USRE32932E - Cold hearth refining - Google Patents
Cold hearth refining Download PDFInfo
- Publication number
- USRE32932E USRE32932E US07/217,610 US21761088A USRE32932E US RE32932 E USRE32932 E US RE32932E US 21761088 A US21761088 A US 21761088A US RE32932 E USRE32932 E US RE32932E
- Authority
- US
- United States
- Prior art keywords
- hearth
- segment
- mold
- segments
- area
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000007670 refining Methods 0.000 title claims abstract description 35
- 239000012768 molten material Substances 0.000 claims abstract description 34
- 239000000463 material Substances 0.000 claims abstract description 33
- 238000010894 electron beam technology Methods 0.000 claims abstract description 30
- 239000000155 melt Substances 0.000 claims abstract description 22
- 230000008018 melting Effects 0.000 claims 10
- 238000002844 melting Methods 0.000 claims 10
- 239000002994 raw material Substances 0.000 abstract description 10
- 229910052751 metal Inorganic materials 0.000 description 14
- 239000002184 metal Substances 0.000 description 14
- 229910001069 Ti alloy Inorganic materials 0.000 description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 206010037844 rash Diseases 0.000 description 5
- -1 titanium alloys Chemical class 0.000 description 5
- 238000007514 turning Methods 0.000 description 5
- 239000000356 contaminant Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 238000005266 casting Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000001627 detrimental effect Effects 0.000 description 3
- 210000003625 skull Anatomy 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 239000011364 vaporized material Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/16—Remelting metals
- C22B9/22—Remelting metals with heating by wave energy or particle radiation
- C22B9/228—Remelting metals with heating by wave energy or particle radiation by particle radiation, e.g. electron beams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D27/00—Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B3/00—Hearth-type furnaces, e.g. of reverberatory type; Electric arc furnaces ; Tank furnaces
- F27B3/08—Hearth-type furnaces, e.g. of reverberatory type; Electric arc furnaces ; Tank furnaces heated electrically, with or without any other source of heat
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B3/00—Hearth-type furnaces, e.g. of reverberatory type; Electric arc furnaces ; Tank furnaces
- F27B3/10—Details, accessories or equipment, e.g. dust-collectors, specially adapted for hearth-type furnaces
- F27B3/18—Arrangements of devices for charging
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B3/00—Hearth-type furnaces, e.g. of reverberatory type; Electric arc furnaces ; Tank furnaces
- F27B3/10—Details, accessories or equipment, e.g. dust-collectors, specially adapted for hearth-type furnaces
- F27B3/20—Arrangements of heating devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D99/00—Subject matter not provided for in other groups of this subclass
- F27D99/0001—Heating elements or systems
- F27D99/0006—Electric heating elements or system
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D99/00—Subject matter not provided for in other groups of this subclass
- F27D99/0001—Heating elements or systems
- F27D99/0006—Electric heating elements or system
- F27D2099/003—Bombardment heating, e.g. with ions or electrons
Definitions
- This invention relates to .[.electron beam.]. cold hearth refining of metals such as titanium alloys which must be completely free of unrefined, inclusions and, more particularly, to a new and improved .[.electron beam.]. cold hearth refining furnace which is especially adapted to prevent contamination of refined metal.
- a water cooled hearth is supplied with lumps or pieces of titanium sponge or machine turnings of titanium alloy consisting of scrap from the manufacture of titanium alloy parts.
- This material is introduced by gravity feed at one end of a cooled elongated hearth in .[.an electron beam.]. .Iadd.a .Iaddend.furnace in which the material is melted and refined by electron beam .Iadd.or plasma .Iaddend.impingement.
- the refined molten material is poured from the opposite end of the hearth into a cylindrical mold where it forms a vertically disposed cylindrical ingot that is withdrawn downwardly within the mold as it solidifies.
- the raw material In conventional .[.electron beam.]. cold hearth furnaces used for refining of titanium alloy or the like, the raw material often includes vaporizable contaminants such as chlorine in titanium sponge and oil or moisture in machine turnings. As such materials are introduced into the melt area of the hearth and are heated by the molten metal and by an electron beam, .Iadd.for example, .Iaddend.the vaporizable contaminants frequently produce relatively violent eruptions in the molten metal being refined. Such eruptions have been found to cause both molten and unmelted material from the melt area to be spattered toward other areas of the electron beam furnace including the casting area where the refined ingot is being molded.
