WO1996023583A1 - Calcium silicate mass for storing acetylene gas - Google Patents
Calcium silicate mass for storing acetylene gas Download PDFInfo
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- WO1996023583A1 WO1996023583A1 PCT/US1996/001330 US9601330W WO9623583A1 WO 1996023583 A1 WO1996023583 A1 WO 1996023583A1 US 9601330 W US9601330 W US 9601330W WO 9623583 A1 WO9623583 A1 WO 9623583A1
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- WIPO (PCT)
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- mass
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- mixture
- wet weight
- silica
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C11/00—Use of gas-solvents or gas-sorbents in vessels
- F17C11/002—Use of gas-solvents or gas-sorbents in vessels for acetylene
Definitions
- This invention relates to a porous calcium silicate filler material. More particularly, the invention relates to acetylene gas storage vessels having an asbestos-free calcium silicate filler material therein and a method for manufacturing same.
- Acetylene is widely used in oxy-acetylene torches because it enables temperatures of up to 3500°C. to be reached for the welding and cutting of metals.
- acetylene gas is difficult to store because it is unstable and can decompose to its elements, carbon and hydrogen, with explosive violence at pressures greater than about 1 atmosphere if not properly stabilized.
- the gas must be dissolved in a solvent.
- Acetylene gas is thus typically stored in the form of an acetylene gas solution dissolved in, for example, an acetone solvent, in a vessel containing a porous filler mass.
- the storage vessel may be a steel cylinder. In this way, acetylene can be safely stored and shipped under pressures of up to about 17 atmospheres.
- the porous filler mass comprises a capillary system of interconnecting micropores.
- the porous filler mass is a hardened calcium silicate mass having a porosity of about 90%.
- the calcium silicate mass allows sufficient surface area to aid in maximum contact between the solvent and the acetylene. This system will absorb acetylene at a rate approaching 0.58 lbs. of acetylene per pound of the solvent .
- the acetylene-containing cylinders are produced by filling the cylinder with the porous filler mass and injecting the solvent into the cylinder. Acetylene is then introduced into the cylinder and is distributed throughout the capillary system of the porous material as a result of its dissolution in the solvent. In this way, it is possible to insure safe storage of dissolved acetylene in quantities of up to eight times the volume of the gas which could be stored without the porous mass/solvent system.
- the calcium silicate storage mass is made by mixing quicklime (calcium oxide) into water to form an aqueous slurry. Ground quartz silica is added to the slurry. A reinforcing agent is added during the mixing step to help create and hold a homogenous solution to insure a uniform mass throughout the cylinder after curing and drying. Traditionally, asbestos fibers have been used for this purpose. During mixing, one or more agents can be added to insure that the mass remains monolithic before the crystalline structure is formed during curing.
- the solids are mixed in an aqueous solution for certain mixing times.
- the slurry is then pumped into cylinder shells completely filling them and is then cured, creating a crystalline calcium silicate mass in the cylinder.
- the mass is then dried to form a high porosity core, which allows the absorption of the solvent and the acetylene gas.
- the calcium silicate filler mass should be monolithic and should be substantially free of voids. Void spaces in the filler mass provide an available space for the formation of unacceptable volumes of acetylene gas with the attendant explosion risk. Thus, the filler mass must be formed with uniformly distributed very fine pores. During drying, the mass shrinkage must be kept controlled to less than 0.5% in any dimension but never to exceed 0.125 inches (0.060 inches for cylinders with filler lengths of 18 inches or less) in a longitudinal direction inside the steel shell.
- asbestos fibers were introduced into the aqueous slurry from which the calcium silicate filler mass was produced.
- the asbestos fibers functioned as a settling resistant or suspending agent to retard the settling or separation of the lime and silica from the water in the aqueous slurry composition prior to its hardening into the calcium silicate filler mass.
- the asbestos fibers acted as a reinforcing agent to help maintain the structural integrity of the filler mass.
- One known substitute for asbestos fibers in the calcium silicate filler mass is an alkali resistant glass fiber.
