US970473A - Manufacture of lubricating-oils. - Google Patents
Manufacture of lubricating-oils. Download PDFInfo
- Publication number
- US970473A US970473A US49526209A US1909495262A US970473A US 970473 A US970473 A US 970473A US 49526209 A US49526209 A US 49526209A US 1909495262 A US1909495262 A US 1909495262A US 970473 A US970473 A US 970473A
- Authority
- US
- United States
- Prior art keywords
- oils
- lubricating
- manufacture
- molecules
- formation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000010687 lubricating oil Substances 0.000 title description 5
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000003921 oil Substances 0.000 description 11
- 235000019198 oils Nutrition 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 7
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 5
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000002480 mineral oil Substances 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000010775 animal oil Substances 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229940013317 fish oils Drugs 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000001131 transforming effect Effects 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- UHDGCWIWMRVCDJ-CCXZUQQUSA-N Cytarabine Chemical compound O=C1N=C(N)C=CN1[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O1 UHDGCWIWMRVCDJ-CCXZUQQUSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
- C10M101/04—Fatty oil fractions
Definitions
- a cylinder A In a cylinder A are arranged on a shaft a series of parallel plates, alternately of metal B and of insulating material C. Counting from the left, the first, third and fifth B plates are connected to one pole of a source of current by a wire F, and the second, fourth and sixth B plates are connected to the second pole of the source of current by a wire G.
- the cylinder is rotated by means of avpulley D, and owing to a number of conduits g, fixed to the interior of the wall, the oil is continually sprinkled over the upper part of the plates.
- the increase of molecular weight is very small, consisting merely in the addition of a molecular weight of hydrogen.
- the second case as I have ascertained by the boiling point and freezing.
- Oils which contain much stearin are inappropriate for lubrication because this substance is a bad lubricant; moreover, it presents the great inconvenience that it makes the oils insufficiently fluid at ordinary temperatures and too fluid at raised-temperatures.
- the polymerized oils have not these defects; the are viscous but are not solidified by cold furthermore, when the temperature is raised they become gradually more fluid, but always possess a satisfactory consistence which is the quality required for lubricating oils.
- the present process seeks to avoid or diminish the formation of stearin and to favor the formation of molecules of a high degree of polymerization.
- the silent electric discharge is caused to act not on the pure oil, but on a mixture of vegetable, animal or mineral oils.
- a mixture comprisin mineral oil is preferred.
- the proportion 0 such oil in the mixture varies according to the quality of the oils under treatment and the degree of viscosity desired.
- the particular effect ob tained is due to the interaction of the liduid molecules under the influence of the si ent electric discharge so that one may operate in any gaseous atmosphere or in a partial Vacuum.
- the change may, for instance, be effected in. the apparatus described and shown in U. S. Patent 852,662, of May 7, 1907; it is sufficient to leave the mixture in the apparatus long enough to reach the desired degree of viscosity.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Description
A. DE HEMPTINNE. MANUFACTURE OF LUBRIGATING OILS. APPLICATION FILED MAY 11. 1909.
970,473. Patented Sept. 20, 1910.
\NvE -roR, \TN E33 ALEXAN ER DE HENIPTINNE b My 7 Attoma yield and of the The apparatus ALEXANDRE DE HEMPTINNE, OF GHENT, BELGIUM.
MANUFACTURE OF LUBRICATING-OILS.
To all whom it may concern:
Be it known that I, ALEXANDRE DE HEMP- TINNE, professor of university, a subject of the King of Belgium, residing at Ghent,
No. 51 rue Basse des Champs, Belgium, have invented a new and useful Manufacture of Lubricating-Oils; and I do hereby declare the following to be a full, clear, and exact description of the same.
When the silent electric discharge acts on olein or similar products in an atmosphere of hydrogen, stearin is produced. This process has been patented in the United States Patent No. 797,112 of 15th August 1905. A second United StatesPatent, No. 852,662 of 7th May 1907, relates to a process for deodorizing fish oils, based on the same principle. In this latter process there is also a formation of stearin which raises the solidif ing temperature of the oil.
I have ound that the electric discharge acting directly on a liquid in a partial vacuum or in any gaseous atmosphere, has the efiect of polymerizing the molecules. There follows a considerable increase in the viscosity, such that by mixing with mineral oils the animal or vegetable oils thus treated lubricating oils are obtained.