- unrefined metal containing undesirable inclusions such as titanium nitrides or tungsten carbides, for example, is introduced into the mold and thereby incorporated into the cast ingot and into any final product produced from the ingot, such as a jet engine compressor disc, for example.
- Another object of the invention is to provide a new and improved .[.electron beam.]. cold hearth refining furnace which provides greater assurance that refined metal will be free of undesirable inclusions.
- an elongated hearth arrangement having hearth segments which extend at an angle to each other, a supply device for introducing raw material to a melt area at one end of one of the hearth segments, a mold for receiving refined material from the opposite end of another segment, and a shield disposed in the angle between the hearth segments at a location such that a straight line extending between the melt area and the mold intersects the shield at a position laterally spaced from both of the hearth segments.
- the two hearth segments are separate hearths disposed at right angles to each other at different levels so that refined molten metal from the first hearth is poured into the adjacent end of the second hearth.
- FIG. 1 is a schematic view in longitudinal section illustrating a representative conventional electron beam cold hearth refining arrangement
- FIG. 2 is a schematic plan view illustrating a typical electron beam cold hearth refining arrangement in accordance with the present invention.
- a hearth 10 comprises a hearth bed 11 containing cooling pipes 12 through which water or another cooling liquid may be circulated.
- a chute 13 directs pieces 14 of the raw material to be refined, such as titanium sponge or titanium alloy machine turnings, into the hearth and a series of electron beam guns 15 disposed above the hearth produces controllable beams of electrons 16 which can be directed to desired areas of the hearth to heat the material to be refined in a desired manner.
- One of the beams 16 is concentrated on the raw material 14 at the melt area 17 of the hearth so as to melt the raw material, and other electron beams 16 are controlled so as to refine the molten metal during its passage from the melt area 17 to a pouring lip 18 at the other end of the hearth.
- other energy sources such as plasma torches, may be used in place of electron beam guns. .Iaddend.
- the raw material introduced into the hearth forms a molten pool 19 which flows from the melt area 17 to the lip 18.
- a solid skull 20 of the molten material 19 in the pool forms on the inner surface of the hearth bed, protecting it from degradation by the molten material.
- molten mater0155 ral 19 As the molten mater0155 ral 19 flows through the hearth, it is completely melted and refined, producing a stream 21 of molten refined material which pours from the pouring lip 18 into a vertical mold 22 containing cooling pipes 23. The molten metal then cools in the mold 22, forming an ingot 24 which is gradually moved downwardly within the mold in a conventional manner as indicated by the arrow.
- Another electron beam gun 25 directs a beam of electrons 26 in a controlled manner toward the surface of the molten material 27 within the mold so as to control the cooling and solidification of that material into the ingot 21 in a desired manner.
- the entire arrangement is, of course, contained within a sealed enclosure (not shown) and maintained at a high vacuum in the conventional manner.
- the raw material 14 As the raw material 14 is introduced into the melt area of the hearth, it frequently carries with it certain contaminants which are volatile at the temperature of the molten material 19 and which are therefore removed during the refining process.
- chlorine may be contained within titanium sponge particles and liquids such as oil and water may be carried by titanium alloy turnings as they are poured from the chute 13 into the melt area 17.
- the introduction of such volatile materials into the molten material 19 causes rapid vaporization of the volatile material at or below the surface of the molten material, producing eruptions which spatter both molten and unmelted material in all directions.
- such eruptions may spatter unrefined material directly from the melt area 17 of the hearth into the mold 22 as indicated by the dotted line paths 28 in FIG. 1.
- the electron beam gun 25 directs a beam of electrons 26 at the surface of the molten material 27 in the mold, that material is generally at a lower temperature than the material in the hearth and the electron beam 26 will normally not be sufficient to refine any unrefined material within the mold.
- the spattered unrefined metal containing inclusions such as titanium nitrides or tungsten carbides, may be incorporated into the ingot 20224 4, contaminating the final product made from that ingot with detrimental results to that product.
