USRE30102E - Cross-linkable compounds based on saturated polyesters - Google Patents
Cross-linkable compounds based on saturated polyesters Download PDFInfo
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- USRE30102E USRE30102E US05/885,107 US88510778A USRE30102E US RE30102 E USRE30102 E US RE30102E US 88510778 A US88510778 A US 88510778A US RE30102 E USRE30102 E US RE30102E
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/31794—Of cross-linked polyester
Definitions
- the invention concerns compounds based on saturated polyesters and cross-linking agents, for use as binders for powder paints.
- the compounds according to the invention make it possible to obtain coatings with excellent resistance to solvents, weathering and ultra-violet rays, good resistance to bending and shock and very satisfactory surface appearance, adhesion and deep drawing properties.
- the compounds comprise a saturated polyester with terminal hydroxyl groups and a cross-linking agent. They are characterized in that the polyester has a softening temperature of from 70° to 130° C., a hydroxyl number from 150 to 250 and an acid number below 10, and that the cross-linking agent comprises a dianhydride with ester groups (functions), is the product of a reaction between trimellitic anhydride and a diol, and has a softening temperature of 60° to 130° C.
- the polyester used is prepared in known manner, by reacting an aromatic dicarboxylic acid or a lower alkyl ester of aromatic dicarboxylic acid with a diol, in theoretical proportions according to the required hydroxyl number.
- aromatic dicarboxylic acids are represented more particularly by terephthalic and isophathalic acid, used alone or in admixture or with saturated aliphatic dicarboxylic acids, such as adipic, succinic or sebacic acid.
- Futhermore in order to increase the number of branches in the polyester, it is possible to associate the dicarboxylic acids with acids having more than two aromatic or aliphatic carboxylic groups. Examples of these are trimellitic acid and anhydride, pyromellitic, acid and anhydride and butanetetracarboxylic acid.
- the diols which can be used to obtain the polyester include: ethylene-glycol, diethylene-glycol, propylene-glycol, dipropylene-glycol, butanediols, bishydroxyethyl-bisphenol A, neopentyl-glycol and hydrogenated bisphenol A. These diols are either used alone or mixed with one another or with other diols.
- triols such as glycerol, trimethylolpropane and trihydroxyethylisocyanurate.
- the polyester used may alternatively be a polyester obtained by reacting ethylene-glycol polyterephthalate of high molecular weight in the form of granules, films, fibers, etc. with a triol such as glycerol, trimethylolpropane or trihydroxyethyl isocyanurate.
- a triol such as glycerol, trimethylolpropane or trihydroxyethyl isocyanurate.
- the polyester forming the compounds is a colorless substance with a softening temperature of from 70° to 130° C., a hydroxyl number from 150 to 250 and an acid number as low as possible and always less than 10.
- the cross-linking agent which is the other constituent of the compounds, is the product of a reaction between trimellitic anhydride and an aliphatic diol containing 2 to 10 carbon atoms, such as ethylene-glycol, diethylene-glycol, propylene-glycol, dipropylene-glycol or neopentyl-glycol, in quantities such that the anhydride/diol molar ratios is 2/1 to 1.5.
- the reaction is carried out at a temperature from 180° to 250° C. and preferably from 220°-240° C., until no more water is liberated.
- the product obtained comprises a majority of dianhydride-ester mixed with substances having an acid group. Its softening temperature is approximately 60° to 130° C., preferably 100° to 120° C. and its acid number is very close to the theoretical one, allowing for the nature and quantity of diol used.
- the compounds comprising the polyester and cross-linking agent can be cross-linked by polyaddition and poly-condensation at temperatures of from 140° to 200° C. for periods ranging from 5 to 30 minutes.
- the polyester and cross-linking agent are mixed in proportions corresponding to the respective hydroxyl and acid numbers of the two constituents, by any method conventionally used in the manufacture of powder paints, e.g. by spraying or by successive rapid cold-mixing, extruding, crushing, grinding and sifting operations.
- Spreading agents which change the surface tension of the paint, are added during the mixing process in quantities ranging from 0.1% to 1% by weight of the compound. These agents, which are commonly used, are represented particularly by acrylic polymers and silicon fluids.
- additives traditionally employed in the paint industry may also be added, such as pigments, colors and fillers.
- the mixtures obtained are then applied as a coating by any known methods, e.g. by means of a fluidized bath or electro-static spraying onto rigid surfaces of any materials which will tolerate temperatures of about 200° C., such as metal or glass.
- the coated materials are then subjected to temperatures of 140° to 200° C. for 5 to 30 minutes to bring about cross-linking of the compound.
- the coatings have the following properties:
- the compounds according to the invention are paint binders which are particularly appropriate for the automobile, electrical household goods, agricultural machinery and lead industries.
- the polyester used is prepared by reacting 2,490 g (15 moles) of terephthalic acid, 725 g (11.16 moles) of ethylene glycol, 288 g (1.2 mole) of hydrogenated bisphenol A and 552 g (6 moles) of glycerol at 240° C. in a nitrogen atmosphere.
