US8463423B2 - Methods and systems for measurement and control of process parameters - Google Patents
Methods and systems for measurement and control of process parameters Download PDFInfo
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- US8463423B2 US8463423B2 US12/803,385 US80338510A US8463423B2 US 8463423 B2 US8463423 B2 US 8463423B2 US 80338510 A US80338510 A US 80338510A US 8463423 B2 US8463423 B2 US 8463423B2
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- particle
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K1/00—Details of thermometers not specially adapted for particular types of thermometer
- G01K1/02—Means for indicating or recording specially adapted for thermometers
- G01K1/024—Means for indicating or recording specially adapted for thermometers for remote indication
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K13/00—Thermometers specially adapted for specific purposes
- G01K13/02—Thermometers specially adapted for specific purposes for measuring temperature of moving fluids or granular materials capable of flow
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01K—MEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
- G01K2207/00—Application of thermometers in household appliances
- G01K2207/02—Application of thermometers in household appliances for measuring food temperature
Definitions
- the present invention relates generally to systems and processes suitable for measuring process parameters of process systems, primarily systems for processing food products, making use of application specific integrated circuits identifiable by radio frequency signals.
- thermal treatment can be achieved either prior to or after filling the product into the package.
- low acid foods where product is thermally processed prior to filling into the package can employ vastly different processing systems as compared to product that is thermally processed in-package.
- the manufacturer needs to know how much heat is applied to the product. This heat treatment can be observed as a function of temperature and time.
- Product temperature is heated to a certain degree and held at-least this temperature for a prescribed amount of time, thus corresponding to a “lethality” value which is conventionally used in the food industry to standardize and quantify the intensity of a thermal process.
- the temperature of the product can be measured easily by temperature probes at prescribed locations in a process system.
- the use of conventional temperature probes is not preferred and is in practice almost impossible when temperature is desired to be measured within particulate foods (i.e., liquid foods with native constituent particles) such as soups. In these circumstances, only the liquid fraction of the particulate food can be monitored for temperature by the use of conventional temperature probes. A distinct challenge arises when temperature measurements of the different native constituent particles in the foods are desired.
- the goal is to ensure commercial sterility in the product as a whole.
- the product is comprised of a homogeneous liquid fraction
- measurement can be facilitated by use of conventional temperature probes.
- the product is comprised of several different particles suspended in a liquid fraction, such as in a garnished soup
- it can be extremely difficult to predict sterility in the product as a whole based on the process data that is readily available in a conventional continuous flow sterilization system.
- the difficulty arises from the fact that different particle types in the product may heat up differently from the liquid stream, thus abrogating the utility and veracity of temperature probe measurements of the liquid faction as an indicator of particle temperature.
- Particle residence time distribution in the process system adds to the complexity of ensuring commercial sterility of all components.
- Batch blending of products in a kettle or ribbon blender can result in particle distribution issues for several reasons, including insufficient blending time, inappropriate agitator design, inappropriate agitator speed or direction, kettle size and shape, garnish level and size, overall liquid amount, particle density, and liquid viscosity. It can, therefore, be difficult to measure a variety of process conditions of interest such as, for example, the direction, orientation, speed, or temperature of a particle in a mixing vessel. Indeed, direct particle temperature measurement using conventional techniques, such as temperature probes, would be significantly challenged, if at all possible, by the movement of particles during such unit operation. It is, therefore, desirable to further optimize such batch process conditions.
- the temperature of a single particle may not be uniform throughout the whole volume of that particle.
- the outer surface of the particle can heat faster than the core of the particle because the outer surface of the particle is in direct contact with the liquid fraction.
- thermal operations where the food is heated by other means such as infra-red, microwave, direct solar heating, radiation heating, inductive heating, or resistive heating.
- different types of particles will flow at different speeds within the liquid fraction as the entire food volume is being pumped through the process system. The particles that flow faster through the system will be subject to the heat treatment for less time.
- Aseptic thermal processing generally involves continuous sterilization of the food material using a suitable heat exchanger.
- the type of heat exchanger used is dictated by properties of the food material such as, for example, viscosity, particle size, and homogeneity.
- Some food products, such as juice, milk, and broth are homogeneous products and can be processed in plate heat exchangers.
- Other food products, such as soups having solid particles can be processed in heat exchangers that can handle particles, such as tubular heat exchangers.
