WO1995005935A1 - Three-dimensional rapid prototyping - Google Patents

Three-dimensional rapid prototyping Download PDF

Info

Publication number
WO1995005935A1
WO1995005935A1 PCT/IB1994/000256 IB9400256W WO9505935A1 WO 1995005935 A1 WO1995005935 A1 WO 1995005935A1 IB 9400256 W IB9400256 W IB 9400256W WO 9505935 A1 WO9505935 A1 WO 9505935A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
materials
complementary
contours
processing
Prior art date
Application number
PCT/IB1994/000256
Other languages
French (fr)
Inventor
Alfredo De Angelis
Original Assignee
Alfredo De Angelis
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alfredo De Angelis filed Critical Alfredo De Angelis
Priority to DE69427305T priority Critical patent/DE69427305T2/en
Priority to EP94923822A priority patent/EP0722386B1/en
Publication of WO1995005935A1 publication Critical patent/WO1995005935A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/40Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10Processes of additive manufacturing
    • B29C64/141Processes of additive manufacturing using only solid materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10Processes of additive manufacturing
    • B29C64/188Processes of additive manufacturing involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/30Auxiliary operations or equipment
    • B29C64/386Data acquisition or data processing for additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y30/00Apparatus for additive manufacturing; Details thereof or accessories therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y40/00Auxiliary operations or equipment, e.g. for material handling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y40/00Auxiliary operations or equipment, e.g. for material handling
    • B33Y40/20Post-treatment, e.g. curing, coating or polishing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y50/00Data acquisition or data processing for additive manufacturing
    • B33Y50/02Data acquisition or data processing for additive manufacturing for controlling or regulating additive manufacturing processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2791/00Shaping characteristics in general
    • B29C2791/001Shaping in several steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/30Auxiliary operations or equipment
    • B29C64/307Handling of material to be used in additive manufacturing
    • B29C64/321Feeding
    • B29C64/336Feeding of two or more materials

