WO1985001230A1 - Powder mixture free of segregation - Google Patents

Powder mixture free of segregation Download PDF

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Publication number
WO1985001230A1
WO1985001230A1 PCT/SE1984/000290 SE8400290W WO8501230A1 WO 1985001230 A1 WO1985001230 A1 WO 1985001230A1 SE 8400290 W SE8400290 W SE 8400290W WO 8501230 A1 WO8501230 A1 WO 8501230A1
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WO
WIPO (PCT)
Prior art keywords
powder
iron
segregation
mixture
powder mixture
Prior art date
Application number
PCT/SE1984/000290
Other languages
French (fr)
Inventor
Ulf Fredrik Ivar ENGSTRÖM
Original Assignee
Höganäs Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Höganäs Ab filed Critical Höganäs Ab
Priority to DE8484903300T priority Critical patent/DE3473839D1/en
Publication of WO1985001230A1 publication Critical patent/WO1985001230A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C33/00—Making ferrous alloys
    • C22C33/02—Making ferrous alloys by powder metallurgy
    • C22C33/0257—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
    • C22C33/0264—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements the maximum content of each alloying element not exceeding 5%
    • C22C33/0271—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements the maximum content of each alloying element not exceeding 5% with only C, Mn, Si, P, S, As as alloying elements, e.g. carbon steel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/14—Treatment of metallic powder
    • B22F1/148—Agglomerating
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C33/00—Making ferrous alloys
    • C22C33/02—Making ferrous alloys by powder metallurgy
    • C22C33/0207—Using a mixture of prealloyed powders or a master alloy
    • C22C33/0214—Using a mixture of prealloyed powders or a master alloy comprising P or a phosphorus compound

Definitions

  • the present invention relates to iron based powder mi with low risk of segregation and/or dusting. According to t invention it is now possible to produce mechanical mixes of iron or steel powders and alloying powders with low risk of segregation and dusting without deteriorating the character istic physical properties of the mixture.
  • iron or steel powders are often used together wi one or more alloying elements such as copper or nickel in o to reach mechanical properties which cannot be obtained whe using plain iron or steel powders.
  • powders for these purposes are in general pr pared in two ways, viz. either as powder mixtures or as ful prealloyed powders.
  • Powder mixtures are prepared by mixing iron or steel powder with powder containing the desired all ing element or elements, either in the elementary form or as master alloys.
  • the fully prealloyed steel powders are manuf ured e.g. by atomizing a steel melt containing the desired alloying elements to a powder.
  • the preallo powder has another great drawback, viz. its low compressibil which is a result of the solid solution hardening effect wh the alloying elements have on each powder particle.
  • High co pressibility is essential when high density is a prerequisi for reaching high mechanical properties.
  • the compressibility of a powder mixture is on the oth hand substantially the same as the compressibility of the i powder included therein. This fact together with the flexib lity as regards the alloying composition have made powder m tures the most commonly used raw material inthe.production low alloy sintered steels. In such powder mixtures the plai iron powder is used as a base powder.
  • alloying elements such as e.g. phosphorus the form of a ferrophosphorus powder and carbon in the form graphite powder, cannot be sufficiently diffusion alloyed an iron or steel powder without deteriorating the compressi lity, there is a risk that mixtures in which these alloying elements are used are prone to segregation and/or dusting.
  • the Swedish patent application No. 8001764-3 describe method to prevent segregation and/or dusting by adding to a powder mixture up to 1% of a sticky binder, which does not change its sticky properties with time at normal temperatur
  • binding agents of this nature are added to a dry powder mix the amount, which can added, is controlled by the characteristic flowability of t powder mix.
  • the amount which can be used with regard to the flow results in a decreased bonding effect between the iron particles and the particles of the alloying elements, why a optimal powder mix from segregation/dusting point of view cannot be obtained.
  • the aim of the present invention is therefore to provi powder mixtures on iron powder base, in which the risk of se gregation and dusting is very low at the same time as the physical powder characteristics are maintained.
  • this aim is fulfilled by ad ing during the mechanical mixing operation a binding agent b means of which the alloying particles are attached to the ir or steel powder particles.
  • a bin ing agent with good wetting properties in liquid state whic after the admixing is transformed into solid state when expo to the oxygen in the air.
  • the binding agent should have such proper ties that is can be burned off without any problems at a sui able temperature, e.g. during the sintering of the component made of the powder mixture.
  • the binder should be active in the powder mixture u after the compaction it is not allowed to affect the charact ristic physical powder properties of the mixture such as app rent density, flow, compressibility and green strength. To fulfil the above mentioned demands it is preferred add up to 0.5 , preferably 0.10 - 0.30 % , of the binding ag Here and in the following ⁇ .” is referred to as percent by weight.
  • the binding agent that is p ferred is talloil.
  • an iron based powder is mix with one or more alloying elements, such as graphite of phos phorus, in powder form together with a lubricant for some mi tes in order to obtain some homogenization of the mixture.
  • a total content of up to 0.5 , preferably 0.10 - 0.30 , of t binder is then added and the mixing operation is carried out for a period of time sufficient to obtain a homogeneous
  • a lubricant might be added during the ing operation to facilitate the pressing of the powder in a tool at the final use.
  • Example 1 A number of powder mixtures consisting of 98.2 % spon iron powder with a maximum particle size of 175 ⁇ , 1.0 % g phite powder with a mean particle size of about 5.0 ⁇ m, 0.8 of zincstearate and different additions of polyethyleneglyc 400 and talloil up to 0.5 I respectively were prepared. The mixtures were analyzed with regard to both the bonding eff between the iron particles and the alloying particles and t flowability of the powder. The bonding effect was determine by blowing a certain amount of air through the powder mixtu and then determine the loss of graphite. The results obtain are shown in Fig. 1 (bonding effect) and Fig. 2 (flowabilit of the powder) .
  • a binder according to the pre invention makes it possible to use iron-graphite-mixtures, which are free of segregation.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Powder Metallurgy (AREA)

