US7010258B2 - High heat transfer fuser roller - Google Patents

High heat transfer fuser roller Download PDF

Info

Publication number
US7010258B2
US7010258B2 US10/814,316 US81431604A US7010258B2 US 7010258 B2 US7010258 B2 US 7010258B2 US 81431604 A US81431604 A US 81431604A US 7010258 B2 US7010258 B2 US 7010258B2
Authority
US
United States
Prior art keywords
thermal conductivity
fuser roller
layer
inches
roller
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related, expires
Application number
US10/814,316
Other versions
US20050220511A1 (en
Inventor
Fangsheng Wu
Muhammed Aslam
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Midwest Athletics And Sports Alliance LLC
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Priority to US10/814,316 priority Critical patent/US7010258B2/en
Assigned to NEXPRESS SOLUTIONS LLC reassignment NEXPRESS SOLUTIONS LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ASLAM, MUHAMMED, WU, FANGSHENG
Assigned to EASTMAN KODAK COMPANY reassignment EASTMAN KODAK COMPANY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: NEXPRESS SOLUTIONS, INC. (FORMERLY NEXPRESS SOLUTIONS LLC)
Priority to PCT/US2005/008430 priority patent/WO2005101136A1/en
Priority to EP05725531A priority patent/EP1730602A1/en
Priority to TW094109224A priority patent/TW200602821A/en
Publication of US20050220511A1 publication Critical patent/US20050220511A1/en
Application granted granted Critical
Publication of US7010258B2 publication Critical patent/US7010258B2/en
Assigned to CITICORP NORTH AMERICA, INC., AS AGENT reassignment CITICORP NORTH AMERICA, INC., AS AGENT SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: EASTMAN KODAK COMPANY, PAKON, INC.
Assigned to WILMINGTON TRUST, NATIONAL ASSOCIATION, AS AGENT reassignment WILMINGTON TRUST, NATIONAL ASSOCIATION, AS AGENT PATENT SECURITY AGREEMENT Assignors: EASTMAN KODAK COMPANY, PAKON, INC.
Assigned to BANK OF AMERICA N.A., AS AGENT reassignment BANK OF AMERICA N.A., AS AGENT INTELLECTUAL PROPERTY SECURITY AGREEMENT (ABL) Assignors: CREO MANUFACTURING AMERICA LLC, EASTMAN KODAK COMPANY, FAR EAST DEVELOPMENT LTD., FPC INC., KODAK (NEAR EAST), INC., KODAK AMERICAS, LTD., KODAK AVIATION LEASING LLC, KODAK IMAGING NETWORK, INC., KODAK PHILIPPINES, LTD., KODAK PORTUGUESA LIMITED, KODAK REALTY, INC., LASER-PACIFIC MEDIA CORPORATION, NPEC INC., PAKON, INC., QUALEX INC.
Assigned to PAKON, INC., EASTMAN KODAK COMPANY reassignment PAKON, INC. RELEASE OF SECURITY INTEREST IN PATENTS Assignors: CITICORP NORTH AMERICA, INC., AS SENIOR DIP AGENT, WILMINGTON TRUST, NATIONAL ASSOCIATION, AS JUNIOR DIP AGENT
Assigned to JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE reassignment JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE INTELLECTUAL PROPERTY SECURITY AGREEMENT (FIRST LIEN) Assignors: CREO MANUFACTURING AMERICA LLC, EASTMAN KODAK COMPANY, FAR EAST DEVELOPMENT LTD., FPC INC., KODAK (NEAR EAST), INC., KODAK AMERICAS, LTD., KODAK AVIATION LEASING LLC, KODAK IMAGING NETWORK, INC., KODAK PHILIPPINES, LTD., KODAK PORTUGUESA LIMITED, KODAK REALTY, INC., LASER-PACIFIC MEDIA CORPORATION, NPEC INC., PAKON, INC., QUALEX INC.
Assigned to BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT reassignment BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT INTELLECTUAL PROPERTY SECURITY AGREEMENT (SECOND LIEN) Assignors: CREO MANUFACTURING AMERICA LLC, EASTMAN KODAK COMPANY, FAR EAST DEVELOPMENT LTD., FPC INC., KODAK (NEAR EAST), INC., KODAK AMERICAS, LTD., KODAK AVIATION LEASING LLC, KODAK IMAGING NETWORK, INC., KODAK PHILIPPINES, LTD., KODAK PORTUGUESA LIMITED, KODAK REALTY, INC., LASER-PACIFIC MEDIA CORPORATION, NPEC INC., PAKON, INC., QUALEX INC.
Assigned to MIDWEST ATHLETICS AND SPORTS ALLIANCE LLC reassignment MIDWEST ATHLETICS AND SPORTS ALLIANCE LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: EASTMAN KODAK COMPANY
Assigned to MIDWEST ATHLETICS AND SPORTS ALLIANCE LLC reassignment MIDWEST ATHLETICS AND SPORTS ALLIANCE LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: EASTMAN KODAK COMPANY
Assigned to EASTMAN KODAK COMPANY reassignment EASTMAN KODAK COMPANY RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: JP MORGAN CHASE BANK N.A.
Assigned to EASTMAN KODAK COMPANY reassignment EASTMAN KODAK COMPANY RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: BANK OF AMERICA N.A.
Assigned to KODAK AVIATION LEASING LLC, PAKON, INC., NPEC, INC., KODAK AMERICAS, LTD., KODAK IMAGING NETWORK, INC., KODAK REALTY, INC., FAR EAST DEVELOPMENT LTD., FPC, INC., LASER PACIFIC MEDIA CORPORATION, QUALEX, INC., KODAK PHILIPPINES, LTD., KODAK (NEAR EAST), INC., EASTMAN KODAK COMPANY, KODAK PORTUGUESA LIMITED, CREO MANUFACTURING AMERICA LLC reassignment KODAK AVIATION LEASING LLC RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Assigned to QUALEX, INC., LASER PACIFIC MEDIA CORPORATION, PFC, INC., EASTMAN KODAK COMPANY, FAR EAST DEVELOPMENT LTD., NPEC, INC., KODAK (NEAR EAST), INC., PAKON, INC., KODAK PORTUGUESA LIMITED, KODAK AVIATION LEASING LLC, CREO MANUFACTURING AMERICA LLC, KODAK PHILIPPINES, LTD., KODAK IMAGING NETWORK, INC., KODAK REALTY, INC., KODAK AMERICAS, LTD. reassignment QUALEX, INC. RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Assigned to FPC INC., LASER PACIFIC MEDIA CORPORATION, QUALEX INC., EASTMAN KODAK COMPANY, KODAK AMERICAS LTD., KODAK (NEAR EAST) INC., NPEC INC., FAR EAST DEVELOPMENT LTD., KODAK PHILIPPINES LTD., KODAK REALTY INC. reassignment FPC INC. RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: BARCLAYS BANK PLC
Adjusted expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G15/00Apparatus for electrographic processes using a charge pattern
    • G03G15/20Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat
    • G03G15/2003Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat using heat
    • G03G15/2014Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat using heat using contact heat
    • G03G15/2053Structural details of heat elements, e.g. structure of roller or belt, eddy current, induction heating
    • G03G15/2057Structural details of heat elements, e.g. structure of roller or belt, eddy current, induction heating relating to the chemical composition of the heat element and layers thereof

