US5233054A - Process for the preparation of halophthalic anhydrides - Google Patents
Process for the preparation of halophthalic anhydrides Download PDFInfo
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- US5233054A US5233054A US07/721,004 US72100491A US5233054A US 5233054 A US5233054 A US 5233054A US 72100491 A US72100491 A US 72100491A US 5233054 A US5233054 A US 5233054A
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/54—Preparation of carboxylic acid anhydrides
- C07C51/567—Preparation of carboxylic acid anhydrides by reactions not involving carboxylic acid anhydride groups
Definitions
- This invention relates to a process for the preparation of halophthalic anhydrides by dehydrogenation of halogen substituted saturated or partially saturated phthalo compounds, such as halogen, substituted tetrahydro or hexahydro phthalic anhydrides.
- halophthalic anhydrides are useful chemical intermediates for the synthesis of various commercial products, including polymers, dyes and plasticizers.
- halophthalic anhydrides are particularly useful as intermediates for the preparation of dianhydride monomers, such as oxydiphthalic anhydride which may be co-polymerized with a suitable diamine to form a condensation polyimide.
- dianhydride monomers such as oxydiphthalic anhydride which may be co-polymerized with a suitable diamine to form a condensation polyimide.
- the preparation of dianhydride monomers for the high performance polymer industry requires halophthalic anhydrides of very high purity, since the presence of even what normally would be considered as minor amounts of impurities would degrade the polymer product and perhaps render the product unsuitable for certain uses.
- Halophthalic anhydrides may be prepared by the reaction of bromine with halo-substituted saturated or partially saturated phthalic anhydrides, such as halotetrahydrophthalic anhydride or gem-dihalohexahydrophthalic anhydride, at temperatures in excess of 200° Celsius.
- halo-substituted saturated or partially saturated phthalic anhydrides such as halotetrahydrophthalic anhydride or gem-dihalohexahydrophthalic anhydride
- U.S. Pat. No. 4,560,772 to Telschow discloses the reaction of 4-methyltetrahydrophthalic anhydride with excess sulfur and a catalytic amount of zinc oxide and 2-mercaptobenzothiazole to produce 4-methylphthalic anhydride and hydrogen sulfide.
- U.S. Pat. No. 4,560,773 and 4,559,405 to Telschow disclose the preparation of substituted phthalic anhydrides by reaction of bromine with an alkyl or aryl-substituted tetrahydrophthalic anhydride, especially 4-methyltetrahydrophthalic anhydride, in the presence of an acid acceptor, such as pyridine or dimethylformamide.
- an acid acceptor such as pyridine or dimethylformamide.
- U.S. Pat. No. 4,560,773 discloses yields of 62-82% and purity of only 90-95% even after vacuum distillation. According to the patentee, the yield and purity of the desired end product would be even lower if the reaction were carried out in the absence of an acid acceptor.
- U.S. Pat. No. 4,709,056 to Cotter, Lin, and Pawlak discloses the preparation of 4,4-difluorohexahydrophthalic anhydride and 4-chloro-4-fluorohexahydrophthalic anhydrides by reaction of hydrogen fluorides with 4-chlorotetrahydrophthalic anhydride.
- Co-pending application Ser. No. 07/393,449 which is a C-I-P or Ser. No. 160,033 and Ser. No. 160,034, is directed to the preparation of halophthalic anhydrides by the reaction of chlorine with halotetrahydrophthalic anhydride or gem-dihalohexahydrophthalic anhydride at temperatures of 200° Celsius and higher.
- halogen substituted phthalic anhydrides of the formula ##STR1## or intermediates thereof, wherein each X is independently F--, Cl--, Br--, or I--, and n is 1 or 2, may be prepared efficiently and in high yield and purity by the liquid phase reaction of a brominating agent, at temperatures below 230° Celsius, with a halogen substituted hexa-, or tetra-, hydrophthalo reactant of the formula ##STR2## wherein Q is monohalo and is the same as X or is gem-dihalo, wherein at least one halogen is the same as X, and n is the same number as in formula I, and Y and Z are CN, COBr, COCl, or COF; or Y and Z when taken together may comprise an anhydride group.
- each monohalo is directly attached to a double bond carbon and when Q is gem-dihalo, the gem-dihalo is directly attached to a non-double bond carbon.
- Y and Z are CN, COBr, COCl, or COF, the product of the bromine reaction may, in a known manner, be hydrolyzed to the dicarboxylic acid which, in turn is dehydrated to form the anhydride of formula I.
- the starting reactants for the process of this invention are saturated and partially saturated halo-ortho-phthalo- hexa-, or tetra-hydroaromatic compounds including halotetrahydrophthalic anhydrides such as those of the formulae ##STR3## and the like, and gem-dihalohexahydrophthalic anhydrides such as those of the formula ##STR4## and the like, wherein Hal represents halogen; and the corresponding halotetrahydro- and gem-dihalohexahydro-ortho-phthalonitriles and ortho-phthaloyl dihalides.
