WO1994021980A1 - Firing a composition with a microwave generator________________ - Google Patents
Firing a composition with a microwave generator________________ Download PDFInfo
- Publication number
- WO1994021980A1 WO1994021980A1 PCT/FR1994/000291 FR9400291W WO9421980A1 WO 1994021980 A1 WO1994021980 A1 WO 1994021980A1 FR 9400291 W FR9400291 W FR 9400291W WO 9421980 A1 WO9421980 A1 WO 9421980A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- microwave
- generator
- pyrotechnic composition
- line
- composition
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41A—FUNCTIONAL FEATURES OR DETAILS COMMON TO BOTH SMALLARMS AND ORDNANCE, e.g. CANNONS; MOUNTINGS FOR SMALLARMS OR ORDNANCE
- F41A19/00—Firing or trigger mechanisms; Cocking mechanisms
- F41A19/58—Electric firing mechanisms
- F41A19/63—Electric firing mechanisms having means for contactless transmission of electric energy, e.g. by induction, by sparking gap
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B6/00—Heating by electric, magnetic or electromagnetic fields
- H05B6/46—Dielectric heating
- H05B6/48—Circuits
- H05B6/50—Circuits for monitoring or control
Definitions
- the present invention relates to the field of devices for initiating pyrotechnic compositions. Many pyrotechnic igniters have already been proposed.
- the known igniters generally comprise a housing 10 which contains a pyrotechnic and electrically conductive composition 12 and which carries two electrodes 14, 16.
- a filament placed in the composition can connect the two electrodes.
- the electrodes 14, 16 are accessible outside the housing 10 and immerse in the composition 12. Thus the application of adequate electrical energy between the electrodes 14, 1 6 allows the composition 12 to be ignited.
- the object of the present invention is to propose improved means for initiating pyrotechnic compositions.
- the above object is achieved by an initiation process comprising the step which consists in coupling a microwave generator and a pyrotechnic composition block comprising charges with resistive electrical losses and / or magnetic, sensitive to microwaves, and to control the microwave generator in a suitable way to synthesize a shock wave equivalent to a detonator.
- detonators are devices designed to apply shock waves to pyrotechnic compositions, while igniters have the function of transmitting a thermal effect.
- the above-mentioned method is implemented using a single microwave applicator.
- the aforementioned method is implemented using several applicators controlled successively in a controlled sequence.
- This controlled sequence is preferably such that the ratio between the distance separating the different applicators and the time interval between the application of microwave energy to these applicators is substantially equal to the speed of mechanical propagation in the pyrotechnic material, in detonating regime.
- the aforementioned method is implemented using electrically conductive lines, generally divergent in proximity to the coupling on the generator, and placed in the mass of the pyrotechnic composition.
- an initiation device of the type comprising:
- a block of pyrotechnic composition comprising charges with resistive and / or magnetic electrical losses, sensitive to microwaves, adapted to be coupled to the microwave generator, in which there is further provided a directional coupler coupled to the line of preferably at the output of the microwave generator, and sensitive to the wave reflected on the end thereof, means for controlling the low power microwave generator and means for controlling the wave reflected at the end of the line.
- FIG. 1 previously described represents a schematic view of an igniter according to the state of the art
- FIG. 2 represents a schematic view of an initiation device according to the present invention with a single applicator
- FIGS. 3 and 4 respectively represent two alternative layouts of a microwave application line on a block of pyrotechnic composition
- FIG. 5 schematically illustrates the production of an assembly bringing together different initiation devices in accordance with the present invention for the sequential firing of a plurality of munitions
- FIG. 6 shows an alternative embodiment of a device according to the present invention for the design of a detonator, using multiple applicators
- FIG. 7 and 8 show two implementation variants with lines electric integrated in the composition 102
- FIG. 9 shows a variant with multiple applicators spread evenly around the composition.
- FIG. 2 schematically, an embodiment of an initiation device according to the present invention.
- This device comprises a block of suitable pyrotechnic composition 102, sensitive to microwaves, placed in a box 100.