Definitions

  • This invention relates to fusing stations in electrostatographic reproduction apparatus, and more particularly to an improved fusing roller with high heat transfer efficiency.
  • an electrostatic latent image is formed on a primary image-forming member such as a photoconductive surface and is developed with thermoplastic toner particles to form a toner image.
  • the toner image is thereafter transferred to a receiver member, e.g., a sheet of paper or plastic, and the toner image is subsequently fused or fixed to the receiver member in a fusing station using heat and pressure.
  • the fusing station includes a fuser member which can be a roller, belt, or any surface having a suitable shape for fixing thermoplastic toner particles to the receiver member.
  • the toned receiver member is commonly passed between a pair of engaged rollers that produce an area of pressure contact known as a fusing nip.
  • at least one of the rollers typically includes a compliant or conformable layer. Heat is transferred from at least one of the rollers to the toner in the fusing nip, causing the toner to partially melt and attach to the receiver member.
  • the fuser member is a deformable heated roller
  • a resilient elastomeric layer is typically bonded to the core of the roller, with the roller having a smooth outer surface.
  • the fuser member is in the form of a belt, e.g., a flexible endless belt that passes around the heated roller, the belt typically has a smooth outer surface which may also be hardened.
  • Simplex fusing stations attach toner to only one side of the receiver member at a time.
  • the engaged roller that contacts the unfused toner is commonly known as the fuser roller and is a heated roller.
  • the roller that contacts the other side of the receiver member is known as the pressure roller and is usually unheated.
  • Either or both rollers can have a compliant layer on or near the surface. It is common for one of these rollers to be driven rotatable by an external source while the other roller is rotated frictionally by the nip engagement.
  • a conventional toner fuser roller commonly includes a rigid cylindrical core member, typically a metallic core such as aluminum, coated with one or more synthetic layers usually formulated with polymeric materials made from elastomers.
  • a resilient base cushion layer which may contain filler particles to improve mechanical strength and/or thermal conductivity, is typically formed on the surface of the core, which may advantageously be coated with a primer to improve adhesion of the resilient layer.
  • Roller base cushion layers are commonly made of silicone rubbers or silicone polymers such as, for example, polydimethylsiloxane (PDMS) polymers disclosed by the Chen, et al. patents (U.S. Pat. Nos. 5,960,245 or 6,020,038).
  • fuser roller The most common type of fuser roller is internally heated, i.e., a source of heat is provided within the roller for fusing.
  • a fuser roller generally has a hollow core, inside of which is located a source of heat, usually a lamp.
  • a source of heat usually a lamp.
  • an externally heated fuser roller which fuser roller is typically heated by surface contact with one or more heating rollers.
  • Externally heated fuser rollers are disclosed by the O'Leary patent (U.S. Pat. No. 5,450,183), the Derimiggio, et al. patent (U.S. Pat. No. 4,984,027), the Aslam, et al. patent (U.S. Pat. No. 6,567,641), and the Chen, et al. patent (U.S. Pat. No. 6,490,430).
  • Some roller fusers rely on film splitting of low viscosity oil to enable release of the toner and (hence) receiver member from the fuser roller.
  • the oil is typically applied to the surface of the fuser from a donor roller coated with the oil provided from a supply sump.
  • a donor roller is disclosed in the Chen, et al. patent (U.S. Pat. No. 6,190,771) and in the Chen, et al. patent application (U.S. patent application Ser. No. 09/960,661, filed Sep. 21, 2001).
  • Release oils are composed of, for example, polydimethylsiloxanes.
  • fuser oils When applied to the fuser roller surface to prevent the toner from adhering to the roller, fuser oils may, upon repeated use, interact with PDMS material included in the resilient layer(s) in the fuser roller, which in time can cause swelling, softening, and degradation of the roller.
  • a thin barrier layer made of, for example, a cured fluoroelastomer and/or a silicone elastomer, is typically formed on the resilient cushion layer, as disclosed in the Davis, et al. patent (U.S. Pat. No. 6,225,409).
  • the area of contact of a conformable fuser roller with the toner-bearing surface of a receiver member sheet as it passes through the fusing nip is determined by the amount of pressure exerted by the pressure roller and by the characteristics of the resilient cushion layer. The extent of the contact area helps establish the length of time that any given portion of the toner image will be in contact with and heated by the fuser roller.
  • Prior art internally heated fuser rollers typically have one or more synthetic polymeric layers including a deformable layer such as a base cushion layer surrounding a hollow metallic core member, with a source of heat such as a lamp provided within the hollow core member.
  • a source of heat such as a lamp provided within the hollow core member.
  • Such fuser rollers rely on thermal conductivity through the synthetic layers for conduction of heat from the source of heat to the surface of the roller so as to provide heat for fusing toner particles to receiver members.
  • the thermal conductivity attainable by the use of one or more suitable particulate fillers, is determined by the filler concentration.
  • the thermal conductivity of most polymers is very low and the thermal conductivity generally increases as the filler concentration is increased. However, if the filler concentration is too high, the mechanical properties of a polymer are usually compromised.
  • the stiffness of the synthetic layers may be increased by too much filler so that there is insufficient deformability to create a wide enough nip for proper fusing. Moreover, too much filler will cause the synthetic layers to have a propensity to delaminate or crack or otherwise cause failure of the roller.
  • An auxiliary internal source of heat may optionally be used with an externally heated fuser roller, e.g., as disclosed in the Stack, et al. patent (U.S. Pat. No. 6,567,641) and in the Chen, et al. patent (U.S. Pat. No. 6,490,430).
  • Such an internal source of heat is known to be useful when the fusing station is quiescent and/or during startup when relatively cold toned receiver members first arrive at the fusing station for fusing therein. It will be evident from the preceding paragraph above that in order for such an auxiliary internal source of heat to be effective (when intermittently needed), the fuser roller must have a sufficiently large thermal conductivity.
  • this invention is directed to a high heat transfer efficiency fusing roller for a fusing station of an electrostatographic printer for fusing toner images to receiver members.
  • the high heat transfer efficiency fusing roller includes an annular elastomeric base cushion layer around a rigid cylindrical core member, with a high thermal conductivity layer around the base cushion layer, and a thin flexible release layer around the high thermal conductivity layer.
  • the base cushion layer is less thermally conductive than the high thermal conductivity layer, which high thermal conductivity layer has a thermal conductivity equal to or greater than 1 BTU/hr/ft/° F.
  • the subject fuser roller at the same nominal fusing temperature has an improved fusing efficiency, the fusing station thereby having a higher throughput rate of fused receiver members for the same heating load.
  • the improved efficiency permits the source of heat to use a smaller heating load when fusing at the same nominal fusing temperature and the same baseline throughput rate.
  • FIG. 1 shows a side elevational view of a fusing station with a fusing roller of the invention
  • FIG. 2 shows, in an axially directed view, on an enlarged scale, the layers of the fuser roller of the invention.
  • Fusing stations and fuser rollers for use therein according to this invention are readily includable in typical electrostatographic reproduction apparatus of many types, such as for example electrophotographic color printers.
  • the invention relates to an electrostatographic reproduction or printing apparatus for forming a toner image on a receiver member and utilizing a fusing station employing a deformable fuser roller for thermally fusing or fixing the toner image to a receiver member, e.g., of paper.
  • the fusing station commonly includes two rollers which are engaged to form a fusing nip in which an elastically deformable fuser roller comes into direct contact with an unfused toner image as the receiver member is being frictionally moved through the nip.
  • the fuser roller may be heated by an internal heat source, by an external heat source, or a combination of both.
  • the toner image in an unfused state may include a single-color toner or it may include a composite image of at least two single-color toner images, e.g., a full color composite image made for example from superimposed black, cyan, magenta, and yellow single-color toner images.
  • the unfused toner image has been transferred, e.g., electrostatically, to the receiver member from one or more toner image bearing members such as primary image-forming members or intermediate transfer members. It is well established that for high quality electrostatographic color imaging with dry toners, small toner particles are necessary.
  • the fusing station and fuser roller of the invention are suitable for the fusing of dry toner particles having a mean volume weighted diameter in a range of approximately between 2 mm–9 mm, and more typically, about 7 mm–9 mm, but the invention is not limited to these size ranges.
  • the fusing temperature to fuse such particles included in a toner image on a receiver member is typically in a range 100° C.–200° C., and more usually, 140°–180° C., but the invention is not limited to these temperature ranges.
  • FIG. 1 illustrates a simplex fusing station, of the type in which the fuser roller of the invention may be used.
  • the fusing station includes a heated, elastically deformable fuser roller 10 , engaged under pressure with a relatively harder, i.e., relatively nondeformable, pressure roller 20 , so as to form a fusing nip 25 .
  • fuser roller 10 is heated by an internal heat source 16 , for example a heat lamp, but in other embodiments fuser roller 10 could be externally heated, for example by contact with one or more heated rollers, or fuser roller 10 could be heated by a combination of internal and external heat sources.
  • Fuser roller 10 is a multilayer roller incorporating a high thermal conductivity layer.
  • a receiver member 15 carrying an unfused toner image 17 is shown moving in the direction of arrow A towards the fusing nip 25 , by any suitable transport mechanism (not shown), for passage therethrough.
  • Receiver member 15 is made of any suitable material, e.g., of paper or plastic, and the receiver member can be in cut sheet form (as depicted) or can be a continuous web.
  • Fuser roller 10 generally includes a rigid, cylindrical, core member 14 , around which is a deformable annular structure 12 including at least one elastomeric layer.
  • the core member 14 is preferably made of a thermally conductive material such as a metal, preferably aluminum, and the core member is typically hollow as shown.
  • an outer diameter of the core member is in a range between about 5 inches and 7 inches, and the outer diameter is more preferably about 6.0 inches.
  • the deformable annular structure 12 includes several layers and will be described in detail below.
  • Pressure roller 20 includes a rigid, cylindrical, core member 24 around which is an annular structure 22 including one or more layers.
  • the core member 24 usually made of a metal, preferably aluminum, and typically (but not necessarily) hollow as shown.
  • an outer diameter of the core member 24 is in a range between about 3 inches and 4 inches, and the outer diameter is more preferably about 3.5 inches.
  • a preferred annular structure 22 includes a resilient base cushion layer and an outer layer around the base cushion layer (individual layers of structure 22 not separately shown).
  • the base cushion layer of annular structure 22 preferably has a thickness in a range of approximately between 0.18 inches and 0.22 inches, and the thickness is more preferably about 0.20 inches.
  • the base cushion layer of structure 22 can for example be made of a commercially available condensation-crosslinked PDMS elastomer which contains about 32–37 volume percent aluminum oxide filler and about 2–6 volume percent iron oxide filler, sold by Emerson and Cuming (Lexington, Mass.) under the trade name EC 4952.
