WO1995003782A1 - Pearlescent based concentrate for personal care products - Google Patents
Pearlescent based concentrate for personal care products Download PDFInfo
- Publication number
- WO1995003782A1 WO1995003782A1 PCT/AU1994/000421 AU9400421W WO9503782A1 WO 1995003782 A1 WO1995003782 A1 WO 1995003782A1 AU 9400421 W AU9400421 W AU 9400421W WO 9503782 A1 WO9503782 A1 WO 9503782A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- group
- chosen
- formula
- pearlescent
- alkyl
- Prior art date
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0089—Pearlescent compositions; Opacifying agents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/143—Sulfonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
Definitions
- the invention relates to pearlescent based concentrates comprising at least one al ylpolysaccharide, traditional pearlescent esters or acid and alkyl sulphates and to processes for the preparation thereof.
- Personal care products such as handsoaps, bubble baths, shampoos and hair conditioners often include in their composition agents which impart a pleasant, pearl-like glossy appearance in order to enhance the appeal of such products to the consumer.
- the agents which impart this appearance are known as pearlescent based concentrates and generally comprise microscopic platelike crystals which remain dispersed in compositions to which they are added and reflect light in such a manner as to impart a pearl-like appearance.
- Pearlescent based concentrates of the prior art have included finely divided natural substances or inorganic compounds such as mica, fish scale, bismuth oxychloride or the like.
- Japanese patent application no. 90/134,825 (Priority Date; 24 May 1990) describes compositions for cosmetics having a pearly appearance, comprising glucose fatty acid esters and mica and/or mica Ti.
- a fatty acid glycolic ester in pearlescent concentrates has been particularly favoured.
- such concentrates are produced by adding a fatty acid glycolic ester which is solid at room temperature to a composition such as shampoo or the like, followed by heating of the mixture to melt the fatty acid glycolic ester, and then by cooling to recrystallise it and thereby providing small crystals which impart a pearl-like gloss to the composition.
- a pearling agent dispersion such as a fatty acid glycolic ester dispersion, which is dissolved and cooled to recrystallise in advance
- Other known pearlescent based concentrates have comprised microcrystalline polyvalent metal salts of higher fatty acids or fatty acid glycolic esters such as those described in United States Patent 4,959,200 (Date of Patent; 25 September 1990).
- pearlescent based concentrates have been prepared using ethylene glycol monostearate, ethylene glycol di-stearate, glycerol monostearate, glycerol di- stearate or a cetyl stearly alcohol or the like in conjunction with other similar esters.
- These pearlescent based concentrates of the prior art have also normally comprised ether sulphates, betaines, ethanolamide, amine based surfactants and the like which can be used as emulsifiers.
- United States Patent 5,017,305 (Date of Patent; 21 May 1991) describes a typical pearlescent concentrate in the form of a free-flowing dispersion comprising pearlescing esters, ether carboxylic acids and one or more monoethanolamides of C 12 to C 22 fatty acids.
- alkyl polyglucosides demonstrate very little tendency to scalp irritations.
- alkylpolysaccharides are particularly attractive for use in personal care products because they contain no toxic trace impurities and because they are derived from renewable resources such as coconut oil and wheat starch.
- the current invention therefore provides a pearlescent based concentrate including: between 5 and 40% by weight of the composition of alkylpolysaccharide of formula
- R is selected from the group comprising linear or branched C 6 to C 22 alkyl or alkenyl group where G is selected from the group comprising a C 5 or C 6 saccharide and x is from 1 to 10;
- R2 -(°C n H 2n ) ⁇ -OR 3 where R is chosen from the group including C 16 to C 22 fatty acyl groups, R 3 is chosen from the group comprising H or R2, n is 2 or 3 and x is from 1 to 120.
- the current invention further provides a pearlescent based concentrate including: H-G ⁇ -0R 1 where R is selected from the group comprising linear or branched C 6 to C 22 alkyl or alkenyl group where G is selected from the group comprising a C 5 or C 6 saccharide and x is from 1 to 10; between 3 and 30% by weight of the composition of alkyl sulphate and/or alkyl ether sulphate; and between 5 to 20% by weight of pearlescing acid of formula R COOH where R is chosen from the group comprising C 16 to C 22 alkyl groups.
- the pearlescing esters or acid of the current invention is chosen from ethylene glycol monostearate, ethylene glycol disterate, stearic acid and mixtures thereof.
