WO1990015011A1 - Method and device for carbonating and cooling a liquid - Google Patents

Method and device for carbonating and cooling a liquid Download PDF

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Publication number
WO1990015011A1
WO1990015011A1 PCT/SE1990/000371 SE9000371W WO9015011A1 WO 1990015011 A1 WO1990015011 A1 WO 1990015011A1 SE 9000371 W SE9000371 W SE 9000371W WO 9015011 A1 WO9015011 A1 WO 9015011A1
Authority
WO
WIPO (PCT)
Prior art keywords
liquid
carbon dioxide
vessel
cooling
conduit
Prior art date
Application number
PCT/SE1990/000371
Other languages
French (fr)
Inventor
Bengt Adolfsson
Original Assignee
Post-Mix Equipment Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Post-Mix Equipment Ab filed Critical Post-Mix Equipment Ab
Priority to CA002056624A priority Critical patent/CA2056624A1/en
Priority to EP90909209A priority patent/EP0474758B1/en
Priority to KR1019910701729A priority patent/KR920701034A/en
Priority to BR909007408A priority patent/BR9007408A/en
Priority to DE69012559T priority patent/DE69012559T2/en
Publication of WO1990015011A1 publication Critical patent/WO1990015011A1/en
Priority to FI915579A priority patent/FI91958C/en
Priority to NO914679A priority patent/NO176473C/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67DDISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
    • B67D1/00Apparatus or devices for dispensing beverages on draught
    • B67D1/04Apparatus utilising compressed air or other gas acting directly or indirectly on beverages in storage containers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B9/00Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
    • F25B9/002Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
    • F25B9/008Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant being carbon dioxide
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/04Production of frozen sweets, e.g. ice-cream
    • A23G9/06Production of frozen sweets, e.g. ice-cream characterised by using carbon dioxide or carbon dioxide snow or other cryogenic agents as cooling medium
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/36Freezing; Subsequent thawing; Cooling
    • A23L3/37Freezing; Subsequent thawing; Cooling with addition of or treatment with chemicals
    • A23L3/375Freezing; Subsequent thawing; Cooling with addition of or treatment with chemicals with direct contact between the food and the chemical, e.g. liquid nitrogen, at cryogenic temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/236Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids specially adapted for aerating or carbonating beverages
    • B01F23/2362Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids specially adapted for aerating or carbonating beverages for aerating or carbonating within receptacles or tanks, e.g. distribution machines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67DDISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
    • B67D1/00Apparatus or devices for dispensing beverages on draught
    • B67D1/0042Details of specific parts of the dispensers
    • B67D1/0057Carbonators
    • B67D1/0069Details
    • B67D1/0071Carbonating by injecting CO2 in the liquid
    • B67D1/0072Carbonating by injecting CO2 in the liquid through a diffuser, a bubbler
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67DDISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
    • B67D1/00Apparatus or devices for dispensing beverages on draught
    • B67D1/08Details
    • B67D1/0857Cooling arrangements
    • B67D1/0858Cooling arrangements using compression systems
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/90Heating or cooling systems
    • B01F2035/98Cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/50Circulation mixers, e.g. wherein at least part of the mixture is discharged from and reintroduced into a receptacle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B2309/00Gas cycle refrigeration machines
    • F25B2309/06Compression machines, plants or systems characterised by the refrigerant being carbon dioxide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S261/00Gas and liquid contact apparatus
    • Y10S261/07Carbonators