- To be able to quantify the thermal process for an aseptic operation one would need to be able to identify the slowest heating particle at its core by assessing known characteristics of the particles, such as size, thermal conductivity, or density.
- the temperature of this particle can be known at the entrance and exit of the holding tubes associated with the heating system being used, to ensure proper thermal treatment as measured by a variety of decisional factors such as cook-value, lethality, etc.
- the art lacks a system that can monitor process conditions, such as direct temperature of the particles, in at least near real time during a continuous flow thermal treatment.
- U.S. Pat. No. 5,261,282 to Grabowski et al. discloses the use of implanted radio frequency transponders (in the form of RFID chips) to identify the residence times of simulated particles passing through a continuous processing system.
- U.S. Pat. No. 5,741,979 to Arndt et al. discloses the use of dipole antenna marker implants in the particles and microwave transducer detectors to measure particle residence times. Systems such as these, however, do not provide information pertaining to the temperature of the particles of interest, and cannot provide pertinent temperature process information relating to the slowest heating, fastest moving particle(s) of a system.
- Magnetic resonance imaging thermometry such as that disclosed by Kantt et al., “Temperature Mapping of Particles During Aseptic Processing with Magnetic Resonance Imaging”, Journal of Food Science, Volume 63, No. 2 (1998), is a non-obstructing and non-contact method, but is not sufficiently rapid enough to provide in-line real time measurement. Eight seconds were taken to image a single 64 ⁇ 64 cross-sectional temperature map. During this time, however, a considerable quantity of product can pass the detector unmonitored. Thus, the number of cross sections that can be observed is very limited, i.e., the detection of the initial location where the lethal thermal treatment is achieved may not be determined for all possible cases.
- thermoresistive implants include those implementing thermoresistive implants.
- One such example of this is the local magnetic temperature measurement approach disclosed in U.S. Pat. No. 5,722,317 to Ghiron et al., which is directed to the use of spherical paramagnetic particles for implants and detector coils around the pipes for sensors.
- This approach then implements a correlation between falling magnetic field strength and temperature increase to calculate the implant temperature from the signals of three sensor coils.
- the negative correlation between the measured magnetic field and the increasing temperature employed by this approach can cause a non-conservative temperature estimation, i.e., the resulting calculation can indicate a higher temperature than is actually present in the implant.
- magnetic field reduction can be caused by a variety of factors other than temperature increase in the implant, such as obstruction of detection by other materials (e.g., other food particles that are present).
- the magnetic thermometry approach can be highly susceptible to electro-magnetic interference, thereby greatly increasing the complexity of data collection or veracity of the collected data.
- ASIC application specific integrated circuits
- a preferred system for monitoring process conditions of a batch or continuous thermal treatment uses at least one application specific integrated circuit (ASIC) identifiable by radio frequency signal, coupled with at least one sensor capable of measuring at least one process condition.
- ASIC application specific integrated circuit
- the system further has at least one transceiver capable of communication with the circuit and at least one particle embedded with the circuit.
- the particle passes within a heterogeneous fluid having a plurality of constituent food particles subjected to direct thermal treatment, indirect thermal treatment, or other food processing treatments. Aseptic processes or non-aseptic processes can be employed, where appropriate.
- the circuit-embedded particle can be an actual constituent particle or a particle that simulates any number of constituent particle properties.
- Some currently preferred systems utilize a circuit placed within a native constituent particle.
- Other currently preferred systems utilize a circuit placed within a simulated particle for passing through the continuous processing system.
- Such circuits can be exposed at the surface of the particle, or can be positioned within the particle, preferably at least near the center of the particle, so that the particle emulates at least one physical, thermal, or dielectric characteristic of a native constituent particle.
- Dielectric properties can include, by way of example only, electric conductivity, magnetic permeability, relative dielectric constant, relative dielectric loss factor, and/or dielectric loss angle.
- Other preferred methods further include a data logging system for measuring and storing information pertaining to at least one process condition, as measured by at least one circuit-embedded particle.
- data logging can be along at least a portion of the process path, at-least one discrete location along the process path, or both. Accordingly, such data logging can be continuous, intermittent or combinations of both.
