US3897357A - Bacteriostatic toilet bowl cleaner compositions - Google Patents

Bacteriostatic toilet bowl cleaner compositions Download PDF

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Publication number
US3897357A
US3897357A US312767A US31276772A US3897357A US 3897357 A US3897357 A US 3897357A US 312767 A US312767 A US 312767A US 31276772 A US31276772 A US 31276772A US 3897357 A US3897357 A US 3897357A
Authority
US
United States
Prior art keywords
composition according
water
chloro
phenol
dichlorophenoxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US312767A
Other languages
English (en)
Inventor
Robert Carmello
Barry A Salka
Garland G Corey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reckitt and Colman Subsidiary Corp
Original Assignee
American Home Products Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Home Products Corp filed Critical American Home Products Corp
Priority to US312767A priority Critical patent/US3897357A/en
Priority to CA186,169A priority patent/CA1001919A/en
Priority to AU62742/73A priority patent/AU485839B2/en
Priority to IE2241/76A priority patent/IE38534B1/xx
Priority to IE211273A priority patent/IE38533B1/xx
Priority to CH1678573A priority patent/CH606412A5/de
Priority to JP13565973A priority patent/JPS4986535A/ja
Priority to DE2360330A priority patent/DE2360330C3/de
Priority to GB5612773A priority patent/GB1446069A/en
Priority to FR7343261A priority patent/FR2209588B1/fr
Priority to GB154976A priority patent/GB1446070A/en
Priority to BE138612A priority patent/BE808329A/xx
Priority to US05/560,898 priority patent/US3970576A/en
Publication of US3897357A publication Critical patent/US3897357A/en
Application granted granted Critical
Priority to HK30977A priority patent/HK30977A/xx
Priority to HK30877A priority patent/HK30877A/xx
Priority to JP14146977A priority patent/JPS5386019A/ja
Assigned to BOYLE-MIDWAY HOUSEHOLD PRODUCTS, INC., A CORP. OF DE. reassignment BOYLE-MIDWAY HOUSEHOLD PRODUCTS, INC., A CORP. OF DE. ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: AMERICAN HOME PRODUCTS CORPORATION, A DE. CORP.
Assigned to RECKITT & COLMAN SUBSIDIARY CORPORATION reassignment RECKITT & COLMAN SUBSIDIARY CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: BOYLE-MIDWAY HOUSEHOLD PRODUCTS, INC., A CORP OFF DE
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/16—Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system

Definitions

  • ABSTRACT New automatic toilet bowl cleaner compositions that are capable of inhibiting the growth or multiplication of microbiological organisms are described herein.
  • the bacteriostatic agent in the above compositions is 5-chloro-2-(2,4-dich1orophenoxy)phenol.
  • Ingrcdient By Weight Isopropanol 10-20 5-chloro-2-( 2,4-dichlorophenoxy )phenol 0.5-6 Alkoxylated primary fatty alcohol 0.1-20 Linear Alkyl Aryl Sulfonate Salt I 05-20 Sodium hydroxide -2 Water, Dye, Perfume Sufficient to make up to 100%
  • the preferred formula for an effective liquid cleaning and bacteriostatic composition is as follows:
  • the liquid compositions of this invention have the'ability to exhibit bacteriostatic properties at use levels as low as 0.2 parts per million of the anti-microbial.
  • Thesolid compositions exhibit bacteriostatic properties at use levels as low as 0.1 parts per million of the antimicrobial.
  • the examples will also indicate the antimicrobial agents known in the prior art are either ineffective or are not readily or efficiently compounded or solubilized.
  • the bacteria employed as the test organisms are representative of both gram negative and gram positive'bacteria.
  • the test procedure employed is the Agar Plate Test and the Agar Cup Plate Test as described in U.S.D.A.circular No'. 198, 1931. The results are reported as zones of inhibition and measured in millimeters.
  • EXAMPLE 1 Sufiicient to make Water, Dye, Perfume :up to I007! 3 4 Average Zone of Inhibition (mm) Dilution l:23,000 -Continued Ingredient By Weight T070 propylene oxide S. aureus [5. col! P. mirabllis of a near alcohol whose carbon chain length is C ,-C Agar P Plate Test 10 5 3 5 Water, Dye. Perfume Sufficient to Agar Plate Test 5 2 1 make up to A preferred alternate formulation is represented by Example 2.
  • EXAMPLE 4 S. aureus E. coli Agar Cup Plate Test 10 4 Ingredient By Weight (Partial) Isopropanol (99%) C 7 C d 450 l 3 7 5 g fifgflf gg g g flg i ffi 5,00
  • This example illustrates another antimicrobial agent n-Alkyl (68% 12. 32 i y 5 00 which requires high levels of solubilizers and which re- Ethylbenzyl Ammomum chlonde sults in only a partial zone of inhibition at the high level 50% ethylene oxide l0)? propylene oxide uddlict employed.
  • EXAMPLE 7 Ingredient Ey Weight Alkyl pyridinium 5-chloro-2-mercapto- 3 12.00 benzothiazole (96%) N-methgl-Z-pyrrolidone 60.00 Octyl p enoxy poly (ethyleneoxy) ethanol 10.00 Water 18.00
  • EXAMPLE 9 This Example illustrates the use of -chloro-2-(2,4- dichlorophenoxy)phenol in the following liquid formulation where it is present at 0.50% by weight in a use dilution of 1:23,000 and 1:40.000.
  • EXAMPLE 1 1 Component By Weight Ethoxylated Alcohol Adduct 31.00 Polyethylene Glycol (mol. wt. about 6000) 5.00 Oxyethylated Alcohol Surfactant 5.00- 3,4',5 Tribromosalicylanilide 2.50 Sodium Sulfate 54.00
  • EXAMPLE 1 2 The following data represents the ability of the preferred compositions of this invention to help retard stain buildup on a ceramic surface immersed in a solution containing an iron salt. Results are reported as units of stain pickup on white ceramic tiles. Less than 1 unit difference is visible to the-naked eye.
  • a method for preventing the growth ormultiplication of E. Coli in toilet bowls which comprises dispensing into the water of a toilet an antibacterial liquid composition consisting essentially of:
  • An antibacterial liquid composition consisting essentially of:
  • 5-chloro-2-(2,4-dichlorophenoxy)phenol is present at a use dilution level in amounts of about 0.2 parts per million to less than 0.7 parts per million and wherein the alkyl chain length of the alkoxylated primary alcohol is from about 12 carbon atoms to about 18 carbon atoms.
  • a method for preventing the growth or multiplication of S. Aureus,., P.-Mirabilis and E. Coli in toilet bowls which comprises dispensing the composition of claim 2 into the water of a toilet to prevent such growth.
  • 8'. A composition according to claim 2 wherein 5- chloro-2-(2,4-dichlorophenoxy)phenol has a lower limit'ofabout l.'l"pe'rcent;v P 1 9.
  • An antibacterialliq'uid composition consisting essentially of:
US312767A 1972-12-06 1972-12-06 Bacteriostatic toilet bowl cleaner compositions Expired - Lifetime US3897357A (en)

