WO1980000957A1 - Generateur d'hydrogene utilisant l'energie solaire pour dissocier l'eau - Google Patents

Generateur d'hydrogene utilisant l'energie solaire pour dissocier l'eau Download PDF

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Publication number
WO1980000957A1
WO1980000957A1 PCT/CH1978/000036 CH7800036W WO8000957A1 WO 1980000957 A1 WO1980000957 A1 WO 1980000957A1 CH 7800036 W CH7800036 W CH 7800036W WO 8000957 A1 WO8000957 A1 WO 8000957A1
Authority
WO
WIPO (PCT)
Prior art keywords
une
réactor
que
par
tubes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CH1978/000036
Other languages
German (de)
English (en)
French (fr)
Inventor
P Genequand
D Gross
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Battelle Memorial Institute Inc
Original Assignee
Battelle Memorial Institute Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Battelle Memorial Institute Inc filed Critical Battelle Memorial Institute Inc
Priority to JP50006778A priority Critical patent/JPS55500862A/ja
Priority to PCT/CH1978/000036 priority patent/WO1980000957A1/de
Publication of WO1980000957A1 publication Critical patent/WO1980000957A1/de
Priority to EP78900229A priority patent/EP0022764A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/04Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of inorganic compounds
    • C01B3/042Decomposition of water
    • C01B3/045Decomposition of water in gaseous phase
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122Incoherent waves
    • B01J19/127Sunlight; Visible light
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24SSOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S20/00Solar heat collectors specially adapted for particular uses or environments
    • F24S20/20Solar heat collectors for receiving concentrated solar energy, e.g. receivers for solar power plants
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/40Solar thermal energy, e.g. solar towers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight

Definitions

  • que le generator d'hydrogene present a nominal output of 50 kW, a global thermal yield ⁇ of 40%, and a degree of dissociation of 20%; The generator that produces the hydrogen with a debit of 0.1 moles of H 2 /sec.
  • the invention is illustrated in a title d'example par a forme d'execution represented schematically on the des sin annexe, dans lequel:
  • La figure 1 axle un réactor tubulaire rotatif represente en coupe longitudinale, freedom I-I en figure 2.
  • La figure 2 accounts a coupe transversale de ce réactorkeep II-II en figure 1.
  • Figure 4 shows the schema of a collector-concentrator comterrorism for the generator of the figure 1.
  • Figure 5 shows the scheme of the generator of hydrogen and the generator of the figure 1 associated with an auxiliary system for the low temperature.
  • Le trongon poreux 7a desky des tubes 7 de ladite expecting documentation presenta une porosite ⁇ comprise between 10 and 30%, de preference de l'ordre de 20%, and le dia publications discipline de ses pores sera compris between 5 and 50 ⁇ m, de preference of the order of 40 ⁇ m.
  • Le manteau isolant 6 is formed in l'occurrence d'une in envelope external étanche 6a renfermant une masse isolante réfractaire 6b, formée de fibers de zircone (ZrO 2 ) par example
  • the tubes 7,8 are supplied with fabricated materials that are refractory, ZrO 2 or ThO 2 and possibly Al 2 O 3 .
  • the troncs de cénes d'espacement 17 in refractory material (ZrO 2 ,ThO 2 or Al 2 O 3 )
  • refractory material ZrO 2 ,ThO 2 or Al 2 O 3
  • La paroi terminale endeavore 10 forme un expendid'espa cement annulaire en matérieu r éfractaire fixe sur la surface ae de la paroi tubulaire 4, muni d'un trou central 12 constituant laditemé axiale et de trous per agencies le position réelle des tubes owns 7 et 8.
  • Il est . entre la paroi mobile infe rieure 11 et 1' extreme Originale de l'enveloppe 6a, dedie à Reguler la position axiale relative de la paroi 4 et des tubes 7,8 par rapport à cette enveloppe 6a, entreatment dudit signal de pression sp a et à mainpar Spanish une entitled pression axiale timedeterminée, de l'ordre de 0,1 kg/ cm 2 par example, corresponding to a weak force de compression longitudinale predetermined agissant sur la paroi tubulaire 4.
  • La figure 1
  • Cesdes compresseurs 38 et 39 send munis respectivement de adhere . . . 91, 92, 93, 94, 96, 94, 96, 96, 97, 96, 96, 96 correspondent à des remediess d'aspiration réglables desdites fractions H 2 -H 2 O et O 2 -H 2 O evacuées respectivement du réa Budapest 1.
  • ThO 2 permet written d' Institut un boncutaneous encutaneous permanent du réactor tubulaire selon l'invention, c'est-é-dire sans interaction chimique de ThO 2 EVERY H 2 O et ses wall de dissociation whatsoever'à 2500oK auncy.
  • ThO 2 n'absorbe quegnament la boast dans le specter visible.
  • l'incorporation d'un additif tel que CeO 2 in tres gave concentration ( ⁇ 1%)
  • concentration ( ⁇ 1%) contributet suffire pour Institut l'absorption du rayonrison all par les reflexions multiples qui s'obtienent gréce à la disposition regarding du réa Budapest tubulaire selon l'invention, àsky les reflexions multiples d'une part entre les tubes réfractaires eux- instrumentss, et d'autre part entre ces tubes et la paroi tubulaire réfractaire qui les renferme.
  • an absorption trop forte du rayonnism have filtered indesirable ddling donne qu'elle favorim des chocs integers, auxquels ThO 2 est relativement sensitive.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Sustainable Energy (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Electromagnetism (AREA)
  • Thermal Sciences (AREA)
  • Sustainable Development (AREA)
  • Toxicology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
PCT/CH1978/000036 1978-11-03 1978-11-03 Generateur d'hydrogene utilisant l'energie solaire pour dissocier l'eau Ceased WO1980000957A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP50006778A JPS55500862A (https=) 1978-11-03 1978-11-03
PCT/CH1978/000036 WO1980000957A1 (fr) 1978-11-03 1978-11-03 Generateur d'hydrogene utilisant l'energie solaire pour dissocier l'eau
EP78900229A EP0022764A1 (fr) 1978-11-03 1980-05-20 Generateur d'hydrogene utilisant l'energie solaire pour dissocier l'eau

