US5791308A - Plug assembly - Google Patents
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- US5791308A US5791308A US08/897,016 US89701697A US5791308A US 5791308 A US5791308 A US 5791308A US 89701697 A US89701697 A US 89701697A US 5791308 A US5791308 A US 5791308A
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- Prior art keywords
- wire
- electrode
- igniter plug
- comprised
- igniter
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- 238000002485 combustion reaction Methods 0.000 claims abstract description 23
- 239000000446 fuel Substances 0.000 claims abstract description 21
- 238000010438 heat treatment Methods 0.000 claims abstract description 15
- 230000003197 catalytic effect Effects 0.000 claims abstract description 13
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 25
- 239000003054 catalyst Substances 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 230000003647 oxidation Effects 0.000 claims description 12
- 238000007254 oxidation reaction Methods 0.000 claims description 12
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- 229910052697 platinum Inorganic materials 0.000 claims description 4
- 229910052741 iridium Inorganic materials 0.000 claims description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229910052703 rhodium Inorganic materials 0.000 claims description 2
- 239000010948 rhodium Substances 0.000 claims description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims 4
- 239000010937 tungsten Substances 0.000 claims 4
- 238000000034 method Methods 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 239000000919 ceramic Substances 0.000 abstract description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000013461 design Methods 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
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- 239000003345 natural gas Substances 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- -1 Platinum group metals Chemical class 0.000 description 1
- 229910001260 Pt alloy Inorganic materials 0.000 description 1
- 229910000629 Rh alloy Inorganic materials 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000001668 ameliorated effect Effects 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- YVPJCJLMRRTDMQ-UHFFFAOYSA-N ethyl diazoacetate Chemical compound CCOC(=O)C=[N+]=[N-] YVPJCJLMRRTDMQ-UHFFFAOYSA-N 0.000 description 1
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- 239000003502 gasoline Substances 0.000 description 1
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- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
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- 238000012546 transfer Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23Q—IGNITION; EXTINGUISHING-DEVICES
- F23Q7/00—Incandescent ignition; Igniters using electrically-produced heat, e.g. lighters for cigarettes; Electrically-heated glowing plugs
- F23Q7/001—Glowing plugs for internal-combustion engines
Definitions
- the invention relates to an assembly for ignition of combustion in combustion chambers.
- Glow plugs of various designs, exposed heater and enclosed heater, are used for ignition in a wide variety of combustion systems.
- glow plugs serve to enable cold start ignition.
- Glow plugs can also be used in diesel engines to provide a continuous ignition source to support reduced emissions or to enable combustion of low cetane fuels, such as natural gas or methanol. Where a glow plug is employed as a continuous ignition source, it also provides the cold start ignition.
- enclosed heater style glow plugs similar to those found in U.S. Pat. Nos. 4,896,636, 5,580,476 and 5,593,607, have been relied upon for this dual purpose mission. Such plugs not only avoid exposure of the heater element to the combustion environment but allow use of a heater consisting of a fairly high number of coils of fairly fine wire and thus can operate on a higher voltage.
- the enclosed heater style glow plug relies on heat conduction from the center heater to heat the external surface to provide sufficient heat to support continuous ignition or cold starting. This design, however, has two significant short comings.
- durability of the glow plug is a function of durability of the surface encasing the enclosed heating element; failure of the surface around the heating element leads to failure of the heater element.
- the heater must always be operated at a temperature above the temperature required to support ignition or cold starting, since the heat must be transmitted from the heater to the surface of the protective surface encasing the heating element.
- the requirement for increased operating temperature of the heating element places additional stress on the heater element with direct durability consequences in continuous ignition applications.
- Use of low cetane fuels only serves to worsen the problem.
- a catalyst as in the above noted patents.
- the use of a catalyst, coated on the surface or wrapped around the surface of the tip of the glow plug reduces the temperature required of the glow plug to support continuous ignition, thereby allowing the heating element to operate at a lower temperature for any given fuel cetane level.
- the glow plug can now support the use of lower cetane fuels than otherwise.
- the internally heated glow plug is still temperature limited by the internal heater, the encasing surface durability, and the heat that the heater can dependably and durably impart to the surface. Therefore, in those operating conditions where a high heating level is required, such as extreme cold starting or continuous ignition operation, sheathed glow plugs suffer sever durability consequences. Plug life is much too short.
- the present invention meets this objective by combining the best attributes of enclosed heater glow plugs and exposed heater glow plugs into a unique exposed heater design which allows the benefits of catalytically supported combustion.
- the present invention provides igniters which combine catalytic activity and the resulting ability to operate at lower temperatures with the capability to operate at high temperatures in a combustion environment.
- igniters durable at temperatures much higher than conventional combustion chamber glow plugs can be fabricated by winding high melting point, oxidation resistant wire onto a heat sink mandrel of a refractory oxide material, such as alumina or similar ceramic material, and providing electrical leads to allow direct electrical heating of the wire. Coils of at least four or more turns are preferred for igniters of the present invention.