- the box 100 The box
- housing 100 can be the subject of numerous embodiments. It will therefore not be described in detail below. It will simply be noted that the housing 100 must be locally transparent to the microwave.
- the pyrotechnic composition block 102 can also be formed from any suitable conventional pyrotechnic composition provided that this composition 102 is sensitive to microwaves and includes resistive and / or magnetic electrical loss charges.
- the aforementioned fillers can be formed for example of graphite, ferrite or metallic oxides or even of any equivalent material.
- control circuit 1 10 comprising a microwave generator 1 1 1 selectively coupled, by a line 120, to the block 102 of pyrotechnic composition.
- Selective coupling of generator 1 1 1 to block 102 can be obtained by directly connecting the output of generator 1 1 1 to a microwave application line on block 102 and by controlling generator 1 1 1 in all or nothing or by modulating the power output thereof.
- the microwave generator 11 1 is coupled to line 120 by means of a switch 130 consisting of a PIN diode.
- the PIN diode 130 thus constitutes a microwave switch.
- the invention is of course not limited to the use of such a particular switch.
- the output 1 12 of the microwave generator is connected to the anode of the PIN diode 130 by means of a coupling capacitor C1 13.
- the cathode of the PIN diode 130 is coupled to the line 120.
- Line 120 is itself coupled to composition 102 by capacitive coupling.
- the control circuit shown in Figure 2 also includes a controller module 140 whose function is to apply a bias voltage on the PIN diode to make it selectively conductive and allow the passage of microwaves, generator 1 11, on block 102 in order to initiate it.
- the output 141 of the controller 140 is connected to the anode of the PIN diode 10 by means of an inductor L142.
- the cathode of the PIN diode 130 is connected to ground via a second inductor L143 allowing the closure of the bias circuit.
- the operation of the initiator device shown in Figure 2 is essentially as follows. As long as the controller 140 does not apply the adequate bias voltage to the anode of the PIN diode 130, the latter is blocked in the non-conducting state. The microwaves from the generator 1 1 1 cannot therefore be applied to line 120 and therefore cannot therefore be applied to pyrotechnic composition 102. In this state, the device has great immunity to untimely initiations.
- the controller 140 When the controller 140, on the other hand, applies the correct bias voltage to the anode of the PIN diode 130 via the inductor L142, this PIN diode 130 is turned on.
- the microwaves from the HF generator 111 are then applied via the PIN diode 130 on the line 120, and from there on the pyrotechnic composition block 102.
- This application of microwaves causes a rise in temperature in the area of resistive and / or magnetic loss charges of block 102. This area can typically be of the order of lmm 2 . Once this rise in temperature is obtained, the propagation throughout the block 102 occurs rapidly.
- the controller 140 applies on line 141 a sequence of polarization pulses adapted to generate in composition 102 a shock wave of speed substantially equal to the speed of mechanical propagation in the material in detonating regime in order to synthesize a shock wave equivalent to a detonator.
- the entire pyrotechnic composition 102 is homogeneous.
- the propagation of the initiation takes place in a homogeneous material of the same nature as the zone initiated by the microwaves. Thanks to this arrangement, an excellent communicability of the initiation and a rapidity of the transfer thereof are obtained.
- Current microwave components allow powers much higher than lkW / mm 2 . It is understood that the use of a microwave initiator therefore makes it possible to obtain a strong immunity with regard to external aggressions. Indeed, in the current state of the art, it is completely unthinkable to generate such a power density at a distance.
- the PIN diodes currently available on the market allow ultra-fast switching on the order of nano-seconds, while pyrotechnic compositions have response times on the order of microseconds.
- the invention is not limited to the use of a semiconductor switch of the PIN diode type.
- a mechanical type switch interposed between the HF generator 1 1 1 and the line 120.
- FIG. 3 illustrates an example of installation of the application line 120 on the housing 100.
- the application line 120 is placed in the center of the face 104 of the base of the housing 100. More specifically, an electrically insulating sheet 106 is interposed between the application line 120 coming from the PIN diode 130 and the pyrotechnic composition block 102.