Definitions

  • the present invention concerns a method for carbonating and cooling a liquid, particularly a beverage, wherein carbon dioxide under high pressure is introduced under the liquid surface and is allowed to expand and dissolve in the liquid.
  • the invention also concerns a device for carrying out this method, said device including a closed vessel, a liquid inlet opening into the vessel, a carbon dioxide inlet opening into the vessel under the surface of the liquid, a discharge conduit for carbonated liquid, and, leading from the vessel above the liquid surface a re-circulation conduit for carbon dioxide not dissolved in the liquid.
  • US-A-4 022 119 describes a method and a device for simultaneous carbonating and cooling of a liquid using expanding carbon dioxide.
  • the carbon dioxide is kept stored in a tank from which it is introduced at the bottom of an upwardly open carbonating vessel, into which is also successively introduced the liquid to be carbonated.
  • the carbonated liquid flows over the edge of the upwardly open carbonating vessel and down into a surrounding vessel from the bottom of which the carbonated liquid is conducted further to be drawn into containers for consumption.
  • the cooling with expanding carbon dioxide has as its only object to make possible dissolution of larger amounts of carbon dioxide than otherwise would be possible.
  • the object of the present invention is to provide a new method and a new device for carbonating and cooling of liquids, said device working with only one circuit, which makes the device more simple and cheap.
  • the device shall be suitable for preparing cooled carbonated beverages in households, in offices and the like where a fast and effectively working device requiring little space is demanded.
  • a feeding conduit 2 for liquid such as water
  • a high pressure conduit 3 for introducing carbon dioxide in the liquid
  • a refill conduit 4 for carbon dioxide
  • a discharge conduit 5 for carbonated liquid.
  • a re-circulation conduit 6 for carbon dioxide.
  • the re-circulation conduit 6 is. connected to a compressor 7 the output side of which is connected to the high pressure conduit 3 through a cooler 8.
  • the undissolved carbon dioxide located in the volume 10, possibly through a humidity regulator 11, is re-circulated through the re-circulation conduit 6 to the container 1.
  • this takes place through the compressor 7 which shall be capable to achieve a substantial rise of the pressure in the carbon dioxide from a pressure of about 0,7 - 1 MPa preferably to a pressure of about 6,5 MPa or more, such that the carbon dioxide is transferred to liquid phase.
  • the temperature of the carbon dioxide is considerably raised (up to about 250°C) . Therefore, it is suitable to divide the compression in two steps by means of a two step compressor with intervening cooling.
  • the carbon dioxide which is hot after compression, is cooled in the cooler 8, whereafter the carbon dioxide, preferably in liquid state, is introduced through the conduit 6 and a restriction nozzle 12 into the volume 9 of liquid and is there allowed to expand and transform into steam phase.
  • the lowering of temperature resulting from the expansion in the restriction nozzle 12 is used for cooling the liquid simultaneously as the gaseous carbon dioxide on its way up towards the liquid surface partly dissolves in the liquid and carbonates it.
  • a device according to the present invention used for carbonating and cooling bererages i.e., as a lemonade machine, provides substantial advantages compared to such devices having separate carbonating and cooling circuits.
  • Tests have been performed applicating the method stated and utilizing a test device using liquid carbon dioxide from a bottle.
  • the carbon dioxide had a temperature of about +20°C and was injected into a water volume of 3 litres which also had a temperature of about +20°C.
  • a carbon dioxide flow of about 100 g/min a lowering of temperature in the water volume of 6,3°C/lmin was obtained which corresponds to a cooling effect of -0,53°C per 20 cl and second.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Food Science & Technology (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Non-Alcoholic Beverages (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Heat Treatments In General, Especially Conveying And Cooling (AREA)
  • Devices For Dispensing Beverages (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Devices That Are Associated With Refrigeration Equipment (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

In a method for simultaneously carbonating and cooling a liquid carbon dioxide under high pressure is introduced under the liquid surface and is allowed to expand and dissolve in the liquid. Carbon dioxide not dissolved in the liquid is re-introduced under the liquid surface through a compressor and a cooler. A device for carrying out the method includes a closed vessel (1), a liquid inlet (2) opening into the vessel, a carbon dioxide inlet (12) opening into the vessel (1) under the liquid surface, a discharge conduit (5) for carbonated vessel, and, leading from the vessel (1) above the liquid surface, a re-circulation conduit (6, 3) for carbon dioxide not dissolved in the liquid, a compressor (7) and a cooler (8) being arranged in the re-circulation conduit (6, 3).

