substrates being coated. This is advantageous for coating and mutually bonding thermally sensitive substrates.
- the thermoplastic composition preferably exhibits certain rheolcgical characteristics such that the complex viscosity at high shear rates (1,000 rad/sec) is less than about 500 poise and the complex viscosity at low shear rates (1 rad/sec) is between about 100 and about 1,000 poise.
- Some neat thermoplastic resins such as typical film grade polyolefines, may be suitable for the method of the present invention.
- compounded hotmelt adhesives are preferred due to the ability to independently control the visco-elastic properties, open time, etc. Compounded hotmelt are also advantageous to insure adequate adhesion to the carrier substrate or for delayed detackification of the C'ating after adherence to the substrate.
- the resulting coating produced from said method is useful, for a variety of applications wherein a consistent continuous coating is desired. Coating weights of less than 30 g/m 2 of the
- thermoplastic composition are preferred to reduce expenditure and improve the tactile quality of disposable hygienic articles.
- coating weights higher than 30 g/m 2 may be useful for other applications wherein reducing the mechanical and heat-induced stresses is of primary importance.
- the resulting coating is preferable for producing a body fluid impermeable barrier layer in a disposable hygienic article having improved exterior tactile quality.
- the coating method is
- the disposable article as described herein has at least one first layer wherein said first layer is a permeable substrate and at least one second layer wherein said second layer is a barrier coating produced from the coating method described above.
- Figure 1 depicts the method of the present invention wherein a continuous thermoplastic coating is formed and adhered to a carrier substrate.
- Substrate 1 (1) travels past a series of idle rollers (2) to ensure the web is in proper alignment prior to approaching the coating device (3).
- the coating device is initially in contact with the substrate to adhere the leading edge of the coating to the substrate.
- the coating device is removed from Substrate 1 at a distance most often ranging from about 0.5 mm to about 20 mm, depending on the properties of the thermoplastic composition being coating.
- Substrate 2 (4) is optionally adhered to the coating surface by means of a nip roll (5).
- Substrate 2 may be any substrate present in a hygienic article such as an absorbent, elastomeric strands or webs, tissue, films, coverstock materials such as nonwoven or perforated polyethylene, as well as any material that is not necessarily in the form of a web such as superabsorbent polymer.
- a hygienic article such as an absorbent, elastomeric strands or webs, tissue, films, coverstock materials such as nonwoven or perforated polyethylene, as well as any material that is not necessarily in the form of a web such as superabsorbent polymer.
- adhesive preferably substantially air-free
- a coating or release device in such a way that it exits the device as a continuous film.
- a typical example for this is a slot nozzle, as it has previously been used for coating in direct contact with a substrate.
- melt coating devices which are already at hand can be reset for use according to the invention in that the slot nozzle is lifted off the substrate and is adjusted to have a suitable distance from the substrate.
- the viscous but flowable molten adhesive leaves the coating device, it does not contact the substrate immediately, but rather travels for a distance as a continuous coating film suspended above the substrate without touching either the device or the substrate.
- the distance between the coating device and the substrate ranges from about 0.5 mm to about 20 mm. It is possible that at suitable machine speed settings, and with specific adhesives or other coating materials, the distance can be even greater than 20 mm. The distance is largely dictated by the viscosity and open time of the thermoplastic composition being coated.
- thermoplastic composition cools sufficiently in its suspended state such that it has built in viscosity and cohesive strength to the extent that any filaments or fibers present on the substrate surface cannot penetrate the coating, yet the thermoplastic composition is molten or soft enough to adequately adhere to the substrate.
- a roller can be provided in the path of movement of the substrate to give the substrate a substantially vertical, upward direction, as the substrate passes the coating device.
- the coating device such as a slot nozzle, can be provided substantially horizontally beside the roller so that the coating travels from the side towards the surface of the
- the diameter of the coating role is preferably about 15 mm to about 50 mm in diameter with the nozzle slightly above the center of the coating roll such that the angle at which the
- thermoplastic coating contacts the substrate is less than about 60° as the substrate is moving away form the nozzle.
- the coating head is adjusted by one of ordinary skill in the art to optimize for even flow and distribution of the thermoplastic coating over the entire width of the application.
- the substrate is preferably a textile material such as a nonwoven
- the thus produced material comprises the textile substrate layer and a coating, preferably a hotmelt barrier layer.
- the thermoplastic coating is of such a composition that it substantially detackifies after sufficient cooling, the laminate of the coated substrate, thus formed, can be rolled up and stored. The laminate can then be used at some later time e.g. as a body fluid impermeable backsheet having improved tactile quality in a disposable hygienic article.
