US6054098A - Apparatus for measuring ozone - Google Patents
Apparatus for measuring ozone Download PDFInfo
- Publication number
- US6054098A US6054098A US09/122,537 US12253798A US6054098A US 6054098 A US6054098 A US 6054098A US 12253798 A US12253798 A US 12253798A US 6054098 A US6054098 A US 6054098A
- Authority
- US
- United States
- Prior art keywords
- ozone
- sample gas
- gas line
- reference gas
- introducing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000003054 catalyst Substances 0.000 claims abstract description 16
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052709 silver Inorganic materials 0.000 claims abstract description 10
- 239000004332 silver Substances 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- 210000002268 wool Anatomy 0.000 claims abstract description 6
- 230000000694 effects Effects 0.000 abstract description 7
- 238000001179 sorption measurement Methods 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000011410 subtraction method Methods 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
- G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
- G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
- G01N33/0036—General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component
- G01N33/0039—O3
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/20—Oxygen containing
- Y10T436/206664—Ozone or peroxide
Definitions
- numeral 5 designates a glass tube, 6 silver wool as catalyst packed in the glass tube 5, and 7 a heater block (temperature control means), for which for example, positive temperature characteristic thermister with self-temperature control capabilities or various cartridge heaters are used, and whose temperature is set to 100 to 130° C. so that the interference effects of SO 2 component can be suppressed.
- a heater block temperature control means
- FIG. 3 is a graph showing the relationship between the catalyst reaction temperature and SO 2 interference, and in this case, three measured values for determining the concentration difference (between reference gas line 11 and sample gas line 12) due to adsorption of SO 2 component at each temperature are shown with ⁇ , +, and ⁇ marks connected with solid line, broken line, and alternate long and short dash line, respectively, indicating that in the temperature range from 100 to 130° C., adsorption of SO 2 component to the surface of oxidized silver wool (AgO) is slight. Because ozone decomposes at 100° C. or higher, the above temperature range is set as a condition in that SO 2 adsorption is slight in the temperature range of 100° C. to 130° C.
- the catalyst reaction temperature is set to a temperature range from 100 to 130° C. in the apparatus for measuring ozone using the ozone decomposer with silver used as a catalyst, adsorption of SO 2 component to the oxidized silver surface is able to be held slight and SO 2 interference effects can be reduced and suppressed.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
- Sampling And Sample Adjustment (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Abstract
This invention provides an apparatus for measuring ozone in which interference effects of SO2 are intended to be reduced. This invention comprises a reference gas line for generating reference gas with ozone removed by allowing the sample gas to pass through the ozone decomposer with silver wool used as a catalyst, a sample gas line for introducing the sample gas as it is, an ozone analyzer to which the reference gas line and the sample gas line are connected via a selector valve and which measures the ozone component in the sample gas by introducing the reference gas and the sample gas alternately at specified intervals, and a temperature controller installed to the ozone decomposer for setting the catalyst reaction temperature to a range from 100 to 130° C.
Description
1. Field of the Invention
The present invention relates to an apparatus for measuring ozone component in the sample gas.
2. Description of the Prior Art
In the ozone measuring apparatus configured to determine the ozone component by the subtraction method by connecting the reference gas line for introducing reference gas with ozone removed by allowing the gas to pass the ozone decomposer and a sample gas line for introducing the sample gas as it is to an ozone analyzer via a selector valve and by introducing the reference gas and the sample gas alternately at specified intervals from both lines, there is an advantage of little interference effects because interference components are canceled each other.
For the above-mentioned ozone decomposer, various oxidation catalysts are used, but for example, when silver wool is used, the ozone decomposer is usually heated to about 170° C. for reducing the interference caused by H2 O in the atmosphere for application.
However, at this level of temperature, oxidation reactions shown by ##EQU1## and reduction reactions shown by ##EQU2## take place, but the oxidation reaction of Eq. (1) is more conspicuous than the reduction reaction of Eq. (2), and adsorption of SO2 component occurs on the AgO surface.
Because there is a portion in which SO2 ultraviolet ray absorption spectrum overlaps ultraviolet ray absorption of ozone, if the SO2 component is contained in the sample gas, SO2 may be adsorbed to the ozone decomposer, causing a concentration difference of SO2 between reference gas and sample gas, and SO2 interference effects occur.
Under these circumstances, it is an object of this invention to provide an apparatus for measuring ozone in which interference effects of SO2 are intended to be reduced.
This invention configures the means for solving the above problems in the following manner.
That is, this invention comprises a reference gas line for generating reference gas with ozone removed by allowing the sample gas to pass through the ozone decomposer with silver used as a catalyst, a sample gas line for introducing the sample gas as it is, an ozone analyzer to which the reference gas line and the sample gas line are connected via a selector valve and which measures the ozone component in the sample gas by introducing the reference gas and the sample gas alternately at specified intervals, and a temperature control means installed to the ozone decomposer for setting the catalyst reaction temperature to a range from 100 to 130° C.
Since ozone decomposes at temperature of 100° C. or higher, SO2 interference can be reduced by setting conditions in which temperature is 100° C. or higher and SO2 interference is slight. FIG. 3 is a graph showing catalyst reaction temperature and SO2 interference, which indicates that the SO2 interference is a little in the temperature range from 100 to 130° C., suggesting that the catalyst should be reacted in this temperature range.
FIG. 1 is a block diagram showing one embodiment of the apparatus for measuring ozone according to this invention;
FIG. 2 is a block diagram of the ozone decomposer; and
FIG. 3 is a graph showing the relationship between the catalyst reaction temperature and SO2 interference effects in the ozone decomposer.
Referring now to the drawings, a preferred embodiment of the apparatus for measuring ozone according to the invention will be described in detail hereinafter.
