WO1996023033A1 - Curable resin composition, coating composition and method for forming coated film - Google Patents
Curable resin composition, coating composition and method for forming coated film Download PDFInfo
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- WO1996023033A1 WO1996023033A1 PCT/JP1996/000079 JP9600079W WO9623033A1 WO 1996023033 A1 WO1996023033 A1 WO 1996023033A1 JP 9600079 W JP9600079 W JP 9600079W WO 9623033 A1 WO9623033 A1 WO 9623033A1
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- 239000011342 resin composition Substances 0.000 title claims abstract description 68
- 239000008199 coating composition Substances 0.000 title claims description 54
- 238000000034 method Methods 0.000 title claims description 15
- 239000002253 acid Substances 0.000 claims abstract description 146
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 84
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 70
- 239000007787 solid Substances 0.000 claims abstract description 66
- 125000004018 acid anhydride group Chemical group 0.000 claims abstract description 49
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 48
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 47
- 229920000728 polyester Polymers 0.000 claims abstract description 44
- 150000001875 compounds Chemical class 0.000 claims abstract description 29
- 239000004593 Epoxy Substances 0.000 claims abstract description 24
- 229920005906 polyester polyol Polymers 0.000 claims abstract description 15
- 239000000178 monomer Substances 0.000 claims description 69
- 125000003700 epoxy group Chemical group 0.000 claims description 36
- 125000004432 carbon atom Chemical group C* 0.000 claims description 25
- 239000002904 solvent Substances 0.000 claims description 24
- -1 lactone compound Chemical class 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000011248 coating agent Substances 0.000 claims description 19
- 238000000576 coating method Methods 0.000 claims description 19
- 229920005989 resin Polymers 0.000 claims description 18
- 239000011347 resin Substances 0.000 claims description 18
- 150000007942 carboxylates Chemical group 0.000 claims description 15
- 150000005846 sugar alcohols Polymers 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 13
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 7
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 6
- 125000002947 alkylene group Chemical group 0.000 claims description 5
- OZJPLYNZGCXSJM-UHFFFAOYSA-N delta-Valerolactone Natural products O=C1CCCCO1 OZJPLYNZGCXSJM-UHFFFAOYSA-N 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 4
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 2
- 229920002732 Polyanhydride Polymers 0.000 claims 1
- 238000003916 acid precipitation Methods 0.000 abstract description 4
- 238000006243 chemical reaction Methods 0.000 description 57
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 38
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 38
- 239000008096 xylene Substances 0.000 description 38
- 239000000243 solution Substances 0.000 description 29
- 229920005573 silicon-containing polymer Polymers 0.000 description 27
- 239000002966 varnish Substances 0.000 description 26
- 239000000203 mixture Substances 0.000 description 25
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
- 239000003999 initiator Substances 0.000 description 23
- FVQMJJQUGGVLEP-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOOC(C)(C)C FVQMJJQUGGVLEP-UHFFFAOYSA-N 0.000 description 22
- 230000015572 biosynthetic process Effects 0.000 description 22
- 238000003786 synthesis reaction Methods 0.000 description 22
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 21
- 238000001816 cooling Methods 0.000 description 19
- 229910052757 nitrogen Inorganic materials 0.000 description 19
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 18
- 150000008064 anhydrides Chemical class 0.000 description 18
- 125000003545 alkoxy group Chemical group 0.000 description 13
- MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 12
- 229920000877 Melamine resin Polymers 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000004640 Melamine resin Substances 0.000 description 10
- 238000009472 formulation Methods 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
- 238000005886 esterification reaction Methods 0.000 description 9
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 9
- 238000003860 storage Methods 0.000 description 9
- 238000004132 cross linking Methods 0.000 description 8
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 8
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 7
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
- 125000000524 functional group Chemical group 0.000 description 6
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 6
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 150000003606 tin compounds Chemical class 0.000 description 6
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 150000008065 acid anhydrides Chemical group 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 238000004070 electrodeposition Methods 0.000 description 5
- BHXIWUJLHYHGSJ-UHFFFAOYSA-N ethyl 3-ethoxypropanoate Chemical compound CCOCCC(=O)OCC BHXIWUJLHYHGSJ-UHFFFAOYSA-N 0.000 description 5
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 4
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 4
- FKBMTBAXDISZGN-UHFFFAOYSA-N 5-methyl-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1C(C)CCC2C(=O)OC(=O)C12 FKBMTBAXDISZGN-UHFFFAOYSA-N 0.000 description 4
- 229920003270 Cymel® Polymers 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 239000002390 adhesive tape Substances 0.000 description 4
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000001276 controlling effect Effects 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 3
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 3
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- PWEVMPIIOJUPRI-UHFFFAOYSA-N dimethyltin Chemical compound C[Sn]C PWEVMPIIOJUPRI-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 239000003607 modifier Substances 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 229940014800 succinic anhydride Drugs 0.000 description 3
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 3
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 2
- ARXKVVRQIIOZGF-UHFFFAOYSA-N 1,2,4-butanetriol Chemical compound OCCC(O)CO ARXKVVRQIIOZGF-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- WMYINDVYGQKYMI-UHFFFAOYSA-N 2-[2,2-bis(hydroxymethyl)butoxymethyl]-2-ethylpropane-1,3-diol Chemical compound CCC(CO)(CO)COCC(CC)(CO)CO WMYINDVYGQKYMI-UHFFFAOYSA-N 0.000 description 2
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 2
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 238000010533 azeotropic distillation Methods 0.000 description 2
- HTZCNXWZYVXIMZ-UHFFFAOYSA-M benzyl(triethyl)azanium;chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC1=CC=CC=C1 HTZCNXWZYVXIMZ-UHFFFAOYSA-M 0.000 description 2
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000012986 chain transfer agent Substances 0.000 description 2
- 238000006482 condensation reaction Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 2
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical group 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- GAEKPEKOJKCEMS-UHFFFAOYSA-N gamma-valerolactone Chemical compound CC1CCC(=O)O1 GAEKPEKOJKCEMS-UHFFFAOYSA-N 0.000 description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- XLSMFKSTNGKWQX-UHFFFAOYSA-N hydroxyacetone Chemical compound CC(=O)CO XLSMFKSTNGKWQX-UHFFFAOYSA-N 0.000 description 2
- 125000003010 ionic group Chemical group 0.000 description 2
- 229940119545 isobornyl methacrylate Drugs 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
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- 150000007519 polyprotic acids Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- TVDSBUOJIPERQY-UHFFFAOYSA-N prop-2-yn-1-ol Chemical compound OCC#C TVDSBUOJIPERQY-UHFFFAOYSA-N 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 238000000518 rheometry Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 2
- NHGXDBSUJJNIRV-UHFFFAOYSA-M tetrabutylammonium chloride Chemical compound [Cl-].CCCC[N+](CCCC)(CCCC)CCCC NHGXDBSUJJNIRV-UHFFFAOYSA-M 0.000 description 2
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 description 1
- JLBXCKSMESLGTJ-UHFFFAOYSA-N 1-ethoxypropan-1-ol Chemical compound CCOC(O)CC JLBXCKSMESLGTJ-UHFFFAOYSA-N 0.000 description 1
- LHENQXAPVKABON-UHFFFAOYSA-N 1-methoxypropan-1-ol Chemical compound CCC(O)OC LHENQXAPVKABON-UHFFFAOYSA-N 0.000 description 1
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 1
- HCGSQUAEWDJWSK-UHFFFAOYSA-N 16-methylheptadecanoic acid;phosphoric acid Chemical compound OP(O)(O)=O.CC(C)CCCCCCCCCCCCCCC(O)=O HCGSQUAEWDJWSK-UHFFFAOYSA-N 0.000 description 1
- OLQFXOWPTQTLDP-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCO OLQFXOWPTQTLDP-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- PLDLPVSQYMQDBL-UHFFFAOYSA-N 2-[[3-(oxiran-2-ylmethoxy)-2,2-bis(oxiran-2-ylmethoxymethyl)propoxy]methyl]oxirane Chemical compound C1OC1COCC(COCC1OC1)(COCC1OC1)COCC1CO1 PLDLPVSQYMQDBL-UHFFFAOYSA-N 0.000 description 1
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 description 1
- MECNWXGGNCJFQJ-UHFFFAOYSA-N 3-piperidin-1-ylpropane-1,2-diol Chemical compound OCC(O)CN1CCCCC1 MECNWXGGNCJFQJ-UHFFFAOYSA-N 0.000 description 1
- SXIFAEWFOJETOA-UHFFFAOYSA-N 4-hydroxy-butyl Chemical group [CH2]CCCO SXIFAEWFOJETOA-UHFFFAOYSA-N 0.000 description 1
- YKXAYLPDMSGWEV-UHFFFAOYSA-N 4-hydroxybutyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCO YKXAYLPDMSGWEV-UHFFFAOYSA-N 0.000 description 1
- FYYIUODUDSPAJQ-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-ylmethyl 2-methylprop-2-enoate Chemical compound C1C(COC(=O)C(=C)C)CCC2OC21 FYYIUODUDSPAJQ-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229930188620 butyrolactone Natural products 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000002296 dynamic light scattering Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- YEJRWHAVMIAJKC-UHFFFAOYSA-N gamma-butyrolactone Natural products O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229940049920 malate Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 1
- 239000012974 tin catalyst Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-M toluene-4-sulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-M 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/064—Copolymers with monomers not covered by C09D133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/062—Copolymers with monomers not covered by C08L33/06
- C08L33/064—Copolymers with monomers not covered by C08L33/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
Definitions
- the present invention relates to a curable resin composition which is suitable for an automotive top coating composition and a coil coating composition.
