Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
  • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
  • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
  • C08G63/682—Polyesters containing atoms other than carbon, hydrogen and oxygen containing halogens
  • C08G63/6824—Polyesters containing atoms other than carbon, hydrogen and oxygen containing halogens derived from polycarboxylic acids and polyhydroxy compounds
  • C08G63/6828—Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation

Definitions

• the object of this invention is to provide a technologically simple method for the production of polyarylate films and coatings which apart from a high thermoresistance, and good mechanical, optical and dielectric properties are also resistant against the action of chemical reagents, primarily against organic solvents.
• the process according to this invention refers to polyarylates containing in the normal chain a group 'in which the carbon atom between two aryl rings with substituents or without substituents is connected by a double bond to a CCl group.
• Such polyarylates are obtainable by the polycondensation of chlorobisphenols or their mixture or of a mixture of chlorobisphenols with bis(hydroxyaryl)alkanes and dicarboxylic acid chlorides or their mixtures, or dicarboxylic acid esters or their mixtures.
• polyarylates obtained by polycondensation of chlorobisphenol diesters or their mixtures or of mixtures of chlorobisphenol diesters with diesters of bis(hydroxyaryl)alkanes and dicarboxylic acids or their mixtures.
• At least one of these chlorobisphenols and respectively, at least one of the chlorobisphenol diesters has a group in which the carbon atom between two aryl rings with substituents or without substituents is connected by a double bond to a CCl group.
• chlorobisphenols may be used: 2,2-bis(4-hydroxyphenyl l l -dichloroethylene; 2,2- bis( 3 ,5-dichloro-4 hydroxyphenyl I l dichloroethylene; 2,2-bis(3-methyl-4-hydroxyphenyl)- l,l-dichloroethyle ne or 2,2-bis(4-hydroxynaphthyl)- 1,l-dichloroethylene or acetates of these chlorobisphenols.
• bis(hydroxyaryl) alkanes bis(hydroxyphenyl)- alkanes
• bis(hydroxynaphthypalltanes, phthaleins or anthrahydroquinones may be used.
• the method according to this invention is characterized by a high technological simplicity and the films and coatings obtained, apart from good mechanical, dielectric and thermal properties, reveal a very good chemical resistance, particularly in relation to chlorinated aliphatic hydrocarbons.
• the conditioned film was fully resistant to the action of solvents.
• Example III The process of Example III was used except that 3 g of polyarylate was used which had been obtained from a mixture of 2,2-bis(3-methyl-4-hydroxyphenyl)-1,1- dichloroethylene with 2,2-bis(4- hydroxynaphthyl)methane and a mixture of terephthalic acid methyl ester and isophthalic acid methyl ester.
• a process for the manufacture ofa chemical resistant, self-extinguishing polyarylate film or coating formed from a polyarylate based on a chlorobisphenol or ester thereof in which the carbon atom between two aryl rings with substituents or without substituents is connected by a double bond to a CCl group comprising subjecting said film or coating to a temperature of 320C for l to 10 hours.
• polyarylate is the condensation product of said chlorobisphenol or a mixture of said chlorobisphenol with a bis(hydroxyaryl)alkane and at least one dicarboxylic acid chloride or ester.
• a process according to claim 2 wherein the bis( hydroxyaryl)alkane is selected from the group consisting of bis(hydroxyphenybalkanes, bis(hydroxynaphthyl)- allgarres phthaleins and anthrahydroquinones.
• chlorobisphenol is a mixture of 2,2-bis(4-hydroxyphenyl)- l,l-dichloroethylene and 2,2-bis(4-hydroxyphenol)- propane.

Landscapes

• Chemical & Material Sciences (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Organic Chemistry (AREA)
• Polyesters Or Polycarbonates (AREA)

Applications Claiming Priority (2)

Publications (1)

Family

ID=26652846

Family Applications (1)

Country Status (8)

Cited By (3)

Citations (4)

• 0
  • BE BE795743D patent/BE795743A/xx unknown
• 1973
  • 1973-02-20 FR FR7305897A patent/FR2175761B1/fr not_active Expired
  • 1973-02-22 GB GB863173A patent/GB1395862A/en not_active Expired
  • 1973-02-28 NL NL7302819.A patent/NL160586C/xx active
  • 1973-03-08 US US00339053A patent/US3856556A/en not_active Expired - Lifetime
  • 1973-03-13 DD DD169404A patent/DD102393A5/xx unknown
  • 1973-03-14 HU HUPO533A patent/HU165595B/hu unknown
  • 1973-03-14 SE SE7303566A patent/SE379775B/xx unknown

Patent Citations (4)

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