US503028A - George archbold - Google Patents
George archbold Download PDFInfo
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- US503028A US503028A US503028DA US503028A US 503028 A US503028 A US 503028A US 503028D A US503028D A US 503028DA US 503028 A US503028 A US 503028A
- Authority
- US
- United States
- Prior art keywords
- rock
- tank
- hydro
- george
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000011435 rock Substances 0.000 description 42
- 150000002430 hydrocarbons Chemical class 0.000 description 22
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 22
- 239000005864 Sulphur Substances 0.000 description 16
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000004215 Carbon black (E152) Substances 0.000 description 12
- 239000002253 acid Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 239000007789 gas Substances 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000000341 volatile oil Substances 0.000 description 6
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- 235000015450 Tilia cordata Nutrition 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- 239000010426 asphalt Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000005086 pumping Methods 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 240000002027 Ficus elastica Species 0.000 description 2
- 241000490025 Schefflera digitata Species 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000003028 elevating Effects 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000003517 fume Substances 0.000 description 2
- 201000005569 gout Diseases 0.000 description 2
- 235000015250 liver sausages Nutrition 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920001195 polyisoprene Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/04—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S208/00—Mineral oils: processes and products
- Y10S208/951—Solid feed treatment with a gas other than air, hydrogen or steam
Definitions
- the object of my invention is to separate the terrelite from the other constituents of the rock rapidly and at a small expense and to this end I make use of the process fully set forth hereinafter and preferably of the apparatus illustrated in the accompanying drawelevation.
- I conduct the air from a pump F through a pipe e, to an air-tight reservoir or casing G, in which is arranged a pan f, containing the sulphur to be burned and I so restrict the outlet as to secure the desired pressure in the tank G and I connect the latter through the medium of a pipe g, with a perforated pipe i, extending along the bottom of the tank A, and the air forced by the pump F, into the tank G, takes up the fumes of the sulphur burning in the said tank and conducts the same to the water in the tank A, which combines with the sulphur forming sulphurous acid in the liquid state while sufficient air is permitted through openings w, into the tank A to combine with the sulphur if that forced by the pump is not sufficient to form sulphurous acid in a gaseous condition, so that sulphurous acid gas flows upward through the mass of rock while the liquid sulphurous acid flows downward over the rock which is thereby speedily disintegrated
- the acid of course combines with the earthy matters of the rock and after the water in the tank A becomes saturated with sulphites of said earthy matters in solution the solution is withdrawn and replaced by fresh water and if desired the same may be subsequently treated to separate the ingredients, while the terrelite is withdrawn to give place to an ad ditional charge of bituminous rock.
Description
(No Model.) 7
G. AROHBOLD. METHOD OF AND MEANS FOR EXTRAGTING HYDROGARBONS FROM BITUMINOUS ROCKS.
No. 503,028. 4 Pate t 11g. 8, 1893.
W E i ii; 12 MM.
' WWII WW ll EM UNITED STATES PATENT OFFICE.
GEORGE ARCHBOLD, OF WASHINGTON, DISTRICT OF COLUMBIA, ASSIGNOR 1 TO HERBERT L. TERRELL, OF NEW YORK, N. Y.
METHOD OF AND MEANS FOR EXTRACTING HYDROCARBONS FROM BITUMINOUS ROCKS.
- SPECIFICATION forming part of Letters Patent No. 503,028, dated August 8, 1893- Application filed March 26, 1892- Serlal No, 426,439.
(No model.)
.To all whom it may concern:
Be it known that I, GEORGE 'ARCHBOLD, a citizen of the United States, and a resident of Washington, in the District of Columbia, have ments in Methods of and Means for Extracting Hydro-carbons from Bituminous Rocks, of which the following is a specification.
It has been found desirable for the produc-' tion of artificial india-rubber and for other purposes toseparate the ingredients or constituents of a grayish rock, which is found in abundance in the State of Texas, and which consists generally of lime and silica and mineral hydro-carbon, the object in separating the ingredients being to secure the hydro-carbon in a mass separate from the lime and silica, the said hydro-carbon when separated being in a spongy condition in which it has received the name of terrelite.
The object of my invention is to separate the terrelite from the other constituents of the rock rapidly and at a small expense and to this end I make use of the process fully set forth hereinafter and preferably of the apparatus illustrated in the accompanying drawelevation.
ing, which shows the same in part sectional I have discovered that when the said grayish rock hereinafter termed bituminous rock is subjected to the action of sulphurous acid, either as gas or a liquid the chalky and silicious portions will be rapidly dissolved leaving the hydro-carbon or terrelits in a spongy condition.
