US6458630B1 - Antifuse for use with low k dielectric foam insulators - Google Patents
Antifuse for use with low k dielectric foam insulators Download PDFInfo
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- US6458630B1 US6458630B1 US09/417,853 US41785399A US6458630B1 US 6458630 B1 US6458630 B1 US 6458630B1 US 41785399 A US41785399 A US 41785399A US 6458630 B1 US6458630 B1 US 6458630B1
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- polymer
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- 239000006260 foam Substances 0.000 title claims description 4
- 239000012212 insulator Substances 0.000 title description 7
- 229920000642 polymer Polymers 0.000 claims abstract description 81
- 229920001721 polyimide Polymers 0.000 claims abstract description 26
- 239000004642 Polyimide Substances 0.000 claims abstract description 24
- 239000000758 substrate Substances 0.000 claims abstract description 23
- 229920000767 polyaniline Polymers 0.000 claims abstract description 15
- 150000003839 salts Chemical class 0.000 claims abstract description 13
- 239000011833 salt mixture Substances 0.000 claims abstract description 12
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- 239000004065 semiconductor Substances 0.000 claims abstract description 9
- 239000003989 dielectric material Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 31
- 239000004020 conductor Substances 0.000 claims description 17
- 238000010000 carbonizing Methods 0.000 claims description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000002861 polymer material Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229920002382 photo conductive polymer Polymers 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 description 34
- 239000002184 metal Substances 0.000 description 34
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 16
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 12
- 239000010408 film Substances 0.000 description 12
- 239000011521 glass Substances 0.000 description 8
- 238000010884 ion-beam technique Methods 0.000 description 8
- 235000012239 silicon dioxide Nutrition 0.000 description 8
- 239000000377 silicon dioxide Substances 0.000 description 8
- 229910052786 argon Inorganic materials 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000002161 passivation Methods 0.000 description 5
- NXDMHKQJWIMEEE-UHFFFAOYSA-N 4-(4-aminophenoxy)aniline;furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=CC(N)=CC=C1OC1=CC=C(N)C=C1.C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O NXDMHKQJWIMEEE-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229920003223 poly(pyromellitimide-1,4-diphenyl ether) Polymers 0.000 description 4
- AVFZOVWCLRSYKC-UHFFFAOYSA-N 1-methylpyrrolidine Chemical compound CN1CCCC1 AVFZOVWCLRSYKC-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- AHVYPIQETPWLSZ-UHFFFAOYSA-N N-methyl-pyrrolidine Natural products CN1CC=CC1 AHVYPIQETPWLSZ-UHFFFAOYSA-N 0.000 description 3
- 229910052581 Si3N4 Inorganic materials 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 229910052681 coesite Inorganic materials 0.000 description 3
- 229920001940 conductive polymer Polymers 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 150000004767 nitrides Chemical class 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 3
- 229910052682 stishovite Inorganic materials 0.000 description 3
- 229910052905 tridymite Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- -1 FSG Chemical compound 0.000 description 2
- XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 2
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
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- 239000010409 thin film Substances 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- RBFRSIRIVOFKDR-UHFFFAOYSA-N [C].[N].[O] Chemical compound [C].[N].[O] RBFRSIRIVOFKDR-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
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- 238000004880 explosion Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
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- 229910052757 nitrogen Inorganic materials 0.000 description 1
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- 229920002120 photoresistant polymer Polymers 0.000 description 1
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- 239000011148 porous material Substances 0.000 description 1
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- 239000010703 silicon Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/525—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body with adaptable interconnections
- H01L23/5252—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body with adaptable interconnections comprising anti-fuses, i.e. connections having their state changed from non-conductive to conductive
- H01L23/5254—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body with adaptable interconnections comprising anti-fuses, i.e. connections having their state changed from non-conductive to conductive the change of state resulting from the use of an external beam, e.g. laser beam or ion beam
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/52—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/532—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
- H01L23/5329—Insulating materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
Definitions
- This invention relates to a fuse element used in integrated circuit (IC) devices and, more particularly, to a fuse structure and method of making the fuse which employs a local change in electrical conductivity of a film in contact with metal lines.
- Fuses are used in integrated circuit devices such as semiconductor chips to provide redundancy, electrical chip identification and customization of function.
- the fuses are typically formed from a segment of one of the wiring layers, e.g., the “last metal” or “last metal minus one” wiring layer.
- Fusing i.e., deletion of a segment of metal fuse line, is accomplished by exposing the segment to a short, high intensity pulse of “light” from an infra-red laser. The molten metal then boils, vaporizes or explodes out of its oxide surroundings, disrupting line continuity and causing high electrical resistance.