Definitions

  • the present invention relates to methods of prototype constiuction and/or small quantity manufacture by controlled layerwise deposition and extraction.
  • Rapid Prototyping Systems in the prior art, to a large degree, attempts to address the needs and problems mentioned above
  • a single automated system can be used to produce prototype parts and small production runs direct ly from engineering designs.
  • Such a system is limited only by the size of the part and not by the intricacy of the part geometry.
  • Automated prototyping machines furthermore, require a minimum of human expertise for successful operation and a relatively negligible amount of set up time for a particular part.
  • Parts of complex geometries can be realized in relatively short amounts of lime with significant benefit to industry especially where designs are changed frequently and prototypes or mock-ups are needed for design evaluation.
  • Stercolithography produces part layers by scanning a laser across the surface of a photopolymer liquid bath and curing the photopolyincr along the part contours.
  • the precision is only limited by the boundary of photopolymerizalion initially, but as the parts continue curing in the post build stage, war page becomes a limiting factor.
  • the material properties of the parts arc also limited by the material properties of photopolyiners.
  • SLS Selective laser Sintering
  • Rapid prototyping by Precision Metal Spraying employs precision cut masks for each part layer and thus has the advantage of geometric control limited by the mask precision and/or the aspect ratio (mask feature width-to-layer depth), notwithstanding any problems associated with mask/part material selection such as binding, warping, and mask melting.
  • the intra/inter layer bonding in sprayed parts is often primarily mechanical because the material particles are cooled before they hit the surface layer.
  • Obtaining stress-free layers with desirable material properties involves significant tradeoffs with geometric control of the part.
  • parts made by Ballistic Particle Manufacturing or InkJet Printing (CAMPS) must also trade off part quality with geometric control.
  • 3-D printing systems deposit tiny binder material droplets onto a layer of powder, essentially precision printing each successive part layer.
  • These systems have the disadvantage of porosity (tow density) and poor bonding in green parts (prior to oven baking) due to the fizid mechanics and physics of the printing and binding processes. Once the parts arc oven heated to bake out the binder material, warpage and distortion related to shrinkage limit the attainable precision of the final parts.
  • each process is additive That is, they all produce a 3-D part by incrementally adding material to built it up. Furthermore, the additive technotogies which distinguish these processes all involve a tradeoff between maintaining a high degree of geometric precision and attaining suitable material properties in the final part.
  • 3-D manufacturing by controlled layerw ise deposition/extraction is a novel rapid prototyping method that integrates the precision control of established subtractive processes with additive processes optimized to produce desired material properties in order to produce a superior rapid prototyping system that does not suffer from any of the above mentioned shortcomings of prior art systems.
  • each layer is formed by selectively depositing part and complementary materials on the preceding layer (work surface).
  • Complementary material surrounds the part material on each layer to provide such things as structural support, chemical and/or thermal integrity, and adhesion; such being chosen based on the specific materials and the specific implementation of the method.
  • Systems for selective deposition of materials are generally based on the properties of the materials and will be discussed in more detail hereinafter.
  • Part materials are extracted from the initial part contours produced by the deposition systems to arrive within specified geometric tolerance of the part material layer.
  • Selective deposition and extraction of complementary materials can be used to form control contours for the selective deposition of part materials.
  • control contours are used to guide the deposition system into producing near net shape part contours such that the amount of subtractive processing for the part material layer is reduced.
  • Precut masks can be used as a form of control contour for selective deposition, By preforming masks from complementary materials and leaving them in place, the additive processing of complementary materials can also be reduced.
  • the type of control contour and the level of precision in any control contour will be determined by the part and complementary materials, their respective area ratios over the work surface, and/or the particular embodiment of the method.
  • each completed layer is an aggregate of part materials contours and complementary materials contours, the part materials contours being within prespecified geometric and material property tolerances and the remaining area of the aggregate layer (work surface) filled with complementary materials.
  • the method for rapid prototyping of the invention may be used with many different materials including, for example, metals, alloys, thermoforming plastics, thermosetting plastics, ceramics, and salts. These different materials may be used simultaneously within the part.
  • An object of the present invention is to provide a new and superior method of automated manufacturing of prototypes and/or small quantities of items that, unlike pr ior art techniques based upon incrementally adding material to build up the item, with attendant requirements of a high degree of precision, uses the established and precise methods of subtractive processes in conjunction with additive processes optimized to attain specified material properties, to provide improved rapid prototyping that obviates shortcomings of such prior art techniques.
  • a f urther object is to provide novel apparatus for carrying out the novel method of the invention.
  • Still a f urther object is to provide such a new technique of controlled layerwise deposition/extraction wherein each layer is formed by selectively depositing and removing part and complementary materials from the current layer or work surface
  • the invention embraces a method of automated layerwise fabrication of a three-dimensional part from a computer model, through controlled deposition and extraction of materials, that comprises, providing a three-dimensional computer model representation of the part and, by software, slicing the same into a plurality of successive layers corresponding to layers of predetermined thickness(es) of the part; generating sequences of part and complementary support materials) contours corresponding to each layer; depositing material(s) for one or more contours onto a work surface within a processing enclosure; material(s) processing said deposited contour (s) in order to achieve prespecified material properties for part and complementary contours; removing portions of said material(s) from said contour(s) under the control of the computer model contour(s) corresponding thereto; repeating the depositing, processing, and removing as necessary under the control of the computer model corresponding to the layer to complete an aggregate layer comprising part material contours within prespecified geometric and material properly tolerances and complementary material(s) elsewhere on the aggregate layer;
  • Fig.'s 1 A and 1 B are (low charts of the general operation of embodiments of the invention, effecting its method of layerwise controlled deposition/extraction, with and without precut masks respectively;
  • Fig. 1 B allows for the first deposition to be part or complementary material
  • Fig. 2 is a block diagram of a preferred computer and controls subsystem for operating the apparatus and controlling the process or method of the invention
  • Fig. 3A illustrates suitable mask-formation apparatus where masks are to be used, with Fig.'s 3B and 3C showing precut masks of different precision for continuous film stock and discrete film stock, respectively
  • Fig. 3D illustrates contour factorization that can be used with masks;
  • Fig.'s 3E- G and 3H- J are modifications of respective Fig.'s 3A-C;
  • Fig. 4 is a diagram of a suitable processing enclosure, work surface, and environmental control system
  • Fig.'s 5A and 5B show part and complementary materials deposition and fusion bonding apparatus used in depositing, materials processing, and adhering the successive layers in the materials additive subsystem of the invention
  • Fig.'s 5C and 5D respectively diagram radial and grid type discretization of the layers for the deposition of material
  • Fig.'s 5E, 5F, and 5G are diagrams of the primary deposition step using material spray, powder dispensing, molten material dispensing, pre-cured resin dispensing, and sol get dispensing;
  • Fig. 511 is a diagram of a fusion bonding apparatus for adhering the successive deposited layers and establishing desired material properties in the layer;
  • Fig.'s 6A and 6B are views of laser/F-beam and milling/grinding materials subtraction, extraction, or removal in accordance with the invention
  • Fig. 7 is a diagram of a suitable interlayer processing apparatus; Fig.'s 7A, 7B and 7C show a part, the layered (sliced) part, and an aggregate layer corresponding to a particular part layer.
  • Fig.'s 8A, 8B, and 8C illustrate par t post-processing steps of hear and surface treatment, chemical bath treatment and polishing, respectively.
  • the main subsystems associated with such rapid prototyping by layerwise controlled deposition/extraction include ( 1 ) a computer and controls subsystem, (2) an optional mask-forming subsystem, (3) a part chamber and work surface subsystem, (4) an environmental control subsystem, (5) a mater ials additive processes subsystem, (6) a materials subtractive processes subsystem, (7), a layer processing and prepping subsystem, and (8) a part post -processing subsystem.
  • This categorization is made according to purpose and not according to physical realization or placement, as some subsystems may be distributed throughout the apparatus.
  • FIG.'s 1 A and 1 B show the underlying 3-D controlled deposition/extraction (or removal or subtraction) processes of the invention and its various hereinafter described embodiments, employing precut masks and without precut masks, respectively.
  • Fig. 1 A following mask formation in real lime or in batch mode and "Mask Handling", so-labeled, the part material is applied by additive processing (primary deposition and then fusion bonding), such steps also being effected with the complementary material(s) (primary deposition and possibly fusion bonding), and with the deposited and bonded part material subjected to the subtractive processing of the invention, all as more fully described hereinafter.
  • additive processing primary deposition and then fusion bonding
  • the part material(s) and the complementary material(s) are again applied by primary deposition and then fusion bonding (routes A and B corresponding to part material(s) first and complementary material(s) first, respectively) followed by subtractive processing of the work surface, with repetition as at ( 1 ), until the aggregate layer corresponding to a completed layer of the part is formed.
  • “Surface Treatment” the process is repealed for successive layers.
  • This subsystem lakes in a
  • This subsystem generates the process control signals ( 12) which drive the other subsystems of the apparatus, and monitors the whole process to ensure proper operation.
  • This subsystem will generate part layers and controls based on operator preference and on minimizing process difficulties within the processing enclosure ( 14) such as part support problems, desired material properties issues, material matching problems, feature size constraints, material Mow and shrinkage problems, and wor kspace constraints, all of which ar e diagnosed up front to allow for redesign of the part or reconfiguration of the apparatus.
  • This system also provides mechanisms for in process diagnoses, correction, and learning.
  • the optional mask forming subsystem 2 can provide preformed mask contours to reduce the amount of materials additive and/or subtractive processing required to attain the desired geometry for the part layer. If utilized (Fig. 1 B), the mask formation subsystem produces masks for the deposition or the part materials. The mask functions as a control contour, not necessarily within tolerance, for the part materials to fill, thereby reducing the amount of additive processing required during the formation of the layer . This is described further in the hereafter presented materials additive and subtractive process subsystems 5 and 6, Fig.'s 5A-5H and 6A-6B. Furthermore, the mask contours, if made of complementary materials and left in place as support for the part contours, can significantly reduce the amount of complementary material that must be deposited to complete the layer.
  • the masks may be made of materials other than complementary materials to suit the materials additive process. Nevertheless, the mask contours need to be formed and positioned accurately over the work surface The use and precision (ranging from near net shape to gross contours) of preformed masks in the formation of layers is a process choice to be made.
  • the mask formation subsystem stores and delivers mask materials, and forms the mask contours maintaining mask handling and positioning control, and mask contour geometry. Additionally, this subsystem performs mask enhancements and preparations which facilitate the use of masks in the other subsystems of the apparatus, including, positioning markers, coaling and surface treatment, material flow pathways, and bridges and/or fixtures for islands.
  • the part processing enclosure and work surface subsystem 3, Fig. 4, contains and manipulates the part as it is being built in the enclosure ( 14), one layer at a time.
  • This subsystem provides access to the part and to the current work surface (layer) of the part to subsystems which monitor and/or operate on the part: including, for example, additive processes, subtractive processes, positioning and/or handling systems, and probing/measurement systems.
  • the environmental control subsystem 4 maintains the proper environment for the subsystems of the apparatus as commanded by the computer and controls subsystem.
  • the environmental variables which may be controlled include, temperature, pressure, inertness and other chemical conditions, cleanliness (debris and condensation), and vibration and noise
  • the materials additive subsystem 5, Fig.'s 5A-5B is comprised of the various additive processes for part and complementary materials. These processes deliver and deposit part materials within the geometric control provided by the respective apparatus and/or by control contours provided by selectively deposited and extracted complementary materials or by precut masks. In addition, these systems deposit complementary materials where necessary to complete the current layer.
  • the part materials additive processes have two phases: the primary deposition phase and the fusion bonding phase so-labeled in Fig. 5A. In the primary deposition phase, the material is deposited to a prespecified thickness on the work surface or only on selected discrete areas of the discretized (sectioned) work surface, such as shown in Fig.'s 5C and 5D, respectively for radial and grid type discretization (sectioning).
  • a fusion bond occurs between the current and previous part layers and that the deposited material is energy treated to achieve a prespecified, set of material properties (microstructure).
  • the two phases may coincide and/or be achieved by the same apparatus.
  • the complementary materials additive processes may have two similar phases, but it is not required that a fusion bond be established: only that the complementary materials fill in empty areas and provide, as needed, structural support, chemical and/or thermal integrity, and a substrate for future layer adhesion.
  • Various additive processes are used within the materials additive subsystem and scheduled according to the process requirements by the computer and controls subsystem, ( 12) Fig. 2, to achieve prespecified final part qualities. Examples of materials additive processes include powder deposition and melting, Fig. 5F, plasma spaying and heat/energy beam glazing, Fig. 5E, molten material dispensing, and pre-cured material dispensing and curing
  • heat source/energy beam preferably procured resin and/or sol-gel and the like
  • the materials additive subsystem incorporates surface heating, layer glazing, and rapid solidification as required for the various additive processes.
  • the other subsystems have all acted on the deposited layer such that all the physical and material properties of the layer such as material density and microstructure, and residual stresses are all within prespecified tolerances for the deposited contours.
  • the materials subtractive subsystem then selectively removes the final materials, as specified by the respective contours for that layer from the computer and controls subsystem 1 , without altering the prespecified physical and material parameters significantly.
  • control contours in the additive process determines the amount of subtractive processing required to arrive within the geometric tolerance of the desired part layer.
  • the ent ire part layer must be formed by the subtractive processing of the deposited part materials.
  • Near net shape part layer contours in the mask reduces the amount of subtractive processing, as would a discretized ma terials additive process.
  • complementary materials are deposited by the materials additive subsystem into empty regions of the work surface.
  • the interlayer processing and preparation subsystem 7, Fig. 7, consists of work surface preparations performed between each part layer as required by the computer and controls subsystem 1 , Fig. 2. These operations include surface treatment such as heating ( 18), roughening, grinding, leveling, etc. ( 16), addition of surfactants, binders, chemical barriers, alloying materials, etc. (20), and addition and/or configuration of fixtures.
  • surface treatment such as heating ( 18), roughening, grinding, leveling, etc. ( 16), addition of surfactants, binders, chemical barriers, alloying materials, etc. (20), and addition and/or configuration of fixtures.
  • the part post-processing subsystem 8, Fig. 8 performs finishing operations on the completed part after it is removed from the part chamber. Such operations include removal of complementary malerials through oxidation or thermal/mechanical processes, Fig. 8A, and/or vaporization or dissolution. Fig. 8B, polishing, Fig. 8C, machining, heal treating, chemical t reatment, coatings application, and assembly.
  • Fig.'s 2-8C the automated rapid prototyping method of the invention based on selective deposition/removal of materials is performed with the sequences of operation previously summarized in the flow charts of Fig.'s 1 A and 1 B.
  • the computer and controls subsystem 1 Fig. 2, embodies, as the controls generator and system monitor ( 12), for example, a commercially available computer with CAD/CAM slicing software, a user interface, and I/O hardware by which to communicate with other subsystems.
  • the slicing software exists commercially, such as, for example, the CAMAND and ULTRACAM products from CAMAX Systems Inc., and can readily be modified and extended, as is well known in the art, to provide expert diagnosis capabilities based on materials and process variables as well as learning capabilities.
  • the optional mask forming subsystem 2 may consist of a machining station (22), Fig.'s 3A and 3E, at which continuous films or sets of sheets arc laser cut, on a system such as the Landmark laser marking system of AB Lasers Co., or machined by milling, Fig. 311, or punching to produce a precut contour for the part layer.
  • the precut masks if made of complementary material and left in place, can also serve as complementary material contours for each layer.
  • Graphite films or sheets are one possible choice of complementary material precut masks, and may be used for high temperature applications such as with parts involving tool steels or ceramics since graphite has a high moiling temperature. Graphite also oxidizes rapidly well below its melting point which facilitates removing the graphite complementary materials surrounding the finished part.
  • complementary material may also be made depending on the process requirements. These complementary materials may then be removed by a variety of processes including heating, oxidation, solution bathing, vibration, ete..
  • the mask stock may be in the form of a continuous film loaded into the apparatus and advanced accordingly, Fig.'s 3A and 313, 3E and M1, and/or 311 and 31, or in the form of discrete sheets loaded sequentially, Fig.'s 3C and 3G, and/or 3J.
  • the precut mask contours may be rough cuts of the desired part contour so as to reduce subsequent subtract ive processing and debris.
  • the precut mask contours may be precision machined to within the tolerance of the desired part layer to minimize subsequent subtractive processing and debris.
  • the degree of precision in the mask formation process 2 would be at best equal to the precision of the materials subtractive process subsystem.
  • additional precut mask processing operations is the machining of the mask handling and positioning markings, Fig.'s 313, 3C, 3F, 3G, 3l and 3J. and the forming of removable bridges to any mask islands which were created intentionally in favor of employing subtractive processes in particular regions of the mask.
  • Fig. 3D may be used to prevent mask islands.
  • the finished precul masks are conveyed to a mask buffer, Fig.'s 3A. 3E, and 311, from which they aic scheduled for accurate positioning, aligning, and flattening over the work surface in Fig. 4.
  • the environmental control subsystem, 4, and the part processing enclosure subsystem, 3, arc shown in Fig. 4 as a scaled enclosure (4), with sensors, heaters/coolers, gas flow ducts and pumps, and windows, for directed energy beams and sensors.
  • the part chamber preferably consists of a servo controlled piston in a cylinder encompassed in the lower chamber enclosure ( 14), and the current work surface, Fig.
  • the part upper chamber processing enclosure (4) houses or provides access of the work surface to the environment contr ol subsystem 4, the malerials additive and subtractive processes subsystems 5 and 6, Fig.'s 5A-5H and 6A and 6B, and the interlayer processing subsystem 7, Fig. 7.
  • the part chamber is mounted to a precision x-y-z positioning table, schematically represented by the 3-axis vector diagram, and the additive and subtractive subsystem apparatus are scheduled over the work surface
  • the convention is used herein of schematically showing the required positioning tables as an axis vector diagram, such apparatus being well known and deemed unnecessary to complicate the drawings herein.
  • the part chamber may be mounted to a precision x and/or y and/or z positioning table and each additive and/or subtractive processing apparatus may be capable of x-y and/or z-axis motion in addition the motion of the work surface.
  • the part chamber may be fixed and the additive and/or the subtractive apparatus are capable of precision x-y and/or z motion.
  • the processing enclosure and part chamber may be kept at elevated temperatures to reduce thermal cycling, residual stresses, and facilitate the materials additive processes and the formation of quality interlayer bonds, and may provide an inert and clean environment via debris and contaminant removal.
  • the processing enclosure and the part chamber may be capable of pressure cycling for materials additive processing, interlayer processing, and/or debris removal at ( 1 1 ), Fig. 4.
  • the p rocessing enclosure and/or part chamber houses or provides access to material stock and mask buffers which supply the various processes inherent to part layer formation.
  • the processing enclosure and chamber are designed and operated to regulate the level of oxygen, non-inert gasses (labeled "gas" in Fig. 4) and contaminants during the building of the part.
  • one of two processing scenarios may be carried out based upon the particular embodiment and/or the volume fraction of part to complementary materials in the current layer.
  • Complementary material is selectively deposited first. Part material is subsequently deposited within the control contours provided by the complementary materials. Material processing operations before described, such as heating, chemical treating, or energy treating are then performed on the deposited part materials (and possibly complementary materials) contours by the materials additive system to ensure that the part (and possibly complementary) materials are within tolerance of prespecified material properties.
  • Complementary material may be deposited by either placing a precut mask made of complementary material or selectively through the materials additive subsystem, and may be machined or selectively removed in addition. The precision of the precut mask contour and/or the complementary materials selective deposition apparatus is a parameter of the particular embodiment or apparatus.
  • Scenario Two Part material is first selectively deposited. Complementary material may/may not be subsequently selectively deposited. Material processing operations such as heating, chemical treating, or energy treating are then performed on the deposited part material (and possibly complementary material) contours by the materials additive system to ensure that the part (and possibly complementary) materials are within tolerance of prespecified material properties. Part material may be deposited through a precut mask or selectively through the materials additive subsystem. The controlled deposition and extraction of part and complementary materials, as staled scenarios One and Two, is repealed to include all part and complementary materials predetermined for the part layer. At this point in the process, the layer is at least partially covered by deposited part materials and/or complementary materials within tolerance of their respective prespecified material properties.
  • the materials subtractive subsystem then processes the part contours to arrive within the specified geometric tolerance of the part.
  • the materials additive subsystem completes the layer by depositing complementary material in any empty regions of the current layer in order to complete the layer. Materials processing of this additional complementary material may/may not be performed by the materials additive subsystem.
  • Interlayer processing such as layer thickness control by surface machining and surface treatment and/or roughening, Fig. 7, is performed on the completed (aggregate) layer by the interlayer processing and preparation system in preparation for the next layer. All of the above occurs within a regulated environment dictated by the environment control subsystem 4 , Fig. 4,
  • the part contours may be surfaced machined in order to attain thickness tolerances before the materials subtractive system acts on the part contours.
  • the primary deposition system may consist of a powder dispenser, Fig. 5F which deposits powder onto the work surface.
  • a roller or squeegee-like mechanism (R) is used to regulate the powder layer height and a mask may be used, if so desired, to control the contour of the powder layer.
  • Fig. 511 consist of a laser, such as the Diamond SL-64 made by Coherent General, electron beam, or other regional effect heat/energy source, and are employed within an appropriate environmental cycle (e.g. temperature and pressure) to ensure a dense, fusion bonded layer within tolerance of specified material properties, as is well known.
  • the primary deposition process may, as before described, consist of a powder or wire fed, multi-material plasma spraying system, Fig. 5E, (either multi-head or multi-material feeds) such as the SG-200 plasma spray gun based system made by Plasmadyne Co..
  • the plasma spraying parameters arc chosen to regulate the layer height, and a mask may also be used, if so desired, to control the deposited contour.
  • the bonding in the plasma sprayed layer may be partially mechanical and partially from fusion, depending on the choice of spraying parameters such as stand-off distance, amperage, and gas velocity.
  • the fusion bonding system consists of a laser or electron beam or other regional effect heat/energy source. Fig. 511, and is employed within an appropriate environmental cycle. (e.g. temperature and pressure, and gas concentration) to ensure a dense, fusion bonded layer within tolerance of its specified material properties.
  • the additive processing of complementary materials need not include a fusion bonding phase provided that the plasma spraying parameters can be chosen to provide a suitable support structure Additionally, rapid solidification mechanisms such as localized cooling devices may be used if required for good material properties.
  • the primary deposition phase may embody the previously described powder or wire fed, molten material dispenser. Multiple heads or multiple material feeds allows for multiple material deposition.
  • the molten materials dispensing parameters are chosen to regulate the layer height and a mask may also be used, if so desired, to control the layer contour.
  • the fusion bonding system, Fig. 511 as before, consists of a laser or electron beam or other regional effect heat/energy source and is employed within an appropriate environmental cycle (e.g. temperature, pressure, and gas concentrations) to ensure a dense, fusion bonded layer within tolerance of its specified material properties.
  • the complementary materials additive process may employ either the molten materials dispenser or a plasma-spray head and may not require a full fusion bond to provide a suitable support structure.
  • Fig. 5G consists of a liquid dispenser for the before mentioned pre- cured resin or thermosetting materials or for materials in sol-gel or solution form (eg. ceramics).
  • the dispensing parameters are again chosen to regulate the layer height, and a mask may also be used, if so desired, to control the layer contour.
  • the same fusion bonding system of Fig. 511 and/or a general heal source through the environmental control subsystem may be used to cure the thermoset or evaporate the solvent to ensure a dense, fusion bonded layer within tolerance of its specified material properties.
  • Any of the above mentioned additive processing apparatus may be employed for the complementary materials depending on the choice of complementary material.
  • the materials subtractive processes subsystem consists, as before staled, of precision machining systems such as: milling, drilling, routing, grinding, Fig. 613, or laser or electron beam machining. Fig. 6A, or electrostatic discharge machining, as examples. Each such system is capable of operating within the environment required by the computer and controls subsystem. To this end, liquid and/or gas coolant or high temperature tooling may be employed. The choice of subtractive process largely depends on the materials and environment and thus various processes may be scheduled according to need. Debris removal, as at ( 1 1 ), Fig. 4. is required to maintain a contaminant lice environment in the part processing enclosure. Debris comes in the form of chips and/or loose powder and/or vapor and/or liquid from the various material deliveries, additive and sublraclivc processes, and possibly coolants.
  • Gas flows (“Gas", Fig. 4) may be used to blow material vapor, debris, and other unwanted products through gas ducts and fillers such as in the model 1005/1310 Fume Exhauster and Filtered Air Cleaner by KEI. Gas flows may also be used to clear areas only on the work surface, as needed. Gas flows may also be induced by high pressure nozzles or by vacuum diffusers which are opened within the part processing enclosure during a high pressure cycle The gas flows may be fixed locally to the subtractive processing apparatus to blow or suck debris as it is formed. More global gas flows may also be used to suck vapors out of the part processing enclosure with drainage paths employed to remove unvaporized liquids.
  • Subtractive processing the part layer to tolerance in Fig.'s 6A and 6B may create empty areas of the work surface which require filling with complementary material.
  • the part (aggregate) layer is formed to tolerance in the work surface plane, but not necessarily in the vertical plane (height or thickness of the layer).
  • the interlayer processing subsystem. Fig. 7, machines the completed layer to vertical tolerance (height) and surface-preps (roughening, adding alloying or bonding elements, chemical treating, etc.) the layer to facilitate the construction of the next part layer.
  • Fig.'s 7A-7C a part is shown in Fig. 7A comprising 3 part materials, as an example, with the aggregate layer being shown in expanded view in Fig. 7C for a particular part layer of Pig. 713.
  • complementary materials may be removed by thermal or mechanical shocking, chemical baths or melting as shown in Fig.'s 8A-8C.
  • Complementary material may have a melting point below that of part material, and thus may be removed by healing.
  • Complementary material may be soluble in an appropriate liquid or gas based solvent for removal, and indeed, may be soluble in water— such as a variety of inorganic salts, certain waxes, or water soluble aluminum alloys.
  • the complementary material(s) may include glass materials such as a borosilicate, soluble, for example, in solvents such as acetone, or may include ceramic materials of the like. As before stated, if graphite or a graphite-based material is used, such oxidizes readily under appropriate heating and/or oxygen concentrations. Thermal and/or mechanical cycling and/or shocking, as previously mentioned, may also be used for removing the complementary malerial(s).
  • the invention is applicable to a wide variety of part materials including, as examples, metals and metallic alloys, thermoforming and thermosetting plastics, waxes, ceramics, glasses, graphites, and inorganics or various types, all such being depositable in multi- material, composite layers, as described. Further modifications will occur to those skilled in this art, and such as are considered to fall within the sphere and scope of the invention as defined in the appended claims.

