US7537633B2 - Filter unit for filtering particles contained in exhaust gas of an internal combusting engine - Google Patents

Filter unit for filtering particles contained in exhaust gas of an internal combusting engine Download PDF

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US7537633B2
US7537633B2 US10/564,838 US56483806A US7537633B2 US 7537633 B2 US7537633 B2 US 7537633B2 US 56483806 A US56483806 A US 56483806A US 7537633 B2 US7537633 B2 US 7537633B2
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filter unit
filter
inlet
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US20060168928A1 (en
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Sébastien Bardon
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Saint Gobain Centre de Recherche et dEtudes Europeen SAS
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418Honeycomb filters
    • B01D46/2451Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
    • B01D46/247Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure of the cells
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418Honeycomb filters
    • B01D46/2451Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418Honeycomb filters
    • B01D46/2451Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
    • B01D46/2482Thickness, height, width, length or diameter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418Honeycomb filters
    • B01D46/2451Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
    • B01D46/2484Cell density, area or aspect ratio
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418Honeycomb filters
    • B01D46/2451Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
    • B01D46/2486Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure characterised by the shapes or configurations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • B01D46/2418Honeycomb filters
    • B01D46/2498The honeycomb filter being defined by mathematical relationships
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/022Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/022Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
    • F01N3/0222Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being monolithic, e.g. honeycombs
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/06Ceramic, e.g. monoliths
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/30Honeycomb supports characterised by their structural details
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/30Honeycomb supports characterised by their structural details
    • F01N2330/48Honeycomb supports characterised by their structural details characterised by the number of flow passages, e.g. cell density
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S55/00Gas separation
    • Y10S55/05Methods of making filter
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S55/00Gas separation
    • Y10S55/10Residue burned
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S55/00Gas separation
    • Y10S55/30Exhaust treatment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24149Honeycomb-like