- the polyester thus obtained is perfectly clear and colorless and has a softening temperature of 80° C., an acid number of 7 and a hydroxyl number of 190.
- the cross-linking agent is prepared by bringing 576 g (3 moles) of trimellitic anhydride to 230° C. in a nitrogen atmosphere; 93 g (1.5 mole) of ethylene glycol is gradually added to it over 15 minutes. After two hours, no more water is being given off.
- the product obtained has a softening temperature of 110° C. and an acid number of 518 in an aqueous medium and 336 in an alcohol medium, corresponding to a dianhydride yield of 65%.
- 1,000 g of the ground polyester, 290 g of the cross-linking agent, 770 g of rutile titanium dioxide, commercially available under the name of "CL 220”, and 7 g of spreading agent, based on acrylic polymer and known by the trade name of "Modaflow”, are mixed in a quick-action mixer, then extruded.
- the extrusion product is cooled, then ground and finally sifted.
- the powder consists of particles with a maximum diameter of 100 ⁇ m. It is applied to the surface of a metal plate by electrostatic spraying, in a uniform film of about 50 ⁇ m. The plate is next heated for 30 minutes to 180° C., then cooled.
- a metal plate is prepared, as described above, with a mixture of 75 g of polyester prepared from 1 mole of terephthalic acid, 1 mole of neopentylglycol and 0.08 mole of trimethylolpropane; 25 g of a cross-linking agent obtained by reacting 2 moles of isophorone diisocyanate, 1 mole of diethylene glycol and 2 moles of caprolactan; 0.55 g of "Modaflow" and 60 g of "CL 220°.”
- a metal plate is coated in the same way with a mixture of 100 g of a condensate of epichlorohydrin and bisphenol A (epoxy equivalent 900), 4 g of dicyandiamide, 0.57 g by weight of "Modaflow” and 62 g of "CL 220.”
- Cross-linking takes place at 180° C. for 20 minutes.
- Example 1 is repeated, except that the polyester is prepared from 2,910 g (15 moles) of methyl terephthalate instead of terephthalic acid, at 220° C. and in the presence of 22 g of butyl titanate. After reaction for 5 hours, 960 g of methanol is collected and the polyester obtained has a softening temperature of 80° C., an acid number of 0 and a hydroxyl number of 190.
- the coating has the same characteristics as that in Example 1.
- Example 1 is repeated with a polyester prepared by reacting 1,992 g (12 moles) of terephthalic acid, 1,488 g (24 moles) of ethylene glycol and 768 g (4 moles) of trimellitic anhydride at 220° C. in a nitrogen atmosphere for 12 hours.
- the resin obtained has a softening temperature of 80° C., an acid number of 3 and a hydroxyl number of 150.
- the coating has the following properties:
- the polyester is prepared by reacting 2,450 g (15 moles) of terephthalic acid with 725 g (11.7 moles) of ethylene glycol, 379 (1.2 mole) of bishydroxyethyl bisphenol A and 552 g (6 moles) of glycerol at 200°-240° C.
- the polyester obtained which is perfectly clear, has a softening temperature of 75° C., an acid number of 7 and a hydroxyl number of 190.
- the cross-linking agent is prepared by a reaction at 230° C. between 576 g (3 moles) of trimellitic anhydride and 111.6 g (1.8 mole) of ethylene glycol, which is introduced over a period of 15 minutes. When no more water is given off, the reaction product is cooled. It has a softening temperature of approximately 110° C. and an acid number of 455 in an aqueous medium and 280 in an alcohol medium, i.e., a dianhydride yield of 82%.
- Example 1 1,000 g of ground polyester, 430 g of ground dianhydride, 850 g of rutile titanium dioxide and 11 g of "Modeflow" are intimately mixed, then worked and applied as in Example 1.
- the properties of the coating are as follows:
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- Polymers & Plastics (AREA)
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- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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Abstract
The invention relates to compounds based on saturated polyester and cross-linking agent. The compositions comprise a saturated polyester with terminal hydroxyl groups and a cross-linking agent consisting of a dianhydride with ester groups, the product of reaction between a trimellitic anhydride and a diol. Use of the compounds as a binder for powder paints applicable to the automobile, electrical household goods, agricultural machinery and lead industries.
Description
The invention concerns compounds based on saturated polyesters and cross-linking agents, for use as binders for powder paints.
The use of powder paints is tending to spread, so it has been proposed that various resins, usually associated with cross-linking agents, should be used as binders. However, coatings obtained with such paints have some disadvantages. Coatings based on cross-linked epoxy resins show poor resistance to weathering, ultra-violet light and solvents. Coatings where the binders are saturated polyesters with terminal hydroxyl groups, cross-linked by hexamethylolmelamine ethers, show little resistance to solvents and weathering and have poor mechanical properties. The same polyesters cross-linked by isocyanates give coatings with very poor resistance to solvents and furthermore, if the isocyanate is aromatic, the coating will turn yellow in the presence of ultra-violet rays. If the binders are saturated polyesters with acid end groups, cross-linked by epoxy resins, the coatings will have a poor surface.
