WO1994019497A1 - Methode et appareil pour la production de fer - Google Patents

Methode et appareil pour la production de fer Download PDF

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Publication number
WO1994019497A1
WO1994019497A1 PCT/FI1994/000023 FI9400023W WO9419497A1 WO 1994019497 A1 WO1994019497 A1 WO 1994019497A1 FI 9400023 W FI9400023 W FI 9400023W WO 9419497 A1 WO9419497 A1 WO 9419497A1
Authority
WO
WIPO (PCT)
Prior art keywords
reactor
concentrate
slag
post
layer
Prior art date
Application number
PCT/FI1994/000023
Other languages
English (en)
Inventor
Rolf Malmström
Hans Elvander
Original Assignee
A. Ahlstrom Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by A. Ahlstrom Corporation filed Critical A. Ahlstrom Corporation
Priority to BR9406272-2A priority Critical patent/BR9406272A/pt
Priority to AU58854/94A priority patent/AU673049B2/en
Priority to JP6518683A priority patent/JPH08506858A/ja
Priority to KR1019950703611A priority patent/KR960701224A/ko
Priority to EP94905111A priority patent/EP0686204A1/fr
Publication of WO1994019497A1 publication Critical patent/WO1994019497A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B13/00—Making spongy iron or liquid steel, by direct processes
    • C21B13/0006—Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B11/00—Making pig-iron other than in blast furnaces
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B3/00—Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces
    • F27B3/10—Details, accessories, or equipment peculiar to hearth-type furnaces
    • F27B3/22—Arrangements of air or gas supply devices
    • F27B3/225—Oxygen blowing
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D1/00—Casings; Linings; Walls; Roofs
    • F27D1/12—Casings; Linings; Walls; Roofs incorporating cooling arrangements
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/001—Extraction of waste gases, collection of fumes and hoods used therefor
    • F27D17/003—Extraction of waste gases, collection of fumes and hoods used therefor of waste gases emanating from an electric arc furnace
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/40—Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
    • C21B2100/44—Removing particles, e.g. by scrubbing, dedusting

