US6887351B1 - Process for regulating the porosity and printing properties of paper by use of colloidal precipitated calcium carbonate, and paper containing such colloidal precipitated calcium carbonate - Google Patents

Process for regulating the porosity and printing properties of paper by use of colloidal precipitated calcium carbonate, and paper containing such colloidal precipitated calcium carbonate Download PDF

Info

Publication number
US6887351B1
US6887351B1 US09/701,261 US70126101A US6887351B1 US 6887351 B1 US6887351 B1 US 6887351B1 US 70126101 A US70126101 A US 70126101A US 6887351 B1 US6887351 B1 US 6887351B1
Authority
US
United States
Prior art keywords
paper
pcc
colloidal
porosity
μm
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
US09/701,261
Inventor
Klaus Akilles Lunden
Ib Attrup
Jens Toftelund Madsen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
J M Huber Denmark ApS
Original Assignee
J M Huber Denmark ApS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
Priority to DK73598 priority Critical
Application filed by J M Huber Denmark ApS filed Critical J M Huber Denmark ApS
Priority to PCT/DK1999/000286 priority patent/WO1999061703A1/en
Application granted granted Critical
Publication of US6887351B1 publication Critical patent/US6887351B1/en
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8096945&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=US6887351(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/04Addition to the pulp; After-treatment of added substances in the pulp
    • D21H23/06Controlling the addition
    • D21H23/12Controlling the addition by measuring properties of the formed web
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675Oxides, hydroxides or carbonates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/22Agents rendering paper porous, absorbent or bulky

Abstract

The invention relates to a process for regulating the porosity and printing properties of paper, in particular uncoated wood-containing paper such as SC-paper, wherein a sufficient quantity of colloidal PCC having a BET surface area of 10-100 m2/g is used as a filter in the paper to achieve a desired porosity of the paper; as well as paper containing colloidal PCC as filler, and a pigment mixture suitable for paper manufacture and containing colloidal PCC.

Description

FIELD OF THE INVENTION

The invention relates to use of colloidal PCC (precipitated calcium carbonate) as a filler in the preparation of paper for the purpose of controlling the porosity and printing properties of the paper.

BACKGROUND OF THE INVENTION

In the connection with the manufacture of paper it is very important to be able to control the porosity of the paper. For example, a paper with low porosity is required in order to obtain an acceptable result in, e.g., ink-jet and rotogravure printing. If the paper is too porous it will function like blotting paper during printing and the resulting print may appear blurred, the contrast between printed and unprinted areas or between differently coloured areas not being rendered sharply. Similarly, on a paper which is of non-uniform porosity it can be seen that the intensity of colouration varies (“mottling”), which is of course undesirable since the coloured surface appears variegated or mottled. On the other hand, the porosity of the paper can also be too low, since a very dense paper will have difficulty in absorbing printing ink, which among other things may result in smudging (“set off”) between printed sheets. This phenomenon can influence the printing results, the printing speed and the printing process employed in a negative manner.

The paper industry presently uses several different ways of regulating the porosity of paper. Use is made among other things of the fact that certain minerals in the form of flakes, e.g. talc and kaolin, will, as result of their form, be able to reduce the porosity since the individual particles will become deposited like the scales on a fish and thereby seal the surface. Fine silicates can be used in connection with pigmentation to reduce the porosity of the paper. When they come into or onto the paper, these fine particles will close the pores which contribute to the porosity of the paper.

In order to regulate the properties of the paper, a combination of one or more fillers and a variety of other additives is often used. Among the group of additives are alkylketene dimers (AKD), alkenylsuccinic acid anhydride (ASA), starch and retention agents. Retention agents are added to facilitate the manufacture of the paper, whilst AKD, ASA and starch are added to ensure the quality of the paper (strength, printing properties, etc.).

Regardless of which of the presently known methods is used, they all have drawbacks. Kaolin and talc in the form of flakes will negatively influence the brightness of the paper compared to the whiter fillers, such as ground marble or PCC (precipitated calcium carbonate).

The fine silicate products used for pigmentation have relatively good technical properties. However, the silicate products have the disadvantage of being much more expensive than the fillers normally used in paper manufacture. The same applies to other additives normally used in connection with paper manufacture. These are often many times more expensive than a calcium carbonate filler.

Over the years, numerous attempts have been made to optimise paper compositions precisely for the purpose of improving the porosity and printing properties of the paper. The problem has been, however, that none of these approaches to a solution have been ideal, since they have either had a negative influence on the other properties of the paper (among other things the brightness) or are relatively expensive to use (silicate products).

The use of colloidal PCC as such in paper is known. For example, U.S. Pat. No. 4,892,590 discloses the use of a two-component binder system as a retention agent for paper manufacture, wherein the binder comprises colloidal PCC with a high specific surface area together with a cationic starch. The PCC used has a surface area of 10-200 m2/g, and the weight ratio between PCC and cationic starch is from 2:1 to 1:20.

U.S. Pat. No. 4,460,637 discloses ink-jet paper (coated paper) with 2 different peaks of pore size distribution in the ink-receiving layer or layers. The desired pore size distribution can be achieved, inter alia by means of agglomerates with an average diameter of 1-50 μm in which the individual particles in the agglomerates have a size of at most 0.20 μm, e.g. colloidal particles of at most 0.01 μm; such colloidal particles can be colloidal calcium carbonate.

It is not believed that colloidal PCC has previously been described or used as a filler in paper for the purpose of controlling the porosity and printing properties of the paper.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a graph showing the particle sized distribution of a PCC product according to the invention.

FIG. 2 is a SCM picture of typical aggregates in a product according to the invention.

DESCRIPTION OF THE INVENTION

It has not been found that use of colloidal PCC with a large surface area as a filler makes it possible to replace a proportion of the previously mentioned pigments whilst also providing the possibility of regulating the porosity and printability properties of the paper. Compared with the previously described methods, the use of colloidal PCC has numerous advantages. It is cheap, produces low wear, it can produce greater brightness than kaolin and talc flakes, and the product is more adaptable to individual types of paper.

In its broadest aspect, the present invention relates to the use of colloidal PCC as a filler to control the porosity and printing properties of paper, in particular to reduce the porosity relative to the porosity which can otherwise be achieved with other types of fillers and pigments conventionally used in the manufacture of paper.