- a sensing circuit is used to detect fuse segment resistance. Sense circuits can be designed to detect that fusing has occurred when line resistance increases or line resistance decreases.
- the dielectric surrounding the fuse must act much like a pressure vessel, i.e., holding the fuse captive until sufficient pressure is achieved during the superheating phase to cause the fuse link to explode through the weakest wall of the pressure vessel and instantaneously boil away. If pressure is released too soon, the fuse melts and extrudes to the surface through the cracks in the dielectric. Any porous materials in contact with the fuse link will experience compression of the voids with subsequent loss of pressure. If material is a polymer, actual reduction in mass occurs as T g , the glass transition temperature (typically less than 500° C. for polyimide-like materials) is exceeded and the voids are expelled.
- a further object of the invention is to provide a method of utilizing a fuse structure in which there is no physical disruption to the fuse.
- a method of programming a device comprising first providing a device having an open circuit comprising a pair of wires having ends thereof separated by a gap. Thereafter a polymer block is formed over the separated ends of the wire. The polymer block is then exposed to an energy beam in order to increase the conductivity of the polymer and electrically connect the wire ends.
- the polymer block comprises a polyimide capable of carbonizing when exposed to an ion or other energy beam for a sufficient time so as to become electrically conductive.
- the polymer block comprises a photoconductive polymer material, and most preferably, the polymer block comprises a polymer/onium salt mixture.
- the polymer block may comprise a polyaniline polymer doped with a triphenylsufonium salt.
- the method may further comprise providing a low dielectric constant (low k) nanopore/nanofoam dielectric material adjacent the wire ends.
- the present invention provides a method of making a fuse for a semiconductor device comprising initially providing an insulating substrate having a surface. Thereafter, a conductive line pair is formed on the surface of the insulating substrate, the conductive line pair having spaced ends. Finally, there is formed over the insulating substrate and between the conductive line pair ends a layer of a polymer capable of carbonizing when exposed to an ion or other energy beam for a sufficient time so as to become electrically conductive.
- the polymer comprises a polyimide, more preferably, a polymer/onium salt mixture, and most preferably, a polyaniline polymer doped with a triphenylsufonium salt.
- the method may further include the step of exposing the polymer in a region between the spaced ends of the conductive line pair to an energy beam to increase the conductivity of the polymer thereby forming a conductive connection between each line of the conductive line pair.
- the present invention provides a method of forming an antifuse comprising forming a first conductor in a dielectric layer, forming a second conductor in the dielectric layer and forming a polymer layer over the first and second conductors. Thereafter, the polymer layer is exposed in a region overlapping at least a portion of both the first and second conductors to an energy beam to lower the electrical resistance of the polymer in the region and electrically connect the first and second conductors.
- the dielectric layer comprises a low k dielectric foam.
- the polymer layer may comprise a polyimide and the first and second conductors may comprise aluminum or copper.
- the present invention provides a fusible link for a semiconductor device comprising an insulating substrate and a conductive line pair on the surface of the insulating substrate, with the conductive line pair having spaced ends.
- a polymer is disposed over the insulating substrate and between the conductive line pair ends.
- the polymer is capable of being changed from a non-conductive to a conductive state upon exposure to an energy beam.
- the polymer comprises a polyimide, more preferably, a polymer/onium salt mixture, most preferably, a polyaniline polymer doped with a triphenylsufonium salt.
- the link may further comprise a low k nanopore/nanofoam dielectric material adjacent the conductive line ends.
- FIG. 1 is an elevational view of a preferred fuse of the present invention.
- FIG. 2 is an elevational view of the fuse of FIG. 1 after it has been blown to change the fuse area from the non-conductive state to the conductive state.
- FIG. 3 is a top plan view of fuses made in accordance with the present invention in which some fuses have been blown.
- FIGS. 4-7 are sequential elevational views of the formation of one embodiment of the fuse of the present invention, in which a portion of the carbonizable non-conductive polymer layer is made electrically conductive before the fuse cover layer is applied.
- FIGS. 8-12 are sequential elevational views of the formation of another embodiment of the fuse of the present invention, in which a portion of the carbonizable non-conductive polymer layer is made electrically conductive and the non-conductive portions are removed before the fuse cover layer is applied.
- FIGS. 13-16 are sequential elevational views of the formation of another embodiment of the fuse of the present invention, in which a portion of the carbonizable non-conductive polymer layer is made electrically conductive after the fuse cover layer is applied.