- R 4 CH(CH 3 )S0 3 M where R 4 is chosen from the group comprising
- C 6 to C 22 alkyl groups and M is chosen from the group comprising alkali metals
- R 5 (OC 2 H 4 ) y OH where R 5 is chosen from the group including
- the pearlescent based concentrate of the current invention may further include between 0 and 30% by weight of the composition of one or more optional additives chosen from the group including: alkylsulphosuccinate or polyoxyalkylenealkylsulphosuccinate of the formula
- R 6 -0-[CH(R 7 )CH 2 0] n -[COCH(S0 3 M)CH 2 COOM 1 ] where R is chosen from the group including C 8 to C 20 linear or branched alkyl groups, R 7 is H or CH 3 ,
- M and M are independently chosen from the group comprising alkali metals, alkaline earth metals, NH 4 + , C ⁇ to C 3 alkyl groups, substituted ammonia and hydroxy substituted C 2 or C 3 alkyl substituted ammonia and n is from 0 to 8; sorbitan fatty acid esters of formula,
- R is chosen from the group including C 12 to C 18 ; secondary alkane sulphonates; fatty alcohol alkoxylates; fatty acid alkoxylates; fatty alcohols; alkanoyl N- methylglucamides; ether carboxylic acids; ethoxylated sorbitan fatty acid esters; and alpha-olefin sulphonates.
- R 9 OH where R is chosen from the group comprising
- the optional additives of the pearlescent concentrate of the current invention includes alkanoyl N-methylglucamides of the formula COR 10
- the optional additives of the pearlescent concentrate of the current invention includes ether carboxylic acids of the formula R u C(0)0(C 2 H 4 0) ⁇ H where R is chosen from the group includes C 6 to C 22 alkyl groups and m is from 1 to 120
- R is chosen from the group comprising
- R 13 CH CHCH 2 S0 3 M 2 where R is chosen from the group comprising C 6 to C 22 alkyl groups and M is chosen from the group comprising Na & K.
- Another optional additive to the pearlescent based concentrates of the current invention is between 0 and 2% of at least one inorganic salt including alkali metal halide salt such as NaCl, KCl, Kl and the like.
- the pearlescent based concentrates of the current invention may also be diluted with between 10 and 90% of the weight of the composition of water or other suitable solvent.
- the pearlescent based concentrates of the current invention may also have added optional agents including perfumes, pigments, UV absorbers and antioxidants.
- the pearlescent based concentrates of the current invention may also be prepared by a method comprising the following steps;
- a pearlescent based concentrate of the following composition was prepared by the method described below.
- Component Composition (% w/w)
- Decylpolysaccharide (50% a.i.) 36.00 Sodium lauryl sulphate (30% a.i, 10.00 Ethylene Glycol mono-stearate 16.25 Sodium chloride 1.00 Water 36.75
- Ethylene glycol monostearate, decylpolysaccharide, alkyl sulphate, water and sodium chloride were heated to 80°C with vigorous stirring. The solution was maintained at 80°C with stirring for further 30 minutes before being rapidly cooled to 65°C. Once the solution temperature reached 65°C the stirring rate was slowed and the solution cooled at a controlled rate of 10°C per hour until the temperature reached 40°C. The stirrer was then stopped and the pearlescent blend allowed to cool to room temperature.
- a pearlescent based concentrate of the following composition was prepared by the method described below.
- Component Com osition (% w/w)
- Ethylene glycol mono-stearate, dodecylpolysaccharide, sodium lauryl sulphate, TERIC 12A23 water and sodium chloride were heated to 80°C with vigorous stirring. Once the solution had reached 80°C, the stirring rate was slowed and the solution cooled at a controlled rate of 10°C per hour until the solution temperature had dropped to 0°C. When the solution temperature had reached 40°C the stirrer was stopped and the pearlescent based composition was allowed to cool to room temperature. (TERIC is a registered trade mark of ICI Australia Operations Proprietary Limited) .
- Component Composition (%w/w)
- Ethylene glycol monostearate, decylpolysaccharide, sodium lauryl sulphate, cetyl-stearyl alcohol and water were heated to 75°C with vigorous stirring. The solution was cooled until the temperature reached 70°C at which point the rate of cooling was controlled at 15°C/hour and the stirring rate reduced. When temperature reached 40°C, stirring was stopped and the pearlescent based composition allowed to cool to room temperature.
- Component Composition (%w/w)
- Component Composition (%w/w)
- the sodium chloride was dissolved in a portion of the water. The remaining components were blended together and the salt solution mixed in. The resultant mixture was heated to 70°C with rapid stirring then the stirring rate was reduced and the mixture cooled at a rate of 8°C per hour. When the mixture reached 40°C all stirring was ceased.
- Component Composition (%w/w)
- Example 5 The above components were combined according to the method of Example 5 to form a pearlescent based concentrate.