- a top coating composition for an automobile generally comprises, as a binder component, a combination of a hydroxyl group-containing polymer and a melamine resin curing agent.
- a coated film obtained by using a melamine resin as a curing agent generally has poor acid resistance. Accordingly, such a coated film is liable to be damaged by an acid rain which has recently become a serious problem, and an appearance of the coated film is deteriorated.
- the poor acid resistance which is provided by using a melamine resin is believed to be originate from a triazine nucleus in the melamine resin. Accordingly, a drawback of poor acid resistance is not dissolved, so far as a melamine resin is used as a curing agent.
- the coating composition comprises an acid group and an epoxy group therein, and the acld group and the epoxy group reacts to form a crosslinking point of an ester bond, and therefore, acid resistance of the resulting coated film is excellent.
- the coating composition however, has high functional group content and high viscosity. Therefore, a large amount of solvent must be used for controlling viscosity, and it is difficult to prepare a high-solid type coating composition.
- Japanese Laid-Open Patent Publication No. 6-166741 there is disclosed a high-solid coating composition using a silicone polymer.
- a hydroxyl group functional silicone polymer is reacted with an acid anhydride group-containing compound in order to impart acid functionality, and incorporated into the coating composition. Accordingly, an amount of functional group of the composition can not be increased, Tg of the resulting resin becomes low, and therefore, Tg of the resulting coated film can not be increased.
- Japanese Laid-Open Patent Publication No. 6-41575 there is disclosed a high-solid coating composition comprising a polyepoxide (a) and a polyester polycarboxylic acid (b).
- solid content of the coating composition is not sufficiently high in order to prevent the harmful influence on environment, and the coated film formed has poor acid resistance.
- An object of the present invention Is to solve the above conventional problem, and provide a high-solid curable resin composition which forms a coated film having excellent acid rain resistance, mar resistance and appearance, as well as a high-solid coating composition and a method for forming a coated film using the same.
- the present invention provides high-solid curable resin composition, comprising:
- An acrylic polycarboxylic acid (a) to be used in the present invention has 2 or more carboxyl groups per molecule on an average, an acid value of 5 to 300 mg KOH/g, preferably 25 to 250 mg KOH/g, more preferably 50 to 200 mg KOH/g, and a number average-molecular weight of 500 to 8000, preferably 800 to 6000, more preferably 1500 to 4000.
- the acrylic polycarboxylic acid is obtained by copolymerizing 5 to 80% by weight of a carboxyl group- containing ethylenically unsaturated monomer with 20 to 95% by weight of an ethylenically unsaturated monomer having no carboxyl group according to a method known to the art.
- the copolymerization can be carried out at a polymerization temperature of 80 to 200°C for a polymerization time of 3 to 10 hours under normal or applied pressure, using an azo or peroxide initiator as a radical polymerization initiator in an amount of 0.5 to 20 parts by weight, based on 100 parts by weight of the total ethylenically unsaturated monomers.
- a conventional polymerization controlling agents such as a chain transfer agent, a color protection agent and the like may be added during the polymerization.
- Examples of the carboxyl group-containing ethylenically unsaturated monomer include acrylic acid, methacrylic acid, itaconic acid, maleic acid, an adduct of these with ⁇ - caprolactone (e.g. "Allonlx M-5300", manufactured by Toa Gosei Kagaku Co., Ltd., etc.), an adduct of an ethylenically unsaturated monomer having a hydroxyl group represented by the formula (I) with an acid anhydride group-containing compound, and an adduct of an acid anhydride group- containing ethylenically unsaturated monomer with a monoalcohol.
- the ethylenically unsaturated monomer having a carboxyl group can be used alone or in combination thereof.
- the acid anhydride group-containing compound is half- esterified by a hydroxyl group to provide a carboxy functional group in an ambient reaction condition such as room temperature to 150°C under normal pressure. It is preferred to use an acid anhydride group-containing compound having 4 to 12 carbon atoms, particularly 8 to 10 carbon atoms, which has a (unsaturated or saturated) cyclic group. Such a component may improves compatibility of the resulting resin.
- Examples of the preferred acid anhydride group- containing compound include phthalic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride, 4-methyl hexahydrophthalic anhydride, trimellltic anhydride, succinic anhydride, etc.
- Examples of the acid anhydride group-containing ethylenically unsaturated monomer to be used herein include itaconic anhydride, maleic anhydride, citraconic anhydride, etc .
- Examples of the monoalcohol to be used herein include methanol, ethanol, n-propanol, i-propanol, n-butanol, i- butanol, t-butanol, n-hexyl alcohol, lauryl alcohol, methyl cellosolve, ethyl cellosolve, methoxypropanol, ethoxypropanol, furfuryl alcohol, dimethylamino ethanol, diethylamino ethanol, acetol, allyl alcohol, propargyl alcohol, etc.
- Examples of the ethylenically unsaturated monomer having no carboxyl group include styrene, -methylstyrene, p-t-butylstyrene, (meth)acrylate (e.g. methyl (meth)acrylate, ethyl (meth)acrylate, propyl (meth)acrylate, n-, i- and t- butyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, lauryl (meth)acrylate, cyclohexyl (meth)acrylate, isobornyl (meth)acrylate) , etc.), VeoVa-9 and VeoVa-10 manufactured by Shell Co., etc.
- styrene or a styrene derivative is used as the ethylenically unsaturated monomer having no carboxyl group, it is preferred to use in an amount of 5 to 40% by weight.
- a preferred acrylic polycarboxylic acid (a) of the curable resin composition of the present invention has a carboxyl group and a carboxylate group, which bond to adjacent carbon atoms each other, because acid resistance of the resulting coated film is improved.
- the acrylic polycarboxylic acid (a) having a carboxyl group and a carboxylate group is obtained, for example, by reacting an acrylic polyacid anhydride (a)(i) with a monoalcohol (a)(ii).
- the acrylic polyacid anhydride (a)(1) is obtained by copolymerizing 15 to 40% by weight, preferably 15 to 35% by weight of an acid anhydride group-containing ethylenically unsaturated monomer (a)(i)(l) with 60 to 85% by weight, preferably 65 to 85% by weight of an ethylenically unsaturated monomer having no acid anhydride group (a)(i)(2).
- an amount of the acid anhydride group-containing ethylenically unsaturated monomer (a)(i)(l) is smaller than 15% by weight, curability becomes poor.
- the amount exceeds 40% by weight the resulting coated film becomes too brittle, which results in poor weather resistance.
- Examples of the acid anhydride group-containing ethylenically unsaturated monomer (a)(i)(l) include those which have already described.
- the ethylenically unsaturated monomer having no acid anhydride group (a)(1) (2) is not specifically limited unless It exerts a harmful influence on an acid anhydride group.
- Preferred are those having 3 to 15 carbon atoms, particularly 3 to 12 carbon atoms, which has one ethylenically unsaturated bond.
- a mixture of 2 or more ethylenically unsaturated monomers is also may be used as the ethylenically unsaturated monomer having no acid anhydride group (a)(i)(2), because it is effective to improve compatibility between resins.
- Specific examples of the monomer (a)(1) (2) include those described above as the ethylenically unsaturated monomer having no carboxyl group.
- a monomer having a carboxyl group, such as acrylic acid, methacryllc acid, itaconic acid, maleic acid, etc. can also be used as the ethylenically unsaturated monomer having no acid anhydride group (a)(1) (2).
- a long-chain carboxylic acid monomer having a spacer moiety of about 5 to 20 carbon atoms between an ethylenically unsaturated group and a carboxyl group.
- Specific examples thereof include an adduct of the monomer having a carboxyl group with ⁇ -caprolactone (e.g. Allonlx M-5300).
- the long- chain carboxylic acid monomer may improve mar resistance of the coated film.
