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WO1996014824A1 - Hair-regenerating preparations - Google Patents

Hair-regenerating preparations

Info

Publication number
WO1996014824A1
WO1996014824A1 PCT/EP1995/004281 EP9504281W WO9614824A1 WO 1996014824 A1 WO1996014824 A1 WO 1996014824A1 EP 9504281 W EP9504281 W EP 9504281W WO 9614824 A1 WO9614824 A1 WO 9614824A1
Authority
WO
Grant status
Application
Patent type
Prior art keywords
hair
alkyl
preparations
acid
preferred
Prior art date
Application number
PCT/EP1995/004281
Other languages
German (de)
French (fr)
Inventor
Detlef Hollenberg
Kurt Seidel
Dieter Goddinger
Christian Priebe
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toilet preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42Amides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
    • A61K8/00Cosmetics or similar toilet preparations
    • A61K8/18Cosmetics or similar toilet preparations characterised by the composition
    • A61K8/30Cosmetics or similar toilet preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILET PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/06Preparations for styling the hair, e.g. by temporary shaping or colouring

Abstract

Described are preparations containing an active-substance complex made from a cationic derivative of panthenol and a carbohydrate, such preparations having a significant regenerative effect on split hairs. This action can be increased by the addition of non-ionic or anionic polymers.

Description

"Haarreαenerierende Zubereitunαen"

The invention relates to hair cosmetic preparations containing a special combination of active ingredients haarregenerierende.

The human hair is nowadays treated in diverse ways with haarkosme--Nazi preparations. This includes, for example, cleaning the hair with shampoos and shower preparations and bleaching, coloring and shaping of hair with corrugated itteln, th tints and Stylingpräpara¬. As a result, almost all hair treatments can cause unwanted Beein¬ trächtigungen the hair structure come. These impairments show, among other things in a bad wet and Trockenkäm availability, a verstärk¬ th electrostatic charge, increased brittleness and in gravie¬ renderers cases in gesplißten, ie split hair (end) s. This ver¬ deteriorated not only the external appearance of the hairstyle, but ins¬ particular the split ends should be counteracted also due to hair health.

One known way to alleviate these ills is to subject the hair to a post-treatment with appropriate drugs, mostly cationic surfactants, which are optionally combined with other substances.

However, this procedure is not satisfactory in a number of points.

It is known that cationic surfactants are good only for the treatment of non-oily hair; its application to quickly nachfettendem hair is problematic, however, as they weigh the hair in addition to and improve the natural regreasing of hair.

remains unsatisfactory that treatment with cationic surfactants usually in a separate step, typically a rinse, must be followed by ER, as these cationic Tens de often not gen in Zubereitun¬ with anionic surfactants such las¬ example incorporate shampoos sen.

Alternatively, the path was followed to supply special haarregenerierende active ingredients to the hair, in particular to combat split ends. According to German Offenlegungsschrift 37 11 841, the combination of panthenol drawing with a mono- or disaccharide through a strong, haar¬ from regenerating effect even if they remain on the hair for a short time.

From the PCT publication WO 92/13829 is finally known that quaternized panthenol are characterized by an increased substantivity to the hair and to counteract, inter alia, caused by the ridges split ends.

It has now surprisingly been found that the regeneration gesplißter hair can be achieved in a very large scale if the gesplißten hair is treated with preparations containing certain carbohydrates in addition to a quaternized panthenol derivatives.

The invention thus relates to compositions for the treatment of keratinized shear fibers, in particular human hair, characterized in that it consists of (A) a cationically deriva- vatisierten panthenol and (B) a carbohydrate selected from monosaccharides charides an active ingredient combination, oligosaccharides, on- and uronic acids (sugar acids), bring Zuckeralko¬ containing glycosides and quaternized monosaccharides.