- a shield may be placed above the outlet end of the hearth, as indicated by the dotted outline 29 in FIG. 1, to block material spattered from the melt area from passing directly into the mold 22.
- unrefined material spattered from the melt area 17 toward the mold which strikes the shield 29 is frequently deflected downwardly to the surface of the molten material 19 as it is being poured into the mold so that it is carried directly into the mold with the molten material.
- vaporized material and spattered molten material solidifies on the surface of the shield and portions of such solidified material may be dislodged so that they fall directly into the molten material being poured with the same detrimental result.
- a first hearth segment 30 is in the form of an elongated hearth having an inlet end at which raw material, such as titanium sponge or titanium alloy turnings 14, is introduced from a chute 13 into the melt area 17.
- Electron beam guns similar to the guns 15 shown in FIG. 1 but not shown in FIG. 2, are arranged above the hearth segment 30 to melt the raw material in the melt area 17 and to refine the molten material 31 as it passes toward a pouring lip 32 at the outlet end of the hearth segment 30.
- a second elongated hearth segment 33 positioned at a lower level than the hearth segment 30 and at right angles to the segment 30 receives molten material 34 from the pouring lip 32.
- One or more additional electron guns similar to the guns 15 of FIG. 1 but not illustrated in FIG. 2, direct electron beams toward the surface of the molten material in a refining area 35 of this hearth segment to complete the refining of the material as it flows through the hearth segment.
- the hearth segment 33 has a pouring lip 36 through which refined molten metal 37 is poured into a mold 38 to produce a refined ingot in the same manner described above with respect to FIG. 1.
- the mold 38 as illustrated in FIG. 2 has a circular cross section but it may, instead, have any other desired cross-sectional configuration, such as rectangular, for example.
- a solid shield 39 is mounted in the angle between the first and second hearth segments 30 and 33 in such manner that a direct line between the melt area 17 at the inlet to the hearth segment 30 and either the refining area 35 of the second hearth segment or the mold 38 intersects the shield 39.
- the shield 39 is laterally displaced from the hearth segments so that molten material spattered against it or vaporized or spattered material which has solidified on its surface will not fall into the molten material in either the first hearth segment 30 or the second hearth segment 33.
- any number of hearth segments may, of course, be used as long as a shielding arrangement is provided to prevent material spattered from the melt area from reaching the mold.
- metals such as titanium alloy can be refined in .[.an electron beam.]. .Iadd.a .Iaddend.cold hearth furnace without concern over possible inclusions which might be spattered into the mold at the end of the hearth by the introduction of materials containing vaporizable contaminants at the melt area of the hearth.
- two or more hearth segments at different levels are used, as in the embodiment shown in FIG. 2, two separate hearth skulls are formed so that thermal expansion and contraction of the skulls can occur in each hearth segment independently of the conditions in the other hearth segment.
- different refining conditions can be used in the hearth segments and improved stirring of the material being refined is provided by the cascading of molten material from one segment to the other so that improved refining of the material can be obtained.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Plasma & Fusion (AREA)
- Physics & Mathematics (AREA)
- Toxicology (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/217,610 USRE32932E (en) | 1987-03-06 | 1988-07-01 | Cold hearth refining |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2243087A | 1987-03-06 | 1987-03-06 | |