  • the base cushion layer of structure 22 is coated on the core member 24 and the outer layer of structure 22 is formed as a topcoat layer on the underlying base cushion layer, with the topcoat layer preferably made of a fluorocarbon thermoplastic random copolymer (FLC) material such as for example the copolymer of vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene disclosed in the Chen, et al. patent (U.S. Pat. No. 6,429,249).
  • the topcoat layer thickness is preferably in a range of approximately between 0.001 inches–0.004 inches, and more preferably 0.0015 inches–0.0025 inches.
  • a suitable pressure roller 20 is preferably similar to the pressure roller disclosed in the Chen, et al. patent (U.S. Pat. No. 6,429,249). Due to the incorporated fillers, the EC 4952 material usable for the base cushion layer of structure 22 has a relatively high nominal thermal conductivity of about 0.35 BTU/hr/ft/° F. However, the thermal conductivity of the base cushion layer of structure 22 is not critical to the operation of the fusing station. In certain circumstances, a considerably lower thermal conductivity of the base cushion layer of structure 22 may be preferable so as not to drain too much heat from the contact zone of nip 25 .
  • a preferred base cushion layer of pressure roller 20 is made of an elastomeric material having any suitable thermal conductivity, which elastomeric material has a Shore A hardness greater than about 50, preferably greater than about 60.
  • the base cushion layer may include a particulate filler.
  • an oiling roller mechanism Operating in conjunction with fusing roller 10 is an oiling roller mechanism, generally indicated by numeral 30 , including a wick 35 in contact with a liquid release agent (e.g., fuser oil) 34 contained in reservoir 33 .
  • wick 35 absorbs the release agent 34 and transfers the release agent to a metering roller 32 , with the amount of release agent on the surface of metering roller 32 controlled by blade 36 .
  • Metering roller 32 is in contact with a release agent donor roller 31 , which release agent donor roller contacts fuser roller 10 and thereby delivers a continuous flow of release agent 34 to the surface of fuser roller 10 .
  • a preferred release agent donor roller is similar to that of the cited Chen, et al. patent application (U.S. patent application Ser. No. 09/960,661, filed Sep. 21, 2001).
  • release agent Approximately 1 to 20 milligrams of release agent is needed for each receiver member (e.g., receiver member sheet 15 ) passing through nip 25 .
  • a suitable release agent is typically a silicone oil.
  • a preferred polymeric release agent 34 for use in the fusing station is an amine-functionalized polydimethylsiloxane having a preferred viscosity of about 300 centipoise as disclosed in the Chen, et al. patent (U.S. Pat. No. 6,190,771).
  • a suitable release agent donor roller 31 for use in the fusing station includes for example a hollow aluminum core of outer diameter about 0.875 inches, the core coated by a cushion layer about 0.230 inches thick made of a compliant material having a low thermal conductivity such as for example obtainable commercially as S5100 from Emerson and Cuming (Lexington, Mass.), with a release layer about 0.0025 inches thick coated on the cushion layer (individual layers not illustrated in FIG. 1 ).
  • the release layer can be made from an interpenetrating network composed of a crosslinked fluoroelastomer and two different silicone elastomers such as disclosed in the Davis, et al. patent (U.S. Pat. No. 6,225,409).
  • the release layer is made of a copolymer of vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene as disclosed in the Chen, et al. patent (U.S. Pat. No. 6,429,249). Any suitable dimensions of the core, cushion layer, and release layer may be used.
  • an oiling web mechanism (not illustrated) may be used, the oiling web mechanism including a movable fuser-oil-impregnated donor web pressed against fuser roller 10 by using one or more backup rollers.
  • a selectively activated source of heat is located substantially within the interior hollow core member 14 .
  • the internal source of heat is preferably a tubular heating lamp 16 coaxially located along the central longitudinal axis of core member 14 . Intermittent or variable ohmic heating (as may be required) of lamp 16 is selectively controllable by a programmable power supply (not shown).
  • the amount of heat transferred from fuser roller 10 to receiver member 15 and toner image 17 is dependent on the width of nip 25 and the thermal conductivity of annular structure 12 .
  • the wider the nip 25 and the higher the thermal conductivity of annular structure 12 the greater the amount of heat transferred to receiver member 15 and toner image 17 .
  • the more compliant annular structure 12 the wider the nip 25 .
  • Heat transfer to receiver member 15 and toner image 17 is therefore maximized when both the compliance and thermal conductivity of annular structure 12 are maximized.
  • compliance and thermal conductivity are contradistinctive.
  • Elastomeric materials suitable for use as compliant layers in fuser rollers have inherently low thermal conductivity.
  • the thermal conductivity of these elastomeric materials may be increased by incorporating particulate fillers, such as for example metals, metal oxides, metal hydroxides, metal salts, and mixtures thereof into these elastomeric materials.
  • the thermal conductivity, attainable by the use of one or more suitable particulate fillers, is determined by the filler concentration.
  • the thermal conductivity generally increases as the filler concentration is increased.
  • the compliance of these elastomeric materials generally decreases as the filler concentration is increased. It has been discovered that a novel combination of annular layer materials for annular structure 12 may be provided, with such combination resulting in higher heat transfer rates than prior art fusing rollers.
  • FIG. 2 shows an axial view cross section of a preferred embodiment of the fuser roller of the invention, designated generally be the numeral 10 ′, for use in an electrostatographic reproduction apparatus fusing station. Elements having a prime (′) in FIG. 2 refer to the corresponding unprimed elements in FIG. 1 .
  • the activated source of heat is a lamp 16 ′ which is entirely similar to the lamp 16 described above, and the core member 14 ′ is preferably thermally conductive and otherwise entirely similar to core member 14 .
  • the elastically deformable annular structure 12 ′ is a trilayer structure including a base cushion layer 6 around the core member 14 ′, a high thermal conductivity layer 7 around the base cushion layer 6 , and a flexible release layer 8 around the high thermal conductivity layer 7 .
  • the base cushion layer (BCL) 6 is preferably formed on the core member 14 ′ by any suitable coating method, with BCL 6 having a thermal conductivity preferably in a range of approximately between 0.1 BTU/hr/ft/° F. to 0.2 BTU/hr/ft/° F., and more preferably between 0.15 BTU/hr/ft/° F. to 0.17 BTU/hr/ft/° F.
  • Base cushion layer 6 may be made of any suitable resilient elastomeric material, such as for example a highly crosslinked polyorganosiloxane and may include a particulate filler.
  • the filler is preferably primarily a structural filler for strengthening the base cushion layer, and the filler may further include a minority proportion of thermally conductive particles, such as for example particles of ferric oxide.
  • the structural filler particles are made of materials such as mineral silica particles, fumed silica, and the like.
  • the total weight percentage of filler in BCL 6 is preferably less than about 30% w/w, and more preferably is in a range of approximately between 10% w/w to 20% w/w.
  • a filler in BCL 6 preferably has a particle size in a range of approximately between 0.1 ⁇ m to 20 ⁇ m, and more preferably 0.5 ⁇ m to 10 ⁇ m.
  • BCL 6 may have any suitable thickness.
  • the thickness of BCL 6 is in a range of approximately between 0.180 inches to 0.250 inches, and more preferably, 0.190 inches to 0.195 inches.
  • the high thermal conductivity layer (HTCL) 7 has a thermal conductivity preferably equal to or greater than 1 BTU/hr/ft/° F.
  • HTCL 7 is a metal with a thermal conductivity greater than 5 BTU/hr/ft/° F.
  • a metal may be copper, brass, aluminum, or nickel.
  • HTCL 7 is a removable replaceable annular sleeve member comprised of electroformed nickel available from Stork Screens America, Inc., of Charlotte, N.C.
  • HTCL 7 may also be fabricated from a metal sheet by, for example, forming a smooth seam by ultrasonic welding or by using an adhesive.
  • the flexible release layer 8 is preferably formed on the HTCL 7 by any suitable coating method including ring coating and blade coating.
  • Flexible release layer (FRL) 8 is preferably made with a chemically unreactive, low surface energy, flexible, polymeric material suitable for high temperature use, such as for example a fluoropolymer.
  • a preferred polymeric material for inclusion in FRL 8 is a fluorocarbon thermoplastic random copolymer (FLC) material such as for example the copolymer of vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene as disclosed in the Chen, et al. patent (U.S. Pat. No.
  • the FLC random copolymer having subunits of: —(CH 2 CF 2 )x-, —(CF 2 CF(CF 3 ))y-, and —(CF 2 CF 2 )z-,
  • x is from 1 to 50 or 60 to 80 mole percent
  • y is from 10 to 90 mole percent
  • z is from 10 to 90 mole percent
  • x+y+z 100 mole percent
  • the FRL 8 may have any suitable thickness and may include one or more particulate fillers. It is preferred that the one or more particulate fillers in of FRL 8 include zinc oxide particles or fluoroethylenepropylene (FEP) resin particles. However, in substitution of or in addition to the aforementioned one or more particulate fillers, any other particulate filler material may be included in FRL 8 , either singly or in combination. It is necessary for good release of a toner image to keep the filler concentration relatively low and the particle size of the filler small, so that a matte effect on the toner image due to filler particles at the surface of FRL 8 can be minimized.
  • FEP fluoroethylenepropylene
  • a filler used in the formulation of FRL 8 preferably has a particle size in a range of approximately between 0.1 ⁇ m to 10 ⁇ m, and more preferably 0.1 ⁇ m to 2.0 ⁇ m.
  • the total concentration of fillers included in FRL 8 is preferably less than about 20% by weight.
  • the concentration of zinc oxide is in a range of approximately between 5% to 7% w/w
  • the concentration of FEP particles is in a range of approximately between 7% to 9% w/w.
  • the thickness of the FRL 8 is in a range of approximately between 0.001 inches to 0.004 inches, and more preferably 0.0015 inches to 0.0025 inches.
  • the thermal conductivity of FRL 8 is preferably no less than approximately 0.07 BTU/hr/ft/° F., and more preferably in a range of approximately between 0.08 BTU/hr/ft/° F. to 0.11 BTU/hr/ft/° F.
  • the outer surface of the FRL 8 is preferably very smooth and the smoothness can be measured by any known method.
  • the smoothness of FRL 8 can be characterized by a gloss measurement using for example a gloss meter, such as a Micro-TRI-Gloss 20-60-85 Glossmeter available from BYK Gardener USA of Rivers Park, Md.
  • a Gardener gloss value is proportional to the intensity of specularly reflected light reflected off a surface divided by the intensity of the incident light for a specified angle of incidence measured from a perpendicular to the surface (angle of incidence equal to the angle of reflection), e.g., at 20, 60, or 85 degrees.
  • a G60 gloss value is measured at an angle of 60 degrees.
  • a suitable G60 gloss value for the FRL 8 is preferably greater than approximately 10, and more preferably, greater than or equal to approximately 12.
  • the subject fuser roller having a high thermal conductivity layer around a relatively thermally insulating base cushion layer gives a greatly improved heat transfer advantage for fusing toner images to receiver members in a fusing station of the invention.
  • This improved heat transfer advantage can be utilized to provide a high productivity (throughput rate) of the fusing station for a given nominal fusing temperature as required by a given type of toner particles and type of receiver member.
  • the improved heat transfer advantage permits the process speed to be reduced, thereby allowing a reduced external heating load from the external source of heat.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Rolls And Other Rotary Bodies (AREA)
  • Fixing For Electrophotography (AREA)

