US4394199A - Explosive emulsion composition - Google Patents
Explosive emulsion composition Download PDFInfo
- Publication number
- US4394199A US4394199A US06/299,742 US29974281A US4394199A US 4394199 A US4394199 A US 4394199A US 29974281 A US29974281 A US 29974281A US 4394199 A US4394199 A US 4394199A
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- US
- United States
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- composition
- water
- oil
- weight
- oil phase
- Prior art date
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- Expired - Lifetime
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- 239000000203 mixture Substances 0.000 title claims abstract description 29
- 239000000839 emulsion Substances 0.000 title claims abstract description 26
- 239000002360 explosive Substances 0.000 title claims abstract description 15
- 239000012071 phase Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical class CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000008346 aqueous phase Substances 0.000 claims abstract description 10
- 230000001590 oxidative effect Effects 0.000 claims abstract description 10
- 150000003839 salts Chemical class 0.000 claims abstract description 10
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical group OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 8
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 8
- 239000012188 paraffin wax Substances 0.000 claims description 6
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 5
- 239000000787 lecithin Substances 0.000 claims description 5
- 229940067606 lecithin Drugs 0.000 claims description 5
- 235000010445 lecithin Nutrition 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 239000004005 microsphere Substances 0.000 claims description 4
- 235000010344 sodium nitrate Nutrition 0.000 claims description 4
- 239000004317 sodium nitrate Substances 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims 3
- 230000001235 sensitizing effect Effects 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 claims 2
- 239000007762 w/o emulsion Substances 0.000 claims 2
- 239000000446 fuel Substances 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 4
- 239000003921 oil Substances 0.000 description 17
- -1 fatty acid salts Chemical class 0.000 description 6
- 238000005422 blasting Methods 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 125000004971 nitroalkyl group Chemical group 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 4
- 239000002562 thickening agent Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000005474 detonation Methods 0.000 description 3
- 239000000295 fuel oil Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Chemical class 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 2
- 239000010451 perlite Substances 0.000 description 2
- 235000019362 perlite Nutrition 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 1
- HZTVIZREFBBQMG-UHFFFAOYSA-N 2-methyl-1,3,5-trinitrobenzene;[3-nitrooxy-2,2-bis(nitrooxymethyl)propyl] nitrate Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O.[O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O HZTVIZREFBBQMG-UHFFFAOYSA-N 0.000 description 1
- FGLBSLMDCBOPQK-UHFFFAOYSA-N 2-nitropropane Chemical compound CC(C)[N+]([O-])=O FGLBSLMDCBOPQK-UHFFFAOYSA-N 0.000 description 1
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 description 1
- 241000609240 Ambelania acida Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000002918 oxazolines Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229940083466 soybean lecithin Drugs 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/14—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase comprising a solid component and an aqueous phase
- C06B47/145—Water in oil emulsion type explosives in which a carbonaceous fuel forms the continuous phase
Definitions
- This invention relates to an explosive emulsion composition.
- this invention relates to an explosive emulsion composition containing a nitroalkane.
- the composition is generally prepared by preparing the aqueous phase and the oil phase separately, then adding the aqueous phase slowly to the oil phase with a high degree of agitation, such as by means of a high sheer mixer.
- a sensitizer such as an entrapped gas component, e.g., hollow microspheres (e.g. Microballoons) or perlite, is then added and well mixed.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Colloid Chemistry (AREA)
Abstract
An explosive, water-in-oil type emulsion composition comprising an aqueous phase of from 70-90% by weight comprising water 10-30%, oxidizing salt 50-75%, an oil phase 5-20%, an air entrapping material 1-5% and an emulsifying agent 1-5%. Nitropropanes constitute all or a portion of the fuel component.
Description
This invention relates to an explosive emulsion composition. In a particular aspect, this invention relates to an explosive emulsion composition containing a nitroalkane.
Water-in-oil type of emulsions are very useful blasting agents in the explosives art because such emulsions have considerable water resistance. They can, therefore, be used in wet holes where oil-in-water or ANFO type blasting agents would be unsuitable. Also, they offer the advantages of safety and low material cost when compared to conventional high explosives, especially those containing metal particulates as sensitizers.