| US07/217,610 USRE32932E (en) | 1987-03-06 | 1988-07-01 | Cold hearth refining |
Related Parent Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US2243087A Continuation | 1987-03-06 | 1987-03-06 | |
| US07/102,276 Reissue US4750542A (en) | 1987-03-06 | 1987-09-28 | Electron beam cold hearth refining |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| USRE32932E true USRE32932E (en) | 1989-05-30 |
Family
ID=26695917
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US07/217,610 Expired - Lifetime USRE32932E (en) | 1987-03-06 | 1988-07-01 | Cold hearth refining |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | USRE32932E (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0571605A4 (en) * | 1991-12-16 | 1994-02-23 | Axel Johnson Metals, Inc. | |
| EP0493591A4 (en) * | 1990-07-19 | 1994-06-08 | Johnson Axel Metals | Vacuum processing of reactive metal |
| US6019812A (en) | 1996-10-22 | 2000-02-01 | Teledyne Industries, Inc. | Subatmospheric plasma cold hearth melting process |
| US6175585B1 (en) | 1999-07-15 | 2001-01-16 | Oregon Metallurgical Corporation | Electron beam shielding apparatus and methods for shielding electron beams |
| US6264884B1 (en) | 1999-09-03 | 2001-07-24 | Ati Properties, Inc. | Purification hearth |
| US20070006989A1 (en) * | 2002-09-20 | 2007-01-11 | Ajax Tocco Magnethermic Corporation | Method and apparatus for melting titanium using a combination of plasma torches and direct arc electrodes |
| US20110308760A1 (en) * | 2009-02-09 | 2011-12-22 | Hisamune Tanaka | Apparatus for production of metallic slab using electron beam, and process for production of metallic slab using the apparatus |
| US9050650B2 (en) | 2013-02-05 | 2015-06-09 | Ati Properties, Inc. | Tapered hearth |
| US11150021B2 (en) * | 2011-04-07 | 2021-10-19 | Ati Properties Llc | Systems and methods for casting metallic materials |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3342250A (en) * | 1963-11-08 | 1967-09-19 | Suedwestfalen Ag Stahlwerke | Method of and apparatus for vacuum melting and teeming steel and steellike alloys |
| US4027722A (en) * | 1963-02-01 | 1977-06-07 | Airco, Inc. | Electron beam furnace |
-
1988
- 1988-07-01 US US07/217,610 patent/USRE32932E/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4027722A (en) * | 1963-02-01 | 1977-06-07 | Airco, Inc. | Electron beam furnace |
| US3342250A (en) * | 1963-11-08 | 1967-09-19 | Suedwestfalen Ag Stahlwerke | Method of and apparatus for vacuum melting and teeming steel and steellike alloys |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0493591A4 (en) * | 1990-07-19 | 1994-06-08 | Johnson Axel Metals | Vacuum processing of reactive metal |
| EP0571605A4 (en) * | 1991-12-16 | 1994-02-23 | Axel Johnson Metals, Inc. | |
| US6019812A (en) | 1996-10-22 | 2000-02-01 | Teledyne Industries, Inc. | Subatmospheric plasma cold hearth melting process |
| US6175585B1 (en) | 1999-07-15 | 2001-01-16 | Oregon Metallurgical Corporation | Electron beam shielding apparatus and methods for shielding electron beams |
| US6264884B1 (en) | 1999-09-03 | 2001-07-24 | Ati Properties, Inc. | Purification hearth |
| US7503376B2 (en) * | 2002-09-20 | 2009-03-17 | Ajax Tocco Magnethermic Corporation | Method and apparatus for melting titanium using a combination of plasma torches and direct arc electrodes |
| US20070006989A1 (en) * | 2002-09-20 | 2007-01-11 | Ajax Tocco Magnethermic Corporation | Method and apparatus for melting titanium using a combination of plasma torches and direct arc electrodes |
| US20110308760A1 (en) * | 2009-02-09 | 2011-12-22 | Hisamune Tanaka | Apparatus for production of metallic slab using electron beam, and process for production of metallic slab using the apparatus |
| EP2394758A4 (en) * | 2009-02-09 | 2014-06-04 | Toho Titanium Co Ltd | METAL ARRAY FABRIC DEVICE USING ELECTRON BEAM AND METHOD FOR MANUFACTURING METAL ARRAY USING THE DEVICE |
