WO1992002108A1 - Procede pour preparer des membranes pour des applications acoustiques en particulier pour haut-parleurs, et membranes obtenues par ce procede - Google Patents

Procede pour preparer des membranes pour des applications acoustiques en particulier pour haut-parleurs, et membranes obtenues par ce procede Download PDF

Info

Publication number
WO1992002108A1
WO1992002108A1 PCT/FR1991/000603 FR9100603W WO9202108A1 WO 1992002108 A1 WO1992002108 A1 WO 1992002108A1 FR 9100603 W FR9100603 W FR 9100603W WO 9202108 A1 WO9202108 A1 WO 9202108A1
Authority
WO
WIPO (PCT)
Prior art keywords
macropolymer
gel
dispersion
membrane
product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR1991/000603
Other languages
English (en)
French (fr)
Inventor
Pierre Fontaine
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Audax Industries SA
Original Assignee
Audax Industries SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Audax Industries SA filed Critical Audax Industries SA
Priority to JP3512793A priority Critical patent/JP3046351B2/ja
Priority to DE91913851T priority patent/DE540622T1/de
Priority to US07/969,801 priority patent/US5380960A/en
Priority to KR1019930700197A priority patent/KR100195826B1/ko
Priority to EP91913851A priority patent/EP0540622B1/fr
Priority to DE69121572T priority patent/DE69121572T2/de
Publication of WO1992002108A1 publication Critical patent/WO1992002108A1/fr
Anticipated expiration legal-status Critical
Priority to GR940300018T priority patent/GR940300018T1/el
Priority to GR960402995T priority patent/GR3021624T3/el
Ceased legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04RLOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; ELECTRIC HEARING AIDS; PUBLIC ADDRESS SYSTEMS
    • H04R31/00Apparatus or processes specially adapted for the manufacture of transducers or diaphragms therefor
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04RLOUDSPEAKERS, MICROPHONES, GRAMOPHONE PICK-UPS OR LIKE ACOUSTIC ELECTROMECHANICAL TRANSDUCERS; ELECTRIC HEARING AIDS; PUBLIC ADDRESS SYSTEMS
    • H04R31/00Apparatus or processes specially adapted for the manufacture of transducers or diaphragms therefor
    • H04R31/003Apparatus or processes specially adapted for the manufacture of transducers or diaphragms therefor for diaphragms or their outer suspension
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09GARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
    • G09G5/00Control arrangements or circuits for visual indicators common to cathode-ray tube indicators and other visual indicators
    • G09G5/22Control arrangements or circuits for visual indicators common to cathode-ray tube indicators and other visual indicators characterised by the display of characters or indicia using display control signals derived from coded signals representing the characters or indicia, e.g. with a character-code memory
    • G09G5/222Control of the character-code memory