- An acetylene storage vessel having a hardened asbestos-free calcium silicate filler mass reinforced by glass fibers is disclosed in U. S. Patent No. 4,349,463. While glass fibers are acceptable for this purpose, the cost of such alkali resistant glass fibers is rather high. Therefore, others have tried to use organic suspending and reinforcing agents such as cellulose, together with mineral suspending agents .
- One known such calcium silicate filler mass is disclosed in U. S. Patent No. 4,895,825. This mass includes cellulose reinforcing fibers, as well as a mineral suspending agent which can be either solid glass fibers or solids of purified clay.
- this filler material is still rather high.
- the blending sequence of this material is complicated since it involves the steps of slaking quicklime with hot water to form a first mixture; adding additional water and stirring at a slow speed to form a second mixture; dispersing a cellulose reinforcing agent in the second mixture to form a third mixture; introducing with stirring into the third mixture a mixture of natural silica and either calcium silicate or amorphous ultrafine synthetic silica to form a fourth mixture and subsequently dispersing a second mineral suspending agent, which can be /23583 PC17US96/01330
- the process comprises the steps of mixing about 8-15% by wet weight, quicklime with ambient temperature water to form a first mixture.
- the subsequent exothermic reaction is allowed to go to completion (about 1-3 hours) .
- 8-15% by wet weight, quartz silica is blended into the first mixture to form a second mixture which is allowed to sit for a minimum of 1 to 24 hours.
- 0.5 to 3% by wet weight, of a fibrous reinforcing material is blended into the second mixture to form a third mixture.
- precipitated silica is added to the third mixture to form a fourth mixture.
- the fourth mixture can also be made by adding 0.2% to 1.5% by wet weight, synthetic silica to the third mixture.
- the fourth mixture is then transferred into a cylinder to be filled.
- the fourth mixture is cured under saturated steam pressure of about 145 psig for about 20-36 hours.
- the cylinder is then dried for about four to five days at a temperature of about 375o F to 615oF.
- the first mixing step can occur at approximately 75-1250 rpm, as can the second mixing step.
- the blending and homogenizing steps can, if desired, be performed by stirring at approximately 75-1250 rpm.
- the homogenizing step can be performed under a partial vacuum between about 10 inches and 18 inches of Hg.
- the step of transferring can comprise, if desired, the subsidiary step of pumping the slurry at a vacuum of about 10 inches of Hg.
- the fibrous reinforcing material is cellulose.
- a gas storage cylinder is provided for storing gases therein.
- the storage cylinder comprises a metal shell and a monolithic dry mass filling the shell.
- the mass has a porosity of about 88 to 92% and a density range of about 250 g/1 to 350 g/1.
- the mass constitutes a dry product of an aqueous paste consisting essentially of a fibrous reinforcing material at about 0.5% to 3.0% total wet weight, water, precipitated silica at about 1.0% to 3.5% total wet weight (or synthetic silica at about 0.2% to 1.5% total wet weight), quicklime at about 8% to 15% total wet weight, and ground quartz silica at about 8% to 15% total wet weight.
- the water can be present in an amount of about three times greater than the amount of solids.
- the cylinder can further comprise acetylene gas solution disposed in the mass.
- a solvent can be disposed in the mass.
- the solvent comprises acetone.
- the mass can have a crush strength between 300 and 580 psig.
- the mass has a porosity between 88% and 89.2%.
- the mass has a density between 274 g/1 and 312 g/1.
- the fibrous reinforcing material comprises cellulose.
- the fibrous reinforcing material can comprise aluminum silicate.
- Another advantage of the present invention is the provision of a high porosity calcium silicate filler mass having only cellulose fibers which function as both the reinforcing agent and the suspending agent thereby reducing the cost of the filler mass.
- Still another advantage of the present invention is the provision of a method for mixing a slurry to form a calcium silicate filler mass in which quicklime is slaked with ambient temperature water rather than hot water to reduce the mixing time of the mass and to increase operator safety.
- Yet another advantage of the present invention is the provision of a method for manufacturing a high porosity calcium silicate filler mass in which only a limited range of mixing speeds could be used for the mixing, blending and homogenizing steps. This reduces the equipment needed and the number of steps needed to mix the slurry to form the filler mass. Lower or higher mixing speeds can be used for the various mixtures if so desired.