Definitions

  • the invention relates to a filter unit for filtering particles contained in the exhaust gas of an internal combustion engine, in particular of the diesel type, and to a filter body including at least one filter unit according to the invention.
  • Porous honeycomb structures are used as filter bodies for filtering particles emitted by diesel vehicles.
  • These filter bodies are generally made of ceramic (cordierite, silicon carbide, etc.). They may be monolithic or consist of separate units. In the latter case, the units are cemented together by means of a ceramic cement. The whole is then machined to the required section, which is generally circular or elliptical.
  • the filter body includes a plurality of passages. It is inserted into a metal enclosure. Each passage is blocked at one or the other of its ends. There are therefore inlet passages and outlet passages. The exhaust gases are therefore constrained to pass through the lateral walls of the inlet passages into the outlet passages; thus particles and soot are deposited in the filter body.
  • soot accumulates in the passages of the filter body, which increases the head loss caused by the filter and degrades the performance of the engine. For this reason, the filter body must be regenerated regularly, conventionally after about 7 to 10 hours of operation, when the head loss has reached a value of approximately 150 dPa (for an engine of about 2 liters cubic capacity driving on a motorway with a filter body of approximately 4 liters).
  • Regeneration consists in oxidizing the soot. To this end, it is necessary to heat the soot since the temperature of the exhaust gases is of the order of 300° C. whereas the flash point temperature of the soot is more of the order of 600° C., under normal operating conditions. Despite such regeneration, combustion residues remain in the filter body. Accordingly, the head loss induced by the filter body after regeneration is always higher than that induced by the filter body before regeneration. This phenomenon of clogging continues on each regeneration and it is necessary for the dealer to clean the filter block completely, for example every 80 000 km. This cleaning constitutes a drawback to the use of filter bodies.
  • FR 2 473 113 proposes a filter body that can be produced by extrusion and has inlet passages of greater cross section than the outlet passages.
  • the authors indicate a filtering area of the filter unit of 7.89 cm 2 /cm 3 (i.e. 0.789 cm 2 /l) with a constant inlet passage cross section less than 12.9 mm 2 and a wall thickness less than or equal to 0.7 mm.
  • the filter body described in FR 2 473 113 induces a high head loss, which means that the filter body must be regenerated frequently. It is therefore difficult to envisage the industrial use of this filter body.
  • the invention relates more particularly to a filter unit for filtering particles contained in the exhaust gases of an internal combustion engine, comprising interleaved sets of adjacent inlet passages and outlet passages, said inlet and outlet passages being in fluid communication through their lateral walls, said lateral walls having, in cross section, an undulation determined to increase the overall volume of said inlet passages at the expense of that of the outlet passages, and the overall volume of the inlet passages being greater than that of the outlet passages, noteworthy in that:
  • the invention also relates to a filter body intended for a particle filter that is noteworthy in that it includes at least one filter unit according to the invention.
  • FIG. 1 a is a partial view of the front face (i.e. that on which the exhaust gases impinge) of a prior art filter unit
  • FIG. 1 b is a view of that unit in section taken along the line AA in FIG. 1 a
  • FIG. 1 c is a view in cross section of an extrusion die for producing the above filter unit
  • FIGS. 2 a to 2 c are views analogous to those of FIGS. 1 a to 1 c , respectively, and show a first embodiment of a filter body of the invention
  • FIG. 3 is a partial view of the front face of a second embodiment of a filter unit of the invention.
  • FIG. 4 is a graph representing the head loss as a function of the time of use for various new, “clean”, tested filter bodies, and
  • FIG. 5 is a graph representing the head loss as a function of the time of use for various tested filter bodies in which the combustion residues occupy a volume corresponding to 50% of the volume of the inlet passages of the reference filter, which corresponds to a distance traveled by the vehicle of approximately 80 000 km. Such filter bodies are referred to as “clogged”. The residues are generally in the far end of the inlet passage.
  • FIGS. 1 to 3 correspond to partial views of filter units and may be regarded as a partial view of a monolithic filter body or a partial view of a filter body formed by assembling filter units.
  • the thickness of the walls between the passages is not to scale and is not limiting on the invention.
  • FIG. 1 a is a diagram of the front face of a filter unit currently used to trap particles contained in the exhaust gases of motor vehicles propelled by a diesel engine.
  • This filter unit has identical passages whose cross section is square and of constant size throughout the length of the filter body. On this front face, one in two passages is blocked. The passages 1 and 2 are open and therefore constitute inlet passages. The passages 3 and 4 are blocked and therefore constitute outlet passages.
  • FIG. 1 b is a view in longitudinal section taken along the line AA in FIG. 1 a . The flow F of exhaust gases enters the filter unit via the inlet passages and then passes through the lateral walls of the passages into the outlet passages.
  • FIG. 1 c is a view in cross section of the extrusion die used to fabricate the filter units used at present and represented in FIG. 1 a . In this view, the solid lines represent machined openings through which the ceramic can pass.
  • FIG. 2 a is a diagram of the front face of a first embodiment of a filter unit of the invention.
  • the passages 10 and 11 are open and constitute inlet passages.
  • the passages 12 and 13 are blocked and constitute outlet passages.
  • the passages are arranged in an array of passages having a triangular cross section that is deformed to increase the overall volume of the inlet passages at the expense of that of the outlet passages.
  • a non-plane intermediate wall between an inlet passage and an outlet passage may be concave on the side of the inlet passage, as shown in FIG. 2 a , and convex on the side of the outlet passage.
  • FIG. 2 b is a view in section taken along the line AA in FIG. 2 a .
  • the flow F of exhaust gases enters the filter body via the inlet passages and passes through the walls of the passages into the outlet passages. Because of the increase in the overall volume of the inlet passages referred to above, the area available on the walls of the inlet passages, or “filtering area”, is increased to the detriment of that of the outlet passages compared to a prior art filter body such as that shown in FIG. 1 .
  • All of the area of the inlet passages is advantageously used to filter the exhaust gases, as there are no portions of one or more inlet passages that open into other inlet passages, such portions being of no utility for filtration since the exhaust gases can pass through them in both directions.
  • the inlet passages and outlet passes are preferably parallel and straight. It is therefore possible to produce the filter unit of the invention by extrusion, which is advantageous.
