WO1992013667A2 - Electrochemical machining - Google Patents
Electrochemical machining Download PDFInfo
- Publication number
- WO1992013667A2 WO1992013667A2 PCT/GB1992/000229 GB9200229W WO9213667A2 WO 1992013667 A2 WO1992013667 A2 WO 1992013667A2 GB 9200229 W GB9200229 W GB 9200229W WO 9213667 A2 WO9213667 A2 WO 9213667A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- workpiece
- tool
- edge
- broaching
- anodic
- Prior art date
Links
- 238000003754 machining Methods 0.000 title claims abstract description 25
- 239000003792 electrolyte Substances 0.000 claims abstract description 40
- 238000000034 method Methods 0.000 claims abstract description 20
- 230000005684 electric field Effects 0.000 claims abstract description 15
- 239000004020 conductor Substances 0.000 claims abstract description 7
- 238000009826 distribution Methods 0.000 claims abstract description 5
- 238000009413 insulation Methods 0.000 claims abstract description 5
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 239000000956 alloy Substances 0.000 description 9
- 229910045601 alloy Inorganic materials 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000002905 metal composite material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000002250 progressing effect Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910000629 Rh alloy Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23H—WORKING OF METAL BY THE ACTION OF A HIGH CONCENTRATION OF ELECTRIC CURRENT ON A WORKPIECE USING AN ELECTRODE WHICH TAKES THE PLACE OF A TOOL; SUCH WORKING COMBINED WITH OTHER FORMS OF WORKING OF METAL
- B23H9/00—Machining specially adapted for treating particular metal objects or for obtaining special effects or results on metal objects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23H—WORKING OF METAL BY THE ACTION OF A HIGH CONCENTRATION OF ELECTRIC CURRENT ON A WORKPIECE USING AN ELECTRODE WHICH TAKES THE PLACE OF A TOOL; SUCH WORKING COMBINED WITH OTHER FORMS OF WORKING OF METAL
- B23H3/00—Electrochemical machining, i.e. removing metal by passing current between an electrode and a workpiece in the presence of an electrolyte
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23H—WORKING OF METAL BY THE ACTION OF A HIGH CONCENTRATION OF ELECTRIC CURRENT ON A WORKPIECE USING AN ELECTRODE WHICH TAKES THE PLACE OF A TOOL; SUCH WORKING COMBINED WITH OTHER FORMS OF WORKING OF METAL
- B23H9/00—Machining specially adapted for treating particular metal objects or for obtaining special effects or results on metal objects
- B23H9/006—Cavity sinking
Definitions
- This invention concerns improvements in or relating to electrochemical machining, and in particular relates firstly to an improved method of using an electrochemical machining operation to shape an edge of an electrically conductive component, and secondly to provide precision broaching of metal and alloy components.
- a specific embodiment of the invention contemplates shaping said edge so as to provide a radius thereon.
- the present invention provides in a first aspect a method of shaping an edge of an anodic workpiece in an electrochemical machining operation by controlling the intensity of the electrical field in the electrolyte adjacent said edge, in a second aspect an electrochemical broaching apparatus for making a channel in a workpiece, and in a third aspect a method of supplying electrolyte to a electrochemical machining tool in a broaching operation.
- a method of electrochemically machining a workpiece made of electrically conductive material so as to provide a radius on an edge of the workpiece comprising, (a) providing a cathodic tool comprising a cathode section sandwiched between two anode sections and separated therefrom by insulation, (b) locating the tool adjacent to but - £ -
- an electrochemical broaching apparatus comprising an electrolyte bath, a first end wall of which is provided by a workpiece of electrically conductive material to be broached, an elongate broaching tool, an elongate horizontally disposed support member adapted to carry underneath it the broaching tool, the workpiece providing the anode of an electrochemical broaching operation and the broaching tool providing the cathode of the electrochemical broaching operation, wherein the support member is arranged to be supported by a second end wall of the bath opposed to the first end wall and to be moved in its elongate direction over the bath and over the workpiece, and the broaching tool is of a wedge shape, the narrow end of which is near the first end wall at the start of the broaching operation and the remainder of which is immersed in the electrolyte bath.
- a broaching tool for making an aperture in an anodic workpiece, the tool being provided with at least one cathodic portion and characterised in that at least two portions of the tool are provided with mutually independent means for supplying electrolyte to the tool.