- Process conditions which can be measured using such a system can include, by way of example but without limitation, liquid pH, particulate temperature, liquid temperature, particulate speed, particulate location, particulate rotation, liquid speed, liquid nutrient characteristics, chemical characteristics, system pressure, particulate orientation, particulate position, and/or liquid salinity.
- Nutrient measurement can, for example, identify the amounts, concentrations, or ratios of sugar, protein, starch, and/or various vitamins or minerals that may be present in the liquid fraction of the heterogeneous fluid.
- Nutrient measurement can further include identifying the amounts, concentrations or ratios of various phytochemicals such as, but not limited to, phytosterols, carotenoids, tocotrienols, isoflavones, omega-3 fatty acids, phospholipids, nucleosides, nucleotides, glucosamine, ferulic acid, and/or coumaric acid.
- phytochemicals such as, but not limited to, phytosterols, carotenoids, tocotrienols, isoflavones, omega-3 fatty acids, phospholipids, nucleosides, nucleotides, glucosamine, ferulic acid, and/or coumaric acid.
- Particulate or liquid temperature measurements can be made from about ⁇ 40° C. to about 200° C., preferably between 100° C. to 140° C.
- Preferred systems can measure temperature with an accuracy of 1° C.
- System pressure measurements can be made up to 1 kpsi, preferably up to 150 kpsi.
- Yet another preferred method of measuring process conditions uses at least one application specific integrated circuit identifiable by radio frequency signal having at least one sensor capable of measuring at least one process condition, providing the application specific integrated circuit in a heterogeneous fluid, and measuring at least one process condition as determined by the circuit at-least one location within the process system.
- the location lies along at least a portion of the length of the process path, at a discrete cross-section of the process path which is subject to a transceiver, or both. In this way, for example, particulate orientation, particulate position, or both, can be measured relative to the process space.
- FIG. 1 is a schematic view showing various components of a thermal process system.
- FIG. 2 is a schematic view showing a circuit-embedded particle having an embedded transducer, as compared to an actual native food particle.
- FIG. 3 is a schematic view showing a planar cross section of a circuit-embedded particle, as compared to an actual native food particle.
- FIG. 4 is an enlarged, schematic view showing an embedded transducer.
- FIG. 5 is an exploded, schematic view showing a transceiver antenna coupled with a process tube.
- FIG. 6 is a schematic view showing measurement along at least a portion of the length of the process path, and measurement at a discrete spatial plane of the process path.
- ASIC Application specific integrated circuits
- PCBA printed circuit board assembly
- RFID identification
- an on-chip memory device can be used to store a unique ID.
- the sensing data communicated by the integrated circuit (IC) is accompanied by the ID of the chip.
- the communication protocol can be either wired or wireless.
- RFID radio frequency identification
- an antenna connected to the IC is used to receive and send the radio signals to a transceiver.
- a transceiver Such a unit, including the antenna, is often referred to as a transducer.
- FIG. 1 shows an apparatus 1 which is exemplary of a continuous cooking process in which food particles such as vegetables in a garnished soup are sterilized in a flowing stream. It should be understood that the apparatus 1 shown in FIG. 1 is illustrative only, and that any of a variety of different systems, capable of processing any of a variety of different food products, can similarly be implemented in accordance with the present invention.
- a soup is blended in a blending kettle 2 , and the blended soup is pumped into the tubes of a tubular heat exchanger through a timing pump 3 .
- the pump speed can be adjusted using a variable frequency drive to maintain a prescribed flowrate, which can be measured using a flowmeter 4 .
- the blended soup enters the sterilizing heat exchanger through the discharge of the timing pump 3 , passing through a heating section 5 , a holding section 6 , and a cooling section 7 , and is then filled into a container.
- the overall holding tube length and the flowrate of product can be adjusted to reach a predetermined holding time.
- a positive displacement pump 25 is preferably placed between the discharge of the cooling section 7 and downstream filling equipment, and can be used to regulate backpressure throughout the various tubes by controlling the speed of the pump 25 .
- a circuit-embedded food particle 8 which can pass through the apparatus 1 during active preparation of the food product.
- the circuit-embedded food particle 8 is preferably configured to monitor the progress of the slowest heating and fastest flowing food particle passing through the apparatus 1 , and can either be implemented using a native food particle or as a simulated food particle formed in the shape of a native food particle.