Abstract

Iron based powder mixtures, which except iron or steel powder and one or more alloying elements in powder form also contain an addition of up to 0.5 % of talloil to prevent segregation/dusting.

Description

TITLE OF INVENTION
POWDER MIXTURE FREE OF SEGREGATION
TECHNICAL FIELD
The present invention relates to iron based powder mi with low risk of segregation and/or dusting. According to t invention it is now possible to produce mechanical mixes of iron or steel powders and alloying powders with low risk of segregation and dusting without deteriorating the character istic physical properties of the mixture. In powder metallurgical manufacturing of various type components iron or steel powders are often used together wi one or more alloying elements such as copper or nickel in o to reach mechanical properties which cannot be obtained whe using plain iron or steel powders. Nowadays powders for these purposes are in general pr pared in two ways, viz. either as powder mixtures or as ful prealloyed powders. Powder mixtures are prepared by mixing iron or steel powder with powder containing the desired all ing element or elements, either in the elementary form or as master alloys. The fully prealloyed steel powders are manuf ured e.g. by atomizing a steel melt containing the desired alloying elements to a powder.
One of the drawbacks of powder mixtures is related to fact that such powders consist of particles which often diff considerably in size, shape and density, and which are not mechanically interconnected. This means that such a powder m ture is susceptible to segregation during its transport and handling. This segregation leads to varying composition of t green compacts manufactured from the powder, and thus to var dimensional changes during the sintering operation and to va mechanical properties in the as-sintered pτoduct.
Another drawback of powder mixtures is their tendency dust especially if the alloying element is present in the fo of very small particles. This can lead to difficult environ- mental problems when the powder mixture is handled.
In the case of fully prealloyed powders there is no ri of segregation as every powder particle has the same composi ion, also the risk of dusting is redu
Figure imgf000003_0001
• having small particle size is included. However, the preallo powder has another great drawback, viz. its low compressibil which is a result of the solid solution hardening effect wh the alloying elements have on each powder particle. High co pressibility is essential when high density is a prerequisi for reaching high mechanical properties.
The compressibility of a powder mixture is on the oth hand substantially the same as the compressibility of the i powder included therein. This fact together with the flexib lity as regards the alloying composition have made powder m tures the most commonly used raw material inthe.production low alloy sintered steels. In such powder mixtures the plai iron powder is used as a base powder.
BACKGROUND ART The Swedish patent application No. 76122T7-5 describe method to produce an iron powder containing copper, which h a low risk of segregation and dusting at the same time as t powder properties are maintained. According to this method the powder is produced by an annealing treatment of a mixtu of iron and copper powder, at which a so-called partially diffusion alloy between iron and copper is obtained.
As certain alloying elements, such as e.g. phosphorus the form of a ferrophosphorus powder and carbon in the form graphite powder, cannot be sufficiently diffusion alloyed an iron or steel powder without deteriorating the compressi lity, there is a risk that mixtures in which these alloying elements are used are prone to segregation and/or dusting.
The Swedish patent application No. 8001764-3 describe method to prevent segregation and/or dusting by adding to a powder mixture up to 1% of a sticky binder, which does not change its sticky properties with time at normal temperatur However, it has been found that when binding agents of this nature are added to a dry powder mix the amount, which can added, is controlled by the characteristic flowability of t powder mix. The amount which can be used with regard to the flow results in a decreased bonding effect between the iron particles and the particles of the alloying elements, why a optimal powder mix from segregation/dusting point of view cannot be obtained.
DISCLOSURE OF INVENTION
The aim of the present invention is therefore to provi powder mixtures on iron powder base, in which the risk of se gregation and dusting is very low at the same time as the physical powder characteristics are maintained.
According to the invention this aim is fulfilled by ad ing during the mechanical mixing operation a binding agent b means of which the alloying particles are attached to the ir or steel powder particles.