  • FIG. 2 c is a view in cross section of the extrusion die used to produce the filter unit shown in FIG. 3 a ; in this view the solid lines represent machined openings through which the ceramic may pass.
  • This die is used to fabricate passages of constant cross section throughout the length of the filter unit, which facilitates extruding them.
  • the passages are straight along the length of the filter body. Accordingly, in longitudinal section (see FIG. 2 b ), the passages have a constant cross section throughout their length L. This facilitates the fabrication of the filter units.
  • the inlet passages have a greater cross section than the outlet passages in order to increase the volume available for storing soot.
  • the inlet passages and the outlet passages are arranged with respect to each other so that all of the gas filtered by any inlet passage passes into outlet passages adjacent that inlet passage, which optimizes the surface area available for a given filter unit volume.
  • FIG. 3 is a diagram of the front face of another embodiment of a filter unit of the invention.
  • the passages 10 and 11 are open and constitute inlet passages.
  • the passages 12 and 13 are blocked and constitute outlet passages.
  • the passages are organized in an array of passages having a square cross section that is deformed to increase the overall volume of the inlet passages at the expense of that of the outlet passages.
  • the inlet and outlet channels are disposed alternately, forming a checkerboard structure.
  • the lateral wall 14 of an inlet passage 11 is therefore formed of four lateral wall portions 14 a - 14 d separating the interior volume of that passage from the interior volumes of the four respective adjacent outlet passages.
  • a non-plane intermediate wall 15 between two horizontal rows R 1 and R 2 , and/or two vertical rows, of passages is preferably concave on the side of the inlet passages and convex on the side of the outlet passages.
  • the intermediate wall 15 preferably has an undulating or “wavy” shape in cross section, the wall 15 undulating by substantially one half of an undulation length across the width of a passage.
  • the “length” of an undulation is the distance between two points of the undulation located at the same height with the same direction of variation of slope. In the case of a periodic undulation, the “length” of the undulation is called the “period”.
  • the undulation is preferably periodic, but the amplitude of the undulations may be constant or variable.
  • the amplitude is preferably constant. It is also preferable if the undulation has a sinusoidal shape whose half-period is equal to the pitch “p” of the array of passages, as shown in FIG. 3 .
  • ratio of asymmetry refers to the ratio between the amplitude “h” and the half-length of said undulation (or between the amplitude “h” and the half-period in the case of a periodic undulation).
  • Table 1 The following examples summarized in table 1 are provided by way of illustration and are not limiting on the invention.
  • FIGS. 4 and 5 represent curves of the increasing head loss as a function of time corresponding to certain examples from table 1, with clean and clogged filters, respectively.
  • the filter bodies that were tested were produced by assembling 16 filter units fastened together by means of a joint 1 mm thick. These filter bodies were cylindrical with a diameter of 144 mm and a length of 9 inches (228.6 mm).
  • the passages were of the type represented in FIG. 4 , the walls having a substantially sinusoidal profile and the outlet and inlet passages having a cross section of constant area through the length L of the filter body.
  • the exhaust gases were introduced into the inlet passages of the filter bodies under test at a temperature of 250° C. and a flowrate of 320 m 3 /hour.
  • the concentration of particles in the exhaust gases was 2.2*10 ⁇ 5 kg/m 3 .
  • the concentration of combustion residues in the inlet passages was 1.8*10 ⁇ 9 m 3 /m 3 of exhaust gas.
  • the reference example “Ref” corresponds to a filter constituted by assembling 16 filter units fastened together with a joint 1 mm thick.
  • This filter was cylindrical with a diameter of 144 mm and a length of 9 inches (228.6 mm).
  • the passages were of the type represented in FIG. 1 , the outlet and inlet passages having a square cross section of constant area through the length L of the filter body.
  • the pitch of the array was 1.8 mm and the thickness of the walls was 350 ⁇ m.
  • hydroaulic diameter used in relation to a cross section or a passage refers to the ratio between four times the section of the passage and the perimeter of the passage.
  • the passage density is expressed as a number of passages per square inch (cells per square inch (cpsi)).
  • Ve denotes the total volume of the inlet passages, Vs the total volume of the outlet passages.
  • filtering area refers to the area of the walls of the inlet passages through which the flow of gas to be filtered can pass.
  • the filtering area is evaluated in square meters per liter of filter unit.
  • the measured time “t” in minutes to achieve a head loss “dP” of x mbar is denoted t /x .
  • the filtering area is not the only criterion, as is shown by comparing example 15 and the reference example. That comparison shows that, according to the invention, a higher ratio r has the advantage of compensating a lower filtering area when the filters are clogged.
  • a high ratio r means a greater volume in the inlet passages for storing the combustion residues.
  • the proportion of the filtering area that is ineffective because it is covered by the combustion residues is therefore lower.
  • the induced head loss is therefore lower. Between two regenerations, the head loss induced by the filter body therefore increases more slowly.
  • the large volume in the inlet passages can store a greater quantity of combustion residues.
  • the number of regenerations before removing/refitting the filter can therefore be increased.
  • an increase in the ratio of asymmetry implies an increase in the storage capacity of the inlet passages and an increase in the filtering area of the unit.
  • the ratio of asymmetry must not be increased excessively, as this could reduce the section of the outlet passages to the point of a prejudicial increase in the head loss.
  • the ratio of asymmetry is less than 20%, preferably less than 15%, more preferably less than 12%, and greater than 5%, preferably greater than 6%.
  • the time between two filter body demounting/cleaning operations is therefore increased not only because of reduced residual clogging of the filtering area by combustion residues after each regeneration, which slows down clogging by soot between two regenerations, but also because a greater number of regenerations is possible, the combustion residue storage volume being greater.
  • the motorist can therefore travel a greater distance without performing any maintenance on the filter.
  • Table 1 shows that if the hydraulic diameter of the outlet passages is very small, the head loss induced by the clean filter body is much too high. This may prove unacceptable since the official power rating of an engine takes account of the exhaust line.
  • the hydraulic diameter of the outlet passages must be greater than or equal to 0.9 mm and preferably from 0.95 to 1.4 mm.
  • the filter unit could have any shape and any arrangement of the passages.
  • cross section of the passages is not limited to the shapes described.

