US883703A - Process of making dibromindigo. - Google Patents
Process of making dibromindigo. Download PDFInfo
- Publication number
- US883703A US883703A US36490907A US1907364909A US883703A US 883703 A US883703 A US 883703A US 36490907 A US36490907 A US 36490907A US 1907364909 A US1907364909 A US 1907364909A US 883703 A US883703 A US 883703A
- Authority
- US
- United States
- Prior art keywords
- indigo
- dibromindigo
- making
- bromin
- nitrobenzene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 8
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 12
- 229940097275 indigo Drugs 0.000 description 12
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 12
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- ZLHGTHCCYUEAIK-UHFFFAOYSA-N 5,7-dibromo-2-(5,7-dibromo-3-hydroxy-1H-indol-2-yl)indol-3-one Chemical compound [O-]c1c([nH]c2c(Br)cc(Br)cc12)C1=[NH+]c2c(cc(Br)cc2Br)C1=O ZLHGTHCCYUEAIK-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- SURLGNKAQXKNSP-DBLYXWCISA-N chlorin Chemical compound C\1=C/2\N/C(=C\C3=N/C(=C\C=4NC(/C=C\5/C=CC/1=N/5)=CC=4)/C=C3)/CC\2 SURLGNKAQXKNSP-DBLYXWCISA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000000950 dibromo group Chemical group Br* 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B7/00—Indigoid dyes
- C09B7/02—Bis-indole indigos
- C09B7/04—Halogenation thereof
Definitions
- Example. 20 parts of indigo, 200 parts of nitrobenzene and 2424.5 parts (four atomic proportions) ofbromin are well mixed together and heated in a reflux apparatus in an oil bath in such a manner that in the course of about an hour the temperature of the vlatter rises to 225 C., the heating is then continued for about 1%- to 2 hours at 226 to 228 0., much hydrogen bromid being evolved, this ceasing completely, however, after the lapse of the time named. After cooling and filtering, the solid dibromo-derivative of indigo is washed with alcohol and dried; it forms a deep blue crystalline powder and the yield is nearly quantitative.
- the product of the example yields a bright yellow vat more easily and with more complete dissolution than is the case with indigo RR under like conditions.
- Cotton is dyed in the vat vivid reddish blue tints, which in comparison with the dyeings obtained in the indigo vat, besides being considerably more vivid and more intense, are characterized by an essentially greater fastness to Washing and chlorin.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
UNITED STATES PATENT OFFICE.
GADIENTQENGI, OF BASEL, SWITZERLAND, ASSIGNOR TO THE FIRM OF SOCIETY OF CHEMICAL INDUSTRY IN BASLE, OF BASEL, SWITZERLAND.
PROCESS OF MAKING DIBROMINDIGO.
Specification of Letters Patent.
Application filed March 27, 1907.
Patented April 7, 1908.
Serial No. 364,909.
To all whom it may concern:
Be it known that I, GADIENT ENG-T, doctor of philosophy and chemist, a citizen of the Swiss Republic, and resident of Basel, Switzerland, have invented a new and useful Dibromo Derivative of Indigo and a Process for the Manufacture of the Same, of which the following is a full and exact specification.
In my United States Patents No. 856687 & No. 856776 dated June 11th 1907, I described the manufacture of triand tetrabromoderivatives of indigo consisting in treating indigo, monoor dibromindigo at a raised temperature with the appropriate proportion of bromin in presence of a suitable indifferent diluent or solvent, particularly of nitrobenzene. I have found that this process may also be applied advantageously for producing a dibromoderivative of indigo, the heating of indigo with the theoretically necessary quantity of bromin (4 atomic proportions) in presence of nitrobenzene furnishing a dibromoderivative in a very pure condition and with a quantitative out-put.
comparatively to the processes for the manufacture of bromindigo described in the German Patent No. 128575 and in the United States Patents No. 729217 and No. 807782, my new process has the advantage to give directly-by employing the theoretical necessary quantity of bromina dibromindigo containing the exact percentage of bromin (about 37.8% of Br.) and corresponding to the formula C H 0 N Br while by brominating indigo with 4 atomic proportions of bromin, according to the process of the said patents, a product is obtained, which contains only about 33% of bromin.
Example. 20 parts of indigo, 200 parts of nitrobenzene and 2424.5 parts (four atomic proportions) ofbromin are well mixed together and heated in a reflux apparatus in an oil bath in such a manner that in the course of about an hour the temperature of the vlatter rises to 225 C., the heating is then continued for about 1%- to 2 hours at 226 to 228 0., much hydrogen bromid being evolved, this ceasing completely, however, after the lapse of the time named. After cooling and filtering, the solid dibromo-derivative of indigo is washed with alcohol and dried; it forms a deep blue crystalline powder and the yield is nearly quantitative.
By treatment with alkaline reducing agents, preferably dilute caustic soda lye and sodium hydrosulfite, the product of the example yields a bright yellow vat more easily and with more complete dissolution than is the case with indigo RR under like conditions. Cotton is dyed in the vat vivid reddish blue tints, which in comparison with the dyeings obtained in the indigo vat, besides being considerably more vivid and more intense, are characterized by an essentially greater fastness to Washing and chlorin.
What I claim is The herein described process for the manufacture of a dibromoderivative of indigo by heating indigo with four atoms of bromin in presence of nitrobenzene.
In witness whereof I have hereunto signed my name this 11 day of March 1907, in the presence of two subscribing witnesses.
GADIENT ENGI.
Witnesses GEO. GIFFORD, AMAND BRAUN.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36490907A US883703A (en) | 1907-03-27 | 1907-03-27 | Process of making dibromindigo. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36490907A US883703A (en) | 1907-03-27 | 1907-03-27 | Process of making dibromindigo. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US883703A true US883703A (en) | 1908-04-07 |
Family
ID=2952143
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US36490907A Expired - Lifetime US883703A (en) | 1907-03-27 | 1907-03-27 | Process of making dibromindigo. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US883703A (en) |
-
1907
- 1907-03-27 US US36490907A patent/US883703A/en not_active Expired - Lifetime
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