Description

METHOD AND DEVICE FOR CARBONATING AND COOLING A LIQUID
The present invention concerns a method for carbonating and cooling a liquid, particularly a beverage, wherein carbon dioxide under high pressure is introduced under the liquid surface and is allowed to expand and dissolve in the liquid. The invention also concerns a device for carrying out this method, said device including a closed vessel, a liquid inlet opening into the vessel, a carbon dioxide inlet opening into the vessel under the surface of the liquid, a discharge conduit for carbonated liquid, and, leading from the vessel above the liquid surface a re-circulation conduit for carbon dioxide not dissolved in the liquid.
Many different methods and devices for carbonating liquids are known, for instance through DE-25 59 651 and 29 40 407, wherein carbon dioxide under relatively low pressure and through porous diffusers are introduced under the surface of the liquid in order to raise against the liquid surface in the shape of very fine bubbles and under dissolution in the liquid. According to DE-29 40 407 the liquid is further sprayed in an atomized shape into the volume of carbon dioxide undissolved in the liquid which is located above the liquid surface in order threreby to further increase the amount of carbon dioxide dissolved in the liquid. A pump withdraws carbon dioxide from the volume of undissolved carbon dioxide mentioned and re-introduces it under the surface of the liquid. Cooling of the liquid is achieved by cooling circuits arranged in the liquid or outside its vessel .
The known devices for carrying out these methods, thus, require a carbon dioxide circuit as well as a cooling circuit and, therefore, are expensive as well as cumbersome. US-A-4 022 119 describes a method and a device for simultaneous carbonating and cooling of a liquid using expanding carbon dioxide. The carbon dioxide is kept stored in a tank from which it is introduced at the bottom of an upwardly open carbonating vessel, into which is also successively introduced the liquid to be carbonated. The carbonated liquid flows over the edge of the upwardly open carbonating vessel and down into a surrounding vessel from the bottom of which the carbonated liquid is conducted further to be drawn into containers for consumption. In this known method, which is adapted for industrial, large scale operation, the cooling with expanding carbon dioxide has as its only object to make possible dissolution of larger amounts of carbon dioxide than otherwise would be possible.
The object of the present invention is to provide a new method and a new device for carbonating and cooling of liquids, said device working with only one circuit, which makes the device more simple and cheap. Particularly, the device shall be suitable for preparing cooled carbonated beverages in households, in offices and the like where a fast and effectively working device requiring little space is demanded.
In order to achieve these objects the invention has been given the characteristics appearing in the following claims.
The invention will now be more closely explained, reference being made to the accompanying drawing schematically showing a device according to the invention.
In a vertical wall of a closed container 1 opens a feeding conduit 2 for liquid, such as water, and in the bottom of the container open a high pressure conduit 3 for introducing carbon dioxide in the liquid and a refill conduit 4 for carbon dioxide. Also extending from the bottom of the container is a discharge conduit 5 for carbonated liquid. From the upper wall of the container extends a re-circulation conduit 6 for carbon dioxide.
The re-circulation conduit 6 is. connected to a compressor 7 the output side of which is connected to the high pressure conduit 3 through a cooler 8.
When filling liquid through conduit 2 a volume 9 of liquid is obtained in the container 1, and, by injection of carbon dioxide through the filling conduit 4 a volume 10 of carbon dioxide undissolved in the liquid is obtained located above the liquid surface.
In a known manner the undissolved carbon dioxide located in the volume 10, possibly through a humidity regulator 11, is re-circulated through the re-circulation conduit 6 to the container 1. According to the present invention, however, this takes place through the compressor 7 which shall be capable to achieve a substantial rise of the pressure in the carbon dioxide from a pressure of about 0,7 - 1 MPa preferably to a pressure of about 6,5 MPa or more, such that the carbon dioxide is transferred to liquid phase. At compression the temperature of the carbon dioxide is considerably raised (up to about 250°C) . Therefore, it is suitable to divide the compression in two steps by means of a two step compressor with intervening cooling. In any case, the carbon dioxide, which is hot after compression, is cooled in the cooler 8, whereafter the carbon dioxide, preferably in liquid state, is introduced through the conduit 6 and a restriction nozzle 12 into the volume 9 of liquid and is there allowed to expand and transform into steam phase. According to the present invention, the lowering of temperature resulting from the expansion in the restriction nozzle 12 is used for cooling the liquid simultaneously as the gaseous carbon dioxide on its way up towards the liquid surface partly dissolves in the liquid and carbonates it.
In the device is also included means not shown to achieve filling of liquid through the conduit 2 preferably opening - above the liquid surface, as well as means not shown to fill carbon dioxide into the system through the conduit 4 at need.
A device according to the present invention used for carbonating and cooling bererages, i.e., as a lemonade machine, provides substantial advantages compared to such devices having separate carbonating and cooling circuits. Tests have been performed applicating the method stated and utilizing a test device using liquid carbon dioxide from a bottle. The carbon dioxide had a temperature of about +20°C and was injected into a water volume of 3 litres which also had a temperature of about +20°C. At a carbon dioxide flow of about 100 g/min a lowering of temperature in the water volume of 6,3°C/lmin was obtained which corresponds to a cooling effect of -0,53°C per 20 cl and second. This, in turn means that the system theoretically manages to cool a normal drinking glass (20 cl> of a +15°C beverage to +5°C in less than 20 seconds. Since usual tap water normally has a temperature of about +10°C one can calculate to obtain a cooling of 20 cl such water to +5°C in less than 10 seconds. Simultaneously, carbonating takes place within a few seconds .