Preferred cationically derivatized panthenols (A) are compounds of formula (I),

wherein R, R and R2 are independently an alkyl group having 1-24 carbon atoms or an alkenyl group having 8-24 carbon atoms, 3 for an alkylene group having 1-18 carbon atoms, Y is monovalent for an OH group or hydrogen and X is an , organic or anorgani¬ ULTRASONIC anion.

those compounds according to formula (I) in which R is an alkyl or alkenyl group having 8-24 carbon atoms are preferred. Such alkyl or alkenyl groups are, for example, lauryl, myristyl, cetyl, stearyl and oleyl groups. R 1 and R 2 are preferably alkyl groups having 1-4 carbon atoms, especially methyl groups. R3 is preferably a kür¬ zere alkylene group having 1-4 carbon atoms, in particular a methylene group. Y is, due to manufacturing, preferably a hydroxy group, X is a halide ion, in particular chloride.

Information regarding the preparation of these panthenol derivatives of the cited document WO 92/13829 can be found, which is expressly incorporated herein by reference. A similar product is sold by Tri-K under the name PANTHEQUAT R.

The cationically derivatized panthenols are present in the inventive preparations preferably in an amount of 0.05 to 10 wt .-%, insbeson particular from 0.05 to 5% by weight, based on the preparation as a whole.

When carbohydrates (B) according to the invention Both monosaccharides and oligosaccharides such as cane sugar, lactose and raffinose, can be used. The use of monosaccharides is preferred. Among the monosaccharides, such compounds are again preferred which contain 5 or 6 carbon atoms. Suitable pentoses and hexoses, for example, ribose, arabinose, xylose, lyxose, allose, altrose, glucose, mannose, gulose, idose, galactose, talose and fructose. Arabinose, glucose, galactose and fructose are carbohydrates vorzugt used; Glucose is especially preferred.

Furthermore, derivatives of these pentoses and hexoses, such as the onic and uronic ent speaking can (sugar acids), sugar alcohols and glyco- side, are used according to the invention. Preferred sugar acids are gluconic acid, glucuronic acid, saccharic acid, mannosaccharic acid and mucic acid. Preferred sugar alcohols are sorbitol, mannitol and dulcitol. Preferred glycosides are the methyl glucosides.

Quaternized carbohydrates may also be used erf ndungsgemäß as component (B). The commercial product GlucquatRlOO (corresponding to the CTFA name: Lauryl Methyl Gluceth-10 Hydroxypropyl Dimonium Chlo¬ ride) is a preferred quate ned carbohydrate.

Since the carbohydrates used are usually obtained from natural raw materials such as starch, carbohydrates have the die¬ sen raw materials corresponding configurations (for example, D-glucose, D-tose Fruc- and D-galactose) in the rule.

The carbohydrates are present in the inventive preparations preferably in an amount of 0.1 to 10 wt .-%, in particular from 0.1 to 5% by weight, bezo¬ gene on the preparation as a whole.

Furthermore, it was found that certain classes of polymers whose representatives even in combination with panthenol derivatives have no gesteiger¬ th haarregenerierenden properties haarregenerierende effect in the agents in a synergistic manner like stei¬ or no.

In these polymer classes is the nonionic and anionic polymers.

Suitable nonionic polymers are, for example: polyvinyl pyrrolidones, as for example under the name Luviskol® (BASF). Polyvinylpyrrolidones are bevor¬ ferred nonionic polymers within the scope of the invention.

Vinylpyrrolidone / Vinylester copolymers, such as for example, under the trade name Luviskol® (BASF). Lüviskol R VA 64 and Luviskol VA 73, each vinylpyrrolidone / vinyl acetate copolymers, are also preferred nonionic polymers.