- the laminate can be bonded by any suitable bonding technique
- the coating of the barrier layer is done "inline" immediately before any further processing of the thus produced coated textile laminate.
- the surface of the barrier layer which is pointing away from the substrate and is still sufficiently tacky can be used for a constructive adhesion step and therefore car. also serve to bond the coated textile material to other elements of a hygienic article.
- Other elements that could be simultaneously bonded in this manner during the formation of the barrier layer include absorbent, superabsorbent polymer, elastomeric strands or webs, tissue, films, as well as various permeable coverstock materials such as nonwoven or perforated films.
- hotmelt coating can be provided at extremely low temperatures, materials can also be provided with barrier layers which are too sensitive mechanically and/or thermally for customary coating methods.
- Such sensitive materials include low gauge polyethylene
- a substantial advantage of the invention is that continuous, sufficiently impermeable barrier layers can be made from hotmelts at very low coating weights. Even with customary commercially available hotmelts, closed barrier layers can be produced at coating weight of not more than 30 g/m 2 , and generally, it is easily possible to achieve coating weights between 10 g/m 2 and 20 g/m 2 and most preferably less than 10 g/m 2 .
- the prior art coating of hotmelts according to customary methods for forming edge leakage barriers as in US patent 4,692,161, requires area weights of about 70 g/ ⁇ r to create the preferred film thickness of around 75 ⁇ m. At thickness of 25 ⁇ m, the suggested minimum according to this art, the contact-coated layer is perforated by substrate fibre, and is not closed.
- the very thin barrier layers which can be produced according to the invention do not only contribute to the economical advantages of the inventive method, but also make it possible to achieve a very much reduced stiffness of the material, which thus comes much closer, in its properties, to a textile material which is not provided with a barrier layer at all.
- Thermoplastic Composition is the Thermoplastic Composition
- thermoplastic materials such as polyolefins, especially polyethylene, polypropylene, amorphous polyolefins such as Vestoplast 703® (H ⁇ ls) and the like, may be suitable thermoplastic materials for the coating method of the present invention.
- hotmelt adhesives are preferred due to the ability to independently tailor the visco-elastic properties, open time, tack, and various other
- Hotmelt adhesives commonly have melt flew indices required for such processing already at very low temperatures. Typical hotmelts are fluid enough for such processing at
- temperatures ranging from about 60°C to 110°C.
- the thermoplastic composition exhibits certain rheological characteristics such that a continuous, especially a body fluid impermeable coating can be produced at coating weights of less than about 30 g/m 2 .
- the rheological characteristics such that a continuous, especially a body fluid impermeable coating can be produced at coating weights of less than about 30 g/m 2 .
- the rheological characteristics such that a continuous, especially a body fluid impermeable coating can be produced at coating weights of less than about 30 g/m 2 .
- the rheological characteristics such that a continuous, especially a body fluid impermeable coating can be produced at coating weights of less than about 30 g/m 2 .
- thermoplastic compositions preferably fall within a rheological window wherein the complex viscosity at high shear rates (1,000 rad/sec) is less than about 500 poise and the complex viscosity at low shear rates ( ⁇ 1 rad/sec) is between about 100 and about 1,000 poise.
- preferable thermoplastic compositions exhibit
- Thermoplastic compositions having wide windows of application are those in which the composition exhibits the appropriate rheological properties at a variety of application settings, particularly low temperatures.
- Narrow application windows are those in which the rheological parameters are only met under very specific conditions.
- Amorphous polyolefins based hotmelt adhesives such as Lunatack® D-8370 (H.B. Fuller Company) tend to exhibit relatively flat viscosity curves at low shear rates (less than bout 10 rad/sec) and consequently relatively wide application windows.
- Block copolymer based hotmelt adhesives tend to exhibit particularly steep viscosity profiles causing very narrow application windows.
- the high shear information relates to the processing conditions at the slot die exit.
- a composition with too high of a complex viscosity at 1,000 radians/sec would require excessive pump pressure to exit the coating device.
- a die with a shim gap larger than 3 mm could be used to process these materials but a higher coating weight may result.
- the low shear information relates to the settling of the coating on the substrate during the time it is suspended above the substrate. If the low shear value is too high, the coating may not adhere adequately to the substrate and/or the thermoplastic composition builds up at the nozzle causing a streaked,
- the coating may seep into the substrate, causing poor barrier properties.