- a further advantage of the present invention is the provision of a method for manufacturing a high porosity calcium silicate filler mass in which only a single reinforcing agent is used and a limited number of ingredients are used thereby reducing the mixing steps needed to form the filler mass, as well as the cost thereof .
- An additional advantage of the present invention is the provision of a method for forming a calcium silicate mass in which the slaking reaction is allowed to reach completion (so that there is no further temperature rise) . This can take about 1-3 hours. Then quartz silica is added to the slaked lime and is allowed sufficient time to finish the chemical reaction. The reaction can take about 1 to 24 hours. This procedure has been found to eliminate the variability in final clearance values--between the filler mass and the adjacent cylinder wall--that might occur when adequate reaction times are not provided.
- a yet further advantage of the present invention is the provision of a method of manufacturing a high porosity calcium silicate filler mass in which precipitated silica is used in addition to quartz silica to ensure that the lime and silica reaction goes to completion.
- This procedure has two benefits. First, it minimizes water separation which can lead to rejections of the storage cylinders due to excessive clearance between the filler mass and the cylinder wall. Second, the use of precipitated silica is less expensive than the use of synthetic silica while providing the same results.
- the single figure of the drawing is a simplified schematic cross-sectional view of an acetylene storage vessel having an asbestos-free hardened porous calcium silicate filler mass reinforced with only cellulose fibers in accordance with the present invention.
- an acetylene storage vessel 10 comprises a metal shell 20 typically having a cylindrical shape forming an enclosed volume.
- the acetylene storage vessel is also typically provided with a valve 30 and fuse plugs 40.
- a hardened monolithic porous calcium silicate filler mass 50 is disposed in and substantially fills the enclosed volume of the shell 20 for receiving a dissolved acetylene gas solution. /23583 PC17US96/01330
- a small clearance space 60 is desirable, although not required, between the upper end of the cylinder shell and the filler mass 30.
- Such clearance space assists in charging the cylinder with a dissolved acetylene gas solution and in the release of acetylene gas from the solution disposed in the porous calcium silicate filler mass 50.
- this clearance space can be no greater than 0.5% of any cylinder shell dimension and not greater than 0.125 inches in a longitudinal direction inside the cylinder 20.
- the allowable clearance is only 0.060 inches. Excessive clearance must be avoided due to safety considerations. An excessively large clearance space would provide unsafe storage of the acetylene because free acetylene gas could form in these locations and potentially explode.
- the space 60 is shown as being larger only for the sake of comprehension.
- the vessel 10 is also provided with a foot ring 70 in order to stabilize the shell 20 in an upright position.
- the method according to the present invention involves adding quicklime to water at ambient temperature to form a first mixture which is allowed to slake completely. Then quartz silica is added to the slaked lime and allowed to react sufficiently. Cellulose is then blended in to form a third mixture. After the third mixture has been blended for a predetermined short time, precipitated silica is added forming a fourth mixture, which is further homogenized.
- cellulose fibers have been found, after mixing at certain levels, to form a sufficient reinforcement in a calcium silicate mass to allow proper size and distribution of the pores to achieve a porosity of up to 92% and a strength of up to 575 psig in the resulting mass.
- a fibrous reinforcing material has been shown to be the most effective at a level of about 0.5% to 3.0% total wet weight.
- the fibrous reinforcing material can be cellulose, aluminum silicate, carbon fiber, glass fiber or magnesium silicate. As is known, the cellulose is at least partially delignified, either chemically or mechanically, or both.
- the ground quartz silica used has an average particle size diameter of 11.9 microns.
- the precipitated silica has a surface area between 135 and 165 m 2 /g.
- the synthetic silica has an average surface area of 200 m 2 /g.
- the quicklime addition is in amounts proportional to the amount of silica. They should be added in a one to one molar ratio. Therefore, the amount of quicklime will vary between about 8% to about 15% total wet weight with ground quartz silica ranging from about 8% to 15% total wet weight. Precipitated silica is used in smaller amounts of about 1.0% to 3.5% to total weight (or synthetic silica in much smaller amounts of about 0.2% to 1.5%) . A fibrous reinforcing material, such as cellulose, is added in amounts of 0.5% to 3.0% total wet weight.