- Figure 1 is a perspective view of a dovetail slot in a rotor disc of a gas turbine engine. Such a slot is used for locating engine compressor and turbine blades in the disc.
- Figures 2, 3 and 4 are respectively left-hand, middle, and right-hand segments in longitudinal section of an electrochemical broaching tool for making the slot shown in Figure 1. Left-hand and right-hand are to be read with respect to the drawings.
- Figure 5 is an end view of the tool of Figure 2 taken in the direction of arrow V.
- Figures 6-9 are cross sections of the tool of Figure 2 taken at lines VI-VI, VII-VII, VIII-VIII and IX-IX respectively.
- Figure 10 shows the use of the broaching tool of Figures 2-4 in radiusing an edge of a workpiece.
- Figure 11 is a longitudinal cross section through an apparatus for applying the broaching tool of Figures 2-4 to a rotor disc of a gas turbine engine.
- Figures 12 and 13 are sections through the apparatus of Figure 11 taken at lines XII-XII and XIII-XIII respectively.
- Figure 14 is a longitudinal section through a further embodiment of a broaching tool according to the invention, incorporating electrolyte flow passages in the tool.
- Figure 14a is a graph showing the direction of flow through the flow passages of Figure 14 at various stages in the operation of the apparatus.
- Figure 15 is an end view of the tool of Figure 14 taken in the direction of arrow XV.
- Figure 15a is a cross section through the apparatus of Figure 15 taken at line XVa-XVa.
- FIGS 16, 17 are cross sections through an alternative design of broaching tool.
- a portion of a rotor disc 10 for a gas turbine engine there is shown one of a number of dovetail grooves 12 spaced round the periphery of the disc and extending from one face to the other.
- the disc 10 may for example be made of a nickel based alloy, a titanium based alloy, or titanium metal composites.
- the disc 10 is but one example of many components or workpieces suitable for treatment by electrochemical machining or broaching techniques, and provides the anode of the electrochemical machining/broaching operation of the present invention.
- the electrolyte envisaged in the operation of the invention may, for example, be sodium chloride based in the case of titanium based alloys, or sodium nitrate based in the case of nickel based alloys. In either case, the electrolyte may contain additives to enhance surface finish of the final product. Other materials may require other electrolytes.
- FIGS 2 and 5-9 show various views of an electrochemical broaching tool 14 (the cathode of the operation) for producing the grooves 12 in the anodic disc 10.
- the broaching tool 14 is of a wedge shape and comprises a number of sections as follows.
- the initial section 16 to position a-a is designed to achieve two functions: rapid engagement of the tool 14 along the complete cut length, achieved by a shallow approach angle, e.g. 5 , followed by a steepening of approach angle over the second section 18 between a-a to b-b, e.g. 10 , in order to optimise metal ionisation volumes in terms of tool feed rate and areas engaged.
- This is followed by the third section 20 from b-b to c-c with an approach angle embracing all surfaces of the two dimensional form still typically at an angle of 10°.
- Feed rate, voltage and electrolyte conductivity are adjusted such that a minimum machining gap is achieved along the lengths of the cut commensurate with the electrolyte flow limitations and maximising ionisaticn rates for the bulk metal removal.
- the fourth section 22 of the tool from c-c to d-d is relatively short compared with the preceding sections and is angled more steeply, typically between 15 -20 to effect progressively and over a short flow path length a significant reduction in the local machining gap width - L -
- This fourth section of the tool provides the precision of a finishing cut and the accurate reproduction of the final geometry of the tool.
- the mean ionising voltage gradients above the anode surface of the disc 10 when it is being machined by this final section of the tool are targeted at between 600-12C0 volts/cm. This ensures that the differences in ionisation rates due to the different dissociation voltages of the varying material phases in the alloy of the anodic disc 10 do not give rise to significant micro level electrochemical machining gap variations, and results in a smooth surface finish.
- FIG. 3 Immediately following d-d. Figure 3, is a short parallel insulation stage 24 sandwiching a charged anode 26 enveloping the full two dimensional shape thereby providing protection from "stray machining" to the component from point d-d onwards.
- the problem of "stray machining" and attempts to solve it are described in US Patent 3723268. This protection ensures that no deterioration in surface finish or accuracy is permitted to occur.