Abstract

A method of automated layer-wise fabrication of a three-dimensional part from a computer model through controlled deposition and extraction of materials. The method integrates the precision control of established subtractive processes with additive processes optimised to produce desired material properties in order to produce a superior rapid prototyping system that does not suffer from the short-comings of prior art systems.

Description

THREE-DIMENSIONAL RAPID PROTOTYPING
The present invention relates to methods of prototype constiuction and/or small quantity manufacture by controlled layerwise deposition and extraction.
BACKGROUND OF THE INVENTION
There is considerable interest within industry in manufacturing prototypes or small production batches in a rapid and cost effective manner. Conventional part production methods are neither time nor cost effective when only a small number of units are needed because they require expensive part-specific tooling, setting up machining protocols, and generating and programming three- dimensional (3-D) tool paths which require much time and professional expertise. The cost and time to set up and run machine-specific tooling, along with the initial capital costs for tooling, make conventional prototyping/small production run processes both time and cost intensive. Furthermore, conventional
prototyping methods are limited in practice to simple part geometries. Complex parts involving inner features and cores/cavitics aie difficult to produce using conventional techniques and often require precision casting methods which are highly expensive, lime consuming, and require a broad range ol exper tise.
Rapid Prototyping Systems (RPS) in the prior art, to a large degree, attempts to address the needs and problems mentioned above A single automated system can be used to produce prototype parts and small production runs direct ly from engineering designs. Such a system is limited only by the size of the part and not by the intricacy of the part geometry. Thus, such a machine is not so part-specific as conventional tooling, and a capital investment in such a machine is all that is needed to produce virtually any part within the size constraints of the system. Automated prototyping machines, furthermore, require a minimum of human expertise for successful operation and a relatively negligible amount of set up time for a particular part. Parts of complex geometries can be realized in relatively short amounts of lime with significant benefit to industry especially where designs are changed frequently and prototypes or mock-ups are needed for design evaluation.
All such RPS make use of a common approach involving the stratification of the prototype.
Software "slices" the prototype part geometry into a sequence of cross-sectional contours(strata) used to drive a materials processing system which recreates each contour out of prespecified materials. The prototype part is built up by adhering successive part cross-sections together until the part is complete
Currently, there are several realizations of RPS, each employing a particular technology with its own strengths and weaknesses:
* Stereolithography, referenced in US patent 4,575,330 by Charles W. Hull;
* Computer Aided Manufacturing Process and System (CAMPS), as described in US patent 4,665,492 by William E. Masters;
* Laminations Method, described in US patent 4,752,352 by Michael Feygin; * Selective Laser Sintering (SLS), described in US patent 4,863,538 by Carl R.
Deckard; * Mask and Deposit (MD*) System, described in US patent 5,126,529 by Lee F.
Weiss. * Three Dimensional Printing, discussed in the Publication " Three Dimensional
Printing: Form, Materials, and Performance ", by Michael J. Cima and Emanuel M. Sachs, Solid Free form Fabrication Symposium, University of Texas at Austin, Austin TX, August 1991. Stercolithography produces part layers by scanning a laser across the surface of a photopolymer liquid bath and curing the photopolyincr along the part contours. The precision is only limited by the boundary of photopolymerizalion initially, but as the parts continue curing in the post build stage, war page becomes a limiting factor. The material properties of the parts arc also limited by the material properties of photopolyiners.
Selective laser Sintering (SLS) produces part layers by scanning powder with a high powered laser to induce sintering local to the laser path. While this process creates complicated geometries, the sintered material densities arc low. Consequently, the mechanical properties of SLS parts arc relatively unsuitable for functional prototypes. Increasing the density of SLS parts would require a higher degree of .sintering/melting of the part powder, thereby compromising the geometric control provided by SLS.
Rapid prototyping by Precision Metal Spraying (Mask and Deposition the other hand, employs precision cut masks for each part layer and thus has the advantage of geometric control limited by the mask precision and/or the aspect ratio (mask feature width-to-layer depth), notwithstanding any problems associated with mask/part material selection such as binding, warping, and mask melting. The intra/inter layer bonding in sprayed parts, however, is often primarily mechanical because the material particles are cooled before they hit the surface layer. Obtaining stress-free layers with desirable material properties involves significant tradeoffs with geometric control of the part. Similarly, parts made by Ballistic Particle Manufacturing or InkJet Printing (CAMPS) must also trade off part quality with geometric control. The building of prototypes from welded or adhered precut laminations as in the Laminations Method, moreover, suffers from a tradeoff between inter lamination bonding and geo metr ic control, as well as from sever al precision handling problems associated with complicated part cross sections.
Lastly, 3-D printing systems deposit tiny binder material droplets onto a layer of powder, essentially precision printing each successive part layer. These systems, however, have the disadvantage of porosity (tow density) and poor bonding in green parts (prior to oven baking) due to the f luid mechanics and physics of the printing and binding processes. Once the parts arc oven heated to bake out the binder material, warpage and distortion related to shrinkage limit the attainable precision of the final parts.
All of the present rapid prototyping methods, therefore, unfortunately are subject to contain inherent difficulties and limitations in aspects of their prototype creation. In summary, the key disadvantages associated with one or more of the current systems arc: ( 1 ) poor material properties and/or distribution of material properties; (2) poor geometric control and/or difficulty with complex geometry; and (3) trade off between geometric part control and interlayer bond strength and/or part properties, such as density or microstructure.
While each of the above prior processes is different, they all share a key element: each process is additive That is, they all produce a 3-D part by incrementally adding material to built it up. Furthermore, the additive technotogies which distinguish these processes all involve a tradeoff between maintaining a high degree of geometric precision and attaining suitable material properties in the final part.
In accordance with the present invention on the other hand, 3-D manufacturing by controlled layerw ise deposition/extraction is a novel rapid prototyping method that integrates the precision control of established subtractive processes with additive processes optimized to produce desired material properties in order to produce a superior rapid prototyping system that does not suffer from any of the above mentioned shortcomings of prior art systems.
In the controlled layerwise deposition/extraction method of the invention, each layer is formed by selectively depositing part and complementary materials on the preceding layer (work surface). Complementary material surrounds the part material on each layer to provide such things as structural support, chemical and/or thermal integrity, and adhesion; such being chosen based on the specific materials and the specific implementation of the method. Systems for selective deposition of materials are generally based on the properties of the materials and will be discussed in more detail hereinafter. Part materials are extracted from the initial part contours produced by the deposition systems to arrive within specified geometric tolerance of the part material layer. Selective deposition and extraction of complementary materials can be used to form control contours for the selective deposition of part materials. These control contours are used to guide the deposition system into producing near net shape part contours such that the amount of subtractive processing for the part material layer is reduced. Precut masks can be used as a form of control contour for selective deposition, By preforming masks from complementary materials and leaving them in place, the additive processing of complementary materials can also be reduced. The type of control contour and the level of precision in any control contour will be determined by the part and complementary materials, their respective area ratios over the work surface, and/or the particular embodiment of the method. In any case, each completed layer is an aggregate of part materials contours and complementary materials contours, the part materials contours being within prespecified geometric and material property tolerances and the remaining area of the aggregate layer (work surface) filled with complementary materials. My employing various deposition and extraction processes, and by maintaining strict control of the processing environment, the method for rapid prototyping of the invention may be used with many different materials including, for example, metals, alloys, thermoforming plastics, thermosetting plastics, ceramics, and salts. These different materials may be used simultaneously within the part.
OBJEC T OF THE INVEN TION
An object of the present invention, therefore, is to provide a new and superior method of automated manufacturing of prototypes and/or small quantities of items that, unlike pr ior art techniques based upon incrementally adding material to build up the item, with attendant requirements of a high degree of precision, uses the established and precise methods of subtractive processes in conjunction with additive processes optimized to attain specified material properties, to provide improved rapid prototyping that obviates shortcomings of such prior art techniques.
A f urther object is to provide novel apparatus for carrying out the novel method of the invention.
Still a f urther object is to provide such a new technique of controlled layerwise deposition/extraction wherein each layer is formed by selectively depositing and removing part and complementary materials from the current layer or work surface
Other and further objects will be hereinafter described and more particularly delineated in the appended claims.
SUMMARY OF INVENTION
In summary, from one of its broader aspects, the invention embraces a method of automated layerwise fabrication of a three-dimensional part from a computer model, through controlled deposition and extraction of materials, that comprises, providing a three-dimensional computer model representation of the part and, by software, slicing the same into a plurality of successive layers corresponding to layers of predetermined thickness(es) of the part; generating sequences of part and complementary support materials) contours corresponding to each layer; depositing material(s) for one or more contours onto a work surface within a processing enclosure; material(s) processing said deposited contour (s) in order to achieve prespecified material properties for part and complementary contours; removing portions of said material(s) from said contour(s) under the control of the computer model contour(s) corresponding thereto; repeating the depositing, processing, and removing as necessary under the control of the computer model corresponding to the layer to complete an aggregate layer comprising part material contours within prespecified geometric and material properly tolerances and complementary material(s) elsewhere on the aggregate layer; completing the computer model sliced layer by further processing said aggregate layer such as machining off a sublayer to ensure thickness tolerances or roughening or chemically enhancing the surface to ensure selective binding to the next aggregate layer; repeating said controlled layer creation steps to build the entire part surrounded by the complementary material/s; and removing said complementary material/s to obtain the fabricated part.
Preferred and best mode embodiments and designs will hereinafter be described in detail
DRAWINGS The invention will now be described in connection with the accompanying drawings, Figs. 1 -8. which are schematic views of necessary steps in the procedure of a preferred embodiment of the invention;
Fig.'s 1 A and 1 B are (low charts of the general operation of embodiments of the invention, effecting its method of layerwise controlled deposition/extraction, with and without precut masks respectively;
Fig. 1 B allows for the first deposition to be part or complementary material; Fig. 2 is a block diagram of a preferred computer and controls subsystem for operating the apparatus and controlling the process or method of the invention; Fig. 3A illustrates suitable mask-formation apparatus where masks are to be used, with Fig.'s 3B and 3C showing precut masks of different precision for continuous film stock and discrete film stock, respectively; Fig. 3D illustrates contour factorization that can be used with masks;
Fig.'s 3E- G and 3H- J are modifications of respective Fig.'s 3A-C;
Fig. 4 is a diagram of a suitable processing enclosure, work surface, and environmental control system;
Fig.'s 5A and 5B show part and complementary materials deposition and fusion bonding apparatus used in depositing, materials processing, and adhering the successive layers in the materials additive subsystem of the invention;
Fig.'s 5C and 5D respectively diagram radial and grid type discretization of the layers for the deposition of material;
Fig.'s 5E, 5F, and 5G are diagrams of the primary deposition step using material spray, powder dispensing, molten material dispensing, pre-cured resin dispensing, and sol get dispensing;
Fig. 511 is a diagram of a fusion bonding apparatus for adhering the successive deposited layers and establishing desired material properties in the layer;
Fig.'s 6A and 6B are views of laser/F-beam and milling/grinding materials subtraction, extraction, or removal in accordance with the invention;
Fig. 7 is a diagram of a suitable interlayer processing apparatus; Fig.'s 7A, 7B and 7C show a part, the layered (sliced) part, and an aggregate layer corresponding to a particular part layer.
Fig.'s 8A, 8B, and 8C illustrate par t post-processing steps of hear and surface treatment, chemical bath treatment and polishing, respectively.
DESCRIP TION OF PREFERRED EMBODIMEN T(S) OF INVEN TION
Before proceeding to describe embodiments illustrating the method and preferred apparatus for carrying out the layerwise controlled deposition/extraction technique underlying the invention, a brief description of the general framework lor such rapid prototyping is believed to be useful. The main subsystems associated with such rapid prototyping by layerwise controlled deposition/extraction include ( 1 ) a computer and controls subsystem, (2) an optional mask-forming subsystem, (3) a part chamber and work surface subsystem, (4) an environmental control subsystem, (5) a mater ials additive processes subsystem, (6) a materials subtractive processes subsystem, (7), a layer processing and prepping subsystem, and (8) a part post -processing subsystem. This categorization is made according to purpose and not according to physical realization or placement, as some subsystems may be distributed throughout the apparatus.
The flow charts of Fig.'s 1 A and 1 B show the underlying 3-D controlled deposition/extraction (or removal or subtraction) processes of the invention and its various hereinafter described embodiments, employing precut masks and without precut masks, respectively.
Referring first to Fig. 1 A, following mask formation in real lime or in batch mode and "Mask Handling", so-labeled, the part material is applied by additive processing (primary deposition and then fusion bonding), such steps also being effected with the complementary material(s) (primary deposition and possibly fusion bonding), and with the deposited and bonded part material subjected to the subtractive processing of the invention, all as more fully described hereinafter. Following redeposition f complementary material in empty regions and subsequent surface treatment, these steps are repealed for successive layers as indicated by the feedback lines from "Surface Treatment" to the "Mask Formation" and "Mask Handling" process step blocks. When no precut masks are employed on the layered prototype or part build-up. Fig. 1 B, the part material(s) and the complementary material(s) are again applied by primary deposition and then fusion bonding (routes A and B corresponding to part material(s) first and complementary material(s) first, respectively) followed by subtractive processing of the work surface, with repetition as at ( 1 ), until the aggregate layer corresponding to a completed layer of the part is formed. Following "Surface Treatment", the process is repealed for successive layers.
( 1 ) Computer and Controls Subsystem
The computer and controls subsystem 1 , Fig. 2, interfaces with all other subsystems and the operator to initiate and control the rapid prototyping process. This subsystem lakes in a
CAD/CAM representation of the prototype part and slices it, by software as indicated at
( 10), into the sequence of layers (L) used to drive the remaining subsystems. This subsystem generates the process control signals ( 12) which drive the other subsystems of the apparatus, and monitors the whole process to ensure proper operation. This subsystem will generate part layers and controls based on operator preference and on minimizing process difficulties within the processing enclosure ( 14) such as part support problems, desired material properties issues, material matching problems, feature size constraints, material Mow and shrinkage problems, and wor kspace constraints, all of which ar e diagnosed up front to allow for redesign of the part or reconfiguration of the apparatus.
This system also provides mechanisms for in process diagnoses, correction, and learning.
(2) Optional Mask Forming Subsystem
The optional mask forming subsystem 2, Fig.'s 3A-3J, can provide preformed mask contours to reduce the amount of materials additive and/or subtractive processing required to attain the desired geometry for the part layer. If utilized (Fig. 1 B), the mask formation subsystem produces masks for the deposition or the part materials. The mask functions as a control contour, not necessarily within tolerance, for the part materials to fill, thereby reducing the amount of additive processing required during the formation of the layer . This is described further in the hereafter presented materials additive and subtractive process subsystems 5 and 6, Fig.'s 5A-5H and 6A-6B. Furthermore, the mask contours, if made of complementary materials and left in place as support for the part contours, can significantly reduce the amount of complementary material that must be deposited to complete the layer. However, the masks may be made of materials other than complementary materials to suit the materials additive process. Nevertheless, the mask contours need to be formed and positioned accurately over the work surface The use and precision (ranging from near net shape to gross contours) of preformed masks in the formation of layers is a process choice to be made.
The mask formation subsystem stores and delivers mask materials, and forms the mask contours maintaining mask handling and positioning control, and mask contour geometry. Additionally, this subsystem performs mask enhancements and preparations which facilitate the use of masks in the other subsystems of the apparatus, including, positioning markers, coaling and surface treatment, material flow pathways, and bridges and/or fixtures for islands.
(3) Part Processing Enclosure and Work Surface Subsystem
The part processing enclosure and work surface subsystem 3, Fig. 4, contains and manipulates the part as it is being built in the enclosure ( 14), one layer at a time. This subsystem provides access to the part and to the current work surface (layer) of the part to subsystems which monitor and/or operate on the part: including, for example, additive processes, subtractive processes, positioning and/or handling systems, and probing/measurement systems.
(4) Environmental Control Subsystem
The environmental control subsystem 4, also in Fig. 4, maintains the proper environment for the subsystems of the apparatus as commanded by the computer and controls subsystem. The environmental variables which may be controlled include, temperature, pressure, inertness and other chemical conditions, cleanliness (debris and condensation), and vibration and noise
(5) Materials Additive Subsystem