- the balance of the formula is water, which is present in the mixture in an amount of about three times greater than the amount of solids. A preferred amount of water is about 3.2 to 3.4 times the amount of solids.
- Shrinkage is less than 0.5%. Most typically, the actual shrinkage approaches only 0.060 inches in a longitudinal direction and less than 0.025 inches latitudinally in the cylinder.
- the density of the dry mass has been found to be between 270 g/1 to 310 g/1.
- a crush strength between 250 psig and 575 psig is also typical. It is estimated that a minimum of 35% by weight and most typically greater than 50% of the hardened porous calcium silicate filler mass is in a crystalline phase to minimize shrinkage.
- the mass is very capable of holding acetylene gas safely in a solution of a solvent, preferably acetone as mentioned, within the mass.
- a solvent preferably acetone as mentioned
- EXAMPLE 1 A total of 198 lb. quicklime (3/4 rock, 94% CaO from Dravo in Birmingham, AL) was mixed with 130 gallons of ambient temperature water at about 1000 rpm until completely slaked (about 1 to 3 hours, until the temperature of the solution no longer increases) . After slaking, 200 lb. of quartz silica (Grade #53 Silcosil from U. S. Silica Co. of Pittsburgh, PA) was added, mixed at about 1000 rpm and allowed to react for two days (about 48 hours) .
- the mixing speed was indicated in Example I to be about 1000 to 1250 rpm. However, depending on the batch size, lower mixing speeds can be used as well in order to avert the need to use very large motors for the mixing process in large mixing vessels. Therefore, when a large size mixing vessel is used, the mixing speed can be on the order of about 100 rpm instead of about 1000 rpm. It has been found that the process according to the present invention is essentially independent of the speed employed during the mixing, homogenizing, blending or dispersing steps .
- the monolithic slurry was pumped into a cylinder shell under a vacuum of 10 inches of mercury.
- the resulting mass in the cylinder was cured for approximately 36 hours at 145 psig saturated steam. It was then dried for 5 days at a temperature of about 375 to 400°F.
- the physical properties of the resulting porous calcium silicate filler mass showed a porosity of 89.2%, a shrinkage of less than 0.010 inches both longitudinally and latitudinally, a density of between 289 g/1 and 312 g/1, and a crush strength of between 508 and 562 psig.
- EXAMPLE II A total of 198 lb. quicklime was mixed with 130 gallons of ambient temperature water at about 1000 rpm until completely slaked. After slaking, 165 lb. of quartz silica was added and mixed at about 1000 rpm and allowed to react overnight (about 12 to 18 hours) . Forty-five pounds of cellulose fibers which had been pre-soaked in 20 gallons of water was then added together with 13 gallons of water and blended for 3 minutes at about 1250 rpm. Then, thirty-five pounds of precipitated silica (HI-SIL ABS from PPG, Lake Charles, LA) was added and homogenized at about 1250 rpm for fourteen minutes under a vacuum of 15 inches of mercury.
- HI-SIL ABS from PPG, Lake Charles, LA
- the monolithic slurry was pumped into a cylinder shell under a vacuum of 10 inches of mercury.
- the resulting mass in the cylinder was cured for approximately 24 hours at 145 psig saturated steam.
- Another batch of the same mass was cured for 30 hours at the same pressure. Both batches were then dried for 5 days at a temperature of about 375oF to 400oF.
- the physical properties of the resulting porous calcium silicate filler mass indicated a porosity of 88.0%, a shrinkage of less than 0.020 inches both longitudinally and latitudinally and a density of between 274 and 292 g/1 for both batches.
- a crush test of 379 psig was achieved for the 24 hour cure batch and a crush test of 577 psig was achieved for the 30 hour cure batch.