By cross-linking at temperatures not over 200° C., the compounds according to the invention make it possible to obtain coatings with excellent resistance to solvents, weathering and ultra-violet rays, good resistance to bending and shock and very satisfactory surface appearance, adhesion and deep drawing properties.
The compounds comprise a saturated polyester with terminal hydroxyl groups and a cross-linking agent. They are characterized in that the polyester has a softening temperature of from 70° to 130° C., a hydroxyl number from 150 to 250 and an acid number below 10, and that the cross-linking agent comprises a dianhydride with ester groups (functions), is the product of a reaction between trimellitic anhydride and a diol, and has a softening temperature of 60° to 130° C.
The polyester used is prepared in known manner, by reacting an aromatic dicarboxylic acid or a lower alkyl ester of aromatic dicarboxylic acid with a diol, in theoretical proportions according to the required hydroxyl number.
The aromatic dicarboxylic acids are represented more particularly by terephthalic and isophathalic acid, used alone or in admixture or with saturated aliphatic dicarboxylic acids, such as adipic, succinic or sebacic acid.
Futhermore, in order to increase the number of branches in the polyester, it is possible to associate the dicarboxylic acids with acids having more than two aromatic or aliphatic carboxylic groups. Examples of these are trimellitic acid and anhydride, pyromellitic, acid and anhydride and butanetetracarboxylic acid.
The diols which can be used to obtain the polyester include: ethylene-glycol, diethylene-glycol, propylene-glycol, dipropylene-glycol, butanediols, bishydroxyethyl-bisphenol A, neopentyl-glycol and hydrogenated bisphenol A. These diols are either used alone or mixed with one another or with other diols.
In order to increase the number of branches and the number of hydroxyl end groups in the polyester, it is advisable to associate the diols with triols, such as glycerol, trimethylolpropane and trihydroxyethylisocyanurate.
It is obvious that, if the polyester is to be prevented from cross-linking during its preparation, substances with more than two acid groups or more than two alcohol groups can be used only within the limits prescribed by Flory's law (Turner Alfrey, Mechanical Behavior of High Polymers, Interscience publishers-- Volume VI, page 268).
The polyester used may alternatively be a polyester obtained by reacting ethylene-glycol polyterephthalate of high molecular weight in the form of granules, films, fibers, etc. with a triol such as glycerol, trimethylolpropane or trihydroxyethyl isocyanurate.
The polyester forming the compounds is a colorless substance with a softening temperature of from 70° to 130° C., a hydroxyl number from 150 to 250 and an acid number as low as possible and always less than 10.
The cross-linking agent, which is the other constituent of the compounds, is the product of a reaction between trimellitic anhydride and an aliphatic diol containing 2 to 10 carbon atoms, such as ethylene-glycol, diethylene-glycol, propylene-glycol, dipropylene-glycol or neopentyl-glycol, in quantities such that the anhydride/diol molar ratios is 2/1 to 1.5. The reaction is carried out at a temperature from 180° to 250° C. and preferably from 220°-240° C., until no more water is liberated. The product obtained comprises a majority of dianhydride-ester mixed with substances having an acid group. Its softening temperature is approximately 60° to 130° C., preferably 100° to 120° C. and its acid number is very close to the theoretical one, allowing for the nature and quantity of diol used.
The compounds comprising the polyester and cross-linking agent can be cross-linked by polyaddition and poly-condensation at temperatures of from 140° to 200° C. for periods ranging from 5 to 30 minutes.
When the compounds are used as binders for powder paints, the polyester and cross-linking agent are mixed in proportions corresponding to the respective hydroxyl and acid numbers of the two constituents, by any method conventionally used in the manufacture of powder paints, e.g. by spraying or by successive rapid cold-mixing, extruding, crushing, grinding and sifting operations.
Spreading agents, which change the surface tension of the paint, are added during the mixing process in quantities ranging from 0.1% to 1% by weight of the compound. These agents, which are commonly used, are represented particularly by acrylic polymers and silicon fluids.
Any of the additives traditionally employed in the paint industry may also be added, such as pigments, colors and fillers.
The mixtures obtained are then applied as a coating by any known methods, e.g. by means of a fluidized bath or electro-static spraying onto rigid surfaces of any materials which will tolerate temperatures of about 200° C., such as metal or glass. The coated materials are then subjected to temperatures of 140° to 200° C. for 5 to 30 minutes to bring about cross-linking of the compound.
The coatings have the following properties:
-Thickness: 40 to 100 μm
-Surface appearance: good surface tension; glossy, matt or satin surface
-Resistance to methylethylketone: (one drop of methylethylketone is deposited on the coating, then the area is scratched with a finger-nail for long enough to remove the coating)-- a period of over 3 minutes
-Accelerated aging: (exposure in a xenotest and recording when yellowing begins)-- over 800 hours
-Adhesion: (French Standard T 30038)-- at least 4
-Deep drawing (French Standard T 30019)-- at least 7.