FIG. 1 shows a configuration of the apparatus for measuring ozone using the ultraviolet ray absorption method, and numeral 1 designates a sample introducing line for introducing the sample gas, and the sample introducing line 1 branches into a reference gas line 11 and a sample gas line 12 at the branching point B, and to the reference gas line 11, an ozone decomposer 2 using silver wool as a catalyst is installed and ozone in the sample gas is removed to generate reference gas, while to the sample gas line 12, sample gas is introduced as it is, and the reference gas line 11 and the sample gas line 12 are connected to the ozone analyzer 4 using the ultraviolet ray absorption method via a three-way selector valve 3, and the reference gas and sample gas are introduced into the ozone analyzer 4 alternately at specified intervals.
The configuration of the above ozone decomposer 2 is shown in FIG. 2, and numeral 5 designates a glass tube, 6 silver wool as catalyst packed in the glass tube 5, and 7 a heater block (temperature control means), for which for example, positive temperature characteristic thermister with self-temperature control capabilities or various cartridge heaters are used, and whose temperature is set to 100 to 130° C. so that the interference effects of SO2 component can be suppressed.
FIG. 3 is a graph showing the relationship between the catalyst reaction temperature and SO2 interference, and in this case, three measured values for determining the concentration difference (between reference gas line 11 and sample gas line 12) due to adsorption of SO2 component at each temperature are shown with □, +, and ∘ marks connected with solid line, broken line, and alternate long and short dash line, respectively, indicating that in the temperature range from 100 to 130° C., adsorption of SO2 component to the surface of oxidized silver wool (AgO) is slight. Because ozone decomposes at 100° C. or higher, the above temperature range is set as a condition in that SO2 adsorption is slight in the temperature range of 100° C. to 130° C.
As described above, because the catalyst reaction temperature is set to a temperature range from 100 to 130° C. in the apparatus for measuring ozone using the ozone decomposer with silver used as a catalyst, adsorption of SO2 component to the oxidized silver surface is able to be held slight and SO2 interference effects can be reduced and suppressed.
Claims (2)
1. An apparatus for measuring ozone comprising a reference gas line for generating reference gas with ozone removed by allowing the sample gas to pass through the ozone decomposer with silver used as a catalyst, a sample gas line for introducing the sample gas as it is, an ozone analyzer to which the reference gas line and the sample gas line are connected via a selector valve and which measures the ozone component in the sample gas by introducing the reference gas and the sample gas alternately at specified intervals, and a temperature control means installed to the ozone decomposer for setting the catalyst reaction temperature to a range from 100 to 130° C.
2. An apparatus for measuring ozone according to claim 1, in which the catalyst is silver wool.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21812597A JP3374052B2 (en) | 1997-07-28 | 1997-07-28 | Ozone measurement device |
| JP9-218125 | 1997-07-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US6054098A true US6054098A (en) | 2000-04-25 |
Family
ID=16715035
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US09/122,537 Expired - Lifetime US6054098A (en) | 1997-07-28 | 1998-07-24 | Apparatus for measuring ozone |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US6054098A (en) |
| JP (1) | JP3374052B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2060628A1 (en) | 2002-02-13 | 2009-05-20 | XOMA Technology Ltd. | Eukaryotic signal sequences for polypeptide expression and polypeptide display libraries |
| WO2017202571A1 (en) * | 2016-05-27 | 2017-11-30 | Ams Sensor Solutions Germany Gmbh | Method for determining an absolute gas concentration using a gas sensor arrangement and gas sensor arrangement for determining an absolute gas concentration |
| WO2021123864A1 (en) * | 2019-12-16 | 2021-06-24 | Aeroqual Ltd. | Improved measurement of gases |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4521264B2 (en) * | 2004-12-22 | 2010-08-11 | 東亜ディーケーケー株式会社 | Sampling device |
| WO2024142653A1 (en) * | 2022-12-27 | 2024-07-04 | 株式会社堀場製作所 | Analysis device, analysis method, and ozone decomposer |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3464797A (en) * | 1966-10-26 | 1969-09-02 | Cabot Corp | Instrument for determining ozone |
-
1997
- 1997-07-28 JP JP21812597A patent/JP3374052B2/en not_active Expired - Fee Related
-
1998
- 1998-07-24 US US09/122,537 patent/US6054098A/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3464797A (en) * | 1966-10-26 | 1969-09-02 | Cabot Corp | Instrument for determining ozone |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2060628A1 (en) | 2002-02-13 | 2009-05-20 | XOMA Technology Ltd. | Eukaryotic signal sequences for polypeptide expression and polypeptide display libraries |
| WO2017202571A1 (en) * | 2016-05-27 | 2017-11-30 | Ams Sensor Solutions Germany Gmbh | Method for determining an absolute gas concentration using a gas sensor arrangement and gas sensor arrangement for determining an absolute gas concentration |
| US10948445B2 (en) | 2016-05-27 | 2021-03-16 | Sciosense B.V. | Method and gas sensor arrangement for determining an absolute gas concentration with a gas sensor and decomposing gas to be measured |
| WO2021123864A1 (en) * | 2019-12-16 | 2021-06-24 | Aeroqual Ltd. | Improved measurement of gases |
| GB2606062A (en) * | 2019-12-16 | 2022-10-26 | Aeroqual Ltd | Improved measurement of gases |
| GB2606062B (en) * | 2019-12-16 | 2024-01-17 | Aeroqual Ltd | Improved measurement of gases |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH1144620A (en) | 1999-02-16 |
| JP3374052B2 (en) | 2003-02-04 |
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| Date | Code | Title | Description |
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Owner name: HORIBA, LTD., JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:KATO, JUNJI;OHNISHI, TOSHIKAZU;REEL/FRAME:009597/0243 Effective date: 19981009 |
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