- FIGS. 1-16 of the drawings in which like numerals refer to like features of the invention.
- Features of the invention are not necessarily shown to scale in the drawings.
- all references to conductivity, non-conductivity or resistivity are with regard to electrical current.
- the dielectric constant is normally about 4.0 for silicon dioxide and about 3.5 for the common polyimide materials. Adding fluorine to either silicon dioxide, e.g. FSG, or polyimide reduces the dielectric constant to 3.0 or less. However, to achieve dielectric constants below about 2.5, air pockets or voids must be added into the insulator film so that the resultant dielectric constant is the net of the dielectric constant of the full density insulator and air. Void containing insulator materials are typically described as nanofoams if they are polymers or nanopores if they are inorganic. In either case, the introduction of voids into the matrix of the insulator material reduces its mechanical strength and modifies other properties such as thermal conductivity. Reduction of mechanical strength compromises the effectiveness of the traditional metal link laser fuse blow process.
- the present invention avoids the need to physically blow fuses by utilizing polymers that can be made to become conductive upon exposure to a laser or other energy source, e.g., ion beam.
- the described structure allows formation of fuses with either polymer or glass low k dielectric films with minimum impact to the dielectric structure.
- the invention provides a fuse structure that is compatible with nanopore/nanofoam low dielectric constant insulating films required for advanced integrated circuit devices. Because the fusing metaphor is changed from deleting a segment of metal line via a localized explosion to causing a local change in the conductivity of a film in contact with the metal lines. mechanically fragile and porous insulator films can be used.
- the invention is preferably comprised of an array of metal conductor wires such as those that may be found the BEOL (back end of the line) of a silicon integrated circuit device.
- the wires are preferably surrounded by dielectric films.
- a low k nanopore/nanofoam dielectric is placed under, over and between the wires.
- a window is opened in the overlayer dielectric, exposing the surface of the wires to be fused, i.e., electrically connected.
- any required windows for wire bonding or C4 are opened to the appropriate metal pads.
- This thin film is imaged to open windows over the medal pads used for wire bond or C4 with conventional lithographic techniques and, if required, cured. Window images need not be opened over the wires to be fused.
- the cure conditions are such that there is minimum impact to the underlying porous dielectric films.
- Selected fuse areas of the completed structure may then be exposed to an ion, laser or other energy beam that increases the local carbon concentration in the thin polymer insulator film, resulting in increased conductivity of the carbonized region, i.e. increased conduction between adjacent metal lines that are in contact with the carbonized part of the film. Areas that are not exposed to the ion, laser or other energy beam do not show increased conductivity.
- Fuse state i.e. whether the structure is fused or not fused, is determined either by direct measurement of conduction between wires or by a comparison scheme measuring resistance or capacitance as compared to a reference structure that is never exposed to the ion beam. In this invention, there is no requirement for mechanically robust dielectric films, or high temperature removal of metal line segments, to accomplish fusing.
- FIG. 1 is a cross-sectional view of the fuse device of the present invention and a contact pad as fabricated by the method of the invention, which may also be referred to as an antifuse, since the metal wiring layer is initially non-conductive and may be made conductive if desired to program an integrated circuit device in which it is formed.
- a low k nanopore/nanofoam dielectric substrate 20 contains separates wiring layers 24 of metals such as copper or aluminum connected as desired by electrically conductive vias 22 . These wiring layers and vias form the circuitry of the integrated circuit device to be programmed by the fuse of the present invention.
- a metal contact pad 26 has an area 36 exposed to the surface of the device, and a metal wiring layer has segments 26 a , 26 b electrically separated by a gap filled with the dielectric 20 .
- Overlying portions of the metal segments 26 a , 26 b is a low k nanopore/nanofoam dielectric barrier layer 28 .
- a fuse area 40 is formed by a nonconductive polymer layer 30 which extends over barrier 28 and down to cover the exposed portions of metal layer segments 26 a , 26 b and the intervening dielectric 20 . This polymer layer is capable of carbonizing when exposed to an ion, laser or other energy beam for a sufficient time so as to become electrically conductive.
- FIG. 2 is a cross-sectional view of the antifuse of FIG. 1 after the antifuse has been exposed to the ion beam and the carbonized polyimide 130 is formed.
- FIG. 3 is a top view showing several antifuses of the types shown in FIG. 1 in proximity. Fuses A and C are electrically open (non-conducting) between metal segments 26 a , 26 b .
- Fuse B has been blown by carbonizing polymer layer 30 to create an electrically conductive, carbonized layer 130 connecting metal segments 26 a , 26 b .