- Extensional viscosity which was not measured can also strongly influence the melt strength.
- Higher levels of branching or the addition of a small concentration of a high molecular weight material can strongly influence the melt strength. More
- compositions that meet the target rheological parameters at low application temperatures of less than about 125°C, most preferably less than about 110°C.
- Hotmelt adhesives typically comprise at least one thermoplastic polymer, at least one plasticizer and at least one tackifying resin.
- such suitable hotmelts comprise up to 40% by weight of thermoplastic polymer, up to 40% by weight of a plasticizer and up to 70% by weight of tackifying resin.
- polyalphaolefins such as Vestoplast® 708 (Huls) and synthetic rubbers such as S-EB-S block copolymers have been found to be especially suited, particularly those as used in hotmelt
- ether thermoplastic polymers such as ethylene-vinylacetate copolymers or other synthetic rubbers as available in commerce under the tradenames Kraton®, Solprene®, and Stereon®.
- Plasticizers and tackifying resins used in hotmelt adhesives are known. Oils such as naphthenic oils are preferred plasticizers.
- tackifying resins those resins already known for such purposes are generally suitable, especially hydrocarbon resins, ester resins and other such compatible resins. The components are mixed and processed in a known manner to prepare the hotmelts which can be used according to this invention.
- thermoplastic compositions comprising a water soluble, saline (body fluid) insoluble copoiyester such as Eastman AQ 1350®, commercially available from Eastman, are also particularly useful for creating barrier films that are impervious to body fluid, yet readily water soluble. This feature is of particular interest for creating flushable and compostable disposable hygienic products. Furthermore, there may be applications wherein water permeability is desired. Accordingly, this coating method may also be suitable for coating water permeable, water soluble and/or biodegradable thermoplastic materials.
- Embodiment example 1 is a diagrammatic representation of Embodiment example 1:
- Embodiment example 2 is a diagrammatic representation of Embodiment example 2:
- Embodiment example 3 is a diagrammatic representation of Embodiment example 3:
- polyolefine about 40% hydrocarbon resin with a cyclopentadiene component, about 15% polyisobutylene and about 10% naphthenic oil.
- the hotmelts according to embodiment examples 1 through 3 were placed in a customary processing machine provided with a slot nozzle such as Nordson EP 51.
- the slot nozzle was provided horizontally facing a roller over which a polypropylene nonwoven was led in an upward direction.
- the distance between the slot nozzle and the substrate was 2 mm, at a nozzle slot length of 70 mm.
- the web speed of the nonwoven was 25 m/min.
- the hotmelt was coated onto the substrate, where it formed a closed barrier layer. Immediately thereafter, the thus coated substrate was adhered to a customary absorptive body (tissue).
- the hotmelt barrier layer formed between the tissue and the substrate was found to be completely liquid-impermeable. Processing was without any problems.
- the coating weight was an average of 21 g/m 2 . At corresponding fine adjustment of release temperature of hotmelt, system pressure, distance between slot nozzle and substrate, machine speed etc. etc., it was systematically possible to form water-tight closed barrier layers at area weights of less than 20 g/m 2 on this substrate. Examples 4-16:
- Table 1 depicts rheological data on Examples 4 through 16.
- D-3964 exhibits too high of a complex viscosity at 1 rad/sec.
- D-3964 exhibits to low of a complex viscosity at 1 rad/sec, causing the material to soak into the substrate.
- the applicants surmise a temperature exists between 90°C and 110°C wherein D-3964 would produce a continuous coating.
- a thermoplastic composition exhibiting such a narrow rheological window would have little chance of commercial success.
- Example 14 exhibits the utility of blending a thermoplastic composition that does not meet the rheological window with another material such that the resulting composition is useful for producing a continuous coating.
- D-3964 since D-3964 exhibits too low of a complex viscosity at 1 rad/sec, it is blended with a material to raise the complex viscosity at 1 rad/sec such that the blend exhibits the
- examples exhibiting too high of a complex viscosity at 1 rad/sec, such as examples 4 through 9 can be blended with compatible materials to lower the complex viscosity such that the blended material may be coated at the preferable application temperature of less than 125°C.
- Examples 4 through 16 were tested in a similar manner as Examples 1 - 3.
- the application conditions and rheological data of the adhesive compositions are depicted in Table 1.
- a system pressure ranging from about 40 to about 65 bar was obtained during coating of examples 10 through 16.
- the rheological data was generated from a dynamic mechanical spectrometer such as a Rheometric Scientific RDS 7700 (10,00C g/cm transducer, 10 g/cm - ⁇ 10,000 g/cm torque).