- Charged anode voltage levels used are typically between 2-10 volts above the anodic potential of the workpiece, depending on materials, gap geometry and the machining cut-off point required.
- the final section 28 of the tool is for edge radiusing at the front and rear faces of the form produced. It comprises a cathode section 30 sandwiched between adjacent charged anode sections 32 and insulated from the anode sections by insulation 34.
- Figure 10 there is shown the electric field density between the final section 28 of the tool and an edge 36 of the workpiece 10. In the electric field near the edge - -
- the cathode section 30 is preset through machine control to a nominal position centrally over the edge 36, with electrolyte flowing between the surfaces. Voltages of preset peak values are applied simultaneously to the workpiece 10 and the charged anode sections 32. The voltages on the anode sections 32 are controlled by electronic means (not shown) such that their values are cycled between just above the voltage of the workpiece 10 and the preset peak values, thereby moving the null points 38, 40 backwards and forwards across the edge 36 being radiused. The period of the cycle is set to ensure an overall energy distribution across the edge 36 to create the radius required and the necessary smooth blends into adjacent surfaces.
- the cathode 30 is preset through machine control to a nominal position centrally over the edge 36 to be radiused, with electrolyte flowing between the surfaces. Preset voltages are applied simultaneously to the workpiece 10 and the charged anode sections 32. The voltages on the charred anode sections 32 are then progressively reduced in value to a level just exceeding that of the anode workpiece. This permits the null points 38, 40 to move apart thereby enabling the edge 36 to be radiused and blended into controlled surfaces at a controlled rate.
- the cathode 30 is preset through machine control to a nominal position centrally over the edge 36 to be radiused, with electrolyte flowing between the surfaces. Preset anodic voltages are appplied simultaneously to the workpiece 10 and the charged anode sections 32 such that the electrical field null points 38, 40 at the anodic workpiece surface are to either side of and immediately adjacent the edge 36 to be radiused.
- the cathode 30 is then indexed rapidly in forward and reverse to a preset cycle such that the period of the cycle is set to ensure an overall energy distribution across the edge to create the radius required and the necessary blends into adjacent surfaces. Axial tool movement, forward and reverse, moves polarity transition points on the workpiece surface, thereby controlling ionisation across the edge profile.
- the manufacture of linear broaching tools for electrochemical machining may utilise conventional numerical control techniques, programmed to produce the required face angles on each segment of tooling.
- the individual tool sections are located and clamped into a common carrier thereby making up the composite tool.
- High conductivity copper alloys form the main tool body.
- the non-conducting, insulated portions are typically in glass reinforced plastic laminate and the charged ancde material in a suitably electro-corrosive resistant alloy material, typically platinum rhodium alloy.
- Flow inlet and outlet passages and restrictors are suitably positioned as dictated by the profile geometry. These either direct the flow longitudinally along the broaching tool between discrete inlet and outlet slots, or alternatively are sited along a lower tool surface to flow the electrolyte radially across the tool flanks.
- a tool generally requires a combination of such flow geometries. Ways of achieving these aims are shown in Figures 11-17.
- an electrochemical broaching apparatus for broaching an anodic workpiece 50 of electrically conductive material comprises an electrolyte bath 52, a first end wall of which is provided by the workpiece.
- An elongate horizontally disposed tool support member 54 extends over the bath 52 from a second end wall opposite the workpiece 50 to the workpiece itself.
- the electrolyte bath 52 is provided with an electrolyte supply inlet (not shown) and an outlet (not shown) to remove spent electrolyte, so that there is a continuous supply of fresh electrolyte to the bath.
- the member 54 carries underneath it an elongate broaching tool 56 which provides the cathode of the electrochemical broaching operation. Sealing between the support member 54 and the second end wall is provided by a labyrinth and brush seal arrangement 58.
- the support member 54 is able to be moved, by means of a motor arrangement (not shown) in its elongate direction over the bath 52 and over the workpiece 50.
- the broaching tool 56 is of wedge shape and is of the general construction described above with reference to Figures 2-10.
- the narrow end of the tool is provided by - ⁇ Q -
- FIG. 14a A second arrangement for supplying electrolyte to the bath 52 is shown in Figures 14, 14a, 15, and 15a.