Cellulose ethers such as hydroxypropyl cellulose, hydroxyethyl cellulose and methylhydroxypropyl cellulose as Culminal R and Benecel R (AQUALON) are sold for example under the Waren¬ sign.

shellac

Examples of suitable anionic polymers according to the invention are:

Polyacrylic and polymethacrylic acids, salts thereof, copolymers thereof wer¬ with acrylic and methacrylic esters and amides and their derivatives obtained by crosslinking with polyfunctional agents to. Compounds of this type are, for example, under the Bezeich¬ voltages Carbopol® 934, Carbopol® 934P, Carbopol® 940 (Carbopol EDT 2001), Carbopol 941 (Carbopol EDT R 2050), Carbopol® 950, Carbopol® 980, Carbopol® 981, Carbopol EDT R 2020 and R Hostacerin PN 73 available.

Copolymers of acrylic acid and / or methacrylic acid or their esters with Cιo-30 alkyl acrylates, such as are sold for example under the name Pemulen R.

Polyoxycarboxylic as Polyketo- and polyaldehydocarboxylic acids and salts thereof, such as P0C R HS 5060 and P0C R AS5060.

Polymers and copolymers of crotonic acid with esters and amides of acrylic and methacrylic acid, such as vinyl acetate-crotonic acid and vinyl acetate-vinyl propionate-crotonic acid copolymers. Compounds of this type are available under the trade designations Resyn R (National Starch), Luviset R (BASF) and Gafset R (GAF); the products Luviset.RTM R CA-66 and R Luviset.RTM CAP may be particularly preferred.

Vinylpyrrolidone / vinyl acrylate copolymers, obtainable for example under the trade name Luviflex R (BASF). A preferred polymer is the VBM-35 (BASF) under the name Luviflex R available vinyl pyrrole don / acrylate terpolymers.

Acrylic acid / ethyl acrylate / N-tert-butylacrylamide terpolymers spielsweise under the name Ultrahold R strong (BASF), as well as methacrylic acid / ethyl acrylate / t-butyl acrylate terpolymer that sold under the name Luvimer R 100P (BASF) become.

These nonionic or anionic polymers are preferably used in an amount of 0.01 to 5 wt .-%, in particular from 0.1 to 2% by weight based on the total preparation.

Furthermore, preparations of the invention surfactants, especially nonionic surfactants. Non-ionic surfactants contain as hydrophilic group, for. For example, a polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether. Such compounds are for example

Addition products of 2 to 30 mol ethylene oxide and / or 0 to 5 mol propylene oxide onto linear fatty alcohols containing 8 to 22 carbon atoms to fatty acids having 12 to 22 carbon atoms and with alkylphenols having 8 to 15 C-Ato¬ men in the alkyl group,

2 -C 2 2- fatty acid mono - un d diesters of addition products of 1 to 30 mol ethylene oxide onto glycerol,

Addition products of 5 to 60 mol ethylene oxide onto castor oil and hydrogenated castor oil. Methylglucosedifettsäureester etherified with oligoglycerol.

Particularly preferred nonionic surfactants are the alkyl polyglycosides of the general formula R0 (Z) x. These compounds are characterized by the following parameters. The alkyl group R contains 6 to 22 carbon atoms and may be both linear and branched. primary linear and methyl-branched in the 2-position, aliphatic radicals are preferred. Such alkyl radicals are, for example, 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and 1-stearyl. Especially preferred are 1-octyl, 1-decyl, 1-lauryl, 1-myristyl. When using so¬ called "oxo-alcohols" as starting materials, compounds with an odd number of carbon atoms in the alkyl chain.

The inventive alkyl glycosides used contain only one specific alkyl residue R. These compounds are normally but starting oils from natural fats and or provide herge¬ mineral oils. In this case, the alkyl radicals R are mixtures corresponding to the starting compounds or to the particular working of these compounds.

And Ci4 alkyl groups essentially of CSS to Ci5 alkyl groups or consists essentially of Cι 2 - - to C j ß Particularly preferred alkyl polyglycosides are those in which R consists essentially of Cg and CIQ alkyl groups essentially of Cι 2 are alkyl groups there.