One aspect of the invention thus relates to a process for regulating the porosity and printing properties of paper, wherein a sufficient quantity of colloidal PCC having a BET surface area of 10-100 m2/g is used as a filler to achieve a desired porosity of the paper.

In another aspect, the invention relates to paper containing colloidal PCC as a filler.

In a third aspect, the invention relates to a pigment mixture which is suitable for manufacture of paper and which contains colloidal PCC.

Other aspects and preferred embodiments will be apparent from the following detailed description of the invention.

As employed in the present description and claims, the term “colloidal PCC” (chemical formula: CaCO3) designates a PCC product in the form of aggregates/agglomerates of individual PCC particles in which the aggregates/agglomerates have a surface area of at least 10 m2/g as determined by the BET method (Brunauer, Emmet, Teler, DIN 66131). The aggregates/agglomerates preferably have an equivalent spherical particle size (median particle size, MPS) in the range about 0.1-5.0 μm, e.g. about 0.2-4 μm, typically about 0.5-3.0 μm, as determined e.g. by sedimentation on a Sedigraph 5100 from Micromeritics. The aggregates'/agglomerates' BET surface area will typically be up to about 100 m2/g, more typically up to about 80 m2/g, e.g. up to about 50 m2/g, e.g. up to about 30 m2/g and typically at least about 15 m2/g, e.g. at least about 20 m2/g. The aggregates/agglomerates consist of a greater or smaller number of single crystals having an equivalent spherical particle size of, typically, about 0.01-0.50 μm.

It will be apparent to the skilled person that colloidal PCC can also occur as aggregates with a surface area of less than 10 m2/g, but as mentioned above the expression “colloidal PCC” in the context of the present application is to be understood as PCC with the stated surface area of at least 10 m2/g. Correspondingly, according to the present invention a PCC mixture in which a part of the mixture is colloidal PCC with a surface area of at least 10 m2/g and a part of the mixture is “non-colloidal PCC” can be used, “non-colloidal PCC” being defined as PCC with a surface area of less than 10 m2/g.

An example of a colloidal PCC product according to the invention is given in the table below:

Parameter Value Median particle size, MPS (μm) 1.5 Brightness (R457-ISO, %) 95.8 Surface area (BET, m2/g) 25.0

The particle size distribution of this PCC product is shown in FIG. 1, whilst FIG. 2 shows a SEM picture of typical aggregates.

The colloidal PCC can, if desired, be used alone, i.e. as sole filler or pigment, in the manufacture of paper, but will presumably normally be used with at least one further filler or pigment. These further fillers and pigments can be selected among both non-colloidal PCC and other types of fillers. There is a wide variety of types of PCC with different crystal forms which are suited as a filler, e.g. scalenohedral PCC, rhombohedral PCC, needle-shaped PCC (aragonite) and spherical PCC (vaterite). Among other types of filler and pigments which are suited for incorporation in paper, the following can be named: kaolin, calcined kaolin, talc, gypsum, ground marble, aluminium silicate, calcium silicate, magnesium silicate and other silicate-containing minerals, calcium sulphate, barium sulphate, titanium dioxide, zinc oxide, zinc carbonate, calcium sulfoaluminates (satin white), aluminium hydroxide, diatomaceous earth, plastic particles and organic pigments. Paper manufactured according to the present invention can, in addition to the colloidal PCC, suitably contain one or more such PCC or non-PCC fillers or pigments to obtain the desired paper properties. Preferred further fillers are non-colloidal PCC, kaolin, calcined kaolin, talc, gypsum, chalk, ground marble, silicate-containing minerals and calcium sulfoaluminates. Non-colloidal PCC, kaolin, calcined kaolin, chalk and ground marble are particularly preferred.

The finding which forms the basis of the invention, namely the fact that the porosity of paper can be regulated accurately by means of colloidal PCC, provides the advantage, however, that the relative amount of the colloidal PCC relative to other fillers and/or pigments, as well as the colloidal PCC's properties (especially the surface area), can be adjusted in each individual case in order to achieve the properties which are desired for the paper in question. It is thus clear that the amount of colloidal PCC which is to be used depends on the type of paper to be manufactured and on the type and amount of any other fillers. The amount of colloidal PCC to be used can therefore vary widely, i.e. from about 1% by weight of the total filler up to 100% of the total filler. The colloidal PCC will normally be used in an amount of at least 10% by weight, more typically at least 20% by weight, e.g. at least about 50% by weight, based on the weight of the total filler. The precise amount of colloidal PCC to be used in order to achieve the desired properties for a given paper, including a particular porosity, will be easily determined by the skilled person, e.g. by simply preparing a series of paper samples in which there are used different amounts of the colloidal PCC relative to the other fillers.

Typically, the amount of colloidal PCC used according to the invention will be at least about 1% by weight based on the total weight of the paper, more typically at least about 2% by weight, e.g. at least about 3% by weight, such as at least about 4% or 5% by weight. Depending on the total amount of filler in the paper and the proportion of the filler that is comprised by the colloidal PCC, the colloidal PCC can of course be present in significantly higher amounts, however.

According to the invention, the colloidal PCC can be used as a filler to regulate the porosity and printing properties of any type of paper, including e.g. wood-containing paper such as super-calendered (SC) paper/newsprint and wood-free paper such as fine paper. The invention is particularly suited for regulating the porosity and printing properties of uncoated paper, more particularly uncoated wood-containing paper, since these properties can be difficult to regulate in such paper compared to coated paper, where the porosity is controlled by the coating layer. In a preferred embodiment, the invention relates to the use of the colloidal PCC in the preparation of SC paper.

It will be known to persons skilled in the art of paper manufacturing that the terms “wood-containing” and “wood-free” refer to whether or not the lignin component of the ligno-cellulose wood fibres has been removed. These terms are used herein in accordance with their conventional meanings in the art, i.e. “wood-free” refers to cellulose fibres in which substantially all or at least most of the lignin has been removed, whereas “wood-containing” refers to ligno-cellulose fibres in which the lignin component has not been removed. While the specific amount of lignin that can be present in “wood-free” pulp may vary from country to country, this amount is relatively small. For example, in Finland wood-free paper is defined as paper in which less than 10% by weight of the pulp is groundwood or other lignin-containing pulp. In the present context, “wood-containing paper” thus refers to paper in which the fibres comprise a substantial lignin component, wherein typically at least about 5% by weight of the pulp is lignin-containing pulp, more typically at least about 10% by weight, such as at least about 15 or 20% by weight.