- a total of 198 lb. quicklime was mixed with 130 gallons of ambient temperature water at about 75-100 rpm until completely slaked. After slaking, 165 lb. of quartz silica was added, mixed at 75-100 rpm and allowed to react overnight. Forty-two pounds of cellulose fibers, which had been pre-soaked in 20 gallons of water, was then added along with 15 gallons of water and blended for 3 minutes at about 1250 rpm. Then, thirty-five pounds of precipitated silica was added and homogenized at 1250 rpm for fourteen minutes under a vacuum of 15 inches of mercury. The monolithic slurry was pumped into a cylinder shell under a vacuum of 10 inches of mercury. The resulting mass in the cylinder was cured for approximately 24 hours at 145 psig saturated steam. Another batch of the material was cured for 26 hours at the same pressure. Both batches were then dried for 5 days at a temperature of about 375oF to 400°F.
- the physical properties of the resulting porous calcium silicate filler mass cured for 24 hours indicated a porosity of 89.2%, a shrinkage of less than 0.060 inches both longitudinally and latitudinally and a density of about 296 g/1.
- a crush test of 368 psig was achieved for the 24 hour cure.
- a crush test of 427 psig was achieved for the 26 hour cure.
- EXAMPLE IV A total of 198 lbs. quicklime was mixed with 130 gallons of ambient temperature water at about 1000 rpm until completely slaked. After slaking, 165 lbs. of quartz silica was added and mixed at about 1000 rpm and allowed to react overnight (about 12 to 18 hours) . Forty lbs. of aluminum silicate fibers (sold under the trademark Kaowool by Thermal Ceramics of Baton Rouge, Louisiana) was added together with 23 gallons of water and blended for three minutes at about 1250 rpm. Then, 12 lbs. of synthetic silica was added and homogenized at about 1250 rpm for 14 minutes under a vacuum of 15 inches of mercury.
- the monolithic slurry was pumped into a cylinder shell under a vacuum of 10 inches of mercury.
- the resulting mass in the cylinder was cured for approximately 36 hours at 145 psig saturated steam.
- the batch was then dried for about 4 days at a temperature of about 615OF.
- a total of 174 lbs. quicklime (small pebble 95% CaO from Chemline in Dallas, Texas) was mixed with 66.5 gallons of ambient temperature water in a first mixing vessel at 1000 rpm for 30 minutes. While the quicklime was slaking, the following ingredients were added in a second mixing vessel in the following order: 63 gallons of ambient temperature water, 158 lbs. of quartz silica (Grade 106 Silcosil from U. S. Silica Co. of Pittsburgh, PA) , and 34.6 lbs. of cellulose fibers (Brunswick softwood filter pulp from Georgia Pacific of Charlotte, North Carolina), 6 lbs. of synthetic silica (HDK-N20 from Wacker Silicones of Adrian, Michigan) . This mixture was agitated for 5 minutes at 1000 rpm to form a slurry.
- the quicklime After the quicklime has been mixed for 30 minutes, it was transferred into the second mixing vessel containing the water, cellulose fibers, silica and synthetic silica.
- the resulting slurry was mixed at 1000 rpm for 15 minutes under a vacuum of 18 inches of mercury. Then, while the slurry continued to be mixed, 5.5 lbs. of ethyl hydroxyethyl cellulose (Bermocoll E4116 from Berol Nobel of Newark, New Jersey) was added and mixed for an additional 10 minutes at 1000 rpm, again under a partial vacuum of 18 inches Hg.
- the monolithic slurry was pumped into a cylinder shell under 22 inches Hg vacuum.
- the resulting mass in the cylinder was cured for approximately 25 hours at 145 psig saturated steam. It was then dried for 5 days at 325oF.
- a total of 168 lbs. quicklime was mixed with 80 gallons of ambient temperature water for 20 minutes at 1000 rpm in a first mixing vessel. While the quicklime was slaking, the following ingredients were added to a second mixing vessel in the order listed: 74.5 gallons of ambient temperature water, 156 lbs. of quartz silica, 40 lbs. of cellulose fibers and 8 lbs. of synthetic silica. This mixture was agitated for 5 minutes at 1000 rpm to form a slurry. After the quicklime has slaked, it was transferred into the second mixing vessel containing the water, cellulose fibers, silica and synthetic silica.