According to the invention it is proposed to use a bin ing agent with good wetting properties in liquid state, whic after the admixing is transformed into solid state when expo to the oxygen in the air. By using such a binder a dry powde mix with good flow properties can be obtained.
Furthermore, the binding agent should have such proper ties that is can be burned off without any problems at a sui able temperature, e.g. during the sintering of the component made of the powder mixture.
As the binder should be active in the powder mixture u after the compaction it is not allowed to affect the charact ristic physical powder properties of the mixture such as app rent density, flow, compressibility and green strength. To fulfil the above mentioned demands it is preferred add up to 0.5 , preferably 0.10 - 0.30 % , of the binding ag Here and in the following ■■." is referred to as percent by weight.
According to the invention the binding agent that is p ferred is talloil.
According to the invention an iron based powder is mix with one or more alloying elements, such as graphite of phos phorus, in powder form together with a lubricant for some mi tes in order to obtain some homogenization of the mixture. A total content of up to 0.5 , preferably 0.10 - 0.30 , of t binder is then added and the mixing operation is carried out for a period of time sufficient to obtain a homogeneous
OMP IP mixture. If desired, a lubricant might be added during the ing operation to facilitate the pressing of the powder in a tool at the final use.
EXAMPLES In the following the invention is exemplified and in connection therewith the experiments which have been made w powder according to the invention are described together wi the surprising results which the experiments have given. Example 1 A number of powder mixtures consisting of 98.2 % spon iron powder with a maximum particle size of 175 μ , 1.0 % g phite powder with a mean particle size of about 5.0 μm, 0.8 of zincstearate and different additions of polyethyleneglyc 400 and talloil up to 0.5 I respectively were prepared. The mixtures were analyzed with regard to both the bonding eff between the iron particles and the alloying particles and t flowability of the powder. The bonding effect was determine by blowing a certain amount of air through the powder mixtu and then determine the loss of graphite. The results obtain are shown in Fig. 1 (bonding effect) and Fig. 2 (flowabilit of the powder) .
From the results it can be seen that when talloil is as a binder a more or less segregation-free powder mixture iron powder and graphite powder with maintained or improved flow properties can be manufactured. The amount added shoul be in the range of 0.10 - 0.30 % when iron powder with a particle size mainly below 175 μm is used.
When polyethyleneglycol 400 is added to such type of powder the amount, which can be permitted to maintain the characteristic flowability of the powder mixture, is not bi enough to result in a completely satisfying binding effect segregation point of view.
When working with powder mixtures, whose particle siz mainly below 175 μm, it is therefore not satisfying to use this type of binder. However, a binder according to the pre invention makes it possible to use iron-graphite-mixtures, which are free of segregation. Exa ple 2
Two powder mixtures 1 and 2 with a composition as show in the table below were prepared:
Mix 1: 98.8 % iron powder with a particle size mainly below 147 μm,
1.2 % graphite with a particle size below 45 μm.
Mix 2: 98.8 iron powder with a particle size mainly below 147 μm,
1.2 % graphite with a particle size below 45 μm, 0.1 %- talloil
To both mixes 0.8 % zincstearate was admixed as lubricant.
A fullscale"production test was carried out at a manu¬ facturer of sintered components, where 10,000 parts of each 1 and 2 were compacted and sintered under normal conditions. The component in question was included in the normal product run of the manufacturer who normally manufactured it from ma rial according to mixture 1. The compacts of the two mixes w sintered at the same time at 1115 C in a mesh belt furnace i endothermic atmosphere. After sintering a sufficient number of components from statistical point of view was sampled and the carbon content of these parts were measured. For mixture 1 carbon contents between 0.97 % and 1.11 % were obtained, while the same numb for mixture 2 were 1.07 % and 1.10 % , i.e. the carbon conten range for the material corresponding to mix 1 was 0.14 % and
0.03 ' for the material made of mix 2. These results are sho in Fig. 3.
The above results clearly show that the variation in carbon content within a production series is substantilly le when the components have been manufactured from mixture 2 th when the components have been manufactured from mixture 1.
OMPI

