US673364A - Process of the purification of aluminium. - Google Patents

Process of the purification of aluminium. Download PDF

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Publication number
US673364A
US673364A US2881500A US1900028815A US673364A US 673364 A US673364 A US 673364A US 2881500 A US2881500 A US 2881500A US 1900028815 A US1900028815 A US 1900028815A US 673364 A US673364 A US 673364A
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aluminium
bath
process
anode
fluorid
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US2881500A
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William Hoopes
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PITTSBURGH REDUCTION Co
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PITTSBURGH REDUCTION Co
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/24Refining

Description

No. 673,364. Patented Apr. 30, NHL W. HOUPES.

PROCESS OF THEPURIFICATION 0F ALUMINIUM.

(Application filed Sept. 1, 1900.)

(No Model.)

WITNESSES INYEN'I'OR WWW 70:2614 mum m: NORRIS PETERS o0. pnomuwo, whsumumm a c while the impurities remain unaffected.

UNITED STATES PATENT OFFICE.

WILLIAM HOOPES, OF NEW KENSINGTON, PENNSYLVANIA, ASSIGNOR TO THE PITTSBURGH REDUCTION COMPANY, OF SAME PLACE.

PROCESS OF THE PURIFICATION OF ALUMINIUM.

SPECIFICATION formingpart of Letters Patent No. 673,364, dated April 30, 1901.

Application filed September 1, 1900. Serial No. 28,815- (No specimens.)

To all whom, it may concern:

Be it known that l, WILLIAM HOOPES, of New Kensington, in the county of Westmoreland and State of Penusylvania,have invented a new Process for the Purification of Aluminium, of which the following is a specification.

I have discovered that if impure aluminium is used in a melted state as anode in an electrolytic cell, especially one in which the electrolyte contains fused aluminium fluorid and afiuorid of a metal more electropositive than aluminium, pure aluminium will be deposited at the cathode when current is passed through the cell. I attribute this to the fact that aluminium is the most readily oxidizable element present in the usual specimens of impure aluminium, so that when the current sets free aluminium at the cathode and fluorin at the anode, the aluminium having greater affinity for fluorin than have the usual impuritiessilicon, iron, or copper-the aluminium of the anode will be attacked by the fiuorin, If the aluminium anode should contain as impurity any metal-such as magnesium, sodium, or potassiumwhich has a greater affinity for fluorin than has aluminium, such metals, although they would be dissolved by the bath, would not be deposited at the cathode, since their fluorids are less easily decomposed by the electric current than is alu minium fluorid. They would merely cause some of the aluminium fluorid in the bath to be displaced by the fluorid of the metal dissolved. The eIfec-t, therefore, of using impure aluminium as the anode of the electrolytic cell is to deposit pure aluminium on the cathode, the impurities of the anode which have less affinity for fluorin than aluminium remain undissolved, and those that have a greater affinity for fluorin than has aluminium pass into and remain in the bath. A somewhatsimilar action takes place When the bath "contains alumina in solution, as in this case the aluminium anode Will be attacked by the oxygen set free in advance of all impurities likely to be found excepting magnesium and calcium, and if these are present they will be dissolved by the oxygen and will remain in solution so long as any dissolved alumina is present. I have made these discoveries the basis of a process of purifying impure aluminium, and I will now describe the same with reference to the accompanying drawing, which shows in cross-section a form of apparatus in which my process may be practiced, although other forms of apparatus may be substituted.

In the drawing, 2 represents an electrolytic pot having a carbon lining 3, adapted to contain a molten bath 4 of double fluorid of aluminium and sodium. One or more fluorids of other metals more electropositive than aluminium maybe substituted for the fluorid of sodium. A carbon tray or holder 5 is set in the pot and is connected to the positive terminal of the electric generator by a conductor 6, which is protected from the bath by a carbon tube or sheath 7 and which may serve as the support for the tray. The tray is charged with a body of impure aluminium 8 in a melted state, and a current having a density, preferably, of twenty to thirty ampcres per square inch of the surface of the aluminium anode 8 is passed through the bath for several hours. It will be .found that by such procedure the aluminium will be caused to deposit on the surface of the pot-lining 3, which is the cathode, and that the impurities will remain in the residuum of metal which remains in the suspended tray. Metal of great purity can thus be obtained at the oathode. Like results are obtainable when alumina is dissolved in the double-fluorid bath.

In my broader claims I do not restrict myself to the fluorid-bath described, as other molten baths may be used within the scope of my invention.

1 claim-- 1. The method herein described of purifying impure aluminium, which consists in passing an electric current from an anode composed of such impure aluminium in a melted state to a suitable cathode through a bath capable during electrolysis of dissolving the aluminium of the anode; substantially as described.

2. The method herein described of purifying impure aluminium, which consists in passing an electric current from an anode composed of such impure aluminium in a melted state to a suitable cathode,- through a bath containing fiuorid of aluminium and the fluorid of a metal more electropositive than aluminium; substantially as described.

In testimony whereof I have hereunto set my hand.

WILLIAM HOOPES.

Witnesses: F. E. GAITHER, G. B. BLEMINGi

US2881500A 1900-09-01 1900-09-01 Process of the purification of aluminium. Expired - Lifetime US673364A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2512157A (en) * 1946-03-20 1950-06-20 Reynolds Metals Co Purification of aluminum
US2539743A (en) * 1946-01-03 1951-01-30 Reynolds Metals Co Electrolytic refining of impure aluminum
US3110660A (en) * 1960-11-28 1963-11-12 Reynolds Metals Co Cathode structure for electrolytic reduction cell
US4183745A (en) * 1976-02-16 1980-01-15 Yoshishige Tsumura Demagging process for aluminum alloy without air pollution
US4214955A (en) * 1979-01-02 1980-07-29 Aluminum Company Of America Electrolytic purification of metals

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2539743A (en) * 1946-01-03 1951-01-30 Reynolds Metals Co Electrolytic refining of impure aluminum
US2512157A (en) * 1946-03-20 1950-06-20 Reynolds Metals Co Purification of aluminum
US3110660A (en) * 1960-11-28 1963-11-12 Reynolds Metals Co Cathode structure for electrolytic reduction cell
US4183745A (en) * 1976-02-16 1980-01-15 Yoshishige Tsumura Demagging process for aluminum alloy without air pollution
US4214955A (en) * 1979-01-02 1980-07-29 Aluminum Company Of America Electrolytic purification of metals

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