Although nitromethane is well-known in the explosives art, higher nitroalkanes, especially the nitropropanes, have received considerably less attention. However, it is known from Egly et al, U.S. Pat. No. 3,161,551 to provide water-in-oil emulsions utilizing nitroalkanes. These emulsions were said to be suitable for use in the preparation of blasting agents. Suitable emulsifiers included oxazolines, fatty acid salts of alkaline earth metals, polyoxyethylene derivatives of sorbitol esters and of fatty acids. The emulsions contained 50-70% ammonium nitrate, 15-35% water and 5-20% of an organic liquid including fuel oils and nitroalkanes. The emulsions were then mixed with additional ammonium nitrate to produce the blasting agent. However, according to R. B. Clay, U.S. Pat. No. 4,111,727, compositions of this type were found not to be reliably detonable without being gassed or aerated. Minnick, in U.S. Pat. No. 3,338,165, taught the preparation of gels using, among other ingredients, nitromethane and air-entrapping materials and in U.S. Pat. No. 3,419,444 taught the preparation of aqueous slurries in which gelled nitroalkanes were dispersed. Other workers have disclosed water-in-oil type emulsions useful as explosives, but none of them taught nitropropane-containing emulsions.
There is, therefore, a need for water-in-oil type of blasting agents wherein the nitropropanes can be used as a portion of the fuel.
It is an object of this invention to provide an explosive emulsion composition.
It is another object of this invention to provide an explosive emulsion composition containing a nitropropane.
Other objects of this invention will be apparent to those skilled in the art from the disclosure herein.
An explosive emulsion composition of the water-in-oil variety has been discovered wherein the water phase comprises about 70-90% by weight of the emulsion and oil phase comprises about 5 to about 20%. The water phase comprises an aqueous solution of oxidizing salts and the oil phase comprises the fuel portion. The composition also includes sufficient emulsifying agent to produce a suitable emulsion and one or more sensitizers.
The composition of the present invention generally comprises an aqueous phase of from about 70-90% by weight, an oil phase of from about 5-20%, a thickener 0-4%, emulsifiers 1.0 to 8.0%, and one or more sensitizers 0.5-6%.
The composition is generally prepared by preparing the aqueous phase and the oil phase separately, then adding the aqueous phase slowly to the oil phase with a high degree of agitation, such as by means of a high sheer mixer. A sensitizer, such as an entrapped gas component, e.g., hollow microspheres (e.g. Microballoons) or perlite, is then added and well mixed.
The aqueous phase comprises an aqueous solution of an oxidizing salt, such as alkali and alkaline earth nitrates and perchlorates, ammonium perchlorate, ammonium nitrate, or mixtures thereof. Generally, the aqueous phase is comprised of about 5-35% water and 50-90% of oxidizing salt. Preferably, the oxidizing salt portion comprises 50-75% of the mixture with 50-75% water and consists of ammonium nitrate or a mixture of ammonium nitrate with up to about 20% sodium nitrate and/or calcium nitrate, preferably about 10% of sodium nitrate (based on the total emulsion). The ammonium nitrate is preferably supplied as the 83% aqueous solution, which is commercially available, and additional water is added as needed.
The oil phase, which comprises from 5-20% of the finished emulsion, supplies the fuel portion of the explosive. Suitable ingredients include coal, paraffin wax, fuel oil (e.g. No. 2 or No. 5) and nitropropane or mixtures thereof. Nitropropane, which can be 1- or 2-nitropropane, is a preferred fuel ingredient and is usually present, though not necessarily so, in an amount of from 1 to about 20% based on the finished emulsion. Nitropropanes are preferred because they produce better density, improved detonation rate and less negative oxygen balance. Coal, when used, is generally used along with paraffin and oil, e.g. No. 5 oil, in an amount of 1%. Paraffin, when used, is generally present in an amount up to about 6%. Fuel oil is used in an amount up to about 8%. Other fuel ingredients include other hydrocarbons, such as olefins, aromatics, alkanes in general, waxes in general, and fatty acid triglycerides.
If desirable, a thickener, up to about 4%, can be added to the fuel portion, especially with nitropropane. Any thickener useful in the explosives art can be used. Suitable thickeners include but are not limited to cellulose acetatebutyrate and polystyrene.
Any art-recognized water-in-oil emulsifying agent may be used in the practice of this invention including lecithin, fatty acid esters of polyoxyethylene alcohols or sorbitan, lignosulfonates, alkali metal soaps of fatty acids. Lecithin is a preferred emulsifying agent. It is used in the range of 0.1-15%, preferably 1-8%. The lecithin can be either the solid or liquid form including any of the water, acetone, or alcohol soluble forms. Suitable sources include commercial soybean lecithin. The unbleached liquid form is the most economical and hence is particularly preferred.
As is known in the art, emulsions must usually be sensitized to perform satisfactorily. Many such sensitizers are known and are useful in the practice of this invention. Such sensitizers include air-entrapping materials such as wood pulp, bagasse, celite, preferably aluminum flakes or hollow microspheres or perlite. The amount of sensitizer used is generally in the range of 0.5-6%, usually 2-4%, depending on the sensitivity of the formulation. Hollow microspheres are preferred.