- a master curve of G' (shear storage modulus), G" (shear loss modulus) and complex viscosity as a function of frequency was obtained through time temperature superposition.
- G' sinometric Scientific RDS 7700
- G" shear loss modulus
- complex viscosity as a function of frequency was obtained through time temperature superposition.
- the sample was loaded at the upper test temperature between 50 mm diameter parallel plate discs with a 1 to 2 mm gap. After allowing the sample temperature to stabilize for at least about 10 minutes, a frequency sweep was performed from about 0.1 to about 100 radians per second.
- the sample temperature was lowered to the next temperature and the procedure repeated.
- the strain amplitude was adjusted to improve the resolution and ranged from about 20% to about 40%.
- time-temperature superposition was used to overlay the data into a single master curve at the application temperature. If the actual coating temperature was not one of the actual temperatures tested, the Williams, Landel, Ferry (WLF) (Ferry, J.D. Viscoelastic Properties of Polymers, 3rd Ed., Wiley: NY, 1980) equation was used to obtain the master curve.
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- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Heart & Thoracic Surgery (AREA)
- Vascular Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Biomedical Technology (AREA)
- Manufacturing & Machinery (AREA)
- Epidemiology (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Adhesive Tapes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
Claims
Priority Applications (13)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU47854/96A AU706113B2 (en) | 1995-02-23 | 1996-01-30 | Method for producing a continuous thermoplastic coating and articles constructed therefrom |
KR1019970705875A KR100511760B1 (en) | 1995-02-23 | 1996-01-30 | Process for preparing continuous thermoplastic coatings and articles made thereby |
KR10-2003-7015761A KR100506376B1 (en) | 1995-02-23 | 1996-01-30 | A textile article and disposable hygienic article |
EP96903949A EP0814736B2 (en) | 1995-02-23 | 1996-01-30 | disposable article |
BR9607429A BR9607429A (en) | 1995-02-23 | 1996-01-30 | Process for the production of a continuous thermoplastic coating and articles made from it |
CA002213205A CA2213205C (en) | 1995-02-23 | 1996-01-30 | Method for producing a continuous thermoplastic coating and articles constructed therefrom |
JP52533496A JP4294729B2 (en) | 1995-02-23 | 1996-01-30 | Method for producing continuous thermoplastic coating and article composed thereof |
DE69634533T DE69634533T3 (en) | 1995-02-23 | 1996-01-30 | disposable |
US08/705,380 US6120887A (en) | 1995-02-23 | 1996-08-29 | Disposable articles having a continuous thermoplastic coating comprising a metallocene polyolefin |
MXPA/A/1997/006366A MXPA97006366A (en) | 1995-02-23 | 1997-08-21 | Method to produce a termoplasticcountinua cover and articles built with me |
US09/057,406 US7078075B1 (en) | 1995-02-23 | 1998-04-08 | Method for producing a continuous thermoplastic coating and articles constructed therefrom |
US09/527,403 US6583332B1 (en) | 1995-02-23 | 2000-03-16 | Article having a continuous thermoplastic coating |
US10/427,888 US7699826B2 (en) | 1995-02-23 | 2003-05-01 | Article having a continuous thermoplastic coating |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ATPCT/EP95/00665 | 1995-02-23 | ||
EPPCT/EP95/00665 | 1995-02-23 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EPPCT/EP95/00665 Continuation | 1995-02-23 | 1995-02-23 |
Related Child Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US08/705,578 Continuation-In-Part US5827252A (en) | 1995-02-23 | 1996-08-29 | Method for producing a continuous thermoplastic coating and articles constructed therefrom |
US08/705,578 Continuation US5827252A (en) | 1995-02-23 | 1996-08-29 | Method for producing a continuous thermoplastic coating and articles constructed therefrom |