Removal of lignin to result in wood-free fibres can performed by means of various well-known processes, e.g. using the Kraft process or by sulphite pulping. Such processes that remove lignin from the wood fibres result in higher quality, but also more expensive fibres.

In the case of SC paper, in particular SC-A paper, containing colloidal PCC according to the invention, the porosity can e.g. be reduced to a value of at most about 0.30 μm/Pas, e.g. at most about 0.28 μm/Pas, e.g. at most about 0.26 μM/Pas, e.g. at most about 0.24 μM/Pas, e.g. at most about 0.22 μM/Pas. In other words, the porosity of the paper can be reduced to a value around, or possibly even lower than, the value of the porosity of an equivalent paper prepared on the basis of kaolin; this is illustrated in Example 1.

The present invention also allows improved porosity values in SC-B paper. Thus, SC-B paper containing colloidal PCC according to the invention may have a porosity of at most about 0.60 μm/Pas, e.g. at most about 0.50 μm/Pas, e.g. at most about 0.40 μm/Pas, e.g. at most about 0.35 μm/Pas.

It will be known to persons skilled in the art that SC paper may be classified into one of several subcategories based on properties of brightness, filler level, roughness, sheet gloss and porosity. The top grade of SC paper is thus SC-A+. SC-A paper typically differs from SC-A+ in having a somewhat lower brightness, while SC-B typically differs from SC-A in having one or more of a lower brightness, a lower filler level, a lower sheet gloss and a higher porosity.

In the context of the present specification and claims, the SC paper grades SC-A, SC-A+ and SC-B are defined as follows.

SC-A

Brightness≧64%

Filler level≧30%

Roughness (0.5 bar)≦2.0 μm

Roughness (1 bar)≦1.5 μm

Porosity≦0.3 μm/Pas

SC-A+

As SC-A above, but brightness≧70%

SC-B

SC papers that do not fulfil the requirements for SC-A, but which fulfil the following requirements:

Brightness≧64%

Filler level≧15%

Roughness (0.5 bar)≦3.0 μm

Roughness (1 bar)≦2.5 μm

Porosity≦0.6 μm/Pas

In the case of newsprint, the use of colloidal PCC according to the invention will make it possible to reduce the porosity of the paper to a value of at most about 20 μm/Pas, e.g. at most about 18 μm/Pas, e.g. at most about 16 μm/Pas; this is illustrated in Example 2. For SC paper, newsprint and other types of paper the porosity achieved in each case will depend among other things on the pulp used and on the amount and properties of the colloidal PCC and any other fillers used. The above mentioned porosity values for SC paper and newsprint, respectively, are therefore only to be taken as examples, the important feature of the invention being the possibility of regulating (reducing) the porosity relative to the porosity which would otherwise be achievable in a given paper using a filler according to the prior art.

Colloidal PCC can be prepared in a known manner by carbonating milk of lime (calcium hydroxide slurry) under suitable conditions. The following conditions are to be regarded as a non-limiting example of the preparation of colloidal PCC.

Burnt lime having a reactivity (DIN T60) of between 10 sec. and 5 min. is slaked in 40° C. warm water using a water/lime ratio of 4:1. The thus-prepared milk of lime is diluted to 40% dry matter content, after which it is screened through a 500 μm screen.

After screening, the milk of lime is cooled to 20° C. and carbonated in an appropriate gas flow reactor using flue gas or a CO2-air mixture typically containing 20% CO2. Carbonation is continued until the pH has fallen below 8.

At a gas flow of 2.5 m3 flue gas per m3 reactor volume the reaction will occur over a period of about 3 hours. After carbonation is completed the colloidal PCC is screened through a 45 μm screen.

The invention is further illustrated by the following non-limiting examples.

In the example below, the following standards were used for determining paper properties:

Gram weight: Scan-P 6:75 Thickness: Scan-P 7:96 Density: Sacn-P 7:96 Gloss: Tappi T480 om-92 Brightness: ISO 2470 Opacity: ISO 2471 Roughness: Scan-P 76:95 Porosity: PPS method

All amounts are by weight unless otherwise indicated.

EXAMPLE 1 Regulation of Porosity in SC Paper

The following pigments were tested in SC paper:

Kaolin reference Rhombohedral PCC Colloidal PCC Filler - M Standard product Experimental (ECC (Faxe Paper product (Faxe Paper International) Pigments A/S) Pigments A/S) Brightness 78.9 97.0 95.9 (R457-ISO, %) MPS (μm) 3.3 1.8 1.1 BET 9.0 6.2 25 (m2/g)

The test was carried out on a pilot paper machine with filler levels of 27, 30 and 33%.

The fibers were of Scandinavian origin and consisted of:

    • TMP (thermomechanical pulp) and GW (groundwood) 85%
    • Kraft (cellulose fibers processed by the “kraft” process) 15%

The following chemicals were used in the manufacturing process:

    • Retention agent none
    • Other none
    • pH adjusted to 7.3 by addition of H3PO4.

For comparison purposes the results for paper are interpolated to 30% filler after calendering. The results are shown in the table below.

Kaolin reference Rhombohedral PCC Colloidal PCC Gram weight 55 56 56 (g/m2) Thickness (μm) 49 54 55 Density (g/m2) 1.123 1.030 1.020 Gloss (75°, %) 35 32 36 Brightness 69.6 76.3 72.5 (R457-ISO, %) Opacity (%) 86.8 90.0 85.9 Roughness 1.48 1.48 1.46 (μm) Porosity 0.19 0.32 0.21 μm/Pas

It can be seen from the above table that colloidal PCC surprisingly is capable of lowering the porosity of the paper from 0.32 μm/Pas using a standard PCC to 0.21 μm/Pas with colloidal PCC, which is on a par with the kaolin reference.

EXAMPLE 2 Reduction of Porosity of Newsprint using Colloidal PCC as Filler

The following pigments were tested in newsprint:

Reference Colloidal PCC Calcined Faxe Chalk 89 Rhombohedral Experimental Kaolin Chalk PCC product (Ansilex from (Faxe Kridt (Faxe Paper (Faxe Paper Engelhard) A/S) Pigments A/S) Pigments A/S) Brightness 89.6 87.4 96.2 95.7 (R457-ISO, %) MPS (μm) 0.9 1.5 1.2 1.1 BET (m2/g) 15.0 3.2 9.2 23.0

The test was carried out on a pilot paper machine with filler levels from 2-10%.

