US5780081A - Fortification of food with calcium and process of making - Google Patents
Fortification of food with calcium and process of making Download PDFInfo
- Publication number
- US5780081A US5780081A US08/739,070 US73907096A US5780081A US 5780081 A US5780081 A US 5780081A US 73907096 A US73907096 A US 73907096A US 5780081 A US5780081 A US 5780081A
- Authority
- US
- United States
- Prior art keywords
- foodstuff
- calcium
- complex
- fortified
- hydrolysed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 239000011575 calcium Substances 0.000 title claims abstract description 22
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims description 8
- 235000013305 food Nutrition 0.000 title description 4
- 235000013365 dairy product Nutrition 0.000 claims abstract description 4
- 239000001814 pectin Substances 0.000 claims description 13
- 235000010987 pectin Nutrition 0.000 claims description 13
- 229920001277 pectin Polymers 0.000 claims description 13
- 239000000725 suspension Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 6
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 235000013361 beverage Nutrition 0.000 claims description 2
- 235000009508 confectionery Nutrition 0.000 claims description 2
- 235000015243 ice cream Nutrition 0.000 claims description 2
- 230000000087 stabilizing effect Effects 0.000 claims 2
- 159000000007 calcium salts Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 150000004676 glycans Chemical class 0.000 abstract description 11
- 229920001282 polysaccharide Polymers 0.000 abstract description 11
- 239000005017 polysaccharide Substances 0.000 abstract description 11
- 235000013336 milk Nutrition 0.000 abstract description 8
- 239000008267 milk Substances 0.000 abstract description 8
- 210000004080 milk Anatomy 0.000 abstract description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 7
- 239000000243 solution Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000015271 coagulation Effects 0.000 description 4
- 238000005345 coagulation Methods 0.000 description 4
- 238000004062 sedimentation Methods 0.000 description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000007900 aqueous suspension Substances 0.000 description 3
- 239000001110 calcium chloride Substances 0.000 description 3
- 229910001628 calcium chloride Inorganic materials 0.000 description 3
- 235000010418 carrageenan Nutrition 0.000 description 3
- 229920001525 carrageenan Polymers 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 235000020124 milk-based beverage Nutrition 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- -1 organic acid salts Chemical class 0.000 description 3
- 239000013049 sediment Substances 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 102000014171 Milk Proteins Human genes 0.000 description 2
- 108010011756 Milk Proteins Proteins 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- 229940043430 calcium compound Drugs 0.000 description 2
- 150000001674 calcium compounds Chemical class 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 235000021239 milk protein Nutrition 0.000 description 2
- 235000019629 palatability Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 235000020183 skimmed milk Nutrition 0.000 description 2
- HFVMEOPYDLEHBR-UHFFFAOYSA-N (2-fluorophenyl)-phenylmethanol Chemical compound C=1C=CC=C(F)C=1C(O)C1=CC=CC=C1 HFVMEOPYDLEHBR-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- QISOBCMNUJQOJU-UHFFFAOYSA-N 4-bromo-1h-pyrazole-5-carboxylic acid Chemical compound OC(=O)C=1NN=CC=1Br QISOBCMNUJQOJU-UHFFFAOYSA-N 0.000 description 1
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Natural products OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- VJHCJDRQFCCTHL-UHFFFAOYSA-N acetic acid 2,3,4,5,6-pentahydroxyhexanal Chemical compound CC(O)=O.OCC(O)C(O)C(O)C(O)C=O VJHCJDRQFCCTHL-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000023555 blood coagulation Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 1
- 239000001354 calcium citrate Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 230000003915 cell function Effects 0.000 description 1
- 230000007073 chemical hydrolysis Effects 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 230000007071 enzymatic hydrolysis Effects 0.000 description 1
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 description 1
- 235000020189 fortified milk Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000006486 human diet Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 230000007102 metabolic function Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004118 muscle contraction Effects 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- YZNWXXJZEDHRKB-UHFFFAOYSA-N octadecyl 2-hydroxypropanoate;sodium Chemical compound [Na].CCCCCCCCCCCCCCCCCCOC(=O)C(C)O YZNWXXJZEDHRKB-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000011164 ossification Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical class [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 235000013337 tricalcium citrate Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/152—Milk preparations; Milk powder or milk powder preparations containing additives
- A23C9/154—Milk preparations; Milk powder or milk powder preparations containing additives containing thickening substances, eggs or cereal preparations; Milk gels
- A23C9/1544—Non-acidified gels, e.g. custards, creams, desserts, puddings, shakes or foams, containing eggs or thickening or gelling agents other than sugar; Milk products containing natural or microbial polysaccharides, e.g. cellulose or cellulose derivatives; Milk products containing nutrient fibres
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/152—Milk preparations; Milk powder or milk powder preparations containing additives
- A23C9/1522—Inorganic additives, e.g. minerals, trace elements; Chlorination or fluoridation of milk; Organic salts or complexes of metals other than natrium or kalium; Calcium enrichment of milk
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/152—Milk preparations; Milk powder or milk powder preparations containing additives
- A23C9/154—Milk preparations; Milk powder or milk powder preparations containing additives containing thickening substances, eggs or cereal preparations; Milk gels
- A23C9/1542—Acidified milk products containing thickening agents or acidified milk gels, e.g. acidified by fruit juices
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/231—Pectin; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
- A23L33/16—Inorganic salts, minerals or trace elements
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
- A23L33/16—Inorganic salts, minerals or trace elements
- A23L33/165—Complexes or chelates
Definitions
- the present invention relates to the fortification of food and more particularly to the fortification of food with calcium.
