US496032A - And lamartine c - Google Patents
And lamartine c Download PDFInfo
- Publication number
- US496032A US496032A US496032DA US496032A US 496032 A US496032 A US 496032A US 496032D A US496032D A US 496032DA US 496032 A US496032 A US 496032A
- Authority
- US
- United States
- Prior art keywords
- blast
- tuyeres
- slag
- smelting
- converter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002184 metal Substances 0.000 description 40
- 229910052751 metal Inorganic materials 0.000 description 40
- 238000000034 method Methods 0.000 description 36
- 239000002893 slag Substances 0.000 description 32
- 238000003723 Smelting Methods 0.000 description 30
- 239000000463 material Substances 0.000 description 24
- 150000003568 thioethers Chemical class 0.000 description 22
- 150000002739 metals Chemical class 0.000 description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- 238000007670 refining Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000000571 coke Substances 0.000 description 8
- 239000000446 fuel Substances 0.000 description 8
- 229910052742 iron Inorganic materials 0.000 description 8
- 239000005864 Sulphur Substances 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- UCKMPCXJQFINFW-UHFFFAOYSA-N sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 6
- 241001062472 Stokellia anisodon Species 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 210000000481 Breast Anatomy 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 241000005139 Lycium andersonii Species 0.000 description 2
- 102000001839 Neurturin Human genes 0.000 description 2
- 108010015406 Neurturin Proteins 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 235000015450 Tilia cordata Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229910052570 clay Inorganic materials 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000003517 fume Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910052904 quartz Inorganic materials 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 230000001105 regulatory Effects 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N silicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0026—Pyrometallurgy
- C22B15/0028—Smelting or converting
- C22B15/003—Bath smelting or converting
- C22B15/0041—Bath smelting or converting in converters
Definitions
- the object of my invention is to provide for smelting ores and refining metals in one operation, and for utilizing as fuel the sulphur in the ores to be refined or smelted; and the invention consists in the process hereinafter described and claimed.
- Figure l is a vertical sectional elevation
- Fig. 2 a cross section taken on line 2 of Fig. 1.
- A is the converter, or the tuyeres, and a the metal tap thereof; B the blast furnace, b the tuyeres, and b the slag spout thereof; and O the opening for the introduction of concentrates, ore, matte, or other substances to be treated.
- a combined converter and blast furnace which, as shown, is circular inform, but which may be square, oval, rectangular, or in any shape desired.
- the sides of the converter and furnace are preferably made of steel, iron, or copper plates, with an intervening water space as in the usual form of Water jacket blast furnace, the bottom being also water jacketed-although the water jacketing is not in all cases necessary.
- the raw concentrates, ore, matte, or other substances to be treated, are introduced through a suitable openingin the top or sides as may be most convenient.
- the top of the furnace may be so shaped that the particles thrown upward by the force of the blast will strike against a covering, preferably water jacketed, after which they will be conducted, along with the fumes and gases, into dust chambers or fiues, and thence through a stack or chimney to the outer air.
- a covering preferably water jacketed
- Theplugsinthelowertuyeres beingremoved-- if formed of the material to be treated, they may be simply driven inand a blast of sufficient pressure, according to the height of charge, being turned on, the conversion of the sulphides to metals will immediately begin, the oxygen and sulphur uniting with the air to form S0, which escapes through the stack.
- the iron in the ore present as a sulphide,which in this state refuses, even in the plastic condition, to unite with the silica, (SiO becomes an oxide, (FeO,) and unites with the silica to form a silicate of iron.
- the blast is stopped or checked and the material allowed to separate in the furnace, after which the slag tap is opened with a pointed bar or otherwise, asin other forms of blast furnace smelting, and a certain amount of slag allowed to run out, the amount being determined by measurement in suitable vessels and approximated to the weight of slag making material treated,which has been previously determined by the metallurgist in charge.
- care should be taken not to remove all the slag, a certain amount being necessary to arrest the oxides formed in the converter below. These oxides are arrested by coming in contact with the molten sulphides on top of the me tallic bath, or by passing through slag above the molten sulphides.
- a certain amount of metal, say copper or lead, is now tapped out, during which process an equal weight of sulphides is added to the charge from above.
- the tuyeres being reopened and the blast again turned on, the molten mass that remains, being at a white heat, ignites the new charge immediately; and so the process goes on continuously, the slag and metal being drawn E and ore added as in other smelting processes.
- a sufficient height of molten material to cover the tuyeres must be carried at all times during the operation of the furnace, and the blast must be strong enough to prevent the molten material from entering the tuyeres.