Sugar building blocks Z Any mono- or oligosaccharides can be set einge¬. Usually, sugars having 5 or 6 carbon atoms and the corresponding oligosaccharides are used. Such sugars are, for example, glucose, fructose, galactose, arabinose, ribose, xylose, lyxose, allose, altrose, mannose, gulose, idose, talose and sucrose. Be¬ ferred sugar units are glucose, fructose, galactose, arabinose and sucrose; Glucose is especially preferred.

The invention polyglycosides usable contained in section

1.1 to 5 sugar units. Alkyl glycosides with x-values ​​of 1.1 to 1.6 are preferred. Very particular preference is given to alkyl glycosides in which x is 1.1 to 1.4.

The alkoxylated homologs of the specified alkyl polyglycosides can also be used according to the invention. These homologs may contain on average up to 10 ethylene oxide and / or propylene oxide units per alkyl glycoside unit.

When used as surfactants compounds with alkyl groups may be single compounds. However, it is preferred in the gel Re¬ to proceed in the preparation of these substances from native vegetable or animal raw materials so that mixtures with terschiedlichen un¬ holds depending on the raw er¬ alkyl chain lengths.

The surfactants which are addition products of ethylene and / or propylene oxide of these addition products with fatty alcohols or derivatives represent, both products having a "normal" homologue distribution or those may be used with a narrow HomologenVerte lung. Under "normal" homolog distribution are mixtures of homologs were ver¬ doing that you koholaten in the reaction of fatty alcohol and alkylene oxide using alkali metals, alkali metal hydroxides or Alkalimetallal- receives as catalysts. Narrowed homolog distributions wer¬ the contrast, obtained if hydrotalcite, alkaline earth metal salts of ether carboxylic acids, alkaline earth metal oxides, hydroxides or alcoholates -alcohol are used as catalysts. The use of products with a narrow homolog distribution may be preferred.

Preferably, the preparations erf ndungsgemäßen surfactants in Men¬ gene of 0.2 to 20 wt .-%, based on the particular preparation.

The other constituents of hair treatment compositions according to the invention depend on the type of hair treatment agent. In principle, the inventive formulations include all known types of hair treatment agents such as hair shampoos, hair rinses, hair conditioning edium, hair treatments, setting lotions, hair sprays, setting lotions, permanent wave agents and Haar¬ dyes. Hair treatments are a preferred form of the inventive compositions.

Preferred hair treatment composition according to the invention are generally those which remain on the hair after application. However, it may also be preferred in special cases, to formulate compositions of the invention in the form of so-called rinse-off products.

Further components of the compositions of the invention can be, for example: anionic surfactants, such as Fettalkylsulfate- and -ether- sulfates and alkyl ether carboxylic acids, zwitterionic surfactants, such as betaines, ampholytic surfactants, structurants, such as maleic acid, hair-conditioning compounds, such as phospholipids, for example soya lecithin, egg lecithin and cephalins, and silicone oils, protein hydrolysates, in particular elastin, collagen, keratin, Milch¬ in protein, soy protein and wheat, their condensation products with fatty acids and quaternized protein hydrolysates, perfume oils, dimethyl isosorbide and cyclodextrins,

Solubilizers, such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol, dyes,

Antidandruff active ingredients such as piroctone olamine and zinc Omadine, further substances for adjusting the pH,

Active ingredients such as panthenol, allantoin, pyrrolidone and salts thereof, plant extracts and vitamins, light stabilizers,

Thickeners like Zuckerester, polyol esters or polyol, fats and waxes, such as spermaceti, beeswax, montan wax, paraffins and fatty alcohols, fatty acid,

Complexing agents such as EDTA, NTA and phosphonic acids,

Swelling and penetration substances, such as glycerol, Propylenglykolmonoethyl- ether, carbonates, hydrogen carbonates, guanidines, ureas and pri¬ mare, secondary and tertiary phosphates, opacifiers, such as latex,

Pearlescent agents such as ethylene glycol mono- and distearate, propellants such as propane-butane mixtures, N 2 0, dimethyl ether, C0 2 and air as well as antioxidants, direct dyes, so-called coupler and developer components as oxidation dye precursors,

Reducing agent such as thioglycolic acid and derivatives thereof, thio lactic acid, cysteamine, thiomalic acid and α-mercaptoethanesulfonic acid,

Oxidation edium such as hydrogen peroxide, potassium bromate and Natriumbro- mat.