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  • Physics & Mathematics (AREA)
  • Geometry (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Filtering Of Dispersed Particles In Gases (AREA)
  • Processes For Solid Components From Exhaust (AREA)
  • Filtering Materials (AREA)

Abstract

The inventive filter unit for filtering particles contained in exhaust gas of an internal combusting engine comprises sets of imbricated input channels (10, 11) and adjacent output channels (12, 13) which are fluidly communicating by means of the lateral walls thereof. Said lateral walls are cross-sectionally provided with a corrugation which is determined in such a way that the total volume of the input channels (10, 11) is increased with respect to that of the output channels (12, 13), whereby the total volume (Ve) of the input channels (10, 11) being greater than that (Vs) of the output channels (12, 13).

Description

The invention relates to a filter unit for filtering particles contained in the exhaust gas of an internal combustion engine, in particular of the diesel type, and to a filter body including at least one filter unit according to the invention.
BACKGROUND OF THE INVENTION
Porous honeycomb structures are used as filter bodies for filtering particles emitted by diesel vehicles. These filter bodies are generally made of ceramic (cordierite, silicon carbide, etc.). They may be monolithic or consist of separate units. In the latter case, the units are cemented together by means of a ceramic cement. The whole is then machined to the required section, which is generally circular or elliptical. The filter body includes a plurality of passages. It is inserted into a metal enclosure. Each passage is blocked at one or the other of its ends. There are therefore inlet passages and outlet passages. The exhaust gases are therefore constrained to pass through the lateral walls of the inlet passages into the outlet passages; thus particles and soot are deposited in the filter body.
After a certain time of use, soot accumulates in the passages of the filter body, which increases the head loss caused by the filter and degrades the performance of the engine. For this reason, the filter body must be regenerated regularly, conventionally after about 7 to 10 hours of operation, when the head loss has reached a value of approximately 150 dPa (for an engine of about 2 liters cubic capacity driving on a motorway with a filter body of approximately 4 liters).
Regeneration consists in oxidizing the soot. To this end, it is necessary to heat the soot since the temperature of the exhaust gases is of the order of 300° C. whereas the flash point temperature of the soot is more of the order of 600° C., under normal operating conditions. Despite such regeneration, combustion residues remain in the filter body. Accordingly, the head loss induced by the filter body after regeneration is always higher than that induced by the filter body before regeneration. This phenomenon of clogging continues on each regeneration and it is necessary for the dealer to clean the filter block completely, for example every 80 000 km. This cleaning constitutes a drawback to the use of filter bodies.
FR 2 473 113 proposes a filter body that can be produced by extrusion and has inlet passages of greater cross section than the outlet passages. The authors indicate a filtering area of the filter unit of 7.89 cm2/cm3 (i.e. 0.789 cm2/l) with a constant inlet passage cross section less than 12.9 mm2 and a wall thickness less than or equal to 0.7 mm.
However, the filter body described in FR 2 473 113 induces a high head loss, which means that the filter body must be regenerated frequently. It is therefore difficult to envisage the industrial use of this filter body.
There is therefore a need for a filter body having a low head loss throughout its service life and therefore necessitating less frequent cleaning. The invention aims to meet that need.
SUMMARY OF THE INVENTION
The invention relates more particularly to a filter unit for filtering particles contained in the exhaust gases of an internal combustion engine, comprising interleaved sets of adjacent inlet passages and outlet passages, said inlet and outlet passages being in fluid communication through their lateral walls, said lateral walls having, in cross section, an undulation determined to increase the overall volume of said inlet passages at the expense of that of the outlet passages, and the overall volume of the inlet passages being greater than that of the outlet passages, noteworthy in that:
    • the hydraulic diameter of said outlet passages is from 0.9 to 1.4 mm, preferably greater than 0.95 mm,
    • the ratio r of the overall volume of the inlet passages to the overall volume of the outlet passages is from 1.15 to 4, preferably greater than 1.35 and/or less than 3,
    • the filtering area is from 0.825 m2 to 1.4 m2 per liter of said filter unit, preferably greater than 0.92 m2
    • the ratio of asymmetry of said undulation is less than 20%.
As will emerge in more detail hereinafter, this significantly reduces the head loss induced by the filter unit and therefore reduces the frequency of regeneration of the filter body of which it forms part.
According to other preferred features of the invention:
    • said outlet passages have a cross section of constant area throughout the length of said filter unit;
    • said inlet and outlet passages are straight and parallel;
    • said inlet and outlet passages are arranged relative to each other so that all of the gas filtered by any inlet passage passes into outlet passages adjacent said inlet passage;
    • said undulation has a sinusoidal shape in cross section; the ratio of asymmetry of said undulation is less than 15%, preferably less than 12%, and/or greater than 5%, preferably greater than 6%;
    • said undulation is periodic and a half-period of said undulation extends over the width of one of said channels;
    • said inlet and outlet channels are disposed alternately in any horizontal row or vertical row of said unit, thus forming a checkerboard structure on the front or rear face of the unit.
The invention also relates to a filter body intended for a particle filter that is noteworthy in that it includes at least one filter unit according to the invention.
BRIEF DESCRIPTION OF THE DRAWINGS
The following description with reference to the appended drawings and the examples explain the invention and its advantages. In the drawings:
FIG. 1 a is a partial view of the front face (i.e. that on which the exhaust gases impinge) of a prior art filter unit, FIG. 1 b is a view of that unit in section taken along the line AA in FIG. 1 a, and FIG. 1 c is a view in cross section of an extrusion die for producing the above filter unit,
FIGS. 2 a to 2 c are views analogous to those of FIGS. 1 a to 1 c, respectively, and show a first embodiment of a filter body of the invention,
FIG. 3 is a partial view of the front face of a second embodiment of a filter unit of the invention,
FIG. 4 is a graph representing the head loss as a function of the time of use for various new, “clean”, tested filter bodies, and