- the blast pressure must be greater during the smelting operation than the weight of molten material above the tuyeres.
- This strong blast necessarily keeps the molten mass in constant agitation while the smelting operation is in progress; but as soon as matte or metal of a desired grade is produced, the blast must be stopped or checked by closing some or all of the tuyeres, as above mentioned, to the extent necessary to stop agitation.
- I avoid the preliminary calcining or roasting of the sulphide ores and the subsequent smelting to metallic matte, and also save much of the fuel necessary in smelting.
Description
(No Model.)
0. M. ALLEN. PROCESS OF SMBLTING 0358 AND REPINING METALS.
No. 496,032. Patented Apr. 25, 1893.
an O NrTn STATES PATENT OFFICE.
CHARLES M. ALLEN, OF BUTTE, MONTANA, ASSIGNOR OF ONE-HALFTO WVILLIAM J. OHALMERS, OF CHICAGO, ILLINOIS, AND LAMARTINE O. TRENT, OF SALT LAKE CITY, UTAH TERRITORY.
PROCESS OF SMELTING; ORES AND REF'INING METALS.
SPECIFICATION forming part of Letters Patent No. 496,032, dated April 25, 1893- Application filed April 12, 1892. Serial No. 423,830. (No model.)
To all whom it may concern.-
Be it known that 1, CHARLES M. ALLEN, a citizen of the United States, residing at Butte City, in the county of Silver Bow and State of Montana, haveinvented a new and useful Process of Smelting Ores and Refining Metals, of which the following is a specification.
The object of my invention is to provide for smelting ores and refining metals in one operation, and for utilizing as fuel the sulphur in the ores to be refined or smelted; and the invention consists in the process hereinafter described and claimed.
In the accompanying drawings, Figure l is a vertical sectional elevation, and Fig. 2 a cross section taken on line 2 of Fig. 1.
A is the converter, or the tuyeres, and a the metal tap thereof; B the blast furnace, b the tuyeres, and b the slag spout thereof; and O the opening for the introduction of concentrates, ore, matte, or other substances to be treated.
In carrying out my process, I use a combined converter and blast furnace, which, as shown, is circular inform, but which may be square, oval, rectangular, or in any shape desired. The sides of the converter and furnace are preferably made of steel, iron, or copper plates, with an intervening water space as in the usual form of Water jacket blast furnace, the bottom being also water jacketed-although the water jacketing is not in all cases necessary. There are two rows of tuyeres, one above the other, the upper row being for the blast furnace and the lower row for the converter. The raw concentrates, ore, matte, or other substances to be treated, are introduced through a suitable openingin the top or sides as may be most convenient. The top of the furnace may be so shaped that the particles thrown upward by the force of the blast will strike against a covering, preferably water jacketed, after which they will be conducted, along with the fumes and gases, into dust chambers or fiues, and thence through a stack or chimney to the outer air.
In operation a wood fire is built in the b0ttom of the converter, after which coke is added until a good coke fire is burning above the tuyeres. A gentle blast'is then turned on through the upper row of tuyeres, the lower row being closed with plugs of the material to be treated, or with clay or rnetahthe metal tap held through the brick breast, and the slag tap being closed with a suitable plug or stopper. After the coke is all aglow, the raw sulphides are added and the blast increased, gradually adding sulphides and coke until the molten mass reaches the upper tuyeres. Theplugsinthelowertuyeres beingremoved-- if formed of the material to be treated, they may be simply driven inand a blast of sufficient pressure, according to the height of charge, being turned on, the conversion of the sulphides to metals will immediately begin, the oxygen and sulphur uniting with the air to form S0,, which escapes through the stack. The iron in the ore, present as a sulphide,which in this state refuses, even in the plastic condition, to unite with the silica, (SiO becomes an oxide, (FeO,) and unites with the silica to form a silicate of iron. By regulating the proportion of the pyrites to silica or quartz, which can be readily done by previous concentration with jigs and Vanners or other concentrating machinery, or if necessary by the addition to the charge of lime rock, (CaOo any desired slag can be produced. As the presence of sulphides of iron always reduces the oxides of copper, and, as by the use of this continuous process fresh raw sulphides are constantly added,'this operation is peculiarly adapted to make good clean slag. After the blowing has progressed sufficiently, the blast is stopped or checked and the material allowed to separate in the furnace, after which the slag tap is opened with a pointed bar or otherwise, asin other forms of blast furnace smelting, and a certain amount of slag allowed to run out, the amount being determined by measurement in suitable vessels and approximated to the weight of slag making material treated,which has been previously determined by the metallurgist in charge. Of course care should be taken not to remove all the slag, a certain amount being necessary to arrest the oxides formed in the converter below. These oxides are arrested by coming in contact with the molten sulphides on top of the me tallic bath, or by passing through slag above the molten sulphides. A certain