The fibres consisted of:

    • Unbleached TMP (thermomechanical pulp) 95%
    • Bleached cellulose prepared by the sulphate process 5%

The following chemicals were used in the preparation:

    • Retention agent Percol 23OL (cationic polyacrylamide from Allied Colloids)
    • Other none
    • pH adjusted to 7.3 by addition af H2SO4.

For comparison purposes the results for paper are interpolated to 4% filler. The results are given in the following table, the gram weight of the papers being 46 g/m2.

Reference Colloidal PCC Calcined Faxe Chalk 89 Rhombohedral Experimental Kaolin Chalk PCC product (Ansilex from (Faxe Kridt (Faxe Paper (Faxe Paper Engelhard) A/S) Pigments A/S) Pigments A/S) Thickness (μm) 106 106 105 105 Roughness 5.2 6.2 6.2 6.2 (μm) Porosity 17 21 20 15 (μm/Pas) Brightness 63.5 61.1 61.6 60.5 (R457-ISO, %) Opacity (%) 90.2 89.4 89.8 90.6

It can be seen from the table above that colloidal PCC surprisingly is able to lower the porosity of the paper from 21 μm/Pas with a standard PCC to 15 μm/Pas with colloidal PCC, which is lower than the kaolin reference at 4% filler level.

Conclusion

By using colloidal PCC as filler the porosity of the paper is lowered significantly. The amount of colloidal PCC in the paper can thereby be varied as required, so that the porosity and thereby also the printing properties can be regulated precisely. The colloidal PCC can thus be used as required instead of or in combination with other conventional fillers and pigments in order to achieve the desired porosity.

EXAMPLE 3

A pigment mixture consisting of 50 parts (by weight) fine scalenohedral PCC, 30 parts fine rhombohedral PCC and 20 parts colloidal PCC was tested in production scale as a filler in SC-A grade paper at a commercial paper mill. The PCC pigment mixture was pH-stabilised by addition of a small amount of phosphoric acid in order to avoid the need for acid addition on the paper machine for pH-control. The properties of the PCC mixture and the reference clay filler used in the trial are listed in the table below.

Experimental PCC mixture Reference kaolin clay (Faxe Paper Pigments (European filler grade) A/S) Brightness (R457- 79.2 94.1 ISO %) MPS (μm) 1.38 1.62 BET surface area 11.7 10.8 (m2/g)

The pulp finish composition was 50 parts deinked pulp (DIP), 40-45 parts groundwood (GW) and 5-10 parts Kraft pulp.

The trial PCC mixture was tested at a constant total filler level with two levels of PCC addition. The balance to give the total amount of filler is reference clay and filler introduced with the DIP (recycled paper).

The properties of the papers resulting from the trial are listed in the table below.

Reference Trial 1 Trial 2 Added PCC1  0% 10% 20% Added clay1 32% 22% 12% Analysed  1.5% 13.4% 24.2% CaCO3 content1 Analysed clay 37.6% 25.6% 15.2% content1 Gram weight 57 g/m2 56 g/m2 56 g/m2 Roughness TS  1.70 μm  1.75 μm  1.65 μm (0.5 bar) Roughness WS  1.70 μm  1.70 μm  1.55 μm (0.5 bar) Porosity (PPS)2  0.122 μm/Pa · s  0.197 μm/Pa · s  0.228 μm/Pa · s Gloss 75°, 50% 45% 45% TS MD Gloss 75°, 48% 49% 49% WS MD Brightness, 66.4% 70.1% 72.1% R457-ISO Opacity 92.1% 92.5% 91.8% 1By weight, based on the total weight of paper; TS = topside; WS = wireside; MD = machine direction 2PPS = Parker-Print-Surf method

The runnability of the paper machine remained good during the two-day trial period and it was possible to increase the production capacity by 1.5%. The Hydrocol™ two-component retention system was used on the paper machine. The amount of cationic polymer could be reduced during the trial as the PCC pigment mixture was easier to retain than the reference clay. The pH in the paper machine headbox was 7.4 prior to the trial and it increased only slightly (to 7.6) during the trial.

The paper produced during the trial showed excellent results in full-scale commercial printing. It is remarkable that the paper brightness has been increased by 6 percentage points without any loss in opacity. The resulting 72% brightness is close to the superior SC-A+ quality.

EXAMPLE 4

A pigment mixture consisting of 80 parts (by weight) fine rhombohedral PCC and 20 parts colloidal PCC was tested in production scale as a filler in SC-B grade paper at a commercial paper mill. The rhombohedral PCC and the colloid PCC had BET surface areas of approximately 7 and 20 m2/g, respectively, to provide a mixture having an overall BET surface area of 9.1 mg2/g as indicated below. The PCC pigment mixture was pH-stabilised by addition of a small amount of phosphoric acid in order to avoid the need for acid addition on the paper machine for pH-control. The properties of the PCC mixture and the reference fillers used in the trial are listed in the table below.

Reference kaolin Experimental PCC clay mixture (European filler Reference (Faxe Paper Filler: grade) PCC Pigments A/S) Brightness (R457- 76.6 96.2 95.4 ISO %) MPS (μm) 2.13 1.70 1.31 BET (m2/g) 11.9 8.6 9.1

The pulp furnish composition was 30‥35 parts deinked pulp (DIP), 10-15 parts chemothermomechanical pulp (CTMP) and groundwood (GW), adding up to a total of 100 parts.

The trial PCC mixture was tested at a constant total filler level with two levels of PCC addition. The balance to give the total amount of filler is reference clay and filler introduced with the DIP (recycled paper).

The properties of the papers resulting from the trial are listed in the table below.

Reference Trial 1 Trial 2 Added Faxe  0% 11% 18% PCC1 Added 11%  0%  0% reference PCC1 Added clay1 11% 11%  4% Analysed 15.8% 14.8% 22.4% CaCO3 content1 Analysed clay 17.8% 17.4% 11.2% content Gram weight 57 g/m2 56 g/m2 56 g/m2 Roughness TS  2.80 μm  2.90 μm  2.90 μm (0.5 bar) Roughness WS  2.60 μm  2.80 μm  2.80 μm (0.5 bar) Porosity (PPS)  0.570 μm/Pa · s  0.514 μm/Pa · s  0.554 μm/Pa · s Gloss 75°, 27% 27% 26% TS MD Gloss 75°, 24% 25% 24% WS MD Brightness 63.4% 62.6% 64.8% R457-ISO Opacity 96.4% 95.9% 96.0%


1) By weight, based on the total weight of paper: TS=topside; WS=wireside; MD=machine direction.