Priority Applications (16)

Application Number Priority Date Filing Date Title
US312767A US3897357A (en) 1972-12-06 1972-12-06 Bacteriostatic toilet bowl cleaner compositions
CA186,169A CA1001919A (en) 1972-12-06 1973-11-19 Bacteriostatic compositions
AU62742/73A AU485839B2 (en) 1972-12-06 1973-11-21 Bacteriostatic compositions
IE2241/76A IE38534B1 (en) 1972-12-06 1973-11-21 Novel antibacterial compositions
IE211273A IE38533B1 (en) 1972-12-06 1973-11-21 Novel antibacterial compositions
CH1678573A CH606412A5 (en) 1972-12-06 1973-11-29 5-Chloro 2-(2,4-dichlorophenoxy) phenol compsns
JP13565973A JPS4986535A (ja) 1972-12-06 1973-12-03
GB5612773A GB1446069A (en) 1972-12-06 1973-12-04 Antibacterial compositions
DE2360330A DE2360330C3 (de) 1972-12-06 1973-12-04 Flüssiges oder festes antimikrobielles Toilettenreinigungsmittel
FR7343261A FR2209588B1 (ja) 1972-12-06 1973-12-04
GB154976A GB1446070A (en) 1972-12-06 1973-12-04 Antibacterial compostiions
BE138612A BE808329A (fr) 1972-12-06 1973-12-06 Compositions bacteriostatiques
US05/560,898 US3970576A (en) 1972-12-06 1975-03-21 Bacteriostatic toilet bowl cleaner compositions
HK30977A HK30977A (en) 1972-12-06 1977-06-16 Novel antibacterial compositions
HK30877A HK30877A (en) 1972-12-06 1977-06-16 Novel antibacterial compositions
JP14146977A JPS5386019A (en) 1972-12-06 1977-11-24 Solid antibacterial composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US312767A US3897357A (en) 1972-12-06 1972-12-06 Bacteriostatic toilet bowl cleaner compositions
US05/560,898 US3970576A (en) 1972-12-06 1975-03-21 Bacteriostatic toilet bowl cleaner compositions

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US05/560,898 Division US3970576A (en) 1972-12-06 1975-03-21 Bacteriostatic toilet bowl cleaner compositions

Publications (1)

Publication Number Publication Date
US3897357A true US3897357A (en) 1975-07-29

Family

ID=26978535

Family Applications (2)

