US931520A - Emulsion and process for producing the same. - Google Patents
Emulsion and process for producing the same. Download PDFInfo
- Publication number
- US931520A US931520A US45573208A US1908455732A US931520A US 931520 A US931520 A US 931520A US 45573208 A US45573208 A US 45573208A US 1908455732 A US1908455732 A US 1908455732A US 931520 A US931520 A US 931520A
- Authority
- US
- United States
- Prior art keywords
- emulsion
- chlorids
- oils
- producing
- same
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000839 emulsion Substances 0.000 title description 14
- 238000000034 method Methods 0.000 title description 7
- 239000003921 oil Substances 0.000 description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 11
- 239000003925 fat Substances 0.000 description 10
- 150000001721 carbon Chemical group 0.000 description 8
- 239000000344 soap Substances 0.000 description 8
- 229930195733 hydrocarbon Natural products 0.000 description 7
- 150000002430 hydrocarbons Chemical class 0.000 description 7
- 235000011121 sodium hydroxide Nutrition 0.000 description 6
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- KFUSEUYYWQURPO-UHFFFAOYSA-N 1,2-dichloroethene Chemical group ClC=CCl KFUSEUYYWQURPO-UHFFFAOYSA-N 0.000 description 1
- UAHKDGCHPIIACM-UHFFFAOYSA-N C#C.Cl.Cl.Cl.Cl Chemical compound C#C.Cl.Cl.Cl.Cl UAHKDGCHPIIACM-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 240000000543 Pentas lanceolata Species 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- BNIXVQGCZULYKV-UHFFFAOYSA-N pentachloroethane Chemical compound ClC(Cl)C(Cl)(Cl)Cl BNIXVQGCZULYKV-UHFFFAOYSA-N 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/017—Mixtures of compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/03—Organic sulfoxy compound containing
- Y10S516/04—Protein or carboxylic compound containing
Definitions
- watery emulsions of carbon tetrachlorid can be produced by means of sulfonated oils or fats, especially by Turkey-red oils, or by soaps which are high temperatures, sul onated fats or oils with 6%- or more sodium hydrate.
- soap obtained by saponifying sulfona-ted fats, oils, fatty acids or oleic oils, with 6% or more of sodium hydrate, at comparatively high temperatures; then stir into the solution, either hot or cold, 1 to 2 parts of tetrachlorethane, pentachlorethane, trichlorethylene, or perchlorcthylene.
- tetrachlorethane 1,3-bis(trimethylene
- pentachlorethane 1,4-did
- trichlorethylene 1,4-richlorethylene
- perchlorcthylene perchlorcthylene
- emulsions which consists in emulsifying with 'a sulfonated product, such as sulfonated fats, oils, or Turkey-red oil, chlorids of hydrocarbons having more than one carbon atom.
- a new article of manufacture an emulsion composed of a saponified product (especially sulfonated fats, or oils, or Turkey-red oil), and chlorids of hydrocarbons havin more than one carbon atom.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Colloid Chemistry (AREA)
Description
To all whom it may concern:
' obtained by saponifyin at comparativelyfurther treatment (bleaching, dyeing).
JULIUS STOGKHAUSEN, OF OREFELD, GERMANY.
EMULSION AND PROCESS FOR PRODUCING THE SAME.
Application filed October 1-, 1908. Serial No. 455,732.
Be it known that I, J onus SrooKiaAUsnN, a subject of the German Empire, residing in Crefeld, Germany, have invented a new and useful Emulsion and Process for Producing the Same; and I do hereby declare the following to be a -full, clear, and exact descriptlon of the same.