The runnability of the paper machine remained good during the two-day trial period and it was possible to increase the production capacity by 1.3%. The Hydrocol™ two-component retention system was used on the paper machine. The amount of cationic polymer could be reduced during the trial, as the PCC pigment mixture was easier to retain than the reference clay. The amount of blue and yellow colour could be reduced as well. The pH in the paper machine headbox was 7.3 prior to the trial and it was stable at 7.2±0.1 during the trial.

The paper produced during the trial showed excellent results in full-scale commercial printing. The pulp bleaching was reduced in order to keep the paper brightness within the production specifications. The reduced amount of bleaching chemicals is an advantageous cost saving for the paper mill and environmentally beneficial.

EXAMPLE 5

A pigment mixture consisting of 80 parts (by weight) fine rhombohedral PCC and 20 parts colloidal PCC was tested in production scale as a filler in SC-A grade paper at a commercial paper mill. The PCC pigment mixture was pH-stabilised by addition of a small amount of phosphoric acid in order to avoid the need for acid addition on the paper machine for pH-control. The properties of the PCC mixture and the reference clay fillers used in the trial are listed in the table below. The paper mill alternates between use of two clays in their normal production.

Experimental PCC mixture Reference kaolin clay (Faxe Paper Pigments Filler: (European filler grade) A/S) Brightness (R457- 80.7 94.1 ISO %) MPS (μm) 1.79 1.62 BET (m2/g) 15.4 10.8

The pulp furnish composition was 75 parts deinked pulp (DIP), 20 parts groundwood (GW) and 5 parts Kraft pulp.

The trial PCC mixture was tested at a constant total filler level with all fresh filler added being PCC. The balance to give the total amount of filler is filler introduced with the DIP (recycled paper). Paper was made in three gram weights: 48, 52 and 56 g/m2. For the sake of simplicity only results for 56 g/m2 are shown. The results at the other gram weights were similar.

The properties of the papers resulting from the trial are listed in the table below.

Reference Trial Added PCC1  0% 17% Analysed CaCO3 content1  3.5% 18.3% Analysed clay content1 32.9% 17.4% Gram weight 57 g/m2 57 g/m2 Roughness TS (0.5 bar)  2.4 μm  2.20 μm Roughness WS (0.5 bar)  2.65 μm  2.55 μm Porosity (PPS)  0.252 μm/Pa · s  0.367 μm/Pa · s Gloss 75°, TS MD 32.9% 31.7% Gloss 75°, WS MD 26.1% 29.2% Brightness R457-ISO 66.0% 66.4% Opacity 94.1% 95.6% 1By weight based on the total weight of paper; TS = topside; WS = wireside; MD = machine direction.

The runnability of the paper machine remained good during the two-day trial period and it was possible to increase the production capacity by 1.2%. The Hydrocol™ two component retention system was used on the paper machine. The amount of cationic polymer could be reduced by approx. 20% during the trial as the PCC pigment mixture was easier retained than the reference clay. The pH in the paper machine headbox was 7.6 prior to the trial and it increased only slightly (to 7.7) during the trial.

The paper produced during the trial showed excellent results in full-scale commercial printing. It is remarkable that the paper mill had to totally stop bleaching their DIP in order to keep the brightness within the production specifications. This is a big economic advantage and also environmentally beneficial.

EXAMPLE 6

A number of fillers and filler mixtures were tested in a dynamic sheet former trial. The fillers were three PCCs from Faxe Paper Pigments A/S, Denmark (a fine rhombohedral PCC, a fine scalenohedral PCC, and a colloidal PCC), and a kaolin clay from Dorfner. The properties of the fillers used in the trial are listed in the table below.

Brightness (R457- Filler ISO %) MPS (μm) BET (m2/g) Fine rhombohedral 94.6 0.90 7.9 PCC Fine scalenohedral 95.7 2.13 9.3 PCC Colloidal PCC 95.4 1.40 28.1 Kaolin clay 81.7 2.02 8.4 (Dorfner)

Handsheets were made on a dynamic sheet former from Fibertech AB. The pulp furnish consisted of 50 parts groundwood, 30 parts DIP and 20 parts Kraft pulp. The target filler level was 35% by weight of the total weight of the paper. The results are listed below. The target gram weight of the handsheets was 56 g/m2 (The actual gram weights varied between 53.2 and 58.1 g/m2). Handsheets were made at three target filler levels, which were 30%, 33% and 36% filler by weight based on the total weight of the paper. The paper quality parameters were interpolated to a 35% filler level and the results are listed below.

Trial No: 1 2 3 4 5 6 7 Fine rhombohedral PCC1 100 80 70 50 Fine scalenohedral PCC1 100 80 50 Colloidal PCC1 20 30 50 20 Kaolin Clay1 50 Analysed CaCO3 content1 32.5 32.9 32.3 32.7 32.9 32.8 18.8 (%) Analysed clay content2 2.5 2.1 2.7 2.3 2.1 2.2 16.2 (%) Gram weight (g/m2) 54.2 53.9 55.0 56.1 57.0 56.5 56.9 Roughness TS (1 bar) 1.33 1.35 1.31 1.35 1.28 1.28 1.16 (μm) Porosity (PPS) 0.276 0.271 0.265 0.252 0.337 0.259 0.236 (μm/Pa · s) Gloss 75°, TS MD (%) 32.0 35.1 37.2 40.1 39.7 40.2 46.7 Brightness R467-ISO (%) 70.2 69.5 66.6 67.6 68.8 67.4 66.6 Opacity (%) 92.7 93.0 93.8 92.9 93.5 92.9 92.7 1parts by weight, 2By weight based on the total weight of paper; TS = topside, WS = wireside; MD = machine direction.