- igniter of the present invention atomized fuel entering a combustion chamber is reliably ignited as it contacts a hot catalytic wire coil of oxide hardened platinum alloy that has been electrically heated by passage of an electric current. Thermal contact, radiation and conduction, from the wire to the mandrel moderates the effect of high combustion temperatures on the temperature of the catalyst element.
- thermal contact means providing effective heat transfer.
- a high temperature oxidation resistant catalytic metal such as an oxide dispersion hardened platinum group metal for the coil wire not only provides catalytic enhancement of ignition but allows for operation even with temperature excursions over 1700 degrees Kelvin, thus providing a wide margin between the coil temperature required for reliable ignition under adverse operating conditions and the maximum safe plug temperature. Even under adverse ignition conditions, the maximum required coil temperature for ignition is no more than about 1400 degrees Kelvin.
- Platinum group metals include platinum, palladium, iridium, and rhodium as well as alloys thereof.
- FIG. 1 shows a side view of an igniter plug of the present invention using the body of the igniter plug as the second electrode.
- FIG. 2 shows a side view of an igniter plug of the present invention using a second electrode within the body of the igniter plug.
- FIG. 3 shows a partial cross-sectional side view of an embodiment of an igniter element of the invention having an electrical heater/catalyst wire wound on an alpha alumina heat sink mandrel.
- igniter plug 2 comprises an igniter element 4 having an electrically resistive heating element coil of catalytic wire 6 wound on mandrel 8 and connected at one end to electrode 10 and the other end to body 7 which is designed to allow installation of the igniter plug into a combustion zone, such as a diesel engine cylinder.
- Electrode 10 passes through both mandrel 8 and the body 7 and is electrically insulated from body 7.
- igniter plug 2 comprises an igniter element 4 having an electrically resistive heating element coil of catalytic wire 6 wound on mandrel 8 and connected at one end to electrode 10 and the other end is connected to electrode 11 and a body 7 which is designed to allow installation of the igniter plug into a combustion zone, such as a diesel cylinder.
- Electrodes 10 passes through both mandrel 8 and the body 7 and is electrically insulated from body 7.
- Electrode 11 also passes through body 7 and is electrically insulated from both body 7 and electrode 10.
- electrode 10 be selected such that when the igniter plug wire 6 is operating at its desired operating temperature the operating temperature of electrode 10 will be less than the operating temperature of wire 6.
- the specific temperature difference is based on the design considerations for a particular application.
- the major elements that a person skilled in the art should consider when selecting the material for and size of electrode 10 are: the temperature at which the electrode material will fail, the temperature delta between the ultimate temperature inside of the mandrel that will be generated by the heat of the electrode versus the wire temperature to assure that center mandrel temperature will be less than the wire temperature, and that less thermal stress on the electrode will increase the service life of the igniter element.
- the primary design parameter to be used in designing the electrode is electrical resistance. Electrode 10 must have an electrical resistance significantly less than that of wire 6, as must electrode 11.
- igniter element 4 comprises heat sink mandrel 8 having spiral grooves 15 holding a multi-turn coil of catalytic wire 6.
- the grooves have a depth of at least about 25 percent of the wire 6 diameter.
- the catalytic resistance heating element utilizes an alloy wire preferably having a service temperature in air of at least about 1400 degrees Kelvin, and more preferably 1500 degrees Kelvin, such as an alloy of oxide dispersion hardened platinum metal, which serves as both the catalyst and the electrically resistive heater.
- service temperature as used herein is a temperature at which the wire can survive for at least fifty hours.
- a platinum metal alloy having a stable electrical resistivity temperature relationship, provides the advantage of allowing feedback control of the element temperature as well as providing a renewable catalyst surface in erosive environments.
- a platinum wire coil is self regulating in that with a fixed applied voltage the electrical current decreases with increase in wire temperature. This means that plugs can be connected to a fixed voltage supply without use of a temperature controller.
- a platinum group metal clad tungsten wire offers similar advantages.
- the catalytic heating coils may also be formed from other oxidation resistant alloys as for example, from Haynes 214 or Fecralloy wire, such as Allegheny Ludlum's Alpha-IV, coated with an ignition catalyst known in the art, such as a platinum metal catalyst.
- mandrel 8 which is a ceramic alumina support.
- Other ceramic materials of high electrical resistivity to prevent short circuiting between coils and good thermal conductivity are also suitable for heat sink mandrel 8.
- the wire 6 is thus itself a catalyst metal that not only offers the advantages of catalytic reactivity, allowing ignition temperatures below 1400 degrees Kelvin, but provides the capability of reliably operating long term at temperatures as high as 1600 degrees Kelvin, which is a temperature well above that required for ignition of even fuels such as methane or methanol. If desired, the temperature of the element may be most readily monitored and controlled by measurement of element electrical resistance.
- spark plugs were obtained which could be mounted in place of the standard glow plugs used in the Lister-Petter LPW-S2 two cylinder diesel chosen as the test engine.