Claims

1. Iron based powder mixture, characterized in that it besides iron or steel powder and one or more alloying ele ments in powder form also contains an addition of up to 0.5 preferably 0.10 - 0.30 % , of talloil to prevent segregation and/or dusting.
2. Iron based powder mixture according to claim 1, characterized in that the powder mixture contains up to 2.0 of graphite powder.
3. Iron b.ased powder mixture according to claim 1, characterized in that the mixture contains up to 1.5 % of phosphorus added in the form of a ferrophosphorus powder wit a particle size of maximum 44 μm and a phosphorus content of 14 - 18 ..
4. Iron based powder mixture according to claim 3, characterized in that the mixture contains up to 2.0 % of graphite powder.
ΓURI
OMP
PCT/SE1984/000290 1983-09-09 1984-09-05 Powder mixture free of segregation WO1985001230A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE8484903300T DE3473839D1 (en) 1983-09-09 1984-09-05 Powder mixture free of segregation

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE8304832.2 1983-09-09
SE8304832A SE438275B (en) 1983-09-09 1983-09-09 MIX-FREE IRON-BASED POWDER MIX

Publications (1)

Publication Number Publication Date
WO1985001230A1 true WO1985001230A1 (en) 1985-03-28

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US (1) US4676831A (en)
EP (1) EP0187751B1 (en)
JP (1) JPS60502158A (en)
DE (1) DE3473839D1 (en)
IT (1) IT1176685B (en)
SE (1) SE438275B (en)
WO (1) WO1985001230A1 (en)

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EP0264287A2 (en) * 1986-10-15 1988-04-20 Hoeganaes Corporation Iron-based powder mixtures
US5069714A (en) * 1990-01-17 1991-12-03 Quebec Metal Powders Limited Segregation-free metallurgical powder blends using polyvinyl pyrrolidone binder
WO1995002024A1 (en) * 1993-07-06 1995-01-19 Ford Motor Company Limited Solid lubricant and hardenable steel coating system
US5498276A (en) * 1994-09-14 1996-03-12 Hoeganaes Corporation Iron-based powder compositions containing green strengh enhancing lubricants
US6039784A (en) * 1997-03-12 2000-03-21 Hoeganaes Corporation Iron-based powder compositions containing green strength enhancing lubricants