-Shock resistance: (French Standard T 30039 for a mass of 1 kg dropping 50 cm)-- no crazing or unsticking on impact=good
-Bending (French Standard T 30040 -- bending a plate with a transversely scored coating through 180° mm on a mandrel 8 mm in diameter)-- no deterioration at the bend=good.
The compounds according to the invention are paint binders which are particularly appropriate for the automobile, electrical household goods, agricultural machinery and lead industries.
Some examples of the invention follow; they are given purely by way of illustration and not by way of limitation of the invention.
The polyester used is prepared by reacting 2,490 g (15 moles) of terephthalic acid, 725 g (11.16 moles) of ethylene glycol, 288 g (1.2 mole) of hydrogenated bisphenol A and 552 g (6 moles) of glycerol at 240° C. in a nitrogen atmosphere. The polyester thus obtained is perfectly clear and colorless and has a softening temperature of 80° C., an acid number of 7 and a hydroxyl number of 190.
The cross-linking agent is prepared by bringing 576 g (3 moles) of trimellitic anhydride to 230° C. in a nitrogen atmosphere; 93 g (1.5 mole) of ethylene glycol is gradually added to it over 15 minutes. After two hours, no more water is being given off. The product obtained has a softening temperature of 110° C. and an acid number of 518 in an aqueous medium and 336 in an alcohol medium, corresponding to a dianhydride yield of 65%.
1,000 g of the ground polyester, 290 g of the cross-linking agent, 770 g of rutile titanium dioxide, commercially available under the name of "CL 220", and 7 g of spreading agent, based on acrylic polymer and known by the trade name of "Modaflow", are mixed in a quick-action mixer, then extruded. The extrusion product is cooled, then ground and finally sifted. The powder consists of particles with a maximum diameter of 100 μm. It is applied to the surface of a metal plate by electrostatic spraying, in a uniform film of about 50 μm. The plate is next heated for 30 minutes to 180° C., then cooled.
In a first comparative test a metal plate is prepared, as described above, with a mixture of 75 g of polyester prepared from 1 mole of terephthalic acid, 1 mole of neopentylglycol and 0.08 mole of trimethylolpropane; 25 g of a cross-linking agent obtained by reacting 2 moles of isophorone diisocyanate, 1 mole of diethylene glycol and 2 moles of caprolactan; 0.55 g of "Modaflow" and 60 g of "CL 220°."
In a second comparative test, a metal plate is coated in the same way with a mixture of 100 g of a condensate of epichlorohydrin and bisphenol A (epoxy equivalent 900), 4 g of dicyandiamide, 0.57 g by weight of "Modaflow" and 62 g of "CL 220." Cross-linking takes place at 180° C. for 20 minutes.
The characteristics of the 3 tests are set out in the following table:
______________________________________
Comparative
Comparative
Characteristics
Example 1 test 1 test 2
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Surface appearance
glossy- glossy- glossy-
taut taut slight
surface surface orange peel
effect
Resistance to
methylethylketone
>3 min 10 sec 1 min
Accelerated aging
>800 hrs >800 hrs 250 hrs
Adhesion 4 4 3
Deep drawing
7 mm 8 mm 10 mm
Resistance to shock
good good good
Bending good good good
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Example 1 is repeated, except that the polyester is prepared from 2,910 g (15 moles) of methyl terephthalate instead of terephthalic acid, at 220° C. and in the presence of 22 g of butyl titanate. After reaction for 5 hours, 960 g of methanol is collected and the polyester obtained has a softening temperature of 80° C., an acid number of 0 and a hydroxyl number of 190.
The coating has the same characteristics as that in Example 1.
Example 1 is repeated with a polyester prepared by reacting 1,992 g (12 moles) of terephthalic acid, 1,488 g (24 moles) of ethylene glycol and 768 g (4 moles) of trimellitic anhydride at 220° C. in a nitrogen atmosphere for 12 hours. The resin obtained has a softening temperature of 80° C., an acid number of 3 and a hydroxyl number of 150.
The coating has the following properties:
______________________________________
Surface appearance: glossy-taut surface
Resistance to methylethylketone:
>3 min
Accelerated aging >800 hrs
Adhesion 4
Deep drawing 7 mm
Resistance to shock good
Bending good
______________________________________
The polyester is prepared by reacting 2,450 g (15 moles) of terephthalic acid with 725 g (11.7 moles) of ethylene glycol, 379 (1.2 mole) of bishydroxyethyl bisphenol A and 552 g (6 moles) of glycerol at 200°-240° C. The polyester obtained, which is perfectly clear, has a softening temperature of 75° C., an acid number of 7 and a hydroxyl number of 190.
The cross-linking agent is prepared by a reaction at 230° C. between 576 g (3 moles) of trimellitic anhydride and 111.6 g (1.8 mole) of ethylene glycol, which is introduced over a period of 15 minutes. When no more water is given off, the reaction product is cooled. It has a softening temperature of approximately 110° C. and an acid number of 455 in an aqueous medium and 280 in an alcohol medium, i.e., a dianhydride yield of 82%.