- Calcium is an important element in human diets for adequate bone formation and maintenance as well as other metabolic functions, e.g. nerve transmission, blood clotting, proper cell function and muscle contraction. It is common practice to fortify food products with calcium sources which are either insoluble or soluble at around neutral pH. Many of the calcium sources currently used for fortification are insoluble or substantially insoluble at around neutral pH, e.g. calcium carbonate, calcium phosphates, calcium citrate and other organic acid salts of calcium. These materials result in precipitation and a chalky mouth feel. Other calcium sources are soluble or substantially soluble at around neutral pH such as calcium chloride, calcium hydroxide and a few organic acid salts of calcium, but these with milk proteins resulting in undesirable coagulation and sedimentation.
- a fortified foodstuff comprising a fortifying amount of a complex of calcium and a hydrolysed polysaccharide.
- the foodstuff may be a dairy based product such as a milk beverage, a confectionery product, ice cream or another beverage such as a juice.
- the complex may be calcium and a hydrolysed polysaccharide alone or together with an acid.
- the hydrolysed polysaccharide may be derived from any negatively charged polysaccharide , e.g. carboxymethylcellulose, gums or carrageenans but it is advantageously a hydrolysed pectin.
- Pectins typically have a molecular weight of about 10,000 to 150,000 with a Degree of Polymerisation (DP) of about 50 to 800 and are methoxylated from about 20 to 80%. Although pectins may theoretically be hydrolysed to a DP of 1 and demethoxylated to 0%, these levels are difficult to achieve.
- the hydrolysed pectin has an average DP of from about 1 to 25 and more preferably from 1 to 10.
- the hydrolysed pectin is conveniently demethoxylated to more than 50% and preferably more than 75%.
- the hydrolysis (and the demethoxylation when the polysaccharide is pectin) may be carried out by chemical, physical or enzymatic means or any combination thereof.
- the enzymatic hydrolysis may be carried out, for instance, by a process as described in our co-pending U.S. patent application Ser. No. 08/697,222 filed Aug. 21, 1996.
- the chemical hydrolysis may be carried out by treatment with an acid but is preferably carried out by treatment with an alkali.
- the physical hydrolysis may be carried out by shear. As these treatments are already generally known or disclosed in the art, there is no need to further describe them herein.
- the complex of calcium and the hydrolysed polysaccharide may be prepared by mixing an aqueous solution or suspension of a calcium compound with an aqueous solution or suspension of a hydrolysed polysaccharide.
- the calcium compound may be calcium hydroxide or it may be derived from one or more of several salts, e.g. the chloride, carbonate, phosphate, sulfate or citrate.
- the acid is preferably an organic acid, e.g. citric, malic, fumaric, tartaric, succinic or lactic acid.
- One or more acids may be used if desired.
- the complex is formed as an aqueous solution or suspension and, if desired, may be dried, for instance to a powder, by various methods commonly known to those skilled in the art.
- the fortified foodstuff comprising a fortifying amount of a complex of calcium and a hydrolysed polysaccharide may be prepared by mixing the foodstuff with the complex.