- a carboxyl group-containing ethylenically unsaturated monomer obtained by subjecting a hydroxyl group- containing ethylenically unsaturated monomer and an acid anhydride group-containing compound to the half esterification reaction in an amount that a molar ratio of a hydroxyl group to an acid anhydride group becomes 1/0.5 to 1/1.0, preferably 1/0.8 to 1/1.0, can be used as the ethylenically unsaturated monomer having no acid anhydride group (a)(1) (2).
- the molar ratio is more than 1/0.5, viscosity of the polymer becomes high, which results in poor workability.
- the molar ratio is less than 1/1.0, the excessive acid anhydride group- containing compound remains in the resulting coated film, which results in poor water resistance.
- the hydroxyl group-containing ethylenically unsaturated monomer to be used herein preferably has 5 to 23 carbon atoms, more preferably 5 to 13 carbon atoms.
- a carbon chain of the monomer is too short, flexibility around a crosslinking point becomes poor, and the resulting coated film becomes too hard.
- the carbon chain is too long, a molecular weight between crosslinking points becomes too large.
- the hydroxyl group- containing ethylenically unsaturated monomer has a structure represented by the formula:
- R is a hydrogen atom or a methyl group
- X is an organic chain represented by the formula:
- R I [ - O - C H a- C H - ] wherever- wherein R is an hydrogen atom or a methyl group and n is an integer of 2 to 50.
- Examples thereof include 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate. 2-hydroxybutyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate, 6- hydroxyhexyl ( eth)acrylate. reaction products of these with ⁇ -caprolactone, and compounds prepared by esterifying (meth)acryllc acid with an excess amount of diols (e.g. 1,4- butanediol, 1,6-hexanediol, polyethylene glycol, polypropylene glycol, etc.).
- diols e.g. 1,4- butanediol, 1,6-hexanediol, polyethylene glycol, polypropylene glycol, etc.
- Examples of the acid anhydride group-containing compound to be used herein include phthalic anhydride, tetrahydrophthalic anhydride, hexahydrophthalic anhydride, 4-methylhexahydrophthalic anhydride, trimellltic anhydride, succinic anhydride, etc.
- the half esterification reaction between the hydroxyl group-containing ethylenically unsaturated monomer and acid anhydride group-containing compound is carried out at a temperature of room temperature to 150°C according to a method known to the art.
- the copolymerization between the acid anhydride group- containing ethylenically unsaturated monomer (a)(i)(l) and ethylenically unsaturated monomer having no acid anhydride group (a)(1) (2) is carried out by a known method such as solution polymerization (e.g. radical polymerization, etc.). For example, it can be carried out at a polymerization temperature of 100 to 200°C for a polymerization time of 3 to 8 hours under normal or applied pressure.
- an initiator there can be suitably used an azo or peroxide initiator.
- Other additives such as chain transfer agent, etc. can also be used.
- a number-average molecular weight of the resulting polymer is preferably 500 to 8000, more preferably 800 to 6000, particularly 1500 to 4000.
- the number-average molecular weight exceeds 8000, compatibility between the resins becomes poor, which results in poor appearance of the coated film.
- the number-average molecular weight is smaller than 500, curability of the resin composition becomes insufficient.
- the resulting polymer has at least two acid anhydride groups, preferably 2 to 15 acid anhydride groups, per molecule on an average. When the number of the acid anhydride groups per molecule Is smaller than 2, curability of the resin composition becomes insufficient. On the other hand, when it exceeds 15, the resulting coated film becomes too hard and brittle, which results in poor weather resistance.
- the resulting acrylic polyacid anhydride (a)(i) is reacted with a monoalcohol (a) (II) in a proportion so that a molar ratio of an acid anhydride group to a hydroxyl group becomes 1/10 to 1/1, preferably 1/5 to 1/1, more preferably 1/2.0 to 1/1 to prepare an acrylic polycarboxylic acid (a) having a carboxyl group and a carboxylate group.
- the molar ratio is smaller than 1/10, an amount of the excessive alcohol Is too large, which causes plnholes at the step of curing.
- the molar ratio exceeds 1/1, the excessive anhydride group remains in the resulting resin composition, and storage stability becomes poor.
- the monoalcohol (a)(li) which can be used in the present invention has 1 to 12 carbon atoms, particularly 1 to 8 carbon atoms. Such a monoalcohol evaporates when heating, and is convenient for regenerating an acid anhydride group.
- Examples of the preferred monoalcohol include those which have already been described. Particularly preferred examples include acetol, furfuryl alcohol, allyl alcohol, propargyl alcohol, ethanol and methanol.
- the resulting acrylic polycarboxylic acid (a) having a carboxyl group and a carboxylate group has an acid value of 5 to 300 mg KOH/g, preferably 50 to 250 mg KOH/g.
- the acid value Is smaller than 5 mg KOH/g curability of the resulting resin composition becomes insufficient.
- it exceeds 300 mg KOH/g storage stability becomes poor.
- An acrylic polycarboxylic acid (a) component can be contained in an amount of 10 to 70% by weight, preferably 15 to 50% by weight, more preferably 20 to 45% by weight, based on weight of the total solid contained in the curable resin composition.
- an amount of the acrylic carboxylic acid component (a) is smaller than 10% by weight, acid resistance of the resulting coated film becomes poor.
- it exceeds 70% by weight the coated film becomes too hard.
- a polyester polycarboxylic acid (b) to be used for the curable resin composition of the present invention is obtained by subjecting a polyester polyol having 3 or more hydroxyl groups and an acid anhydride group-containing compound to the half esterification reaction.
- polyester polyol means a polyhydric alcohol having 2 or more ester moiety.
- polyhydric alcohol means an alcohol having 2 or more hydroxyl groups.
- the polyester polyol to be used herein reacts with an acid anhydride group-containing compound, and provides a polyester polycarboxylic acid having 2 or more acid functional groups per molecule.
- the polyester polycarboxylic acid has the following characteristics.
- the polyester polyol is generally prepared by condensing a low-molecular weight polyhydric alcohol having 3 to 16 carbon atoms and having 3 or more hydroxyl groups, with a linear aliphatic dicarboxylic acid. As a result, a linear aliphatic group is introduced into the low-molecular weight polyhydric alcohol, thereby flexibility of the resulting coated films Is improved, and impact resistance is improved.
- Examples of the low-molecular weight polyhydric alcohol whlch can be used include trimethylolpropane, trimethylolethane, 1,2,4-butanetriol, ditrimethylolpropane, pentaerythritol, dipentaerythritol, glycerol and mixtures thereof.
- dicarboxylic acid examples include a dibasic acid such as phthalic acid, isophthalic acid, terephthalic acid, succlnlc acid, adlpic acid, azelalc acid, sebacic acid, tetrahydrophthallc acid, hexahydrophthalic acid, maleic acid and fumaric acid, and mixtures thereof.
- a dibasic acid such as phthalic acid, isophthalic acid, terephthalic acid, succlnlc acid, adlpic acid, azelalc acid, sebacic acid, tetrahydrophthallc acid, hexahydrophthalic acid, maleic acid and fumaric acid, and mixtures thereof.
- an acid anhydride group-containing compound such as succlnlc anhydride, phthalic anhydride, tetrahydrophthallc anhydride, hexahydrophthalic anhydride, hymic anhydride, trimellltic anhydride, methylcyclohexenetricarboxylic anhydride and pyromellitic anhydride, and mixtures thereof.
- a polyester ollgomer having comparatively low molecular weight is obtained by the procedure, and a high-solid resin composition may be provided.
- a polyester polyol which is particularly preferred to be used in the present invention is obtained by adding a lactone compound such as ⁇ -caprolactone to the low- molecular weight polyhydric alcohol, and extending a chain of the alcohol.
- the resulting polyester polyol has narrow molecular weight distribution, and it may provide a high- solid resin composition and a coated film having good weather resistance and water resistance.
- Examples of the low-molecular weight polyhydric alcohol which is preferably used include trimethylolpropane, di-trimethylolpropane, pentaerythritol, etc.
- lactone compound to be used in the present invention is a cyclic compound having an oxygen atom in the ring, and it reacts with a nucleophlllc reagent to open its ring and to form a terminal hydroxyl group.
- Preferred lactone compound has 4 to 7 carbon atoms, because It easily react to open its ring.
- Examples thereof include ⁇ -caprolactone, r - caprolactone, ⁇ -valerolactone, ⁇ 5 -valerolactone, r - butyrolactone, etc.
- ⁇ -caprolactone, 7 - valerolactone and 7 -butyrolactone are preferably used.
- the chain extension reaction can be carried out under the same condition as that of a conventional ring opening addition reaction.