US08/705,380 Continuation-In-Part US6120887A (en) | 1995-02-23 | 1996-08-29 | Disposable articles having a continuous thermoplastic coating comprising a metallocene polyolefin |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996025902A1 true WO1996025902A1 (en) | 1996-08-29 |
Family
ID=8165959
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1996/000377 WO1996025902A1 (en) | 1995-02-23 | 1996-01-30 | Method for producing a continuous thermoplastic coating and articles constructed therefrom |
Country Status (11)
Country | Link |
---|---|
US (1) | US5827252A (en) |
EP (3) | EP1459719A3 (en) |
JP (1) | JP4294729B2 (en) |
KR (2) | KR100506376B1 (en) |
CN (1) | CN1130176C (en) |
AR (1) | AR024824A1 (en) |
AU (1) | AU706113B2 (en) |
CA (1) | CA2213205C (en) |
DE (3) | DE69634533T3 (en) |
ES (3) | ES2240990T3 (en) |
WO (1) | WO1996025902A1 (en) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0935955A1 (en) | 1998-02-17 | 1999-08-18 | McNEIL-PPC, Inc. | Application of adhesive to absorbent article |
EP0964026A1 (en) * | 1998-06-09 | 1999-12-15 | The Procter & Gamble Company | Low viscosity thermoplastic compositions for structures with enhanced moisture vapour permeability and the utilisation thereof in absorbent articles |
EP0963837A1 (en) * | 1998-06-09 | 1999-12-15 | The Procter & Gamble Company | Moisture vapour permeable composite structure and the utilisation thereof in absorbent articles |
WO1999066000A1 (en) * | 1998-06-17 | 1999-12-23 | H.B. Fuller Licensing & Financing, Inc. | Hot melt pressure sensitive adhesive composition |
EP1106114A1 (en) | 1999-12-09 | 2001-06-13 | The Procter & Gamble Company | Disposable, moisture vapour permeable, liquid impermeable mattress cover having an improved structure for increased stability |
US6495612B1 (en) | 1998-06-09 | 2002-12-17 | The Procter & Gamble Company | Shape-formed, three dimensional, moisture vapor permeable, liquid impermeable articles |
EP1331092A2 (en) * | 1997-12-01 | 2003-07-30 | H.B. FULLER LICENSING & FINANCING, INC. | Method for producing a thermoplastic coating and articles constructed therefrom |
EP1433450A1 (en) * | 2002-12-23 | 2004-06-30 | The Procter & Gamble Company | Polymeric compositions for moisture vapour permeable structures with improved structural stability and structures comprising said compositions |
US7078075B1 (en) * | 1995-02-23 | 2006-07-18 | H.B. Fuller Licensing & Financing Inc. | Method for producing a continuous thermoplastic coating and articles constructed therefrom |
WO2008074508A1 (en) * | 2006-12-20 | 2008-06-26 | Inatec Gmbh | Laminating process and apparatus for applying an adhesive-composition film to a web-like substrate |
US7405009B2 (en) | 2003-01-24 | 2008-07-29 | H.B. Fuller Licensing & Financing, Inc. | Moisture vapor permeable film including ethylene copolymer and articles including the same |
EP2123444A1 (en) | 2008-05-22 | 2009-11-25 | Bostik SA | Multilayer film for flexible packaging |
US7799431B2 (en) | 2002-04-12 | 2010-09-21 | The Procter & Gamble Company | Liquid impermeable, moisture vapour permeable layers and films comprising thermoplastic hydrophilic polymeric compositions |
US8101814B2 (en) | 2004-05-12 | 2012-01-24 | The Procter & Gamble Company | Breathable absorbent articles and composites comprising a vapor permeable, liquid barrier layer |
EP2687362A1 (en) | 2012-07-19 | 2014-01-22 | Bostik Sa | Multilayer film for flexible package |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
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US6534572B1 (en) | 1998-05-07 | 2003-03-18 | H. B. Fuller Licensing & Financing, Inc. | Compositions comprising a thermoplastic component and superabsorbent polymer |
EP1216152B1 (en) * | 1999-09-27 | 2010-12-08 | E.I. Du Pont De Nemours And Company | Extrusion coating process |
US7285324B1 (en) | 1999-09-27 | 2007-10-23 | E. I. Du Pont De Nemours And Company | Laminate structure |
AU2375000A (en) * | 1999-12-21 | 2001-07-03 | H.B. Fuller Licensing And Financing Inc. | Method of packaging a thermoplastic composition with a film having a low complexviscosity and corresponding packaged article |