Claims

C L A I M S
1. A method for simultaneous carbonating and cooling of a
\ liquid, wherein carbon dioxide under high pressure is introduced under the liquid surface and is allowed to expand and dissolve in the liquid, c h a r a c t e r i z e d i n that carbon dioxide not dissolved in the liquid is re-circulated by being conducted to a compressor and therefrom to a cooler wherefrom the compressed and cooled carbon dioxide is re-introduced under the liquid surface.
2. A method according to claim 1, c h a r a c t e r ¬ i z e d i n that the carbon dioxide is compressed into liquid state.
3. A device for simultaneous carbonating and cooling of a liquid, particularly a beverage, carrying out the method according to any of claims 1 and 2, including a closed vessel (1), a liquid inlet (2) opening into the vessel, a carbon dioxide inlet (12) opening into the vessel <1) under the liquid surface, a discharge conduit <5> for carbonated liquid, and, leading from the vessel (1) above the liquid surface, a re-circulation conduit (6,3) for carbon dioxide not dissolved in the liquid, c h a r a c t e r i z e d i n that a compressor (7) is arranged in the re-circulation conduit (6,3), and in that after the compressor (7) is arranged a cooler (8) which is connected to the carbon dioxide inlet (12).
4. A device according to claim 4, c h a r a c t e r ¬ i z e d i n that a refill conduit (4) for carbon dioxide is also opening into the container (1) under the liquid surface .
PCT/SE1990/000371 1989-05-31 1990-05-30 Method and device for carbonating and cooling a liquid WO1990015011A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CA002056624A CA2056624A1 (en) 1989-05-31 1990-05-30 Method and device for carbonating and cooling a liquid
EP90909209A EP0474758B1 (en) 1989-05-31 1990-05-30 Method and device for carbonating and cooling a liquid
KR1019910701729A KR920701034A (en) 1989-05-31 1990-05-30 Carbonation and cooling method of liquids and apparatus
BR909007408A BR9007408A (en) 1989-05-31 1990-05-30 PROCESS AND DEVICE FOR SIMULTANEOUS CARBONATING AND COOLING OF A LIQUID
DE69012559T DE69012559T2 (en) 1989-05-31 1990-05-30 METHOD AND DEVICE FOR CARBONIZING AND COOLING LIQUIDS.
FI915579A FI91958C (en) 1989-05-31 1991-11-27 Method and apparatus for carbonating and cooling a liquid
NO914679A NO176473C (en) 1989-05-31 1991-11-28 Method and apparatus for simultaneous carbonation and cooling of a liquid