- brush seals 68 are provided the full length of the broaching tool 56 ( Figure 15) , as well as at the front of the dummy section 60, and restrictor plates 70 ( Figure 15a) are provided to ensure low electrolyte pressure downstream.
- Electrolyte flow through the broaching tool 56 is provided by passages 72, 73, 74, 75, 76 located in the tool and extending into the electrolyte bath area between successive sections of the tool analogous to sections 18-22 described above with reference to Figures 2-10.
- Passage 72 extends through the lead-in dummy section 60.
- the final passage 76 is immediately downstream of a steeply inclined section 77 analogous to, and fulfilling the same purpose as, section 22 described above.
- Each passage 72-76 is provided with a valve mechanism (not shown) whereby each passage may individually be an electrolyte inlet, an outlet for spent electrolyte, or be closed off, depending on the stage the tool has reached in the broaching of the workpiece.
- FIG. 14a is a graphical representation of the status of each passage during a broaching operation.
- Stage 1 The lead-in insulated dummy section 60 is located over the workpiece 50.
- Passage 72 is an outlet; the remaining passages are closed; the bath is pressurised with electrolyte.
- Stage 2 The tool has progressed so that flow passage 73 is over the workpiece 50.
- Passage 72 is an inlet; passage 73 is an outlet; passages 73-76 are closed; the bath is pressurised.
- Stage 3 The tool has progressed so that flow passage 74 is over the workpiece 50.
- Passage 72 is an inlet; passage 73 is an outlet; passage 74 is an inlet; passage 75 is an outlet; passage 76 is closed; the bath is not pressurised.
- Stage 4 The tool has progressed so that flow passage 75 is over the workpiece 50.
- Passage 72 is an inlet; passage 73 is an outlet; passage 74 is an inlet; passage 75 is an outlet; passage 76 is closed; the bath is pressurised. - -
- Stage 5 The tool has progressed so that flow passage 76 is over the workpiece 50.
- Passage 72 is an inlet; passage 73 is an outlet; passage 74 is an inlet; passage 75 is an outlet; passage 76 is an inlet; the bath is no t pressurised.
- the tool is advanced so as to carry out the radiusing of the edges of the broached aperture now formed in the workpiece, as described with reference to Figure 10.
- Figures 16 and 17 show a third arrangement for supplying electrolyte to the broaching tool 56.
- Figure 16 shows a cross section through a first section of the tool when it is progressing into the workpiece 50; and
- Figure 17 shows a cross section through a later section of the tool when it is progressing into the workpiece.
- each section of the tool has its independent electrolyte suppply which pumps electrolyte down a passage 80 through the tool into the working area of the workpiece 50 as the tool progresses into the workpiece.
- the electrolyte leaves the working area between the sides of the tool and the sides of the broached aperture in the workpiece , as indicated by arrows 81.
- the invention demonstrates that the process capability of electrochemical machining can be improved so that operations requiring the precision of broaching are feasible on two dimensional profiles. Furthermore, a surface finish and roughness standards on titanium based alloys, nickel based alloys and titanium metal composites can be attained which are the equal of the equivalent metal cutting action.
- the invention eliminates the need for deburring and radiusing of edges as a separate operation by combining both machining and edge radiusing into a single process, thereby effecting significant cost savings.
- the invention further enables workpieces to be broached in substantially less time than would be taken by equivalent mechanical procedures. A time saving of up to 75% or better may be achieved.