FIG. 5 is a graph representing the head loss as a function of the time of use for various tested filter bodies in which the combustion residues occupy a volume corresponding to 50% of the volume of the inlet passages of the reference filter, which corresponds to a distance traveled by the vehicle of approximately 80 000 km. Such filter bodies are referred to as “clogged”. The residues are generally in the far end of the inlet passage.
All of FIGS. 1 to 3 correspond to partial views of filter units and may be regarded as a partial view of a monolithic filter body or a partial view of a filter body formed by assembling filter units.
In the figures, the thickness of the walls between the passages is not to scale and is not limiting on the invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
FIG. 1 a is a diagram of the front face of a filter unit currently used to trap particles contained in the exhaust gases of motor vehicles propelled by a diesel engine. This filter unit has identical passages whose cross section is square and of constant size throughout the length of the filter body. On this front face, one in two passages is blocked. The passages 1 and 2 are open and therefore constitute inlet passages. The passages 3 and 4 are blocked and therefore constitute outlet passages. FIG. 1 b is a view in longitudinal section taken along the line AA in FIG. 1 a. The flow F of exhaust gases enters the filter unit via the inlet passages and then passes through the lateral walls of the passages into the outlet passages. FIG. 1 c is a view in cross section of the extrusion die used to fabricate the filter units used at present and represented in FIG. 1 a. In this view, the solid lines represent machined openings through which the ceramic can pass.
FIG. 2 a is a diagram of the front face of a first embodiment of a filter unit of the invention. The passages 10 and 11 are open and constitute inlet passages. The passages 12 and 13 are blocked and constitute outlet passages. The passages are arranged in an array of passages having a triangular cross section that is deformed to increase the overall volume of the inlet passages at the expense of that of the outlet passages. Thus a non-plane intermediate wall between an inlet passage and an outlet passage may be concave on the side of the inlet passage, as shown in FIG. 2 a, and convex on the side of the outlet passage.
FIG. 2 b is a view in section taken along the line AA in FIG. 2 a. The flow F of exhaust gases enters the filter body via the inlet passages and passes through the walls of the passages into the outlet passages. Because of the increase in the overall volume of the inlet passages referred to above, the area available on the walls of the inlet passages, or “filtering area”, is increased to the detriment of that of the outlet passages compared to a prior art filter body such as that shown in FIG. 1.
All of the area of the inlet passages is advantageously used to filter the exhaust gases, as there are no portions of one or more inlet passages that open into other inlet passages, such portions being of no utility for filtration since the exhaust gases can pass through them in both directions.
The inlet passages and outlet passes are preferably parallel and straight. It is therefore possible to produce the filter unit of the invention by extrusion, which is advantageous.
FIG. 2 c is a view in cross section of the extrusion die used to produce the filter unit shown in FIG. 3 a; in this view the solid lines represent machined openings through which the ceramic may pass. This die is used to fabricate passages of constant cross section throughout the length of the filter unit, which facilitates extruding them.
The passages are straight along the length of the filter body. Accordingly, in longitudinal section (see FIG. 2 b), the passages have a constant cross section throughout their length L. This facilitates the fabrication of the filter units.
The inlet passages have a greater cross section than the outlet passages in order to increase the volume available for storing soot. The inlet passages and the outlet passages are arranged with respect to each other so that all of the gas filtered by any inlet passage passes into outlet passages adjacent that inlet passage, which optimizes the surface area available for a given filter unit volume.
FIG. 3 is a diagram of the front face of another embodiment of a filter unit of the invention. The passages 10 and 11 are open and constitute inlet passages. The passages 12 and 13 are blocked and constitute outlet passages. The passages are organized in an array of passages having a square cross section that is deformed to increase the overall volume of the inlet passages at the expense of that of the outlet passages. In any horizontal row (x) or vertical row (y), the inlet and outlet channels are disposed alternately, forming a checkerboard structure. The lateral wall 14 of an inlet passage 11 is therefore formed of four lateral wall portions 14 a-14 d separating the interior volume of that passage from the interior volumes of the four respective adjacent outlet passages.
A non-plane intermediate wall 15 between two horizontal rows R1 and R2, and/or two vertical rows, of passages (and thus formed by a set of portions of lateral walls 16 1 to 16 8 of those passages) is preferably concave on the side of the inlet passages and convex on the side of the outlet passages.
Along a horizontal row (along the x axis) or a vertical row (along the y axis) of passages, the intermediate wall 15 preferably has an undulating or “wavy” shape in cross section, the wall 15 undulating by substantially one half of an undulation length across the width of a passage.
The “length” of an undulation is the distance between two points of the undulation located at the same height with the same direction of variation of slope. In the case of a periodic undulation, the “length” of the undulation is called the “period”.
The undulation is preferably periodic, but the amplitude of the undulations may be constant or variable. The amplitude is preferably constant. It is also preferable if the undulation has a sinusoidal shape whose half-period is equal to the pitch “p” of the array of passages, as shown in FIG. 3.
Finally, it is preferable if all the vertical or horizontal intermediate walls 15 of a unit have an undulation of exactly the same shape in cross section.
The expression “ratio of asymmetry” refers to the ratio between the amplitude “h” and the half-length of said undulation (or between the amplitude “h” and the half-period in the case of a periodic undulation). The following examples summarized in table 1 are provided by way of illustration and are not limiting on the invention. FIGS. 4 and 5 represent curves of the increasing head loss as a function of time corresponding to certain examples from table 1, with clean and clogged filters, respectively.
The filter bodies that were tested were produced by assembling 16 filter units fastened together by means of a joint 1 mm thick. These filter bodies were cylindrical with a diameter of 144 mm and a length of 9 inches (228.6 mm). The passages were of the type represented in FIG. 4, the walls having a substantially sinusoidal profile and the outlet and inlet passages having a cross section of constant area through the length L of the filter body.