UA77951C2 (en) * | 2000-11-29 | 2007-02-15 | Laminate for packaging of food and method for its formation (variants) | |
US7163740B2 (en) | 2001-06-02 | 2007-01-16 | The Procter & Gamble Company | Process for printing adhesives, adhesive articles and printing equipment |
DE60115859T2 (en) * | 2001-06-02 | 2006-08-17 | The Procter & Gamble Company, Cincinnati | Process for printing adhesives, adhesives and gravure rolls |
US20040146717A1 (en) * | 2001-06-08 | 2004-07-29 | The Procter & Gamble Company | Moisture vapour permeable, liquid impermeable multilayer structures with enhanced moisture vapour permeability and dimensional stability and articles comprising said structures |
ATE294707T1 (en) * | 2001-06-08 | 2005-05-15 | Procter & Gamble | WATER VAPOR PERMEABLE, LIQUID IMPERMEABLE COMPOSITE STRUCTURE WITH ENHANCED WATER VAPOR PERMEABILITY AND DIMENSIONAL STABILITY AND ARTICLES CONTAINING SUCH STRUCTURES |
ATE342936T1 (en) | 2001-08-01 | 2006-11-15 | Fuller H B Licensing Financ | BREATHABLE BIODEGRADABLE HOT MEL COMPOSITION |
EP1620479B1 (en) | 2002-10-15 | 2013-07-24 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US20050022919A1 (en) * | 2003-07-28 | 2005-02-03 | Burlington Industries, Inc. | Alternate method for applying hot melt adhesives to carpet |
US7872168B2 (en) * | 2003-10-31 | 2011-01-18 | Kimberely-Clark Worldwide, Inc. | Stretchable absorbent article |
US20050120947A1 (en) * | 2003-12-09 | 2005-06-09 | Konica Minolta Photo Imaging, Inc. | Coating apparatus and coating method |
US20060173434A1 (en) * | 2005-02-02 | 2006-08-03 | Zoromski Paula K | Ultra thin absorbent article including a hot melt superabsorbent polymer composition |
MXPA05006997A (en) * | 2005-06-27 | 2006-02-13 | David Ocejo Sanchez | Improved disposable absorbent article. |
US7816286B1 (en) * | 2007-11-30 | 2010-10-19 | H. B. Fuller Company | Thermoplastic composition for wallpaper and the wallpaper including the same |
PL2242465T3 (en) | 2008-01-24 | 2015-04-30 | Clopay Plastic Prod Co Inc | Elastomeric materials |
DE102008046607A1 (en) | 2008-09-10 | 2010-05-20 | Paul Hartmann Ag | Incontinence article in panty form |
US9738816B2 (en) * | 2012-12-06 | 2017-08-22 | 3M Innovative Properties Company | Precision coating of viscous liquids and use in forming laminates |
EP3191045B1 (en) * | 2014-09-09 | 2019-11-06 | H. B. Fuller Company | A disposable article including at least one elastic bonded region |
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- 1996-01-30 EP EP04014718A patent/EP1459719A3/en not_active Withdrawn
- 1996-01-30 EP EP96903949A patent/EP0814736B2/en not_active Expired - Lifetime
- 1996-01-30 DE DE69634533T patent/DE69634533T3/en not_active Expired - Lifetime
- 1996-01-30 EP EP99114110A patent/EP0947185B2/en not_active Expired - Lifetime
- 1996-01-30 KR KR10-2003-7015761A patent/KR100506376B1/en not_active IP Right Cessation
- 1996-01-30 ES ES96903949T patent/ES2240990T3/en not_active Expired - Lifetime
- 1996-01-30 WO PCT/EP1996/000377 patent/WO1996025902A1/en active IP Right Grant
- 1996-01-30 CA CA002213205A patent/CA2213205C/en not_active Expired - Fee Related
- 1996-01-30 JP JP52533496A patent/JP4294729B2/en not_active Expired - Fee Related
- 1996-01-30 DE DE69637372T patent/DE69637372T2/en not_active Expired - Lifetime
- 1996-01-30 KR KR1019970705875A patent/KR100511760B1/en not_active IP Right Cessation
- 1996-01-30 AU AU47854/96A patent/AU706113B2/en not_active Ceased
- 1996-01-30 ES ES99114110T patent/ES2287995T3/en not_active Expired - Lifetime
- 1996-01-30 DE DE69637132T patent/DE69637132T3/en not_active Expired - Lifetime
- 1996-01-30 ES ES98114701T patent/ES2299196T3/en not_active Expired - Lifetime
- 1996-01-30 CN CN96192143A patent/CN1130176C/en not_active Expired - Fee Related
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Cited By (38)
Publication number | Priority date | Publication date | Assignee | Title |