Application Number Title Priority Date Filing Date
US312767A Expired - Lifetime US3897357A (en) 1972-12-06 1972-12-06 Bacteriostatic toilet bowl cleaner compositions
US05/560,898 Expired - Lifetime US3970576A (en) 1972-12-06 1975-03-21 Bacteriostatic toilet bowl cleaner compositions

Family Applications After (1)

Application Number Title Priority Date Filing Date
US05/560,898 Expired - Lifetime US3970576A (en) 1972-12-06 1975-03-21 Bacteriostatic toilet bowl cleaner compositions

Country Status (6)

Country Link
US (2) US3897357A (ja)
BE (1) BE808329A (ja)
CA (1) CA1001919A (ja)
DE (1) DE2360330C3 (ja)
FR (1) FR2209588B1 (ja)
GB (2) GB1446070A (ja)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4043931A (en) * 1973-02-26 1977-08-23 Jeyes Group Limited Lavatory cleansing block
US4124520A (en) * 1977-06-20 1978-11-07 United States Borax & Chemical Corp. Anti-microbial bathroom cleaning compositions containing o-benzyl-4-chlorophenol
US4148869A (en) * 1975-03-06 1979-04-10 Baxter Travenol Laboratories, Inc. Immunological reagent and method of using same
US4253951A (en) * 1978-11-09 1981-03-03 The Procter & Gamble Company Method of reducing aerosolization of wastewater
US4310434A (en) * 1980-05-28 1982-01-12 The Procter & Gamble Company Poly(ethylene oxide) compositions with controlled solubility characteristics
US4396522A (en) * 1981-05-13 1983-08-02 The Proctor & Gamble Company Polyethylene oxide cake with reduced gelling for flush toilet wastewater sanitation
DK152378B (da) * 1976-01-13 1988-02-22 United States Borax Chem Antimikrobielle rengoeringspraeparater
US5049299A (en) * 1989-10-26 1991-09-17 Kiwi Brands Incorporated Liquid lavatory cleansing and sanitizing composition
US5256328A (en) * 1992-12-16 1993-10-26 Eastman Kodak Company Liquid toilet bowl cleaner and sanitizer containing halogen donating nanoparticles
US5837274A (en) * 1996-10-22 1998-11-17 Kimberly Clark Corporation Aqueous, antimicrobial liquid cleaning formulation
US6066293A (en) * 1995-10-20 2000-05-23 Chemia Corporation Method using 5-chloro-2-(2,4-dichlorophenoxy)phenol for deodorizing toilets
US20030148913A1 (en) * 2001-10-11 2003-08-07 Klinkhammer Michael E. Hard surface cleaners which provide improved fragrance retention properties to hard surfaces
US20040172741A1 (en) * 2003-03-04 2004-09-09 Troost Erik Herman Toilet rim block holder
US20060128585A1 (en) * 2004-12-15 2006-06-15 Martha Adair Antimicrobial composition for cleaning substrate

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4111844A (en) * 1975-12-15 1978-09-05 Ciba-Geigy Corporation Synergistic microbicidal composition
US4218432A (en) * 1977-06-28 1980-08-19 Yamamoto Kagaku Gosei Co., Ltd. Coloring agent and a composition including the same for coloring toilet bowl flushing water
DE2907029A1 (de) * 1979-02-23 1980-09-04 Henkel Kgaa Verfahren zur herstellung von abspuelbloecken fuer die toilettenhygiene
GB2126894B (en) * 1982-09-17 1986-09-03 Auchincloss Thomas R Disinfectant composition
EP0259249A3 (de) * 1986-07-23 1990-09-19 Ciba-Geigy Ag Mikrobizide Zubereitung

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3173875A (en) * 1961-11-09 1965-03-16 Wyandotte Chemicals Corp Acid bowl cleaner
US3318815A (en) * 1965-07-21 1967-05-09 Drackett Co Germicidal toilet bowl cleaning composition
US3503885A (en) * 1965-11-27 1970-03-31 Henkel & Cie Gmbh Color stable washing,rinsing and cleaning composition
US3650964A (en) * 1968-05-13 1972-03-21 Basf Wyandotte Corp Low foam anionic acid sanitizer compositions
US3700601A (en) * 1968-09-11 1972-10-24 Henkel & Cie Gmbh Color-stable liquid detergent containing disinfectants
US3721629A (en) * 1969-05-21 1973-03-20 Dow Chemical Co Method and composition for removing iron stains from porcelain
US3738943A (en) * 1970-12-18 1973-06-12 Basf Wyandotte Corp Biodegradable detergent for automatic car wash systems
US3762875A (en) * 1970-05-12 1973-10-02 H Burmeister Odor sealing method