The invention also provides the use of the inventive compositions for treating keratin fibers, in particular hair.

The invention is also a method of treating hair in which a preparation according to the invention is applied to the hair and remains there.

The invention finally also provides a method for treating hair in which a formulation of the invention introduced aufge¬ to the hair and, after a contact time (1 to 40 minutes) again is rinsed.

The following examples illustrate the invention.

EXAMPLES I. Antisplißwirkung

Each 20 gesplißte hairs were immersed lauryl ether sulfate solution for 5 minutes in a 12.5% ​​sodium and rinsed with lukewarm water. Subsequently, the hair for 5 minutes were kept in the sample preparations, dried for 30 minutes at 60 ° C in a circulating air drying cabinet. This procedure was repeated 5 times and the hair then at Raumtempera¬ structure (65% rel. Humidity) was investigated. The compositions of the test formulations and the Splißraten after 5 treatments are summarized in Table 1 below.

Table 1: [all amounts in wt .-%]

VI V2 V3 V4 Bl B2

components

Panthequat R 1 1.0 - - 1.0 1.0 1.0

Glucose - 0.3 - - 0.3 0.3

Luviskol® K 30 2 - - 0.1 0.1 - 0.1

Ethanol 7.0 7.0 7.0 7.0 7.0 7.0

Water - to 100 -

Splißrate [%] 55 100 100 60 30 5

1 cationic panthenol derivative (45% active substance; CTFA name: Panthenyl Hydroxypropylsteardimoniumchloride) (TRI-K Industries)

2 Polyvinyl pyrrolidone (95% active ingredient, remainder water) (BASF). II. Applications

The quantities given in the following examples are wt .-%.

1) leave-on hair treatment

Panthequat R 1.2

glucose 0.3

R Luviquat FC 550 3 0.6

Luviskol® K 90 4 0.4

ethanol 8.0

Water to 100

Vinylimidazoliniummethochlorid / vinyl pyrrolidone copolymer (50:50) (average molecular weight: about 80,000 daltons; 40% active substance; CTFA name: Polyquaternium-16) (BASF) Polyvinylpyrrolidone (95% active substance; CTFA name: PVP) (BASF)

2) leave-on hair treatment

Panthequat R 0.6

sucrose 0.7

shellac 0.8

Merquat R 280 5 0.4

sorbitol 0.5

ethanol 25.0

Water to 100

Dimethyl diallyl ammonium chloride-acrylic acid copolymer (about 40% active substance in water; CTFA name: Polyquaternium 22) (CHEMVIR0N) 3) Shampoo

Texapon R N 28 6 48.0

Plantaren 2000 UP R 7 10.0

Dehyton R κ8 8.0

Panthequat R 3.0

lactose 4.0

Luviskol® VA 649 1.5

NaCl 0.9

benzoic 0.45

Citric acid to pH 4.7

Wassser ad 100

Lauryl ether sulfate, sodium salt (28% active substance; CTFA name: Sodium Laureth Sulfate (HENKEL)

CSS IOE fatty alcohol-l ^ glucoside (ca 53% active substance; CTFA name: decyl polyglucose) (HENKEL)

Fatty acid amide derivative of betaine structure with the formula R- C0NH (CH2) 3N + (CH3) 2 CH2 C00- (ca. 30% active substance; CTFA name Cocoa idopropyl Betaine) (HENKEL)

Vinylpyrrolidone-vinyl acetate copolymer (60:40) (CTFA name: PVP-VA copolymer) (BASF)