- a first plate 107 of electrically conductive material central, placed opposite the line 120, and an electrode electrically conductive annular ground 108.
- the electrode 108 surrounds the electrode 107.
- the coupling defined through the insulating sheet 106 between the line 120 and the central electrode 107 is a coupling of the capacitive type.
- the guard ring 108 can be connected to ground by any suitable conventional means, for example by capacitive coupling with an external electrode 105 to ground.
- the resistive and / or magnetic electrical loss charges placed between the central electrode 107 and the ground electrode 108 has an impedance tuned on line 120, for example from a few ohms to a few tens of ohms typically of the order of 50 ⁇ .
- impedance tuned on line 120 for example from a few ohms to a few tens of ohms typically of the order of 50 ⁇ .
- the line 120 from the PIN diode 130 in a different location from the center of the base 104 of the housing 100.
- the end 121 of the line 120 adjacent to the housing 100, as well as the face opposite 104 of the base of the housing 100 can be the subject of numerous geometries.
- This arrangement guarantees better confinement of the microwaves in the pyrotechnic composition block 102. Furthermore, this arrangement makes it easier to center the block 100 on the applicator line 120. This last characteristic is particularly advantageous when the munitions equipped with the composition 102 are placed in removable chargers. It is indeed appropriate in this case to place with precision the block of pyrotechnic composition 102 relative to the applicator line 120 which is generally placed in a fixed and reusable base.
- FIG. 5 shows the structure of an assembly comprising different blocks of pyrotechnic composition 102 associated with respective switches 130 for firing in sequence a plurality of munitions.
- Such an assembly can be used for example for the sequential launch of lures in the field of countermeasures.
- each block of pyrotechnic composition 102 a line 120 connected to the output of the microwave generator 111 by means of a PIN diode 130.
- Each PIN diode 130 is connected by a capacitor of coupling 1 13 on the output of the microwave generator 1 11.
- each PIN diode 130 has its anode connected to a respective output of the controller 140 via an inductor L142 and to its cathode connected to ground by a self L143. It is understood that within the framework of the embodiment represented in FIG.
- the microwave generator 1 1 1 emits microwaves continuously during the firing period, and the controller 140 generates successively and in a controlled sequence, the appropriate bias voltages on its outputs to make the various PIN diodes 130 passably successive and consequently successively initiate the different compositions 102.
- the coupler 150 can be placed at any point between the output 112 of the generator 111 and the end 121 of the line. However, the coupler 150 is preferably connected to the output of the generator 1 1 1. This arrangement makes it possible to avoid multiplying the couplers 150 when the generator 111 attacks several loads.
- the signal from this directional coupler 150 is applied to the control module 152 comprising the microwave generator 1 1 1 and the controller 140.
- the module 152 controls the microwave generator to reduced power.
- the power generated by the microwave generator 1 1 1 must be insufficient to cause the untimely initiation of block 102.
- the microwave generator 11 1 thus works at reduced power and the PIN diode 130 is enabled by the generation of an appropriate bias voltage at the output of the controller 140, the presence of a reflection detected by the coupler 150 signals the absence of charge 102.
- the absence of such reflection detected by the coupler 150 signals the presence of a load 102 opposite the end of the line 120.
- the load 102 being adapted to the terminal impedance of the line 120, it absorbs microwaves, when present, and thus avoid any reflection on the end of line 120.
- This test function can be used, on the one hand to check the correct positioning of an ammunition loader on a base housing the control module 152 and the application lines 120.
- This test function can also be used to control the effect of an initiation by the controller 140 and reiterate the command sequence in the event of failure.
- the signal from the coupler 150 can also be applied in feedback to the HF generator 11 11 in order to tune it on the line and guarantee a maximum amplitude of the microwaves applied to the load 102.
- the microwave generator 11 1 can be formed of a self-oscillator or of a voltage-controlled oscillator associated with a power amplifier.