Definitions

  • the invention relates to films or membranes for acoustic applications which must have specific vibrational properties, in particular to membranes for electro-mechanical transducers capable of transforming an electric current received into sound emission (loudspeakers) or conversely a sound wave received into current electric transmission (microphones), in particular for loudspeakers, and to the process for preparing such films or membranes.
  • the object of the invention is precisely to provide improved films or membranes for various acoustic applications.
  • the subject of the invention is firstly a process for preparing a film or membrane for acoustic applications having improved vibratory properties, characterized in that a dispersion in a liquid of at least one macropolymer is prepared, in particular at least one synthetic macropolymer, comprising in its molecule at least 30,000 atoms, which is added to the dispersion a product capable of swelling said at least one macropolymer and of transforming said dispersion into a gel or the like and which is dried said gel or the like by evaporating substantially all of the liquid from the gel or the like to obtain the film or membrane in the porous solid state.
  • the invention also relates to a porous film or membrane for acoustic applications, in particular a speaker membrane, having improved vibratory properties, characterized in that it comprises a first phase of formation of a gel or the like mistletoe results from the dispersion with dilution in a liquid of a macropolymer, in particular of a synthetic macropolymer, comprising in its molecule at least 30,000 atoms, followed by the addition to the dispersion of a product capable of transforming it into a gel or the like, and a second phase of evaporation of substantially all of the liquid from the gel or the like.
  • the macropolymer consists of a polymer of ethacrylic acid, a polymer of ethyl acetate or a mixture of such polymers, in particular of the type sold by the company HOECHST under the brand "APPRETAN 9110".
  • the macropolymer can also be polyvinyl acetate, a polyvinyl alcohol or more generally a polyvinyl polymer.
  • Another macropolymer which can advantageously be used in the context of the invention is cellulose or one of its derivatives.
  • the product added to the dispersion preferably:
  • a basic, mineral such as ammonia
  • organic liquid such as an amine
  • a basic solid such as caustic soda
  • a macropolymer of polyalcohol type for example of poly (vinyl alcohol) type, - ethyl acetate or tetrahydrofuran for a polyvinyl macropolymer.
  • the gel before drying can either be impregnated on fabrics (woven or non-woven) or locks of natural, artificial or synthetic fibers, or constituting the binder of such fibers, with the possibility of adding fillers (carbon, ceramic, glass, graphite, etc.) in each case.
  • the material thus obtained, once dried and become porous, can advantageously be thermoformed due to the flexibility of the dried material, once heated, and the thermal adhesion of the gel or the like dried on the fabrics or strands of fibers.
  • APPRETAN 9110 is an aqueous dispersion of a mixture of macropolymers consisting of 70% of methacrylic acid polymer (or polymethacrylate) and 30% of ethyl acetate polymer (or poly (ethylacetate )), with a dry extract of 32.50% of the mixture of copolymers relative to the dispersion.
  • the starting point is an aqueous dispersion containing 15% polyvinyl acetate; it is placed on a nylon canvas; the water is evaporated; and the canvas thus coated is dipped in ethyl acetate.
  • a gel having the consistency of honey is obtained, which is dried with hot air to produce the evaporation of the ethyl acetate.
  • Example 1 For example for a membrane 17 cm in diameter, the mass in the case of the application of Example 1 is 1.75 g, while it is of the order of 2.5 to 5 g for a membrane obtained from the starting aqueous dispersion of Example 1 not treated with ammonia or produced from the materials normally used, namely paper, polypropylene or suitable composite.
  • the ethyl acetate is evaporated, also with hot air.
  • the membrane thus obtained is particularly suitable for producing an electro-acoustic transducer membrane, in particular for a loudspeaker for the medium and acute channels.
  • Ammonia is added dropwise until a gel is obtained.
  • the gel thus obtained is mixed with appropriate fibers or fillers (carbon, glass, mica, kevlar, graphite) and is shaped.
  • a bath of the same mother liquor of APPRETAN 9110 is prepared (dry extract of 32.50%) which is diluted in water at the rate of 15% and it is gelled by adding ammonia drop by drop.
  • Carbon fibers are poured into the gel formed and dispersed therein in a manner homogeneous in a mixer.
  • the homogenized mixture thus obtained is passed under pressure through a sieve which retains the fibers impregnated with gel, which are dried on the sieve with hot air.
  • the shape thus obtained is removed from the sieve.
  • this form of membrane is not waterproof, it is sealed by applying a coating, such as butyl latex, or by heat bonding a sheet of waterproof thermo-adhesive polymer, such as "LITREX S "(polyethersulfone) from the company P.CD.
  • a coating such as butyl latex
  • a sheet of waterproof thermo-adhesive polymer such as "LITREX S "(polyethersulfone) from the company P.CD.
  • the invention is not limited to the embodiments or to the compounds indicated and specified, in particular in the examples, in particular to macropolymers, on the one hand, and to stabilizing liquids, on the other hand , or any additives, but it includes modifications and variants within the reach of ordinary skill in the art, including in this regard, the means of applying the product obtained according to its destination in various uses.

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Acoustics & Sound (AREA)
  • Signal Processing (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Theoretical Computer Science (AREA)
  • Diaphragms For Electromechanical Transducers (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Toys (AREA)
  • Piezo-Electric Transducers For Audible Bands (AREA)
PCT/FR1991/000603 1990-07-23 1991-07-22 Procede pour preparer des membranes pour des applications acoustiques en particulier pour haut-parleurs, et membranes obtenues par ce procede Ceased WO1992002108A1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
JP3512793A JP3046351B2 (ja) 1990-07-23 1991-07-22 改善された振動特性を示す音響適用のための膜または振動板の製造方法
DE91913851T DE540622T1 (de) 1990-07-23 1991-07-22 Verfahren zur herstellung von membranen für akustische anwendungen, insbesondere für lautsprecher, und durch dieses verfahren hergestellte membranen.
US07/969,801 US5380960A (en) 1990-07-23 1991-07-22 Process for the preparation of films or diaphragms for acoustic applications
KR1019930700197A KR100195826B1 (ko) 1990-07-23 1991-07-22 음향기기용 특히 확성기용 막의 준비방법 및 이 방법에 의해 얻은 막
EP91913851A EP0540622B1 (fr) 1990-07-23 1991-07-22 Procede pour preparer des membranes pour des applications acoustiques en particulier pour haut-parleurs, et membranes obtenues par ce procede
DE69121572T DE69121572T2 (de) 1990-07-23 1991-07-22 Verfahren zur herstellung von membranen für akustische anwendungen, insbesondere für lautsprecher, und durch dieses verfahren hergestellte membranen
GR940300018T GR940300018T1 (en) 1990-07-23 1994-04-29 Method for preparing membranes for acoustic applications in particular for loudspeakers, and membranes obtained by such method
GR960402995T GR3021624T3 (en) 1990-07-23 1996-11-14 Method for preparing membranes for acoustic applications in particular for loudspeakers, and membranes obtained by such method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9009369A FR2665321A1 (fr) 1990-07-23 1990-07-23 Procede de fabrication de membranes pour applications electro-mecaniques, notamment pour tranducteurs electro-mecaniques et produit en resultant.
FR90/09369 1990-07-23