4) Haarfestiger

Carbopol ETD 2001 10 0.65 R

Panthequat 2.0

Luviskol® K 30 2.0

glucose 2.0

Dow Corning 345 * - * 0.4

Cremophor R RH 40 12 0.8

ethanol 10.0

NaOH to pH 6.7

Water ad 100 crosslinked polyacrylic acid (CTFA name: Carbomer) (Goodrich), decamethylcyclopentasiloxane (CTFA name: Cyclomethicone)

(DOW CORNING) castor oil, hydrogenated + 45 ethylene oxide (CTFA name: PEG-40

Hydrogenated Castor Oil) (BASF)

Claims

claims
Preparations for the treatment of keratinous fibers, especially human hair, characterized in that it comprises an active substance combination consisting of
(A) a cationically derivatized panthenol and
(B) a carbohydrate selected from
- monosaccharides,
- oligosaccharides,
- on- and uronic acids (sugar acids),
- sugar alcohols,
- glycosides and
- contain quaternized monosaccharides.
Preparations according to Claim 1, characterized in that the katio¬ nisch deri ated panthenol (A) a compound of formula (I) is
atoms in the R, R and R2 are independently an alkyl group having 1-24 carbon atoms or an alkenyl group having 8-24 Kohlenstoff¬, R 3 represents an alkylene group having 1-18 carbon atoms, Y represents an OH group or hydrogen and X is a monovalent, orga African or inorganic anion.
Preparations according to Claim 2, characterized in that (A) is a compound of formula (I) in which R is an alkyl or alkenyl group having 8-24 carbon atoms, R 1 and R 2 are methyl groups and R 3 is an alkylene group having 1- 4 carbon atoms, Y is a hydroxy group and X is a halide ion.
4. Preparations according to any one of claims 1 to 3, characterized gekennzeich¬ net, that the carbohydrate (B) is a mono- or disaccharide.
5. Preparations according to claim 1, characterized in that the carbohydrate (B) 5 or 6 carbon atoms contains.
Preparations according to claim 5, characterized in that the carbohydrate (B) is glucose.
Preparations according to one of claims 1 to 6, characterized gekennzeich¬ net, that they additionally contain a non-ionic or anionic polymer.
8. Preparations according to claim 7, characterized in that the Poly mers is nonionic.
9. Preparations as claimed in claim 8, characterized in that the nicht¬ ionic polymer is a homo- or copolymer of vinylpyrrolidone.
10. Preparations according to one of claims 1 to 9, characterized gekennzeich¬ net, that the component (A) in an amount of 0.05 to 10 wt .-%, in particular 0.05 to 5% by weight, based on the total , is preparation.
11. Preparations according to one of claims 1 to 10, characterized gekennzeich¬ net, that component (B) in an amount of 0.1 to 10 wt .-%, in particular 0.1 to 5% by weight based on the entire , is preparation.
12. Preparations according to one of claims 7 to 11, characterized gekennzeich¬ net, that the polymer in an amount of 0.01 to 5 wt .-%, insbeson particular 0.1 to 2% by weight based on the total preparation is included.
13. A method for treatment of hair, characterized in that a preparation according to any one of claims 1 to 12 applied to the hair and remains there.
14. A method for treatment of hair, characterized in that a preparation according to any one of claims 1 to 12 applied to the hair and is rinsed out again after a contact time.
PCT/EP1995/004281 1994-11-11 1995-11-02 Hair-regenerating preparations WO1996014824A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DEP4440315.1 1994-11-11
DE19944440315 DE4440315A1 (en) 1994-11-11 1994-11-11 Haarregenerierende preparations

Publications (1)

Publication Number Publication Date
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999013821A1 (en) * 1997-09-13 1999-03-25 Henkel Kommanditgesellschaft Auf Aktien Hair conditioners for treating split ends