- the circuit-embedded food particle 8 can incorporate encapsulated transducer 10 embedded in a native constituent food particle or a simulated food particle, preferably at the center of the food particle 8 or at least near the center of the food particle 8 .
- the transducer 10 includes a printed circuit board assembly (PCBA) 18 that has an embedded ASIC with an integrated sensor for monitoring a desired parameter, such as temperature and/or pressure.
- PCBA printed circuit board assembly
- an antenna 19 is coupled with the PCBA, and is preferably air-coiled around the PCBA.
- the transducer 10 is also preferably potted with a suitable insulation material 17 , as is otherwise known and used in the industry.
- the transducer 10 is preferably surrounded by an encapsulation material 9 which can be chosen to match certain physical, thermal and/or dielectric properties of a native food particle including, but not limited to, geometry, volume, density, thermal diffusivity, thermal conductivity, specific heat capacity, and/or electric conductivity.
- the fastest flowing particle in the process system will generally be the one that has neutral buoyancy with respect to the liquid stream.
- a practical way of achieving neutral buoyancy is by matching the density of the particle to the density of the liquid.
- the density of the encapsulation material 9 of a simulated food particle should be chosen so that the density and volume of the transducer 10 is taken into account.
- the first step is to determine which native food particle will be heating slowest at its coldest spot. This can be determined experimentally by exposing all the actual native food particles to the same boundary conditions while monitoring their temperature at their center points. This can also be determined theoretically if the thermal diffusivities of all the actual native food particles are known. In this case, a finite element modeling (FEM) software can be used to determine the slowest heating food particle. Once the slowest heating food particle is determined, the thermal diffusivity of the encapsulation material 9 can be determined.
- FEM finite element modeling
- both the slowest heating food particle 11 and the circuit-embedded food particle 8 are shown in FIG. 2 .
- the encapsulated transducer 10 is placed in the middle and the encapsulant 9 is surrounding the transducer 10 .
- the particle shape is not an irregular shape, symmetry can be used to determine thermal diffusivity of the encapsulation material.
- the slowest heating food particle 11 , and the circuit-embedded food particle 8 have the shape of a rectangular prism, such as might be encountered, for example, with a cubed carrot. It should be understood that the shape of the circuit-embedded food particle 8 can be varied, as desired, and can include both regular and irregular shapes.
- FIG. 3 shows both a simulated food particle 15 and a native constituent food particle 16 which have been cut in half along all three planes to make use of symmetry.
- the center point of the food particle 12 is its coldest spot.
- the corresponding point 13 is within the transducer volume and the heat transfer mechanism within the transducer volume is complex due to its heterogeneous nature. Therefore, a conservative assumption is made that the temperature measured by the transducer 10 is equal to the temperature at the surface of the transducer 10 having the shortest distance to the outer surface of the encapsulant 9 .
- the distance 14 is the shortest distance.
- the thermal diffusivity of the encapsulant 9 should be chosen so that when the food particle 16 and the simulated food particle 15 are exposed to the same boundary condition, the temperature at the point 12 will be the same as or slightly higher than the actual temperature at the location 25 . This can be determined by trial and error using FEM, or other suitable software.
- Thermal diffusivity is a function of thermal conductivity, density and specific heat capacity, and can be calculated using the following formula:
- ⁇ k ⁇ ⁇ ⁇ C p
- ⁇ the thermal diffusivity
- k the thermal conductivity
- ⁇ the density
- C p the specific heat capacity
- the encapsulated transducer 10 is placed at least near the center of the encapsulation. Still further, the encapsulated transducer 10 can be exposed at the surface of the encapsulation, or within the encapsulation, as desired.
- the circuit-embedded food particle 8 can be detected using a transceiver antenna 24 in proximity to the circuit-embedded food particle 8 at certain points. Since the encapsulated transducer 10 will be traveling in the process tubes of the apparatus 1 under the influence of the timing pump 3 , and ending with the filling station, the transceiver antenna 24 is preferably positioned in proximity to the product tubes of the apparatus 1 at selected locations. Because conventional process tubing used in the food industry is made of stainless steel, which will block radio frequency (RF) signals, the product tubes are preferably provided with an equivalent RF transparent tube, such as a glass or polymer tube, wherever an RF antenna is to be placed. The RF transparent tube material chosen should also be resistant to high temperature and pressure. By way of example, FIG. 5 shows stainless steel (SS) ends 20 in connection with an RF signal transparent tube 21 .