Abstract

A high heat transfer efficiency fusing roller includes an annular elastomeric base cushion layer around a rigid cylindrical core member, with a high thermal conductivity layer around the base cushion layer, and a thin flexible release layer around the high thermal conductivity layer. The base cushion layer is less thermally conductive than the high thermal conductivity layer, which high thermal conductivity layer has a thermal conductivity equal to or greater than 1 Btu/hr/ft/F.

Description

FIELD OF THE INVENTION
This invention relates to fusing stations in electrostatographic reproduction apparatus, and more particularly to an improved fusing roller with high heat transfer efficiency.
BACKGROUND OF THE INVENTION
In electrostatographic reproduction apparatus, an electrostatic latent image is formed on a primary image-forming member such as a photoconductive surface and is developed with thermoplastic toner particles to form a toner image. The toner image is thereafter transferred to a receiver member, e.g., a sheet of paper or plastic, and the toner image is subsequently fused or fixed to the receiver member in a fusing station using heat and pressure. The fusing station includes a fuser member which can be a roller, belt, or any surface having a suitable shape for fixing thermoplastic toner particles to the receiver member.
In fusing using a roller fuser member, the toned receiver member is commonly passed between a pair of engaged rollers that produce an area of pressure contact known as a fusing nip. In order to form the fusing nip, at least one of the rollers typically includes a compliant or conformable layer. Heat is transferred from at least one of the rollers to the toner in the fusing nip, causing the toner to partially melt and attach to the receiver member. In the case where the fuser member is a deformable heated roller, a resilient elastomeric layer is typically bonded to the core of the roller, with the roller having a smooth outer surface. Where the fuser member is in the form of a belt, e.g., a flexible endless belt that passes around the heated roller, the belt typically has a smooth outer surface which may also be hardened.
Simplex fusing stations attach toner to only one side of the receiver member at a time. In this type of fusing station, the engaged roller that contacts the unfused toner is commonly known as the fuser roller and is a heated roller. The roller that contacts the other side of the receiver member is known as the pressure roller and is usually unheated. Either or both rollers can have a compliant layer on or near the surface. It is common for one of these rollers to be driven rotatable by an external source while the other roller is rotated frictionally by the nip engagement.
A conventional toner fuser roller commonly includes a rigid cylindrical core member, typically a metallic core such as aluminum, coated with one or more synthetic layers usually formulated with polymeric materials made from elastomers. A resilient base cushion layer, which may contain filler particles to improve mechanical strength and/or thermal conductivity, is typically formed on the surface of the core, which may advantageously be coated with a primer to improve adhesion of the resilient layer. Roller base cushion layers are commonly made of silicone rubbers or silicone polymers such as, for example, polydimethylsiloxane (PDMS) polymers disclosed by the Chen, et al. patents (U.S. Pat. Nos. 5,960,245 or 6,020,038).
The most common type of fuser roller is internally heated, i.e., a source of heat is provided within the roller for fusing. Such a fuser roller generally has a hollow core, inside of which is located a source of heat, usually a lamp. Less common is an externally heated fuser roller, which fuser roller is typically heated by surface contact with one or more heating rollers. Externally heated fuser rollers are disclosed by the O'Leary patent (U.S. Pat. No. 5,450,183), the Derimiggio, et al. patent (U.S. Pat. No. 4,984,027), the Aslam, et al. patent (U.S. Pat. No. 6,567,641), and the Chen, et al. patent (U.S. Pat. No. 6,490,430).
Some roller fusers rely on film splitting of low viscosity oil to enable release of the toner and (hence) receiver member from the fuser roller. The oil is typically applied to the surface of the fuser from a donor roller coated with the oil provided from a supply sump. A donor roller is disclosed in the Chen, et al. patent (U.S. Pat. No. 6,190,771) and in the Chen, et al. patent application (U.S. patent application Ser. No. 09/960,661, filed Sep. 21, 2001).
Release oils (commonly referred to as fuser oils) are composed of, for example, polydimethylsiloxanes. When applied to the fuser roller surface to prevent the toner from adhering to the roller, fuser oils may, upon repeated use, interact with PDMS material included in the resilient layer(s) in the fuser roller, which in time can cause swelling, softening, and degradation of the roller. To prevent these deleterious effects caused by release oil, a thin barrier layer made of, for example, a cured fluoroelastomer and/or a silicone elastomer, is typically formed on the resilient cushion layer, as disclosed in the Davis, et al. patent (U.S. Pat. No. 6,225,409).
In the fusing of the toner image to the receiver member, the area of contact of a conformable fuser roller with the toner-bearing surface of a receiver member sheet as it passes through the fusing nip is determined by the amount of pressure exerted by the pressure roller and by the characteristics of the resilient cushion layer. The extent of the contact area helps establish the length of time that any given portion of the toner image will be in contact with and heated by the fuser roller.
Prior art internally heated fuser rollers typically have one or more synthetic polymeric layers including a deformable layer such as a base cushion layer surrounding a hollow metallic core member, with a source of heat such as a lamp provided within the hollow core member. Such fuser rollers rely on thermal conductivity through the synthetic layers for conduction of heat from the source of heat to the surface of the roller so as to provide heat for fusing toner particles to receiver members. The thermal conductivity, attainable by the use of one or more suitable particulate fillers, is determined by the filler concentration. The thermal conductivity of most polymers is very low and the thermal conductivity generally increases as the filler concentration is increased. However, if the filler concentration is too high, the mechanical properties of a polymer are usually compromised. For example, the stiffness of the synthetic layers may be increased by too much filler so that there is insufficient deformability to create a wide enough nip for proper fusing. Moreover, too much filler will cause the synthetic layers to have a propensity to delaminate or crack or otherwise cause failure of the roller.
Because the mechanical requirements of such an internally heated fuser roller require that the filler concentrations be moderate, the ability of the roller to transport heat is thereby limited. In fact, the concentration of filler in prior art internally heated deformable fuser rollers has reached a practical maximum. As a result, the number of copies that can be fused per minute is limited, and this in turn can be the limiting factor in determining the maximum throughput rate achievable in an electrostatographic printer. There is a need, therefore, to provide an improved fusing roller for increasing the number of prints that can be fused per minute, thereby providing opportunity for higher machine productivity.
An auxiliary internal source of heat may optionally be used with an externally heated fuser roller, e.g., as disclosed in the Stack, et al. patent (U.S. Pat. No. 6,567,641) and in the Chen, et al. patent (U.S. Pat. No. 6,490,430). Such an internal source of heat is known to be useful when the fusing station is quiescent and/or during startup when relatively cold toned receiver members first arrive at the fusing station for fusing therein. It will be evident from the preceding paragraph above that in order for such an auxiliary internal source of heat to be effective (when intermittently needed), the fuser roller must have a sufficiently large thermal conductivity. However, this requirement conflicts with a need to keep heat at the surface of an externally heated fuser roller, i.e., so as not to unnecessarily conduct heat into the interior which would compromise the fusing efficiency of the roller. Thus there remains a need to provide an improved efficiency fusing roller so that the throughput rate of an electrostatographic printer can be increased over that of prior art.
SUMMARY OF THE INVENTION
In light of the above, this invention is directed to a high heat transfer efficiency fusing roller for a fusing station of an electrostatographic printer for fusing toner images to receiver members. The high heat transfer efficiency fusing roller includes an annular elastomeric base cushion layer around a rigid cylindrical core member, with a high thermal conductivity layer around the base cushion layer, and a thin flexible release layer around the high thermal conductivity layer. The base cushion layer is less thermally conductive than the high thermal conductivity layer, which high thermal conductivity layer has a thermal conductivity equal to or greater than 1 BTU/hr/ft/° F. By comparison with a prior art fuser roller having a nominal fusing temperature and operated at a baseline throughput rate with a given heating load, the subject fuser roller at the same nominal fusing temperature has an improved fusing efficiency, the fusing station thereby having a higher throughput rate of fused receiver members for the same heating load. Alternatively, the improved efficiency permits the source of heat to use a smaller heating load when fusing at the same nominal fusing temperature and the same baseline throughput rate.
The invention, and its objects and advantages, will become more apparent in the detailed description of the preferred embodiment presented below.
BRIEF DESCRIPTION OF THE DRAWINGS
In the detailed description of the preferred embodiment of the invention presented below, reference is made to the accompanying drawings, in which:
FIG. 1 shows a side elevational view of a fusing station with a fusing roller of the invention; and
FIG. 2 shows, in an axially directed view, on an enlarged scale, the layers of the fuser roller of the invention.
DETAILED DESCRIPTION OF THE INVENTION
Fusing stations and fuser rollers for use therein according to this invention are readily includable in typical electrostatographic reproduction apparatus of many types, such as for example electrophotographic color printers.
The invention relates to an electrostatographic reproduction or printing apparatus for forming a toner image on a receiver member and utilizing a fusing station employing a deformable fuser roller for thermally fusing or fixing the toner image to a receiver member, e.g., of paper. The fusing station commonly includes two rollers which are engaged to form a fusing nip in which an elastically deformable fuser roller comes into direct contact with an unfused toner image as the receiver member is being frictionally moved through the nip. The fuser roller may be heated by an internal heat source, by an external heat source, or a combination of both. The toner image in an unfused state may include a single-color toner or it may include a composite image of at least two single-color toner images, e.g., a full color composite image made for example from superimposed black, cyan, magenta, and yellow single-color toner images. The unfused toner image has been transferred, e.g., electrostatically, to the receiver member from one or more toner image bearing members such as primary image-forming members or intermediate transfer members. It is well established that for high quality electrostatographic color imaging with dry toners, small toner particles are necessary.
The fusing station and fuser roller of the invention are suitable for the fusing of dry toner particles having a mean volume weighted diameter in a range of approximately between 2 mm–9 mm, and more typically, about 7 mm–9 mm, but the invention is not limited to these size ranges. The fusing temperature to fuse such particles included in a toner image on a receiver member is typically in a range 100° C.–200° C., and more usually, 140°–180° C., but the invention is not limited to these temperature ranges.
Turning now to the figures, FIG. 1 illustrates a simplex fusing station, of the type in which the fuser roller of the invention may be used. The fusing station includes a heated, elastically deformable fuser roller 10, engaged under pressure with a relatively harder, i.e., relatively nondeformable, pressure roller 20, so as to form a fusing nip 25. In this embodiment fuser roller 10 is heated by an internal heat source 16, for example a heat lamp, but in other embodiments fuser roller 10 could be externally heated, for example by contact with one or more heated rollers, or fuser roller 10 could be heated by a combination of internal and external heat sources. Fuser roller 10, described in detail below, is a multilayer roller incorporating a high thermal conductivity layer. A receiver member 15 carrying an unfused toner image 17 is shown moving in the direction of arrow A towards the fusing nip 25, by any suitable transport mechanism (not shown), for passage therethrough. Receiver member 15 is made of any suitable material, e.g., of paper or plastic, and the receiver member can be in cut sheet form (as depicted) or can be a continuous web.
Fuser roller 10 generally includes a rigid, cylindrical, core member 14, around which is a deformable annular structure 12 including at least one elastomeric layer. The core member 14 is preferably made of a thermally conductive material such as a metal, preferably aluminum, and the core member is typically hollow as shown. Preferably an outer diameter of the core member is in a range between about 5 inches and 7 inches, and the outer diameter is more preferably about 6.0 inches. The deformable annular structure 12 includes several layers and will be described in detail below.