Inorder that the process may be advan-x point of view both oftageous from the quality of the products, it
in a special manner. for carrying out the proc- 'ess is shown in the accompanying drawings, in which- Figure .1 is a longitudinal section, and Fig. 2, a transverse section.
In a cylinder A are arranged on a shaft a series of parallel plates, alternately of metal B and of insulating material C. Counting from the left, the first, third and fifth B plates are connected to one pole of a source of current by a wire F, and the second, fourth and sixth B plates are connected to the second pole of the source of current by a wire G. The cylinder is rotated by means of avpulley D, and owing to a number of conduits g, fixed to the interior of the wall, the oil is continually sprinkled over the upper part of the plates.
To make the matter clear, I deem it useful to give' some explanations of a scientific character.
should be applied It is important to distinguish between viscosity due to the formation of stearin and that due to the formation of associated or polymerized molecules. In
Specification of Letters Patent.
Application filed May 11, 1909. Serial No. 495,262.
Patented Sept. 20, 1910.
the first case the increase of molecular weight is very small, consisting merely in the addition of a molecular weight of hydrogen. In the second case, as I have ascertained by the boiling point and freezing.
point methods, there is a formation of complex molecules of high molecular weight.
This reaction occurring between the molecules is independent phere.
Oils which contain much stearin are inappropriate for lubrication because this substance is a bad lubricant; moreover, it presents the great inconvenience that it makes the oils insufficiently fluid at ordinary temperatures and too fluid at raised-temperatures. The polymerized oils have not these defects; the are viscous but are not solidified by cold furthermore, when the temperature is raised they become gradually more fluid, but always possess a satisfactory consistence which is the quality required for lubricating oils.
In contradistinction to the object of the aforesaid patents relative to the synthesis of stearic acid and to the deodorizing of fish oils, the present process seeks to avoid or diminish the formation of stearin and to favor the formation of molecules of a high degree of polymerization. For this purpose, the silent electric discharge is caused to act not on the pure oil, but on a mixture of vegetable, animal or mineral oils. In. practice, a mixture comprisin mineral oil is preferred. The proportion 0 such oil in the mixture varies according to the quality of the oils under treatment and the degree of viscosity desired. The particular effect ob tained is due to the interaction of the liduid molecules under the influence of the si ent electric discharge so that one may operate in any gaseous atmosphere or in a partial Vacuum. The change may, for instance, be effected in. the apparatus described and shown in U. S. Patent 852,662, of May 7, 1907; it is sufficient to leave the mixture in the apparatus long enough to reach the desired degree of viscosity.
Having thus described my invention and the best means I know of carrying the same into practical effect, I claim 1. A process for transforming oils into a viscous product, which process consists in subjectin the oil to the action of the silent electric ischarge, in any rarefied gaseous atmosphere. A
of the gaseous atmos-- 2. A process for transforming oils into a name to this specification in the presence of s viscous product, which process consists 1n two subscribing Witnesses.
subjecting a mixture of animal vegetable v and mineral oils to the action of? the silent ALEXANDRE DE HEMPTINNE' .5 electric discharge, in any rarefied gaseous Witnesses atmosphere. N. COLLINET, I
In testimony whereof, I have signed my JAMES M. Gr. FAX.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US49526209A US970473A (en) | 1909-05-11 | 1909-05-11 | Manufacture of lubricating-oils. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US49526209A US970473A (en) | 1909-05-11 | 1909-05-11 | Manufacture of lubricating-oils. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US970473A true US970473A (en) | 1910-09-20 |
Family
ID=3038861
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US49526209A Expired - Lifetime US970473A (en) | 1909-05-11 | 1909-05-11 | Manufacture of lubricating-oils. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US970473A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5034108A (en) * | 1988-06-15 | 1991-07-23 | Shell Oil Company | Plasma process for increasing the molecular weight of hydrocarbons and/or derivatives thereof |
-
1909
- 1909-05-11 US US49526209A patent/US970473A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5034108A (en) * | 1988-06-15 | 1991-07-23 | Shell Oil Company | Plasma process for increasing the molecular weight of hydrocarbons and/or derivatives thereof |
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