For the purposes of the calculations, the exhaust gases were introduced into the inlet passages of the filter bodies under test at a temperature of 250° C. and a flowrate of 320 m3/hour. The concentration of particles in the exhaust gases was 2.2*10−5 kg/m3.
For the clogged filter body tests, the concentration of combustion residues in the inlet passages was 1.8*10−9 m3/m3 of exhaust gas.
The reference example “Ref” corresponds to a filter constituted by assembling 16 filter units fastened together with a joint 1 mm thick. This filter was cylindrical with a diameter of 144 mm and a length of 9 inches (228.6 mm). The passages were of the type represented in FIG. 1, the outlet and inlet passages having a square cross section of constant area through the length L of the filter body. The pitch of the array was 1.8 mm and the thickness of the walls was 350 μm.
The filtering areas, passage volumes and head losses were calculated by the Institut de Mécaniques des Fluides of Toulouse (France).
The expression “hydraulic diameter” used in relation to a cross section or a passage refers to the ratio between four times the section of the passage and the perimeter of the passage.
The passage density is expressed as a number of passages per square inch (cells per square inch (cpsi)).
Ve denotes the total volume of the inlet passages, Vs the total volume of the outlet passages. The ratio r is defined as follows: r=Ve/Vs.
The expression “filtering area” refers to the area of the walls of the inlet passages through which the flow of gas to be filtered can pass. The filtering area is evaluated in square meters per liter of filter unit.
The performance of a filter body is evaluated by measuring the time “t” in minutes to reach a particular head loss “dP” and by the initial head loss (dP for t=0). The measured time “t” in minutes to achieve a head loss “dP” of x mbar is denoted t/x.
It is considered advantageous for a filter body to conform to the following criteria:
    • initial head loss<50 mbar;
    • t/100≧300 for a clean filter;
    • t/150≧500 for a clean filter;
    • t/150≧200 for a clogged filter.
TABLE 1
Outlet Filtering t(min) for t(min) for t(min) for dP
passage area per dP = dP = dP = (mbar)
Passage Wall hydraulic liter of 150 mbar 100 mbar 150 mbar for t = 0
density thickness Ratio of r = diameter filter unit (clean (clean filter (clogged (clean
(cpsi) (μm) asymmetry Ve/Vs (mm) (m2/l) filter unit) unit) filter unit) filter unit)
Ref. 200 350 0 1 1.45 0.918 481 319 134 26.7
Ex1 250 350 0 1 1.26 0.997 495 341 NA 28.7
Ex2 250 350 10% 1.986 1.03 1.149 >600   443 279 33.9
Ex3 250 350 20% 4.806 0.74 1.283 522 100 NA 89.6
Ex4 250 300 10% 1.867 1.09 1.183 >600   508 337 27.8
Ex5 250 300 15% 2.66 0.97 1.25 >600   514 NA 36.8
Ex6 250 300 20% 4.061 0.82 1.314 >600   376 NA 60.5
Ex7 250 400 10% 2.099 0.97 1.115 >600   372 NA 41.8
Ex8 200 350 10% 1.883 1.2 1.05 >600   412 264 29.7
Ex9 200 350 15% 2.723 1.06 1.111 >600   411 309 38.7
Ex10 200 350 20% 4.223 0.89 1.168 >600   281 284 63.8
Ex11 300 350 10% 2.054 0.9 1.233 >600   446 NA 39.5
Ex12 200 350  2% 1.132 1.4 0.946 516 342 160 26.3
Ex13 200 350  5% 1.365 1.33 0.987 566 374 200 26.6
Ex14 100 500 10% 1.367 1.88 0.696 307 180 121 35.7
Ex15 150 400 10% 1.363 1.54 0.856 441 288 200 28.8
“NA” means “not available”.
Table 1 and FIGS. 4 and 5 indicate that:
For new filter bodies, the greater the filtering area, the slower the head loss increases over time. In other words, the loading slope decreases as the filtering area increases. However, the filtering area is not the only criterion, as is shown by comparing example 15 and the reference example. That comparison shows that, according to the invention, a higher ratio r has the advantage of compensating a lower filtering area when the filters are clogged.
Without being bound by any theory, the Applicant explains this phenomenon in the following manner.
A high ratio r means a greater volume in the inlet passages for storing the combustion residues. For a given filtering area and a given combustion residue volume (i.e. a given number of regenerations), the proportion of the filtering area that is ineffective because it is covered by the combustion residues is therefore lower. The induced head loss is therefore lower. Between two regenerations, the head loss induced by the filter body therefore increases more slowly.
Moreover, the large volume in the inlet passages can store a greater quantity of combustion residues. The number of regenerations before removing/refitting the filter can therefore be increased.
For a constant wall thickness, an increase in the ratio of asymmetry implies an increase in the storage capacity of the inlet passages and an increase in the filtering area of the unit.
However, the ratio of asymmetry must not be increased excessively, as this could reduce the section of the outlet passages to the point of a prejudicial increase in the head loss.
A compromise must therefore be arrived at. The ratio of asymmetry is less than 20%, preferably less than 15%, more preferably less than 12%, and greater than 5%, preferably greater than 6%.
According to the invention, the time between two filter body demounting/cleaning operations is therefore increased not only because of reduced residual clogging of the filtering area by combustion residues after each regeneration, which slows down clogging by soot between two regenerations, but also because a greater number of regenerations is possible, the combustion residue storage volume being greater.
The motorist can therefore travel a greater distance without performing any maintenance on the filter.
According to the invention, the optimum is considered to be having:
    • a ratio r greater than or equal to 1.15, preferably greater than 1.35, and less than 4 , preferably less than 3,
    • a filtering area at least equal to 0.825 m2 per liter of filter unit, and preferably greater than or equal to 0.92 m2 per liter of filter unit.
The inlet and outlet passages having a cross section of constant area throughout the length of the filter unit, the increase in the ratio r is the result of increasing the hydraulic diameter of the inlet passages and/or reducing the hydraulic diameter of the outlet passages. Table 1 (see in particular examples 3, 6 and 10) shows that if the hydraulic diameter of the outlet passages is very small, the head loss induced by the clean filter body is much too high. This may prove unacceptable since the official power rating of an engine takes account of the exhaust line.
According to the invention, the hydraulic diameter of the outlet passages must be greater than or equal to 0.9 mm and preferably from 0.95 to 1.4 mm.
Of course, the present invention is not limited to the embodiments shown here and described above, which have been provided by way of illustrative and nonlimiting example.
Thus the invention relates equally to a monolithic filter body. The filter unit could have any shape and any arrangement of the passages.
Finally, the cross section of the passages is not limited to the shapes described.