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE8901970A SE464761B (en) 1989-05-31 1989-05-31 PROCEDURE AND DEVICE FOR CARBON ACID RESOLUTION AND COOLING OF A CHEER
SE8901970-7 1989-05-31

Publications (1)

Publication Number Publication Date
WO1990015011A1 true WO1990015011A1 (en) 1990-12-13

Family

ID=20376133

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE1990/000371 WO1990015011A1 (en) 1989-05-31 1990-05-30 Method and device for carbonating and cooling a liquid

Country Status (18)

Country Link
US (1) US5231851A (en)
EP (1) EP0474758B1 (en)
JP (1) JP2875885B2 (en)
KR (1) KR920701034A (en)
AT (1) ATE111425T1 (en)
AU (1) AU634790B2 (en)
BR (1) BR9007408A (en)
CA (1) CA2056624A1 (en)
DE (1) DE69012559T2 (en)
DK (1) DK0474758T3 (en)
ES (1) ES2060177T3 (en)
FI (1) FI91958C (en)
HU (1) HU212724B (en)
IL (1) IL94517A (en)
MX (1) MX173061B (en)
NO (1) NO176473C (en)
SE (1) SE464761B (en)
WO (1) WO1990015011A1 (en)

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WO1994012425A1 (en) * 1992-11-20 1994-06-09 Ab Konstruktions-Bakelit Method and apparatus for carbonating and chilling a liquid
WO1995009124A1 (en) * 1993-09-28 1995-04-06 Post-Mix Equipment Ab Method and device for cooling and carbonating a liquid
WO2000043311A1 (en) * 1999-01-19 2000-07-27 Whitlenge Drink Equipment Limited Improvements relating to cooling devices
KR100878788B1 (en) 2008-06-03 2009-01-14 주식회사 엠씨테크 Aparatus for dissolution of gas including filter

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NL9401324A (en) * 1994-08-16 1996-04-01 Urenco Nederland Bv Cooling process and cooling installation
FR2782153B1 (en) * 1998-08-05 2000-12-01 Air Liquide DEVICE AND METHOD FOR INJECTING A REFRIGERANT FLUID IN A PRODUCT MIXER
US6178875B1 (en) * 1999-01-19 2001-01-30 Lancer Partnership. Ltd. Carbon dioxide precooling system for a carbonator
US6576276B1 (en) 2000-10-25 2003-06-10 The Coca-Cola Company CO2-hydrate product and method of manufacture thereof
DE20215685U1 (en) * 2002-10-11 2004-04-01 Spengler Gmbh & Co. Kg carbonator
US7344716B2 (en) * 2003-05-13 2008-03-18 Depuy Spine, Inc. Transdiscal administration of specific inhibitors of pro-inflammatory cytokines
GB2425165A (en) * 2005-03-08 2006-10-18 Imi Vision Ltd Making frozen carbonated beverages(FCBs)
GB0511455D0 (en) * 2005-06-06 2005-07-13 Imi Cornelius Uk Ltd Apparatus and method for dispensing frozen carbonated beverages
DE102005045157A1 (en) * 2005-09-21 2007-03-29 Friedhelm Selbach Gmbh Process for the carbonation of water in a beverage dispenser and arrangement for mixing CO2 with water
DE102007016712A1 (en) * 2007-04-04 2008-10-09 Air Liquide Deutschland Gmbh Method and device for cooling a liquid
US8048830B1 (en) 2008-06-19 2011-11-01 Cool Clean Technologies, Inc. Method of forming and using carbonated machining fluid
MX338655B (en) * 2009-10-22 2016-04-27 Angel Jose Enrique Soto Porrua Reduction of the cooling time of the beer in processing tanks by injecting carbon dioxide gas.
EP2766108B1 (en) 2011-10-11 2016-08-17 Flow Control LLC. Adjustable in-line on demand carbonation chamber for beverage applications
US9352355B1 (en) 2012-04-15 2016-05-31 David P. Jackson Particle-plasma ablation process
CA2946442C (en) 2015-10-28 2018-05-01 Guy Tipton Beverage carbonation system and method
BR112018009410B1 (en) * 2015-11-30 2022-09-20 Unilever Ip Holdings B.V. PROCESS FOR MANUFACTURING FROZEN GAS HYDRATES FOR USE IN A FROZEN CONFECTIONERY PRODUCT
MX2019011852A (en) 2017-04-04 2020-12-11 Cleanlogix Llc PASSIVE ELECTROSTATIC CO<sub>2 </sub>COMPOSITE SPRAY APPLICATOR.