- Fuse D has also been blown and electrically connects metal line segments 26 a , 26 b and 26 c.
- FIGS. 4-7 describe another embodiment of the invention. (Both fuse and pad areas are shown, but the lower wiring layers shown in FIGS. 1 and 2 are omitted in the remaining figures.).
- last metal layer 26 is shown on substrate 20 with passivation layer 28 , e.g., oxide and/or nitride, in place.
- passivation layer 28 e.g., oxide and/or nitride
- fuse area 40 a space or gap has been left between the two metal line ends 26 a , 26 b , with a portion of the line end surfaces exposed, and a horizontally spaced contact pad area 36 is left over layer 26 .
- a blanket layer 30 of a polyaniline polymer doped with a triphenylsufonium salt (or other polymer which is capable of being made more electrically conductive by exposure to an energy beam) has been formed over the substrate and over the exposed portions of the line end surfaces, which layer has electrical non-conductivity on the order of 10E10 ohm cm.
- fuse area 40 has been exposed to laser irradiation, which has made the polymer/onium salt conductive 130 , on the order of 10 ohm cm
- an overcoat (passivation) layer 32 e.g., a polyimide, has been formed over fuse area 40 and an opening 36 again made over the pad 26 area.
- polyaniline polyimide layer 30 The same etchants used for the polyaniline polyimide layer 30 can be used to etch the polyaniline passivation layer 32 .
- Polyaniline dielectric layer 32 has been left in place over fuse area 40 forming a fuse cover layer, along with the underlying portions of the unexposed non-conductive layer 30 on either side of fuse layer 130 .
- FIGS. 8-12 describe a further embodiment of the invention showing both fuse and pad areas.
- last metal layer 26 is shown on substrate 20 with passivation (oxide/nitride) layer 28 in place, leaving the surfaces of line ends 26 a , 26 b and pad contact area 36 uncovered, and a space between the line ends in fuse area 40 .
- a blanket layer 30 of a polyaniline polymer doped with a triphenylsufonium salt (or other polymer which is capable of being made more electrically conductive by exposure to an energy beam) has been formed.
- Layer 30 is non-conductive, on the order 10E10 ohm cm, at this point.
- FIGS. 13-6 describe yet another embodiment of the invention showing both fuse and pad areas.
- last metal layer 26 is shown on substrate 20 with passivation (oxide/nitride) layer 28 in place.
- fuse area 40 a space has been left between two line ends 26 a , 26 b , and a portion of the line end surfaces have also been left exposed.
- a blanket layer 30 of a polyaniline polymer doped with a triphenylsufonium salt (or other polymer which is capable of being made more electrically conductive by exposure to an energy beam) has been formed, which layer is non-conductive on the order of 10E10 ohm cm.
- triphenylsufonium salt or other polymer which is capable of being made more electrically conductive by exposure to an energy beam
- overcoat layer 32 of a dielectric polyimide has been formed over non-conductive layer 30 and an opening 36 again made over the pad area to expose the surface of metal layer 26 .
- the portion of layer 30 of the polymer/onium salt mixture is also etched when the overcoat layer 32 is etched.
- fuse area 40 has been exposed to laser irradiation through overcoat or fuse cover layer 32 to form a conductive fuse 130 from the polymer/onium salt mixture, on the order of 10 ohm cm.
- a nanopore glass is deposited as the underlayer dielectric.
- a thin layer of full density silicon dioxide, silicon nitride, or the like can be deposited as a cap over the nanopore glass layer.
- trenches are etched in the glass to define the wiring pattern, and the resist is then stripped.
- the trenches are filled with one or more metals, e.g. copper, to define the conduction wires.
- metals e.g. copper
- a thin layer of full denisity silicon dioxide., silicon nitride, or the like can be deposited as a barrier under the nanopore glass, and a second thin layer of full density silicon dioxide, silicon nitride, or the like can be deposited as a cap over the nanopore glass.
- a suitable RIE reactive ion etch
- RIE reactive ion etch
- the fuse windows or areas are opened and the wire bond opening area to the metal pads/lines is created, and the resist is stripped.
- a thin film of a laser or ion beam-carbonizable polymer such as PMDA-ODA (pyrometallic dianhydride-oxydianline) or other suitable chemistry polyimide is deposited, e.g., by spin application from a dilute solution of the polyimide.
- PMDA-ODA pyrometallic dianhydride-oxydianline
- window areas are opened to the wire bond pad.
- the resist is stripped using a solvent that does not dissolve the polyimide. e.g., n-butyl acetate.
- the film is then cured by heating in nitrogen to 350° C.