1,000 g of ground polyester, 430 g of ground dianhydride, 850 g of rutile titanium dioxide and 11 g of "Modeflow" are intimately mixed, then worked and applied as in Example 1.
The properties of the coating are as follows:
-Surface appearance: glossy-taut surface
-Resistance to methylethylketone: <3 mins
-Accelerated aging: 800 hrs
-Adhesion: 4
-Deep drawing: 7
-Resistance to shock: good
-Bending: good
Claims (14)
1. A binder comprising a saturated polyester with terminal hydroxyl groups and a cross-linking agent, characterized in that the polyester has a softening temperature within the range of 70° to 130° C., a hydroxyl number within the range of 150 to 250 and an acid number below 10, and that the cross-linking agent comprises a dianhydride with ester groups, which is the product of a reaction between trimellitic anhydride and a diol and which has a softening temperature within the range of 60° to 130° C.
2. A binder according to claim 1, characterized in that the polyester is the product of a reaction between at least one dicarboxylic acid selected from the group consisting of aromatic dicarboxylic acid and lower alkyl ester of aromatic dicarboxylic acid with one or more diols.
3. A binder according to claim 2, characterized in that at least one acid selected from the group consisting of saturated aliphatic acid and aromatic or aliphatic acid with more than two carboxylic groups are associated with the aromatic dicarboxylic acid.
4. A binder according to claim 2, characterized in that one or more triols are associated with the diol.
5. A binder according to claim 1, characterized in that the polyester is the product of a reaction between ethylene glycol polyterephthalate of high molecular weight and a triol.
6. A binder according to claim 1, characterized in that the cross-linking agent is obtained by reacting trimellitic anhydride with a diol at a temperature within the range of 180° to 250° C. and in the molar ratio trimellitic anhydride/diol of 2/1 to 1.5.
7. A binder according to claim 6, characterized in that the diol is an aliphatic diol having 2 to 10 carbon atoms.
8. A binder according to claim 1, characterized in that their cross-linking temperature is from 140° to 200° C. for from 5 to 30 minutes.
9. A method of obtaining the binder of claim 1, comprising mixing a polyester having terminal hydroxyl groups with the cross-linking agent formed by reacting trimellitic anhydride with a diol at a temperature within the range of 180° to 250° C. and in the molar ratio of 2 moles of trimellitic anhydride to 1 to 1.5 moles of the diol. .Iadd.
10. A cross-linking agent comprising a dianhydride with ester functions, said cross-linking agent being the product of the reaction between trimellitic anhydride and a diol, at elevated temperatures, and wherein such reaction the molar ratio of the trimellitic anhydride to the diol is not in excess of 2. .Iaddend. .Iadd.11. The cross-linking agent as defined by claim 10, wherein the diol is an aliphatic diol containing from 2 to 10 carbon atoms. .Iaddend. .Iadd.12. The cross-linking agent as defined by claim 11, wherein the diol is selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol and neopentyl glycol. .Iaddend. .Iadd.13. The cross-linking agent as defined by claim 11, said composition having a softening temperature of approximately 60° to 130° C. .Iaddend. .Iadd.14. The cross-linking agent as defined by claim 13, said cross-linking agent having a softening temperature of approximately 100° to 120° C. .Iaddend. .Iadd.15. The cross-linking agent as defined by claim 11, said cross-linking agent having an approximately theoretical
acid number. .Iaddend. .Iadd.16. The cross-linking agent as defined by claim 10, wherein the molar ratio of trimellitic anhydride to diol ranges from 2/1 to 2/1.5. .Iaddend. .Iadd.17. The cross-linking agent as defined by claim 13, wherein the diol is ethylene glycol. .Iaddend. .Iadd.18. The cross-linking agent as defined in claim 17, wherein the molar ratio of trimellitic anhydride to ethylene glycol is 2/1. .Iaddend. .Iadd.19. The cross-linking agent as defined by claim 17, wherein the molar ratio of trimellitic anhydride to ethylene glycol is 3/1.8. .Iaddend. .Iadd.20. A process for preparing a cross-linking agent comprising a dianhydride with ester functions, which process comprises reacting trimellitic anhydride with a diol at elevated temperatures, and wherein the molar ratio of the trimellitic anhydride to the diol is not in excess of 2. .Iaddend. .Iadd.21. The process as defined by claim 20, wherein the reaction is conducted at temperatures ranging from 180° to 250° until no further water is liberated. .Iaddend. .Iadd.22. The process as defined by claim 21, wherein the temperatures range from 220° to
240° C. .Iaddend. .Iadd.23. A coating composition comprising that cross-linking agent as defined by claim 10. .Iaddend. .Iadd.24. The coating composition as defined by claim 23 which comprises a paint. .Iaddend. .Iadd.25. A cross-linked polymer comprising the condensation product of (1) the cross-linking agent as defined by claim 10, and (2) a saturated polyester with terminal hydroxyl groups. .Iaddend. .Iadd.26. The cross-linked polymer as defined by claim 25, wherein the saturated polyester (2) has a softening temperature of from 70° to 130° C., a hydroxyl number of from 150 to 250 and an acid number below 10. .Iaddend. .Iadd.27. The binder as defined by claim 2, wherein the at least one dicarboxylic acid is selected from the group consisting of terephthalic acid and isophthalic acid. .Iaddend. .Iadd.28. The binder as defined by claim 3, wherein the at least one acid associated with the aromatic dicarboxylic acid is selected from the group consisting of adipic
acid, succinic acid and sebacic acid. .Iaddend. .Iadd.29. The binder as defined by claim 3, wherein the at least one acid associated with the aromatic dicarboxylic acid is selected from the group consisting of trimellitic acid, trimellitic acid anhydride, pyromellitic acid, pyromellitic acid anhydride and butanetetracarboxylic acid. .Iaddend. .Iadd.30. The binder as defined by claim 4, wherein the one or more triols are selected from the group consisting of glycerol, trimethylolpropane and trihydroxyethylisocyanurate. .Iaddend. .Iadd.31. The binder as defined by claim 2, wherein the one or more diols are selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, butanediol, bishydroxyethyl-bisphenol A, neopentyl glycol and hydrogenated bisphenol A. .Iaddend. .Iadd.32. The binder as defined by claim 1, wherein the saturated polyester and the cross-linking agent are present in proportions corresponding to their respective hydroxyl and acid numbers. .Iaddend. .Iadd.33. The cross-linked polymer as defined by claim 25, wherein the condensation is effected at a temperature of from 140° to 200° C., for from 5 to 30 minutes.