- a nickel rod electrode extension was welded to the center electrode of each plug for mounting of an alumina tube of 0.157 inch outer diameter and nominally 0.75 inches long and having spiral grooves about 0.010 inches deep, to serve as the heat sink mandrel.
- Heraeus Gmbh, DPH Pt-10Rh was then wound in the grooves in the mandrel. Then, one end of the resulting coil was welded to the center nickel electrode and the other welded to the spark plug body in place of the original grounding electrode.
- the electrode had a diameter of 0.064 inches with an electrical resistance at the operating temperature of the plug of approximately one percent of the wire. Operated at 5.5 volts in air the igniter plugs reached a temperature of about 1,478 degrees Kelvin. Cold cell testing of the Lister-Petter engine operating with Jet-A fuel showed the igniter plugs would start the engine at lower temperatures than the original equipment manufacturer (O.E.M.) glow plugs specified for the engine.
- the igniter plugs of the present invention required less than half the electrical power required for the O.E.M. plugs. In the engine, only about 1/8 inch of the plug igniter tip extended into the engine prechamber. No modification of the engine hardware was required to install the igniter plugs. Igniter plugs of the present invention are readily made for any engine. Ungrounded plugs were made using commercially available multiple feed through Conax fittings in place of spark plug fittings to mount igniter coil/mandrel assemblies of the present invention. In this example, the electrical resistance of the electrode at the operation temperature of the igniter plug was approximately 25% of the wire.
- igniter plugs of the present invention After the tests of example I the igniter plugs were placed in another engine and run for over 200 hours and 27 start cycles using automotive diesel fuel. No change in electrical resistance was detected and cold cell testing of the aged igniter plugs showed no degradation in performance. To further evaluate high temperature durability, samples of the DPH platinum wire used in the igniter plugs of the present invention were heated in air to 1,573 degrees Kelvin for 100 hours to evaluate metal loss rate. Weight loss was only 1.7%.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Ignition Installations For Internal Combustion Engines (AREA)
- Combustion Methods Of Internal-Combustion Engines (AREA)
Abstract
A plug assembly for ignition of fuel in admixture with air within a combustion chamber which comprises an exposed heating element having a multi-turn coil of electrically conductive catalytic wire mounted in grooves formed on the surface of ceramic support structure.
Description
This invention was made with government support under DAAE 07-92-C-R041 awarded by the United States Army. The U.S. government has certain rights in this invention.
1. Field of the Invention
The invention relates to an assembly for ignition of combustion in combustion chambers.
2. Brief Description of Related Art
Glow plugs of various designs, exposed heater and enclosed heater, are used for ignition in a wide variety of combustion systems. For example, in diesel engines glow plugs serve to enable cold start ignition. Glow plugs can also be used in diesel engines to provide a continuous ignition source to support reduced emissions or to enable combustion of low cetane fuels, such as natural gas or methanol. Where a glow plug is employed as a continuous ignition source, it also provides the cold start ignition.
For a glow plug to support cold start ignition at very low temperatures, ie below about 250 degrees Kelvin, or continuous ignition of low cetane fuels, significantly higher plug temperatures are required, thus a wider operating temperature range than available with conventional glow plugs. Moreover, a continuous ignition glow plug requires greater durability than a conventional cold start ignition glow plug. Continuous operation exposes the heating element of the glow plug to many more hours of operation, while the significantly higher igniter temperatures required for extreme cold starting or use with low cetane fuels, such as methanol, ethanol and other alcohols as well as gasoline and natural gas, also impacts durability. Thus, if a low cetane fuel is being used in the engine, durability is impacted by both the increased plug temperature and the increase in operating hours required for continuous ignition. As a result, there is a need for glow plugs which are durable and effective at higher temperatures than state of the art glow plugs.
Conventional exposed heater element glow plugs designed to withstand the combustion environment have a relatively short, heavy gauge wire heating element, typically one or two turns. Therefore, the electrical resistance is low and the voltage is limited to one to two volts. Such plugs are neither durable nor compact enough and thus have largely been displaced as igniter plugs in diesels by enclosed heater (sheathed) glow plugs. Thus, exposed heater glow plugs have not been considered good candidates for continuous duty glow plugs by those skilled in the art.