- the preferred reactants are the saturated and partially saturated phthalic anhydrides.
- the process of this invention comprises the reaction of a brominating agent with a halogen substituted cyclohexane anhydride, cyclohexene anhydride or cyclohexadiene anhydride.
- the preferred brominating agent based on process efficiency and economic considerations, is elemental bromine.
- Other brominating agents which may be employed include, for example, N-bromosuccinimide and bromine chloride.
- the brominating agent is preferably employed in at least stoichiometric amounts, that is two moles of brominating agent per mole of anhydride reactant, and most preferably in an amount of up to about 10 percent excess of that stoichiometric amount.
- the anhydride reactant is a halogen substituted tetrahydro-ortho-phthalo compound or a gem-dihalogen substituted hexahydro-ortho-phthalo- compound.
- Suitable reactants are available commercially or can be prepared by various known methods. For example, the Diels-Alder reaction of a maleic anhydride with a conjugated diene will produce an anhydride with a partially saturated six-membered ring.
- the conjugated diene and/or the maleic anhydride may be selected which contain the appropriate halogen substituents.
- the anhydride reactants that may be employed in the process of this invention include, for example:
- the corresponding iodo compounds may be employed, but are generally less stable and are not preferred.
- the reaction product When the starting reactant is a saturated or partially saturated halogen substituted ortho-phthalonitrile or phthaloyl dihalide, the reaction product may be converted to an anhydride in a known manner.
- a halogen substituted tetrahydrophthalonitrile, or gem dihalohexahydrophthalonitrile is reacted with a brominating agent, in accordance with the invention, the resulting halogen substituted phthalonitrile may be hydrolyzed, in a known manner, for example, using aqueous acid, to form the dicarboxylic acid, which is then dehydrated chemically or thermally to form the corresponding halophthalic anhydrides.
- the halophthalonitrile may be used as an intermediate to prepare the corresponding amides or other useful end products.
- the halo-phthaloyl dihalides may be employed as intermediates in the formation of various esters, by alcoholysis, or in the formation of the corresponding amides by ammonolysis.
- Contemplated equivalents to the anhydride reactants and products of the invention include the corresponding dicarboxylic acids, salts such as alkali metal salts, esters such as phenyl or alkylesters, imides, diamides and the like.
- the process is carried out in the liquid phase, either neat or in the presence of a solvent, at atmospheric pressure or under applied or autogenous pressure at temperatures ranging from about 0° to about 230° Celsius or slightly higher and preferably about 70° to about 170° Celsius. Lower temperatures, such as 30° C. and 40° C., can be used but they are not generally preferred due to long reaction times and/or lower yields. At temperatures substantially higher than about 230° Celsius, some degradation of the reaction or the product of reaction may appear. Moreover, when the reaction mixture is heated to temperatures in excess of about 170° C., it is important that the initial reaction with bromine occur at a temperature below about 170° C.
- Solvents that may be employed are preferably substantially non-reactive to bromine as well as to the organic reactant and preferably are characterized by a boiling point greater than about 100° Celsius. Typical of the solvents that may be employed are bromobenzenes and chlorobenzenes. The most preferred solvent is monochlorobenzene. Lower boiling solvents, such as chloroform, carbon tetrachloride, or chlorinated ethanes may be advantageously employed when the process is carried out at lower temperatures, for example, in the presence of a free radical initiator.
- the process of the invention involves a free radical reaction which may be enhanced by the use of a free radical initiator such as visible or ultra-violet irradiation, or addition of catalytic amounts, typically less than about 5 percent by weight, based on weight of reactants, of initiators such as azo compounds, peroxides and the like.
- a free radical initiator such as visible or ultra-violet irradiation
- catalytic amounts typically less than about 5 percent by weight, based on weight of reactants, of initiators
- Typical azo compounds useful as free-radical initiators are azobis (alpha, gamma-dimethyl valeronitrile), 2,2'-azobis (2,4-dimethyl valeronitrile); and typical peroxides are benzoyl peroxide, diacetyl peroxide, diisopropyl peroxydicarbonate, lauroyl peroxide and the like. Azobisisobutyronitrile is particularly useful in the process of this invention.
- the process of the invention is carried out to substantial completion at a single temperature, or temperature range, it is preferred, based on yield and purity achieved, to carry it out at about 90° to 135° and preferably about 90° to 125° C.
- the higher final temperature may, for example, be as high as about 250° without substantial deleterious effect.
- temperatures greater than about 190° C. offer no particular advantage, it is preferred to employ final temperatures in the range of about 150°-160° to 190° Celsius.