Definitions

  • the present invention relates to a method and an apparatus for producing iron by melt reduction of concentrate or prereduced concentrate in a melt bath in a reactor, e.g. a converter, wherein concentrate or prereduced and partially molten concentrate and carbonaceous reducing agent, such as coal, is supplied to the melt bath consisting of a layer of molten iron and a layer of slag floating thereon; oxygen-containing gas, such as hot air, is blown into a so-called post-combustion zone by means of blowpipes towards the slag layer in order to bring about combustion of the reduction gases being discharged so as to heat the melt bath; the hot exhaust gases produced are discharged through an outlet in the roof of the reactor.
  • a reactor e.g. a converter
  • concentrate or prereduced and partially molten concentrate and carbonaceous reducing agent such as coal
  • the method according to the invention is characterized in that oxygen-containing gas is blown into a post-combustion zone in the converter, which zone is shielded from the walls of the reactor by cooled panels so as to prevent the slag and metal drops splashing up during the blowing from reaching the uncooled walls of the reactor in the gas phase.
  • the apparatus for producing iron by melt reduction of concentrate is characterized in that a shield made of cooled panels is arranged to shield the post-combustion zone from the tile walls of the reactor or corresponding means in an area between the slag layer and the outlet for exhaust gases.
  • the post-combustion takes place in a space shielded by cooled panels from the remaining parts of the reactor.
  • the panel or panels prevent hot molten drops, which splash up into the gas phase in the post-combustion stage, from reaching the tile walls of the reactor.
  • the panel which may be, for instance, water-, gas- or steam-cooled, endures the wear of these drops considerably better than the uncooled tile wall.
  • the panel can be provided with a heat-insulating layer on its outside in order to prevent unnecessary cooling in the remaining part of the reactor. In most cases a protecting layer of solidified drops is anyhow formed on the panels.
  • the cooled panel is preferably shaped as an upright cylinder disposed concentrically between the surface of the slag and the gas outlet.
  • the cylinder surrounds thereby the post-combustion zone of the reactor.
  • the cooled panel can, if needed, be widened at its upper or lower end so that the shielded zone takes the form of a frustum of cone.
  • the gas volumes can be so large that it is advantageous to widen the space shielded by the panels at its lower end.
  • the shield can have a square, rectangular or, for instance, hexagonal cross section.
  • the shield is thus formed of plane water-cooled panels or membrane walls, which is an advantage in the manufacturing stage.
  • the cooled panels are preferably fastened to the roof of the reactor. If needed, openings can be provided in the upper part of the panels or between the panels and the roof of the reactor so that also gases produced outside the shielded part can flow to the gas outlet. Possibly these gases could be withdrawn from the reactor through a separate gas outlet.
  • the lower edge of the cooled panels can in certain cases be allowed to reach the slag surface.
  • a gap between the slag surface and the panels or the openings in the lower parts of the panels allows the gases to flow, if necessary, from the space outside the post-combustion zone via the shielded zone to the gas outlet.
  • the oxygen-containing gas required in the post-combustion stage is preferably introduced tangentially into the converter by means of one or several blowpipes so that the hot gases flowing upwards form a vortex in the shielded part of the reactor already, thereby promoting the formation of a vortex in the flame chamber.
  • the illustrated plant comprises a converter 10 for melt reduction of prereduced molten concentrate.
  • the converter is internally lined with tiles 11.
  • the gas outlet 12 of the converter is connected to a flame chamber 14 for prereduction and smelting of concentrate.
  • the flame chamber is provided with water-cooled membrane walls 15.
  • a reactor 16 having e.g. a fluidized bed is disposed on top of the flame chamber in order to preheat the concentrate.
  • Concentrate is introduced into the reactor chamber 17 of the reactor 16 through an inlet 18. Hot gases from the flame chamber are fed through an opening 20 into the bottom of the reactor.
  • the concentrate is preheated by the exhaust gases in the reactor chamber and flows entrained by the upwards flowing gases via the upper part of the reactor to a particle separator 22. A portion of the preheated concentrate is recycled to the reactor chamber whereas another portion is passed to the flame chamber through a channel 24.
  • Carbonaceous reducing agent 26 is at the same time introduced into the flame chamber.
  • the preheated concentrate is prereduced and smelts in the flame chamber and flows down to the converter for final reduction of the iron oxide in the melt bath 28, 30 of the converter.
  • the melt bath consists of a iron layer 28 on the bottom of the converter and a slag layer 30 on top of the iron layer.
  • Coal 32 and hot blast air 34 is introduced into the converter through openings in the bottom of the converter. Iron and slag is withdrawn through an outlet 36 in the side of the converter.
  • oxygen-containing gas such as hot blast air
  • a post-combustion zone 37 oxygen-containing gas, such as hot blast air
  • the blast air is blown in tangentially by the blowpipes so that upwards flowing gases form a vortex and thereby promote the formation of a vortex in the flame chamber.
  • the blast air brings about a vigorous turbulence in the slag layer while the reducing gases are combusted developing heat.
  • the vigorous turbulence results in a good heat transfer in the post-combustion zone between the gas phase and the slag and metal drops splashing up.
  • the post-combustion zone in the converter is shielded by cooled panels 42.
  • the panels have been formed by extending the cooled walls 15 of the flame chamber downward into the converter.
  • the final reduction is effected by means of carbon dissolved in the metal layer.
  • Hot blast air is used for the post-combustion which supplies energy to the slag layer 30 as well as the metal layer 28.
  • the slag layer is thin in comparison with the iron layer.
  • Other corresponding melt bath processes can use oxygen gas in a post-combustion stage, have a considerably thicker slag layer than iron layer and inject the whole amount of coal from above into the gas phase or the slag layer. In these processes the post-combustion supplies energy primarily to the expanding slag layer. Reduction is achieved by means of coke particles and iron drops suspended in the slag.
  • the invention is not intended to be restricted to the above described and illustrated embodiment, in which the invention primarily is described in connection with melt reduction in a process with prereduction in a flame chamber.
  • the invention can as well be used in various converter processes.
  • the invention can be modified in many ways within the scope of the inventive idea defined in the appended claims.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacture Of Iron (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)
  • Furnace Details (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

Méthode et appareil de production de fer par fusion réductrice d'un concentré ou d'un concentré pré-réduit dans le bain de fusion d'un réacteur, par exemple un convertisseur (10). Le concentré et l'agent réducteur carboné sont amenés au bain de fusion composé d'une couche (28) de fer fondu sur laquelle flotte une couche (30) de scories. Un gaz contenant de l'oxygène, tel que de l'air chaud, est insufflé par des lances (38) dans une zone dite de post-combustion (37) en direction de la couche de scories de façon à brûler les gaz réducteurs produits et à réchauffer le bain de fusion. Les gaz brûlés produits pendant le processus de combustion sont extraits par un orifice (12) pratiqué dans la voûte du réacteur. Le gaz contenant de l'oxygène est insufflé dans une zone de post-combustion isolée des parois du réacteur par des panneaux réfrigérants (42) destinés à empêcher la projection de gouttes de scories et de métal produites pendant le soufflage sur les parois (11) non refroidies du réacteur pendant la phase gazeuse.
PCT/FI1994/000023 1993-02-26 1994-01-21 Methode et appareil pour la production de fer WO1994019497A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BR9406272-2A BR9406272A (pt) 1993-02-26 1994-01-21 Processo e aparelho para produzir ferro
AU58854/94A AU673049B2 (en) 1993-02-26 1994-01-21 Method and apparatus for producing iron
JP6518683A JPH08506858A (ja) 1993-02-26 1994-01-21 鉄を製造する方法と装置
KR1019950703611A KR960701224A (ko) 1993-02-26 1994-01-21 철 제조방법 및 장치(method and apparatus for producing iron)
EP94905111A EP0686204A1 (fr) 1993-02-26 1994-01-21 Methode et appareil pour la production de fer

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI930864 1993-02-26
FI930864A FI93027C (sv) 1993-02-26 1993-02-26 Förfarande och anordning för framställning av järn