Publications (1)

Publication Number Publication Date
WO1992002108A1 true WO1992002108A1 (fr) 1992-02-06

Family

ID=9398990

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR1991/000603 Ceased WO1992002108A1 (fr) 1990-07-23 1991-07-22 Procede pour preparer des membranes pour des applications acoustiques en particulier pour haut-parleurs, et membranes obtenues par ce procede

Country Status (13)

Country Link
US (1) US5380960A (https=)
EP (1) EP0540622B1 (https=)
JP (1) JP3046351B2 (https=)
KR (1) KR100195826B1 (https=)
AT (1) ATE141739T1 (https=)
CA (1) CA2087432A1 (https=)
DE (2) DE69121572T2 (https=)
DK (1) DK0540622T3 (https=)
ES (1) ES2044819T3 (https=)
FR (1) FR2665321A1 (https=)
GR (2) GR940300018T1 (https=)
TW (1) TW203658B (https=)
WO (1) WO1992002108A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007028525A (ja) * 2005-07-21 2007-02-01 Sony Corp 音響振動板及び音響振動板製造方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3153463A (en) * 1961-08-30 1964-10-20 Muter Company Compound loudspeaker diaphragm
FR1445262A (fr) * 1965-08-25 1966-07-08 Decca Ltd Diaphragme de haut-parleur en résine thermo-durcissable
GB1384716A (en) * 1971-05-28 1975-02-19 Matsushita Electric Industrial Co Ltd Loudspeaker diaphragm
EP0087177A1 (en) * 1982-02-22 1983-08-31 Koninklijke Philips Electronics N.V. Electro-acoustic transducer having a diaphragm comprising a layer of polymethacrylimide foam
EP0322587A2 (en) * 1987-12-01 1989-07-05 Kabushiki Kaisha Kenwood Speaker diaphragm

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3003191A (en) * 1958-09-02 1961-10-10 Harold J Luth Method of making a transducer diaphragm
US3858680A (en) * 1971-05-28 1975-01-07 Matsushita Electric Industrial Co Ltd Vibration diaphragm and cfne edge of a loudspeaker
JPS5546661A (en) * 1978-09-29 1980-04-01 Pioneer Electronic Corp Diaphragm for acoustic apparatus and its manufacture
JPS5548226A (en) * 1979-05-25 1980-04-05 Pioneer Electronic Corp Compound and its preparation
JPS58172100A (ja) * 1982-04-02 1983-10-08 Kuraray Co Ltd 音響振動板
JPS5993325A (ja) * 1982-11-19 1984-05-29 Ikeda Bussan Co Ltd 遮音シ−トの製造方法
JPS6248531A (ja) * 1985-08-28 1987-03-03 Nippon Tokushu Toryo Kk 複層成形防音材の製法
JPS62190210A (ja) * 1986-02-14 1987-08-20 Yokohama Rubber Co Ltd:The 放射線・紫外線硬化型ダンピング材組成物
JPH0667035B2 (ja) * 1987-03-04 1994-08-24 松下電器産業株式会社 スピ−カ用振動板
JP2670365B2 (ja) * 1989-10-23 1997-10-29 ソニー株式会社 振動板の製造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3153463A (en) * 1961-08-30 1964-10-20 Muter Company Compound loudspeaker diaphragm
FR1445262A (fr) * 1965-08-25 1966-07-08 Decca Ltd Diaphragme de haut-parleur en résine thermo-durcissable
GB1384716A (en) * 1971-05-28 1975-02-19 Matsushita Electric Industrial Co Ltd Loudspeaker diaphragm
EP0087177A1 (en) * 1982-02-22 1983-08-31 Koninklijke Philips Electronics N.V. Electro-acoustic transducer having a diaphragm comprising a layer of polymethacrylimide foam
EP0322587A2 (en) * 1987-12-01 1989-07-05 Kabushiki Kaisha Kenwood Speaker diaphragm