- SS stainless steel
- FIG. 5 further illustrates an example of a suitable RF transceiver antenna 24 .
- At least one antenna structure 23 can be used within a single RF transceiver antenna 24 .
- the antenna structure 23 includes a drive antenna for providing power to the transducer 10 and a receive antenna for receiving the signal back from the transducer 10 , to develop an antenna structure 23 which operates as a transceiver.
- the drive and receive antennas are coiled around a hollow tube 22 having a slightly larger diameter than the diameter of the product tube that receives it.
- the hollow tube 22 is then preferably housed in a waterproof box 26 to protect it from the environment.
- a transceiver antenna 24 is positioned around the process tubes of the apparatus 1 wherever a condition-measuring food particle 8 needs to be monitored (e.g., for ID and temperature).
- FIG. 1 shows an illustrative embodiment including five transceiver antennas 24 , although other configurations are equally possible.
- transceiver antennas 24 facilitates proper repeatable communication between each transceiver antenna 24 and an encapsulated transducer 10 traveling within a food mixture passing through the process tubes and at the flow rates normally observed in food sterilization applications.
- These locations are preferably along at least a portion of the length of the process path, at a discrete cross-section of the process path subject to a transceiver, or both. Accordingly, such locations can be at the entrance of the heating section 5 , at the middle of the heating section 5 , at the entrance of the holding section 6 (exit of the heating section 5 ), at the exit of the holding section 6 (entrance of the cooling section 7 ) and at the exit of the cooling section 7 , as is shown in FIG. 1 , or in any other desired combination.
- the number and location of transceiver antennas 24 can be varied, as desired.
- a data logging system is preferably provided for measuring, and optionally storing or recording, information pertaining to at least one process condition as measured by at least one circuit-embedded food particle 8 .
- Such data logging can be continuous, intermittent or combinations thereof, and further location and data logging embodiments are envisioned.
- process information can be recorded for certain portions of the process path and read at prescribed locations, or recorded, and stored, for a majority of the process path and read at a transceiver after process completion and at some distance from the process space.
- FIG. 6 Certain location and data logging embodiments are shown in FIG. 6 , and in FIG. 1 .
- a condition-measuring food particle 8 passes by a transceiver antenna 24 , the time of passage, temperature of the transducer 10 and the ID of the transducer 10 are communicated to a computer 28 for real time data monitoring and storage using, for example, a communication module 27 capable of communicating with a corresponding wireless transceiver 29 .
- wired communications can similarly be used.
- Each transceiver antenna 24 is preferably connected to a separate communication module 27 .
- the computer When data is transmitted to the computer 28 by a communication module 27 , the computer captures the ID of the transceiver antenna 24 that the transducer 10 is then passing through. The computer 28 can also capture the identification (ID) of the communication module 27 , if desired.
- ID identification
- This data enables the creation of a time-temperature-location history for each and every transducer 10 that passed through the process system.
- the compiled data can then be used to analyze the variation in residence time (RTD) and temperature for similar simulation particles. This can be used to develop a scheduled process for sterilization or pasteurization of food products, preferably making use of lethality accumulated in the heating section 5 of the apparatus 1 , as well as the lethality accumulated in the holding section 6 .
- the measured process condition can be used to provide at least near real-time feedback such that the timing pump 3 or backpressure pump 25 can be controlled to vary the process time experienced by a circuit-embedded food particle 8 .
- the timing pump 3 or backpressure pump 25 can be controlled to vary the process time experienced by a circuit-embedded food particle 8 .
- certain embodiments of the present invention may be suitable for monitoring bakery processes for the manufacture of baked goods such as pastries, cookies, breads and the like, in continuous or batch oven operations.
- Embedded particles 8 can be placed at or below the surface of the baked goods during operations. In this way, the data collected could be used to optimize the thermal processes such as heating, cooling, and freezing cycles, and to identify thermal variability such as hot and cold spots in the product and/or the oven.