The materials additive subsystem 5, Fig.'s 5A-5B, is comprised of the various additive processes for part and complementary materials. These processes deliver and deposit part materials within the geometric control provided by the respective apparatus and/or by control contours provided by selectively deposited and extracted complementary materials or by precut masks. In addition, these systems deposit complementary materials where necessary to complete the current layer. The part materials additive processes have two phases: the primary deposition phase and the fusion bonding phase so-labeled in Fig. 5A. In the primary deposition phase, the material is deposited to a prespecified thickness on the work surface or only on selected discrete areas of the discretized (sectioned) work surface, such as shown in Fig.'s 5C and 5D, respectively for radial and grid type discretization (sectioning). In the fusion bonding phase, Fig. 5 H, it is ensured thai a fusion bond occurs between the current and previous part layers and that the deposited material is energy treated to achieve a prespecified, set of material properties (microstructure). Depending on the materials, the two phases may coincide and/or be achieved by the same apparatus. The complementary materials additive processes may have two similar phases, but it is not required that a fusion bond be established: only that the complementary materials fill in empty areas and provide, as needed, structural support, chemical and/or thermal integrity, and a substrate for future layer adhesion. Various additive processes are used within the materials additive subsystem and scheduled according to the process requirements by the computer and controls subsystem, ( 12) Fig. 2, to achieve prespecified final part qualities. Examples of materials additive processes include powder deposition and melting, Fig. 5F, plasma spaying and heat/energy beam glazing, Fig. 5E, molten material dispensing, and pre-cured material dispensing and curing
with heat source/energy beam (preferably procured resin and/or sol-gel and the like), Fig. 5G.
The materials additive subsystem incorporates surface heating, layer glazing, and rapid solidification as required for the various additive processes.
(6) Materials Subtractive Subsystem The purpose of the mater ials subtractive, extractive, or removal subsystem 6, Fig.'s 6A and 6B, is to remove part and complementary materials from the work surface as commanded by the computer and controls subsystem 1 , Fig. 2. Laser or E-beam machining is shown in Fig. 6A, and milling or grinding and the like in Fig. 6B. This subsystem provides the final geometric accuracy of the contours after all the potential sources of geometric error on the layer such as bending/warping due to residual stress, shrinkage upon solidification, and distortion due to layer processing (to achieve prespecified material properties within the layer and achieve interlayer fusion bonding), have already been introduced by the other subsystems. In other words, the other subsystems have all acted on the deposited layer such that all the physical and material properties of the layer such as material density and microstructure, and residual stresses are all within prespecified tolerances for the deposited contours. The materials subtractive subsystem then selectively removes the final materials, as specified by the respective contours for that layer from the computer and controls subsystem 1 , without altering the prespecified physical and material parameters significantly.
The use of control contours in the additive process determines the amount of subtractive processing required to arrive within the geometric tolerance of the desired part layer. When no control contour is used, the ent ire part layer must be formed by the subtractive processing of the deposited part materials. Near net shape part layer contours in the mask reduces the amount of subtractive processing, as would a discretized ma terials additive process. After subtractive processing of the part contours, complementary materials are deposited by the materials additive subsystem into empty regions of the work surface.
(7) Interlayer Processing and Preparation Subsystem
The interlayer processing and preparation subsystem 7, Fig. 7, consists of work surface preparations performed between each part layer as required by the computer and controls subsystem 1 , Fig. 2. These operations include surface treatment such as heating ( 18), roughening, grinding, leveling, etc. ( 16), addition of surfactants, binders, chemical barriers, alloying materials, etc. (20), and addition and/or configuration of fixtures. (8) Part Post-processing Subsystem
The part post-processing subsystem 8, Fig. 8, performs finishing operations on the completed part after it is removed from the part chamber. Such operations include removal of complementary malerials through oxidation or thermal/mechanical processes, Fig. 8A, and/or vaporization or dissolution. Fig. 8B, polishing, Fig. 8C, machining, heal treating, chemical t reatment, coatings application, and assembly.
DE TAILS OF OPERATION OF SUBSYS TEMS ( I ) THROUGH (8)
Referring to Fig.'s 2-8C, the automated rapid prototyping method of the invention based on selective deposition/removal of materials is performed with the sequences of operation previously summarized in the flow charts of Fig.'s 1 A and 1 B.
The computer and controls subsystem 1 , Fig. 2, embodies, as the controls generator and system monitor ( 12), for example, a commercially available computer with CAD/CAM slicing software, a user interface, and I/O hardware by which to communicate with other subsystems. The slicing software exists commercially, such as, for example, the CAMAND and ULTRACAM products from CAMAX Systems Inc., and can readily be modified and extended, as is well known in the art, to provide expert diagnosis capabilities based on materials and process variables as well as learning capabilities.
If utilized, the optional mask forming subsystem 2, Fig 's 3A-3 J, may consist of a machining station (22), Fig.'s 3A and 3E, at which continuous films or sets of sheets arc laser cut, on a system such as the Landmark laser marking system of AB Lasers Co., or machined by milling, Fig. 311, or punching to produce a precut contour for the part layer.
The precut masks, if made of complementary material and left in place, can also serve as complementary material contours for each layer. Graphite films or sheets are one possible choice of complementary material precut masks, and may be used for high temperature applications such as with parts involving tool steels or ceramics since graphite has a high moiling temperature. Graphite also oxidizes rapidly well below its melting point which facilitates removing the graphite complementary materials surrounding the finished part.
Different choices of complementary material may also be made depending on the process requirements. These complementary materials may then be removed by a variety of processes including heating, oxidation, solution bathing, vibration, ete.. The mask stock may be in the form of a continuous film loaded into the apparatus and advanced accordingly, Fig.'s 3A and 313, 3E and M1, and/or 311 and 31, or in the form of discrete sheets loaded sequentially, Fig.'s 3C and 3G, and/or 3J.
If utilized, the precut mask contours, Fig.'s 3A-3J, may be rough cuts of the desired part contour so as to reduce subsequent subtract ive processing and debris. Alternatively, the precut mask contours may be precision machined to within the tolerance of the desired part layer to minimize subsequent subtractive processing and debris. In general, the degree of precision in the mask formation process 2 would be at best equal to the precision of the materials subtractive process subsystem. Among the additional precut mask processing operations is the machining of the mask handling and positioning markings, Fig.'s 313, 3C, 3F, 3G, 3l and 3J. and the forming of removable bridges to any mask islands which were created intentionally in favor of employing subtractive processes in particular regions of the mask. If the precut masks arc not intended to be left as support structure, contour factorization. Fig. 3D may be used to prevent mask islands. The finished precul masks are conveyed to a mask buffer, Fig.'s 3A. 3E, and 311, from which they aic scheduled for accurate positioning, aligning, and flattening over the work surface in Fig. 4. The environmental control subsystem, 4, and the part processing enclosure subsystem, 3, arc shown in Fig. 4 as a scaled enclosure (4), with sensors, heaters/coolers, gas flow ducts and pumps, and windows, for directed energy beams and sensors. The part chamber preferably consists of a servo controlled piston in a cylinder encompassed in the lower chamber enclosure ( 14), and the current work surface, Fig. 4, is shown as the topmost surface within the cylinder. The part upper chamber processing enclosure (4), houses or provides access of the work surface to the environment contr ol subsystem 4, the malerials additive and subtractive processes subsystems 5 and 6, Fig.'s 5A-5H and 6A and 6B, and the interlayer processing subsystem 7, Fig. 7. In the embodiment of Fig. 4, the part chamber is mounted to a precision x-y-z positioning table, schematically represented by the 3-axis vector diagram, and the additive and subtractive subsystem apparatus are scheduled over the work surface The convention is used herein of schematically showing the required positioning tables as an axis vector diagram, such apparatus being well known and deemed unnecessary to complicate the drawings herein.
In a modified embodiment the part chamber may be mounted to a precision x and/or y and/or z positioning table and each additive and/or subtractive processing apparatus may be capable of x-y and/or z-axis motion in addition the motion of the work surface.
In still another embodiment, the part chamber may be fixed and the additive and/or the subtractive apparatus are capable of precision x-y and/or z motion. The processing enclosure and part chamber may be kept at elevated temperatures to reduce thermal cycling, residual stresses, and facilitate the materials additive processes and the formation of quality interlayer bonds, and may provide an inert and clean environment via debris and contaminant removal. The processing enclosure and the part chamber may be capable of pressure cycling for materials additive processing, interlayer processing, and/or debris removal at ( 1 1 ), Fig. 4. Additionally, the p rocessing enclosure and/or part chamber houses or provides access to material stock and mask buffers which supply the various processes inherent to part layer formation. The processing enclosure and chamber are designed and operated to regulate the level of oxygen, non-inert gasses (labeled "gas" in Fig. 4) and contaminants during the building of the part.
At the start of each layer one of two processing scenarios may be carried out based upon the particular embodiment and/or the volume fraction of part to complementary materials in the current layer.
Scenario One: Complementary material is selectively deposited first. Part material is subsequently deposited within the control contours provided by the complementary materials. Material processing operations before described, such as heating, chemical treating, or energy treating are then performed on the deposited part materials (and possibly complementary materials) contours by the materials additive system to ensure that the part (and possibly complementary) materials are within tolerance of prespecified material properties. Complementary material may be deposited by either placing a precut mask made of complementary material or selectively through the materials additive subsystem, and may be machined or selectively removed in addition. The precision of the precut mask contour and/or the complementary materials selective deposition apparatus is a parameter of the particular embodiment or apparatus.
Scenario Two: Part material is first selectively deposited. Complementary material may/may not be subsequently selectively deposited. Material processing operations such as heating, chemical treating, or energy treating are then performed on the deposited part material (and possibly complementary material) contours by the materials additive system to ensure that the part (and possibly complementary) materials are within tolerance of prespecified material properties. Part material may be deposited through a precut mask or selectively through the materials additive subsystem. The controlled deposition and extraction of part and complementary materials, as staled scenarios One and Two, is repealed to include all part and complementary materials predetermined for the part layer. At this point in the process, the layer is at least partially covered by deposited part materials and/or complementary materials within tolerance of their respective prespecified material properties. The materials subtractive subsystem then processes the part contours to arrive within the specified geometric tolerance of the part. Next, the materials additive subsystem completes the layer by depositing complementary material in any empty regions of the current layer in order to complete the layer. Materials processing of this additional complementary material may/may not be performed by the materials additive subsystem. Interlayer processing such as layer thickness control by surface machining and surface treatment and/or roughening, Fig. 7, is performed on the completed (aggregate) layer by the interlayer processing and preparation system in preparation for the next layer. All of the above occurs within a regulated environment dictated by the environment control subsystem 4 , Fig. 4, In a particular embodiment where the materials subtractive system is a laser machining system, the part contours may be surfaced machined in order to attain thickness tolerances before the materials subtractive system acts on the part contours.
In one version of the invention as previously described, the primary deposition system may consist of a powder dispenser, Fig. 5F which deposits powder onto the work surface. A roller or squeegee-like mechanism (R), is used to regulate the powder layer height and a mask may be used, if so desired, to control the contour of the powder layer. Both the layer materials processing and fusion bonding systems. Fig. 511, consist of a laser, such as the Diamond SL-64 made by Coherent General, electron beam, or other regional effect heat/energy source, and are employed within an appropriate environmental cycle (e.g. temperature and pressure) to ensure a dense, fusion bonded layer within tolerance of specified material properties, as is well known. This process adds both part and complementary materials to the work surface In a modified version, the primary deposition process may, as before described, consist of a powder or wire fed, multi-material plasma spraying system, Fig. 5E, (either multi-head or multi-material feeds) such as the SG-200 plasma spray gun based system made by Plasmadyne Co.. The plasma spraying parameters arc chosen to regulate the layer height, and a mask may also be used, if so desired, to control the deposited contour. The bonding in the plasma sprayed layer may be partially mechanical and partially from fusion, depending on the choice of spraying parameters such as stand-off distance, amperage, and gas velocity. To achieve predominantly fusion inter/intralayer bonding requires nontrivial spraying parameters, and thus a fusion bonding phase would preferably be utilized. The fusion bonding system consists of a laser or electron beam or other regional effect heat/energy source. Fig. 511, and is employed within an appropriate environmental cycle. (e.g. temperature and pressure, and gas concentration) to ensure a dense, fusion bonded layer within tolerance of its specified material properties. The additive processing of complementary materials need not include a fusion bonding phase provided that the plasma spraying parameters can be chosen to provide a suitable support structure Additionally, rapid solidification mechanisms such as localized cooling devices may be used if required for good material properties.
In still another embodiment, the primary deposition phase, Fig. 5G, may embody the previously described powder or wire fed, molten material dispenser. Multiple heads or multiple material feeds allows for multiple material deposition. The molten materials dispensing parameters are chosen to regulate the layer height and a mask may also be used, if so desired, to control the layer contour. The fusion bonding system, Fig. 511, as before, consists of a laser or electron beam or other regional effect heat/energy source and is employed within an appropriate environmental cycle (e.g. temperature, pressure, and gas concentrations) to ensure a dense, fusion bonded layer within tolerance of its specified material properties. The complementary materials additive process may employ either the molten materials dispenser or a plasma-spray head and may not require a full fusion bond to provide a suitable support structure.
In another modification, the primary deposition system. Fig. 5G, consists of a liquid dispenser for the before mentioned pre- cured resin or thermosetting materials or for materials in sol-gel or solution form (eg. ceramics). The dispensing parameters are again chosen to regulate the layer height, and a mask may also be used, if so desired, to control the layer contour. The same fusion bonding system of Fig. 511 and/or a general heal source through the environmental control subsystem may be used to cure the thermoset or evaporate the solvent to ensure a dense, fusion bonded layer within tolerance of its specified material properties. Any of the above mentioned additive processing apparatus may be employed for the complementary materials depending on the choice of complementary material. Upon formation of the layer with or without any masking, the precision subtractive processes of Fig.'s 6A and 613, arc employed to attain the exact geometry of the desired part. The materials subtractive processes subsystem consists, as before staled, of precision machining systems such as: milling, drilling, routing, grinding, Fig. 613, or laser or electron beam machining. Fig. 6A, or electrostatic discharge machining, as examples. Each such system is capable of operating within the environment required by the computer and controls subsystem. To this end, liquid and/or gas coolant or high temperature tooling may be employed. The choice of subtractive process largely depends on the materials and environment and thus various processes may be scheduled according to need. Debris removal, as at ( 1 1 ), Fig. 4. is required to maintain a contaminant lice environment in the part processing enclosure. Debris comes in the form of chips and/or loose powder and/or vapor and/or liquid from the various material deliveries, additive and sublraclivc processes, and possibly coolants.
Gas flows ("Gas", Fig. 4) may be used to blow material vapor, debris, and other unwanted products through gas ducts and fillers such as in the model 1005/1310 Fume Exhauster and Filtered Air Cleaner by KEI. Gas flows may also be used to clear areas only on the work surface, as needed. Gas flows may also be induced by high pressure nozzles or by vacuum diffusers which are opened within the part processing enclosure during a high pressure cycle The gas flows may be fixed locally to the subtractive processing apparatus to blow or suck debris as it is formed. More global gas flows may also be used to suck vapors out of the part processing enclosure with drainage paths employed to remove unvaporized liquids.
Subtractive processing the part layer to tolerance in Fig.'s 6A and 6B, moreover, may create empty areas of the work surface which require filling with complementary material.
The materials additive subsystem, Fig. 5A, discussed above, then accomplishes this task.
At Ibis point in the process, the part (aggregate) layer is formed to tolerance in the work surface plane, but not necessarily in the vertical plane (height or thickness of the layer).
The interlayer processing subsystem. Fig. 7, machines the completed layer to vertical tolerance (height) and surface-preps (roughening, adding alloying or bonding elements, chemical treating, etc.) the layer to facilitate the construction of the next part layer. In Fig.'s 7A-7C, a part is shown in Fig. 7A comprising 3 part materials, as an example, with the aggregate layer being shown in expanded view in Fig. 7C for a particular part layer of Pig. 713.
The sequences of operations outlined above are repealed until the entire part is built, as described in connection with the flow charts of Fig.'s 1 A and 1 B. The finished part is surrounded by complementary material which must be removed. The previously mentioned graphite, for example, can be removed by rapid oxidation, while other
complementary materials may be removed by thermal or mechanical shocking, chemical baths or melting as shown in Fig.'s 8A-8C.
Complementary material may have a melting point below that of part material, and thus may be removed by healing. Complementary material may be soluble in an appropriate liquid or gas based solvent for removal, and indeed, may be soluble in water— such as a variety of inorganic salts, certain waxes, or water soluble aluminum alloys. The complementary material(s) may include glass materials such as a borosilicate, soluble, for example, in solvents such as acetone, or may include ceramic materials of the like. As before stated, if graphite or a graphite-based material is used, such oxidizes readily under appropriate heating and/or oxygen concentrations. Thermal and/or mechanical cycling and/or shocking, as previously mentioned, may also be used for removing the complementary malerial(s). The invention is applicable to a wide variety of part materials including, as examples, metals and metallic alloys, thermoforming and thermosetting plastics, waxes, ceramics, glasses, graphites, and inorganics or various types, all such being depositable in multi- material, composite layers, as described. Further modifications will occur to those skilled in this art, and such as are considered to fall within the sphere and scope of the invention as defined in the appended claims.