Consequently, enclosed heater style glow plugs, similar to those found in U.S. Pat. Nos. 4,896,636, 5,580,476 and 5,593,607, have been relied upon for this dual purpose mission. Such plugs not only avoid exposure of the heater element to the combustion environment but allow use of a heater consisting of a fairly high number of coils of fairly fine wire and thus can operate on a higher voltage. The enclosed heater style glow plug relies on heat conduction from the center heater to heat the external surface to provide sufficient heat to support continuous ignition or cold starting. This design, however, has two significant short comings. First, durability of the glow plug is a function of durability of the surface encasing the enclosed heating element; failure of the surface around the heating element leads to failure of the heater element. Second, the heater must always be operated at a temperature above the temperature required to support ignition or cold starting, since the heat must be transmitted from the heater to the surface of the protective surface encasing the heating element. The requirement for increased operating temperature of the heating element places additional stress on the heater element with direct durability consequences in continuous ignition applications. Use of low cetane fuels only serves to worsen the problem. Those skilled in the art of glow plug design have realized that this latter problem can be ameliorated by using a catalyst, as in the above noted patents. The use of a catalyst, coated on the surface or wrapped around the surface of the tip of the glow plug, reduces the temperature required of the glow plug to support continuous ignition, thereby allowing the heating element to operate at a lower temperature for any given fuel cetane level. For a given temperature, this yields the benefit that the glow plug can now support the use of lower cetane fuels than otherwise. The internally heated glow plug, however, is still temperature limited by the internal heater, the encasing surface durability, and the heat that the heater can dependably and durably impart to the surface. Therefore, in those operating conditions where a high heating level is required, such as extreme cold starting or continuous ignition operation, sheathed glow plugs suffer sever durability consequences. Plug life is much too short.
Thus there is a need for durable, continuous operation glow plugs that can survive at the higher temperatures needed to support the broad-spectrum, continuous ignition of lower cetane fuels under adverse operating conditions. The present invention meets this objective by combining the best attributes of enclosed heater glow plugs and exposed heater glow plugs into a unique exposed heater design which allows the benefits of catalytically supported combustion. The present invention provides igniters which combine catalytic activity and the resulting ability to operate at lower temperatures with the capability to operate at high temperatures in a combustion environment.
It has now been found that igniters durable at temperatures much higher than conventional combustion chamber glow plugs can be fabricated by winding high melting point, oxidation resistant wire onto a heat sink mandrel of a refractory oxide material, such as alumina or similar ceramic material, and providing electrical leads to allow direct electrical heating of the wire. Coils of at least four or more turns are preferred for igniters of the present invention. Using the preferred embodiment igniter of the present invention, atomized fuel entering a combustion chamber is reliably ignited as it contacts a hot catalytic wire coil of oxide hardened platinum alloy that has been electrically heated by passage of an electric current. Thermal contact, radiation and conduction, from the wire to the mandrel moderates the effect of high combustion temperatures on the temperature of the catalyst element. The term "thermal contact" as used herein means providing effective heat transfer. Use of a high temperature oxidation resistant catalytic metal, such as an oxide dispersion hardened platinum group metal for the coil wire not only provides catalytic enhancement of ignition but allows for operation even with temperature excursions over 1700 degrees Kelvin, thus providing a wide margin between the coil temperature required for reliable ignition under adverse operating conditions and the maximum safe plug temperature. Even under adverse ignition conditions, the maximum required coil temperature for ignition is no more than about 1400 degrees Kelvin. Platinum group metals include platinum, palladium, iridium, and rhodium as well as alloys thereof.
FIG. 1 shows a side view of an igniter plug of the present invention using the body of the igniter plug as the second electrode.
FIG. 2 shows a side view of an igniter plug of the present invention using a second electrode within the body of the igniter plug.
FIG. 3 shows a partial cross-sectional side view of an embodiment of an igniter element of the invention having an electrical heater/catalyst wire wound on an alpha alumina heat sink mandrel.
Those skilled in the art will gain an appreciation of the invention from reading the following description of preferred embodiments of the invention in conjunction with viewing of the accompanying drawings.
As shown in FIG. 1, igniter plug 2 comprises an igniter element 4 having an electrically resistive heating element coil of catalytic wire 6 wound on mandrel 8 and connected at one end to electrode 10 and the other end to body 7 which is designed to allow installation of the igniter plug into a combustion zone, such as a diesel engine cylinder. Electrode 10 passes through both mandrel 8 and the body 7 and is electrically insulated from body 7.
As shown in FIG. 2, igniter plug 2 comprises an igniter element 4 having an electrically resistive heating element coil of catalytic wire 6 wound on mandrel 8 and connected at one end to electrode 10 and the other end is connected to electrode 11 and a body 7 which is designed to allow installation of the igniter plug into a combustion zone, such as a diesel cylinder. Electrodes 10 passes through both mandrel 8 and the body 7 and is electrically insulated from body 7. Electrode 11 also passes through body 7 and is electrically insulated from both body 7 and electrode 10.
It is important that electrode 10 be selected such that when the igniter plug wire 6 is operating at its desired operating temperature the operating temperature of electrode 10 will be less than the operating temperature of wire 6. The specific temperature difference is based on the design considerations for a particular application. The major elements that a person skilled in the art should consider when selecting the material for and size of electrode 10 are: the temperature at which the electrode material will fail, the temperature delta between the ultimate temperature inside of the mandrel that will be generated by the heat of the electrode versus the wire temperature to assure that center mandrel temperature will be less than the wire temperature, and that less thermal stress on the electrode will increase the service life of the igniter element. The primary design parameter to be used in designing the electrode is electrical resistance. Electrode 10 must have an electrical resistance significantly less than that of wire 6, as must electrode 11.