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- General Preparation And Processing Of Foods (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
- Dairy Products (AREA)
- Control Of Temperature (AREA)
Abstract
Description
where α is the thermal diffusivity, k is the thermal conductivity, ρ is the density, and Cp is the specific heat capacity. As the density of the encapsulation material 9 was determined previously, the ratio of thermal conductivity to the specific heat capacity can be calculated using the results of the FEM analysis. The way that the encapsulation material will be applied depends on the material chosen. It is possible to use different potting materials and, therefore, different application methods for the encapsulation. Regardless of the manner in which the encapsulation material 9 is applied, the
Claims (35)
Priority Applications (7)
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US12/803,385 US8463423B2 (en) | 2010-06-25 | 2010-06-25 | Methods and systems for measurement and control of process parameters |
CA2744478A CA2744478C (en) | 2010-06-25 | 2011-06-23 | Methods and systems for measurement and control of process parameters |
MX2011006835A MX2011006835A (en) | 2010-06-25 | 2011-06-23 | Methods and systems for measurement and control of process parameters. |
AU2011203087A AU2011203087B2 (en) | 2010-06-25 | 2011-06-24 | Methods and systems for measurement and control of process parameters |
EP11005143.0A EP2400282B1 (en) | 2010-06-25 | 2011-06-24 | Methods and systems for measurement and control of process parameters |
CN2011101802114A CN102331277A (en) | 2010-06-25 | 2011-06-24 | Methods and systems for measurement and control of process parameters |
ES11005143.0T ES2574665T3 (en) | 2010-06-25 | 2011-06-24 | Procedures and systems for measuring and controlling process parameters |
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US12/803,385 US8463423B2 (en) | 2010-06-25 | 2010-06-25 | Methods and systems for measurement and control of process parameters |
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US8463423B2 true US8463423B2 (en) | 2013-06-11 |
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EP3004825A1 (en) | 2013-05-31 | 2016-04-13 | Tetra Laval Holdings & Finance SA | Determining the degree of heat treatment of a liquid product |
EP2974603B1 (en) * | 2014-07-16 | 2017-02-15 | Consiglio Nazionale Delle Ricerche | A pasteurizer for continuously treating small volumes of liquid foods |
US10359319B2 (en) | 2014-12-02 | 2019-07-23 | HBC Holding Company, LLC | Method for design and control of properties of simulated food particles for process monitoring and validation of aseptically processed multiphase foods and biomaterials |
EP3332651A1 (en) * | 2016-12-08 | 2018-06-13 | Tetra Laval Holdings & Finance S.A. | Heat treating liquid food with particles |
US11612273B2 (en) | 2016-12-15 | 2023-03-28 | Koninklijke Philips N.V. | Monitoring apparatus and a food processing device using the same |
EP3537124B1 (en) * | 2018-03-08 | 2021-01-27 | ABB Schweiz AG | Method and system for non-intrusive determining of a temperature of a fluid flowing through a conduit section |
ES2735426A1 (en) * | 2018-06-18 | 2019-12-18 | Cunha Rodriguez Manuel Da | Procedure to prepare and preserve dough for the preparation of cakes and the like (Machine-translation by Google Translate, not legally binding) |
EP3786745B1 (en) * | 2019-08-28 | 2023-02-22 | Siemens Aktiengesellschaft | Identification of deviations between an actual system and a digital twin |
CN110567627B (en) * | 2019-10-25 | 2024-05-17 | 中国科学技术大学 | A device and method for measuring the levitation force of an ultrasonic levitator |
US11724239B2 (en) * | 2019-12-20 | 2023-08-15 | Klueber Lubrication Muenchen Se & Co. Kg | Frictional temperature regulation of a fluid |
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2011
- 2011-06-23 CA CA2744478A patent/CA2744478C/en not_active Expired - Fee Related
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- 2011-06-24 CN CN2011101802114A patent/CN102331277A/en active Pending
- 2011-06-24 ES ES11005143.0T patent/ES2574665T3/en active Active
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MX2011006835A (en) | 2012-01-02 |
CN102331277A (en) | 2012-01-25 |
EP2400282B1 (en) | 2016-04-06 |
EP2400282A2 (en) | 2011-12-28 |
ES2574665T3 (en) | 2016-06-21 |
CA2744478C (en) | 2018-02-13 |
EP2400282A3 (en) | 2014-08-13 |
CA2744478A1 (en) | 2011-12-25 |
US20110320060A1 (en) | 2011-12-29 |
AU2011203087B2 (en) | 2015-07-30 |
AU2011203087A1 (en) | 2012-01-19 |
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