The invention will be better understood with reference to the following examples. It is understood that these examples are intended only to illustrate the invention and it is not intended that it be limited thereby.
The following emulsions were prepared by art-recognized methods. They had good density and were all cap or booster sensitive. The rate of detonation in 21/4 inch diameter was above 5000 m/second. In the following examples, the booster, when used, was Pentolite.
__________________________________________________________________________
EXAMPLE
1 2 3 4 5 6 7 8 9 10 11 12
__________________________________________________________________________
Aqueous Phase, %
86.00
88.00
89.10
86.00
88.00
87.00
82.50
83.5
84.50
71.3
75.00
86.00
Oxidizers, %
71.38
73.04
73.95
71.38
73.04
72.21
68.48
72.4
54.97
52.58
51.67
60.95
AN 71.38
73.04
73.95
71.38
73.04
72.21
68.48
54.72
37.47
42.58
51.67
50.95
NaNO.sub.3 -- -- -- -- -- -- -- 18.18
-- 10.00
-- 10.00
Ca(NO.sub.3).sub.2
-- -- -- -- -- -- -- -- 17.50
-- -- --
Water, % 14.62
14.96
15.15
14.62
14.96
14.79
14.02
11.1
29.53
18.72
23.33
25.05
Water, added
-- -- -- -- -- -- -- -- 14.36
10.00
12.75
14.62
Water, from AN
14.62
14.96
15.15
14.62
14.96
14.79
14.02
11.1
7.67
8.72
10.58
10.43
Water, from Ca Nit
-- -- -- -- -- -- -- -- 7.5
-- -- --
Oil Phase, %
9.0
9.0
7.92
11.0
9.0
10.0
14.0
13.0
12.0
19.80
17.00
8.00
Paraffin 3.0
2.0
-- -- 5.0
3.0
3.0
3.0
5.0
-- 3.00
4.00
Oil #2 3.0
3.0
-- 1.0
-- -- -- -- -- -- -- --
Oil #5 2.0
1.0
-- -- 1.0
1.0
1.0
-- -- -- -- --
Nitropropane
1.0
3.0
7.92
10.0
3.0
6.0
10.0
10.0
7.00
19.80
14.00
4.00
Lecithin, % 1.0
1.0
1.0
1.0
1.0
1.0
1.5
1.5
1.5
2.00
5.00
4.00
Microballoons, %
4.0
2.0
1.98
2.0
2.0
2.0
2.0
2.0
2.0
3.00
2.0
2.0
Total, % 100
100
100
100
100
100
100
100
100
100
100
100
PROPERTIES
Density 1.14
1.27
1.27
1.27
1.20
1.20
1.21
1.28
1.27
1.22
-- --
Sensitivity 5 g
#16
3 g
3 g
3 g
3 g
5 g+
5 g+
10 g
#10
50 g
50 g
cap cap
Detonation rate, m/sec
2" diameter*
4174
-- 5275
-- -- -- -- -- -- 4857
-- --
11/2" steel pipe
-- -- -- -- 5826
6094
-- -- -- -- -- --
__________________________________________________________________________
*Unconfined
Claims (9)
1. A water-in-oil emulsion explosive composition consisting essentially of (a) an aqueous phase comprised of a solution of oxidizing salts, (b) an oil phase consisting essentially of a nitroparaffin having three carbon atoms and optionally a hydrocarbon, (c) an emulsifying agent, and (d) at least one sensitizing agent.
2. The composition of claim 1 wherein the aqueous phase contains 5-35% water and 50-90% oxidizing salt, based on the composition as a whole.
3. The composition of claim 2 wherein the oxidizing salt is ammonium nitrate or a mixture thereof with sodium nitrate or calcium nitrate.
4. The composition of claim 3 wherein the oxidizing salt is a mixture of ammonium nitrate 40-55% and sodium nitrate 10-18% based on the total weight of the mixture.
5. The composition of claim 1 wherein the oil phase consists essentially of, based on the weight of the final emulsion, a nitropropane from about 1.0 wt.% to about 20.0 wt.%, paraffin wax from about 0 wt.% to about 5 wt.%, and a liquid hydrocarbon from about 0 wt.% to about 3 wt.%.