- a chain extended polyester polyol Is derived from the low-molecular weight polyhydric alcohol, by reacting at a temperature of 80 to 200°C in the presence or absence of a suitable solvent for 5 hours or less.
- a tin compound catalyst and the like may also be use
- a molar amount of the lactone compound is 0.2- to 10- fold, preferably 0.25- to 5-fold, more preferably 0.3- to 3- fold, based on a molar amount of OH group of the low- molecular weight polyhydric alcohol.
- a molar amount of the lactone compound based on that of OH group Is smaller than 0.2-fold, the resin becomes hard, which results in poor impact resistance of the coated film.
- it exceeds 10-fold hardness of the coated film becomes poor.
- a polyester polycarboxylic acid (b) to be used for the curable resin composition of the present invention has an acid value of 50 to 350, preferably 100 to 300, more preferably 150 to 250 mg KOH/g (solid content), a number average-molecular weight of 400 to 3500, preferably 500 to 2500, more preferably 700 to 2000 and a ratio of weight- average molecular weight to number-average molecular weight of 1.8 or less, preferably 1.5 or less, more preferably 1.35 or less.
- the half esterification reaction between the polyester polyol and the acid anhydride group-containing compound can be carried out by using the acid anhydride group-containing compound such as phthalic anhydride, tetrahydrophthallc anhydride, hexahydrophthalic anhydride, 4- methylhexahydrophthalic anhydride, trimellltic anhydride, succinic anhydride, etc. under an ambient reaction condition such as room temperature to 150°C and normal pressure. It is not necessary to convert all hydroxyl groups of the polyester polyol Into carboxyl groups, but a part of the hydroxyl group may remains.
- the acid anhydride group-containing compound such as phthalic anhydride, tetrahydrophthallc anhydride, hexahydrophthalic anhydride, 4- methylhexahydrophthalic anhydride, trimellltic anhydride, succinic anhydride, etc.
- a polyester polycarboxylic acid having a hydroxyl group provides both a carboxyl group and a hydroxyl group on a surface of the coated film. Therefore, in case of recoating, it provides excellent adhesiveness, in comparison with a polyester polycarboxylic acid having no hydroxyl group.
- the polyester polycarboxylic acid (b) may have a hydroxyl value of not more than 150 mg KOH/g (solid content), preferably 5 to 100 mg KOH/g, more preferably 10 to 80 mg KOH/g. When the hydroxyl value exceeds 150 mg KOH/g, water resistance of the coated film becomes poor.
- polyester polycarboxylic acid having a hydroxyl group and a carboxyl group can react and bond with both polyepoxide (c) and acrylic polycarboxylic acid (a), and therefore, a strong coated film can be obtained.
- Those having 0.1 or more hydroxyl groups per molecule on an average are preferred.
- a molar amount of an acid anhydride group of the acid anhydride group-containing compound is 0.2- to 1.0-fold, particularly 0.5- to 0.9-fold based on a molar amount of OH group of the polyester polyol.
- curability of the resulting resin composition becomes poor.
- a polyester polycarboxylic acid (b) component can be contained in an amount of 5 to 70% by weight, preferably 5 to 50% by weight, more preferably 10 to 40% by weight, based on weight of the total solid contained in the curable resin composition.
- an amount of the polyester polycarboxylic acid is smaller than 5% by weight, solid content of the resin composition is not increased.
- it exceeds 70% by weight weather resistance of the coated film becomes poor.
- a polyepoxide (c) to be used for the curable resin composition of the present invention has 2 or more epoxy groups, preferably 2 to 10 epoxy groups, more preferably 3 to 8 epoxy groups per molecule on an average.
- Examples thereof include a glycidyl ether of a polyhydric alcohol and a glycidyl ester of a polybasic acid, such as glycerol trlglycidyl ether, trimethylolpropane triglycidyl ether, pentaerythritol tetraglycidyl ether, sorbltol hexaglycidyl ether, dlglycldyl hexahydrophthalate, etc .
- a number-average molecular weight of the polyepoxide is 200 to 10000, preferably 500 to 8000, more preferably 800 to 5000.
- a number-average molecular weight of the acrylic polyepoxide is smaller than 200, curability of the resulting coated film becomes poor.
- solid content of the resulting resin composition becomes low.
- an epoxy equivalent is 50 to 700, preferably 80 to 600, more preferably 100 to 500.
- curability of the resin composition becomes poor.
- the epoxy equivalent is smaller than the lower limit, the coated film becomes hard and brittle, and It is not preferred.
- a polyepoxide which is preferably used in the present invention is an acrylic polyepoxide obtained by copolymerizing 10 to 60% by weight, preferably 15 to 50% by weight of an epoxy group-containing ethylenically unsaturated monomer with 40 to 90% by weight, preferably 10 to 60% by weight of an ethylenically unsaturated monomer having no epoxy group.
- an amount of the epoxy group- containing ethylenically unsaturated monomer is smaller than 10% by weight, curability becomes poor.
- the amount is larger than 60% by weight, the coated film becomes too hard and weather resistance becomes poor.
- Examples of the epoxy group-containing ethylenically unsaturated monomer include glycidyl (meth)acrylate, ⁇ - methylglycidyl (meth)acrylate, 3,4-epoxycyclohexanyl (meth)acrylate, etc. It is preferred to use glycidyl (meth)acrylate so as to obtain a resin composition having good balanced curability and storage stability.
- Examples of the ethylenically unsaturated monomer having no epoxy group include those described above as the ethylenically unsaturated monomer having no acid anhydride group (a)(1) (2) which is used for preparing the acrylic polyacid anhydride (a)(i).
- the copolymerization can also be carried out according to the same manner as that described above.
- a number-average molecular weight of the acrylic polyepoxide is 500 to 10000, preferably 1000 to 8000, more preferably 1500 to 5000.
- a number-average molecular weight of the acrylic polyepoxide is smaller than 500, curability of the resulting coated film becomes poor.
- solid content of the resulting resin composition becomes low.
- an epoxy equivalent is 50 to 700, preferably 80 to 600, more preferably 100 to 500.
- curability of the resin composition becomes poor.
- the epoxy equivalent is smaller than the lower limit, the coated film becomes hard and brittle, and It is not preferred.
- the above-described hydroxyl group-containing ethylenically unsaturated monomer which is used for preparing the ethylenically unsaturated monomer having no acid anhydride group (a)(1) (2) can also be used as the ethylenically unsaturated monomer having no epoxy group.
- the acrylic polyepoxide having a hydroxyl group and a carboxylate group which is obtained by using the ethylenically unsaturated monomer having a hydroxyl group as the ethylenically unsaturated monomer having no epoxy group, reacts and bonds with an acrylic polycarboxylic acid (a) having a carboxyl group and a carboxylate group, in both functional groups (e.g. hydroxyl group and epoxy group), as described hereinafter. Therefore, a strong coated film can be obtained.
- a hydroxyl value of the resulting acrylic polyepoxide is 5 to 300 mg KOH/g, preferably 10 to 200 mg KOH/g, more preferably 15 to 150 mg KOH/g.
- the hydroxyl value exceeds 300, solid content of the resin composition is lowered and water resistance of the cured coated film becomes poor.
- it is smaller than 5 adhesiveness of the coated film becomes poor.
- Particularly preferred polyepoxide (c) to be used in the present invention is obtained by copolymerizlng
- R is a hydrogen atom or a methyl group
- X is an organic chain represented by the formula:
- the polyepoxide (c) having a hydroxyl group and an epoxy group has preferably 2 to 12 epoxy groups, more preferably 3 to 10 epoxy groups and 0.5 to 10 hydroxyl groups, more preferably 1 to 8 hydroxyl groups per molecule on an average.
- a polyepoxide (c) component can be contained in an amount of 10 to 80% by weight, preferably 20 to 70% by weight. more preferably 30 to 65% by weight, based on weight of the total solid contained in the curable resin composition.
- an amount of the polyepoxide is smaller than 10% by weight, curability of the resulting coated film becomes poor.
- it exceeds 70% by weight yellowing resistance of the coated film becomes poor.
- acrylic polycarboxylic acid (a) polyester polycarboxylic acid (b) and polyepoxide (c) were formulated to obtain a curable resin composition of the present invention.
- the formulation of the acrylic polycarboxylic acid (a) , polyester polycarboxylic acid (b) and polyepoxide (c) can be carried out according to an amount and a method known to those skilled in the art.
- an acrylic polycarboxylic acid having a carboxyl group and a carboxylate group as the acrylic polycarboxylic acid (a)
- a polyepoxide having a hydroxyl group and an epoxy group as the polyepoxide (c)
- there can be obtained a high- solid curable resin composition which forms a coated film having good acid resistance.