Claims

WHAT IS CLAIMED IS:
1 A method of automated layerwise fabrication of a three-dimensional part from a computer model, through controlled deposition and extraction of materials, (hat comprises, producing a three-dimensional computer model representation or the part and, by software, slicing the same into a plurality of successive layers corresponding to layers of predetermined thickness(es) of the part; generating sequences of part and complementary support material(s) contours corresponding to each layer; depositing material(s) for one or more of said contours onto a work surface within a processing enclosure; material(s) processing said deposited contour(s) in order to achieve prespecified material properties for par t and complementary contours; removing portions of said material(s) from said contour(s) under the control of the computer model contour(s) corresponding thereto; repeating the depositing, processing, and removing as necessary under the control of the computer model corresponding to the layer to complete an aggregate layer comprising part material contours within prespecified geometric and material property tolerances and complementary material(s) elsewhere on the aggregate layer; completing the computer model layer by further processing said aggregate layer to ensure thickness tolerances and selective binding to the next aggregate layer; repeating said controlled layer creation steps to build the entire part surrounded by the complementary material/s; and removing said complementary material/s to obtain the fabricated part.
2. The method of claim 1 wherein the processing of said three-dimensional computer model into contours is done in a batch mode to obtain a full set of contours.
3. The method of claim 1 wherein the processing of said three- dimensional computer model for a given contour is performed as said given contour is needed by the process, with the slicing of the model occurring simultaneously with the part building.
4. The method of claim 1 wherein diagnostics and/or expert decision making arc used to furt her process computer model data and define the slice contours to facilitate the part-building process.
5. A method as claimed in claim 1 and in which the materials deposition is effected upon a pre-cut mask of complementary material, the cut of which corresponds to a corresponding software-slice contour, such that the mask is left in place as complementary support material toward the formation of the aggregate layer.
6. A method of claim 1 and in which the materials deposition is effected upon a pre-cut mask of material other than complementary material, and is removed prior to the formation of the aggregate layer.
7. The method of claim 5 in which a contour factorization approach is used such that there are no island contours lot any given mask.
8. The method of claim 1 in which the precut masks are machined frames on a continuous film that advances over the work surface, or machined individual sheds that are sequentially positioned over the work surface.
9. The method of claim 1 in which the mask forming system consists of a conventional machining or a laser/energy beam machining system.
10. The method of claim 1 wherein the part and/or complementary sections which for m the aggregate layer may consist of multiple materials.
PCT/IB1994/000256 1993-08-20 1994-08-22 Three-dimensional rapid prototyping WO1995005935A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE69427305T DE69427305T2 (en) 1993-08-20 1994-08-22 THREE-DIMENSIONAL PROTOTYPE QUICK BUILDING PROCESS
EP94923822A EP0722386B1 (en) 1993-08-20 1994-08-22 Three-dimensional rapid prototyping

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US110,144 1987-10-19
US08110144 US5398193B1 (en) 1993-08-20 1993-08-20 Method of three-dimensional rapid prototyping through controlled layerwise deposition/extraction and apparatus therefor

Publications (1)

Publication Number Publication Date
WO1995005935A1 true WO1995005935A1 (en) 1995-03-02

Family

ID=22331441

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB1994/000256 WO1995005935A1 (en) 1993-08-20 1994-08-22 Three-dimensional rapid prototyping

Country Status (4)

