US5008204A - Method for determining the compositional distribution of a crystalline copolymer - Google Patents

Method for determining the compositional distribution of a crystalline copolymer Download PDF

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Publication number
US5008204A
US5008204A US07/151,350 US15135088A US5008204A US 5008204 A US5008204 A US 5008204A US 15135088 A US15135088 A US 15135088A US 5008204 A US5008204 A US 5008204A
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Prior art keywords
column
solvent
copolymer
temperature
fractions
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Expired - Fee Related
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US07/151,350
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English (en)
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Ferdinand C. Stehling
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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Priority to US07/151,350 priority Critical patent/US5008204A/en
Priority to CA000589676A priority patent/CA1335072C/fr
Priority to JP1020978A priority patent/JP2684082B2/ja
Priority to DE68920166T priority patent/DE68920166T2/de
Priority to EP89301018A priority patent/EP0327368B1/fr
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Publication of US5008204A publication Critical patent/US5008204A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D9/00—Crystallisation
    • B01D9/0004—Crystallisation cooling by heat exchange
    • B01D9/0013—Crystallisation cooling by heat exchange by indirect heat exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D9/00—Crystallisation
    • B01D9/004—Fractional crystallisation; Fractionating or rectifying columns
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D9/00—Crystallisation
    • B01D9/0063—Control or regulation
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N2030/0075—Separation due to differential desorption
    • G01N2030/008—Thermal desorption
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N25/00—Investigating or analyzing materials by the use of thermal means
    • G01N25/14—Investigating or analyzing materials by the use of thermal means by using distillation, extraction, sublimation, condensation, freezing, or crystallisation
    • G01N25/147—Investigating or analyzing materials by the use of thermal means by using distillation, extraction, sublimation, condensation, freezing, or crystallisation by cristallisation