It is well known that watery emulsions of carbon tetrachlorid can be produced by means of sulfonated oils or fats, especially by Turkey-red oils, or by soaps which are high temperatures, sul onated fats or oils with 6%- or more sodium hydrate. The present process is based upon the discovery that, in a similar way, watery emulsion can also be produced from chlorids of hydrocarbons with more than one carbon atom, such as tetrachlorethane (C H CL), pentas chlorethane: (C HCI trichlorethylene (CHCl :CCl), perehlorethylene (C Ch), and that the emulsions obtained with these chlorids penetrate more easily into the goods and thereby render possible a considerably more thorough removal of the fat than the emulsions produced .with carbon= tetrachlorid. This is of importance, especially. for the Washing of raw wool, because raw wool must contain less than 1% of fat in results in the In the application of emulsion of carbon tetrachlorld, this is only possible if thevwool is also washed withsoap, while with the chlorids containing more than one carbon atom the "same result can be obtained without any use of. soap. Further, intheleniployment of. perchlorethane, acetylene tetrachlorid, trichlore'thylene, dichlorethylene, etc., considerably larger quantities of' these chlorids can be incorporated with the soaps than of carbon 'tertrachlorid. This increase in the capacity of emulsifying is also strikingly shown by the fact that even ordinary soaps order to give satisfactor and saponaceous compounds-.although to a slighter degree-and with less efiiciency-can be incorporated with the chlorids.
The practical carrying out ofthe process can take place for example as follows: Dissolve in {-to 1 part of water, 1 part of the Specification of Letters Patent.
Patented Aug. 17, 1909.
soap obtained by saponifying sulfona-ted fats, oils, fatty acids or oleic oils, with 6% or more of sodium hydrate, at comparatively high temperatures; then stir into the solution, either hot or cold, 1 to 2 parts of tetrachlorethane, pentachlorethane, trichlorethylene, or perchlorcthylene. For increasing the solubility of the chlorid there can be added also diluted soda-lye.
I am aware that it is not new to produce emulsions of chlorids of hydrocarbons, with more than one carbon atom, by means of albuminoids, c. g., mucin, or alkaloids, or enzymes, for example, emulsin, or common soaps. But, my emulsions of chlorids of hydrocarbons with more than one carbon atom are produced by means of a sulfonated product, especially sulfonated fats or oils, or Turkey-red oil, or the soaps obtained by saponification' of sulfona ted fats or oils with at least 6% of sodium hydrate.
Having thus fully described my invention, what I claim is:
1. The process of producing emulsions, which consists in emulsifying with 'a sulfonated product, such as sulfonated fats, oils, or Turkey-red oil, chlorids of hydrocarbons having more than one carbon atom.
2. The process of producin emulsions, which consists in saponifying su fonated fa or oils with at least 6% sodium hydrate, and then emulsifying the soap thus obtained with chlorids of hydrocarbons having more than one carbon atom.
3. A new article of manufacture, an emulsion composed of a saponified product (especially sulfonated fats, or oils, or Turkey-red oil), and chlorids of hydrocarbons havin more than one carbon atom.
4:. is a new article of manufacture, an emulsion composed of sulfonated fats or oils saponified with at least 6% sodium hydrate, and chlorids of hydrocarbons having more than one carbon atom.
In testimony -whereof, I have signed my name to this specification in the presence of two subscribing witnesses.
JULIUS STOCKHAUSEN.
Witnesses:
HENRY QUADFLIEG, Erase KALBUscH.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US45573208A US931520A (en) | 1908-10-01 | 1908-10-01 | Emulsion and process for producing the same. |
| US507443A US1035815A (en) | 1908-10-01 | 1909-07-13 | Process of removing fat and impurities from vegetable and animal materials. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US45573208A US931520A (en) | 1908-10-01 | 1908-10-01 | Emulsion and process for producing the same. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US931520A true US931520A (en) | 1909-08-17 |
Family
ID=2999944
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US45573208A Expired - Lifetime US931520A (en) | 1908-10-01 | 1908-10-01 | Emulsion and process for producing the same. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US931520A (en) |
-
1908
- 1908-10-01 US US45573208A patent/US931520A/en not_active Expired - Lifetime
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