- the resulting slurry was mixed for 15 minutes at 1000 rpm under a vacuum of about 10 inches Hg. While the slurry continued mixing at 1000 rpm, 8 lbs. of ethyl hydroxyethyl cellulose was added. After a further 10 minutes of mixing at 1000 rpm, the mixing was stopped and the resulting slurry was pumped into empty cylinder shells. Curing and drying took place as in Example V.
- the physical properties of the resulting porous calcium silicate filler mass indicated a porosity of 90.5%, a shrinkage of 0.05% both longitudinally and latitudinally and a density of 251 g/1.
- EXAMPLE VII A total of 156 lbs. quicklime was mixed in a first mixing vessel with 75 gallons of ambient temperature water at 1000 rpm for 30 minutes. While the quicklime was slaking, a second mixing vessel had the following ingredients added to it in the order listed: 71 gallons of ambient temperature water, 141 lbs. of quartz silica, 36 lbs. of cellulose fibers and 7 lbs. of synthetic silica. This mixture was agitated for 5 minutes at 1000 rpm to form a slurry. After the quicklime had been mixed for 30 minutes, it was transferred into the second mixing vessel containing the water, cellulose fibers, silica and synthetic silica.
- the resulting slurry was mixed at 1000 rpm for 20 minutes under a partial vacuum of 18 inches Hg. Then, as the mixing continued, 6.75 lbs. of ethyl hydroxyethyl cellulose was added under a partial vacuum of 20 inches Hg. Mixing continued for an additional 15 minutes. Cylinder shells were then filled with the resultant slurry. These cylinders were cured and dried as in Example V.
- the physical properties of the resultant porous calcium silicate mass indicated a porosity of 89.5%, a shrinkage of less than 0.05% both longitudinally and latitudinally and a density of 259 g/1.
- the cylinders so manufactured have successfully passed the Compressed Gas Cylinders Association bonfire test, flashback test and two mechanical strength tests, namely, a mechanical strength of filler test and an impact stability test.
- the tests are described in detail in pamphlet No. C-12 of the Compressed Gas Cylinders Association. These tests have been incorporated into the Department of Transportation's regulations listed in 49 C.F.R. and entitled "Qualifications Procedure for Acetylene Cylinder Design.”
- the proof of the mechanical strength of the filler test involved subjecting the cylinders filled with the porous calcium silicate mass according to the present invention to 5000 drops at 3 inches. In all cases, the filler did not exceed a 0.0625 inch vertical drop. This passes the test .
- the flashback test involved subjecting full cylinders having the porous calcium silicate filler mass according to the present invention to an internal flash. In all cases, the porous calcium silicate mass absorbed the energy without failure to the cylinder.
- the fire test involved subjecting full cylinders employing a calcium silicate filler mass according to the present invention to a chimney fire. In all cases, the cylinder did not rupture and acetylene was vented by the fuse plugs.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
Description
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Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96902174A EP0806983A4 (en) | 1995-01-31 | 1996-01-30 | Calcium silicate mass for storing acetylene gas |
PL96321728A PL183353B1 (en) | 1995-01-31 | 1996-01-30 | Porous calcium silicate body for storing gaseous acetylene, method of filing a cylinder with such body and gaseous acetylene storage cylinder |
BR9606870A BR9606870A (en) | 1995-01-31 | 1996-01-30 | Process for filling a cylinder with a porous calcium silicate mass to produce an acetylene gas storage cylinder gas storage cylinder to store gases therein and filling mass for a gas storage |
CA002210352A CA2210352C (en) | 1995-01-31 | 1996-01-30 | Calcium silicate mass for storing acetylene gas |