- Component Composition ( %w/w) C8-10 Polysaccharide 5 . 00 Decyl Polysaccharide 25 . 00 Sodium lauryl sulphate 20 . 00 Ethylene glycol monostearate 15 . 00 Sodium Chloride 1 . 00 Water 34 . 00 Method
- Example 5 The above components were combined according to the method of Example 5 to form a pearlescent based concentrate
- Component Composition (%w/w)
- Example 5 The above components were combined according to the method of Example 5 to form a pearlescent based concentrate.
- Component Composition (%w/w)
- Example 5 The above components were combined according to the method of Example 5 to form a pearlescent based concentrate
- Example 5 The above components were combined according to the method of Example 5 to form a pearlescent based concentrate,
- the pearlescent based concentrates of each example exhibited small crystals of relatively uniform size which give a lustrous appearance to the concentrate and good reflectance.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU73403/94A AU673099B2 (en) | 1993-07-28 | 1994-07-26 | Pearlescent based concentrate for personal care products |
NZ269755A NZ269755A (en) | 1993-07-28 | 1994-07-26 | Pearlescent based concentrate comprising a pearlescent ester or acid, an alkylpolysaccharide and alkyl sulphates |
KR1019960700426A KR960703565A (en) | 1993-07-28 | 1994-07-26 | PEARLESCENT BASED CONCENTRATE FOR PERSONAL CARE PRODUCTS |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AUPM024693 | 1993-07-28 | ||
AUPM0246 | 1993-07-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1995003782A1 true WO1995003782A1 (en) | 1995-02-09 |
Family
ID=3777096
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/AU1994/000421 WO1995003782A1 (en) | 1993-07-28 | 1994-07-26 | Pearlescent based concentrate for personal care products |
Country Status (4)
Country | Link |
---|---|
KR (1) | KR960703565A (en) |
CA (1) | CA2168346A1 (en) |
NZ (1) | NZ269755A (en) |
WO (1) | WO1995003782A1 (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996002620A1 (en) * | 1994-07-19 | 1996-02-01 | Henkel Kommanditgesellschaft Auf Aktien | Detergent mixtures with improved washing power |
WO1997005224A1 (en) * | 1995-07-25 | 1997-02-13 | Henkel Kommanditgesellschaft Auf Aktien | Pourable nacreous lustre concentrate |
EP0828807A1 (en) * | 1995-05-27 | 1998-03-18 | The Procter & Gamble Company | Cleansing composition containing polyhydroxy fatty acid amide surfactants |
DE19646882A1 (en) * | 1996-11-13 | 1998-05-28 | Henkel Kgaa | Aqueous pearlescent concentrates |
WO1998036048A1 (en) * | 1997-02-15 | 1998-08-20 | Henkel Kommanditgesellschaft Auf Aktien | Method for producing surfactant pearly luster concentrates |
DE19908563A1 (en) * | 1999-02-27 | 2000-08-31 | Cognis Deutschland Gmbh | Detergent for hard surfaces |
WO2001025378A2 (en) * | 1999-10-07 | 2001-04-12 | Rhodia Consumer Specialties Limited Trading As Albright & Wilson Surfactants Europe | Structered surfactant systems containing pearlisers |
US6306916B1 (en) | 1995-03-29 | 2001-10-23 | Henkel Kommanditgesellschaft Auf Aktien | Pearly luster concentrate with newtonian viscosity |
WO2003066796A1 (en) * | 2002-02-09 | 2003-08-14 | Huntsman International Llc | Opacifiers |
FR2929856A1 (en) * | 2008-04-15 | 2009-10-16 | Rhodia Operations Sas | PROCESS FOR THE PREPARATION OF CRYSTALS BASED ON A FATTY ACID ESTER |
EP1132079B2 (en) † | 2000-01-21 | 2010-05-05 | L'oreal | Washing composition for keratinic materials comprising a low-ethoxylated sorbitan ester |
EP3284807A1 (en) * | 2009-08-27 | 2018-02-21 | Clariant International Ltd | Pearlescent concentrate and method for producing the same |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4438096A (en) * | 1982-05-27 | 1984-03-20 | Helene Curtis Industries, Inc. | Pearlescent shampoo |
WO1986005390A1 (en) * | 1985-03-13 | 1986-09-25 | Helene Curtis Industries, Inc. | Pearlescent shampoo and method for preparation of same |
EP0323594A2 (en) * | 1987-12-28 | 1989-07-12 | Kao Corporation | Pearling agent dispersion |
US5017305A (en) * | 1986-11-28 | 1991-05-21 | Henkel Kommanditgesellschaft Auf Aktien | Free-flowing pearlescent concentrate |
EP0512744A2 (en) * | 1991-05-03 | 1992-11-11 | Unilever Plc | Hair treatment composition containing a perfluoropolyether compound and a pearlescing agent |