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 12, no. 40 (C-474)5 Février 1988 & JP,A,62 190 210 ( YOKOHAMA RUBBER CO LTD ) 2 Août 1987 voir abrégé *
PATENT ABSTRACTS OF JAPAN vol. 8, no. 8 (E-221)(1445) 13 Janvier 1984 & JP,A,58 172 100 ( KURARAYA K.K. ) 2 Avril 1982 voir abrégé *

Also Published As

Publication number Publication date
CA2087432A1 (fr) 1992-01-24
DK0540622T3 (da) 1997-01-13
EP0540622A1 (fr) 1993-05-12
DE540622T1 (de) 1994-04-21
JPH06501822A (ja) 1994-02-24
EP0540622B1 (fr) 1996-08-21
ATE141739T1 (de) 1996-09-15
JP3046351B2 (ja) 2000-05-29
ES2044819T1 (es) 1994-01-16
DE69121572T2 (de) 1997-03-27
GR940300018T1 (en) 1994-04-29
US5380960A (en) 1995-01-10
FR2665321A1 (fr) 1992-01-31
ES2044819T3 (es) 1996-12-01
DE69121572D1 (de) 1996-09-26
KR100195826B1 (ko) 1999-06-15
TW203658B (https=) 1993-04-11
GR3021624T3 (en) 1997-02-28
KR930702868A (ko) 1993-09-09

Similar Documents

Publication Publication Date Title
KR102088709B1 (ko) 지지체 상에 nfc 필름의 제작 방법
BE1001197A3 (fr) Materiau de structure a base de silicate et de polymere, resistant a l'eau, et son procede de fabrication.
CN1671249A (zh) 声纸膜和声传感器设备
FR2837493A1 (fr) Aerogel a base d'un polymere ou copolymere hydrocarbone et leur procede de preparation
EP0540622B1 (fr) Procede pour preparer des membranes pour des applications acoustiques en particulier pour haut-parleurs, et membranes obtenues par ce procede
EP0100720B1 (fr) Feuille papetière à très fort taux de latex, son procédé de préparation et ses applications notamment comme produit de substitution de voiles de verre imprégnés
CN110636418A (zh) 一种扬声器纸盆及其制备方法和应用
FR2865482A1 (fr) Nouveau support a base de fibres cellulosiques destine a etre silicone
JPH0984175A (ja) 音響用振動板及びその製造方法
JP6584784B2 (ja) 電気音響変換器用振動板の製造方法
FR2636197A1 (fr) Procede de production d'une membrane acoustique en carbone
FR2599663A1 (fr) Procede pour la fabrication de plaques notamment pour l'isolation acoustique renfermant des fibres minerales et de la perlite expansee et plaques ainsi obtenues
JPH0646491A (ja) 電気音響変換器用振動板
JPS61245699A (ja) スピ−カ用振動板
JPS6075700A (ja) 透気性を備え,ヒ−トシ−ル可能なパ−チメント紙
CN115243874B (zh) 具有增强疏水性的聚丙烯膜及其制备方法和用途
CN1032094A (zh) 传声材料
JP3080788B2 (ja) ボイスコイルボビン
EP0406039B1 (fr) Procédé de préparation par voie papetière de feuilles de produits fibreux à base de cellulose et enrichis de résines élastomères
KR100254889B1 (ko) 스피커용 진동판 및 그 제조방법
CN121151725A (zh) 一种高音球顶音膜及其制备方法和应用
JPS59218095A (ja) スピ−カ用振動板
JPS6041397A (ja) 音響用振動板の製造方法
JPS6135099A (ja) スピ−カ用振動板
JPH06125593A (ja) 電気音響変換器用振動板

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): CA JP KR US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IT LU NL SE

WWE Wipo information: entry into national phase

Ref document number: 1991913851

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2087432

Country of ref document: CA

WWP Wipo information: published in national office

Ref document number: 1991913851

Country of ref document: EP

WWG Wipo information: grant in national office

Ref document number: 1991913851

Country of ref document: EP