Claims (20)

1. A process for regulating the porosity and printing properties of uncoated wood-containing paper, having at least 10% by weight of the pulp being lignin-containing pulp, the process comprising using a sufficient quantity of colloidal precipitated calcium carbonate (PCC) having a BET surface area of 10-100 m2/g as a filler to achieve a desired porosity of the paper.
2. The process according to claim 1 wherein the paper is SC paper, and wherein colloidal PCC is used in a quantity sufficient to achieve a porosity of at most 0.30 μm/Pas.
3. The process according to claim 2, wherein the paper is SC-A paper.
4. The process according to claim 1 wherein the paper is SC-B paper, and wherein colloidal PCC is used in a quantity sufficient to achieve a porosity of at most 0.60 μm/Pas.
5. The process according to claim 1 wherein the paper is newsprint, and wherein colloidal PCC is used in an amount sufficient to achieve a porosity of at most 20 μm/Pas.
6. The process according to claim 1 wherein the colloidal PCC has a BET surface area of 15-50 m2/g.
7. The process according to claim 6 wherein the colloidal PCC has a BET surface area of 20-30 m2/g.
8. The process according to claim 1 wherein colloidal PCC is incorporated into the paper in an amount of at least about 1% by weight based on the total weight of the paper.
9. The process according to claim 8 wherein colloidal PCC is incorporated into the paper in an amount of at least about 2% by weight based on the total weight of the paper.
10. An uncoated wood-containing paper in which at least 10% by weight of the pulp is lignin-containing pulp, and wherein said paper further contains colloidal precipitated calcium carbonate (PCC).
11. The paper according to claim 10 containing colloidal PCC having a BET surface area of 10-100 m2/g as a filler.
12. The paper according to claim 11 comprising at least one further filler selected from the group consisting of non-colloidal PCC, kaolin, calcined kaolin, gypsum, chalk, ground marble, silicate-containing minerals, sulphate-containing minerals, oxide-containing minerals, carbonate-containing minerals, hydroxide-containing minerals, calcium sulfoaluminates, plastic particles and organic pigments.
13. The paper according to claim 11 wherein the colloidal PCC has a BET surface area of 15-50 m2/g.
14. The paper according to claim 10 wherein the colloidal PCC is present in an amount of at least about 1% by weight based on the total weight of the paper.
15. The paper according to claim 14 comprising at least one further filler selected from the group consisting of non-colloidal PCC, kaolin, calcined kaolin, gypsum, chalk, ground marble, silicate-containing minerals, sulphate-containing minerals, oxide-containing minerals, carbonate-containing minerals, hydroxide-containing minerals, calcium sulfoaluminates, plastic particles and organic pigments.
16. The paper according to claim 14 wherein the colloidal PCC has a BET surface area of 10-100 m2/g.
17. The paper according to claim 10, wherein the paper is a SC paper containing colloidal PCC and having a porosity of at most 0.30 μm/Pas.
18. The paper according to claim 10, wherein the paper is a SC-A paper.
19. The paper according to claim 10, wherein the paper is a SC-B paper containing colloidal PCC and having a porosity of at most 0.60 μm/Pas.
20. The paper according to claim 10, wherein the paper is a newsprint containing colloidal PCC and having a porosity of at most 20 μm/Pas.
US09/701,261 1998-05-27 1999-05-27 Process for regulating the porosity and printing properties of paper by use of colloidal precipitated calcium carbonate, and paper containing such colloidal precipitated calcium carbonate Expired - Fee Related US6887351B1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DK73598 1998-05-27
PCT/DK1999/000286 WO1999061703A1 (en) 1998-05-27 1999-05-27 Use of colloidal precipitated calcium carbonate as a filler in the preparation of paper

Publications (1)

Publication Number Publication Date
US6887351B1 true US6887351B1 (en) 2005-05-03

Family

ID=8096945

Family Applications (2)

Application Number Title Priority Date Filing Date
US09/701,261 Expired - Fee Related US6887351B1 (en) 1998-05-27 1999-05-27 Process for regulating the porosity and printing properties of paper by use of colloidal precipitated calcium carbonate, and paper containing such colloidal precipitated calcium carbonate
US11/009,740 Expired - Fee Related US7267719B2 (en) 1998-05-27 2004-12-10 Use of colloidal PCC

Family Applications After (1)

Application Number Title Priority Date Filing Date
US11/009,740 Expired - Fee Related US7267719B2 (en) 1998-05-27 2004-12-10 Use of colloidal PCC

Country Status (9)

Country Link
US (2) US6887351B1 (en)
EP (1) EP1084297B1 (en)
AT (1) AT274616T (en)
AU (1) AU4030199A (en)
CA (1) CA2333113C (en)
DE (1) DE69919703T2 (en)
ES (1) ES2228045T3 (en)
NO (1) NO330049B1 (en)
WO (1) WO1999061703A1 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050126730A1 (en) * 2000-08-17 2005-06-16 Marielle Lorusso Kaolin products and their use
US20060102304A1 (en) * 2002-05-03 2006-05-18 Christopher Nutbeem Paper coating pigments
US20080035293A1 (en) * 2003-04-15 2008-02-14 Kemira Oyj Process for Manufacturing of Paper
US20110146931A1 (en) * 2008-09-09 2011-06-23 Patrick Arthur Charles Gane Compositions of calcium carbonates/pigments for paper formulations, showing print through reduction
US8377260B2 (en) * 2003-03-25 2013-02-19 Nippon Paper Industries Co., Ltd. Newsprint paper for offset printing
US20130112360A1 (en) * 2010-06-03 2013-05-09 Nordkalk Oy Ab Process for manufacturing paper or board
EP2723819B1 (en) 2011-06-21 2017-03-01 Omya International AG Process for the production of precipitated calcium carbonate

