US635168A - Black sulfur dye. - Google Patents
Black sulfur dye. Download PDFInfo
- Publication number
- US635168A US635168A US72686499A US1899726864A US635168A US 635168 A US635168 A US 635168A US 72686499 A US72686499 A US 72686499A US 1899726864 A US1899726864 A US 1899726864A US 635168 A US635168 A US 635168A
- Authority
- US
- United States
- Prior art keywords
- black
- para
- dye
- sulfur
- coloring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/54—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to two or three six-membered aromatic rings
Definitions
- the product obtained in this Way forms in dry state a grayish-black powder, which readily dissolves in water with a dark greenish-blue color, which on addition of caustic-soda lye turns more bluish.
- the aqueous solution of the dye is precipitated when mineral acids or acetic acid is added, a brownish-black precipitate being formed.
- a current of air or carbonic acid By passing a current of air or carbonic acid through the aqueous solution of the dye a dark-blue precipitate is separated after some time.
- concentrated sulfuric acid the dye dissolves with dirty brownishgreen color, while in fuming sulfuric acid containing about twenty per cent. anhydride it dissolves with a bluish-black color.
- the black dye which results from heating equimolecular proportions of dinitrooxydiphenylamin and para-amidophenol with sulfur and alkali sulfids, said dye being readily soluble in water containing a small portion of alkali sulfid with dark greenish-blue color, which on addition of caustic-soda lye turns more bluish, the aqueous solution yielding on addition of mineral acids or acetic acid a brownish-black precipitate while by introduction of a current of air or carbonic acid after some time a black precipitate is formed, dissolving in concentrated sulfuric acid with dirty brownish-green color, in fuming sulfuric acid with bluish-black color, said dye producing on unmordanted cotton in an alkaline bath black shades of great intensity and fastness.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
NITED STATES LATENT Erica.
RICHARD KIROHHOFF AND EMIL I-IAUSSMANN, OF BERLIN, GERMANY,
*ASSIGNORS TO THE ACTIEN-GESELLSOI-IAFT FUR ANILIN FABRIKA- TION, OF SAME PLACE.
BLACK SULFUR DYE.
SPECIFICATION forming part of Letters Patent No. 635,168, dated October 17, 1899.
Application filed August 11, 1899. Serial No. 726,864. (No specimens.)
T0 aZZ whom it 11mg concern:
Be it known that we, RICHARD KIROHHOFF and EMIL HAUSSMANN, of Berlin, in the Kingdom of Prussia, German Empire, have invented new and useful Improvements in Black Dyes; and we do hereby declare that the following is a full, clear, and exact description thereof, which will enable others skilled in the art to which it appertains to make and use the same.
It is well known that by treating certain disubstituted derivatives of benzene, such as para-amidophenol or para-phenylenediamin, with sulfur and sulfids of alkali metals coloring-matters are produced,the so-called Vidalblacks of commerce, as described in United States Letters Patents Nos. 532,503 and 532,484., These dyestufis dissolve in water with bottle-green color and dye cotton darkgreen shades, which only by subsequent oxidation are turned black. On the other hand, it has been shown that by melting with sulfur and sulfids of alkali metals certain nitrooxy derivatives of diphenylamin there are obtained coloring-matters which directly produce on the fiber black tints without requirin g a subsequent'oxidation. A coloring-matter of this kind is brought upon the market under the name of immedial-black. (Oon1 pare United States Letters Patents Nos. 610,541 and 625,717.) WVe have now found that a quite-unexpected reaction takes place if sulfur and sulfids of alkali metals are allowed to act on mixtures of equimolecular proportions of para-amidophenol and of a nitrooxy derivative of diphenylamin. This reaction does not lead, as might be expected, either to the formation of a mixture of Vidalblack and of immedial-black or to the formation of only one of these dyestuffs, but there results an entirely new coloring-matter,which is clearly distinguished from both the dyestuffs mentioned. The new product dyes cotton directly deep-black shades without requiring, like Vidal-black, a subsequent oxidation, Also the shades obtained by means of the new coloring-matter are different from those obtained by means of immedial-black, the latter being more bluish black, whereas our new product yields green black shades. Furthermore, it is not at all possible to produce the shades which are obtained by means of our new product by simply mixing the abovementioned coloring-matters separately prepared by the action of sulfur and sulfids on para-amidophenol and on a nitro derivative of diphenylamin. cate that when mixtures of para-amidophenol and of a nitrooxy derivative of diphenylamin are heated with sulfur and sulfids of alkali metals the two components simultaneously enter into the reaction, a new coloring-matter being formed which is entirely different from the products obtained by treating the two components separately with the same agents.