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US7078075B1 (en) * | 1995-02-23 | 2006-07-18 | H.B. Fuller Licensing & Financing Inc. | Method for producing a continuous thermoplastic coating and articles constructed therefrom |
US7699826B2 (en) | 1995-02-23 | 2010-04-20 | H. B. Fuller Company | Article having a continuous thermoplastic coating |
US7563479B2 (en) | 1996-08-29 | 2009-07-21 | H.B. Fuller Licensing & Financing, Inc | Method for producing a continuous thermoplastic coating and articles constructed therefrom |
AU2008203216B2 (en) * | 1997-12-01 | 2011-09-29 | H.B. Fuller Company | Method For Producing a Thermoplastic Coating and Articles Constructed Therefrom |
DE19753266B4 (en) * | 1997-12-01 | 2010-10-07 | H.B. Fuller Licensing & Financing, Inc., St. Paul | Method for connecting airtight materials |
EP1355005A2 (en) * | 1997-12-01 | 2003-10-22 | H.B. Fuller Licensing & Financing, Inc. | Method for producing a laminate and articles constructed therefrom |
US6843874B1 (en) * | 1997-12-01 | 2005-01-18 | H.B. Fuller Licensing & Financing Inc. | Method for producing a substantially continuous, nonporous thermoplastic coating and articles constructed therefrom |
EP1354699A3 (en) * | 1997-12-01 | 2003-11-12 | H.B. Fuller Licensing & Financing, Inc. | Method for producing a laminate and articles constructed therefrom |
EP1331092A3 (en) * | 1997-12-01 | 2003-11-05 | H.B. FULLER LICENSING & FINANCING, INC. | Method for producing a thermoplastic coating and articles constructed therefrom |
EP1355005A3 (en) * | 1997-12-01 | 2003-11-05 | H.B. Fuller Licensing & Financing, Inc. | Method for producing a laminate and articles constructed therefrom |
EP1354699A2 (en) * | 1997-12-01 | 2003-10-22 | H.B. Fuller Licensing & Financing, Inc. | Method for producing a laminate and articles constructed therefrom |
EP1331092A2 (en) * | 1997-12-01 | 2003-07-30 | H.B. FULLER LICENSING & FINANCING, INC. | Method for producing a thermoplastic coating and articles constructed therefrom |
EP0935955A1 (en) | 1998-02-17 | 1999-08-18 | McNEIL-PPC, Inc. | Application of adhesive to absorbent article |
EP1944336A3 (en) * | 1998-06-09 | 2008-09-24 | The Procter and Gamble Company | Low Viscosity Thermoplastic Compositions for Structures with Enhanced Moisture Vapour Permeability and the Utilisation thereof in Absorbent Articles |
WO1999064499A1 (en) * | 1998-06-09 | 1999-12-16 | The Procter & Gamble Company | Shape-formed, three dimensional, moisture vapour permeable, liquid impermeable articles |
US6495612B1 (en) | 1998-06-09 | 2002-12-17 | The Procter & Gamble Company | Shape-formed, three dimensional, moisture vapor permeable, liquid impermeable articles |
WO1999064237A1 (en) * | 1998-06-09 | 1999-12-16 | The Procter & Gamble Company | Moisture vapour permeable composite structure and the utilisation thereof in absorbent articles |
WO1999064505A1 (en) * | 1998-06-09 | 1999-12-16 | The Procter & Gamble Company | Low viscosity thermoplastic compositions for structures with enhanced moisture vapour permeability and the utilisation thereof in absorbent articles |
US6749923B1 (en) | 1998-06-09 | 2004-06-15 | The Procter & Gamble Company | Moisture vapor permeable composite structure and the utilization thereof in absorbent articles |
EP0964026A1 (en) * | 1998-06-09 | 1999-12-15 | The Procter & Gamble Company | Low viscosity thermoplastic compositions for structures with enhanced moisture vapour permeability and the utilisation thereof in absorbent articles |
US6498201B1 (en) | 1998-06-09 | 2002-12-24 | The Procter & Gamble Company | Low viscosity thermoplastic compositions for structures with enhanced moisture vapor permeability and the utilisation thereof in absorbent articles |
EP0963837A1 (en) * | 1998-06-09 | 1999-12-15 | The Procter & Gamble Company | Moisture vapour permeable composite structure and the utilisation thereof in absorbent articles |
EP1944336A2 (en) | 1998-06-09 | 2008-07-16 | The Procter and Gamble Company | Low Viscosity Thermoplastic Compositions for Structures with Enhanced Moisture Vapour Permeability and the Utilisation thereof in Absorbent Articles |