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4323714B2 (en) * 2000-01-12 2009-09-02 日本製紙株式会社 Newspaper
FI116573B (en) * 2001-11-28 2005-12-30 M Real Oyj Filler for making thin base paper and method for making base paper
EP1712597A1 (en) * 2005-04-11 2006-10-18 Omya Development AG Process for preparing precipitated calcium carbonate pigment, especially for use in inkjet printing pater coatings and precipitated calcium carbonate
US7553526B2 (en) * 2005-12-14 2009-06-30 Eastman Kodak Company Inkjet recording media comprising precipitated calcium carbonate
US9262140B2 (en) * 2008-05-19 2016-02-16 International Business Machines Corporation Predication supporting code generation by indicating path associations of symmetrically placed write instructions
US9296244B2 (en) 2008-09-26 2016-03-29 International Paper Company Composition suitable for multifunctional printing and recording sheet containing same
DE102009010697A1 (en) * 2009-02-27 2010-09-02 Voith Patent Gmbh Method for the production of magazine paper from material suspension having fiber, where the material suspension consists of de-inked wastepaper and a portion of chemithermomechanical fiber and another fiber
US8900678B2 (en) * 2009-05-29 2014-12-02 Hewlett-Packard Development Company, L.P. Coated medium for inkjet printing and method of fabricating the same
CN103608291B (en) * 2011-04-06 2016-03-23 密执安特种矿石公司 For the PCC fill composition of the printability that supercalendered paper improves
US8992042B2 (en) 2011-11-14 2015-03-31 Halma Holdings, Inc. Illumination devices using natural light LEDs
EP2933375B1 (en) * 2014-04-16 2018-12-19 Omya International AG Adsorbing and/or reduction of the amount of organic materials in an aqueous medium by using colloidal precipitated calcium carbonate

Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2188663A (en) * 1938-04-04 1940-01-30 Diamond Alkali Co Process of making fine particle alkaline earth metal carbonates
US4460637A (en) 1981-12-24 1984-07-17 Mitsubushi Paper Mills, Ltd. Ink jet recording sheet
US4892590A (en) 1988-06-03 1990-01-09 Pfizer Inc. Precipitated calcium carbonate-cationic starch binder as retention aid system for papermaking
US5147507A (en) * 1990-03-08 1992-09-15 Pfizer Inc. Cationic polymer-modified filler material, process for its prepartion and method of its use in papermaking
EP0521737A1 (en) 1991-07-04 1993-01-07 NordCarb Oy Ab Process for increasing the solids content of a slurry used in paper manufacturing
US5332564A (en) * 1992-07-10 1994-07-26 Ecc International Inc. Process for production of rhombic shaped precipitated calcium carbonate
EP0650880A1 (en) 1993-10-29 1995-05-03 Gebr. OTTO KG Trolley for transporting a container
WO1996029369A2 (en) 1995-03-17 1996-09-26 Minerals Technologies Inc. Ink jet recording paper incorporating novel precipitated calcium carbonate pigment
US5614325A (en) 1992-11-26 1997-03-25 Arjo Wiggins Papiers Couches S.A. Coated paper for machines having sheet and friction feed systems
US5643415A (en) * 1991-06-04 1997-07-01 Wise; Kenneth J. Precipitated calcium carbonate particles from basic calcium carbonate
WO1997030220A1 (en) 1996-02-13 1997-08-21 Allied Colloids Limited Production of filled paper and compositions for use in this
US5665205A (en) * 1995-01-19 1997-09-09 International Paper Company Method for improving brightness and cleanliness of secondary fibers for paper and paperboard manufacture
US5679220A (en) * 1995-01-19 1997-10-21 International Paper Company Process for enhanced deposition and retention of particulate filler on papermaking fibers
US5711799A (en) * 1996-03-13 1998-01-27 Ecc International Inc. Acid tolerant calcium carbonate composition and uses therefor
US5755930A (en) * 1994-02-04 1998-05-26 Allied Colloids Limited Production of filled paper and compositions for use in this
EP0850880A1 (en) 1996-12-27 1998-07-01 Okutama Kogyo Co., Ltd. Aqueous slurry precipitated calcium carbonate and ground calcium carbonate in combination
US5916420A (en) * 1994-01-12 1999-06-29 Haindl Papier Gmbh Thin printing paper and a process for manufacturing said paper
US6258214B1 (en) * 1998-05-08 2001-07-10 V.I.B. Apparatebau Gmbh Process for the on-line manufacture of SC-A paper

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3304154A (en) * 1964-02-17 1967-02-14 Kiouzes-Pezas Dimitrios Process for producing spheroidal alkaline earth metal carbonates
US4167423A (en) * 1975-04-14 1979-09-11 Union Carbide Corporation Silane reactive mineral fillers
US4026762A (en) * 1975-05-14 1977-05-31 P. H. Glatfelter Co. Use of ground limestone as a filler in paper
ES2063773T3 (en) * 1988-03-07 1995-01-16 Pluss Stauffer Ag Pigment mixing for the paper industry.
US5164006A (en) * 1991-04-08 1992-11-17 Ecc America Inc. Method for preparing acid resistant calcium carbonate pigments
JPH07509684A (en) * 1992-04-03 1995-10-26
JP3299826B2 (en) * 1993-10-05 2002-07-08 株式会社ユポ・コーポレーション White resin film with excellent printability
US6623555B1 (en) * 2000-06-01 2003-09-23 Jukka P. Haverinen Composite precipitated calcium carbonate/silicon compound pigment and method of making same

Patent Citations (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2188663A (en) * 1938-04-04 1940-01-30 Diamond Alkali Co Process of making fine particle alkaline earth metal carbonates
US4460637A (en) 1981-12-24 1984-07-17 Mitsubushi Paper Mills, Ltd. Ink jet recording sheet
US4892590A (en) 1988-06-03 1990-01-09 Pfizer Inc. Precipitated calcium carbonate-cationic starch binder as retention aid system for papermaking
US5147507A (en) * 1990-03-08 1992-09-15 Pfizer Inc. Cationic polymer-modified filler material, process for its prepartion and method of its use in papermaking
US5643415A (en) * 1991-06-04 1997-07-01 Wise; Kenneth J. Precipitated calcium carbonate particles from basic calcium carbonate
EP0521737A1 (en) 1991-07-04 1993-01-07 NordCarb Oy Ab Process for increasing the solids content of a slurry used in paper manufacturing
US5332564A (en) * 1992-07-10 1994-07-26 Ecc International Inc. Process for production of rhombic shaped precipitated calcium carbonate
US5614325A (en) 1992-11-26 1997-03-25 Arjo Wiggins Papiers Couches S.A. Coated paper for machines having sheet and friction feed systems
EP0650880A1 (en) 1993-10-29 1995-05-03 Gebr. OTTO KG Trolley for transporting a container
US5916420A (en) * 1994-01-12 1999-06-29 Haindl Papier Gmbh Thin printing paper and a process for manufacturing said paper
US5755930A (en) * 1994-02-04 1998-05-26 Allied Colloids Limited Production of filled paper and compositions for use in this
US5665205A (en) * 1995-01-19 1997-09-09 International Paper Company Method for improving brightness and cleanliness of secondary fibers for paper and paperboard manufacture
US5679220A (en) * 1995-01-19 1997-10-21 International Paper Company Process for enhanced deposition and retention of particulate filler on papermaking fibers
WO1996029369A2 (en) 1995-03-17 1996-09-26 Minerals Technologies Inc. Ink jet recording paper incorporating novel precipitated calcium carbonate pigment
WO1997030220A1 (en) 1996-02-13 1997-08-21 Allied Colloids Limited Production of filled paper and compositions for use in this
US5711799A (en) * 1996-03-13 1998-01-27 Ecc International Inc. Acid tolerant calcium carbonate composition and uses therefor
EP0850880A1 (en) 1996-12-27 1998-07-01 Okutama Kogyo Co., Ltd. Aqueous slurry precipitated calcium carbonate and ground calcium carbonate in combination
US5879442A (en) * 1996-12-27 1999-03-09 Okutama Kogyo Co., Ltd. Aqueous slurry of precipitated calcium carbonate and ground calcium carbonate in combination
US6258214B1 (en) * 1998-05-08 2001-07-10 V.I.B. Apparatebau Gmbh Process for the on-line manufacture of SC-A paper