- the present invention makes it possible to reinforce security by eliminating the use of primary, even secondary, which we know to be very sensitive to temperature.
- the invention synthesizes a detonator using a single microwave applicator.
- the present invention also proposes to produce a detonator using an initiation device with multiple applicators.
- FIG. 6 it is proposed in the context of the present invention, to associate different applicators 120 with the same block of pyrotechnic composition 102, which applicators 120 receive successively, via diodes PIN 1 30 respectively, the microwaves coming from the microwave generator 111.
- the controller 140 can synthesize waves equivalent to those of a conventional detonator. More precisely, for this, in the context of the present invention, the controller 140 applies to the various PIN diodes 130 a sequence of respective control pulses separated from each other by a time ⁇ t such that the ratio between the distance separating the different applicators 120 and this time difference ⁇ t is substantially equal to the mechanical propagation speed in the composition 102, in detonating regime.
- the Applicant has obtained satisfactory results with a composition 102 formed from a tolite type explosive whose propagation speed in detonating regime is of the order of 4 km / s, and applicators 120 spaced between 10 mm and powered by lkW pulses sequenced at 0.6 ⁇ s.
- the initiation device according to the present invention can be used to directly attack a conventional primer, as shown in FIG. 1. More specifically, it is possible to envisage placing an applicator
- a conventional primer directly against the housing 10 of a conventional primer, if the latter comprises charges adapted to resistive electrical losses or to magnetic losses. If the conventional primer does not include such charges with resistive and / or magnetic electrical losses, the initiation of a conventional primer can be obtained by juxtaposing therewith an adequate composition block 102 provided with such charges, associated with an applicator 120.
- the control circuit comprising the microwave generator 111, the controller 140 and the switch formed by the PIN diode 130 can be designed as a consumable or reusable product.
- the initiation device according to the present invention can be used for any type of ammunition such as missile, bomb, shell, etc.
- the initiation device according to the present invention offers the advantage of being insensitive to attack external, in particular to thermal shock such as fire, to mechanical shock, such as bullet impacts or detonations, and insensitive to external electromagnetic influences.
- it is possible to synthesize a shock wave equivalent to a detonator by placing in composition 102 electrically conductive lines 160, 162 generally divergent in approximation of the coupling on the generator. 11 1, and placed in the mass of the pyrotechnic composition 102.
- the generator 1 1 1 can permanently supply the lines 160, 162 and no longer impulse as indicated above.
- these lines 160, 162 are rectilinear. According to Figure 8, these lines 160, 162 are broken, not straight.
- the present invention is not limited to the particular embodiments which have just been described but extends to any variant in accordance with its spirit.
- the present invention can be used to ignite the initiation device by passing it in front of an applicator 120, thanks to the capacitive coupling then obtained between the applicator 120 and the pyrotechnic composition 102.
- the present invention also applies to an arrangement of applicators 120 distributed evenly around composition 102, for example but not limitatively of circular or semi-circular contour.