The following directions will explain in what manner we proceed in order to carry out our invention. Forty-eight parts, by weight, of sodium sulfid, seventeen parts of sulfur,and five parts of water are heated together, and to this mixture is added at to centigrade a mixture of ten parts of dinitrooxy-diphenylamin and four parts of para-amidophenols (equimolecular proportions.) The formation of the coloring-matter commences at about centigrade. The temperature is slowly raised up to to centigrade and maintained for about four to five hours. The dry melt is powdered and can be directly employed for dyeing. The product obtained in this Way forms in dry state a grayish-black powder, which readily dissolves in water with a dark greenish-blue color, which on addition of caustic-soda lye turns more bluish. The aqueous solution of the dye is precipitated when mineral acids or acetic acid is added, a brownish-black precipitate being formed. By passing a current of air or carbonic acid through the aqueous solution of the dye a dark-blue precipitate is separated after some time. In concentrated sulfuric acid the dye dissolves with dirty brownishgreen color, while in fuming sulfuric acid containing about twenty per cent. anhydride it dissolves with a bluish-black color.
These facts clearly indi- The dye is practically insoluble in the usual solvents, such as alcohol, benzene, ether, and the like.
Our new dye produces directly on uninordanted cotton black shades.
The following alterations may be made in the above example without materially changing the character of the product obtained. For the para-amidophenol we may substitute para-phenylenediamin. Moreover, instead of directly introducing these diamins or amidophenol into the reaction we mayequally well use the corresponding nitro derivativesthat is to say, para-nitrophenol, para-nitranilin, para-nitro toluidin,or para-dinitrobenzene and para-dinitrotoluene-these substances being converted into the amido products by the action of sulfids during the melting process. Further, the quantities of sulfur and sodium sulfid in the above example may be varied within wide limits, and we do not confine ourselves to the figures given in the above example.
Having now described our invention and in what manner the same can be perforined,what I we claim as new is l The black dye which results from heating equimolecular proportions of dinitrooxydiphenylamin and para-amidophenol with sulfur and alkali sulfids, said dye being readily soluble in water containing a small portion of alkali sulfid with dark greenish-blue color, which on addition of caustic-soda lye turns more bluish, the aqueous solution yielding on addition of mineral acids or acetic acid a brownish-black precipitate while by introduction of a current of air or carbonic acid after some time a black precipitate is formed, dissolving in concentrated sulfuric acid with dirty brownish-green color, in fuming sulfuric acid with bluish-black color, said dye producing on unmordanted cotton in an alkaline bath black shades of great intensity and fastness.
In witness whereof we have hereunto signed our names, this 21st day of July, 1899, in the presence of two subscribing Witnesses.
RICHARD KIROI-IHOFE EMIL HAUSSMANNA Witnesses:
WALDEMAR HAUPT, WILLIAM llIAYNER;
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US72686499A US635168A (en) | 1899-08-11 | 1899-08-11 | Black sulfur dye. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US72686499A US635168A (en) | 1899-08-11 | 1899-08-11 | Black sulfur dye. |
Publications (1)
Publication Number | Publication Date |
---|---|
US635168A true US635168A (en) | 1899-10-17 |
Family
ID=2703759
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US72686499A Expired - Lifetime US635168A (en) | 1899-08-11 | 1899-08-11 | Black sulfur dye. |
Country Status (1)
Country | Link |
---|---|
US (1) | US635168A (en) |
-
1899
- 1899-08-11 US US72686499A patent/US635168A/en not_active Expired - Lifetime
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US635168A (en) | Black sulfur dye. | |
US635169A (en) | Black sulfur dye. | |
US647847A (en) | Black sulfur dye. | |
US536532A (en) | Gesellschaft fur anilin fabrikation | |
US536880A (en) | Gesellschaft fur anilin fabrikation | |
US732090A (en) | Blue sulfur dye and process of making same. | |
US651077A (en) | Green-black sulfur dye. | |
US655659A (en) | Black sulfur dye. | |
US628607A (en) | Black dye. | |
US628608A (en) | Black dye. | |
US645738A (en) | Black sulfur dye. | |
US536878A (en) | Gesellschaft fur anilin fabrikation | |
US1702022A (en) | Alpha-di (methylamino)-alpha-dihydroxy-anthraquinone disulphonic acids and process of making the same | |
US764733A (en) | Black sulfur dye and process of making same. | |
US650293A (en) | Black sulfur dye. | |
US675585A (en) | Black sulfur dye and process of making same. | |
US680732A (en) | Blue acid dye. | |
US688646A (en) | Black sulfur dye and process of producing same. | |
US641588A (en) | Black sulfur dye. | |
US545337A (en) | boiin | |
US647846A (en) | Black sulfur dye. | |
US640559A (en) | Brown sulfur dye. | |
US650327A (en) | Black sulfur dye. | |
US734325A (en) | Green anthraquinone dye and process of making same. | |
US551885A (en) | Joseph bierer |