.Iadd. . A coated substrate, the coating comprising the cross-linked polymer as defined by claim 25. .Iaddend. .Iadd.35. The coated substrate as defined by claim 34, the coating comprising a paint. .Iaddend. .Iadd.36. A coated substrate, the coating comprising the binder as defined by claim 1. .Iaddend. .Iadd.37. The coated substrate as defined by claim 36, the coating comprising a paint. .Iaddend. .Iadd.38. The cross-linking agent as defined by claim 11, said composition having an acid number of about 518 in aqueous medium and about 336 in alcoholic medium. .Iaddend. .Iadd.39. The cross-linking agent as defined by claim 11, said composition having an acid number of about 455 in aqueous medium and about 280 in alcoholic medium..Iaddend.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/885,107 USRE30102E (en) | 1974-12-24 | 1978-03-09 | Cross-linkable compounds based on saturated polyesters |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7442685 | 1974-12-24 | ||
| FR7442685A FR2295990A1 (en) | 1974-12-24 | 1974-12-24 | CROSS-LINKABLE COMPOSITIONS BASED ON SATURATED POLYESTERS |
| US05/640,479 US4024111A (en) | 1974-12-24 | 1975-12-15 | Cross-linkable compounds based on saturated polyesters |
| US05/885,107 USRE30102E (en) | 1974-12-24 | 1978-03-09 | Cross-linkable compounds based on saturated polyesters |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US05/640,479 Reissue US4024111A (en) | 1974-12-24 | 1975-12-15 | Cross-linkable compounds based on saturated polyesters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| USRE30102E true USRE30102E (en) | 1979-09-25 |
Family
ID=9146579
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US05/640,479 Expired - Lifetime US4024111A (en) | 1974-12-24 | 1975-12-15 | Cross-linkable compounds based on saturated polyesters |
| US05/885,107 Expired - Lifetime USRE30102E (en) | 1974-12-24 | 1978-03-09 | Cross-linkable compounds based on saturated polyesters |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US05/640,479 Expired - Lifetime US4024111A (en) | 1974-12-24 | 1975-12-15 | Cross-linkable compounds based on saturated polyesters |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US4024111A (en) |
| JP (1) | JPS5935928B2 (en) |
| BE (1) | BE836957A (en) |
| CA (1) | CA1096998A (en) |
| CH (1) | CH608511A5 (en) |
| DE (2) | DE2558295C2 (en) |
| DK (1) | DK588475A (en) |
| ES (1) | ES443816A1 (en) |
| FR (1) | FR2295990A1 (en) |
| GB (1) | GB1485596A (en) |
| IE (1) | IE42389B1 (en) |
| IT (1) | IT1052618B (en) |
| LU (1) | LU74098A1 (en) |
| NL (1) | NL179737C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4326509A (en) | 1978-12-27 | 1982-04-27 | Tokyo Eizai Laboratory Co. Ltd. | Thermoplastic composition for setting bandages and a solventless process for the manufacture thereof |
| US4837126A (en) | 1985-06-07 | 1989-06-06 | W. R. Grace & Co. | Polymer composition for photoresist application |
| US5326831A (en) * | 1990-08-24 | 1994-07-05 | Exxon Chemical Patents Inc. | Phenol terminated diester compositions derived from discarboxylic acids, polyester polymers or alkyd polymers, and curable compositions containing same |
| US5536794A (en) * | 1990-12-19 | 1996-07-16 | Exxon Chemical Patents Inc. (Ecpi) | Thermoset coating compositions having improved hardness |
| CN113370340A (en) * | 2021-06-21 | 2021-09-10 | 德华兔宝宝装饰新材股份有限公司 | Modified fast-growing poplar solid wood floor and modification method thereof |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4182840A (en) * | 1976-09-22 | 1980-01-08 | Rhone-Poulenc Industries | Cross-linkable saturated powderous compositions and powderous painting and coating compositions containing same |
| JPS53111335A (en) * | 1977-03-11 | 1978-09-28 | Dainippon Ink & Chem Inc | Powder coating resin composition |
| FR2401205A1 (en) * | 1977-05-23 | 1979-03-23 | Rhone Poulenc Ind | IMPROVED CROSS-LINKABLE SATURATED COMPOSITIONS FOR POWDER PAINT |