- the addition of bromine to the reaction mixture is carried out in stages with associated increases in temperature.
- a major portion of the bromine such as 65-80 percent, is added slowly while the reaction mixture is maintained at a temperature of about 90° to 125° Celsius until the bromine is substantially consumed.
- the temperature is then increased to about 130° to 145° and the remaining 20-35 percent of the bromine is added slowly while the temperature is maintained until the bromine is substantially consumed.
- the temperature is then increased to about 160°-175° and preferably maintained thereat for a period of time, such as about 3 to 8 hours to remove any remaining dissolved HBr and convert any residual intermediates to the final product.
- the reaction mixture was heated to 135° C. and maintained thereat for 3 hours while 240.0 g (1.5 moles) of bromine was added slowly, then heated to 165°-170° C. over a 20-minute period.
- a sample was analyzed and found to contain 79% 4-chlorophthalic anhydride.
- the temperature was maintained at about 165°-170° C. while 30 g (0.1875 mole) bromine was added over a 35-minute period. Temperature was maintained for an additional 5 hours.
- Final analysis of the crude reaction mixture by gas chromatography indicated (in area %) 94.7% 4-chlorophthalic anhydride, 2.1% bromophthalic anhydride and no detectable 4-chlorotetrahydrophthalic anhydride starting material.
- a simple up-and-over distillation at reduced pressure afforded a product of greater than 98% purity.
- Example IV The procedure of Example IV was repeated except that an acid acceptor, pyridine (1.6 g/0.02 mole) was added to the initial reaction mixture. Results of analysis by gas chromatography are set forth in Table I.
- an additional amount of bromine such as about 10 to 15 g, may be added to complete the conversion of 4-chlorotetrahydrophthaloyl chloride.
- an additional amount of bromine such as about 10 to 15 g, may be added to complete the conversion of 4-chlorotetrahydrophthaloyl chloride.
- a good yield of 4-chlorophthaloyl chloride will be obtained from the distillation of the mixture.
- an additional amount of bromine such as about 10 to 15 g, may be added to complete the conversion of 4-chlorotetrahydro-phthalonitrile.
- a good yield of 4-chlorophthalonitrile can be obtained by distilling out the chlorobenzene.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
TABLE I ______________________________________ Example Reaction Mixture (g) IV IV-A ______________________________________ 4-chlorotetrahydrophthalic anhydride 37.3 37.3 Pyridine 1.6 Bromine 77.0 77.0 Analysis of crude Reaction Product (area %) 4-chlorophthalic anhydride 91.1 84.9 4-bromophthalic anhydride 3.2 1.6 Phthalic anhydride 1.0 10.8 Other products 4.7 2.7 ______________________________________
Claims (26)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/721,004 US5233054A (en) | 1989-09-11 | 1991-06-26 | Process for the preparation of halophthalic anhydrides |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/405,606 US5049682A (en) | 1989-09-11 | 1989-09-11 | Process for the preparation of halophthalic anhydrides |
US07/721,004 US5233054A (en) | 1989-09-11 | 1991-06-26 | Process for the preparation of halophthalic anhydrides |
Related Parent Applications (1)
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US07/405,606 Division US5049682A (en) | 1989-09-11 | 1989-09-11 | Process for the preparation of halophthalic anhydrides |
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US5233054A true US5233054A (en) | 1993-08-03 |
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US07/721,004 Expired - Lifetime US5233054A (en) | 1989-09-11 | 1991-06-26 | Process for the preparation of halophthalic anhydrides |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5574172A (en) * | 1993-05-27 | 1996-11-12 | Mitsubishi Chemical Corporation | Process for producing halogenated phthalic anhydride |
US6498224B1 (en) | 2001-12-05 | 2002-12-24 | General Electric Company | Methods for the preparation poly(etherimide)s |
US6528663B1 (en) | 2001-12-05 | 2003-03-04 | General Electric Company | Methods for the preparation of 4-chlorophthalic anhydride |
US6576770B1 (en) | 2001-12-05 | 2003-06-10 | General Electric Company | Preparation of substituted phthalic anhydrides and substituted phthalimides |
US6649773B2 (en) | 2002-03-22 | 2003-11-18 | General Electric Company | Method for the manufacture of halophthalic acids and anhydrides |
US6657067B2 (en) | 2002-03-22 | 2003-12-02 | General Electric Company | Method for the manufacture of chlorophthalic anhydride |
US6657068B2 (en) | 2002-03-22 | 2003-12-02 | General Electric Company | Liquid phase oxidation of halogenated ortho-xylenes |