- the complex may be in the form of a solution or suspension or it may be in a dry form such as a powder.
- the amount of complex present in the fortified foodstuff may be from about 0.05 to 5%, preferably from 0.1 to 2.5%, and more preferably from 0.2 to 1% by weight based on the weight of the foodstuff.
- the foodstuff may subsequently be further stabilised by adding gums, e.g. carrageenans, gum arabic, guar gum, etc., or by adding emulsifiers, e.g. mono- or di-glycerides, lecithin, sodium stearyl lactate, or the citric acid ester of monoglyceride.
- gums e.g. carrageenans, gum arabic, guar gum, etc.
- emulsifiers e.g. mono- or di-glycerides, lecithin, sodium stearyl lactate, or the citric acid ester of monoglyceride.
- the fortified foodstuff may be frozen, refrigerated or shelf-stable.
- the solutions/suspensions are mixed and then added to 940 mL skim milk.
- the milk is then homogenised and pasteurised, and stored in a refrigerator at 2°-5° C.
- the milk was found to be stable, without sediment and of good flavor after 7 weeks.
- pectin hydrolysates consisting of approximately 77% DP 1-3 (the remainder being primarily insoluble matter and moisture) in 40 mL water.
- solutions/suspensions A and B are mixed, then solution C is added.
- the final mixture is then added to 940 mL skim milk.
- the milk is then homogenised and pasteurised, and stored in a refrigerator at 2°-5° C. The milk was found to be stable, without sediment and of good flavor after 7 weeks.
- Example 2 Fortified milk is prepared as in Example 2 except that instead of being pasteurised, it is ultra high temperature treated (UHT). After being stored in a refrigerator at 2°-5° C. for three weeks, the milk was found to be stable, without sediment and of good flavor.
- UHT ultra high temperature treated
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Food Science & Technology (AREA)
- Nutrition Science (AREA)
- Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Mycology (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Dairy Products (AREA)
- Jellies, Jams, And Syrups (AREA)
- Confectionery (AREA)
Abstract
Description
Claims (12)
Priority Applications (20)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/739,070 US5780081A (en) | 1996-10-28 | 1996-10-28 | Fortification of food with calcium and process of making |
ZA978476A ZA978476B (en) | 1996-10-28 | 1997-09-19 | Fortification of food |
CN97191497A CN1072910C (en) | 1996-10-28 | 1997-09-22 | Fortification of food with complex of calcium |
AT97910328T ATE260050T1 (en) | 1996-10-28 | 1997-09-22 | REINFORCEMENT OF FOODS WITH A CALCIUM COMPLEX |
TR1998/01209T TR199801209T1 (en) | 1996-10-28 | 1997-09-22 | A calcium complex to support wheat. |
EP97910328A EP0889696B1 (en) | 1996-10-28 | 1997-09-22 | Fortification of food with a complex of calcium |
JP10519965A JP2000504229A (en) | 1996-10-28 | 1997-09-22 | Food fortification with calcium complex |
KR10-1998-0704958A KR100494868B1 (en) | 1996-10-28 | 1997-09-22 | Fortification of food with a complex of calcium |
PCT/EP1997/005192 WO1998018349A1 (en) | 1996-10-28 | 1997-09-22 | Fortification of food with a complex of calcium |
RU98114095/13A RU2191515C2 (en) | 1996-10-28 | 1997-09-22 | Product enriched with calcium on base of skimmed milk and method of its preparation |
DE69727794T DE69727794T2 (en) | 1996-10-28 | 1997-09-22 | Reinforcing foods with a calcium complex |
BR9706900-0A BR9706900A (en) | 1996-10-28 | 1997-09-22 | Fortification of food with a calcium complex. |
NZ330706A NZ330706A (en) | 1996-10-28 | 1997-09-22 | A fortified dairy based foodstuff (e.g. milk or a milk product) comprising a fortifying amount of calcium and a hydrolysed polysaccharide |