With reference to FIG. 3, a partial sectional view of an embodiment assembly of the invention as seen from the side, igniter element 4 comprises heat sink mandrel 8 having spiral grooves 15 holding a multi-turn coil of catalytic wire 6. Advantageously, the grooves have a depth of at least about 25 percent of the wire 6 diameter. In preferred embodiments of the invention, the catalytic resistance heating element utilizes an alloy wire preferably having a service temperature in air of at least about 1400 degrees Kelvin, and more preferably 1500 degrees Kelvin, such as an alloy of oxide dispersion hardened platinum metal, which serves as both the catalyst and the electrically resistive heater. The term "service temperature" as used herein is a temperature at which the wire can survive for at least fifty hours. The use of a platinum metal alloy, having a stable electrical resistivity temperature relationship, provides the advantage of allowing feedback control of the element temperature as well as providing a renewable catalyst surface in erosive environments. In addition, since electrical resistance increases with increase in temperature, a platinum wire coil is self regulating in that with a fixed applied voltage the electrical current decreases with increase in wire temperature. This means that plugs can be connected to a fixed voltage supply without use of a temperature controller. A platinum group metal clad tungsten wire offers similar advantages. Less advantageously the catalytic heating coils may also be formed from other oxidation resistant alloys as for example, from Haynes 214 or Fecralloy wire, such as Allegheny Ludlum's Alpha-IV, coated with an ignition catalyst known in the art, such as a platinum metal catalyst.
In the embodiment shown, wire 6, made from oxide hardened platinum, is wound on mandrel 8 which is a ceramic alumina support. Other ceramic materials of high electrical resistivity to prevent short circuiting between coils and good thermal conductivity are also suitable for heat sink mandrel 8. For long-life and durability, the wire 6 is thus itself a catalyst metal that not only offers the advantages of catalytic reactivity, allowing ignition temperatures below 1400 degrees Kelvin, but provides the capability of reliably operating long term at temperatures as high as 1600 degrees Kelvin, which is a temperature well above that required for ignition of even fuels such as methane or methanol. If desired, the temperature of the element may be most readily monitored and controlled by measurement of element electrical resistance.
To provide catalytic igniters of the present invention for evaluation, spark plugs were obtained which could be mounted in place of the standard glow plugs used in the Lister-Petter LPW-S2 two cylinder diesel chosen as the test engine. After removing the side ground electrode of the spark plugs a nickel rod electrode extension was welded to the center electrode of each plug for mounting of an alumina tube of 0.157 inch outer diameter and nominally 0.75 inches long and having spiral grooves about 0.010 inches deep, to serve as the heat sink mandrel. Thirteen turns (coils) of 0.020 inch diameter wire made of oxide dispersion processed 90% platinum-10% rhodium alloy (W. C. Heraeus Gmbh, DPH Pt-10Rh) was then wound in the grooves in the mandrel. Then, one end of the resulting coil was welded to the center nickel electrode and the other welded to the spark plug body in place of the original grounding electrode. In this embodiment, the electrode had a diameter of 0.064 inches with an electrical resistance at the operating temperature of the plug of approximately one percent of the wire. Operated at 5.5 volts in air the igniter plugs reached a temperature of about 1,478 degrees Kelvin. Cold cell testing of the Lister-Petter engine operating with Jet-A fuel showed the igniter plugs would start the engine at lower temperatures than the original equipment manufacturer (O.E.M.) glow plugs specified for the engine. At conditions at which either the O.E.M. glow plugs or the igniter plugs would start the engine, the igniter plugs of the present invention required less than half the electrical power required for the O.E.M. plugs. In the engine, only about 1/8 inch of the plug igniter tip extended into the engine prechamber. No modification of the engine hardware was required to install the igniter plugs. Igniter plugs of the present invention are readily made for any engine. Ungrounded plugs were made using commercially available multiple feed through Conax fittings in place of spark plug fittings to mount igniter coil/mandrel assemblies of the present invention. In this example, the electrical resistance of the electrode at the operation temperature of the igniter plug was approximately 25% of the wire.
To evaluate the durability of igniter plugs of the present invention, after the tests of example I the igniter plugs were placed in another engine and run for over 200 hours and 27 start cycles using automotive diesel fuel. No change in electrical resistance was detected and cold cell testing of the aged igniter plugs showed no degradation in performance. To further evaluate high temperature durability, samples of the DPH platinum wire used in the igniter plugs of the present invention were heated in air to 1,573 degrees Kelvin for 100 hours to evaluate metal loss rate. Weight loss was only 1.7%.
Those skilled in the art will appreciate that many modifications of the preferred embodiment described above can be made without departing from the spirit and scope of the invention.