US20040063897A1 (en) * | 2002-09-25 | 2004-04-01 | Odle Roy Ray | Method for the preparation poly(etherimide)s |
US7732559B2 (en) | 2004-06-30 | 2010-06-08 | Sabic Innovative Plastics Ip B.V. | Method of making halophthalic acids and halophthalic anhydrides |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4517372A (en) * | 1983-05-12 | 1985-05-14 | Occidental Chemical Corporation | Process for the preparation of 4-fluorophthalic anhydride |
US4559405A (en) * | 1984-04-16 | 1985-12-17 | Stauffer Chemical Company | Process for preparing substituted phthalic anhydrides |
US4560773A (en) * | 1984-04-16 | 1985-12-24 | Stauffer Chemical Company | Process for preparing substituted phthalic anhydrides |
US4560772A (en) * | 1984-10-22 | 1985-12-24 | Stauffer Chemical Company | Preparation of substituted phthalic anhydrides |
US4689179A (en) * | 1984-07-30 | 1987-08-25 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for production of fluorinated quinones |
US4792618A (en) * | 1984-05-02 | 1988-12-20 | Occidental Chemical Corporation | Fluorinated carbocylic compounds |
US5003088A (en) * | 1988-02-24 | 1991-03-26 | Occidental Chemical Corporation | Method for the preparation of halophthalic anhydrides |
US5049682A (en) * | 1989-09-11 | 1991-09-17 | Occidental Chemical Corporation | Process for the preparation of halophthalic anhydrides |
-
1991
- 1991-06-26 US US07/721,004 patent/US5233054A/en not_active Expired - Lifetime
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4517372A (en) * | 1983-05-12 | 1985-05-14 | Occidental Chemical Corporation | Process for the preparation of 4-fluorophthalic anhydride |
US4559405A (en) * | 1984-04-16 | 1985-12-17 | Stauffer Chemical Company | Process for preparing substituted phthalic anhydrides |
US4560773A (en) * | 1984-04-16 | 1985-12-24 | Stauffer Chemical Company | Process for preparing substituted phthalic anhydrides |
US4792618A (en) * | 1984-05-02 | 1988-12-20 | Occidental Chemical Corporation | Fluorinated carbocylic compounds |
US4689179A (en) * | 1984-07-30 | 1987-08-25 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for production of fluorinated quinones |
US4560772A (en) * | 1984-10-22 | 1985-12-24 | Stauffer Chemical Company | Preparation of substituted phthalic anhydrides |
US5003088A (en) * | 1988-02-24 | 1991-03-26 | Occidental Chemical Corporation | Method for the preparation of halophthalic anhydrides |
US5049682A (en) * | 1989-09-11 | 1991-09-17 | Occidental Chemical Corporation | Process for the preparation of halophthalic anhydrides |
Non-Patent Citations (7)
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Bergmann, J. Amer. Chem. Soc. 64, 176 (1942). * |
Izv. Akad Nauk SSSR, Ser. Khim (6) 1315 20, 1970 CA103 (25):214656n. * |
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Izv. Akad Nauk SSSR, Ser. Khim (8) 1709 15, 1985 CA74 (17):87221x. * |
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Skvarchenko, V. R. Russian Chemical Reviews, Nov. 1963 vol. 32, No. 11, pp. 571 589. * |
Skvarchenko, V. R. Russian Chemical Reviews, Nov. 1963 vol. 32, No. 11, pp. 571-589. |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5574172A (en) * | 1993-05-27 | 1996-11-12 | Mitsubishi Chemical Corporation | Process for producing halogenated phthalic anhydride |
US6498224B1 (en) | 2001-12-05 | 2002-12-24 | General Electric Company | Methods for the preparation poly(etherimide)s |
US6528663B1 (en) | 2001-12-05 | 2003-03-04 | General Electric Company | Methods for the preparation of 4-chlorophthalic anhydride |
US6576770B1 (en) | 2001-12-05 | 2003-06-10 | General Electric Company | Preparation of substituted phthalic anhydrides and substituted phthalimides |
US6590108B1 (en) | 2001-12-05 | 2003-07-08 | General Electric Company | Methods for the preparation of dianhydrides |
US6649773B2 (en) | 2002-03-22 | 2003-11-18 | General Electric Company | Method for the manufacture of halophthalic acids and anhydrides |
US6657067B2 (en) | 2002-03-22 | 2003-12-02 | General Electric Company | Method for the manufacture of chlorophthalic anhydride |
US6657068B2 (en) | 2002-03-22 | 2003-12-02 | General Electric Company | Liquid phase oxidation of halogenated ortho-xylenes |
US20040063897A1 (en) * | 2002-09-25 | 2004-04-01 | Odle Roy Ray | Method for the preparation poly(etherimide)s |
US6881815B2 (en) | 2002-09-25 | 2005-04-19 | General Electric Company | Method for the preparation poly(etherimide)s |
US7732559B2 (en) | 2004-06-30 | 2010-06-08 | Sabic Innovative Plastics Ip B.V. | Method of making halophthalic acids and halophthalic anhydrides |
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