Different means may be employed for facilitating the application of the sulphurous acid to the bituminous. rock. Thus, I make use,of a water pipe tank or receptacle A, having a grate or partition B, upon which the rock is deposited in a mass 0, preferably in lumps of about three or four inches in thickness affording ample interstices for the passage of the acid, and I make use of a pump D, driven by a motor E of any suitable character with pipes a, b, throughwhich the acid is drawn from the bottom of the tank and thrown upward to the top of the tank or conveyed to a suitable distributor 0, consisting of a perforated pipe discharging the acid in small streams on the mass of rock. Any other suitable form of distributor and elevating apparatus may be employed. In order tomanufacture the sulphurous acid rapidly and economically and further to invented certain new and useful I|nprovc-' secure the same in both a gaseous andliquid condition, I pass a current of air over burning sulphur and then into a perforated pipe lying in a body of water at the bottom of the receptacle A. As it would take twenty-four hours to burn a cubic foot of sulphur in the open air I expedite the combustion by making use of compressed air a current of' air at sixty pounds pressure insuring the combustion of a cubic foot of sulphur in six hours. Thus, I conduct the air from a pump F through a pipe e, to an air-tight reservoir or casing G, in which is arranged a pan f, containing the sulphur to be burned and I so restrict the outlet as to secure the desired pressure in the tank G and I connect the latter through the medium of a pipe g, with a perforated pipe i, extending along the bottom of the tank A, and the air forced by the pump F, into the tank G, takes up the fumes of the sulphur burning in the said tank and conducts the same to the water in the tank A, which combines with the sulphur forming sulphurous acid in the liquid state while sufficient air is permitted through openings w, into the tank A to combine with the sulphur if that forced by the pump is not sufficient to form sulphurous acid in a gaseous condition, so that sulphurous acid gas flows upward through the mass of rock while the liquid sulphurous acid flows downward over the rock which is thereby speedily disintegrated. The acid of course combines with the earthy matters of the rock and after the water in the tank A becomes saturated with sulphites of said earthy matters in solution the solution is withdrawn and replaced by fresh water and if desired the same may be subsequently treated to separate the ingredients, while the terrelite is withdrawn to give place to an ad ditional charge of bituminous rock.
I am aware that it has been proposed to use naphtha for the purpose of dissolvin gout bitumen or hydro-carbon substances from minerals, and subsequently separating the bitumen or hydro-carbon from the naphtha in ICO which it is held in solution by treating it with steam which carriesoft the naphtha. But the action of the steam results in carrying oif along with the naphtha the volatile oils of the 5 hydro-carbons which are thereby lost. My process diflfers from this process just referred to in that I employ an acid which does not drive off or eflect the volatile oils but extracts the earthy matters only, leaving the hydroro' carbon in a plastic condition resulting from the retention of the volatile oils.
, Without limiting myself to the use of the apparatus constructed as shown, I claim as my invention'- 1. The within described method of separating earthy matters from the hydro-carbons in bituminous rock the same consisting in subjecting a mass of said rock to the action of sulphurous acid, substantially as set forth. :0 2. In the treatment of bituminous rock which separates the earthy matters and the hydro-carbons, subjecting a mass of said rock to the action of sulphurous acid in botha liquid and gaseous condition, substantially as 25 set forth.
3. The combination of a tank having-a support for bitn minons rock, a pump and pipe arranged to pump sulphurous acid onto the rock from a position below said support, means for generating sulphurous acid gas and for conducting the same to a body of water below said support, substantially as set forth.
4. The combination with the tank supporting a mass of bituminous rock a receptacle for waterbelowsaid mass and a pump for pumping the liquid from'the receptacle-to the top of the mass, acasing G with a support for burning sulphur and a pipe connecting said casing with the water receptacle, and means for pumping the air under pressure into the casing, substantial y as and for the purpose described. 4
'In testimony whereof I have signed my name to this specification in the presence of two subscribing witnesses.
GEORGE ARCH BOLD.
Witnesses:
W. CLARENCE DUVALL, ALLE N. DOBSON.
Publications (1)
Publication Number | Publication Date |
---|---|
US503028A true US503028A (en) | 1893-08-08 |
Family
ID=2571864
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US503028D Expired - Lifetime US503028A (en) | George archbold |
Country Status (1)
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US (1) | US503028A (en) |
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- US US503028D patent/US503028A/en not_active Expired - Lifetime
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