Pressure roller 20 includes a rigid, cylindrical, core member 24 around which is an annular structure 22 including one or more layers. The core member 24 usually made of a metal, preferably aluminum, and typically (but not necessarily) hollow as shown. Preferably an outer diameter of the core member 24 is in a range between about 3 inches and 4 inches, and the outer diameter is more preferably about 3.5 inches. A preferred annular structure 22 includes a resilient base cushion layer and an outer layer around the base cushion layer (individual layers of structure 22 not separately shown). The base cushion layer of annular structure 22 preferably has a thickness in a range of approximately between 0.18 inches and 0.22 inches, and the thickness is more preferably about 0.20 inches.
The base cushion layer of structure 22 can for example be made of a commercially available condensation-crosslinked PDMS elastomer which contains about 32–37 volume percent aluminum oxide filler and about 2–6 volume percent iron oxide filler, sold by Emerson and Cuming (Lexington, Mass.) under the trade name EC 4952. Preferably the base cushion layer of structure 22 is coated on the core member 24 and the outer layer of structure 22 is formed as a topcoat layer on the underlying base cushion layer, with the topcoat layer preferably made of a fluorocarbon thermoplastic random copolymer (FLC) material such as for example the copolymer of vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene disclosed in the Chen, et al. patent (U.S. Pat. No. 6,429,249). The topcoat layer thickness is preferably in a range of approximately between 0.001 inches–0.004 inches, and more preferably 0.0015 inches–0.0025 inches.
A suitable pressure roller 20 is preferably similar to the pressure roller disclosed in the Chen, et al. patent (U.S. Pat. No. 6,429,249). Due to the incorporated fillers, the EC 4952 material usable for the base cushion layer of structure 22 has a relatively high nominal thermal conductivity of about 0.35 BTU/hr/ft/° F. However, the thermal conductivity of the base cushion layer of structure 22 is not critical to the operation of the fusing station. In certain circumstances, a considerably lower thermal conductivity of the base cushion layer of structure 22 may be preferable so as not to drain too much heat from the contact zone of nip 25. A preferred base cushion layer of pressure roller 20 is made of an elastomeric material having any suitable thermal conductivity, which elastomeric material has a Shore A hardness greater than about 50, preferably greater than about 60. The base cushion layer may include a particulate filler.
Operating in conjunction with fusing roller 10 is an oiling roller mechanism, generally indicated by numeral 30, including a wick 35 in contact with a liquid release agent (e.g., fuser oil) 34 contained in reservoir 33. Wick 35 absorbs the release agent 34 and transfers the release agent to a metering roller 32, with the amount of release agent on the surface of metering roller 32 controlled by blade 36. Metering roller 32 is in contact with a release agent donor roller 31, which release agent donor roller contacts fuser roller 10 and thereby delivers a continuous flow of release agent 34 to the surface of fuser roller 10. A preferred release agent donor roller is similar to that of the cited Chen, et al. patent application (U.S. patent application Ser. No. 09/960,661, filed Sep. 21, 2001).
Approximately 1 to 20 milligrams of release agent is needed for each receiver member (e.g., receiver member sheet 15) passing through nip 25. As is well known, a suitable release agent is typically a silicone oil. A preferred polymeric release agent 34 for use in the fusing station is an amine-functionalized polydimethylsiloxane having a preferred viscosity of about 300 centipoise as disclosed in the Chen, et al. patent (U.S. Pat. No. 6,190,771).
A suitable release agent donor roller 31 for use in the fusing station includes for example a hollow aluminum core of outer diameter about 0.875 inches, the core coated by a cushion layer about 0.230 inches thick made of a compliant material having a low thermal conductivity such as for example obtainable commercially as S5100 from Emerson and Cuming (Lexington, Mass.), with a release layer about 0.0025 inches thick coated on the cushion layer (individual layers not illustrated in FIG. 1). The release layer can be made from an interpenetrating network composed of a crosslinked fluoroelastomer and two different silicone elastomers such as disclosed in the Davis, et al. patent (U.S. Pat. No. 6,225,409). More preferably, the release layer is made of a copolymer of vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene as disclosed in the Chen, et al. patent (U.S. Pat. No. 6,429,249). Any suitable dimensions of the core, cushion layer, and release layer may be used.
In lieu of the oiling roller mechanism 30, an oiling web mechanism (not illustrated) may be used, the oiling web mechanism including a movable fuser-oil-impregnated donor web pressed against fuser roller 10 by using one or more backup rollers.
A selectively activated source of heat is located substantially within the interior hollow core member 14. The internal source of heat is preferably a tubular heating lamp 16 coaxially located along the central longitudinal axis of core member 14. Intermittent or variable ohmic heating (as may be required) of lamp 16 is selectively controllable by a programmable power supply (not shown).
As receiver member 15 traverses nip 25, the amount of heat transferred from fuser roller 10 to receiver member 15 and toner image 17 is dependent on the width of nip 25 and the thermal conductivity of annular structure 12. The wider the nip 25 and the higher the thermal conductivity of annular structure 12, the greater the amount of heat transferred to receiver member 15 and toner image 17. For a given nip pressure, the more compliant annular structure 12, the wider the nip 25. Heat transfer to receiver member 15 and toner image 17 is therefore maximized when both the compliance and thermal conductivity of annular structure 12 are maximized. Unfortunately compliance and thermal conductivity are contradistinctive.
Elastomeric materials suitable for use as compliant layers in fuser rollers have inherently low thermal conductivity. The thermal conductivity of these elastomeric materials may be increased by incorporating particulate fillers, such as for example metals, metal oxides, metal hydroxides, metal salts, and mixtures thereof into these elastomeric materials. The thermal conductivity, attainable by the use of one or more suitable particulate fillers, is determined by the filler concentration. The thermal conductivity generally increases as the filler concentration is increased. However, the compliance of these elastomeric materials generally decreases as the filler concentration is increased. It has been discovered that a novel combination of annular layer materials for annular structure 12 may be provided, with such combination resulting in higher heat transfer rates than prior art fusing rollers.
FIG. 2 shows an axial view cross section of a preferred embodiment of the fuser roller of the invention, designated generally be the numeral 10′, for use in an electrostatographic reproduction apparatus fusing station. Elements having a prime (′) in FIG. 2 refer to the corresponding unprimed elements in FIG. 1. The activated source of heat is a lamp 16′ which is entirely similar to the lamp 16 described above, and the core member 14′ is preferably thermally conductive and otherwise entirely similar to core member 14. In the preferred embodiment 10′, the elastically deformable annular structure 12′ is a trilayer structure including a base cushion layer 6 around the core member 14′, a high thermal conductivity layer 7 around the base cushion layer 6, and a flexible release layer 8 around the high thermal conductivity layer 7.
The base cushion layer (BCL) 6 is preferably formed on the core member 14′ by any suitable coating method, with BCL 6 having a thermal conductivity preferably in a range of approximately between 0.1 BTU/hr/ft/° F. to 0.2 BTU/hr/ft/° F., and more preferably between 0.15 BTU/hr/ft/° F. to 0.17 BTU/hr/ft/° F. Base cushion layer 6 may be made of any suitable resilient elastomeric material, such as for example a highly crosslinked polyorganosiloxane and may include a particulate filler. The filler is preferably primarily a structural filler for strengthening the base cushion layer, and the filler may further include a minority proportion of thermally conductive particles, such as for example particles of ferric oxide. The structural filler particles are made of materials such as mineral silica particles, fumed silica, and the like. The total weight percentage of filler in BCL 6 is preferably less than about 30% w/w, and more preferably is in a range of approximately between 10% w/w to 20% w/w. A filler in BCL 6 preferably has a particle size in a range of approximately between 0.1 μm to 20 μm, and more preferably 0.5 μm to 10 μm. BCL 6 may have any suitable thickness. Preferably, the thickness of BCL 6 is in a range of approximately between 0.180 inches to 0.250 inches, and more preferably, 0.190 inches to 0.195 inches.
The high thermal conductivity layer (HTCL) 7 has a thermal conductivity preferably equal to or greater than 1 BTU/hr/ft/° F. In the preferred embodiment HTCL 7 is a metal with a thermal conductivity greater than 5 BTU/hr/ft/° F. Such a metal may be copper, brass, aluminum, or nickel. In one embodiment HTCL 7 is a removable replaceable annular sleeve member comprised of electroformed nickel available from Stork Screens America, Inc., of Charlotte, N.C. HTCL 7 may also be fabricated from a metal sheet by, for example, forming a smooth seam by ultrasonic welding or by using an adhesive.
The flexible release layer 8 is preferably formed on the HTCL 7 by any suitable coating method including ring coating and blade coating. Flexible release layer (FRL) 8 is preferably made with a chemically unreactive, low surface energy, flexible, polymeric material suitable for high temperature use, such as for example a fluoropolymer. A preferred polymeric material for inclusion in FRL 8 is a fluorocarbon thermoplastic random copolymer (FLC) material such as for example the copolymer of vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene as disclosed in the Chen, et al. patent (U.S. Pat. No. 6,429,249), the FLC random copolymer having subunits of:
—(CH2CF2)x-, —(CF2CF(CF3))y-, and —(CF2CF2)z-,
wherein,
x is from 1 to 50 or 60 to 80 mole percent,
y is from 10 to 90 mole percent,
z is from 10 to 90 mole percent,
x+y+z equals 100 mole percent.
The FRL 8 may have any suitable thickness and may include one or more particulate fillers. It is preferred that the one or more particulate fillers in of FRL 8 include zinc oxide particles or fluoroethylenepropylene (FEP) resin particles. However, in substitution of or in addition to the aforementioned one or more particulate fillers, any other particulate filler material may be included in FRL 8, either singly or in combination. It is necessary for good release of a toner image to keep the filler concentration relatively low and the particle size of the filler small, so that a matte effect on the toner image due to filler particles at the surface of FRL 8 can be minimized.
A filler used in the formulation of FRL 8 preferably has a particle size in a range of approximately between 0.1 μm to 10 μm, and more preferably 0.1 μm to 2.0 μm. The total concentration of fillers included in FRL 8 is preferably less than about 20% by weight. Specifically, in a preferred formulation of FRL 8 which includes zinc oxide and FEP particles, the concentration of zinc oxide is in a range of approximately between 5% to 7% w/w, and the concentration of FEP particles is in a range of approximately between 7% to 9% w/w. Preferably, the thickness of the FRL 8 is in a range of approximately between 0.001 inches to 0.004 inches, and more preferably 0.0015 inches to 0.0025 inches. The thermal conductivity of FRL 8 is preferably no less than approximately 0.07 BTU/hr/ft/° F., and more preferably in a range of approximately between 0.08 BTU/hr/ft/° F. to 0.11 BTU/hr/ft/° F.
The outer surface of the FRL 8 is preferably very smooth and the smoothness can be measured by any known method. Typically the smoothness of FRL 8 can be characterized by a gloss measurement using for example a gloss meter, such as a Micro-TRI-Gloss 20-60-85 Glossmeter available from BYK Gardener USA of Rivers Park, Md. A Gardener gloss value is proportional to the intensity of specularly reflected light reflected off a surface divided by the intensity of the incident light for a specified angle of incidence measured from a perpendicular to the surface (angle of incidence equal to the angle of reflection), e.g., at 20, 60, or 85 degrees. Thus, a G60 gloss value is measured at an angle of 60 degrees. A suitable G60 gloss value for the FRL 8 is preferably greater than approximately 10, and more preferably, greater than or equal to approximately 12.
In summary, in improving over prior art, the subject fuser roller having a high thermal conductivity layer around a relatively thermally insulating base cushion layer gives a greatly improved heat transfer advantage for fusing toner images to receiver members in a fusing station of the invention. This improved heat transfer advantage can be utilized to provide a high productivity (throughput rate) of the fusing station for a given nominal fusing temperature as required by a given type of toner particles and type of receiver member. Alternatively, the improved heat transfer advantage permits the process speed to be reduced, thereby allowing a reduced external heating load from the external source of heat.
The invention has been described in detail with particular reference to certain preferred embodiments thereof, but it will be understood that variations and modifications can be effected within the spirit and scope of the invention.