Claims (26)
1. An igniter element comprising:
a) a heat sink mandrel,
b) an oxidation resistant wire having two ends and a service temperature in excess of approximately 1400 degrees Kelvin wherein coiled around and in thermal contact with said heat sink mandrel, and
c) an electrode having first and second ends, said electrode placed within said mandrel, said electrode having an electrical resistance less than said wire and an end of said wire is connected to an end of said electrode.
2. The igniter plug of claim 1 wherein said electrode has an electrical resistance less than about 25% of said wire.
3. The igniter plug of claim 1 wherein said heat sink mandrel has groves in the surface into which said wire is placed.
4. The igniter plug of claim 1 wherein the surface of said wire comprises an oxidation catalyst.
5. The igniter plug of claim 4 wherein said oxidation catalyst is comprised of a platinum group metal.
6. The igniter plug of claim 5 wherein said wire is comprised of a platinum metal clad tungsten.
7. The igniter plug of claim 4 wherein said wire is comprised of an oxide hardened platinum group metal.
8. The igniter plug of claim 7 wherein said wire is comprised of platinum.
9. The igniter plug of claim 7 wherein said wire is comprised of palladium.
10. The igniter plug of claim 7 wherein said wire is comprised of rhodium.
11. The igniter plug of claim 7 wherein said wire is comprised of iridium.
12. The igniter plug of claim 4 wherein said heat sink mandrel has groves in the surface into which said wire is placed.
13. The ignition plug of claim 1 wherein said mandrel comprises alumina.
14. An igniter plug for the ignition of fuel in admixture with air within a combustion chamber including a body with means for mounting said igniter plug in the combustion chamber wherein said body is capable of providing an electrical ground, and a first electrode which is sealed within said body to prevent the escape of the fuel/air mixture from the combustion chamber wherein said first electrode is electrically insulated from said body, the improvement comprising:
a) a second electrode which is an extension of said first electrode,
b) a heat sink mandrel with grooves in the surface mounted around said second electrode,
c) an oxidation resistant wire having a service temperature in excess of approximately 1400 degrees Kelvin wherein said wire is coiled around and in thermal contact with said heat sink mandrel wherein the first end of said wire is connected to the first end of said second electrode and the second end of said wire is attached to said body.
15. The igniter plug of claim 14 wherein the surface of said wire comprises an oxidation catalyst.
16. The igniter plug of claim 15 wherein the oxidation catalyst comprises a platinum group metal.
17. The igniter plug of claim 16 wherein said wire is comprised of an oxide hardened platinum group metal.
18. The igniter plug of claim 15 wherein said wire is comprised of platinum clad tungsten.
19. An igniter plug for the ignition of fuel in admixture with air within a combustion chamber including a body with means for mounting said igniter plug in the combustion chamber, a first electrode sealed within said body to prevent the escape of the fuel/air mixture from the combustion chamber wherein said first electrode is electrically insulated from said body, and a second electrode sealed within the body to prevent the escape of the fuel/air mixture from the combustion chamber wherein said second electrode is insulated from said first electrode and said body, the improvement comprising:
a) a third electrode which is an extension of said first electrode,
b) a heat sink mandrel with grooves in the surface mounted around said third electrode,
c) an oxidation resistant wire having a service temperature in excess of approximately 1400 degrees Kelvin wherein said wire is coiled around and in thermal contact with said heat sink mandrel wherein the first end of said wire is connected to the first end of said third electrode and the second end of said wire is connected to the first end of said second electrode.
20. The igniter plug claim 19 wherein the surface of said wire comprises an oxidation catalyst.
21. The assembly of claim 20 wherein the oxidation catalyst comprises a platinum group metal.
22. The assembly of claim 21 wherein said wire is comprised of oxide hardened platinum metal.
23. The assembly of claim 20 wherein said wire is comprised of a platinum group metal clad tungsten.
24. A method for combusting low cetane fuels in an internal combustion engine comprising:
a) passing an electrical current through a catalytic metal wire having a service temperature in excess of approximately 1400 degrees Kelvin, said wire coiled around and in thermal contact with a heat sink mandrel;
b) injecting fuel into admixture with air in a combustion chamber; and
c) contacting said fuel with said wire; thereby heating the wire and igniting the fuel.