Publications (1)

Publication Number Publication Date
WO1994019497A1 true WO1994019497A1 (fr) 1994-09-01

Family

ID=8537466

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FI1994/000023 WO1994019497A1 (fr) 1993-02-26 1994-01-21 Methode et appareil pour la production de fer

Country Status (11)

Country Link
EP (1) EP0686204A1 (fr)
JP (1) JPH08506858A (fr)
KR (1) KR960701224A (fr)
CN (1) CN1121358A (fr)
AU (1) AU673049B2 (fr)
BR (1) BR9406272A (fr)
CA (1) CA2156631A1 (fr)
FI (1) FI93027C (fr)
TW (1) TW260711B (fr)
WO (1) WO1994019497A1 (fr)
ZA (1) ZA94772B (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998029573A1 (fr) * 1996-12-27 1998-07-09 Kabushiki Kaisha Kobe Seiko Sho Procede de production de fer metallique
WO2000001854A1 (fr) * 1998-07-01 2000-01-13 Technological Resources Pty. Ltd. Cuve et procede de fusion directe
WO2005103305A1 (fr) * 2004-04-26 2005-11-03 Technological Resources Pty Limited Installation de traitement metallurgique
CZ299875B6 (cs) * 1997-09-26 2008-12-17 Technological Resources Pty. Ltd. Zpusob výroby kovu prímým tavením z oxidu kovu
CZ301945B6 (cs) * 1998-07-01 2010-08-11 Technological Resources Pty. Ltd. Zpusob prímého tavení

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101419404B1 (ko) * 2012-07-30 2014-07-15 주식회사 포스코 열처리 장치 및 이를 이용한 원료 열처리 방법
CN112725645A (zh) * 2020-12-22 2021-04-30 大冶市兴进铝业有限公司 一种新型铝型材制备装置

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4309025A (en) * 1979-10-04 1982-01-05 Thyssen Aktiengesellschaft Apparatus for carrying out metallurgical reactions in a ladle
DE3427087C1 (de) * 1984-07-19 1986-04-10 Mannesmann AG, 4000 Düsseldorf Metallurgisches Gefaess

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE9103412L (sv) * 1990-11-20 1992-05-21 Mitsubishi Materials Corp Roerformig vattenkyld mantel foer ugnar
DE4103508A1 (de) * 1991-02-06 1992-08-13 Kortec Ag Verfahren und vorrichtung zur kuehlung von gefaessteilen fuer die durchfuehrung von pyro-verfahren, insbesondere metallurgischer art
AU682578B2 (en) * 1994-02-16 1997-10-09 University Of Melbourne, The Internal refractory cooler

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4309025A (en) * 1979-10-04 1982-01-05 Thyssen Aktiengesellschaft Apparatus for carrying out metallurgical reactions in a ladle
DE3427087C1 (de) * 1984-07-19 1986-04-10 Mannesmann AG, 4000 Düsseldorf Metallurgisches Gefaess

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998029573A1 (fr) * 1996-12-27 1998-07-09 Kabushiki Kaisha Kobe Seiko Sho Procede de production de fer metallique
US6063156A (en) * 1996-12-27 2000-05-16 Kabushiki Kaisha Kobe Seiko Sho Production method of metallic iron
CN1070923C (zh) * 1996-12-27 2001-09-12 株式会社神户制钢所 金属铁的生产方法
CZ299875B6 (cs) * 1997-09-26 2008-12-17 Technological Resources Pty. Ltd. Zpusob výroby kovu prímým tavením z oxidu kovu
WO2000001854A1 (fr) * 1998-07-01 2000-01-13 Technological Resources Pty. Ltd. Cuve et procede de fusion directe
CZ300875B6 (cs) * 1998-07-01 2009-09-02 Technological Resources Pty. Ltd. Nádoba na výrobu kovu prímým tavením a zpusob prímého tavení
CZ301945B6 (cs) * 1998-07-01 2010-08-11 Technological Resources Pty. Ltd. Zpusob prímého tavení
WO2005103305A1 (fr) * 2004-04-26 2005-11-03 Technological Resources Pty Limited Installation de traitement metallurgique
EA010709B1 (ru) * 2004-04-26 2008-10-30 Текнолоджикал Ресорсиз Пти Лимитед Установка для металлургической обработки
US7947217B2 (en) 2004-04-26 2011-05-24 Technological Resources Pty. Limited Metallurgical processing installation

Also Published As

Publication number Publication date
FI930864A0 (fi) 1993-02-26
FI93027B (sv) 1994-10-31
KR960701224A (ko) 1996-02-24
TW260711B (fr) 1995-10-21
CA2156631A1 (fr) 1994-09-01
FI930864A (fi) 1994-08-27
JPH08506858A (ja) 1996-07-23
BR9406272A (pt) 2002-06-18
AU673049B2 (en) 1996-10-24
CN1121358A (zh) 1996-04-24
AU5885494A (en) 1994-09-14
ZA94772B (en) 1995-08-04
FI93027C (sv) 1995-02-10
EP0686204A1 (fr) 1995-12-13

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