Claims (18)

1. In a fusing station for fusing a toner image to a receiver member, said fusing station including a heated fuser roller operatively associated with a pressure roller, said fuser roller comprising:
a rigid, cylindrical, thermally conductive, metal core member;
a multilayer deformable annular structure around said core member, said deformable annular structure including an elastomeric base cushion layer innermost around said core member, a high thermal conductivity layer around said base cushion layer, said high thermal conductivity layer comprising a metal having thickness in a range of approximately between 0.002 inches to 0.005 inches, and a thin flexible toner release layer around said high thermal conductivity layer;
wherein thermal conductivity of said base cushion layer is lower than thermal conductivity of said high thermal conductivity layer; and
wherein the value of thermal conductivity of said high thermal conductivity layer is equal to or greater than 5 BTU/hr/ft/° F.
2. The fuser roller of claim 1, wherein:
said thermal conductivity of said base cushion layer is in a range of approximately between 0.1 BTU/hr/ft/° F. to 0.2 BTU/hr/ft/° F.; and
said thickness of said base cushion layer is in a range of approximately between 0.180 inches to 0.250 inches.
3. The fuser roller of claim 2, wherein:
said thermal conductivity of said base cushion layer is in a range of approximately between 0.15 BTU/hr/ft/° F. to 0.17 BTU/hr/ft/° F.; and
said thickness of said base cushion layer is in a range of approximately between 0.190 inches to 0.195 inches.
4. The fuser roller of claim 1, wherein said base cushion layer is an elastomeric material comprising less than 30% by weight of a particulate filler including a structural filler, said particulate filler including particles having sizes in a range of approximately between 0.1 μm to 20 μm, said particles including at least one particulate filler selected from the group consisting of: mineral silica particles, fumed silica particles, and iron oxide particles.
5. The fuser roller of claim 1, wherein:
said high thermal conductivity layer includes a metal with thermal conductivity equal to or greater than 5 BTU/hr/ft/° F. and thickness in a range of approximately between 0.002 inches to 0.005 inches.
6. The fuser roller of claim 1, wherein:
said metal is selected from the group consisting of: copper, brass, aluminum, and nickel.
7. The fuser roller of claim 1, wherein said thickness of said toner release layer is equal to or less than 0.0005 inches.
8. The fuser roller of claim 1, wherein said toner release layer includes a fluoropolymer.
9. The fuser roller of claim 8, wherein said fluoropolymer includes a random copolymer of vinylidene fluoride, tetrafluoroethylene, and hexafluoropropylene, said random copolymer having subunits of:

—(CH2CF2)x-, —(CF2CF(CF3))y-, and —(CF2CF2)z-,
wherein:
x is from 1 to 50 or 60 to 80 mole percent of vinylidene fluoride,
y is from 10 to 90 mole percent of hexafluoropropylene,
z is from 10 to 90 mole percent of tetrafluoroethylene, and
x+y+z equals 100 mole percent.
10. The fuser roller of claim 1, wherein said toner release layer includes a particulate filler.
11. The fuser roller of claim 10, wherein in said toner release layer, said particulate filler has a particle size in a range of approximately between 0.1 μm to 10 μm; and
said particulate filler has a total concentration in said toner release layer of less than about 20% by weight.
12. The fuser roller of claim 11, wherein said particulate filler has a particle size in a range of approximately between 0.1 μm to 2.0 μm.
13. The fuser roller of claim 10, wherein:
said particulate filler in said toner release layer includes zinc oxide particles and fluoroethylenepropylene resin particles, said zinc oxide particles having a concentration in a range of approximately between 5% to 7% by weight, and said fluoroethylenepropylene resin particles having a concentration in a range of approximately between 7% to 9% by weight.
14. The fuser roller of claim 1, wherein said fuser roller further comprises a removable replaceable annular sleeve member, said sleeve member including at least one of the layers included in said deformable annular structure.
15. The fuser roller of claim 1, wherein:
said base cushion layer includes an addition-crosslinked polydimethylsiloxane; and
said toner release layer includes a fluorocarbon thermoplastic random copolymer of vinylidene fluoride, tetrafluoroethylene and hexafluoropropylene.
16. The fuser roller of claim 1, wherein said flexible release layer includes a chemically unreactive, low surface energy, flexible, polymeric material suitable for high temperature use.
17. In an electrostatographic reproduction apparatus for forming a toner image on a receiver member, a fusing station for fusing said toner image to said receiver member, said fusing station comprising:
a pressure roller;
a fuser roller operatively associated with a pressure roller, said fuser roller being elastically deformable and engaged under pressure with said pressure roller so as to form a fusing nip there between, said pressure roller being relatively harder than said fuser roller, said toner image on said receiver member being moved through said fusing nip for said fusing;
wherein said fuser roller includes a rigid, cylindrical, thermally conductive core member; a multilayer deformable annular structure around said core member, said deformable annular structure including an elastomeric base cushion layer innermost around said core member, an high thermal conductivity layer around said base cushion layer, said high thermal conductivity layer comprising a metal having thickness in a range of approximately between 0.002 inches to 0.005 inches, and a thin flexible toner release layer around said high thermal conductivity layer;
wherein thermal conductivity of said base cushion layer is lower than thermal conductivity of said high thermal conductivity layer; and
wherein the value of thermal conductivity of said high thermal conductivity layer is equal to or greater than 5 BTU/hr/ft/° F.
18. The fusing station of claim 17, wherein further:
said thermal conductivity of said base cushion layer is in a range of approximately between 0.1 BTU/hr/ft/° F. to 0.2 BTU/hr/ft/° F.;
said thickness of said base cushion layer is in a range of approximately between 0.180 inches to 0.250 inches; and
said thickness of said toner release layer is equal to or less than 0.0005 inches.
US10/814,316 2004-03-31 2004-03-31 High heat transfer fuser roller Expired - Fee Related US7010258B2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US10/814,316 US7010258B2 (en) 2004-03-31 2004-03-31 High heat transfer fuser roller
PCT/US2005/008430 WO2005101136A1 (en) 2004-03-31 2005-03-15 High heat transfer fuser roller
EP05725531A EP1730602A1 (en) 2004-03-31 2005-03-15 High heat transfer fuser roller
TW094109224A TW200602821A (en) 2004-03-31 2005-03-25 High heat transfer fuser roller