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JPH0745683B2 (en) * 1987-09-30 1995-05-17 川崎製鉄株式会社 Composite steel powder with excellent compressibility and homogeneity
JPH0694563B2 (en) * 1987-09-30 1994-11-24 川崎製鉄株式会社 Iron-based powder mixture for powder metallurgy and method for producing the same
US5108493A (en) * 1991-05-03 1992-04-28 Hoeganaes Corporation Steel powder admixture having distinct prealloyed powder of iron alloys
US5298055A (en) * 1992-03-09 1994-03-29 Hoeganaes Corporation Iron-based powder mixtures containing binder-lubricant
US5256185A (en) * 1992-07-17 1993-10-26 Hoeganaes Corporation Method for preparing binder-treated metallurgical powders containing an organic lubricant
US5368630A (en) * 1993-04-13 1994-11-29 Hoeganaes Corporation Metal powder compositions containing binding agents for elevated temperature compaction
US5629091A (en) * 1994-12-09 1997-05-13 Ford Motor Company Agglomerated anti-friction granules for plasma deposition
US5782954A (en) * 1995-06-07 1998-07-21 Hoeganaes Corporation Iron-based metallurgical compositions containing flow agents and methods for using same
US5976215A (en) * 1997-08-29 1999-11-02 Kawasaki Steel Corporation Iron-based powder mixture for powder metallurgy and process for preparing the same
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US6280683B1 (en) 1997-10-21 2001-08-28 Hoeganaes Corporation Metallurgical compositions containing binding agent/lubricant and process for preparing same
SE9704494D0 (en) 1997-12-02 1997-12-02 Hoeganaes Ab Lubricant for metallurgical powder compositions
JP3964135B2 (en) * 1998-05-15 2007-08-22 ホガナス アクチボラゲット Iron-based composition for metallurgy containing flow agent and method of using the same
US6068813A (en) * 1999-05-26 2000-05-30 Hoeganaes Corporation Method of making powder metallurgical compositions
US6364927B1 (en) 1999-09-03 2002-04-02 Hoeganaes Corporation Metal-based powder compositions containing silicon carbide as an alloying powder
US6346133B1 (en) 1999-09-03 2002-02-12 Hoeganaes Corporation Metal-based powder compositions containing silicon carbide as an alloying powder
KR100697534B1 (en) * 1999-11-04 2007-03-20 회가나에스 코오포레이션 Improved metallurgical powder compositions and methods of making and using the same
WO2005023463A1 (en) * 2003-09-03 2005-03-17 Apex Advanced Technologies, Llc Composition for powder metallurgy
SE0303453D0 (en) * 2003-12-22 2003-12-22 Hoeganaes Ab Metal powder composition and preparation thereof
US7815707B2 (en) * 2005-03-11 2010-10-19 Höganäs Ab Metal powder composition comprising a drying oil binder
KR101362294B1 (en) * 2005-12-30 2014-02-12 회가내스 아베 Metallurgical powder composition
JP5552031B2 (en) 2010-11-09 2014-07-16 株式会社神戸製鋼所 Mixed powder for powder metallurgy
JP5552032B2 (en) 2010-11-22 2014-07-16 株式会社神戸製鋼所 Mixed powder for powder metallurgy and method for producing the same
JP6262078B2 (en) 2014-05-29 2018-01-17 株式会社神戸製鋼所 Mixed powder for powder metallurgy
EP3165302A1 (en) 2015-11-03 2017-05-10 Wachs-Chemie Elsteraue e.K. Lubricant on the basis of sugar cane waxes
EP4043123A1 (en) 2021-02-12 2022-08-17 Höganäs AB (publ) Metal powder composition comprising a binder

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0264287A2 (en) * 1986-10-15 1988-04-20 Hoeganaes Corporation Iron-based powder mixtures
EP0264287A3 (en) * 1986-10-15 1988-07-13 Hoeganaes Corporation Iron-based powder mixtures
US4834800A (en) * 1986-10-15 1989-05-30 Hoeganaes Corporation Iron-based powder mixtures
US5069714A (en) * 1990-01-17 1991-12-03 Quebec Metal Powders Limited Segregation-free metallurgical powder blends using polyvinyl pyrrolidone binder
WO1995002024A1 (en) * 1993-07-06 1995-01-19 Ford Motor Company Limited Solid lubricant and hardenable steel coating system
US5498276A (en) * 1994-09-14 1996-03-12 Hoeganaes Corporation Iron-based powder compositions containing green strengh enhancing lubricants
US5624631A (en) * 1994-09-14 1997-04-29 Hoeganaes Corporation Iron-based powder compositions containing green strength enhancing lubricants
US6039784A (en) * 1997-03-12 2000-03-21 Hoeganaes Corporation Iron-based powder compositions containing green strength enhancing lubricants

Also Published As

Publication number Publication date
EP0187751A1 (en) 1986-07-23
SE8304832D0 (en) 1983-09-09
IT1176685B (en) 1987-08-18
JPH0432122B2 (en) 1992-05-28
DE3473839D1 (en) 1988-10-13
SE8304832L (en) 1985-03-10
SE438275B (en) 1985-04-15
EP0187751B1 (en) 1988-09-07
JPS60502158A (en) 1985-12-12
IT8422579A0 (en) 1984-09-07
US4676831A (en) 1987-06-30

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