AU46589/96A AU690812B2 (en) | 1995-01-31 | 1996-01-30 | Calcium silicate mass for storing acetylene gas |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/381,356 US5632788A (en) | 1995-01-31 | 1995-01-31 | High porosity calcium silicate mass for storing acetylene gas |
US08/381,356 | 1995-01-31 | ||
US08/570,092 | 1995-12-11 | ||
US08/570,092 US5697990A (en) | 1995-01-31 | 1995-12-11 | High porosity calcium silicate mass for storing acetylene gas |
Publications (1)
Publication Number | Publication Date |
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WO1996023583A1 true WO1996023583A1 (en) | 1996-08-08 |
Family
ID=27009362
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1996/001330 WO1996023583A1 (en) | 1995-01-31 | 1996-01-30 | Calcium silicate mass for storing acetylene gas |
Country Status (8)
Country | Link |
---|---|
US (1) | US5697990A (en) |
EP (1) | EP0806983A4 (en) |
KR (1) | KR19980701708A (en) |
AU (1) | AU690812B2 (en) |
BR (1) | BR9606870A (en) |
CA (1) | CA2210352C (en) |
PL (1) | PL183353B1 (en) |
WO (1) | WO1996023583A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998029682A1 (en) * | 1996-12-26 | 1998-07-09 | 'tehnogas' D.D. | Porous mass asbestos free for acetylene vessels |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9609005D0 (en) * | 1996-05-01 | 1996-07-03 | Bowthorpe Plc | Cable enclosure |
US6994932B2 (en) * | 2001-06-28 | 2006-02-07 | Foamex L.P. | Liquid fuel reservoir for fuel cells |
US20040001989A1 (en) * | 2002-06-28 | 2004-01-01 | Kinkelaar Mark R. | Fuel reservoir for liquid fuel cells |
US7291410B2 (en) * | 2002-09-18 | 2007-11-06 | Kinkelaar Mark R | Orientation independent liquid fuel reservoir |
US6622880B1 (en) * | 2003-01-06 | 2003-09-23 | Crest Foam Industries | Foam insert for pressure vessels |
FR2884895A1 (en) * | 2005-04-22 | 2006-10-27 | Air Liquide | Acetylene cylinder for use with oxygen cylinder, has thermal conducting device arranged outside body and is in thermal connection with interior of body in order to operate thermal exchange between device and interior of body |
FR2887013A1 (en) * | 2005-06-09 | 2006-12-15 | Air Liquide | Acetylene cylinder, has outer envelope containing porous mass, and elongated shaped heat conducting unit inserted in porous mass and including axial rod equipped of radial or axial fins whose ends contact with internal wall of cylinder |
FR2933689B1 (en) * | 2008-07-11 | 2011-03-18 | Air Liquide | HIGH PERFORMANCE TRIM STRUCTURE WITH CONTROLLED SIDE GAMES |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3816149A (en) * | 1972-06-02 | 1974-06-11 | Johns Manville | Hydrated calcium sillicate products |
US4129450A (en) * | 1977-11-09 | 1978-12-12 | Union Carbide Corporation | Acetylene vessel filler composition |
US4467041A (en) * | 1981-05-13 | 1984-08-21 | L'air Liquide - Societe Anonyme Pour L'etude Et L'exploitation Des Procedes George Claude | Silicocalcareous mass with high porosity and its preparation |
US4765458A (en) * | 1986-10-14 | 1988-08-23 | Ni Industries, Inc. | Asbestos free hardened monolithic filler mass |
US4895825A (en) * | 1986-09-18 | 1990-01-23 | L'air Liquide | High-porosity silicocalcareous mass for storing of gas, and production process |
US4970246A (en) * | 1988-11-01 | 1990-11-13 | Coyne Cylinder Company | Acetylene storage vessel filler and method |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2883040A (en) * | 1953-04-27 | 1959-04-21 | Union Carbide Corp | Monolithic porous filler for cylinders and method of producing same |
US3794505A (en) * | 1972-04-28 | 1974-02-26 | Owens Corning Fiberglass Corp | Method of producing calcium silicate hydrate insulation material devoid of asbestos |
US3902913A (en) * | 1972-04-28 | 1975-09-02 | Owens Corning Fiberglass Corp | Hydrous calcium silicate insulation products |
