UST103403I4 - 15-Deoxy-16-hydroxy-16-vinyl and cyclopropyl substituted prostanoic acids and congeners - Google Patents

15-Deoxy-16-hydroxy-16-vinyl and cyclopropyl substituted prostanoic acids and congeners Download PDF

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Publication number
UST103403I4
UST103403I4 US06/374,061 US37406182A UST103403I4 US T103403 I4 UST103403 I4 US T103403I4 US 37406182 A US37406182 A US 37406182A US T103403 I4 UST103403 I4 US T103403I4
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United States
Prior art keywords
substituted
para
hydroxy
group
deoxy
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Pending
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US06/374,061
Inventor
Martin J. Weiss
Charles V. Grudzinskas
Middleton B. Floyd, Jr.
Sow-mei L. Chen
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Priority to US06/374,061 priority Critical patent/UST103403I4/en
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Publication of UST103403I4 publication Critical patent/UST103403I4/en
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C405/00Compounds containing a five-membered ring having two side-chains in ortho position to each other, and having oxygen atoms directly attached to the ring in ortho position to one of the side-chains, one side-chain containing, not directly attached to the ring, a carbon atom having three bonds to hetero atoms with at the most one bond to halogen, and the other side-chain having oxygen atoms attached in gamma-position to the ring, e.g. prostaglandins ; Analogues or derivatives thereof
    • C07C405/0008Analogues having the carboxyl group in the side-chains replaced by other functional groups
    • C07C405/0016Analogues having the carboxyl group in the side-chains replaced by other functional groups containing only hydroxy, etherified or esterified hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C405/00Compounds containing a five-membered ring having two side-chains in ortho position to each other, and having oxygen atoms directly attached to the ring in ortho position to one of the side-chains, one side-chain containing, not directly attached to the ring, a carbon atom having three bonds to hetero atoms with at the most one bond to halogen, and the other side-chain having oxygen atoms attached in gamma-position to the ring, e.g. prostaglandins ; Analogues or derivatives thereof
    • C07C405/0008Analogues having the carboxyl group in the side-chains replaced by other functional groups
    • C07C405/0025Analogues having the carboxyl group in the side-chains replaced by other functional groups containing keto groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

This disclosure describes esters having prostaglandin-like activity of 15-deoxy-16-hydroxy-16-substituted-prostanoic acids formed by replacing the hydroxy group of the C1 -carboxylic acid substituent with para-acetamidophenoxy, methylsulfonylamido, para-acetylphenoxy, para-phenylphenoxy, C3 -C10 cycloalkoxy, arylalkoxy wherein the alkoxy group has from 7-12 carbon atoms, phenoxy or phenoxy substituted with 1-3 chlorine atoms or C1 -C3 alkyl, phenacyloxy or phenacyloxy ring-substituted with from 1-3 bromine atoms, a nitro moiety, C1-C 8 arylalkyl, or arylalkoxy wherein the alkoxy group has from 7-12 carbon atoms; substituted arylamino (C1 -C12), substituted-naphthoxy, fluorenoxy, carboxyalkoxy (C5 -C11), 5-indanyloxy, benzoylphenoxy, benzyloxy or ring-substituted benzyloxy, glyceryloxy, phosphatoglyceryloxy, amino substituted with an alkanoyl or cycloalkanoyl group; aroyl or substituted aroyl; alkylsulfonyl; arylsulfonyl or substituted-arylsulfonyl, hydrazinyl and substituted hydrazinyl; alkylamino (C1 -C5), or the semicarbazide of the para-formylphenoxy group.
US06/374,061 1980-10-29 1982-05-03 15-Deoxy-16-hydroxy-16-vinyl and cyclopropyl substituted prostanoic acids and congeners Pending UST103403I4 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US06/374,061 UST103403I4 (en) 1980-10-29 1982-05-03 15-Deoxy-16-hydroxy-16-vinyl and cyclopropyl substituted prostanoic acids and congeners

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US20184280A 1980-10-29 1980-10-29
US06/374,061 UST103403I4 (en) 1980-10-29 1982-05-03 15-Deoxy-16-hydroxy-16-vinyl and cyclopropyl substituted prostanoic acids and congeners

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US20184280A Continuation 1980-10-29 1980-10-29

Publications (1)

Publication Number Publication Date
UST103403I4 true UST103403I4 (en) 1983-09-06

Family

ID=26897140

Family Applications (1)

Application Number Title Priority Date Filing Date
US06/374,061 Pending UST103403I4 (en) 1980-10-29 1982-05-03 15-Deoxy-16-hydroxy-16-vinyl and cyclopropyl substituted prostanoic acids and congeners

Country Status (1)

Country Link
US (1) UST103403I4 (en)

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