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/814,316 US7010258B2 (en) 2004-03-31 2004-03-31 High heat transfer fuser roller

Publications (2)

Publication Number Publication Date
US20050220511A1 US20050220511A1 (en) 2005-10-06
US7010258B2 true US7010258B2 (en) 2006-03-07

Family

ID=34962674

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/814,316 Expired - Fee Related US7010258B2 (en) 2004-03-31 2004-03-31 High heat transfer fuser roller

Country Status (4)

Country Link
US (1) US7010258B2 (en)
EP (1) EP1730602A1 (en)
TW (1) TW200602821A (en)
WO (1) WO2005101136A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4882312B2 (en) * 2005-08-25 2012-02-22 富士ゼロックス株式会社 Method for producing fluororesin-coated member
US8718526B2 (en) * 2011-05-31 2014-05-06 Lexmark International, Inc. High fusing performance externally heated fuser roller
EP3004989A4 (en) * 2013-05-29 2017-02-08 Hewlett-Packard Development Company, L.P. Multilayer roller
TWI514095B (en) * 2013-11-01 2015-12-21 Teco Image Sys Co Ltd Fixing device and roller thereof
CN104614963A (en) * 2013-11-01 2015-05-13 东友科技股份有限公司 Roller and fixation device provided with roller
CN104614964B (en) * 2013-11-01 2017-11-24 东友科技股份有限公司 Fixing device and its roller
US9309359B2 (en) 2014-07-11 2016-04-12 The Boeing Company Temperature-resistant silicone resins
US9534089B2 (en) * 2014-07-11 2017-01-03 The Boeing Company Temperature-resistant silicone resins

Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4518244A (en) * 1981-10-29 1985-05-21 Toray Silicone Company, Ltd. Heat fixer roll with an evaporated metal surface
US4984027A (en) 1988-12-28 1991-01-08 Eastman Kodak Company Fusing apparatus with solid elastomeric fuser roller
US5450183A (en) 1992-07-23 1995-09-12 Eastman Kodak Company Image forming apparatus and method for producing high gloss duplex images
JPH10340023A (en) * 1997-06-05 1998-12-22 Ricoh Co Ltd Heating device
US5960245A (en) 1998-12-03 1999-09-28 Eastman Kodak Company Oil swell controlling fuser member having a silicone T-resin
US6020038A (en) 1997-08-22 2000-02-01 Eastman Kodak Company Fuser member with vinyl and hydride containing polydimethylsiloxane adhesive layer
US6190771B1 (en) 1998-12-28 2001-02-20 Jiann H. Chen Fuser assembly with donor roller having reduced release agent swell
US6225409B1 (en) 1998-09-18 2001-05-01 Eastman Kodak Company Fluorosilicone interpenetrating network and methods of preparing same
JP2002055557A (en) * 2000-08-10 2002-02-20 Dymco:Kk Elastic rotational body and fixing device having the same
US6429249B1 (en) 2000-06-30 2002-08-06 Nexpress Solutions Llc Fluorocarbon thermoplastic random copolymer composition
US6490430B1 (en) 2000-10-04 2002-12-03 Nexpress Solutions Llc Externally heated roller for a toner fusing station
US6512913B2 (en) * 2001-03-28 2003-01-28 Hewlett-Packard Company Fusing system including a heat storage mechanism
US6567641B1 (en) 2000-10-04 2003-05-20 Nexpress Solutions Llc Sleeved rollers for use in a fusing station employing an externally heated fuser roller
US6607259B2 (en) * 2001-10-11 2003-08-19 Hewlett-Packard Development Company, L.P. Thermal inkjet printer having enhanced heat removal capability and method of assembling the printer
US6678495B1 (en) * 1999-10-11 2004-01-13 Xerox Corporation Epoxy silane cured fluoropolymers
US20040165917A1 (en) * 2003-02-20 2004-08-26 Tomoaki Sugawara Fixing device using a rotary body and image forming apparatus including the same
US20050141935A1 (en) * 2003-12-23 2005-06-30 Jiann-Hsing Chen Fuser roller and fusing station

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6517346B1 (en) * 2002-05-06 2003-02-11 Nexpress Solutions Llc Fusing station with improved fuser roller
JP2004053928A (en) * 2002-07-19 2004-02-19 Nitto Kogyo Co Ltd Method for production of fixing roller

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4518244A (en) * 1981-10-29 1985-05-21 Toray Silicone Company, Ltd. Heat fixer roll with an evaporated metal surface
US4984027A (en) 1988-12-28 1991-01-08 Eastman Kodak Company Fusing apparatus with solid elastomeric fuser roller
US5450183A (en) 1992-07-23 1995-09-12 Eastman Kodak Company Image forming apparatus and method for producing high gloss duplex images
JPH10340023A (en) * 1997-06-05 1998-12-22 Ricoh Co Ltd Heating device
US6020038A (en) 1997-08-22 2000-02-01 Eastman Kodak Company Fuser member with vinyl and hydride containing polydimethylsiloxane adhesive layer
US6225409B1 (en) 1998-09-18 2001-05-01 Eastman Kodak Company Fluorosilicone interpenetrating network and methods of preparing same
US5960245A (en) 1998-12-03 1999-09-28 Eastman Kodak Company Oil swell controlling fuser member having a silicone T-resin
US6190771B1 (en) 1998-12-28 2001-02-20 Jiann H. Chen Fuser assembly with donor roller having reduced release agent swell
US6678495B1 (en) * 1999-10-11 2004-01-13 Xerox Corporation Epoxy silane cured fluoropolymers
US6429249B1 (en) 2000-06-30 2002-08-06 Nexpress Solutions Llc Fluorocarbon thermoplastic random copolymer composition
JP2002055557A (en) * 2000-08-10 2002-02-20 Dymco:Kk Elastic rotational body and fixing device having the same
US6567641B1 (en) 2000-10-04 2003-05-20 Nexpress Solutions Llc Sleeved rollers for use in a fusing station employing an externally heated fuser roller
US6490430B1 (en) 2000-10-04 2002-12-03 Nexpress Solutions Llc Externally heated roller for a toner fusing station
US6512913B2 (en) * 2001-03-28 2003-01-28 Hewlett-Packard Company Fusing system including a heat storage mechanism
US6607259B2 (en) * 2001-10-11 2003-08-19 Hewlett-Packard Development Company, L.P. Thermal inkjet printer having enhanced heat removal capability and method of assembling the printer
US20040165917A1 (en) * 2003-02-20 2004-08-26 Tomoaki Sugawara Fixing device using a rotary body and image forming apparatus including the same
US20050141935A1 (en) * 2003-12-23 2005-06-30 Jiann-Hsing Chen Fuser roller and fusing station

Also Published As

Publication number Publication date
US20050220511A1 (en) 2005-10-06
WO2005101136A1 (en) 2005-10-27
EP1730602A1 (en) 2006-12-13
TW200602821A (en) 2006-01-16

Similar Documents

Publication Publication Date Title
US6582222B1 (en) Fusing station including multilayer fuser roller
US6567641B1 (en) Sleeved rollers for use in a fusing station employing an externally heated fuser roller
US4883715A (en) Elastic rotatable member
EP1730602A1 (en) High heat transfer fuser roller
US8326200B2 (en) Fixing device, image forming apparatus and method of controlling fixing device
US7457575B2 (en) Fusing device, image forming apparatus, and belt
US20080063444A1 (en) Fixing member and image forming apparatus using the same
US6393247B1 (en) Toner fusing station having an internally heated fuser roller
JP2004139040A (en) Fixing device, fixing method and image forming apparatus
US6989182B2 (en) Fluoroelastomer roller for a fusing station
US7008678B2 (en) Roller for a fusing station
US6463250B1 (en) Externally heated deformable fuser roller
US5918099A (en) Fuser components with polyphenylene sulfide layer
CA2400992C (en) Fuser member having high temperature plastic layer
JP2004139039A (en) Fixing device, fixing method and image forming apparatus
US6517346B1 (en) Fusing station with improved fuser roller
US7014899B2 (en) Roller for use in a fusing station
US6118968A (en) Intermediate transfer components including polyimide and polyphenylene sulfide layers
US20050015987A1 (en) Metering roller for fuser release oil applicator
US7001653B2 (en) Fusing-station roller
JP2010128429A (en) Image heating device and heating rotating member used for the same
JP2007025475A (en) Heat fixing device and image forming apparatus
JP2007212580A (en) Transfer fixing device and image forming apparatus equipped therewith
US6801745B1 (en) Fuser for an electrophotographic printer and method of using same
US20060067752A1 (en) Belt fuser assembly with heated backup roll in an electrophotographic imaging device

Legal Events

Date Code Title Description
AS Assignment

Owner name: NEXPRESS SOLUTIONS LLC, NEW YORK

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:WU, FANGSHENG;ASLAM, MUHAMMED;REEL/FRAME:015163/0312