AU47768/97A AU731661B2 (en) | 1996-10-28 | 1997-09-22 | Fortification of food with a complex of calcium |
CA002239774A CA2239774C (en) | 1996-10-28 | 1997-09-22 | Fortification of food with a complex of calcium |
ARP970104998A AR008509A1 (en) | 1996-10-28 | 1997-10-28 | A FORTIFIED FOOD PRODUCT AND THE PROCESS TO PREPARE IT |
US09/070,628 US6063411A (en) | 1996-10-28 | 1998-04-30 | Calcium fortified foodstuff and method of preparing same |
NO982934A NO982934D0 (en) | 1996-10-28 | 1998-06-24 | Strengthening foods with a complex of calcium |
MX9805161A MX9805161A (en) | 1996-10-28 | 1998-06-25 | Fortification of food with a complex of calcium. |
US09/559,591 US6342257B1 (en) | 1996-10-28 | 2000-04-28 | Calcium fortified foodstuff |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/739,070 US5780081A (en) | 1996-10-28 | 1996-10-28 | Fortification of food with calcium and process of making |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/070,628 Continuation-In-Part US6063411A (en) | 1996-10-28 | 1998-04-30 | Calcium fortified foodstuff and method of preparing same |
Publications (1)
Publication Number | Publication Date |
---|---|
US5780081A true US5780081A (en) | 1998-07-14 |
Family
ID=24970675
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US08/739,070 Expired - Fee Related US5780081A (en) | 1996-10-28 | 1996-10-28 | Fortification of food with calcium and process of making |
US09/070,628 Expired - Fee Related US6063411A (en) | 1996-10-28 | 1998-04-30 | Calcium fortified foodstuff and method of preparing same |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/070,628 Expired - Fee Related US6063411A (en) | 1996-10-28 | 1998-04-30 | Calcium fortified foodstuff and method of preparing same |
Country Status (18)
Country | Link |
---|---|
US (2) | US5780081A (en) |
EP (1) | EP0889696B1 (en) |
JP (1) | JP2000504229A (en) |
KR (1) | KR100494868B1 (en) |
CN (1) | CN1072910C (en) |
AR (1) | AR008509A1 (en) |
AT (1) | ATE260050T1 (en) |
AU (1) | AU731661B2 (en) |
BR (1) | BR9706900A (en) |
CA (1) | CA2239774C (en) |
DE (1) | DE69727794T2 (en) |
MX (1) | MX9805161A (en) |
NO (1) | NO982934D0 (en) |
NZ (1) | NZ330706A (en) |
RU (1) | RU2191515C2 (en) |
TR (1) | TR199801209T1 (en) |
WO (1) | WO1998018349A1 (en) |
ZA (1) | ZA978476B (en) |
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US6063411A (en) * | 1996-10-28 | 2000-05-16 | Nestec S.A. | Calcium fortified foodstuff and method of preparing same |
US6342257B1 (en) | 1996-10-28 | 2002-01-29 | Nestec S.A. | Calcium fortified foodstuff |
US6428837B1 (en) * | 2000-06-09 | 2002-08-06 | Cp Kelco Aps | Deesterified pectins, processes for producing such pectins, and stabilized acidic liquid systems comprising the same |
US20030003192A1 (en) * | 1998-09-29 | 2003-01-02 | The Procter & Gamble Company | Calcium fortified beverages |
US6565898B2 (en) | 2001-05-03 | 2003-05-20 | Tropicana Products, Inc. | Reduction of heartburn episodes after ingestion of orange juice |
US20040013786A1 (en) * | 2001-05-03 | 2004-01-22 | Mcardle Richard N. | Orange juice of low citrus oil content for reduction of heartburn episodes |
US6682767B2 (en) | 2001-05-03 | 2004-01-27 | Tropicana Products, Inc. | Reduction of heartburn episodes upon ingestion of orange juice |
US20040071789A1 (en) * | 2002-02-14 | 2004-04-15 | Baron John A | Calcium supplementation to reduce prostate cancer risk |
US20060094688A1 (en) * | 2002-09-20 | 2006-05-04 | Inc Admin Agcy Natl Agric & Bio-Oriented Res Org | Histamine release inhibitor |