25. The method of claim 24 wherein said wire is comprised of an oxide hardened platinum group metal.
26. The method of claim 24 wherein said wire is comprised of a platinum group metal clad tungsten.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/897,016 US5791308A (en) | 1997-07-18 | 1997-07-18 | Plug assembly |
| CA002296474A CA2296474A1 (en) | 1997-07-18 | 1998-06-12 | Plug assembly |
| AU81424/98A AU741008B2 (en) | 1997-07-18 | 1998-06-12 | Plug assembly |
| PCT/US1998/012302 WO1999004199A1 (en) | 1997-07-18 | 1998-06-12 | Plug assembly |
| EP98931258A EP0996842A4 (en) | 1997-07-18 | 1998-06-12 | Plug assembly |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/897,016 US5791308A (en) | 1997-07-18 | 1997-07-18 | Plug assembly |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US5791308A true US5791308A (en) | 1998-08-11 |
Family
ID=25407227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US08/897,016 Expired - Fee Related US5791308A (en) | 1997-07-18 | 1997-07-18 | Plug assembly |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5791308A (en) |
| EP (1) | EP0996842A4 (en) |
| AU (1) | AU741008B2 (en) |
| CA (1) | CA2296474A1 (en) |
| WO (1) | WO1999004199A1 (en) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000079185A1 (en) * | 1999-06-18 | 2000-12-28 | Daimlerchrysler Ag | Electrically heatable glow plug or glow rod for combustion engines |
| US6684632B2 (en) * | 2000-08-09 | 2004-02-03 | Dr. Ing. H.C.F. Porsche Ag | Arrangement and method for igniting a combustible gas mixture for the exhaust system of an internal-combustion engine and corresponding exhaust system |
| US20050274107A1 (en) * | 2004-06-14 | 2005-12-15 | Ke Liu | Reforming unvaporized, atomized hydrocarbon fuel |
| USD561790S1 (en) * | 2007-05-04 | 2008-02-12 | Greenleaf Richard J | Washer punch insert plug |
| US20100290766A1 (en) * | 2008-01-29 | 2010-11-18 | Shunji Mochizuki | Immersion heater |
| US20110000797A1 (en) * | 2009-07-06 | 2011-01-06 | Ada Technologies, Inc. | Electrochemical device and method for long-term measurement of hypohalites |
| US20120032689A1 (en) * | 2008-09-29 | 2012-02-09 | Phillips Richard W | Blade tip clearance measurement sensor for gas turbine engines |
| CN104508380A (en) * | 2012-08-09 | 2015-04-08 | 博世株式会社 | Pressure sensor type glow plug |
| JP2015180602A (en) * | 2011-07-07 | 2015-10-15 | エレメント・ワン・コーポレーション | Hydrogen generating assembly and hydrogen purification device |
| US20150337793A1 (en) * | 2013-02-11 | 2015-11-26 | Contour Hardening, Inc. | Combustion ignition system |
| US20150359565A1 (en) * | 2013-08-22 | 2015-12-17 | Olympus Corporation | Trocar |
| US9616389B2 (en) | 2012-08-30 | 2017-04-11 | Element 1 Corp. | Hydrogen generation assemblies and hydrogen purification devices |
| US9914641B2 (en) | 2012-08-30 | 2018-03-13 | Element 1 Corp. | Hydrogen generation assemblies |
| US10717040B2 (en) | 2012-08-30 | 2020-07-21 | Element 1 Corp. | Hydrogen purification devices |
| US11428181B2 (en) * | 2020-03-25 | 2022-08-30 | Cummins Inc. | Systems and methods for ultra-low NOx cold start warmup control and fault diagnosis |
| US11738305B2 (en) | 2012-08-30 | 2023-08-29 | Element 1 Corp | Hydrogen purification devices |
| US12187612B2 (en) | 2021-06-15 | 2025-01-07 | Element 1 Corp | Hydrogen generation assemblies |
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- 1998-06-12 AU AU81424/98A patent/AU741008B2/en not_active Ceased
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- 1998-06-12 EP EP98931258A patent/EP0996842A4/en not_active Withdrawn
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| US4437440A (en) * | 1979-06-20 | 1984-03-20 | Ngk Spark Plug Co., Ltd. | Auxiliary combustion chamber preheating device |
| US4426568A (en) * | 1981-05-21 | 1984-01-17 | Nippondenso Co., Ltd. | Glow plug for diesel engines |
| US4896636A (en) * | 1989-02-17 | 1990-01-30 | Pfefferle William C | Method of operating I. C. engines and apparatus thereof |
| US5580476A (en) * | 1995-06-21 | 1996-12-03 | Caterpillar Inc. | Combination catalyst wire wrapped a glow plug |
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Cited By (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000079185A1 (en) * | 1999-06-18 | 2000-12-28 | Daimlerchrysler Ag | Electrically heatable glow plug or glow rod for combustion engines |
| US6684632B2 (en) * | 2000-08-09 | 2004-02-03 | Dr. Ing. H.C.F. Porsche Ag | Arrangement and method for igniting a combustible gas mixture for the exhaust system of an internal-combustion engine and corresponding exhaust system |
| US20050274107A1 (en) * | 2004-06-14 | 2005-12-15 | Ke Liu | Reforming unvaporized, atomized hydrocarbon fuel |