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19615145A1 (en) * 1996-04-18 1997-10-23 Henkel Kgaa A method and means for simultaneously dyeing and care of keratin fibers
DE19720366A1 (en) * 1997-05-15 1998-11-19 Wella Ag Hair cleaner with gloss-enhancing properties
DE19721411A1 (en) * 1997-05-22 1998-11-26 Beiersdorf Ag Use of carbohydrate compounds or carbohydrate derivatives
DE19737604C5 (en) * 1997-08-28 2008-02-07 Kao Corp. Use of a composition as a shampoo
DE19810598A1 (en) * 1998-03-12 1999-09-23 Braun Gmbh Hair treatment device which allows a treatment agent to be applied
US6800302B2 (en) 2001-03-30 2004-10-05 L'oreal S.A. Heat activated durable styling compositions comprising C1 to C22 Substituted C3-C5 monosaccharides and methods for same

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1987003196A1 (en) * 1985-11-22 1987-06-04 Agave Cosmetics Proprietary Limited Hair treatment
EP0287876A1 (en) * 1987-04-08 1988-10-26 Henkel Kommanditgesellschaft auf Aktien Hair-regenerating compositions
WO1992013829A1 (en) * 1991-02-06 1992-08-20 Smith Ronald J Quaternized panthenol compounds and their use
WO1992019217A1 (en) * 1991-05-04 1992-11-12 The Procter & Gamble Company Cosmetic compositions
DE4214652A1 (en) * 1992-05-02 1993-11-04 Henkel Kgaa Hair treatment compsn. to improve hair growth - contains succinic acid ester esp. di:ethyl succinate
WO1993024101A1 (en) * 1992-05-22 1993-12-09 The Procter & Gamble Company Cosmetic compositions
US5270035A (en) * 1992-05-21 1993-12-14 Lexin International Marketing Corporation Hair conditioner containing disodium cocoamphodiacetate
US5340570A (en) * 1991-11-18 1994-08-23 Shiseido Co., Ltd. Dispensing system for sprayable gel-type hair conditioner
DE9311095U1 (en) * 1993-07-24 1994-11-24 Goldwell Ag Hair care products
US5384118A (en) * 1993-09-13 1995-01-24 Lavalle; Lila S. Gel hairdressing composition
DE4324962A1 (en) * 1993-07-24 1995-01-26 Goldwell Ag Hair care composition

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1987003196A1 (en) * 1985-11-22 1987-06-04 Agave Cosmetics Proprietary Limited Hair treatment
EP0287876A1 (en) * 1987-04-08 1988-10-26 Henkel Kommanditgesellschaft auf Aktien Hair-regenerating compositions
DE3711841A1 (en) * 1987-04-08 1988-10-27 Henkel Kgaa Haarregenerierende preparations
WO1992013829A1 (en) * 1991-02-06 1992-08-20 Smith Ronald J Quaternized panthenol compounds and their use
WO1992019217A1 (en) * 1991-05-04 1992-11-12 The Procter & Gamble Company Cosmetic compositions
US5340570A (en) * 1991-11-18 1994-08-23 Shiseido Co., Ltd. Dispensing system for sprayable gel-type hair conditioner
DE4214652A1 (en) * 1992-05-02 1993-11-04 Henkel Kgaa Hair treatment compsn. to improve hair growth - contains succinic acid ester esp. di:ethyl succinate
US5270035A (en) * 1992-05-21 1993-12-14 Lexin International Marketing Corporation Hair conditioner containing disodium cocoamphodiacetate
WO1993024101A1 (en) * 1992-05-22 1993-12-09 The Procter & Gamble Company Cosmetic compositions
DE9311095U1 (en) * 1993-07-24 1994-11-24 Goldwell Ag Hair care products
DE4324962A1 (en) * 1993-07-24 1995-01-26 Goldwell Ag Hair care composition
US5384118A (en) * 1993-09-13 1995-01-24 Lavalle; Lila S. Gel hairdressing composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999013821A1 (en) * 1997-09-13 1999-03-25 Henkel Kommanditgesellschaft Auf Aktien Hair conditioners for treating split ends
US6569414B1 (en) 1997-09-13 2003-05-27 Henkel Kommanditgesellschaft Auf Aktien Hair conditioners for treating split ends

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