US20070026110A1 (en) * | 2003-02-28 | 2007-02-01 | Kraft Foods Holdings, Inc. | Mineral Complexes of Lactobionic Acid and Method of Using for Mineral Fortification of Food Products |
US20080014304A1 (en) * | 2004-02-18 | 2008-01-17 | Kraft Foods Holdings, Inc. | Amorphous Water-Soluble Calcium Citrate Salts and Method of Making and Using Same |
US7371402B2 (en) | 1998-08-14 | 2008-05-13 | Danisco A/S | Use of a composition |
US20080125346A1 (en) * | 2004-08-20 | 2008-05-29 | N.V. Nutrica | Infant Formula |
US20090053389A1 (en) * | 2007-08-23 | 2009-02-26 | Novartis Ag | Dietary Suppliment fiber composition with calcium and chelating agent |
US20100261669A1 (en) * | 2007-11-02 | 2010-10-14 | N.V. Nutricia | Unit dosage for brain health |
US8697158B2 (en) | 2008-07-09 | 2014-04-15 | Melaleuca, Inc. | Mineral amino acid polysaccharide complex |
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US20210137147A1 (en) * | 2018-07-19 | 2021-05-13 | Csm Bakery Solutions Europe Holding B.V. | Calcium concentrate |
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- 1997-09-19 ZA ZA978476A patent/ZA978476B/en unknown
- 1997-09-22 BR BR9706900-0A patent/BR9706900A/en not_active Application Discontinuation
- 1997-09-22 JP JP10519965A patent/JP2000504229A/en not_active Abandoned
- 1997-09-22 KR KR10-1998-0704958A patent/KR100494868B1/en not_active IP Right Cessation
- 1997-09-22 TR TR1998/01209T patent/TR199801209T1/en unknown
- 1997-09-22 NZ NZ330706A patent/NZ330706A/en unknown
- 1997-09-22 CA CA002239774A patent/CA2239774C/en not_active Expired - Fee Related
- 1997-09-22 CN CN97191497A patent/CN1072910C/en not_active Expired - Fee Related
- 1997-09-22 RU RU98114095/13A patent/RU2191515C2/en not_active IP Right Cessation
- 1997-09-22 AT AT97910328T patent/ATE260050T1/en not_active IP Right Cessation
- 1997-09-22 DE DE69727794T patent/DE69727794T2/en not_active Expired - Fee Related
- 1997-09-22 AU AU47768/97A patent/AU731661B2/en not_active Ceased
- 1997-09-22 EP EP97910328A patent/EP0889696B1/en not_active Expired - Lifetime
- 1997-09-22 WO PCT/EP1997/005192 patent/WO1998018349A1/en active IP Right Grant
- 1997-10-28 AR ARP970104998A patent/AR008509A1/en unknown
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1998
- 1998-04-30 US US09/070,628 patent/US6063411A/en not_active Expired - Fee Related
- 1998-06-24 NO NO982934A patent/NO982934D0/en unknown
- 1998-06-25 MX MX9805161A patent/MX9805161A/en not_active IP Right Cessation
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JPH0436166A (en) * | 1990-05-31 | 1992-02-06 | Pola Chem Ind Inc | Food raw material for improving property of skin |
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JPH0856567A (en) * | 1994-08-26 | 1996-03-05 | Calpis Food Ind Co Ltd:The | Calcium-reinforced milky acidic condensed drink and its manufacturing |
Cited By (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6342257B1 (en) | 1996-10-28 | 2002-01-29 | Nestec S.A. | Calcium fortified foodstuff |
US6063411A (en) * | 1996-10-28 | 2000-05-16 | Nestec S.A. | Calcium fortified foodstuff and method of preparing same |
US7371402B2 (en) | 1998-08-14 | 2008-05-13 | Danisco A/S | Use of a composition |
US6811800B2 (en) | 1998-09-29 | 2004-11-02 | The Procter & Gamble Co. | Calcium fortified beverages |
US20030003192A1 (en) * | 1998-09-29 | 2003-01-02 | The Procter & Gamble Company | Calcium fortified beverages |
US20050025861A1 (en) * | 1998-09-29 | 2005-02-03 | The Procter & Gamble Company | Calcium fortified beverages |
US6994877B2 (en) | 1998-09-29 | 2006-02-07 | The Procter + Gamble Co. | Calcium fortified beverages |
US6428837B1 (en) * | 2000-06-09 | 2002-08-06 | Cp Kelco Aps | Deesterified pectins, processes for producing such pectins, and stabilized acidic liquid systems comprising the same |
