WO1990000928A1 - Salzwasserdestillationsvorrichtung - Google Patents

Salzwasserdestillationsvorrichtung Download PDF

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Publication number
WO1990000928A1
WO1990000928A1 PCT/EP1989/000860 EP8900860W WO9000928A1 WO 1990000928 A1 WO1990000928 A1 WO 1990000928A1 EP 8900860 W EP8900860 W EP 8900860W WO 9000928 A1 WO9000928 A1 WO 9000928A1
Authority
WO
WIPO (PCT)
Prior art keywords
spacer grid
condensation
distillate
spacer
concentrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1989/000860
Other languages
German (de)
English (en)
French (fr)
Inventor
Günter WIEDNER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of WO1990000928A1 publication Critical patent/WO1990000928A1/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/36Pervaporation; Membrane distillation; Liquid permeation
    • B01D61/364Membrane distillation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/10Spiral-wound membrane modules
    • B01D63/101Spiral winding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/131Reverse-osmosis

Definitions

  • the invention relates to a salt water distillation device according to the preamble of claim 1, which is used in particular for the production of fresh water from sea water.
  • membrane distillation which is derived from the magazine Chem.-Ing.-Tech. 56 (1984) No. 7, pages 514 to 521. From this document and US Pat. No. 3,340,186 it is already known to wind up the individual layers contained in the device in a spiral, so as to achieve a compact structural arrangement with a large distillation area.
  • the efficiency of the known salt water distillation devices is limited by the fact that the turbulence within the hot concentrate stream and within the cooling liquid stream is too low.
  • an increase in the turbulence must not result in an excessive pressure loss between the flow inlet and outlet, because this would again increase the energy consumption of the device too much.
  • the aim of the invention is therefore to create a salt water distillation device of the type mentioned at the outset, the efficiency of which is increased by increased turbulence in the hot water and cooling channels, but the pressure loss occurring in the individual channels remains low.
  • the invention is significantly developed by the features of claims 6 to 9. Because a special distillate spacer grid is provided in the distillation chamber or channel, the distillate can be discharged largely without resistance and unhindered and without the formation of pockets in the direction of the path of the hot concentrate.
  • the embodiment according to claim 10 is useful to the unreinforced layer of the membrane against the distillate to protect the support grid, which can be designed according to the requirements of proper spacing and removal of the distillate in the distillate channel.
  • FIG. 1 shows a schematic cross section through part of the spiral winding of a salt water distillation device according to the invention
  • FIG. 2 shows a top view of a hot concentrate or cooling liquid spacer grid for a salt water distillation device according to the invention
  • FIG. 3 shows a section along line III-III in FIG. 2,
  • Fig. 4 is a schematic plan view of a distillate spacer grid according to the invention.
  • Fig. 5 is a cal atic section along line VV in Fig.4.
  • Fig. 1 shows only a section of a spiral wrap for a salt water distillation device according to the invention.
  • the various positions shown in FIG. 1 repeat themselves radially outwards and inwards to an outermost or innermost position, which radially supplies the unheated cool sea water K or radially inwards the heated sea water W in countercurrent or the distillate D formed is removed radially outside.
  • the core component of the spiral wrap is two microporous membranes 12 arranged on the two surfaces of a hot concentrate spacer grid 11, which have the property that they let steam through, but not water or salt molecules.
  • a water-permeable protective layer 18 which can be designed, for example, as a perforated plastic film and represents a support layer for the actual membrane 12.
  • a protective layer grid 19 indicated by dots, which can have the shape of a fine fabric or a very thin perforated film.
  • a distillate spacer grid 17 adjoins the water-permeable protective layer 19 radially outwards or inwards, followed by a water and vapor-impermeable condensation film 13 on the outside or inside, on which a coolant is applied radially from the outside or radially from the inside.
  • Spacer grid 14 connects, which is again covered on the outside or inside by a water and vapor impermeable condensation film 13.
  • the spiral wrap is tightly sealed by cast synthetic resin plates, so that the outer or inner circumferential side introduced liquid is forced to flow on spiral tracks from the outside in or from the inside out.
  • unheated and preferably cool sea water K flows into the space containing the cooling liquid spacer grids 14 between two condensation foils 13, which sea water K is discharged axially in the center of the spiral winding (not shown) and is fed to a heating device which is preferably heated by solar energy .
  • the heated sea water is fed back centrally into the winding and, in countercurrent to the cool sea water K as hot sea water stream W, is introduced into the space formed by the hot concentrate spacer grid 11, where it rotates counterclockwise in the spiral wrap radially from the inside flows outside.
  • the heated sea water W which had largely been cooled up to that point, is again removed from the spiral wrap and either returned to the sea or passed through the spiral wrap in a further cycle.
  • the distillate D collects in the space formed by the distillate spacing grid 17 and then flows counterclockwise in the direction of the arrows D in FIG. 1 in a spiral wrap gradually from the inside out, where it is then drawn off at the radially outermost positions can.
  • the direction of flow of the unheated sea water K or of the heated sea water W is designated by R in FIG. 2.
  • the webs 15, 16 of the two spacer grids 11 and 14 are clearly arranged at an angle of 45 ° to the flow direction R, while according to FIG. 3 the webs 16 are arranged on the webs 15 running at 90 ° to them , ie that the webs 16 and the webs 15 run in two different planes.
  • the warp and weft threads extend in or perpendicular to the flow direction S of the distillate D, openings for the distillate D are thus provided in the circumferential direction over the entire axial extent of the spiral wrap, so that there is a uniform outflow of the distillate D over the entire axial length of the spiral wrap . This also significantly increases the distillation efficiency.
  • the condensation films 13 are preferably designed as FEP films (Hostaflon-ET) and have a thickness of 150 ⁇ .
  • the spacer grids 11, 14 are advantageously made of polypropylene or high density polyethylene.
  • the distillation spacer grid 17 can also be made of the same material, but is only about 1/10 as thin as the spacer grid 11, 14.
  • the condensation foils 13 can advantageously consist of cold-rolled stainless steel strip with a thickness of 0.2 mm.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
PCT/EP1989/000860 1988-07-21 1989-07-21 Salzwasserdestillationsvorrichtung Ceased WO1990000928A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP3824839.5 1988-07-21
DE3824839A DE3824839C1 (https=) 1988-07-21 1988-07-21