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
WOCH78/00036 1978-11-03
PCT/CH1978/000036 WO1980000957A1 (fr) 1978-11-03 1978-11-03 Generateur d'hydrogene utilisant l'energie solaire pour dissocier l'eau

Publications (1)

Publication Number Publication Date
WO1980000957A1 true WO1980000957A1 (fr) 1980-05-15

Family

ID=4536129

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CH1978/000036 Ceased WO1980000957A1 (fr) 1978-11-03 1978-11-03 Generateur d'hydrogene utilisant l'energie solaire pour dissocier l'eau

Country Status (3)

Country Link
EP (1) EP0022764A1 (https=)
JP (1) JPS55500862A (https=)
WO (1) WO1980000957A1 (https=)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999057058A3 (en) * 1998-05-05 2000-04-06 Shec Labs Solar Hydrogen Energ Process for the production of hydrogen by thermal decomposition of water
CN102744027A (zh) * 2012-07-24 2012-10-24 南京工业大学 太阳能高温热化学耦合相变反应器
CN106927428A (zh) * 2017-05-02 2017-07-07 郑州大学 一种用于点式聚光的太阳能制氧部件
CN113124575A (zh) * 2021-04-01 2021-07-16 西安交通大学 一种一体化抛物槽式折流型光热协同反应装置

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE845009A (fr) * 1975-08-27 1977-02-09 Dispositif generateur d'hydrogene
US4019868A (en) * 1976-03-24 1977-04-26 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Solar hydrogen generator
US4053576A (en) * 1975-05-19 1977-10-11 The Regents Of The University Of Minnesota System for obtaining hydrogen and oxygen from water using solar energy
US4071608A (en) * 1975-10-20 1978-01-31 Diggs Richard E Dissociation of water into hydrogen and oxygen using solar energy

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4053576A (en) * 1975-05-19 1977-10-11 The Regents Of The University Of Minnesota System for obtaining hydrogen and oxygen from water using solar energy
BE845009A (fr) * 1975-08-27 1977-02-09 Dispositif generateur d'hydrogene
FR2366217A1 (fr) * 1975-08-27 1978-04-28 Comp Generale Electricite Dispositif generateur d'hydrogene
US4071608A (en) * 1975-10-20 1978-01-31 Diggs Richard E Dissociation of water into hydrogen and oxygen using solar energy
US4019868A (en) * 1976-03-24 1977-04-26 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Solar hydrogen generator

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999057058A3 (en) * 1998-05-05 2000-04-06 Shec Labs Solar Hydrogen Energ Process for the production of hydrogen by thermal decomposition of water
US6521205B1 (en) 1998-05-05 2003-02-18 SHEC Labs—Solar Hydrogen Energy Corporation Process for the production of hydrogen by thermal decomposition of water, and apparatus therefor
CN102744027A (zh) * 2012-07-24 2012-10-24 南京工业大学 太阳能高温热化学耦合相变反应器
CN102744027B (zh) * 2012-07-24 2014-04-09 南京工业大学 太阳能高温热化学耦合相变反应器
CN106927428A (zh) * 2017-05-02 2017-07-07 郑州大学 一种用于点式聚光的太阳能制氧部件
CN106927428B (zh) * 2017-05-02 2023-08-08 郑州大学 一种用于点式聚光的太阳能制氧部件
CN113124575A (zh) * 2021-04-01 2021-07-16 西安交通大学 一种一体化抛物槽式折流型光热协同反应装置

Also Published As

Publication number Publication date
EP0022764A1 (fr) 1981-01-28
JPS55500862A (https=) 1980-10-30

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