AU2605892A (en) * | 1991-10-03 | 1993-04-08 | Kao Corporation | Liquid detergent composition with opaque appearance containing a pearlescent agent |
WO1993015171A1 (en) * | 1992-01-27 | 1993-08-05 | Deutsche Ici Gmbh | Pearlescent surfactant composition |
-
1994
- 1994-07-26 CA CA002168346A patent/CA2168346A1/en not_active Abandoned
- 1994-07-26 WO PCT/AU1994/000421 patent/WO1995003782A1/en active Application Filing
- 1994-07-26 KR KR1019960700426A patent/KR960703565A/en not_active Application Discontinuation
- 1994-07-26 NZ NZ269755A patent/NZ269755A/en unknown
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4438096A (en) * | 1982-05-27 | 1984-03-20 | Helene Curtis Industries, Inc. | Pearlescent shampoo |
WO1986005390A1 (en) * | 1985-03-13 | 1986-09-25 | Helene Curtis Industries, Inc. | Pearlescent shampoo and method for preparation of same |
US5017305A (en) * | 1986-11-28 | 1991-05-21 | Henkel Kommanditgesellschaft Auf Aktien | Free-flowing pearlescent concentrate |
EP0323594A2 (en) * | 1987-12-28 | 1989-07-12 | Kao Corporation | Pearling agent dispersion |
EP0512744A2 (en) * | 1991-05-03 | 1992-11-11 | Unilever Plc | Hair treatment composition containing a perfluoropolyether compound and a pearlescing agent |
AU2605892A (en) * | 1991-10-03 | 1993-04-08 | Kao Corporation | Liquid detergent composition with opaque appearance containing a pearlescent agent |
WO1993015171A1 (en) * | 1992-01-27 | 1993-08-05 | Deutsche Ici Gmbh | Pearlescent surfactant composition |
Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996002620A1 (en) * | 1994-07-19 | 1996-02-01 | Henkel Kommanditgesellschaft Auf Aktien | Detergent mixtures with improved washing power |
US6306916B1 (en) | 1995-03-29 | 2001-10-23 | Henkel Kommanditgesellschaft Auf Aktien | Pearly luster concentrate with newtonian viscosity |
EP0828807A4 (en) * | 1995-05-27 | 1999-01-13 | Procter & Gamble | Cleansing composition containing polyhydroxy fatty acid amide surfactants |
EP0828807A1 (en) * | 1995-05-27 | 1998-03-18 | The Procter & Gamble Company | Cleansing composition containing polyhydroxy fatty acid amide surfactants |
WO1997005224A1 (en) * | 1995-07-25 | 1997-02-13 | Henkel Kommanditgesellschaft Auf Aktien | Pourable nacreous lustre concentrate |
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JPH11510197A (en) * | 1995-07-25 | 1999-09-07 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン | Flowable pearlescent concentrate |
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WO1998036048A1 (en) * | 1997-02-15 | 1998-08-20 | Henkel Kommanditgesellschaft Auf Aktien | Method for producing surfactant pearly luster concentrates |
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WO2001025378A2 (en) * | 1999-10-07 | 2001-04-12 | Rhodia Consumer Specialties Limited Trading As Albright & Wilson Surfactants Europe | Structered surfactant systems containing pearlisers |
WO2001025378A3 (en) * | 1999-10-07 | 2002-05-02 | Rhodia Cons Spec Ltd | Structered surfactant systems containing pearlisers |
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WO2003066796A1 (en) * | 2002-02-09 | 2003-08-14 | Huntsman International Llc | Opacifiers |
FR2929856A1 (en) * | 2008-04-15 | 2009-10-16 | Rhodia Operations Sas | PROCESS FOR THE PREPARATION OF CRYSTALS BASED ON A FATTY ACID ESTER |
WO2009127596A1 (en) * | 2008-04-15 | 2009-10-22 | Rhodia Operations | Method for preparing fatty acid ester crystals |
US20110071308A1 (en) * | 2008-04-15 | 2011-03-24 | Rhodia Operations | Process for preparing crystals based on a fatty acid ester |
JP2011517693A (en) * | 2008-04-15 | 2011-06-16 | ロデイア・オペラシヨン | Method for preparing fatty acid ester crystals |
US8536356B2 (en) | 2008-04-15 | 2013-09-17 | Rhodia Operations | Process for preparing crystals based on a fatty acid ester |
EP3284807A1 (en) * | 2009-08-27 | 2018-02-21 | Clariant International Ltd | Pearlescent concentrate and method for producing the same |
Also Published As
Publication number | Publication date |
---|---|
CA2168346A1 (en) | 1995-02-09 |
KR960703565A (en) | 1996-08-31 |
NZ269755A (en) | 1997-10-24 |
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