Claims (12)

1. A filter unit for filtering particles contained in exhaust gases of an internal combustion engine, comprising:
interleaved sets of adjacent inlet passages (10, 11) and outlet passages (12, 13) in fluid communication through lateral walls of said inlet passages (10, 11) and said outlet passages (12, 13),
said unit including a set of lateral wall portions (16 1-16 8) forming an intermediate wall (15) between said inlet passages (10, 11) and said outlet passages (12, 13) and having, in cross section, an undulation determined to increase an overall volume of said inlet passages (10, 11) at an expense of an overall volume of the outlet passages (12, 13), and the overall volume (Ve) of said inlet passages (10, 11) being greater that the overall volume (Vs) of said outlet passages (12, 13), wherein,
a hydraulic diameter of said outlet passages (12, 13) is from 0.9 to 1.4 mm,
a ratio r of the overall volume (Ve) of the inlet passages (10, 11) to the overall volume (Vs) of the outlet passages (12, 13) is from 1.15 to 4,
a filtering area is from 0.825 m2 to 1.4 m2 per liter of said filter unit, and
a ratio of asymmetry of said undulation is less than 15% and greater than 5%.
2. The filter unit according to claim 1, wherein the hydraulic diameter of said outlet passages (12, 13) is greater than 0.95 mm.
3. The filter unit according to claim 1, wherein said ratio r is greater than 1.35.
4. The filter unit according to claim 1, wherein said ratio r is less than 3.
5. The filter unit according to claim 1, wherein the filtering area is greater than 0.92 m2 per liter of said filter unit.
6. The filter unit according to claim 1, wherein said outlet passages (12, 13) have a cross section of constant area throughout a length (L) of said filter unit.
7. The filter unit according to claim 1, wherein said inlet passages (10, 11) and said outlet passages (12, 13) are straight and parallel.
8. The filter unit according to claim 1, wherein said inlet passages (10, 11) and said outlet passages (12, 13) are arranged relative to each other so that all of the exhaust gases filtered by an one of said inlet passages (10, 11) passes into outlet passages (12, 13) adjacent to the one of said inlet passages (10, 11).
9. The filter unit according to claim 1, wherein the ratio of asymmetry of said undulation is less than 12%.
10. The filter unit according to claim 1, wherein said undulation is periodic and a half-period of said undulation extends over a width of one of said passages (10, 11, 12, 13).
11. The filter unit according to claim 1, wherein said undulation has a sinusoidal shape in cross section.
12. A filter body intended for a particle filter, comprising an least one filter unit according to claim 1.
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080155951A1 (en) * 2007-01-03 2008-07-03 Ford Global Technologies, Llc Porous substrate for use as a particulate filter for catalytic or non-catalytic supported soot regeneration
US20090211214A1 (en) * 2004-08-04 2009-08-27 Purem Abgassysteme Gmbh & Co. Kg Filter plate for a particle filter
US20090241495A1 (en) * 2008-03-28 2009-10-01 Mazda Motor Corporation Particulate filter
US20100307117A1 (en) * 2007-12-20 2010-12-09 Saint-Gobain Centre De Recherches Et D'etudes Eur. Gas filtration structure with concave or convex hexagonal channels
US9987582B2 (en) * 2015-09-02 2018-06-05 Ngk Insulators, Ltd. Plugged honeycomb structure and plugged honeycomb segment
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US11986764B2 (en) 2018-06-11 2024-05-21 Donaldson Company, Inc. Filter media, filter media packs, and filter elements

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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US8814974B2 (en) * 2007-08-24 2014-08-26 Corning Incorporated Thin-walled porous ceramic wall-flow filter
FR2928561B1 (en) * 2008-03-11 2011-08-19 Saint Gobain Ct Recherches GAS FILTRATION STRUCTURE
FR2928562B1 (en) * 2008-03-11 2010-08-13 Saint Gobain Ct Recherches FILTRATION STRUCTURE OF A GAS WITH VARIABLE WALL THICKNESS
US20110262311A1 (en) 2008-12-23 2011-10-27 Saint-Gobain Centre De Rech. Et D'etudes Europeen Filtration structure having inlet and outlet surfaces with a different plugging material
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FR2949690B1 (en) 2009-09-04 2011-10-21 Saint Gobain Ct Recherches SIC PARTICLE FILTER INCORPORATING CERIUM
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WO2011051901A1 (en) 2009-10-28 2011-05-05 Saint-Gobain Centre De Recherches Et D'etudes Europeen Assembled filter body having variable specific thermal resistance
FR2954175B1 (en) * 2009-12-23 2012-01-27 Saint Gobain Ct Recherches ASSEMBLED FILTER STRUCTURE
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FR2969696B1 (en) 2010-12-23 2013-01-04 Saint Gobain Ct Recherches PARTICLE FILTER ASSEMBLY TYPE
JP5762138B2 (en) * 2011-05-28 2015-08-12 京セラ株式会社 Honeycomb structure and gas processing apparatus using the same
FR2979837B1 (en) 2011-09-14 2013-08-23 Saint Gobain Ct Recherches HONEYCOMB ELEMENT HAS REINFORCED CORNERS
EP2698189B1 (en) * 2012-08-17 2019-08-07 Pall Corporation Filter module and filter system comprising same
KR20160041945A (en) * 2013-08-14 2016-04-18 스미또모 가가꾸 가부시끼가이샤 Particulate filter
WO2017062526A1 (en) * 2015-10-06 2017-04-13 Wormser Energy Solutions, Inc. Method and apparatus for adiabatic calcium looping
DE102016111574A1 (en) 2016-06-23 2017-12-28 Iav Gmbh Ingenieurgesellschaft Auto Und Verkehr Device for exhaust gas purification with filter function and diagnostic procedure for this device
EP3551316A1 (en) * 2016-12-12 2019-10-16 Donaldson Company, Inc. Filter media, filter media packs, and filter elements