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Bartz, et al "Alkyl ketene dimer sizing efficiency and reversion in calcium carbonate filled papers" Tappi Journal, vol. 77, No. 12, 1994, pp. 139-148.
Gill, Robert A., et al.; "The behavior of on-site synthesized precipitated" Nordic Pulp & Paper Research Jounal No. 2-1989 4 (1989) p. 120-127.

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050126730A1 (en) * 2000-08-17 2005-06-16 Marielle Lorusso Kaolin products and their use
US7413601B2 (en) * 2000-08-17 2008-08-19 Imerys Pigments, Inc. Kaolin products and their use
US20060102304A1 (en) * 2002-05-03 2006-05-18 Christopher Nutbeem Paper coating pigments
US7758690B2 (en) 2002-05-03 2010-07-20 Imerys Minerals, Ltd. Paper coating pigments
US8377260B2 (en) * 2003-03-25 2013-02-19 Nippon Paper Industries Co., Ltd. Newsprint paper for offset printing
US20080035293A1 (en) * 2003-04-15 2008-02-14 Kemira Oyj Process for Manufacturing of Paper
US8052841B2 (en) * 2003-04-15 2011-11-08 Kemira Oyj Process for manufacturing of paper
US20110146931A1 (en) * 2008-09-09 2011-06-23 Patrick Arthur Charles Gane Compositions of calcium carbonates/pigments for paper formulations, showing print through reduction
US8580082B2 (en) * 2008-09-09 2013-11-12 Omya International Ag Compositions of calcium carbonates/pigments for paper formulations, showing print through reduction
US20130112360A1 (en) * 2010-06-03 2013-05-09 Nordkalk Oy Ab Process for manufacturing paper or board
US8758566B2 (en) * 2010-06-03 2014-06-24 Nordkalk Oy Ab Process for manufacturing paper or board
EP2723819B1 (en) 2011-06-21 2017-03-01 Omya International AG Process for the production of precipitated calcium carbonate

Also Published As

Publication number Publication date
AT274616T (en) 2004-09-15
NO330049B1 (en) 2011-02-07
US20050098066A1 (en) 2005-05-12
NO20005871L (en) 2000-11-27
DE69919703D1 (en) 2004-09-30
WO1999061703A1 (en) 1999-12-02
NO20005871D0 (en) 2000-11-21
US7267719B2 (en) 2007-09-11
ES2228045T3 (en) 2005-04-01
EP1084297A1 (en) 2001-03-21
EP1084297B1 (en) 2004-08-25
CA2333113C (en) 2007-02-13
WO1999061703A8 (en) 2000-08-03
CA2333113A1 (en) 1999-12-02
DE69919703T2 (en) 2005-09-08
AU4030199A (en) 1999-12-13

Similar Documents

Publication Publication Date Title
US10253457B2 (en) Compositions
DK2971347T3 (en) Process for treating microfibrillated cellulose
US7377975B2 (en) Pigment for use in inkjet recording medium coatings and methods
CA2187471C (en) Paper coating pigments and their production and use
AU775953B2 (en) Novel treated filler or pigment or mineral for paper, in particular pigment containing natural CaCo3, method for making same, compositions containing them and uses
EP2931970B1 (en) Cellulose-derived compositions
EP0561828B1 (en) Paper and a method of paper manufacture
DE3017763C2 (en)
EP2157237B1 (en) Methods for producing coating base papers and coated papers
EP1207233B1 (en) High opacity decorative base paper
US7887629B2 (en) Process for the preparation of paper, paperboard and cardboard
ES2229494T3 (en) Precipitated aragonitic calcium carbonate igment for coating printed papers by rotograbado.
US6890652B2 (en) Decorative paper base with improved opacity
US8517291B2 (en) Process of manufacturing a co-ground calcium carbonate mineral of the GCC and PCC type with a specific steepness factor, obtained products and their uses
US6156118A (en) Filler for use in paper manufacture and method for producing it
FI117871B (en) Multilayer fiber product and process for its preparation
CA2046285C (en) Paper manufacturing process, and papers obtainable by means of that process
US8404084B2 (en) Latex-treated filler slurries for use in papermaking
FI63614B (en) Pappersbestrykningsmassor with Høg torrsubstanskoncentration
AU2011260153B2 (en) Process for manufacturing paper or board
CA2397097C (en) Process and coating composition for coating a paper web
US5147507A (en) Cationic polymer-modified filler material, process for its prepartion and method of its use in papermaking
DE4312463C1 (en) CaCO3 3 -Talkum coating pigment slurry, process for its preparation and its use
Subramanian et al. Precipitated calcium carbonate (PCC)–cellulose composite fillers: effect of PCC particle morphology on the production and properties of uncoated fine paper
US20080308010A1 (en) Economical Process of Manufacturing Very Fine Co-Ground Calcium Carbonate Material of the Gcc and Pcc Type, Obtained Products and Their Uses

Legal Events

Date Code Title Description
FPAY Fee payment

Year of fee payment: 4

REMI Maintenance fee reminder mailed
LAPS Lapse for failure to pay maintenance fees
STCH Information on status: patent discontinuation

Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362

FP Expired due to failure to pay maintenance fee

Effective date: 20130503