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- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP92503806A JPH05505351A (en) | 1991-02-07 | 1992-02-06 | electrochemical polishing |
US07/927,490 US5314598A (en) | 1991-02-07 | 1992-02-06 | Electrochemical broaching apparatus |
DE69204932T DE69204932T2 (en) | 1991-02-07 | 1992-02-06 | ELECTROCHEMICAL MACHINING. |
EP92903808A EP0524284B1 (en) | 1991-02-07 | 1992-02-06 | Electrochemical machining |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9102671.6 | 1991-02-07 | ||
GB9102671A GB2254279B (en) | 1991-02-07 | 1991-02-07 | Improvements in or relating to electrochemical machining |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1992013667A2 true WO1992013667A2 (en) | 1992-08-20 |
WO1992013667A3 WO1992013667A3 (en) | 1992-10-01 |
Family
ID=10689709
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB1992/000229 WO1992013667A2 (en) | 1991-02-07 | 1992-02-06 | Electrochemical machining |
Country Status (6)
Country | Link |
---|---|
US (1) | US5314598A (en) |
EP (1) | EP0524284B1 (en) |
JP (1) | JPH05505351A (en) |
DE (1) | DE69204932T2 (en) |
GB (1) | GB2254279B (en) |
WO (1) | WO1992013667A2 (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7059827B1 (en) * | 1996-05-31 | 2006-06-13 | Watson Cogeneration Company | Turbine power plant having minimal-contact brush seal augmented labyrinth seal |
US6332962B1 (en) * | 1997-06-13 | 2001-12-25 | Micrion Corporation | Thin-film magnetic recording head manufacture using selective imaging |
US7192260B2 (en) * | 2003-10-09 | 2007-03-20 | Lehr Precision, Inc. | Progressive cavity pump/motor stator, and apparatus and method to manufacture same by electrochemical machining |
US8647022B2 (en) | 2011-02-01 | 2014-02-11 | United Technologies Corporation | Broaching tool |
US9976227B2 (en) | 2014-05-15 | 2018-05-22 | Baker Hughes, A Ge Company, Llc | Electrochemical machining method for rotors or stators for moineau pumps |
CN104227157B (en) * | 2014-08-01 | 2016-06-29 | 广东工业大学 | A kind of many potential electrolysis processing method |
CN114749739B (en) * | 2022-04-08 | 2023-07-14 | 南京航空航天大学 | Device and method for machining turbine disc mortise through pulsating precise electrolytic broaching |
US20230407516A1 (en) * | 2022-06-17 | 2023-12-21 | General Electric Company | Methods and systems of electrochemical machining |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3875038A (en) * | 1972-04-19 | 1975-04-01 | Gen Electric | Electrolytic machining apparatus |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3305470A (en) * | 1963-01-02 | 1967-02-21 | Anocut Eng Co | Electrolytic shaping apparatus for sequentially reducing the thickness of an elongated workpiece |
US3372099A (en) * | 1963-05-01 | 1968-03-05 | John E. Clifford | Electrochemical machining using a multisegmented electrode with individual current control for each segment |
US3723268A (en) * | 1967-12-21 | 1973-03-27 | Prod Eng Res Ass | Electrochemical machining |
GB1255930A (en) * | 1967-12-21 | 1971-12-01 | Production Engineering Res Ass | Improvements in or relating to electrochemical machining |
US3847781A (en) * | 1972-04-19 | 1974-11-12 | Gen Electric | Apparatus for electrolytic material removal |
JPS57132949A (en) * | 1981-02-05 | 1982-08-17 | Toshiba Corp | Contact detector |
-
1991
- 1991-02-07 GB GB9102671A patent/GB2254279B/en not_active Expired - Fee Related
-
1992
- 1992-02-06 JP JP92503806A patent/JPH05505351A/en active Pending
- 1992-02-06 WO PCT/GB1992/000229 patent/WO1992013667A2/en active IP Right Grant
- 1992-02-06 DE DE69204932T patent/DE69204932T2/en not_active Expired - Fee Related
- 1992-02-06 US US07/927,490 patent/US5314598A/en not_active Expired - Lifetime
- 1992-02-06 EP EP92903808A patent/EP0524284B1/en not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3875038A (en) * | 1972-04-19 | 1975-04-01 | Gen Electric | Electrolytic machining apparatus |
Non-Patent Citations (1)
Title |
---|
Patent Abstracts of Japan, vol. 6, no. 232 (M-172)[1110], 18th November 1982; & JP, A, 5713294 (TOKYO SHIBAURA DENKI K.K.) 17 August 1982, see the abstract * |
Also Published As
Publication number | Publication date |
---|---|
EP0524284A1 (en) | 1993-01-27 |
GB9102671D0 (en) | 1991-03-27 |
DE69204932D1 (en) | 1995-10-26 |
WO1992013667A3 (en) | 1992-10-01 |
JPH05505351A (en) | 1993-08-12 |
DE69204932T2 (en) | 1996-05-23 |
GB2254279B (en) | 1994-08-17 |
US5314598A (en) | 1994-05-24 |
GB2254279A (en) | 1992-10-07 |
EP0524284B1 (en) | 1995-09-20 |
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