WO1999066000A1 (en) * | 1998-06-17 | 1999-12-23 | H.B. Fuller Licensing & Financing, Inc. | Hot melt pressure sensitive adhesive composition |
US6180229B1 (en) | 1998-06-17 | 2001-01-30 | H. B. Fuller Licensing & Financing, Inc. | Hot melt pressure sensitive adhesive composition useful for contact coating on heat sensitive substrates |
EP1106114A1 (en) | 1999-12-09 | 2001-06-13 | The Procter & Gamble Company | Disposable, moisture vapour permeable, liquid impermeable mattress cover having an improved structure for increased stability |
WO2001041601A1 (en) | 1999-12-09 | 2001-06-14 | The Procter & Gamble Company | Disposable, moisture vapour permeable, liquid impermeable mattress cover having an improved structure for increased stability |
US7799431B2 (en) | 2002-04-12 | 2010-09-21 | The Procter & Gamble Company | Liquid impermeable, moisture vapour permeable layers and films comprising thermoplastic hydrophilic polymeric compositions |
WO2004058116A2 (en) * | 2002-12-23 | 2004-07-15 | The Procter & Gamble Company | Polymeric compositions for moisture vapour permeable structures with improved structural stability and structures comprising said compositions |
WO2004058116A3 (en) * | 2002-12-23 | 2004-09-30 | Procter & Gamble | Polymeric compositions for moisture vapour permeable structures with improved structural stability and structures comprising said compositions |
EP1433450A1 (en) * | 2002-12-23 | 2004-06-30 | The Procter & Gamble Company | Polymeric compositions for moisture vapour permeable structures with improved structural stability and structures comprising said compositions |
US7405009B2 (en) | 2003-01-24 | 2008-07-29 | H.B. Fuller Licensing & Financing, Inc. | Moisture vapor permeable film including ethylene copolymer and articles including the same |
US8101814B2 (en) | 2004-05-12 | 2012-01-24 | The Procter & Gamble Company | Breathable absorbent articles and composites comprising a vapor permeable, liquid barrier layer |
US8153857B2 (en) | 2004-05-12 | 2012-04-10 | The Procter & Gamble Company | Breathable absorbent articles and composites comprising a vapor permeable, liquid barrier layer with thickening capabilities |
WO2008074508A1 (en) * | 2006-12-20 | 2008-06-26 | Inatec Gmbh | Laminating process and apparatus for applying an adhesive-composition film to a web-like substrate |
US8551276B2 (en) | 2006-12-20 | 2013-10-08 | Illinois Tool Works, Inc. | Laminating process and apparatus for applying an adhesive-composition film to a web-like substrate |
EP2123444A1 (en) | 2008-05-22 | 2009-11-25 | Bostik SA | Multilayer film for flexible packaging |
EP2687362A1 (en) | 2012-07-19 | 2014-01-22 | Bostik Sa | Multilayer film for flexible package |
Also Published As
Publication number | Publication date |
---|---|
US5827252A (en) | 1998-10-27 |
CA2213205A1 (en) | 1996-08-29 |
KR100506376B1 (en) | 2005-08-10 |
JPH11507290A (en) | 1999-06-29 |
EP0947185A3 (en) | 2000-01-12 |
CN1176589A (en) | 1998-03-18 |
EP0947185B2 (en) | 2012-06-27 |
DE69634533T2 (en) | 2005-09-01 |
EP0947185A2 (en) | 1999-10-06 |
CA2213205C (en) | 2004-12-07 |
ES2240990T3 (en) | 2005-10-16 |
CN1130176C (en) | 2003-12-10 |
KR19980702475A (en) | 1998-07-15 |
EP1459719A3 (en) | 2005-11-09 |
AR024824A1 (en) | 2002-10-30 |
JP4294729B2 (en) | 2009-07-15 |
DE69634533D1 (en) | 2005-05-04 |
EP0814736B1 (en) | 2005-03-30 |
DE69637372D1 (en) | 2008-01-31 |
ES2287995T3 (en) | 2007-12-16 |
DE69634533T3 (en) | 2009-10-15 |
DE69637132T3 (en) | 2012-10-31 |
EP0814736A1 (en) | 1998-01-07 |
EP0814736B2 (en) | 2009-05-13 |
KR20040006008A (en) | 2004-01-16 |
DE69637132D1 (en) | 2007-07-26 |
DE69637132T2 (en) | 2008-02-14 |
AU4785496A (en) | 1996-09-11 |
ES2299196T3 (en) | 2008-05-16 |
AU706113B2 (en) | 1999-06-10 |
EP1459719A2 (en) | 2004-09-22 |
EP0947185B1 (en) | 2007-06-13 |
KR100511760B1 (en) | 2006-01-27 |
DE69637372T2 (en) | 2008-04-10 |
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