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US4808346A (en) * 1972-07-20 1989-02-28 Strenger & Associates Carbonated beverage dispensing apparatus and method

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US3672182A (en) * 1970-06-25 1972-06-27 Air Prod & Chem Water cooling method and apparatus employing liquid nitrogen
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GB1051907A (en) * 1963-05-07
US4808346A (en) * 1972-07-20 1989-02-28 Strenger & Associates Carbonated beverage dispensing apparatus and method
US4022119A (en) * 1975-12-22 1977-05-10 Shasta Beverages Division Of Consolidated Food Corporation Liquid carbon dioxide carbonation apparatus
US4110996A (en) * 1977-05-02 1978-09-05 Phillips Petroleum Company Method and apparatus for recovering vapor
DE2940407A1 (en) * 1979-10-05 1981-04-09 Cornelius Apparate Gmbh, 4018 Langenfeld METHOD AND DEVICE FOR ENRICHING LIQUIDS WITH GASES

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994012425A1 (en) * 1992-11-20 1994-06-09 Ab Konstruktions-Bakelit Method and apparatus for carbonating and chilling a liquid
WO1995009124A1 (en) * 1993-09-28 1995-04-06 Post-Mix Equipment Ab Method and device for cooling and carbonating a liquid
US5749233A (en) * 1993-09-28 1998-05-12 Post-Mix Equipment Ab Method and device for cooling and carbonating a liquid
WO2000043311A1 (en) * 1999-01-19 2000-07-27 Whitlenge Drink Equipment Limited Improvements relating to cooling devices
KR100878788B1 (en) 2008-06-03 2009-01-14 주식회사 엠씨테크 Aparatus for dissolution of gas including filter

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DK0474758T3 (en) 1994-10-17
AU634790B2 (en) 1993-03-04
NO914679L (en) 1991-11-28
ATE111425T1 (en) 1994-09-15
DE69012559T2 (en) 1995-02-02
EP0474758A1 (en) 1992-03-18
DE69012559D1 (en) 1994-10-20
IL94517A0 (en) 1991-03-10
KR920701034A (en) 1992-08-11
BR9007408A (en) 1992-06-16
SE464761B (en) 1991-06-10
SE8901970L (en) 1990-12-01
IL94517A (en) 1992-11-15
NO914679D0 (en) 1991-11-28
CA2056624A1 (en) 1990-12-01
MX173061B (en) 1994-01-31
ES2060177T3 (en) 1994-11-16
US5231851A (en) 1993-08-03
FI91958C (en) 1994-09-12
FI915579A0 (en) 1991-11-27
EP0474758B1 (en) 1994-09-14
HU212724B (en) 1996-10-28
JP2875885B2 (en) 1999-03-31
FI91958B (en) 1994-05-31
AU5823490A (en) 1991-01-07
NO176473B (en) 1995-01-02
NO176473C (en) 1995-04-12
JPH04505904A (en) 1992-10-15
HU904795D0 (en) 1992-02-28
SE8901970D0 (en) 1989-05-31
HUT59359A (en) 1992-05-28

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