Effective date: 20040329

AS Assignment

Owner name: EASTMAN KODAK COMPANY, NEW YORK

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:NEXPRESS SOLUTIONS, INC. (FORMERLY NEXPRESS SOLUTIONS LLC);REEL/FRAME:016508/0075

Effective date: 20040909

Owner name: EASTMAN KODAK COMPANY,NEW YORK

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:NEXPRESS SOLUTIONS, INC. (FORMERLY NEXPRESS SOLUTIONS LLC);REEL/FRAME:016508/0075

Effective date: 20040909

FEPP Fee payment procedure

Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

FPAY Fee payment

Year of fee payment: 4

AS Assignment

Owner name: CITICORP NORTH AMERICA, INC., AS AGENT, NEW YORK

Free format text: SECURITY INTEREST;ASSIGNORS:EASTMAN KODAK COMPANY;PAKON, INC.;REEL/FRAME:028201/0420

Effective date: 20120215

AS Assignment

Owner name: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS AGENT,

Free format text: PATENT SECURITY AGREEMENT;ASSIGNORS:EASTMAN KODAK COMPANY;PAKON, INC.;REEL/FRAME:030122/0235

Effective date: 20130322

Owner name: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS AGENT, MINNESOTA

Free format text: PATENT SECURITY AGREEMENT;ASSIGNORS:EASTMAN KODAK COMPANY;PAKON, INC.;REEL/FRAME:030122/0235

Effective date: 20130322

FPAY Fee payment

Year of fee payment: 8

AS Assignment

Owner name: EASTMAN KODAK COMPANY, NEW YORK

Free format text: RELEASE OF SECURITY INTEREST IN PATENTS;ASSIGNORS:CITICORP NORTH AMERICA, INC., AS SENIOR DIP AGENT;WILMINGTON TRUST, NATIONAL ASSOCIATION, AS JUNIOR DIP AGENT;REEL/FRAME:031157/0451

Effective date: 20130903

Owner name: BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT, NEW YO

Free format text: INTELLECTUAL PROPERTY SECURITY AGREEMENT (SECOND LIEN);ASSIGNORS:EASTMAN KODAK COMPANY;FAR EAST DEVELOPMENT LTD.;FPC INC.;AND OTHERS;REEL/FRAME:031159/0001

Effective date: 20130903

Owner name: BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT, NEW YORK

Free format text: INTELLECTUAL PROPERTY SECURITY AGREEMENT (SECOND LIEN);ASSIGNORS:EASTMAN KODAK COMPANY;FAR EAST DEVELOPMENT LTD.;FPC INC.;AND OTHERS;REEL/FRAME:031159/0001

Effective date: 20130903

Owner name: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE, DELAWARE

Free format text: INTELLECTUAL PROPERTY SECURITY AGREEMENT (FIRST LIEN);ASSIGNORS:EASTMAN KODAK COMPANY;FAR EAST DEVELOPMENT LTD.;FPC INC.;AND OTHERS;REEL/FRAME:031158/0001

Effective date: 20130903

Owner name: PAKON, INC., NEW YORK

Free format text: RELEASE OF SECURITY INTEREST IN PATENTS;ASSIGNORS:CITICORP NORTH AMERICA, INC., AS SENIOR DIP AGENT;WILMINGTON TRUST, NATIONAL ASSOCIATION, AS JUNIOR DIP AGENT;REEL/FRAME:031157/0451

Effective date: 20130903

Owner name: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE, DELA

Free format text: INTELLECTUAL PROPERTY SECURITY AGREEMENT (FIRST LIEN);ASSIGNORS:EASTMAN KODAK COMPANY;FAR EAST DEVELOPMENT LTD.;FPC INC.;AND OTHERS;REEL/FRAME:031158/0001

Effective date: 20130903

Owner name: BANK OF AMERICA N.A., AS AGENT, MASSACHUSETTS

Free format text: INTELLECTUAL PROPERTY SECURITY AGREEMENT (ABL);ASSIGNORS:EASTMAN KODAK COMPANY;FAR EAST DEVELOPMENT LTD.;FPC INC.;AND OTHERS;REEL/FRAME:031162/0117

Effective date: 20130903

FEPP Fee payment procedure

Free format text: MAINTENANCE FEE REMINDER MAILED (ORIGINAL EVENT CODE: REM.)

AS Assignment

Owner name: MIDWEST ATHLETICS AND SPORTS ALLIANCE LLC, NEBRASK

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:EASTMAN KODAK COMPANY;REEL/FRAME:044811/0502

Effective date: 20171120

AS Assignment

Owner name: MIDWEST ATHLETICS AND SPORTS ALLIANCE LLC, NEBRASK

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:EASTMAN KODAK COMPANY;REEL/FRAME:044811/0245

Effective date: 20171120

AS Assignment

Owner name: EASTMAN KODAK COMPANY, NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BANK OF AMERICA N.A.;REEL/FRAME:045095/0299

Effective date: 20171115

Owner name: EASTMAN KODAK COMPANY, NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK N.A.;REEL/FRAME:045095/0317

Effective date: 20171115

LAPS Lapse for failure to pay maintenance fees

Free format text: PATENT EXPIRED FOR FAILURE TO PAY MAINTENANCE FEES (ORIGINAL EVENT CODE: EXP.)

STCH Information on status: patent discontinuation

Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362

FP Lapsed due to failure to pay maintenance fee

Effective date: 20180307

AS Assignment

Owner name: KODAK REALTY, INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:050239/0001

Effective date: 20190617

Owner name: KODAK PORTUGUESA LIMITED, NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:050239/0001

Effective date: 20190617

Owner name: KODAK IMAGING NETWORK, INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:050239/0001

Effective date: 20190617

Owner name: EASTMAN KODAK COMPANY, NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:050239/0001

Effective date: 20190617

Owner name: CREO MANUFACTURING AMERICA LLC, NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:050239/0001

Effective date: 20190617

Owner name: KODAK PHILIPPINES, LTD., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:050239/0001

Effective date: 20190617

Owner name: LASER PACIFIC MEDIA CORPORATION, NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:050239/0001

Effective date: 20190617

Owner name: FAR EAST DEVELOPMENT LTD., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:050239/0001

Effective date: 20190617

Owner name: NPEC, INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:050239/0001

Effective date: 20190617

Owner name: PAKON, INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:050239/0001

Effective date: 20190617

Owner name: KODAK (NEAR EAST), INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:050239/0001

Effective date: 20190617

Owner name: FPC, INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:050239/0001

Effective date: 20190617

Owner name: KODAK AMERICAS, LTD., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:050239/0001

Effective date: 20190617

Owner name: QUALEX, INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:050239/0001

Effective date: 20190617

Owner name: KODAK AVIATION LEASING LLC, NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:050239/0001

Effective date: 20190617

AS Assignment

Owner name: KODAK PORTUGUESA LIMITED, NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:049901/0001

Effective date: 20190617

Owner name: LASER PACIFIC MEDIA CORPORATION, NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:049901/0001

Effective date: 20190617

Owner name: QUALEX, INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:049901/0001

Effective date: 20190617

Owner name: KODAK IMAGING NETWORK, INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:049901/0001

Effective date: 20190617

Owner name: CREO MANUFACTURING AMERICA LLC, NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:049901/0001

Effective date: 20190617

Owner name: KODAK PHILIPPINES, LTD., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:049901/0001

Effective date: 20190617

Owner name: PFC, INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:049901/0001

Effective date: 20190617

Owner name: NPEC, INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:049901/0001

Effective date: 20190617

Owner name: KODAK REALTY, INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:049901/0001

Effective date: 20190617

Owner name: KODAK (NEAR EAST), INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:049901/0001

Effective date: 20190617

Owner name: KODAK AVIATION LEASING LLC, NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:049901/0001

Effective date: 20190617

Owner name: FAR EAST DEVELOPMENT LTD., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:049901/0001

Effective date: 20190617

Owner name: EASTMAN KODAK COMPANY, NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:049901/0001

Effective date: 20190617

Owner name: KODAK AMERICAS, LTD., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:049901/0001

Effective date: 20190617

Owner name: PAKON, INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT;REEL/FRAME:049901/0001

Effective date: 20190617

AS Assignment

Owner name: FPC INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BARCLAYS BANK PLC;REEL/FRAME:052773/0001

Effective date: 20170202

Owner name: FAR EAST DEVELOPMENT LTD., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BARCLAYS BANK PLC;REEL/FRAME:052773/0001

Effective date: 20170202

Owner name: KODAK (NEAR EAST) INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BARCLAYS BANK PLC;REEL/FRAME:052773/0001

Effective date: 20170202

Owner name: KODAK PHILIPPINES LTD., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BARCLAYS BANK PLC;REEL/FRAME:052773/0001

Effective date: 20170202

Owner name: KODAK REALTY INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BARCLAYS BANK PLC;REEL/FRAME:052773/0001

Effective date: 20170202

Owner name: LASER PACIFIC MEDIA CORPORATION, NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BARCLAYS BANK PLC;REEL/FRAME:052773/0001

Effective date: 20170202

Owner name: QUALEX INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BARCLAYS BANK PLC;REEL/FRAME:052773/0001

Effective date: 20170202

Owner name: KODAK AMERICAS LTD., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BARCLAYS BANK PLC;REEL/FRAME:052773/0001

Effective date: 20170202

Owner name: EASTMAN KODAK COMPANY, NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BARCLAYS BANK PLC;REEL/FRAME:052773/0001

Effective date: 20170202

Owner name: NPEC INC., NEW YORK

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:BARCLAYS BANK PLC;REEL/FRAME:052773/0001

Effective date: 20170202