- a focused argon ion beam is used to convert the selected fuse areas to high carbon concentration. By exposing only those regions to the ion beam, the conductivity of the polyimide is increased. Wafer positioning is accomplished within the focused ion beam tool using a precision X-Y stage like that used on step and repeat cameras, and the ion beam parameters are controlled in typical manner, e.g., accelerating voltage or electro-magnetic shuttering.
- Table 1 gives ESCA (electron spectroscopy for chemical analysis) data showing the increase in carbon content of a PMDA-ODA polyimide film after different argon sputter etch times.
- Table 2 gives electrical leakage data, with and without argon sputter etch.
- the present invention provides a fuse structure (or antifuse) in which desired circuits are initially left open in the fuse area.
- the fuse area may left non-conductive or may be made conductive, if desired, by exposure to an energy beam to program the IC device in the desired manner.
- the present invention overcomes the limitations of prior art fuse structures and methods of making the fuse and avoids the need to physically blow fuses.
- the invention also avoids the problem of exposed copper after fuse blow, and allows the use of composite final metals that are otherwise difficult to use as laser fusible links. It allows exotic composite conductors to be used at final metal, because fuse blow is no longer a consideration.
- the present invention also solves the problem of fusing for semiconductor chips when low k organic foams and glasses are used for interlevel dielectrics.
- the energy to make the fusing polymer film conductive is much lower than that required for melting and then vaporizing metal conductors, which could damage the low k material.
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Abstract
Description
TABLE 1 | |||
Polyimide Condition | Carbon | Nitrogen | Oxygen |
Pristine Polyimide (PMDA-ODA) | 76 | 6 | 17 |
300A (SiO2 equiv.) Argon Sputter | 87 | 3 | 9 |
300A (SiO2 equiv.) Argon Sputter | 89 | 2 | 8 |
TABLE 2 | |
Polyimide Condition | Electrical Resistance |
Pristine Polyimide | 1000 E6 ohms @ 200 u; 5 E6 @ 1 u equivalent |
(PMDA-ODA) | |
650A (SiO2 equiv.) | 10 E6 ohms @ 200 u; 5 E6 @ 1 u equivalent |
Argon Sputter | |
Claims (19)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/417,853 US6458630B1 (en) | 1999-10-14 | 1999-10-14 | Antifuse for use with low k dielectric foam insulators |
US10/159,573 US6835973B2 (en) | 1999-10-14 | 2002-05-31 | Antifuse for use with low κ dielectric foam insulators |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/417,853 US6458630B1 (en) | 1999-10-14 | 1999-10-14 | Antifuse for use with low k dielectric foam insulators |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/159,573 Division US6835973B2 (en) | 1999-10-14 | 2002-05-31 | Antifuse for use with low κ dielectric foam insulators |
Publications (1)
Publication Number | Publication Date |
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US6458630B1 true US6458630B1 (en) | 2002-10-01 |
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Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/417,853 Expired - Fee Related US6458630B1 (en) | 1999-10-14 | 1999-10-14 | Antifuse for use with low k dielectric foam insulators |
US10/159,573 Expired - Fee Related US6835973B2 (en) | 1999-10-14 | 2002-05-31 | Antifuse for use with low κ dielectric foam insulators |
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US20020182837A1 (en) * | 1999-10-14 | 2002-12-05 | International Business Machines Corporation | Antifuse for use with low kappa dielectric foam insulators |
US20030178693A1 (en) * | 2002-03-25 | 2003-09-25 | Micron Technology, Inc. | Scalable high performance antifuse structure and process |
US20040051177A1 (en) * | 2002-07-12 | 2004-03-18 | Jean-Pierre Schoellkopf | Adaptation of an integrated circuit to specific needs |
US6734047B1 (en) * | 2002-11-27 | 2004-05-11 | International Business Machines Corporation | Thinning of fuse passivation after C4 formation |
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US7157564B1 (en) | 2000-04-06 | 2007-01-02 | Affymetrix, Inc. | Tag nucleic acids and probe arrays |
US7164188B2 (en) | 2000-12-13 | 2007-01-16 | Micron Technology, Inc. | Buried conductor patterns formed by surface transformation of empty spaces in solid state materials |
US20080268671A1 (en) * | 2007-04-24 | 2008-10-30 | Littelfuse, Inc. | Fuse card system for automotive circuit protection |
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US8647535B2 (en) | 2011-01-07 | 2014-02-11 | International Business Machines Corporation | Conductive metal and diffusion barrier seed compositions, and methods of use in semiconductor and interlevel dielectric substrates |
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