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4276071A (en) 1979-12-03 1981-06-30 General Motors Corporation Ceramic filters for diesel exhaust particulates
US4364761A (en) * 1979-12-03 1982-12-21 General Motors Corporation Ceramic filters for diesel exhaust particulates and methods for making
US4416676A (en) 1982-02-22 1983-11-22 Corning Glass Works Honeycomb filter and method of making it
US5300133A (en) * 1992-01-17 1994-04-05 Mercedes-Benz Ag Soot particle exhaust-gas filter
US5873998A (en) 1995-12-05 1999-02-23 Societe Anonyme: T.A.M.I. Industries Inorganic tubular filter element including channels of non-circular section having optimized profile
FR2789327A1 (en) 1999-02-09 2000-08-11 Ecia Equip Composants Ind Auto Porous filter structure for filtering particles in exhaust gases, comprises assembly of adjacent parallel conduits separated by porous filtration walls
DE10037403A1 (en) 2000-08-01 2002-02-14 Daimler Chrysler Ag particulate Filter
US20030041730A1 (en) 2001-08-30 2003-03-06 Beall Douglas M. Honeycomb with varying channel size
US6843817B2 (en) * 2000-03-13 2005-01-18 Ngk Insulators, Ltd. Ceramic filter and filter device
US20050076627A1 (en) * 2002-03-25 2005-04-14 Motomichi Itou Honeycomb filter
US6887826B2 (en) * 2001-05-30 2005-05-03 Denso Corporation Exhaust gas purifying filter and method of manufacturing the same

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2343366Y (en) * 1998-06-24 1999-10-13 张恒 Vortex filter element for engine cleaner

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4276071A (en) 1979-12-03 1981-06-30 General Motors Corporation Ceramic filters for diesel exhaust particulates
FR2473113A1 (en) 1979-12-03 1981-07-10 Gen Motors Corp CERAMIC FILTER FOR RETAINING PARTICLES OF EXHAUST MATERIAL FROM DIESEL ENGINES
US4364761A (en) * 1979-12-03 1982-12-21 General Motors Corporation Ceramic filters for diesel exhaust particulates and methods for making
US4416676A (en) 1982-02-22 1983-11-22 Corning Glass Works Honeycomb filter and method of making it
US5300133A (en) * 1992-01-17 1994-04-05 Mercedes-Benz Ag Soot particle exhaust-gas filter
US5873998A (en) 1995-12-05 1999-02-23 Societe Anonyme: T.A.M.I. Industries Inorganic tubular filter element including channels of non-circular section having optimized profile
FR2789327A1 (en) 1999-02-09 2000-08-11 Ecia Equip Composants Ind Auto Porous filter structure for filtering particles in exhaust gases, comprises assembly of adjacent parallel conduits separated by porous filtration walls
US6843817B2 (en) * 2000-03-13 2005-01-18 Ngk Insulators, Ltd. Ceramic filter and filter device
DE10037403A1 (en) 2000-08-01 2002-02-14 Daimler Chrysler Ag particulate Filter
US6887826B2 (en) * 2001-05-30 2005-05-03 Denso Corporation Exhaust gas purifying filter and method of manufacturing the same
US20030041730A1 (en) 2001-08-30 2003-03-06 Beall Douglas M. Honeycomb with varying channel size
US20050076627A1 (en) * 2002-03-25 2005-04-14 Motomichi Itou Honeycomb filter

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090211214A1 (en) * 2004-08-04 2009-08-27 Purem Abgassysteme Gmbh & Co. Kg Filter plate for a particle filter
US20080155951A1 (en) * 2007-01-03 2008-07-03 Ford Global Technologies, Llc Porous substrate for use as a particulate filter for catalytic or non-catalytic supported soot regeneration
US20100307117A1 (en) * 2007-12-20 2010-12-09 Saint-Gobain Centre De Recherches Et D'etudes Eur. Gas filtration structure with concave or convex hexagonal channels
US20090241495A1 (en) * 2008-03-28 2009-10-01 Mazda Motor Corporation Particulate filter
US8092565B2 (en) * 2008-03-28 2012-01-10 Mazda Motor Corporation Particulate filter
USD849914S1 (en) 2015-05-13 2019-05-28 Ngk Insulators, Ltd. Filter segment for removing particle matter
USD851229S1 (en) * 2015-05-13 2019-06-11 Ngk Insulators, Ltd. Filter segment for removing particle matter
US9987582B2 (en) * 2015-09-02 2018-06-05 Ngk Insulators, Ltd. Plugged honeycomb structure and plugged honeycomb segment
US11986764B2 (en) 2018-06-11 2024-05-21 Donaldson Company, Inc. Filter media, filter media packs, and filter elements

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JP4431576B2 (en) 2010-03-17
MXPA06000710A (en) 2006-04-19
AU2004265114A1 (en) 2005-02-24
DK1660213T3 (en) 2007-06-04
WO2005016491A1 (en) 2005-02-24
ZA200601406B (en) 2008-07-30
RU2006104979A (en) 2007-08-27
EP1660213B1 (en) 2007-02-14
EP1660213A1 (en) 2006-05-31
CN1822891A (en) 2006-08-23
FR2857696B1 (en) 2005-10-21
CA2532277A1 (en) 2005-02-24
ATE353700T1 (en) 2007-03-15
RU2338577C2 (en) 2008-11-20
US20060168928A1 (en) 2006-08-03
DE602004004800D1 (en) 2007-03-29
JP2007528959A (en) 2007-10-18
PL1660213T3 (en) 2007-07-31
PT1660213E (en) 2007-05-31
ES2282895T3 (en) 2007-10-16
KR101032032B1 (en) 2011-05-02
DE602004004800T2 (en) 2007-10-31
FR2857696A1 (en) 2005-01-21
KR20060113634A (en) 2006-11-02
CN100438948C (en) 2008-12-03
BRPI0412152A (en) 2006-10-17

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