Definitions

  • the present invention relates to the solvent fractionation of a polymer. More specifically, the invention relates to the fractionation of a copolymer with a single solvent at different temperatures.
  • Crystalline copolymers such as linear low density polyethylene (LLDPE) and ethylene vinyl acetate (EVA), are known to have molecular weight distributions and composition distributions.
  • the properties of copolymers having similar average compositions can vary considerably depending upon the compositional distribution of the copolymer.
  • LLDPE linear low density polyethylene
  • EVA ethylene vinyl acetate
  • Compositional distributions are known to have a strong effect on the physical properties of copolymers, e.g., heat sealing, tear strength, and FDA extraction limits.
  • the molecular weight and compositional distributions of copolymers have been determined by solvent fractionation of the crystalline copolymer and analysis of the fractions for molecular weight and composition.
  • Apparatus for solvent fractionating of copolymers are known in the art. Such apparatus typically operate by dissolving the copolymer in a hot solvent and allowing the solvent to cool to ambient temperature within a packed column. The copolymer crystallizes on the column packing as the polymer cools. It is known in the art to cool the polymer to slightly above ambient temperature, about 30° C, before starting fractionation with pure solvent.
  • Fractionation of the crystallized polymer is typically conducted with a single solvent that is passed through the column at increasing column temperatures beginning at the lowest temperature obtained during cooling of the copolymer. Less soluble fractions of the copolymer are dissolved and removed from the column as the column temperature rises such that the solvent effluent from the column containing dissolved copolymer can be collected in consecutive fractions which are identified by a starting and ending column temperature. These fractions are then analyzed for molecular weight distribution and monomer composition by conventional means.
  • the present invention is a method for determining the compositional distributions of a crystalline copolymer comprising the steps of dissolving the copolymer in a solvent at elevated temperature, filling a column with the solvent containing the dissolved copolymer, crystallizing the copolymer within the column by reducing the temperature of the column to below ambient temperature, e.g. to temperatures at least about 6° C or lower, initially passing pure solvent through the column at a constant temperature below ambient to determine the amount of uncrystallized copolymer, and then at increasing temperature to gradually dissolve the copolymer, continuously measuring the concentration of the copolymer in the solvent exiting the column.
  • the method is preferably conducted with a fractionation temperature range of from 0 to 120° C and with tetrachloroethylene as the solvent.
  • the effluent from the fractionation column is preferably continuously analyzed by an IR detector to determine the concentration of polymer in the solvent.
  • FIG. 1 is a schematic diagram of the sample preparation mode for an apparatus which can determine the solubility distribution curve of a crystalline polymer in accordance with the method of the present invention
  • FIG. 2 shows the apparatus of FIG. 1 in the solvent fractionation mode
  • FIG. 3 is an exemplary solubility distribution curve which was generated by the method of the present invention.
  • FIG. 4 is another exemplary solubility distribution curve generated by the method of the present invention.
  • the method of the present invention has been practiced with an apparatus that automatically determines the solubility distribution curve of a crystalline copolymer.
  • a steel column is packed with glass beads (approximately 35 mesh) and immersed in an oil bath 10.
  • a column having an inside diameter of 35 mm and a length of 400 mm has worked well.
  • the temperature of the oil bath can be programmed over any desirable temperature range, e.g. from below ambient, preferably about or below 6 C, or about or below -12° C, although even lower temperatures may be employed, to a temperature up to about 150 C.
  • Solvent used in the fractionation may be prevented from boiling by operating the apparatus at about 3 atmospheres pressure.
  • a weighed amount of sample is placed in a sample preparation chamber 20, that is then sealed and repeatedly evacuated and filled with argon.
  • a metered volume of solvent 30, preferably tetrachloroethylene is then pumped through a three-way valve 32 into the sample preparation chamber 20 where it is stirred and heated to obtain a solution of about 1 percent concentration.
  • a metered volume of this solution is then pumped into the packed column 2 which has been thermostated at a high temperature of usually at least about 120° C.
  • the polymer solution sample is subsequently crystallized by cooling the polymer in the column 2 at a programmed rate of 5° C per hour to below ambient temperature in order to increase the proportion of the polymer crystallized, e.g., to below or about 6° C.
  • some polymers may require lower crystallization temperatures, e.g. about or below -6° C or -12 C.
  • the column 2 is then maintained at this low temperature for at least an hour. Thereafter, the elution of fractionation stage shown in FIG. 2 is started by pumping pure solvent 30 through the column 2 at the rate of 6 cc per minute.
  • Effluent from the column 2 passes through a reheater 40 where it is heated to 120° C before passing through an IR detector 50 which is used to measure the absorbance of the effluent stream.
  • the infrared absorbance of the polymer carbon-hydrogen stretching bands at about 2960 cm -1 serves as a continuous measure of the relative concentration of polymer in the effluent.
  • the temperature of the effluent is reduced to about 110° C and the pressure is reduced to 1 atmosphere before passing the stream into an automatic fraction collection 60.
  • the pure solvent is initially pumped through the column 2 at the low initial temperature for one hour. This serves to flush polymer that has not crystallized during the crystallization stage out of the column 2 so that the percent of uncrystallized polymer can be determined from the infrared trace.
  • the temperature is then programmed upward at 10° C. per hour to 100° C and at 20° C per hour from 100° C to 120° C.
  • compositions of fractions obtained from the various polymers are determined by infrared spectroscopy.
  • the IR compositions are obtained from the intensity of the 1378 cm-1 methyl band, the thickness of the sample, and a calibration curve based on samples whose compositions can be determined independently H 7 by NMR. No corrections for polymer end groups is usually made in obtaining compositions from infrared data.
  • FIG. 3 An example of a solubility distribution obtained from a typical LLDPE sample, Dow 2045 [poly ⁇ ethylene-co-octene ⁇ , 0.918 g/cc, melt index 1.01 obtained using the procedure of the invention described above is shown in FIG. 3.
  • a composition scale obtained by analysis of fractions from poly(ethylene-co-butene ⁇ , poly ⁇ ethylene-co-hexene ⁇ and poly ⁇ ethylene-co-octene ⁇ eluted at various temperatures is also shown in FIG. 3.
  • the solubility versus temperature distributions for the polymer has a peak for the 6° C first-hour elution temperature. This initial peak represents the fraction of total polymer that is not crystallizable at the lowest temperature of the experiment ⁇ about 6° C ⁇ .
  • the typical run length for a sample is about 40 hours.
  • FIG. 4 Another example of a solubility distribution and composition distribution is shown in FIG. 4.
  • the polymer sample was Mitsui Petrochemical Company Tafmor A4085 poly ⁇ ethylene- co-butene ⁇ , density -0.B8 g/cc, melt index 1.0.
  • the curve was obtained according to the invention using the procedures described above. This example illustrates the importance of elution at sub-ambient temperature since only a small portion of this sample would have been resolved by elution only at 30° C and above as done in the prior art.
  • the apparatus and method described above provide a plot of concentration of polymer versus elution temperature.
  • the fractions of solvent containing dissolved copolymer can then be analyzed by conventional means for molecular weight and composition to establish the molecular weight distribution and composition distribution of monomer.
  • a calibration curve relating elution temperature to monomer composition can be generally derived for specific comonomers.

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  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Investigating Or Analyzing Materials Using Thermal Means (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Sampling And Sample Adjustment (AREA)
US07/151,350 1988-02-02 1988-02-02 Method for determining the compositional distribution of a crystalline copolymer Expired - Fee Related US5008204A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US07/151,350 US5008204A (en) 1988-02-02 1988-02-02 Method for determining the compositional distribution of a crystalline copolymer
CA000589676A CA1335072C (fr) 1988-02-02 1989-01-31 Methode permettant d'etablir la distribution de composition d'un copolymere cristallin
JP1020978A JP2684082B2 (ja) 1988-02-02 1989-02-01 結晶性コポリマーの組成分布を決定する方法
DE68920166T DE68920166T2 (de) 1988-02-02 1989-02-02 Verfahren zur Bestimmung der Komponentenverteilung in einem kristallinen Copolymer.
EP89301018A EP0327368B1 (fr) 1988-02-02 1989-02-02 Méthode de détermination de la distribution des composants d'un copolymère cristallin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/151,350 US5008204A (en) 1988-02-02 1988-02-02 Method for determining the compositional distribution of a crystalline copolymer

Publications (1)

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US5008204A true US5008204A (en) 1991-04-16

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US (1) US5008204A (fr)
EP (1) EP0327368B1 (fr)
JP (1) JP2684082B2 (fr)
CA (1) CA1335072C (fr)
DE (1) DE68920166T2 (fr)

Cited By (245)

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DE68920166T2 (de) 1995-05-11
EP0327368A2 (fr) 1989-08-09
JPH02193049A (ja) 1990-07-30
CA1335072C (fr) 1995-04-04
EP0327368B1 (fr) 1994-12-28

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