| USD561790S1 (en) * | 2007-05-04 | 2008-02-12 | Greenleaf Richard J | Washer punch insert plug |
| US20100290766A1 (en) * | 2008-01-29 | 2010-11-18 | Shunji Mochizuki | Immersion heater |
| US8422871B2 (en) * | 2008-01-29 | 2013-04-16 | Tounetsu Corporation | Immersion heater |
| US20120032689A1 (en) * | 2008-09-29 | 2012-02-09 | Phillips Richard W | Blade tip clearance measurement sensor for gas turbine engines |
| US8773115B2 (en) * | 2008-09-29 | 2014-07-08 | Rosemount Aerospace Inc. | Blade tip clearance measurement sensor for gas turbine engines |
| US20110000797A1 (en) * | 2009-07-06 | 2011-01-06 | Ada Technologies, Inc. | Electrochemical device and method for long-term measurement of hypohalites |
| US8329024B2 (en) * | 2009-07-06 | 2012-12-11 | Ada Technologies, Inc. | Electrochemical device and method for long-term measurement of hypohalites |
| US9656215B2 (en) | 2011-07-07 | 2017-05-23 | Element 1 Corp. | Hydrogen generation assemblies and hydrogen purification devices |
| JP2015180602A (en) * | 2011-07-07 | 2015-10-15 | エレメント・ワン・コーポレーション | Hydrogen generating assembly and hydrogen purification device |
| US11701624B2 (en) * | 2011-07-07 | 2023-07-18 | Element 1 Corp | Hydrogen generation assemblies and hydrogen purification devices |
| US20220314175A1 (en) * | 2011-07-07 | 2022-10-06 | Element 1 Corp. | Hydrogen generation assemblies and hydrogen purification devices |
| US11364473B2 (en) * | 2011-07-07 | 2022-06-21 | Element 1 Corp | Hydrogen generation assemblies and hydrogen purification devices |
| US10391458B2 (en) | 2011-07-07 | 2019-08-27 | Element 1 Corp. | Hydrogen generation assemblies and hydrogen purification devices |
| CN104508380A (en) * | 2012-08-09 | 2015-04-08 | 博世株式会社 | Pressure sensor type glow plug |
| CN104508380B (en) * | 2012-08-09 | 2016-04-27 | 博世株式会社 | Integrated pressure sensors formula glowing plug |
| US11738305B2 (en) | 2012-08-30 | 2023-08-29 | Element 1 Corp | Hydrogen purification devices |
| US9914641B2 (en) | 2012-08-30 | 2018-03-13 | Element 1 Corp. | Hydrogen generation assemblies |
| US10702827B2 (en) | 2012-08-30 | 2020-07-07 | Element 1 Corp. | Hydrogen generation assemblies and hydrogen purification devices |
| US10710022B2 (en) | 2012-08-30 | 2020-07-14 | Element 1 Corp. | Hydrogen generation assemblies |
| US10717040B2 (en) | 2012-08-30 | 2020-07-21 | Element 1 Corp. | Hydrogen purification devices |
| US11141692B2 (en) | 2012-08-30 | 2021-10-12 | Element 1 Corp | Hydrogen generation assemblies and hydrogen purification devices |
| US9616389B2 (en) | 2012-08-30 | 2017-04-11 | Element 1 Corp. | Hydrogen generation assemblies and hydrogen purification devices |
| US12138586B2 (en) | 2012-08-30 | 2024-11-12 | Element 1 Corp | Hydrogen purification devices |
| US10166506B2 (en) | 2012-08-30 | 2019-01-01 | Element 1 Corp. | Hydrogen generation assemblies and hydrogen purification devices |
| US11590449B2 (en) | 2012-08-30 | 2023-02-28 | Element 1 Corp | Hydrogen purification devices |
| US20150337793A1 (en) * | 2013-02-11 | 2015-11-26 | Contour Hardening, Inc. | Combustion ignition system |
| US20150359565A1 (en) * | 2013-08-22 | 2015-12-17 | Olympus Corporation | Trocar |
| US11428181B2 (en) * | 2020-03-25 | 2022-08-30 | Cummins Inc. | Systems and methods for ultra-low NOx cold start warmup control and fault diagnosis |
| US11905904B2 (en) | 2020-03-25 | 2024-02-20 | Cummins Inc. | Systems and methods for ultra-low NOx cold start warmup control and fault diagnosis |
| US12187612B2 (en) | 2021-06-15 | 2025-01-07 | Element 1 Corp | Hydrogen generation assemblies |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0996842A4 (en) | 2001-09-26 |
| AU8142498A (en) | 1999-02-10 |
| WO1999004199A1 (en) | 1999-01-28 |
| AU741008B2 (en) | 2001-11-22 |
| CA2296474A1 (en) | 1999-01-28 |
| EP0996842A1 (en) | 2000-05-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: PRECISION COMBUSTION, INC., CONNECTICUT Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:CARTER, ROBERT NASH;JACKSON, GREGORY SCOTT;PFEFFERLE, WILLIAM C.;REEL/FRAME:009072/0671;SIGNING DATES FROM 19980310 TO 19980311 |
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| FEPP | Fee payment procedure |
Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: SMALL ENTITY |
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| REMI | Maintenance fee reminder mailed | ||
| LAPS | Lapse for failure to pay maintenance fees | ||
| STCH | Information on status: patent discontinuation |
Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362 |
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| FP | Lapsed due to failure to pay maintenance fee |
Effective date: 20020811 |