| US11150021B2 (en) * | 2011-04-07 | 2021-10-19 | Ati Properties Llc | Systems and methods for casting metallic materials |
| US9050650B2 (en) | 2013-02-05 | 2015-06-09 | Ati Properties, Inc. | Tapered hearth |
| US9205489B2 (en) | 2013-02-05 | 2015-12-08 | Ati Properties, Inc. | Hearth and casting system |
| US9221097B2 (en) | 2013-02-05 | 2015-12-29 | Ati Properties, Inc. | Method for casting material |
| US9381571B2 (en) * | 2013-02-05 | 2016-07-05 | Ati Properties, Inc. | Hearth |
| US9539640B2 (en) | 2013-02-05 | 2017-01-10 | Ati Properties Llc | Hearth and casting system |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4932635A (en) | Cold hearth refining apparatus | |
| US4750542A (en) | Electron beam cold hearth refining | |
| US4961776A (en) | Cold hearth refining | |
| US4936375A (en) | Continuous casting of ingots | |
| US4838340A (en) | Continuous casting of fine grain ingots | |
| US5291940A (en) | Static vacuum casting of ingots | |
| USRE32932E (en) | Cold hearth refining | |
| US5171357A (en) | Vacuum processing of particulate reactive metal | |
| EP3126079B1 (en) | Granulation of molten ferrochromium | |
| US5084090A (en) | Vacuum processing of reactive metal | |
| GB2117417A (en) | Producing high-purity ceramics- free metallic powders | |
| EA022298B1 (en) | Device and method for cooling melt fragments | |
| GB2202476A (en) | Electron beam refining furnace | |
| EP0300411B1 (en) | Melting retort and method of melting materials | |
| WO2005084850A1 (en) | Method and apparatus for perimeter cleaning in cold hearth refining | |
| RU2191211C2 (en) | Method for metal melting and casting in rotating inclined vessel | |
| JP2001272172A (en) | Multiple hearth devices including barriers | |
| JP2021079395A (en) | Method of making titanium ingot | |
| JPH0688146A (en) | Electron beam overflow melting device | |
| JPS63251786A (en) | Metal melting and casting equipment |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FPAY | Fee payment |
Year of fee payment: 4 |
|
| AS | Assignment |
Owner name: TITANIUM HEALTH TECHNOLOGIES, INC. IS A PENNSYLVAN Free format text: ASSIGNMENT UNDIVIDED JOINT INTEREST AS JOINT TENANTS;ASSIGNOR:AXEL JOHNSON METALS, INC., A DE CORP.;REEL/FRAME:006426/0203 Effective date: 19920831 |
|
| FEPP | Fee payment procedure |
Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
| FPAY | Fee payment |
Year of fee payment: 8 |
|
| AS | Assignment |
Owner name: BANKERS TRUST COMPANY, AS AGENT, NEW YORK Free format text: CONDITIONAL ASSIGNMENT AND ASSIGNMENT OF SECURITY INTEREST IN U.S. PATENTS;ASSIGNOR:TITANIUM HEARTH TECHNOLOGIES, INC.;REEL/FRAME:008660/0849 Effective date: 19970730 Owner name: TITANIUM HEARTH TECHNOLOGIES, INC., PENNSYLVANIA Free format text: PATENT ASSIGNMENT;ASSIGNOR:AXEL JOHNSON METALS, INC.;REEL/FRAME:008660/0815 Effective date: 19961001 Owner name: BANKERS TRUST COMPANY, AS AGENT, NEW YORK Free format text: CONDITIONAL ASSIGNMENT AND SECURITY INTEREST;ASSIGNOR:TITANIUM HEARTH TECHNOLOGIES;REEL/FRAME:008660/0825 Effective date: 19970730 |
|
| FPAY | Fee payment |
Year of fee payment: 12 |
|
| AS | Assignment |
Owner name: CONGRESS FINANCIAL CORPORATION (SOUTHWEST), TEXAS Free format text: SECURITY INTEREST;ASSIGNOR:TITANIUM HEARTH TECHNOLOGIES, INC.;REEL/FRAME:010655/0742 Effective date: 20000225 |
|
| AS | Assignment |
Owner name: TITANIUM HEARTH TECHNOLOGIES, INC., PENNSYLVANIA Free format text: RELEASE AND TERMINATION OF CONDITIONAL ASSIGNMENT AND ASSIGNMENT OF SECURITY INTEREST IN U.S. PATENTS.;ASSIGNOR:BANKERS TRUST CORPORATION, AS COLLATERAL AGENT;REEL/FRAME:010719/0610 Effective date: 20000223 |
|
| AS | Assignment |
Owner name: TITANIUM HEARTH TECHNOLOGIES, INC., PENNSYLVANIA Free format text: RELEASE AND TERMINATION OF CONDITIONAL ASSIGNMENT OF SECURITY INTEREST IN U.S. PATENTS;ASSIGNOR:BANKERS TRUST CORPORATION, AS COLLATERAL AGENT;REEL/FRAME:010719/0591 Effective date: 20000223 |