Country Link
US (1) US5398193B1 (en)
EP (1) EP0722386B1 (en)
DE (1) DE69427305T2 (en)
WO (1) WO1995005935A1 (en)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997011837A1 (en) * 1995-09-27 1997-04-03 3D Systems, Inc. Selective deposition modeling method and apparatus for forming three-dimensional objects and supports
WO1998046415A1 (en) * 1997-04-13 1998-10-22 Notar, Walter Method for making a three-dimensional body
US5943235A (en) * 1995-09-27 1999-08-24 3D Systems, Inc. Rapid prototyping system and method with support region data processing
US6162378A (en) * 1999-02-25 2000-12-19 3D Systems, Inc. Method and apparatus for variably controlling the temperature in a selective deposition modeling environment
US6193923B1 (en) 1995-09-27 2001-02-27 3D Systems, Inc. Selective deposition modeling method and apparatus for forming three-dimensional objects and supports
US6423255B1 (en) 2000-03-24 2002-07-23 Rainer Hoechsmann Method for manufacturing a structural part by deposition technique
US7183335B2 (en) 2000-03-13 2007-02-27 Objet Geometries Ltd. Compositions and methods for use in three dimensional model printing
CN101952023A (en) * 2007-10-08 2011-01-19 巴斯夫欧洲公司 Use of moulded bodies with catalytic properties as reactor fittings
US8460451B2 (en) 2011-02-23 2013-06-11 3D Systems, Inc. Support material and applications thereof
US8883392B2 (en) 2000-03-13 2014-11-11 Stratasys Ltd. Compositions and methods for use in three dimensional model printing
US8932511B2 (en) 2000-03-13 2015-01-13 Stratasys Ltd. Method of making a composite material by three-dimensional ink-jet printing
US9157007B2 (en) 2011-03-09 2015-10-13 3D Systems, Incorporated Build material and applications thereof
US9394441B2 (en) 2011-03-09 2016-07-19 3D Systems, Inc. Build material and applications thereof
DE102016000623A1 (en) 2016-01-09 2017-07-13 Gerald Krell Smart Brick (Intelligent Building Block)
CN108995219A (en) * 2018-05-31 2018-12-14 共享智能铸造产业创新中心有限公司 A kind of dicing method, 3D printing method and product of 3D printing that thickness is variable
EP3796116A3 (en) * 2016-09-15 2021-06-23 IO Tech Group, Ltd. Method and system for additive-ablative fabrication