- a molar ratio of a carboxyl group contained In the acrylic polycarboxylic acid (a) and the polyester polycarboxylic acid (b) to an epoxy group contained in the polyepoxide (c) becomes 1/1.4 to 1/0.6, preferably 1/1.2 to 1/0.8, and a molar ratio of a carboxyl group or a carboxylate group which bonds to a carbon atom adjacent to a carbon atom bonding the carboxyl group contained in the acrylic polycarboxylic acid (a) to a hydroxyl group contained in the polyester polycarboxylic acid (b) and the polyepoxide (c) becomes 1/2.0 to 1/0.5, more preferably 1/1.5 to 1/0.7.
- Curing mechanism of a curable resin composition of the present invention is as follows. That is, a carboxyl group and a carboxylate group In the acrylic polycarboxylic acid (a) reacts together by heating, and form an acid anhydride group and a free monoalcohol in the acrylic polycarboxylic acid (a) . The monoalcohol evaporates and leaves from the system. The acid anhydride group formed in the acrylic polycarboxylic acid (a) reacts with a hydroxyl group contained in the polyester polycarboxylic acid (b) and the polyepoxide (c), and forms a crosslinking point and a carboxyl group again.
- a binder component such as silicone polymer can be optionally formulated in the curable resin composition of the present invention, because it is effective for increasing solid content of the resulting resin composition.
- a silicone polymer which can be used in the present invention is a silicone polymer having an epoxy group and/or an alkoxy group, which is represented by the formula:
- R 1 to R ⁇ independently represents a substituent selected from the group consisting of an alkyl group having 1 to 10 carbon atoms, a phenyl group having 1 to 10 carbon atoms, a phenethyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 5 carbon atoms and the group represented by the formulas: R T - S i ( 0 R ⁇ ) 3 , R ⁇ - S i ( 0 R ⁇ )a C H 3.
- R "7" represents a linear or branched alkylene group or a linear or branched alkylene group having an ether or ester moiety
- R ⁇ represents an alkyl group having 1 to 5 carbon atoms
- Y represents an aliphatic or cycloalkyl group having an epoxy group, provided that at least one of R 1 to R ⁇ is an alkoxy group and another at least one is epoxy group
- 1 represents an integer of 1 to 20
- m represents an integer of 0 to 4
- n represents an integer of 0 to 2.
- a sequence of each repeating unit constituting the silicone polymer may be arranged at random, and Is not limited to the order of the formula (II) .
- Examples of a silicone polymer having an epoxy group include “NUC Silicone” series manufactured by Nippon Unicar Co. , Ltd.
- Examples of a silicone polymer having an alkoxy group include “KC89-S” manufactured by Shin-Etsu Chemical Kogyo Co. , Ltd.
- Examples of a silicone polymer having an epoxy group and an alkoxy group include "MKC Silicate MSEP 2" series manufactured by Mitsubishi Chemical Co. , Ltd. and "NUC Silicone” series manufactured by Nippon Unicar Co. , Ltd.
- R 3 - 1 , R 2 and R 13 represent a hydrocarbon having up to 4 carbon atoms.
- epoxy equivalent means a weight in grams of a compound having 1 gram equivalent of an epoxy group.
- alkoxy equivalent means a weight in grams of a compound having 1 gram equivalent of an alkoxy group.
- hydroxyl equivalent means a weight in grams of a compound having 1 gram equivalent of a hydroxyl group.
- An epoxy equivalent of this silicone polymer is 100 to 1500, and an alkoxy equivalent is 50 to 1500.
- the epoxy equivalent Is less than 100. storage stability of the resin composition becomes poor.
- the epoxy equivalent exceeds 1500, curability becomes poor.
- a preferable range of the epoxy equivalent is 140 to 1000, more preferably 180 to 700.
- a preferable range of the alkoxy equivalent is 60 to 800, more preferably 80 to 500.
- the silicone polymer component having an epoxy group and an alkoxy group can be formulated in an amount of not more than 30% by weight, preferably 1 to 20% by weight, more preferably 3 to 15% by weight. When an amount of the silicone polymer component exceeds 30% by weight, storage stability of the resulting resin composition becomes poor.
- a silicone polymer having a hydroxyl group and a carboxyl group can be used together with or in place of the silicone polymer component having an epoxy group and/or an alkoxy group.
- the silicone polymer having a hydroxyl group and a carboxyl group is obtained by subjecting a silicone polymer having a hydroxyl group and an acid anhydride group-containing compound to the half esterification reaction.
- a number-average molecular weight of this silicone polymer is 500 to 6000, preferably 1000 to 4500.
- a hydroxyl value Is 2 to 120, preferably 10 to 80.
- An acid value is 20 to 180, preferably 35 to 150.
- a silicone polymer having a hydroxyl group is commercially available, and examples thereof include KR-2001 manufactured by Shin-Etsu Chemical Co., Ltd, NUC-Sillcone series manufactured by Nippon Unicar Co.. Ltd. , represented by the following formula:
- a silicone polymer having a hydroxyl group has 3 to 12 hydroxyl groups per molecule on an average.
- curability becomes poor.
- viscosity becomes high and it becomes difficult to increase a solid content of the resulting resin composition.
- the acid anhydride group-containing compound is half- esterifled by a hydroxyl group to provide a carboxy functional group, in an ambient reaction condition such as room temperature to 150°C under normal pressure. It is preferred to use an acid anhydride group-containing compound having 8 to 12 carbon atoms, which has a (unsaturated or saturated) cyclic group. Such a component may improves compatibility of the resulting resin.
- Examples of the preferred acid anhydride group- containing compound include hexahydrophthalic anhydride, phthalic anhydride, tetrahydrophthallc anhydride, 4-methyl hexahydrophthalic anhydride, trimellltic anhydride, etc.
- the half esterification reaction between the hydroxyl group-containing silicone polymer and the acid anhydride group-containing compound is carried out at a temperature of room temperature to 120 for 30 minutes to 8 hours according to a conventional procedure.
- a polyesterlfIcation reaction occurs and a high- molecular weight silicone polyester may be formed. Since such a high-molecular weight silicone polyester has small amount of functional groups and has high viscosity, It is not preferred to use in the present invention.
- a silicone polymer component having a hydroxyl group and a carboxyl group can be formulated in an amount of not more than 30% by weight, preferably 1 to 20% by weight, more preferably 3 to 15% by weight. When an amount of the sillcone polymer component exceeds 30% by weight, storage stability of the resulting resin composition becomes poor.
- a silicone polymer component having an epoxy group and an alkoxy group and a silicone polymer component having a hydroxyl group and a carboxyl group When used in combination, they can be formulated in an amount that the sum of them is not more than 30% by weight, preferably 1 to 20% by weight, more preferably 3 to 15% by weight based on weight of the total solid contained in the curable resin composition. When an amount of the silicone polymer component exceeds 30% by weight, storage stability of the resulting resin composition becomes poor.
- a curable resin composition of the present invention may contain a curing catalyst which is generally used for the esterification reaction between an acid and an epoxy, such as quaternary ammonium salts.
- a curing catalyst which is generally used for the esterification reaction between an acid and an epoxy, such as quaternary ammonium salts.
- the other catalyst which can be used for a curable resin composition of the present invention include benzyltriethylammonium chloride or bromide, tetrabutylammonium chloride, bromide, salicylate or glycolate, paratoluenesulfonate, etc. These curing catalysts may be used in combination thereof.
- a curing catalyst is generally used in an amount of 0.01 to 3.0 by weight, preferably 0.1 to 1.5% by weight, more preferably 0.4 to 1.2% by weight.
- an amount of the curing catalyst is smaller than 0.01% by weight, curability becomes poor.
- it exceeds 3.0% by weight storage stability becomes poor.
- a tin compound may be used in combination with these catalysts, as is described in Japanese Laid-Open Patent Publication Nos. 2-151651 and 2-279713.
- the tin catalyst include dimethyltin bis-(methyl maleate) , dimethyltin bis-(ethyl maleate), dimethyltin bis-(butyl maleate), dibutyltin bls-(butyl maleate), etc.
- the tin compound can be generally used in an amount of 0.05 to 6.0% by weight, preferably 0.1 to 4.0% by weight, more preferably 0.2 to 2.0% by weight.
- an amount of the tin compound Is smaller than 0.05% by weight, storage stability becomes poor. On the other hand, when it exceeds 6.0% by weight, weather resistance becomes poor.
- the weight ratio of the curing catalyst to the tin compound is 1/4 to 1/0.2.
- a blocked isocyanate may be added to a resin composition of the present invention.
- an ultraviolet absorber e.g. methanol, ethanol, propanol, butanol, etc.
- hydrocarbon and ester solvents may be used.