6. The composition of claim 1 wherein the emulsifying agent is provided by lecithin 1.0-8.0%.
7. The composition of claim 1 wherein the sensitizing agent is provided by hollow microspheres, 0.5-6%.
8. A water-in-oil emulsion explosive composition consisting essentially of (a) from about 70 wt.% to about 90 wt.%, based on the weight of the final emulsion, aqueous phase comprised of a solution of oxidizing salts, (b) from about 5 wt.% to about 20 wt.% oil phase, said oil phase essentially free of gelatinizing agent, comprising from about 1 wt.% to about 20 wt.%, based on the weight of the final emulsion, of a nitroparaffin having three carbon atoms, (c) from about 1 wt.% to about 8 wt.% of an emulsifying agent and (d) from about 0.5 to about 6 wt.% sensitizing agent.
9. The composition of claim 1 wherein the oil phase consists essentially of, based on the weight of the final emulsion, from about 1.0 wt.% to about 20.0 wt.% of a nitropropane, from about 0 wt.% to about 5 wt.% paraffin wax, and from about 0 wt.% to about 3 wt.% of a liquid hydrocarbon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/299,742 US4394199A (en) | 1981-09-08 | 1981-09-08 | Explosive emulsion composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/299,742 US4394199A (en) | 1981-09-08 | 1981-09-08 | Explosive emulsion composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US4394199A true US4394199A (en) | 1983-07-19 |
Family
ID=23156097
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US06/299,742 Expired - Lifetime US4394199A (en) | 1981-09-08 | 1981-09-08 | Explosive emulsion composition |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US4394199A (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4698105A (en) * | 1986-01-14 | 1987-10-06 | Nippon Kayaku Kabushiki Kaisha | Water-in-oil type emulsion explosives |
| GB2225572A (en) * | 1988-12-05 | 1990-06-06 | Canadian Ind | Nitroalkane-based emulsion explosive composition: |
| GB2243827A (en) * | 1988-08-10 | 1991-11-13 | Canada Minister Defence | Foamable explosive compositions |
| US20040144456A1 (en) * | 2003-01-28 | 2004-07-29 | Waldock Kevin H. | Explosive Composition, Method of Making an Explosive Composition, and Method of Using an Explosive Composition |
| AU782257B2 (en) * | 1999-09-24 | 2005-07-14 | Stryker European Operations Limited | Method and apparatus for performing intra-operative angiography |
| US20080071176A1 (en) * | 1999-09-24 | 2008-03-20 | National Research Council Of Canada | Method and apparatus for performing intra-operative angiography |
| US9421280B2 (en) | 2005-04-26 | 2016-08-23 | Novadaq Technologies Inc. | Real time imaging during solid organ transplant |
| CN106243323A (en) * | 2016-07-28 | 2016-12-21 | 东北林业大学 | A kind of Salt And Alkali Tolerance height inhales the preparation method of the carboxymethyl cellulose-based sustained-release micro-spheres of fertilizer |
| US9610021B2 (en) | 2008-01-25 | 2017-04-04 | Novadaq Technologies Inc. | Method for evaluating blush in myocardial tissue |
| US9816930B2 (en) | 2014-09-29 | 2017-11-14 | Novadaq Technologies Inc. | Imaging a target fluorophore in a biological material in the presence of autofluorescence |
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| US10278585B2 (en) | 2012-06-21 | 2019-05-07 | Novadaq Technologies ULC | Quantification and analysis of angiography and perfusion |
| US10434190B2 (en) | 2006-09-07 | 2019-10-08 | Novadaq Technologies ULC | Pre-and-intra-operative localization of penile sentinel nodes |
| US10492671B2 (en) | 2009-05-08 | 2019-12-03 | Novadaq Technologies ULC | Near infra red fluorescence imaging for visualization of blood vessels during endoscopic harvest |
| CN110615726A (en) * | 2019-10-31 | 2019-12-27 | 浏阳金科新材料有限公司 | Special composite oil phase for anti-freezing emulsion explosive and preparation method and application thereof |
| US10631746B2 (en) | 2014-10-09 | 2020-04-28 | Novadaq Technologies ULC | Quantification of absolute blood flow in tissue using fluorescence-mediated photoplethysmography |
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|---|---|---|---|---|
| US3161551A (en) * | 1961-04-07 | 1964-12-15 | Commercial Solvents Corp | Ammonium nitrate-containing emulsion sensitizers for blasting agents |
| US3338165A (en) * | 1966-08-11 | 1967-08-29 | Commercial Solvents Corp | Gelled nitromethane explosive containing fluid encapsulations |
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| GB2243827B (en) * | 1988-08-10 | 1994-05-11 | Canada Minister Defence | Foamable explosive compositions |
| GB2225572A (en) * | 1988-12-05 | 1990-06-06 | Canadian Ind | Nitroalkane-based emulsion explosive composition: |
| EP0372739A3 (en) * | 1988-12-05 | 1991-08-07 | C-I-L Inc. | Nitroalkane - based emulsion explosive composition |
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