Families Citing this family (193)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5435884A (en) * 1993-09-30 1995-07-25 Parker-Hannifin Corporation Spray nozzle and method of manufacturing same
GB9501987D0 (en) * 1995-02-01 1995-03-22 Butterworth Steven Dissolved medium rendered resin (DMRR) processing
US5779833A (en) * 1995-08-04 1998-07-14 Case Western Reserve University Method for constructing three dimensional bodies from laminations
US5837960A (en) * 1995-08-14 1998-11-17 The Regents Of The University Of California Laser production of articles from powders
US5746844A (en) * 1995-09-08 1998-05-05 Aeroquip Corporation Method and apparatus for creating a free-form three-dimensional article using a layer-by-layer deposition of molten metal and using a stress-reducing annealing process on the deposited metal
US5669433A (en) * 1995-09-08 1997-09-23 Aeroquip Corporation Method for creating a free-form metal three-dimensional article using a layer-by-layer deposition of a molten metal
US5787965A (en) * 1995-09-08 1998-08-04 Aeroquip Corporation Apparatus for creating a free-form metal three-dimensional article using a layer-by-layer deposition of a molten metal in an evacuation chamber with inert environment
US5718951A (en) * 1995-09-08 1998-02-17 Aeroquip Corporation Method and apparatus for creating a free-form three-dimensional article using a layer-by-layer deposition of a molten metal and deposition of a powdered metal as a support material
US5617911A (en) * 1995-09-08 1997-04-08 Aeroquip Corporation Method and apparatus for creating a free-form three-dimensional article using a layer-by-layer deposition of a support material and a deposition material
US5818718A (en) * 1996-04-01 1998-10-06 University Of Utah Research Foundation Higher order construction algorithm method for rapid prototyping
US6046426A (en) * 1996-07-08 2000-04-04 Sandia Corporation Method and system for producing complex-shape objects
US6021358A (en) * 1996-09-18 2000-02-01 Sachs; George A. Three dimensional model and mold making method using thick-slice subtractive fabrication
US6080343A (en) * 1997-03-17 2000-06-27 Sandia Corporation Methods for freeform fabrication of structures
IL121458A0 (en) * 1997-08-03 1998-02-08 Lipsker Daniel Rapid prototyping
US5936861A (en) * 1997-08-15 1999-08-10 Nanotek Instruments, Inc. Apparatus and process for producing fiber reinforced composite objects
US6027326A (en) * 1997-10-28 2000-02-22 Sandia Corporation Freeforming objects with low-binder slurry
US6401795B1 (en) * 1997-10-28 2002-06-11 Sandia Corporation Method for freeforming objects with low-binder slurry
US6203861B1 (en) 1998-01-12 2001-03-20 University Of Central Florida One-step rapid manufacturing of metal and composite parts
US5993554A (en) * 1998-01-22 1999-11-30 Optemec Design Company Multiple beams and nozzles to increase deposition rate
DE19831335A1 (en) * 1998-07-13 2000-02-10 Michael Angermann Appts to produce micro droplets of molten conductive metals uses a magneto-hydrodynamic pump with modulation to give a clean and controlled droplet ejection
US6129872A (en) * 1998-08-29 2000-10-10 Jang; Justin Process and apparatus for creating a colorful three-dimensional object
US7045015B2 (en) 1998-09-30 2006-05-16 Optomec Design Company Apparatuses and method for maskless mesoscale material deposition
GB9826728D0 (en) * 1998-12-04 1999-01-27 Rolls Royce Plc Method and apparatus for building up a workpiece by deposit welding
KR100291953B1 (en) * 1999-03-15 2001-06-01 윤덕용 Variable deposition manufacturing method and apparatus
US7620527B1 (en) 1999-05-10 2009-11-17 Johan Leo Alfons Gielis Method and apparatus for synthesizing and analyzing patterns utilizing novel “super-formula” operator
US6405095B1 (en) 1999-05-25 2002-06-11 Nanotek Instruments, Inc. Rapid prototyping and tooling system
US6306467B1 (en) 1999-06-14 2001-10-23 Ford Global Technologies, Inc. Method of solid free form fabrication of objects
US20060003095A1 (en) * 1999-07-07 2006-01-05 Optomec Design Company Greater angle and overhanging materials deposition
US6811744B2 (en) 1999-07-07 2004-11-02 Optomec Design Company Forming structures from CAD solid models
AU6747100A (en) 1999-07-07 2001-01-22 Optomec Design Company Method for providing features enabling thermal management in complex three-dimensional structures
US6519500B1 (en) 1999-09-16 2003-02-11 Solidica, Inc. Ultrasonic object consolidation
US6814823B1 (en) 1999-09-16 2004-11-09 Solidica, Inc. Object consolidation through sequential material deposition
DE19964099B4 (en) * 1999-12-31 2006-04-06 Götzen, Reiner, Dipl.-Ing. Method for producing three-dimensionally arranged guide and connection structures for volume and energy flows
US6627835B1 (en) * 2000-02-02 2003-09-30 Purdue Research Foundation Three dimensional object fabrication techniques
US6463349B2 (en) 2000-03-23 2002-10-08 Solidica, Inc. Ultrasonic object consolidation system and method
US6823230B1 (en) 2000-09-07 2004-11-23 Honeywell International Inc. Tool path planning process for component by layered manufacture
US6682684B1 (en) 2000-09-07 2004-01-27 Honeywell International Inc. Procedures for rapid build and improved surface characteristics in layered manufacture
US7050876B1 (en) 2000-10-06 2006-05-23 Phonak Ltd. Manufacturing methods and systems for rapid production of hearing-aid shells
US6805946B2 (en) * 2000-12-04 2004-10-19 Advanced Ceramics Research, Inc. Multi-functional composite structures
US6803003B2 (en) * 2000-12-04 2004-10-12 Advanced Ceramics Research, Inc. Compositions and methods for preparing multiple-component composite materials
US6847699B2 (en) 2000-12-04 2005-01-25 Advanced Ceramics Research, Inc. Composite components for use in high temperature applications
US6797220B2 (en) * 2000-12-04 2004-09-28 Advanced Ceramics Research, Inc. Methods for preparation of three-dimensional bodies
US6740286B2 (en) * 2000-12-04 2004-05-25 Advanced Ceramics Research, Inc. Consolidation and densification methods for fibrous monolith processing
US6974624B2 (en) * 2000-12-04 2005-12-13 Advanced Ceramics Research, Inc. Aligned composite structures for mitigation of impact damage and resistance to wear in dynamic environments
US6709737B2 (en) * 2000-12-04 2004-03-23 Advanced Ceramics Research, Inc. Aligned composite structures for mitigation of impact damage and resistance to wear in dynamic environments
US7029621B2 (en) * 2001-03-01 2006-04-18 Schroeder Ernest C Apparatus and method of fabricating fiber reinforced plastic parts
CA2448736C (en) 2001-06-05 2010-08-10 Mikro Systems, Inc. Methods for manufacturing three-dimensional devices and devices created thereby
US7141812B2 (en) 2002-06-05 2006-11-28 Mikro Systems, Inc. Devices, methods, and systems involving castings
US7785098B1 (en) 2001-06-05 2010-08-31 Mikro Systems, Inc. Systems for large area micro mechanical systems
DE10157647C5 (en) * 2001-11-26 2012-03-08 Cl Schutzrechtsverwaltungs Gmbh Method for producing three-dimensional workpieces in a laser material processing system or a stereolithography system
US20040107019A1 (en) * 2002-07-18 2004-06-03 Shyam Keshavmurthy Automated rapid prototyping combining additive and subtractive processes
US20040075197A1 (en) * 2002-10-21 2004-04-22 Hwa-Hsing Tang Method for rapid forming of a ceramic green part
US20060147332A1 (en) * 2004-12-30 2006-07-06 Howmedica Osteonics Corp. Laser-produced porous structure
CA2448592C (en) 2002-11-08 2011-01-11 Howmedica Osteonics Corp. Laser-produced porous surface
US7589868B2 (en) * 2002-12-11 2009-09-15 Agfa Graphics Nv Method and apparatus for creating 3D-prints and a 3-D printing system
US20040121182A1 (en) * 2002-12-23 2004-06-24 Hardwicke Canan Uslu Method and composition to repair and build structures
AU2003900180A0 (en) * 2003-01-16 2003-01-30 Silverbrook Research Pty Ltd Method and apparatus (dam001)
FR2857889B1 (en) * 2003-07-23 2005-09-23 Snecma Moteurs PROCESS FOR PRODUCING PARTS BY PRECISION FORGING
US6898477B2 (en) * 2003-08-14 2005-05-24 Hewlett-Packard Development Company, L.P. System and method for performing adaptive modification of rapid prototyping build files
US6994245B2 (en) * 2003-10-17 2006-02-07 James M. Pinchot Micro-reactor fabrication
US20050084072A1 (en) * 2003-10-17 2005-04-21 Jmp Industries, Inc., An Ohio Corporation Collimator fabrication
US8066955B2 (en) * 2003-10-17 2011-11-29 James M. Pinchot Processing apparatus fabrication
US7001672B2 (en) * 2003-12-03 2006-02-21 Medicine Lodge, Inc. Laser based metal deposition of implant structures
US7666522B2 (en) * 2003-12-03 2010-02-23 IMDS, Inc. Laser based metal deposition (LBMD) of implant structures
US7261542B2 (en) * 2004-03-18 2007-08-28 Desktop Factory, Inc. Apparatus for three dimensional printing using image layers
US7556490B2 (en) * 2004-07-30 2009-07-07 Board Of Regents, The University Of Texas System Multi-material stereolithography
DE102004057527B4 (en) * 2004-11-29 2007-06-21 Carl Johannes Fruth Method for electrochemical machining of a workpiece and electrode for such a method
US7938341B2 (en) * 2004-12-13 2011-05-10 Optomec Design Company Miniature aerosol jet and aerosol jet array
US7674671B2 (en) 2004-12-13 2010-03-09 Optomec Design Company Aerodynamic jetting of aerosolized fluids for fabrication of passive structures
US7658603B2 (en) * 2005-03-31 2010-02-09 Board Of Regents, The University Of Texas System Methods and systems for integrating fluid dispensing technology with stereolithography
US7419630B2 (en) * 2005-04-22 2008-09-02 Sandia Corporation Methods and systems for rapid prototyping of high density circuits
US7780897B2 (en) * 2005-04-22 2010-08-24 Board Of Regents, The University Of Texas System Hydrogel constructs using stereolithography
US7676298B2 (en) * 2005-06-08 2010-03-09 Crc For Advanced Composite Structures Limited Method and apparatus for surface shaping of polymer composite components
US20070013724A1 (en) * 2005-07-13 2007-01-18 Swift Lawrence W Building of scaled physical models
US20070042327A1 (en) * 2005-08-19 2007-02-22 Swift Lawrence W Determination of scaling for scaled physical architectural models
US7296990B2 (en) * 2005-10-14 2007-11-20 Hewlett-Packard Development Company, L.P. Systems and methods of solid freeform fabrication with translating powder bins
US20070122560A1 (en) * 2005-11-30 2007-05-31 Honeywell International, Inc. Solid-free-form fabrication process including in-process component deformation
US7301120B2 (en) * 2005-11-30 2007-11-27 Honeywell International, Inc. Ion fusion formation process including precise heat input and temperature control
US8728387B2 (en) * 2005-12-06 2014-05-20 Howmedica Osteonics Corp. Laser-produced porous surface
US20070154634A1 (en) * 2005-12-15 2007-07-05 Optomec Design Company Method and Apparatus for Low-Temperature Plasma Sintering
CA2572095C (en) * 2005-12-30 2009-12-08 Howmedica Osteonics Corp. Laser-produced implants
US7879394B1 (en) 2006-06-02 2011-02-01 Optomec, Inc. Deep deposition head
US7951412B2 (en) * 2006-06-07 2011-05-31 Medicinelodge Inc. Laser based metal deposition (LBMD) of antimicrobials to implant surfaces
US8147861B2 (en) 2006-08-15 2012-04-03 Howmedica Osteonics Corp. Antimicrobial implant
US8604381B1 (en) * 2006-10-12 2013-12-10 Purdue Research Foundation Integrated laser material processing cell
US20080116584A1 (en) * 2006-11-21 2008-05-22 Arkalgud Sitaram Self-aligned through vias for chip stacking
DE102007017762B4 (en) * 2007-04-16 2016-12-29 Hermle Maschinenbau Gmbh Method for producing a workpiece with at least one free space
DE102007017754B4 (en) * 2007-04-16 2016-12-29 Hermle Maschinenbau Gmbh Method for producing a workpiece with at least one free space
DE102007017758A1 (en) * 2007-04-16 2008-10-23 Innovaris Gmbh & Co. Kg Process for the production of complex components
DE102007019329A1 (en) * 2007-04-24 2008-10-30 Innovaris Gmbh & Co. Kg Components produced by thermal spraying from predominantly metallic materials
US10226919B2 (en) 2007-07-18 2019-03-12 Voxeljet Ag Articles and structures prepared by three-dimensional printing method
DE102007033715A1 (en) 2007-07-19 2009-01-22 Siemens Ag A method of applying a multi-material product layer to a molded article
WO2009014718A1 (en) * 2007-07-24 2009-01-29 Porex Corporation Porous laser sintered articles
WO2009013751A2 (en) * 2007-07-25 2009-01-29 Objet Geometries Ltd. Solid freeform fabrication using a plurality of modeling materials
US11161308B2 (en) 2007-07-25 2021-11-02 Stratasys Ltd. Solid freeform fabrication using a plurality of modeling materials
TWI482662B (en) 2007-08-30 2015-05-01 Optomec Inc Mechanically integrated and closely coupled print head and mist source
DE102007050953A1 (en) 2007-10-23 2009-04-30 Voxeljet Technology Gmbh Device for the layered construction of models
US8940219B2 (en) 2007-12-31 2015-01-27 Ronald D. Spoor Ophthalmic device formed by additive fabrication and method thereof
DE102008012063B4 (en) * 2008-02-29 2016-01-07 Cl Schutzrechtsverwaltungs Gmbh Process for the preparation of a hybrid molding
DE102008012064B4 (en) * 2008-02-29 2015-07-09 Cl Schutzrechtsverwaltungs Gmbh Method and device for producing a hybrid molding produced by a hybrid process and hybrid molding produced by the process
US8452440B2 (en) * 2008-04-22 2013-05-28 Materials Solutions Method of forming an article
US8491830B2 (en) * 2008-07-11 2013-07-23 Eoplex Limited Boundary configurations for multi-material print-forming
GB0816310D0 (en) 2008-09-05 2008-10-15 Mtt Technologies Ltd Filter assembly
US9315663B2 (en) * 2008-09-26 2016-04-19 Mikro Systems, Inc. Systems, devices, and/or methods for manufacturing castings
GB2472783B (en) * 2009-08-14 2012-05-23 Norsk Titanium Components As Device for manufacturing titanium objects
DE102010013732A1 (en) 2010-03-31 2011-10-06 Voxeljet Technology Gmbh Device for producing three-dimensional models
DE102010014969A1 (en) 2010-04-14 2011-10-20 Voxeljet Technology Gmbh Device for producing three-dimensional models
CN101817121B (en) * 2010-04-15 2012-03-28 华中科技大学 Deposition forming composite manufacturing method of part and mould and auxiliary device thereof
DE102010015451A1 (en) 2010-04-17 2011-10-20 Voxeljet Technology Gmbh Method and device for producing three-dimensional objects
US9156204B2 (en) * 2010-05-17 2015-10-13 Synerdyne Corporation Hybrid scanner fabricator
US8905742B2 (en) 2010-09-17 2014-12-09 Synerdyne Corporation Compact rotary platen 3D printer
US8479795B2 (en) 2010-09-17 2013-07-09 Synerdyne Corporation System and method for rapid fabrication of arbitrary three-dimensional objects
DE102010056346A1 (en) 2010-12-29 2012-07-05 Technische Universität München Method for the layered construction of models
DE102011007957A1 (en) 2011-01-05 2012-07-05 Voxeljet Technology Gmbh Device and method for constructing a layer body with at least one body limiting the construction field and adjustable in terms of its position
DE102011111498A1 (en) 2011-08-31 2013-02-28 Voxeljet Technology Gmbh Device for the layered construction of models
US8813824B2 (en) 2011-12-06 2014-08-26 Mikro Systems, Inc. Systems, devices, and/or methods for producing holes
US8877108B2 (en) * 2011-12-29 2014-11-04 Nike, Inc. System and method for making a golf ball having a patterned surface
US9364896B2 (en) 2012-02-07 2016-06-14 Medical Modeling Inc. Fabrication of hybrid solid-porous medical implantable devices with electron beam melting technology
DE102012004213A1 (en) 2012-03-06 2013-09-12 Voxeljet Technology Gmbh Method and device for producing three-dimensional models
US9180010B2 (en) 2012-04-06 2015-11-10 Howmedica Osteonics Corp. Surface modified unit cell lattice structures for optimized secure freeform fabrication
US9135374B2 (en) 2012-04-06 2015-09-15 Howmedica Osteonics Corp. Surface modified unit cell lattice structures for optimized secure freeform fabrication
DE102012010272A1 (en) 2012-05-25 2013-11-28 Voxeljet Technology Gmbh Method for producing three-dimensional models with special construction platforms and drive systems
DE102012012363A1 (en) 2012-06-22 2013-12-24 Voxeljet Technology Gmbh Apparatus for building up a layer body with a storage or filling container movable along the discharge container
AU2013318709A1 (en) 2012-09-24 2015-04-09 The Antenna Company International N.V. Lens antenna, method of manufacturing and using such an antenna, and antenna system
DE102012020000A1 (en) 2012-10-12 2014-04-17 Voxeljet Ag 3D multi-stage process
DE102013004940A1 (en) 2012-10-15 2014-04-17 Voxeljet Ag Method and device for producing three-dimensional models with tempered printhead
DE102012022859A1 (en) 2012-11-25 2014-05-28 Voxeljet Ag Construction of a 3D printing device for the production of components
US9040867B2 (en) * 2012-12-21 2015-05-26 United Technologies Corporation Manufacturing machine with magnetic field beam steering
US8904847B2 (en) 2013-02-28 2014-12-09 Rolls-Royce Corporation Laminated cavity tooling
DE102013003303A1 (en) 2013-02-28 2014-08-28 FluidSolids AG Process for producing a molded part with a water-soluble casting mold and material system for its production
US10543549B2 (en) * 2013-07-16 2020-01-28 Illinois Tool Works Inc. Additive manufacturing system for joining and surface overlay
DE102013018182A1 (en) 2013-10-30 2015-04-30 Voxeljet Ag Method and device for producing three-dimensional models with binder system
DE102013018031A1 (en) 2013-12-02 2015-06-03 Voxeljet Ag Swap body with movable side wall
DE102013020491A1 (en) 2013-12-11 2015-06-11 Voxeljet Ag 3D infiltration process
EP2886307A1 (en) 2013-12-20 2015-06-24 Voxeljet AG Device, special paper and method for the production of moulded components
CN106029333B (en) * 2014-02-24 2018-06-12 英派尔科技开发有限公司 The interlayer adhesion of increased 3 D-printing article
WO2015147635A1 (en) 2014-03-26 2015-10-01 The Antenna Company International N.V. Patch antenna, method of manufacturing and using such an antenna, and antenna system
DE102014004692A1 (en) 2014-03-31 2015-10-15 Voxeljet Ag Method and apparatus for 3D printing with conditioned process control
DE102014007584A1 (en) 2014-05-26 2015-11-26 Voxeljet Ag 3D reverse printing method and apparatus
US10946556B2 (en) 2014-08-02 2021-03-16 Voxeljet Ag Method and casting mold, in particular for use in cold casting methods
DE102015004570A1 (en) * 2014-08-05 2016-02-11 Miranda Fateri Additive manufacturing method and apparatus for carrying out the additive manufacturing method
EP3218160A4 (en) * 2014-11-14 2018-10-17 Nielsen-Cole, Cole Additive manufacturing techniques and systems to form composite materials
WO2016079494A2 (en) 2014-11-21 2016-05-26 Renishaw Plc Additive manufacturing apparatus and methods
DE102015006533A1 (en) 2014-12-22 2016-06-23 Voxeljet Ag Method and device for producing 3D molded parts with layer construction technique
EP3228404A4 (en) * 2014-12-30 2018-09-19 Yuanmeng Precision Technology (Shenzhen) Institut Multi-electron-beam melting and milling composite 3d printing apparatus
US20160325383A1 (en) * 2014-12-30 2016-11-10 Yuanmeng Precision Technology (Shenzhen) Institute Electron beam melting and laser milling composite 3d printing apparatus
US10994473B2 (en) 2015-02-10 2021-05-04 Optomec, Inc. Fabrication of three dimensional structures by in-flight curing of aerosols
US10218509B2 (en) 2015-03-02 2019-02-26 Xerox Corporation System to authenticate 3D printed objects
DE102015003372A1 (en) 2015-03-17 2016-09-22 Voxeljet Ag Method and device for producing 3D molded parts with double recoater
DE102015006363A1 (en) 2015-05-20 2016-12-15 Voxeljet Ag Phenolic resin method
US10195784B2 (en) 2015-07-31 2019-02-05 The Boeing Company Systems for additively manufacturing composite parts
US10232570B2 (en) 2015-07-31 2019-03-19 The Boeing Company Systems for additively manufacturing composite parts
US10201941B2 (en) 2015-07-31 2019-02-12 The Boeing Company Systems for additively manufacturing composite parts
US10343330B2 (en) 2015-07-31 2019-07-09 The Boeing Company Systems for additively manufacturing composite parts
US10232550B2 (en) 2015-07-31 2019-03-19 The Boeing Company Systems for additively manufacturing composite parts
US10343355B2 (en) 2015-07-31 2019-07-09 The Boeing Company Systems for additively manufacturing composite parts
US10279580B2 (en) * 2015-07-31 2019-05-07 The Boeing Company Method for additively manufacturing composite parts
DE102015011503A1 (en) 2015-09-09 2017-03-09 Voxeljet Ag Method for applying fluids
DE102015011790A1 (en) 2015-09-16 2017-03-16 Voxeljet Ag Device and method for producing three-dimensional molded parts
DE102015015353A1 (en) 2015-12-01 2017-06-01 Voxeljet Ag Method and device for producing three-dimensional components by means of an excess quantity sensor
US20170355133A1 (en) * 2016-06-13 2017-12-14 Yoshihito Shimada Method of manufacturing solid freeform fabrication object
US10457033B2 (en) 2016-11-07 2019-10-29 The Boeing Company Systems and methods for additively manufacturing composite parts
US11440261B2 (en) 2016-11-08 2022-09-13 The Boeing Company Systems and methods for thermal control of additive manufacturing
DE102016013610A1 (en) 2016-11-15 2018-05-17 Voxeljet Ag Intra-head printhead maintenance station for powder bed-based 3D printing
US10766241B2 (en) 2016-11-18 2020-09-08 The Boeing Company Systems and methods for additive manufacturing
US10843452B2 (en) 2016-12-01 2020-11-24 The Boeing Company Systems and methods for cure control of additive manufacturing
US10576683B2 (en) 2017-01-16 2020-03-03 The Boeing Company Multi-part filaments for additive manufacturing and related systems and methods
US11298747B2 (en) 2017-05-18 2022-04-12 Howmedica Osteonics Corp. High fatigue strength porous structure
US10759159B2 (en) 2017-05-31 2020-09-01 The Boeing Company Feedstock lines for additive manufacturing
US10656626B2 (en) * 2017-06-01 2020-05-19 Proto Labs, Inc. Methods and software for manufacturing a discrete object from an additively manufactured body of material including a precursor to a discrete object and a reference feature(s)
US10814550B2 (en) 2017-07-06 2020-10-27 The Boeing Company Methods for additive manufacturing
US10821672B2 (en) 2017-07-06 2020-11-03 The Boeing Company Methods for additive manufacturing
DE102017006860A1 (en) 2017-07-21 2019-01-24 Voxeljet Ag Method and device for producing 3D molded parts with spectrum converter
CN111448068A (en) * 2017-09-12 2020-07-24 马格纳斯金属有限公司 Apparatus and method for additive casting of parts
US10611081B2 (en) 2017-09-15 2020-04-07 The Boeing Company Systems and methods for creating feedstock lines for additive manufacturing of an object
US10603890B2 (en) 2017-09-15 2020-03-31 The Boeing Company Systems and methods for creating feedstock lines for additive manufacturing of an object
US10189237B1 (en) 2017-09-15 2019-01-29 The Boeing Company Feedstock lines for additive manufacturing of an object
US10525635B2 (en) 2017-09-15 2020-01-07 The Boeing Company Systems and methods for creating feedstock lines for additive manufacturing of an object
US10543645B2 (en) 2017-09-15 2020-01-28 The Boeing Company Feedstock lines for additive manufacturing of an object
US10105893B1 (en) 2017-09-15 2018-10-23 The Boeing Company Feedstock lines for additive manufacturing of an object, and systems and methods for creating feedstock lines
US10618222B2 (en) 2017-09-15 2020-04-14 The Boeing Company Systems and methods for additively manufacturing an object
US10828723B2 (en) 2017-11-13 2020-11-10 General Electric Company Process monitoring for mobile large scale additive manufacturing using foil-based build materials
CN111655382B (en) 2017-11-13 2022-05-31 奥普托美克公司 Blocking of aerosol flow
US20190143585A1 (en) * 2017-11-13 2019-05-16 General Electric Company Additively manufactured vertical wall from slurry
US11364564B2 (en) 2017-11-13 2022-06-21 General Electric Company Mobile large scale additive manufacturing using foil-based build materials
US10828724B2 (en) 2017-11-13 2020-11-10 General Electric Company Foil part vectorization for mobile large scale additive manufacturing using foil-based build materials
US10894299B2 (en) 2017-11-13 2021-01-19 General Electric Company Fixed bed large scale additive manufacturing using foil-based build materials
EP3797026A4 (en) 2018-05-22 2022-03-02 Mantle Inc. Method and system for automated toolpath generation
WO2020037732A1 (en) * 2018-08-24 2020-02-27 苏州中瑞智创三维科技股份有限公司 Shape-adapting manufacturing method for three-dimensional printing using high-viscosity material
DE102019000796A1 (en) 2019-02-05 2020-08-06 Voxeljet Ag Exchangeable process unit
DE102019007595A1 (en) 2019-11-01 2021-05-06 Voxeljet Ag 3D PRINTING PROCESS AND MOLDED PART MANUFACTURED WITH LIGNINE SULPHATE
US20230166356A1 (en) * 2020-05-05 2023-06-01 Alloy Enterprises, Inc. Support structures for laminated metallic parts
CN115008751B (en) * 2022-05-27 2023-03-21 西安交通大学 Large-scale powder bed of adjustable velocity of flow direction increase and decrease material equipment dust pelletizing system that discharges fume