| US4154918A (en) * | 1977-07-07 | 1979-05-15 | Ciba-Geigy Corporation | Thermoplastic copolyesters, processes for their preparation and their use |
| DE2860679D1 (en) * | 1977-12-23 | 1981-08-06 | Ciba Geigy Ag | Use of a varnish made of an epoxy-resin and a mixture of esters of trimellitic acid anhydride suitable for layers on the inner surface of a can of metal for foodstuffs or beverages |
| FR2417533A1 (en) * | 1978-02-20 | 1979-09-14 | Rhone Poulenc Ind | SATURATED CROSS-LINKABLE COMPOSITIONS FOR POWDER PAINT WITH MATT AND / OR SATIN SURFACE |
| DE2835617A1 (en) * | 1978-08-14 | 1980-02-28 | Hoechst Ag | METHOD FOR PRODUCING CORROSION-RESISTANT COATINGS |
| US4275189A (en) * | 1980-02-28 | 1981-06-23 | Cargill, Incorporated | Neopentyl glycol, terephthalate, dicarboxy acid, trimellitate thermosetting resin |
| US4379886A (en) * | 1980-04-28 | 1983-04-12 | E. I. Du Pont De Nemours And Company | Liquid coating composition having a reactive catalyst |
| US4328332A (en) * | 1981-06-14 | 1982-05-04 | Recognition Equipment Inc. | Process for producing fluorescent resin for ink jet printers |
| US4442269A (en) * | 1982-12-15 | 1984-04-10 | E. I. Du Pont De Nemours & Company | Staged copolymerization of polyesters |
| DE3301729A1 (en) * | 1983-01-20 | 1984-07-26 | Hoechst Ag, 6230 Frankfurt | BINDING BLEND AND THE USE THEREOF FOR PRODUCING A TWO-LAYER METALLIC PAINT |
| US5055524A (en) * | 1987-07-16 | 1991-10-08 | Ppg Industries, Inc. | Polyol-modified polyanhydride curing agent for polyepoxide powder coatings |
| US5290854A (en) * | 1990-07-23 | 1994-03-01 | Owens-Corning Fiberglas Technology Inc. | Thermoplastic low-profile additives and use thereof in unsaturated polyester resin compositions |
| US5256709A (en) * | 1991-07-22 | 1993-10-26 | Owens-Corning Fiberglas Technology, Inc. | Unsaturated polyester resin compositions containing compatible compounds having aromatic substituents |
| US5256708A (en) * | 1991-07-22 | 1993-10-26 | Owens-Corning Fiberglas Technology, Inc. | Unsaturated polyester resin compositions containing compatible compounds having sulfur-containing substituents |
| CN1076025C (en) * | 1998-12-01 | 2001-12-12 | 中国科学院化学研究所 | Process for preparing polyester oligomer containing carboxyl |
| IT1319683B1 (en) * | 2000-12-06 | 2003-10-23 | Quarella Spa | HARDENABLE COMPOSITIONS INCLUDING AN UNSATURATED EPOXY POLYESTER AND MINERAL CHARGES. |
| TW591341B (en) * | 2001-09-26 | 2004-06-11 | Shipley Co Llc | Coating compositions for use with an overcoated photoresist |
| CN105754091B (en) * | 2016-03-03 | 2018-06-12 | 江苏华夏制漆科技有限公司 | A kind of unsaturated carbamide resin of polyester amide and its preparation method and application |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3652502A (en) * | 1970-08-05 | 1972-03-28 | Eastman Kodak Co | Linear polyesters having free carboxyl radicals distributed along the molecular chain coatings thereof and coated substrates |
| US3692744A (en) * | 1968-01-04 | 1972-09-19 | Rhodiaceta | Injection molded branched polyesters |
| US3725329A (en) * | 1969-10-09 | 1973-04-03 | Eastman Kodak Co | Photographic subbing material |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE631375A (en) * | 1962-04-27 | |||
| US3435002A (en) * | 1967-05-15 | 1969-03-25 | Gen Electric | Polyamide acid resins and polyimides therefrom |
| DE1913923C3 (en) * | 1969-03-19 | 1981-02-19 | Hoechst Ag, 6000 Frankfurt | Thermosetting powdery binder for moldings, in particular for powder coating |
| JPS5139658B2 (en) * | 1972-06-30 | 1976-10-29 | ||
| JPS5213210B2 (en) * | 1972-06-30 | 1977-04-13 | ||
| JPS4927091A (en) * | 1972-07-08 | 1974-03-11 |
-
1974
- 1974-12-24 FR FR7442685A patent/FR2295990A1/en active Granted
-
1975
- 1975-12-15 US US05/640,479 patent/US4024111A/en not_active Expired - Lifetime