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2497057A (en) * 1950-02-07 Toilet bowl -gleanee
US3504384A (en) * 1963-10-23 1970-04-07 Russell Research Ltd Toilet bowl cleaning and disinfecting device
DK123107A (ja) * 1967-04-27
US3545014A (en) * 1968-02-05 1970-12-08 Elbert Davis Sanitizers
US3630925A (en) * 1968-03-11 1971-12-28 Arrowhead Ind Inc Deodorant and germicidal bodies for toilets and urinals

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3173875A (en) * 1961-11-09 1965-03-16 Wyandotte Chemicals Corp Acid bowl cleaner
US3318815A (en) * 1965-07-21 1967-05-09 Drackett Co Germicidal toilet bowl cleaning composition
US3503885A (en) * 1965-11-27 1970-03-31 Henkel & Cie Gmbh Color stable washing,rinsing and cleaning composition
US3650964A (en) * 1968-05-13 1972-03-21 Basf Wyandotte Corp Low foam anionic acid sanitizer compositions
US3700601A (en) * 1968-09-11 1972-10-24 Henkel & Cie Gmbh Color-stable liquid detergent containing disinfectants
US3721629A (en) * 1969-05-21 1973-03-20 Dow Chemical Co Method and composition for removing iron stains from porcelain
US3762875A (en) * 1970-05-12 1973-10-02 H Burmeister Odor sealing method
US3738943A (en) * 1970-12-18 1973-06-12 Basf Wyandotte Corp Biodegradable detergent for automatic car wash systems

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4043931A (en) * 1973-02-26 1977-08-23 Jeyes Group Limited Lavatory cleansing block
US4148869A (en) * 1975-03-06 1979-04-10 Baxter Travenol Laboratories, Inc. Immunological reagent and method of using same
DK152378B (da) * 1976-01-13 1988-02-22 United States Borax Chem Antimikrobielle rengoeringspraeparater
US4124520A (en) * 1977-06-20 1978-11-07 United States Borax & Chemical Corp. Anti-microbial bathroom cleaning compositions containing o-benzyl-4-chlorophenol
US4253951A (en) * 1978-11-09 1981-03-03 The Procter & Gamble Company Method of reducing aerosolization of wastewater
US4310434A (en) * 1980-05-28 1982-01-12 The Procter & Gamble Company Poly(ethylene oxide) compositions with controlled solubility characteristics
US4396522A (en) * 1981-05-13 1983-08-02 The Proctor & Gamble Company Polyethylene oxide cake with reduced gelling for flush toilet wastewater sanitation
US5049299A (en) * 1989-10-26 1991-09-17 Kiwi Brands Incorporated Liquid lavatory cleansing and sanitizing composition
US5256328A (en) * 1992-12-16 1993-10-26 Eastman Kodak Company Liquid toilet bowl cleaner and sanitizer containing halogen donating nanoparticles
US6066293A (en) * 1995-10-20 2000-05-23 Chemia Corporation Method using 5-chloro-2-(2,4-dichlorophenoxy)phenol for deodorizing toilets
US5837274A (en) * 1996-10-22 1998-11-17 Kimberly Clark Corporation Aqueous, antimicrobial liquid cleaning formulation
US20030148913A1 (en) * 2001-10-11 2003-08-07 Klinkhammer Michael E. Hard surface cleaners which provide improved fragrance retention properties to hard surfaces
US6786223B2 (en) 2001-10-11 2004-09-07 S. C. Johnson & Son, Inc. Hard surface cleaners which provide improved fragrance retention properties to hard surfaces
US20040172741A1 (en) * 2003-03-04 2004-09-09 Troost Erik Herman Toilet rim block holder
US20060128585A1 (en) * 2004-12-15 2006-06-15 Martha Adair Antimicrobial composition for cleaning substrate

Also Published As

Publication number Publication date
FR2209588B1 (ja) 1977-08-05
GB1446070A (en) 1976-08-11
GB1446069A (en) 1976-08-11
DE2360330C3 (de) 1978-10-26
CA1001919A (en) 1976-12-21
FR2209588A1 (ja) 1974-07-05
DE2360330A1 (de) 1974-06-12
DE2360330B2 (de) 1978-02-16
AU6274273A (en) 1975-05-22
US3970576A (en) 1976-07-20
BE808329A (fr) 1974-06-06

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Date Code Title Description
STCF Information on status: patent grant

Free format text: PATENTED FILE - (OLD CASE ADDED FOR FILE TRACKING PURPOSES)

AS Assignment

Owner name: BOYLE-MIDWAY HOUSEHOLD PRODUCTS, INC., 685 THIRD A

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:AMERICAN HOME PRODUCTS CORPORATION, A DE. CORP.;REEL/FRAME:004725/0166

Effective date: 19870513

AS Assignment

Owner name: RECKITT & COLMAN SUBSIDIARY CORPORATION, NEW JERSE

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:BOYLE-MIDWAY HOUSEHOLD PRODUCTS, INC., A CORP OFF DE;REEL/FRAME:005403/0343

Effective date: 19900629