- crosslinked resin particles When the crosslinked resin particles are used, they are added in an amount of 0.01 to 10 parts by weight, preferably 0.1 to 5 parts by weight, based on 100 parts by weight of the resin solid of the curable resin composition of the present invention. When an amount of the crosslinked resin particles exceeds 10 parts by weight, appearance of the coated film becomes poor. On the other hand, when it is smaller than 0.01 parts by weight, no rheology controlling effect is obtained.
- a resin to be used in the present invention has an acid group as a functional group. Accordingly, it is also possible to prepare an aqueous resin composition comprising water as a medium by neutralizing the acid group with amine.
- the present invention also provides a coating composition comprising above-described curable resin composition as a binder component.
- a method for preparing the coating composition of the present invention is not specifically limited, and there can be used all methods which are known to those skilled in the art.
- a coating composition of the present invention can be coated by spray coating, brush coating, dip coating, roll coating, curtain coating, etc.
- a substrate may be optionally undercoated or intercoated.
- a known coating composition can be used for undercoating or intercoating the substrate.
- a coating composition of the present invention can be advantageously used for any substrate such as wood, metal, glass, fabric, plastic, foam, etc., particularly plastic and surface of metal such as steel, aluminum and alloys thereof.
- thickness of the coated film varies depending on the desired application. A film thickness of 0.5 to 3 mills is useful in almost all cases.
- High crosslinking density is formed by curing at 100 to 180°C, preferably 120 to 160°C.
- a curing time varies depending on a curing temperature used, but is usually for 10 to 30 minutes at 120 to 160°C.
- a coated film is provided according to the process which comprises the steps of: applying an water-based or solvent-based coating composition on an undercoated or intercoated substrate to form a base coating; applying the clear coating composition of claim 9 thereon to form a clear coating, without curing the base coating; and heating and curing both the base coating and clear coating.
- a high-solid content coating composition which is superior in acid rain resistance, mar resistance and appearance.
- reaction vessel was maintained at 130°C for 30 minutes, and an initiator solution consisting of 20 parts of t- butylperoxy-2-ethyl hexanoate and 20 parts of xylene was added dropwise over 30 minutes.
- an initiator solution consisting of 20 parts of t- butylperoxy-2-ethyl hexanoate and 20 parts of xylene was added dropwise over 30 minutes.
- the reaction was continued at 130°C for additional one hour and 1100 parts of solvent was removed to obtain a varnish having a nonvolatile content of 70%, which contains an acrylic polycarboxylic acid (a)-l having a number-average molecular weight of 1800 and an acid value of 156 mg KOH/g (solid content) .
- a monomer solution consisting of 300 parts of styrene, 109 parts of 2-ethylhexyl methacrylate, 325 parts of isobutyl acrylate, 26 parts of acrylic acid, 240 parts of maleic anhydride and 300 parts of propylene glycol monomethyl ether acetate, and an Initiator solution consisting of 150 parts of t-butylperoxy-2-ethyl hexanoate and 150 parts of xylene were added dropwise over 3 hours, respectively.
- reaction vessel was maintained at 130°C for 30 minutes, and an initiator solution consisting of 20 parts of t- butylperoxy-2-ethyl hexanoate and 20 parts of xylene were added dropwise over 30 minutes.
- an initiator solution consisting of 20 parts of t- butylperoxy-2-ethyl hexanoate and 20 parts of xylene were added dropwise over 30 minutes.
- the reaction was continued at 130°C for additional one hour and 1100 parts of solvent was removed to obtain a varnish having a nonvolatile content of 70%, which contains an acrylic polyacid anhydride (a)(1) having a number-average molecular weight of 2000.
- a varnish having a nonvolatile content of 75% which contains a polyester polycarboxylic acid (b)-6 having a number-average molecular weight of 1800, a ratio of weight-average molecular weight to number-average molecular weight of 1.25, an acid value of 192 mg KOH/g (solid content) and a hydroxyl value of 48 mg KOH/g (solid content) was obtained.
- reaction vessel When a temperature became 220°C, the reaction vessel was maintained at the temperature for one hour, and 30 parts of xylene as a reflux solvent was slowly added in the reaction vessel, and the condensation reaction was continued in the presence of the solvent. When an acid value of the resin reached 10.0, the reaction vessel was cooled to 150°C. Then, the reaction vessel was added 420 parts of phthalic anhydride, maintained at the temperature for one hour, and cooled to 100°C.
- a varnish having a nonvolatile content of 70% which contains a polyester polycarboxylic acid (b)-8 having a number-average molecular weight of 4200, a ratio of weight-average molecular weight to number-average molecular weight of 3.3 and an acid value of 115 mg KOH/g (solid content) .
- a monomer solution consisting of 450 parts of glycidyl methacrylate, 236 parts of isobornyl methacrylate, 64 parts of 4-hydroxybutyl acrylate and 250 parts of t-butylstyrene, and an initiator solution consisting of 110 parts of t-butylperoxy-2-ethyl hexanoate and 150 parts of xylene were added dropwise over 3 hours, respectively.
- reaction vessel was maintained at 130°C for 30 minutes, and an initiator solution consisting of 10 parts of t-butylperoxy-2-ethyl hexanoate and 50 parts of xylene was added dropwise over 30 minutes.
- a monomer solution consisting of 500 parts of glycidyl methacrylate, 250 parts of isobutyl methacrylate and 250 parts of t-butylstyrene, and an Initiator solution consisting of 120 parts of t-butylperoxy- 2-ethyl hexanoate and 140 parts of xylene were added dropwise over 3 hours, respectively.
- reaction vessel was maintained at 135°C for 30 minutes and an initiator solution consisting of 10 parts of t-butylperoxy-2-ethyl hexanoate and 50 parts of xylene were added dropwise over 30 minutes.
- a monomer solution consisting of 550 parts of 3,4-epoxycyclohexylmethyl methacrylate, 130 parts of isobornyl acrylate, 70 parts of 2-hydroxyethyl methacrylate and 250 parts of t-butylstyrene, and an initiator solution consisting of 110 parts of t-butylperoxy- 2-ethyl hexanoate and 150 parts of xylene were added dropwise over 3 hours, respectively.
- reaction vessel was maintained at 130°C for 30 minutes, and an initiator solution consisting of 10 parts of t-butylperoxy-2-ethyl hexanoate and 50 parts of xylene was added dropwise over 30 minutes.
- a monomer solution consisting of 200 parts of Veova 9, 300 parts of glycidyl methacrylate, 230 parts of 4-hydroxybutyl acrylate and 340 parts of cyclohexyl methacrylate. and an initiator solution consisting of 120 parts of t-butylperoxy-2-ethyl hexanoate and 200 parts of xylene were added dropwise over 3 hours, respectively.
- reaction vessel was maintained at 130°C for 30 minutes, and an initiator solution consisting of 10 parts of t-butylperoxy-2-ethyl hexanoate and 50 parts of xylene was added dropwise over 30 minutes.
- a monomer solution consisting of 355 parts of glycidyl methacrylate, 90 parts of isobutyl methacrylate, 250 parts of t-butylstyrene, 238 parts of 4- hydroxybutyl acrylate and 67 parts of 2-hydroxyethyl methacrylate, and an initiator solution consisting of 140 parts of t-butylperoxy-2-ethyl hexanoate and 100 parts of xylene were added dropwise over 3 hours, respectively.
- reaction vessel was maintained at 135°C for 30 minutes, and an initiator solution consisting of 10 parts of t-butylperoxy-2-ethyl hexanoate and 30 parts of xylene was added dropwise over 30 minutes.
- a monomer solution consisting of 300 parts of styrene, 120 parts of 2-ethylhexyl methacrylate, 369 parts of 2-ethylhexyl acrylate, 26 parts of acrylic acid, 185 parts of maleic anhydride and 300 parts of propylene glycol monomethyl ether acetate, and an initiator solution consisting of 100 parts of t-butylperoxy-2-ethyl hexanoate and 100 parts of xylene were added dropwise over 3 hours, respectively.
- reaction vessel was maintained at 130°C for 30 minutes, and an initiator solution consisting of 10 parts of t-butylperoxy-2-ethyl hexanoate and 60 parts of xylene was added dropwise over 30 minutes.
- a monomer solution consisting of 250 parts of styrene, 379 parts of glycidyl methacrylate, 243 parts of isobornyl methacrylate and 128 parts of 4- hydroxybutyl acrylate. and an initiator solution consisting of 110 parts of t-butylperoxy-2-ethyl hexanoate and 110 parts of xylene were added dropwise over 3 hours, respectively.
- reaction vessel was maintained at 126°C for 30 minutes, and an initiator solution consisting of 10 parts of t-butylperoxy-2-ethyl hexanoate and 20 parts of xylene was added dropwise over 30 minutes.