- 1975-12-22 GB GB52421/75A patent/GB1485596A/en not_active Expired
- 1975-12-22 BE BE163020A patent/BE836957A/en not_active IP Right Cessation
- 1975-12-23 CH CH1673575A patent/CH608511A5/xx not_active IP Right Cessation
- 1975-12-23 JP JP50153896A patent/JPS5935928B2/en not_active Expired
- 1975-12-23 IT IT52837/75A patent/IT1052618B/en active
- 1975-12-23 CA CA242,409A patent/CA1096998A/en not_active Expired
- 1975-12-23 LU LU74098A patent/LU74098A1/xx unknown
- 1975-12-23 NL NLAANVRAGE7514997,A patent/NL179737C/en not_active IP Right Cessation
- 1975-12-23 IE IE2815/75A patent/IE42389B1/en unknown
- 1975-12-23 DE DE2558295A patent/DE2558295C2/en not_active Expired
- 1975-12-23 ES ES443816A patent/ES443816A1/en not_active Expired
- 1975-12-23 DK DK588475A patent/DK588475A/en not_active Application Discontinuation
- 1975-12-23 DE DE2560115A patent/DE2560115C2/en not_active Expired
-
1978
- 1978-03-09 US US05/885,107 patent/USRE30102E/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3692744A (en) * | 1968-01-04 | 1972-09-19 | Rhodiaceta | Injection molded branched polyesters |
| US3725329A (en) * | 1969-10-09 | 1973-04-03 | Eastman Kodak Co | Photographic subbing material |
| US3652502A (en) * | 1970-08-05 | 1972-03-28 | Eastman Kodak Co | Linear polyesters having free carboxyl radicals distributed along the molecular chain coatings thereof and coated substrates |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4326509A (en) | 1978-12-27 | 1982-04-27 | Tokyo Eizai Laboratory Co. Ltd. | Thermoplastic composition for setting bandages and a solventless process for the manufacture thereof |
| US4837126A (en) | 1985-06-07 | 1989-06-06 | W. R. Grace & Co. | Polymer composition for photoresist application |
| US5326831A (en) * | 1990-08-24 | 1994-07-05 | Exxon Chemical Patents Inc. | Phenol terminated diester compositions derived from discarboxylic acids, polyester polymers or alkyd polymers, and curable compositions containing same |
| US5334671A (en) * | 1990-08-24 | 1994-08-02 | Exxon Chemical Patents Inc. | Phenol terminated diester compositions derived from dicarboxylic acids, polyester polymers or alkyd polymers, and curable compositions containing same |
| US5536794A (en) * | 1990-12-19 | 1996-07-16 | Exxon Chemical Patents Inc. (Ecpi) | Thermoset coating compositions having improved hardness |
| CN113370340A (en) * | 2021-06-21 | 2021-09-10 | 德华兔宝宝装饰新材股份有限公司 | Modified fast-growing poplar solid wood floor and modification method thereof |
| CN113370340B (en) * | 2021-06-21 | 2022-06-10 | 德华兔宝宝装饰新材股份有限公司 | Modified fast-growing poplar solid wood floor and modification method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| NL179737C (en) | 1986-11-03 |
| LU74098A1 (en) | 1976-11-11 |
| IE42389B1 (en) | 1980-07-30 |
| DE2558295C2 (en) | 1985-12-12 |
| CH608511A5 (en) | 1979-01-15 |
| NL7514997A (en) | 1976-06-28 |
| JPS5935928B2 (en) | 1984-08-31 |
| CA1096998A (en) | 1981-03-03 |
| IT1052618B (en) | 1981-07-20 |
| GB1485596A (en) | 1977-09-14 |
| US4024111A (en) | 1977-05-17 |
| DE2558295A1 (en) | 1976-07-01 |
| DE2560115C2 (en) | 1983-06-09 |
| DK588475A (en) | 1976-06-25 |
| IE42389L (en) | 1976-06-24 |
| FR2295990A1 (en) | 1976-07-23 |
| ES443816A1 (en) | 1977-04-16 |
| NL179737B (en) | 1986-06-02 |
| BE836957A (en) | 1976-06-22 |
| JPS5189556A (en) | 1976-08-05 |
| FR2295990B1 (en) | 1979-02-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: CHLOE CHIMIE, TOUR GENERALE, 5 PLACE DE LA PYRAMID Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:BERNELIN, DANIEL;MEYER, JACQUES;REEL/FRAME:004105/0452 Effective date: 19830315 |
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| AS | Assignment |
Owner name: CRAY VALLEY SA, SOCIETE ANONYME, FRANCE Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:NORSOLOR, SOCIETE ANONYME;REEL/FRAME:006274/0706 Effective date: 19920409 |