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP94909976A EP0689661B1 (en) | 1993-03-16 | 1994-03-16 | Firing a composition with a microwave generator |
DE69409951T DE69409951T2 (en) | 1993-03-16 | 1994-03-16 | IGNITING A PYROTECHNICAL CHARGE BY MEANS OF A MICROWAVE GENERATOR |
CA002158280A CA2158280C (en) | 1993-03-16 | 1994-03-16 | Firing a composition with a microwave generator |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9303003A FR2702832B1 (en) | 1993-03-16 | 1993-03-16 | DEVICE FOR INITIATING A PYROTECHNIC COMPOSITION WITH ATTENUATED RISK. |
FR93/03003 | 1993-03-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994021980A1 true WO1994021980A1 (en) | 1994-09-29 |
Family
ID=9445000
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR1994/000291 WO1994021980A1 (en) | 1993-03-16 | 1994-03-16 | Firing a composition with a microwave generator________________ |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0689661B1 (en) |
CA (1) | CA2158280C (en) |
DE (1) | DE69409951T2 (en) |
ES (1) | ES2115221T3 (en) |
FR (1) | FR2702832B1 (en) |
WO (1) | WO1994021980A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998036235A1 (en) * | 1997-02-14 | 1998-08-20 | Easat Antennas Ltd. | Method and apparatus for the remote clearance of explosive devices |
GB2336341A (en) * | 1997-02-14 | 1999-10-20 | Easat Antennas Ltd | Method and apparatus for the remote clearance of explosive devices |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2796141B1 (en) | 1999-07-07 | 2002-07-12 | Giat Ind Sa | DEVICE FOR INITIATING AN ENERGY COMPOSITION |
US10641572B1 (en) * | 2016-04-19 | 2020-05-05 | Triad National Security, Llc | Microwave ignition of energetic material housed within a gun |
US11585622B1 (en) | 2016-04-19 | 2023-02-21 | Triad National Security, Llc | Microwave ignition systems with launcher affixed to or located within a gun spindle |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2997671A (en) * | 1958-02-26 | 1961-08-22 | Armstrong Cork Co | Dual load transmission system |
DE1123759B (en) * | 1958-08-08 | 1962-02-15 | Siemens Ag | Device for parallel operation of at least two high-frequency generators, each with a capacitive load resistor |
US3601054A (en) * | 1969-03-17 | 1971-08-24 | Unidynamics Phoenix | Method and apparatus for electromagnetically initiating ordnance |
GB2002605A (en) * | 1977-07-23 | 1979-02-21 | Automotive Prod Co Ltd | Radio-frequency heating installations |
DE3131332A1 (en) * | 1980-08-26 | 1982-04-08 | Nippon Oil and Fats Co., Ltd., Tokyo | Detonation method and detonation system |
US4324965A (en) * | 1979-07-25 | 1982-04-13 | Hermann Berstorff Maschinenbau Gmbh | Microwave heating method and apparatus including adjustable tuning members |
EP0235010A1 (en) * | 1986-02-03 | 1987-09-02 | ETAT-FRANCAIS représenté par le DELEGUE GENERAL POUR L'ARMEMENT (DPAG) | Capacitive ignition device for a propulsive charge |
US4883984A (en) * | 1987-07-17 | 1989-11-28 | Siemens Aktiengesellschaft | PIN diode switch |
GB2241563A (en) * | 1989-04-18 | 1991-09-04 | Royal Ordnance Plc | Initiation of propellants |
-
1993
- 1993-03-16 FR FR9303003A patent/FR2702832B1/en not_active Expired - Fee Related
-
1994
- 1994-03-16 DE DE69409951T patent/DE69409951T2/en not_active Expired - Fee Related
- 1994-03-16 WO PCT/FR1994/000291 patent/WO1994021980A1/en active IP Right Grant
- 1994-03-16 ES ES94909976T patent/ES2115221T3/en not_active Expired - Lifetime
- 1994-03-16 CA CA002158280A patent/CA2158280C/en not_active Expired - Fee Related
- 1994-03-16 EP EP94909976A patent/EP0689661B1/en not_active Expired - Lifetime
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2997671A (en) * | 1958-02-26 | 1961-08-22 | Armstrong Cork Co | Dual load transmission system |
DE1123759B (en) * | 1958-08-08 | 1962-02-15 | Siemens Ag | Device for parallel operation of at least two high-frequency generators, each with a capacitive load resistor |
US3601054A (en) * | 1969-03-17 | 1971-08-24 | Unidynamics Phoenix | Method and apparatus for electromagnetically initiating ordnance |