- reaction mixture was then cooled to 140°C, and added dropwise 500 parts of "Cardula E10” (versatic acid glycidyl ester manufactured by Shell Chemical Co.) over 30 minutes. Thereafter, the reaction was continued with stirring for 2 hours. An a photeric ionic group-containing polyester resin having an acid value (solid content) of 55, a hydroxyl value of 91 and a number-average molecular weight of 1250 was obtained.
- Xylene was added to the emulsion and water was removed by azeotropic distillation under reduced pressure to obtain a xylene solution of crosslinked resin particles having a solid content of 20% by weight.
- Preparation of clear coating composition According to the formulation shown in Table 3, the acrylic polycarboxylic acid (a)-l obtained in Synthetic Example 1, the polyester polycarboxylic acid (b)-l obtained in Synthetic Example 7, the polyepoxide (c)-l obtained in Synthetic Example 15, 0.5 parts of a tetrabutylammonium bromide curing catalyst, 0.5 parts of a dibutyltin bis- (butyl malate) curing catalyst, 2 parts of an ultraviolet absorber "Tinubin 900" manufactured by Ciba Geigy Co.
- Nonvolatile content (NV) of coating composition Viscosity of the coating composition was adjusted to 30 seconds at 20°C using a #4 Ford cup, 0.5 g of the coating composition was weighed precisely and diluted with 3 cc of toluene. The resulting coating composition was baked at 110°C for one hour, and nonvolatile content of the coating composition (% by weight) was determined.
- a coated test plate was prepared by coating a phosphated steel plate having a thickness of 0.8 mm with a cationic electrodeposition coating composition (Powertop U-50, manufactured by Nippon Paint Co., Ltd.) and an intermediate coating composition (Orga P-2, manufactured by Nippon Paint Co., Ltd.) so that a dry thickness became 25 and 40 / m, respectively.
- a cationic electrodeposition coating composition Powertop U-50, manufactured by Nippon Paint Co., Ltd.
- an intermediate coating composition Orga P-2, manufactured by Nippon Paint Co., Ltd.
- the coated test plate was then coated by air spraying with a solvent type high-solid base coating composition (manufactured by Nippon Paint Co., Ltd.) so that a dry thickness became about 16 ⁇ m, followed by setting for about 7 minutes to form a base coated film.
- a solvent type high-solid base coating composition manufactured by Nippon Paint Co., Ltd.
- the clear coating composition obtained was coated thereon using an electrodeposition coating device ("Auto Rea” , manufactured by Lansberg Gema Co.) at an atomizing pressure of 5 kg/cm 2 so that a dry thickness became about 40 u m, followed by setting for about 7 minutes and baking at 140°C for 25 minutes.
- an electrodeposition coating device (“Auto Rea” , manufactured by Lansberg Gema Co.) at an atomizing pressure of 5 kg/cm 2 so that a dry thickness became about 40 u m, followed by setting for about 7 minutes and baking at 140°C for 25 minutes.
- a formulation of the solvent type high-solid base coating composition is 20 parts of an acrylic resin (nonvolatile content 80%, hydroxyl value 100, acid value 30, number-average molecular weight 1800) manufactured by Nippon Paint Co. , Ltd. , 30 parts of a polyester (nonvolatile content 80%, hydroxyl value 100, acid value 12, number- average molecular weight 2600) manufactured by Nippon Paint Co., Ltd., 40 parts of a melamine resin "Cymel 202" (nonvolatile content 80%) manufactured by Mitsui Cytec Co. , Ltd. , 10 parts of a melamine resin "Cymel 327" (nonvolatile content 90%) manufactured by Mitsui Cytec Co. , Ltd. , "Alpaste Al 60-600” (nonvolatile content 65%) manufactured by Toyo Aluminum Co., Ltd. and 7 parts of isopropyl alcohol
- the coated film was dipped in tap water of 40°C for 10 days, and a surface of the coated film was visually evaluated according to the following criteria.
- ⁇ A trace is slightly recognized.
- x An abnormality is recognized on the coated film.
- a flannel fabric (2 x 2 cm) was coated with 1 g of 50% aqueous dispersion of a cleanser (abrasive 87%, surfactant 5%, etc, "Newfoaming Cleanser” manufactured by Kao Co., Ltd.).
- the coated flannel fabric was mounted on a sliding head of a Gakushln type rubbing testing machine for dyeing fastness (manufactured by Daiei Kagaku Seiki Co., Ltd.).
- the sliding head was loaded with 500 g weight and it was moved back and forth 20 times on the cured coated film, the 20° gloss of the rubbed surface was measured. A gloss retention (%) was calculated.
- the coated film was contacted with 0.5 ml of 1 wt% aqueous sulfuric acid at 75°C for 30 minutes. A surface of the coated film was visually evaluated according to the following criteria.
- a combination of irradiating the coated film with ultraviolet of 100 mW/cm 2 under a humidity of 70% at a black panel temperature of 63°C for 24 hours and storing it under a humidity of 100% at a black panel temperature of 50°C for 24 hours was repeated 5 times, by using an "Eye super UV tester SUV-W13" manufactured by Iwasaki Denki Co. , Ltd.
- a surface of the coated film was visually evaluated according to the following criteria.
- a surface of a plate coated with an intermediate coating composition was air sprayed with a high-solid base coating composition (manufactured by Nippon Paint Co., Ltd.) so that the dry thickness became about 16// m, followed by setting for about 7 minutes.
- a high-solid base coating composition manufactured by Nippon Paint Co., Ltd.
- the air sprayed coating was set about one minute and preheated at 80°C for 5 minutes.
- the respective resin components were mixed according to the formulations (solid content) shown in Tables 6 and 7 and viscosity was controlled to 30 seconds/#4 Ford cup to prepare a clear coating composition.
- the resulting coating composition was coated on the basecoated plate by using an electrodeposition coating device ("Auto Rea” , manufactured by Lansberg Gema Co.) at an atomizing pressure of 5 kg/cm 2 so that a dry thickness became about 40 m, followed by setting for about 7 minutes and baking at 160°C for 30 minutes.
- the resulting coated plate was left to stand in a desiccator for 30 minutes. Then, the high-solid base coating composition (manufactured by Nippon Paint Co., Ltd.) was coated and set according to the same manner as that described above and the clear coating composition was coated and set according to the same manner as that described above, followed by baking at 120°C for 30 minutes.
- the high-solid base coating composition manufactured by Nippon Paint Co., Ltd.
- Cross cuts (11 vertical cuts x 11 horizontal cuts at 2 mm In space) penetrating through the coated film to a foundation of the coated plate were formed on a surface of the coated film using a cutter knife (NT cutter, S or A type) to form 100 squares on the coated film.
- An adhesive tape (“cellophane tape” manufactured by Nichiban C, Ltd.) having a width of 24 mm was adhered uniformly on the crosscut coated film by hand so that no foam is formed. Immediately, the adhesive tape was rapidly peeled off from the surface of the coated film by pulling one end of the adhesive tape perpendicular to a surface of the coated film.
- Adhesiveness of the coated film were evaluated according to the criteria based on an area (%) of the coated film peeled off together with the adhesive tape.
- Example 15 "F-244-09" manufactured by Nippon Unicar Co., Ltd. was used as the silicone polymer (d)-l.
- R 1 is a methyl group
- R 3 , R 4 , R B and R ⁇ are a methyl group
- 1 is 6
- m is 2
- n 0.
- an epoxy equivalent is 318 and an alkoxy equivalent is 213.
- Example 19 "Denacol EX-314" (glycidyl ether type epoxy resin of glycerol, epoxy equivalent 145, manufactured by Nagase Kasei Kogyo Co., Ltd.) was used as the polyepoxide (c)-6.
- Example 7 According to the same manner as that described in Example 1 except for using a high-solid type melamine coating composition manufactured by Nippon Paint Co. , Ltd. , having the formulation shown in Table 5, a clear coated film was prepared and performances of the coated film were evaluated. The results are shown In Table 7.
- Ultraviolet absorber "Tinubin 900” 2 manufactured by Ciba Geigy Co., Ltd.
- Aromatic hydrocarbon solvent "Solvesso 100", 10 manufactured by Shell Chemical Co.
- a coated test plate was prepared by coating a phosphated steel plate having a thickness of 0.8 mm with a cationic electrodeposition coating composition (Powertop U-50, manufactured by Nippon Paint Co., Ltd.) and an intermediate coating composition (Orga P-2, manufactured by Nippon Paint Co., Ltd.) so that a dry thickness became 25 and 40 / _: m, respectively.