Publications (1)

Publication Number Publication Date
WO1990000928A1 true WO1990000928A1 (de) 1990-02-08

Family

ID=6359264

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1989/000860 Ceased WO1990000928A1 (de) 1988-07-21 1989-07-21 Salzwasserdestillationsvorrichtung

Country Status (3)

Country Link
EP (1) EP0351879A1 (https=)
DE (1) DE3824839C1 (https=)
WO (1) WO1990000928A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113214530A (zh) * 2021-05-27 2021-08-06 齐鲁工业大学 高吸热改性亲水pdms太阳能淡水收集反应器及其应用

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5275726A (en) * 1992-07-29 1994-01-04 Exxon Research & Engineering Co. Spiral wound element for separation
AU4124296A (en) * 1994-12-09 1996-06-26 Nederlandse Organisatie Voor Toegepast- Natuurwetenschappelijk Onderzoek Tno Method and installation for treating a medium
NL9500202A (nl) * 1995-02-03 1996-09-02 Tno Werkwijze en inrichting voor het behandelen van een medium.
DE19603380C2 (de) * 1995-02-01 1998-04-09 Christian Von Dr Geiso Integrierte Verdampfer-Kondensatoreinheit
JP3998142B2 (ja) * 2003-03-20 2007-10-24 日東電工株式会社 スパイラル型分離膜エレメント
DE102004013647A1 (de) * 2004-03-19 2005-10-06 Wolfgang Heinzl Verfahren und Vorrichtung zur Destillation von Lösungen
US20080156730A1 (en) * 2005-02-28 2008-07-03 Alfa Laval Corporate Ab Permeate Spacer Module
SE534744C2 (sv) * 2005-02-28 2011-12-06 Alfa Laval Corp Ab Platt membransystem innefattande ett distanselement
SE530221C2 (sv) * 2005-02-28 2008-04-01 Alfa Laval Corp Ab Spirallindad membranmodul med distanselement för permeat