US20080113041A1 (en) * | 2001-02-16 | 2008-05-15 | Trustees Of Dartmouth College | Calcium supplementation to reduce prostate cancer risk |
US6565898B2 (en) | 2001-05-03 | 2003-05-20 | Tropicana Products, Inc. | Reduction of heartburn episodes after ingestion of orange juice |
US20040013786A1 (en) * | 2001-05-03 | 2004-01-22 | Mcardle Richard N. | Orange juice of low citrus oil content for reduction of heartburn episodes |
US6682767B2 (en) | 2001-05-03 | 2004-01-27 | Tropicana Products, Inc. | Reduction of heartburn episodes upon ingestion of orange juice |
US6761915B1 (en) | 2001-05-03 | 2004-07-13 | Tropicana Products, Inc. | Reduction of heartburn episodes after ingestion of orange juice |
US20040071789A1 (en) * | 2002-02-14 | 2004-04-15 | Baron John A | Calcium supplementation to reduce prostate cancer risk |
US20060094688A1 (en) * | 2002-09-20 | 2006-05-04 | Inc Admin Agcy Natl Agric & Bio-Oriented Res Org | Histamine release inhibitor |
US20070026110A1 (en) * | 2003-02-28 | 2007-02-01 | Kraft Foods Holdings, Inc. | Mineral Complexes of Lactobionic Acid and Method of Using for Mineral Fortification of Food Products |
US7781002B2 (en) | 2003-02-28 | 2010-08-24 | Kraft Foods Global Brands Llc | Mineral complexes of lactobionic acid and method of using for mineral fortification of food products |
US20080014304A1 (en) * | 2004-02-18 | 2008-01-17 | Kraft Foods Holdings, Inc. | Amorphous Water-Soluble Calcium Citrate Salts and Method of Making and Using Same |
US7713559B2 (en) | 2004-02-18 | 2010-05-11 | Kraft Foods Global Brands Llc | Amorphous water-soluble calcium citrate salts and method of making and using same |
US20080125346A1 (en) * | 2004-08-20 | 2008-05-29 | N.V. Nutrica | Infant Formula |
US20090053389A1 (en) * | 2007-08-23 | 2009-02-26 | Novartis Ag | Dietary Suppliment fiber composition with calcium and chelating agent |
US20100261669A1 (en) * | 2007-11-02 | 2010-10-14 | N.V. Nutricia | Unit dosage for brain health |
US8283336B2 (en) | 2007-11-02 | 2012-10-09 | N. V. Nutricia | Unit dosage for brain health |
US8697158B2 (en) | 2008-07-09 | 2014-04-15 | Melaleuca, Inc. | Mineral amino acid polysaccharide complex |
US20210137147A1 (en) * | 2018-07-19 | 2021-05-13 | Csm Bakery Solutions Europe Holding B.V. | Calcium concentrate |
US12082600B2 (en) * | 2018-07-19 | 2024-09-10 | Csm Bakery Solutions Europe Holding B.V. | Calcium concentrate suspension for calcium fortification of food and drinks |
CN112544772A (en) * | 2020-12-08 | 2021-03-26 | 光明乳业股份有限公司 | Raw material composition of calcium-fortified frozen beverage, calcium-fortified frozen beverage and preparation method of calcium-fortified frozen beverage |
Also Published As
Publication number | Publication date |
---|---|
KR19990076831A (en) | 1999-10-25 |
JP2000504229A (en) | 2000-04-11 |
US6063411A (en) | 2000-05-16 |
BR9706900A (en) | 1999-08-31 |
AU4776897A (en) | 1998-05-22 |
CN1072910C (en) | 2001-10-17 |
EP0889696A1 (en) | 1999-01-13 |
CA2239774C (en) | 2003-12-23 |
NO982934D0 (en) | 1998-06-24 |
AU731661B2 (en) | 2001-04-05 |
ATE260050T1 (en) | 2004-03-15 |
DE69727794T2 (en) | 2004-08-05 |
AR008509A1 (en) | 2000-01-19 |
DE69727794D1 (en) | 2004-04-01 |
MX9805161A (en) | 1998-10-31 |
TR199801209T1 (en) | 1998-12-21 |
EP0889696B1 (en) | 2004-02-25 |
NZ330706A (en) | 1999-08-30 |
CN1206334A (en) | 1999-01-27 |
CA2239774A1 (en) | 1998-05-07 |
RU2191515C2 (en) | 2002-10-27 |
KR100494868B1 (en) | 2005-09-09 |
WO1998018349A1 (en) | 1998-05-07 |
ZA978476B (en) | 1999-03-19 |
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