US3909345A (en) * | 1972-12-14 | 1975-09-30 | Basf Wyandotte Corp | Method of treatment of wood pulp for greater efficiency in wood utilization |
US3895096A (en) * | 1973-09-10 | 1975-07-15 | Owens Corning Fiberglass Corp | Method of producing hydrous calcium silicate products and the products thereof |
US3926652A (en) * | 1974-04-26 | 1975-12-16 | Coyne Cylinder Co | Perlite acetylene cylinder filler composition |
US4238240A (en) * | 1979-02-16 | 1980-12-09 | Pieter Krijgsman | Method of and structure for forming a reaction product such as calcium silicate and the resulting structure |
SE462919B (en) * | 1979-05-11 | 1990-09-17 | Sunds Defibrator Ind Ab | PROCEDURE TO PERFORM ALKALIE EXTRACTION OF CELLULOSAMASS IN THE PRESENCE OF ACID |
US4402892A (en) * | 1980-10-15 | 1983-09-06 | Owens-Corning Fiberglas Corporation | Method for making xonotlite insulation by foaming an aqueous slurry of calcareous and siliceous reactants and cellulosic and glass fibers |
US4349463A (en) * | 1981-01-19 | 1982-09-14 | Union Carbide Corporation | Acetylene storage vessel |
US4800930A (en) * | 1987-03-24 | 1989-01-31 | Rabren Michael S | Solvent for porous mass acetylene containers |
US5035774A (en) * | 1990-04-26 | 1991-07-30 | North American Cylinders | Recovery of solvent from acetylene steel cylinders to make the cylinders disposable |
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1995
- 1995-12-11 US US08/570,092 patent/US5697990A/en not_active Expired - Fee Related
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1996
- 1996-01-30 KR KR1019970705104A patent/KR19980701708A/en active IP Right Grant
- 1996-01-30 EP EP96902174A patent/EP0806983A4/en not_active Withdrawn
- 1996-01-30 PL PL96321728A patent/PL183353B1/en unknown
- 1996-01-30 BR BR9606870A patent/BR9606870A/en active Search and Examination
- 1996-01-30 WO PCT/US1996/001330 patent/WO1996023583A1/en not_active Application Discontinuation
- 1996-01-30 CA CA002210352A patent/CA2210352C/en not_active Expired - Fee Related
- 1996-01-30 AU AU46589/96A patent/AU690812B2/en not_active Ceased
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3816149A (en) * | 1972-06-02 | 1974-06-11 | Johns Manville | Hydrated calcium sillicate products |
US4129450A (en) * | 1977-11-09 | 1978-12-12 | Union Carbide Corporation | Acetylene vessel filler composition |
US4467041A (en) * | 1981-05-13 | 1984-08-21 | L'air Liquide - Societe Anonyme Pour L'etude Et L'exploitation Des Procedes George Claude | Silicocalcareous mass with high porosity and its preparation |
US4467040A (en) * | 1981-05-13 | 1984-08-21 | L'air Liquide - Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Preparation and use of high porosity silicocalcareous mass |
US4721698A (en) * | 1981-05-13 | 1988-01-26 | L'Air Liquide--Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude | High porosity silicocalcareous mass |
US4895825A (en) * | 1986-09-18 | 1990-01-23 | L'air Liquide | High-porosity silicocalcareous mass for storing of gas, and production process |
US4765458A (en) * | 1986-10-14 | 1988-08-23 | Ni Industries, Inc. | Asbestos free hardened monolithic filler mass |
US4970246A (en) * | 1988-11-01 | 1990-11-13 | Coyne Cylinder Company | Acetylene storage vessel filler and method |
Non-Patent Citations (1)
Title |
---|
See also references of EP0806983A4 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998029682A1 (en) * | 1996-12-26 | 1998-07-09 | 'tehnogas' D.D. | Porous mass asbestos free for acetylene vessels |
Also Published As
Publication number | Publication date |
---|---|
AU690812B2 (en) | 1998-04-30 |
EP0806983A1 (en) | 1997-11-19 |
KR19980701708A (en) | 1998-06-25 |
CA2210352C (en) | 2001-04-24 |
CA2210352A1 (en) | 1996-08-08 |
PL321728A1 (en) | 1997-12-22 |
EP0806983A4 (en) | 1998-12-02 |
US5697990A (en) | 1997-12-16 |
PL183353B1 (en) | 2002-06-28 |
AU4658996A (en) | 1996-08-21 |
BR9606870A (en) | 1997-12-23 |
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