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0039197A1 (en) * 1980-04-25 1981-11-04 W.L. GORE & ASSOCIATES, INC. Distillation apparatus
EP0088315A1 (en) * 1982-03-05 1983-09-14 W.L. Gore & Associates, Inc. Desalination device and process
EP0096340A2 (de) * 1982-06-01 1983-12-21 GFT Ingenieurbüro für Industrieanlagenbau Membranmodul und seine Verwendung zur Trennung von Flüssigkeiten nach dem Pervaporationsverfahren
GB2151155A (en) * 1983-12-13 1985-07-17 Nitto Electric Ind Co Thermopervaporation apparatus
JPS60187305A (ja) * 1984-03-05 1985-09-24 Sasakura Eng Co Ltd 透過膜式蒸溜装置
JPH0634786A (ja) * 1992-07-15 1994-02-10 Hitachi Ltd 軽水炉プラントを構成する材料の余寿命推定方法とその装置

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Publication number Priority date Publication date Assignee Title
US3340186A (en) * 1964-05-14 1967-09-05 Research Corp Recovery of demineralized water from saline waters
GB1096680A (en) * 1964-12-09 1967-12-29 Pactide Corp Distillation apparatus and method of distillation
DE1519678C3 (de) * 1964-12-09 1978-04-13 Pactide Corp., Cambridge, Mass. (V.St.A.) Destillationsvorrichtung
NL134879C (https=) * 1964-12-09 1900-01-01
US3878054A (en) * 1964-12-09 1975-04-15 Pactide Corp Distillation apparatus and process

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0039197A1 (en) * 1980-04-25 1981-11-04 W.L. GORE & ASSOCIATES, INC. Distillation apparatus
EP0088315A1 (en) * 1982-03-05 1983-09-14 W.L. Gore & Associates, Inc. Desalination device and process
EP0096340A2 (de) * 1982-06-01 1983-12-21 GFT Ingenieurbüro für Industrieanlagenbau Membranmodul und seine Verwendung zur Trennung von Flüssigkeiten nach dem Pervaporationsverfahren
GB2151155A (en) * 1983-12-13 1985-07-17 Nitto Electric Ind Co Thermopervaporation apparatus
JPS60187305A (ja) * 1984-03-05 1985-09-24 Sasakura Eng Co Ltd 透過膜式蒸溜装置
JPH0634786A (ja) * 1992-07-15 1994-02-10 Hitachi Ltd 軽水炉プラントを構成する材料の余寿命推定方法とその装置

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Ind. Eng. Chem. Process Design and Development, Band 20, Nr. 1, Januar 1981, American Chemical Society, (Washington, US) W.G. Light et al.: "Improvement of thin-channel design for pressure-driven membrane systems", Seiten 33-40 *
Patent Abstracts of Japan, Band 10, Nr. 36 (C-328)(2093) 13 February 1986; & JP-A-60187305 (SASAKURA KIKAI) 24. September 1985 *
Patent Abstracts of Japan, Band 9, Nr. 160 (C-289)(1883), 4. Juli 1985; & JP-A-6034786 (KURITA K.K.K.) 22 February 1985 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113214530A (zh) * 2021-05-27 2021-08-06 齐鲁工业大学 高吸热改性亲水pdms太阳能淡水收集反应器及其应用

Also Published As

Publication number Publication date
DE3824839C1 (https=) 1989-10-05
EP0351879A1 (de) 1990-01-24

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