- the coated test plate was then coated with a water type base coating composition (Example 1 of U.S. Patent No. 5,183,504) so that a dry thickness became about 15 / . m, followed by setting at 80°C for 5 minutes to form a base coated film.
- the clear coating composition obtained was coated thereon using an electrodeposition coating device ("Auto Rea” , manufactured by Lansberg Gema Co.) at an atomizing pressure of 5 kg/cm 2 so that a dry thickness became about 40 rn , followed by setting for about 7 minutes and baking at 140°C for 25 minutes.
- an electrodeposition coating device (“Auto Rea” , manufactured by Lansberg Gema Co.) at an atomizing pressure of 5 kg/cm 2 so that a dry thickness became about 40 rn , followed by setting for about 7 minutes and baking at 140°C for 25 minutes.
- a formulation of the aqueous base coating composition is 56.2 parts of the acrylic resin varnish having a number-average molecular weight of 12000, a hydroxyl value of 70, an acid value of 58 and a nonvolatile content of 50% obtained in Preparation Example 1 of the same reference, 15.0 parts of methyled melamine "Cymel 303" (manufactured by Mitsui Cytec Co., Ltd.), 21.5 parts of an urethane emulsion having an acid value of 16.2 and a nonvolatile content of 33%, 7.5 parts of an aluminum pigment paste "Alpaste 7160N" having an aluminum flake content of 65% (manufactured by Toyo Aluminum Co., Ltd.) and 1.0 part of isostearic acid phosphate "Phosphorex A-180L” (manufactured by Sakai Kagaku Co., Ltd.).
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
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Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE69601214T DE69601214D1 (en) | 1995-01-24 | 1996-01-19 | CURABLE RESIN COMPOSITION, COATING COMPOSITION AND METHOD FOR PRODUCING A COATING FILM |
KR1019970705013A KR100336227B1 (en) | 1995-01-24 | 1996-01-19 | Curable resin composition, coating composition and method for forming coated film |
AU44587/96A AU699339B2 (en) | 1995-01-24 | 1996-01-19 | Curable resin composition, coating composition and method for forming coated film |
EP96900712A EP0805837B1 (en) | 1995-01-24 | 1996-01-19 | Curable resin composition, coating composition and method for forming coated film |
CA002211188A CA2211188C (en) | 1995-01-24 | 1996-01-19 | Curable resin composition, coating composition and method for forming coated film |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP910095 | 1995-01-24 | ||
JP7/9100 | 1995-01-24 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US08875175 A-371-Of-International | 1997-07-18 | ||
US09/450,719 Division US6410647B1 (en) | 1995-01-24 | 1999-11-30 | Composition of acrylic polycarboxylic acid, polyester polycarboxylic acid and polyepoxide |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996023033A1 true WO1996023033A1 (en) | 1996-08-01 |
Family
ID=11711212
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1996/000079 WO1996023033A1 (en) | 1995-01-24 | 1996-01-19 | Curable resin composition, coating composition and method for forming coated film |
Country Status (6)
Country | Link |
---|---|
US (2) | US6410647B1 (en) |
EP (1) | EP0805837B1 (en) |
KR (1) | KR100336227B1 (en) |
AU (1) | AU699339B2 (en) |
DE (1) | DE69601214D1 (en) |
WO (1) | WO1996023033A1 (en) |
Cited By (1)
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EP0921167A1 (en) * | 1996-08-22 | 1999-06-09 | Kaneka Corporation | Curable composition for top coating and articles coated using the same |
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KR20000011349A (en) * | 1998-07-01 | 2000-02-25 | 미우라 아끼라 | Photo-polymerizable composition for color filter |
ITMI20010259A1 (en) * | 2001-02-09 | 2002-08-09 | Lonza Spa | SOLID OXYDRYLATED CYCLOALIPHATIC EPOXY RESINS PROCEDURE FOR THE PREPARATION AND COMPOSITIONS OF COATED POWDER PAINTS |
JP2002294213A (en) * | 2001-03-30 | 2002-10-09 | Toyo Ink Mfg Co Ltd | Surface modifier |
US20040242806A1 (en) * | 2001-09-20 | 2004-12-02 | Hideyuki Yamada | Curable resin composition |
US7384881B2 (en) * | 2002-08-16 | 2008-06-10 | H.B. Fuller Licensing & Financing, Inc. | Aqueous formaldehyde-free composition and fiberglass insulation including the same |
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DE102004016479B4 (en) * | 2004-03-31 | 2007-03-15 | Byk-Chemie Gmbh | Use of polyesters as dispersants and polyester-containing masterbatches |
US7435600B2 (en) * | 2004-06-23 | 2008-10-14 | Johns Manville | Infrared methods of measuring the extent of cure of a binder in fibrous products |
DE102004054499A1 (en) * | 2004-11-11 | 2006-05-18 | Bayer Materialscience Ag | Polyester-polyacrylate dispersions with reactive diluents based on lactone-containing compounds |
DE102004054500A1 (en) * | 2004-11-11 | 2006-05-18 | Bayer Materialscience Ag | Polyester-polyacrylate dispersions with reactive diluents based on hydroxy-functional esters |
US20060233955A1 (en) * | 2005-04-14 | 2006-10-19 | Noel Smith | Process for the coating of metallic components with an aqueous organic composition |
DE102006025006A1 (en) * | 2006-05-30 | 2007-12-06 | Bayer Materialscience Ag | Aqueous copolymer dispersion with improved blocking resistance |
US7737238B2 (en) * | 2008-03-04 | 2010-06-15 | Anderson Development Co. | Resin suitable for powder coating compositions |
US8080488B2 (en) * | 2008-03-10 | 2011-12-20 | H. B. Fuller Company | Wound glass filament webs that include formaldehyde-free binder compositions, and methods of making and appliances including the same |
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JP2013175546A (en) * | 2012-02-24 | 2013-09-05 | Dexerials Corp | Underfill material, and method of manufacturing semiconductor device using the same |
JP5826079B2 (en) * | 2012-03-16 | 2015-12-02 | 日本ペイント・オートモーティブコーティングス株式会社 | Jet black multilayer coating film and method for forming the same |
US8791198B2 (en) | 2012-04-30 | 2014-07-29 | H.B. Fuller Company | Curable aqueous composition |
US9416294B2 (en) | 2012-04-30 | 2016-08-16 | H.B. Fuller Company | Curable epoxide containing formaldehyde-free compositions, articles including the same, and methods of using the same |
JP7551666B2 (en) * | 2019-07-02 | 2024-09-17 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | 2K clearcoat composition, its preparation and method of use |
WO2021067693A1 (en) * | 2019-10-04 | 2021-04-08 | Ecovia Renewables, Inc. | Water-absorbent cross-linked polymeric polycarboxylic acid and methods of making |
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WO1995028452A1 (en) * | 1994-04-19 | 1995-10-26 | Nippon Paint Co., Ltd. | Curable resin composition, coating composition, coating method and coated article |
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- 1996-01-19 KR KR1019970705013A patent/KR100336227B1/en not_active IP Right Cessation
- 1996-01-19 EP EP96900712A patent/EP0805837B1/en not_active Expired - Lifetime
- 1996-01-19 AU AU44587/96A patent/AU699339B2/en not_active Expired
- 1996-01-19 DE DE69601214T patent/DE69601214D1/en not_active Expired - Lifetime
- 1996-01-19 WO PCT/JP1996/000079 patent/WO1996023033A1/en active IP Right Grant
-
1999
- 1999-11-30 US US09/450,719 patent/US6410647B1/en not_active Expired - Lifetime
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2002
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EP0588560A2 (en) * | 1992-09-09 | 1994-03-23 | Nippon Paint Co., Ltd. | A curable resin composition, a coating composition and a process for forming a coating film |
WO1995028452A1 (en) * | 1994-04-19 | 1995-10-26 | Nippon Paint Co., Ltd. | Curable resin composition, coating composition, coating method and coated article |
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EP0921167A4 (en) * | 1996-08-22 | 2000-01-12 | Kaneka Corp | Curable composition for top coating and articles coated using the same |
US6265073B1 (en) | 1996-08-22 | 2001-07-24 | Kaneka Corporation | Curable composition for top coating and articles coated using the same |
Also Published As
Publication number | Publication date |
---|---|
EP0805837A1 (en) | 1997-11-12 |
EP0805837B1 (en) | 1998-12-23 |
US6656531B2 (en) | 2003-12-02 |
US6410647B1 (en) | 2002-06-25 |
KR100336227B1 (en) | 2002-06-20 |
DE69601214D1 (en) | 1999-02-04 |
US20020161121A1 (en) | 2002-10-31 |
KR19980701619A (en) | 1998-06-25 |
AU4458796A (en) | 1996-08-14 |
AU699339B2 (en) | 1998-12-03 |
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