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01218434A (en) * 1988-02-25 1989-08-31 Toshiba Corp Image diagnosing device
JPH0365774A (en) * 1989-08-02 1991-03-20 Matsushita Electric Ind Co Ltd Three-dimensional measured result display device
WO1992008200A1 (en) * 1990-10-30 1992-05-14 3D Systems, Inc. Layer comparison techniques in stereolithography
EP0490546A1 (en) * 1990-12-03 1992-06-17 Fritz B. Prinz Method and apparatus for fabrication of three-dimensional articles by thermal spray deposition
EP0523981A1 (en) * 1991-07-15 1993-01-20 Fritz B. Prinz Method of making electronic packages and smart structures formed by thermal spray deposition
EP0606627A1 (en) * 1993-01-15 1994-07-20 Stratasys Inc. Method and apparatus employing sequential two-dimensional geometry for producing shells for fabrication by a rapid prototyping system

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4665492A (en) * 1984-07-02 1987-05-12 Masters William E Computer automated manufacturing process and system
US5236637A (en) * 1984-08-08 1993-08-17 3D Systems, Inc. Method of and apparatus for production of three dimensional objects by stereolithography
US4575330A (en) * 1984-08-08 1986-03-11 Uvp, Inc. Apparatus for production of three-dimensional objects by stereolithography
US5263130A (en) * 1986-06-03 1993-11-16 Cubital Ltd. Three dimensional modelling apparatus
US4752352A (en) * 1986-06-06 1988-06-21 Michael Feygin Apparatus and method for forming an integral object from laminations
US4863538A (en) * 1986-10-17 1989-09-05 Board Of Regents, The University Of Texas System Method and apparatus for producing parts by selective sintering
US5287435A (en) * 1987-06-02 1994-02-15 Cubital Ltd. Three dimensional modeling
US5256340A (en) * 1988-04-18 1993-10-26 3D Systems, Inc. Method of making a three-dimensional object by stereolithography
US5182056A (en) * 1988-04-18 1993-01-26 3D Systems, Inc. Stereolithography method and apparatus employing various penetration depths
US5121329A (en) * 1989-10-30 1992-06-09 Stratasys, Inc. Apparatus and method for creating three-dimensional objects
JP2597778B2 (en) * 1991-01-03 1997-04-09 ストラタシイス,インコーポレイテッド Three-dimensional object assembling system and assembling method
ATE131111T1 (en) * 1991-01-31 1995-12-15 Texas Instruments Inc METHOD AND DEVICE FOR THE COMPUTER-CONTROLLED PRODUCTION OF THREE-DIMENSIONAL OBJECTS FROM COMPUTER DATA.

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01218434A (en) * 1988-02-25 1989-08-31 Toshiba Corp Image diagnosing device
JPH0365774A (en) * 1989-08-02 1991-03-20 Matsushita Electric Ind Co Ltd Three-dimensional measured result display device
WO1992008200A1 (en) * 1990-10-30 1992-05-14 3D Systems, Inc. Layer comparison techniques in stereolithography
EP0490546A1 (en) * 1990-12-03 1992-06-17 Fritz B. Prinz Method and apparatus for fabrication of three-dimensional articles by thermal spray deposition
EP0523981A1 (en) * 1991-07-15 1993-01-20 Fritz B. Prinz Method of making electronic packages and smart structures formed by thermal spray deposition
EP0606627A1 (en) * 1993-01-15 1994-07-20 Stratasys Inc. Method and apparatus employing sequential two-dimensional geometry for producing shells for fabrication by a rapid prototyping system

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 13, no. 532 (C - 659) 28 November 1989 (1989-11-28) *
PATENT ABSTRACTS OF JAPAN vol. 15, no. 224 (P - 1212) 7 June 1991 (1991-06-07) *

Cited By (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6532394B1 (en) 1995-09-27 2003-03-11 3D Systems, Inc. Method and apparatus for data manipulation and system control in a selective deposition modeling system
US5943235A (en) * 1995-09-27 1999-08-24 3D Systems, Inc. Rapid prototyping system and method with support region data processing
US6660209B2 (en) 1995-09-27 2003-12-09 3D Systems, Inc. Selective deposition modeling method and apparatus for forming three-dimensional objects and supports
WO1997011837A1 (en) * 1995-09-27 1997-04-03 3D Systems, Inc. Selective deposition modeling method and apparatus for forming three-dimensional objects and supports
US6508971B2 (en) 1995-09-27 2003-01-21 3D Systems, Inc. Selective deposition modeling method and apparatus for forming three-dimensional objects and supports
US6193923B1 (en) 1995-09-27 2001-02-27 3D Systems, Inc. Selective deposition modeling method and apparatus for forming three-dimensional objects and supports
US6270335B2 (en) 1995-09-27 2001-08-07 3D Systems, Inc. Selective deposition modeling method and apparatus for forming three-dimensional objects and supports
SG87044A1 (en) * 1995-09-27 2002-03-19 3D Systems Inc Selective deposition modeling method and apparatus for forming three-dimensional objects and supports
US7077638B2 (en) 1995-09-27 2006-07-18 3D Systems, Inc. Selective deposition modeling method and apparatus for forming three-dimensional objects and supports
US6193922B1 (en) 1997-04-13 2001-02-27 Ingo Ederer Method for making a three-dimensional body
WO1998046415A1 (en) * 1997-04-13 1998-10-22 Notar, Walter Method for making a three-dimensional body
US6162378A (en) * 1999-02-25 2000-12-19 3D Systems, Inc. Method and apparatus for variably controlling the temperature in a selective deposition modeling environment
US7479510B2 (en) 2000-03-13 2009-01-20 Objet Geometries Ltd. Compositions and methods for use in three dimensional model printing
US7183335B2 (en) 2000-03-13 2007-02-27 Objet Geometries Ltd. Compositions and methods for use in three dimensional model printing
US8883392B2 (en) 2000-03-13 2014-11-11 Stratasys Ltd. Compositions and methods for use in three dimensional model printing
US9334402B2 (en) 2000-03-13 2016-05-10 Stratasys Ltd. Compositions and methods for use in three dimensional model printing
US8932511B2 (en) 2000-03-13 2015-01-13 Stratasys Ltd. Method of making a composite material by three-dimensional ink-jet printing
US10335994B2 (en) 2000-03-13 2019-07-02 Stratasys Ltd Methods for three-dimensional model printing
US9744720B2 (en) 2000-03-13 2017-08-29 Stratasys Ltd. Methods for three dimensional model printing
US6423255B1 (en) 2000-03-24 2002-07-23 Rainer Hoechsmann Method for manufacturing a structural part by deposition technique
CN101952023A (en) * 2007-10-08 2011-01-19 巴斯夫欧洲公司 Use of moulded bodies with catalytic properties as reactor fittings
CN101952023B (en) * 2007-10-08 2013-09-04 巴斯夫欧洲公司 Use of moulded bodies with catalytic properties as reactor fittings
US8460451B2 (en) 2011-02-23 2013-06-11 3D Systems, Inc. Support material and applications thereof
US9534103B2 (en) 2011-02-23 2017-01-03 3D Systems, Inc. Support material and applications thereof
US10232529B2 (en) 2011-02-23 2019-03-19 3D Systems, Inc. Support material and applications thereof
US9604408B2 (en) 2011-03-09 2017-03-28 3D Systems, Inc. Build material and applications thereof
US9394441B2 (en) 2011-03-09 2016-07-19 3D Systems, Inc. Build material and applications thereof
US9157007B2 (en) 2011-03-09 2015-10-13 3D Systems, Incorporated Build material and applications thereof
DE102016000623A1 (en) 2016-01-09 2017-07-13 Gerald Krell Smart Brick (Intelligent Building Block)
EP3796116A3 (en) * 2016-09-15 2021-06-23 IO Tech Group, Ltd. Method and system for additive-ablative fabrication
US11370174B2 (en) 2016-09-15 2022-06-28 Io Tech Group Ltd. Method and system for additive-ablative fabrication
US11420397B2 (en) 2016-09-15 2022-08-23 Io Tech Group Ltd. Method and system for additive-ablative fabrication
CN108995219A (en) * 2018-05-31 2018-12-14 共享智能铸造产业创新中心有限公司 A kind of dicing method, 3D printing method and product of 3D printing that thickness is variable

Also Published As

Publication number Publication date
DE69427305T2 (en) 2002-05-08
EP0722386B1 (en) 2001-05-23
EP0722386A1 (en) 1996-07-24
DE69427305D1 (en) 2001-06-28
US5398193B1 (en) 1997-09-16
US5398193A (en) 1995-03-14

Similar Documents

Publication Publication Date Title
EP0722386B1 (en) Three-dimensional rapid prototyping
Dilberoglu et al. Current trends and research opportunities in hybrid additive manufacturing
EP3756798B1 (en) Additive manufacturing method and device for ceramic and composite thereof
US6193922B1 (en) Method for making a three-dimensional body
EP0529816B1 (en) Method and apparatus for fabrication of three-dimensional articles by weld deposition
US5354414A (en) Apparatus and method for forming an integral object from laminations
Pham et al. Rapid manufacturing: the technologies and applications of rapid prototyping and rapid tooling
EP1773804B1 (en) Sls for tooling applications
EP2319641B1 (en) Method to apply multiple materials with selective laser melting on a 3D article
AU698219B2 (en) Free form article by layer deposition
CA2224769C (en) Article made by layer deposition of metal
US5746844A (en) Method and apparatus for creating a free-form three-dimensional article using a layer-by-layer deposition of molten metal and using a stress-reducing annealing process on the deposited metal
JP2003505250A (en) Apparatus and method for preparing building components from a combination of materials
Bourell et al. Solid freeform fabrication an advanced manufacturing approach
JP2000296561A (en) Variable weld lamination type rapid shaping method and apparatus
Kreutz et al. Rapid prototyping with CO2 laser radiation
CN104550954A (en) Forming method of meal piece through composite milling in 3D (Three-dimensional) printing
Hartmann et al. Robot-assisted shape deposition manufacturing
Kumar Additive Manufacturing Solutions
Karunakaran et al. Hybrid layered manufacturing: direct rapid metal tool-making process
JPH0318484A (en) Method for forming three-dimensional object and device used therein
Medelli´ n-Castillo et al. Rapid prototyping and manufacturing: A review of current technologies
Pham et al. Rapid prototyping processes
Weiss Processes overview
Singh et al. Additive Manufacturing Technologies and Post‐processing, Design Optimization, and Material Considerations for Reliable Printing

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): CA CN JP KP KR

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 1994923822

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1994923822

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

NENP Non-entry into the national phase

Ref country code: CA

WWG Wipo information: grant in national office

Ref document number: 1994923822

Country of ref document: EP