GB2002605A (en) * | 1977-07-23 | 1979-02-21 | Automotive Prod Co Ltd | Radio-frequency heating installations |
US4324965A (en) * | 1979-07-25 | 1982-04-13 | Hermann Berstorff Maschinenbau Gmbh | Microwave heating method and apparatus including adjustable tuning members |
DE3131332A1 (en) * | 1980-08-26 | 1982-04-08 | Nippon Oil and Fats Co., Ltd., Tokyo | Detonation method and detonation system |
EP0235010A1 (en) * | 1986-02-03 | 1987-09-02 | ETAT-FRANCAIS représenté par le DELEGUE GENERAL POUR L'ARMEMENT (DPAG) | Capacitive ignition device for a propulsive charge |
US4883984A (en) * | 1987-07-17 | 1989-11-28 | Siemens Aktiengesellschaft | PIN diode switch |
GB2241563A (en) * | 1989-04-18 | 1991-09-04 | Royal Ordnance Plc | Initiation of propellants |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998036235A1 (en) * | 1997-02-14 | 1998-08-20 | Easat Antennas Ltd. | Method and apparatus for the remote clearance of explosive devices |
GB2336341A (en) * | 1997-02-14 | 1999-10-20 | Easat Antennas Ltd | Method and apparatus for the remote clearance of explosive devices |
Also Published As
Publication number | Publication date |
---|---|
DE69409951T2 (en) | 1998-12-24 |
DE69409951D1 (en) | 1998-06-04 |
FR2702832B1 (en) | 1995-06-09 |
FR2702832A1 (en) | 1994-09-23 |
CA2158280A1 (en) | 1994-09-29 |
CA2158280C (en) | 2006-01-10 |
EP0689661A1 (en) | 1996-01-03 |
EP0689661B1 (en) | 1998-04-29 |
ES2115221T3 (en) | 1998-06-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3362329A (en) | Electro-explosive devices | |
US10451388B1 (en) | High power microwave weapon | |
EP0030580B1 (en) | Device for electric ignition by magnetic induction of a pyrotechnic substance | |
US3601054A (en) | Method and apparatus for electromagnetically initiating ordnance | |
FR2559896A1 (en) | INITIATION DELAY FOR A MILITARY HEAD WITH TANDEM MOUNTED LOADS | |
FR2464453A1 (en) | CONNECTOR FOR ELECTRIC IGNITER | |
CA2158280C (en) | Firing a composition with a microwave generator | |
EP1628111B1 (en) | Method and apparatus for implementing an optical link based with a light beacon | |
EP0800054A1 (en) | Projectile the warhead of which is triggered by means of a target designator | |
US5144893A (en) | Safe ordnance initiation system | |
US3117519A (en) | Electric initiators for explosives, pyrotechnics and propellants | |
EP3265746B1 (en) | System for controlling at least one electronic detonator | |
FR2667200A1 (en) | DEVICE FOR STARTING A HIGH FREQUENCY AND LASER LASER WITH APPLICATION. | |
EP0296962A1 (en) | Initiator for a pyrotechnic generator | |
FR2760266A1 (en) | Fibre=optic system for multipoint explosive firing mechanism | |
EP0235010B1 (en) | Capacitive ignition device for a propulsive charge | |
EP3476015B1 (en) | Power amplification device | |
US4194203A (en) | Pulse doppler-radio proximity fuze | |
FR2718228A1 (en) | Electromagnetic method for anti-aircraft defence by resonant attack | |
FR2612706A1 (en) | IMPULSE SOURCE OF ELECTRIC CURRENT AND ELECTROMAGNETIC CANON USING THE SAME | |
US6198425B1 (en) | Pulse doppler target detecting device | |
FR3005825A1 (en) | EXTENDED PLASMA GENERATOR COMPRISING INTEGRATED ELEMENTARY GENERATORS | |
FR2747185A1 (en) | Projectile with explosive charge producing fragments or main missile | |
WO2023170369A1 (en) | Single-capacitor electronic detonator and system for firing such single-capacitor electronic detonators | |
FR2574923A1 (en) | Improved proximity detection fuse for projectiles |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): CA US |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 1994909976 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2158280 Country of ref document: CA |
|
ENP | Entry into the national phase |
Ref document number: 1995 532745 Country of ref document: US Date of ref document: 19951208 Kind code of ref document: A |
|
WWP | Wipo information: published in national office |
Ref document number: 1994909976 Country of ref document: EP |
|
WWG | Wipo information: grant in national office |
Ref document number: 1994909976 Country of ref document: EP |