amount of metal, say copper or lead,is now tapped out, during which process an equal weight of sulphides is added to the charge from above. The tuyeres being reopened and the blast again turned on, the molten mass that remains, being at a white heat, ignites the new charge immediately; and so the process goes on continuously, the slag and metal being drawn E and ore added as in other smelting processes. Of course a sufficient height of molten material to cover the tuyeres must be carried at all times during the operation of the furnace, and the blast must be strong enough to prevent the molten material from entering the tuyeres. In other words, the blast pressure must be greater during the smelting operation than the weight of molten material above the tuyeres. This strong blast necessarily keeps the molten mass in constant agitation while the smelting operation is in progress; but as soon as matte or metal of a desired grade is produced, the blast must be stopped or checked by closing some or all of the tuyeres, as above mentioned, to the extent necessary to stop agitation. ,This stopping or checking of the blast is an important step in my process, inasmuch as, by stoping agitation, it permits the difierent materials to separate in the furnace-say, as sand suspended in water by agitationsettles when the agitation ceases-and thus allows slag to be drawn from one point, matte or metal from another, &c. It also dispenses with the necessity of tipping the furnace to raise the tuyeres above the charge, when it is desired to accomplish separation. It will thus be seen that I provide for continuously treating metals contained in raw sulphide ores by smelting, converting, refining and smelting at one operation, and also for using the sulphur contained in the metallic sulphides as fuel. In this way I avoid the preliminary calcining or roasting of the sulphide ores and the subsequent smelting to metallic matte, and also save much of the fuel necessary in smelting. In other words, I am able by this process to smelt ore by a blast heated by passing through molten material or matte, and also to smelt ore and convert the valuable metals contained in raw sulphides into a metallic stateas, for instance, black or blister copper-in one operation and without the use of any fuel except that necessary in starting and maintaining the blast. I am also able to dispense with the stove usually employed in heating the blast required for pyritic smelting.
I am aware that attempts have been made to separate matte, metal and slag in a converter by stopping the blast by the use of a movable tuyere adapted to be dipped into the molten material or withdrawn therefrom; but this method has not been found practicable because of the rapid destruction of the tuyere, the ditficulty of keeping it open, and the impossibility of introducing it through a charge of ore. My process obviates all these objections, the tuyere being fixed and indestructible, easily kept open, and capable of use under any charge or weight of ore. I therefore disclaim any process in which the blastis checked or stopped by withdrawing the tuyere from the charge, and limit myself to a process in which a stationary tuyere is used, and the stopping or checking of the blast is effected by plugging the tuyeres.
As the essence of my invention consists in the process described, it will of course be understood that I do not intend to limit myself to minor features or details of operation, or in every case to the accomplishment of all the objects or benefits specified. Nor do I contemplate limiting the use of my process to the treatment of any particular kind of ores, it being my intention to use the same with any ores to which it may be applicable.
I do not herein claim a converter and blast furnace combined, the same being the subject of another application Serial No. 428,831 filed by me April 12, 1892.
I claim--- 1. The process of smelting ores, which consists in subjecting them to a blast heated by passing through molten metal or matte in a furnace or converter, and checking or stopping the blast by plugging the tuyeres to permit slag, matte and metal to separate in the converter, substantially as described.
2. The process of smelting ores and refining metals, which consists in melting ores in a furnace or converter, forcing a blast through the molten material, checking or stopping the blast by plugging the tuyeres to permit slag, matte and metal to separate in the converter, and tapping the slag, matte and metal from the converter separately and at diiferent heights, substantially as described.
3. The process of smelting ores and refining metals,which consists in feeding raw sulphides into a furnace or converter, subjecting them to a blast heated by passing through molten material, checking or stopping the blast by plugging the tuyeres to permit slag, matte and
Publications (1)
Publication Number | Publication Date |
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US496032A true US496032A (en) | 1893-04-25 |
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US496032D Expired - Lifetime US496032A (en) | And lamartine c |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3281236A (en) * | 1964-07-01 | 1966-10-25 | Little Inc A | Method for copper refining |
-
0
- US US496032D patent/US496032A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3281236A (en) * | 1964-07-01 | 1966-10-25 | Little Inc A | Method for copper refining |
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