US3838495A - Method of forming closed sheet metal structures with an internal corrosion-resistant coating - Google Patents

Method of forming closed sheet metal structures with an internal corrosion-resistant coating Download PDF

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Publication number
US3838495A
US3838495A US00237637A US23763772A US3838495A US 3838495 A US3838495 A US 3838495A US 00237637 A US00237637 A US 00237637A US 23763772 A US23763772 A US 23763772A US 3838495 A US3838495 A US 3838495A
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US
United States
Prior art keywords
coating
welding
sheet metal
steel
sheets
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00237637A
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English (en)
Inventor
A Kuhnert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayerische Motoren Werke AG
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Bayerische Motoren Werke AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayerische Motoren Werke AG filed Critical Bayerische Motoren Werke AG
Application granted granted Critical
Publication of US3838495A publication Critical patent/US3838495A/en
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/12—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by mechanical means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B62—LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
    • B62D—MOTOR VEHICLES; TRAILERS
    • B62D25/00—Superstructure or monocoque structure sub-units; Parts or details thereof not otherwise provided for
    • B62D25/02—Side panels
    • B62D25/025—Side sills thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B62—LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
    • B62D—MOTOR VEHICLES; TRAILERS
    • B62D25/00—Superstructure or monocoque structure sub-units; Parts or details thereof not otherwise provided for
    • B62D25/20—Floors or bottom sub-units
    • B62D25/2009—Floors or bottom sub-units in connection with other superstructure subunits
    • B62D25/2036—Floors or bottom sub-units in connection with other superstructure subunits the subunits being side panels, sills or pillars
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B62—LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
    • B62D—MOTOR VEHICLES; TRAILERS
    • B62D25/00—Superstructure or monocoque structure sub-units; Parts or details thereof not otherwise provided for
    • B62D25/20—Floors or bottom sub-units
    • B62D25/2072—Floor protection, e.g. from corrosion or scratching
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/49826—Assembling or joining
    • Y10T29/49885—Assembling or joining with coating before or during assembling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/4998—Combined manufacture including applying or shaping of fluent material
    • Y10T29/49982—Coating

Definitions

  • This invention provides a method of forming partially or completely closed sheet metal structures having a corrosion-resistant coating on the internal surface thereof by welding together shaped sheet metal parts to join the structure.
  • the parts are formed from unshaped sheet metal stock having on at least one side thereof a coating of a coating material having a high content of one or more metals and/or graphite.
  • the coating material is resistant to deepdrawing, is electrically conductive and is suitable for welding.
  • the parts are formed in such a manner that the coated side will form the internal surface of the part in the assembled structure.
  • the object of this invention is to provide a method of forming an even and dense corrosion-resistant layer on the internal surfaces of closed sheet metal structures by simple means and without substantial expenditure of time and labour.
  • a method of forming partially or completely closed sheet metal structures having a corrosion-resistant coating on the internal surface thereof by welding together shaped sheet metal parts to form the structure which comprises forming the parts from unshaped sheet metal stock having on at least one side thereof a coating of a coating material having a high content of at least one material selected from the group consisting of metals and graphite, said coating material being resistant to deep-drawing, electrically conductive and suitable for welding, said parts being formed such'that the coated side will form the internal surface thereof in the assembled structure.
  • FIGURE of the accompanying drawing illustrates a hollow frame for a vehicle floor group, the internal surfaces of which are provided with a corrosion-resistant layer according to the method of this invention.
  • Sheetmetal parts the outer side of which forms a section of the exterior of the superstructure having a multiple layer coating, are expediently produced from sheet metal coated only on one side, whilst those which are so arranged that both sides are covered are preferably produced from sheet metal coated on both sides.
  • the method according to the invention is very easy to carry out and requires no great expenditure, since the raw metal sheets are fully accessible and evenly coated.
  • the coating may be carried out by means of various suitable processes, such as spraying on, pouring on, rolling on, dipping or by electrophoresis.
  • the other side can be covered or pretreated in such a way that it is prevented from being coated.
  • Pretreatments for example, phosphatizing for improving the stability of the anticorrosive layer on the sheet metal parts, are easily carried out.
  • the coating can be carried out immediately before or after another operation, for example, immediately after the finishing pass in the mill before spooling the coils or before packing the flat sheets.
  • Coating materials which have the properties required and have proved particularly suitable are varnishes and paints based on synthetic resins with a content of metal powder, such as zinc powder and aluminium powder, and/or graphite powder.
  • metal powder such as zinc powder and aluminium powder, and/or graphite powder.
  • these materials are also stable to phosphatizing and washing solutions. Consequently, the conventional pretreatment of vehicle superstructures prior to the application of the usual varnish coat can be retained. If the corrosion-resistant layer is applied on one side and the coated side is used as the inner side, then the procedure for applying the paint or varnish coats to the visible outside of the superstructural parts is also not affected in any way.
  • the coating materials preferably contain at least 50 per cent by weight of metal and/or graphite powder.
  • Particularly suitable coating materials comprise a binder mixture which can be cured by stoving and which consists of from 60 to per cent by weight of an epoxy resin containing free hydroxyl groups and having an OH number of from 0.35 to 0.50 mol OH/ g resin and of from 40 to 5 per cent by weight of polyfunctional compound which reacts with hydroxyl groups but does not react or virtually does not react with itself, such as poly-isocyanates, thioplasts of fully blocked aminoplasts; if desired, accelerators and solvents for the binder may be included.
  • a corrosion-resistant layer is rolled on to raw or pretreated deep-drawing sheet metal on one side during respooling of coils and stoved immediately afterwards at a temperature of about 200 to 250C.
  • the coils ready for further processing by deep-drawing then have an uninterrupted unilateral corrosion-resistant layer extending over their whole length.
  • the material for this layer is a zinc dust paint of the following composition: 51.0 parts by weight of zinc dust Z-620, spherical, degree of fineness 2-4p. zinc content; at least 95 percent of metalliczinc;
  • This zinc dust paint is applied in a layer of from to 30p. thickness.
  • the coated side is so arranged that it forms that side of the sheet metal part, such as the outer part of a door threshold for a vehicle, which will subsequently be internal of the structure.
  • the coatings of the coated inner sides of the sheet metal parts to be connected are in immediate contact.
  • the spot-welded flanges of the unilaterally coated outer part of the door threshold are in contact with spot-welded flanges of an inner part of the door threshold, which may be coated on both sides.
  • the coating Due to the high melting temperature during the welding operation the coating likewise melts and permits immediate contact between the metal sheets, that is to say that the coating recedes in the immediate area of the welding process. When the welded areas cool down, the coating material reseals the metal surface so that the corrosion-resistant layer remains complete even in the welded areas.
  • the electric conductivity of the corrosionresistant layer permits further coating of the internal surfaces of the structure with the aid of auxiliary electrodes arranged in the hollow spaces.
  • the protection from corrosion is thus further increased.
  • the outer sides of the sheet metal parts treated in this way are provided, irrespective of the properties of the corrosion-resistant layer applied to the inner sides, with several varnish coatings, a covering of varnish of undiminished high quality being thus achieved, possible with intermediate polishing operations.
  • FIGURE of the accompanying drawing illustrates a hollow frame for a vehicle floor group, the internal surfaces of which are provided with a corrosion-resistant layer according to the method of this invention.
  • a hollow frame 1 of a vehiclc floor groups consists of two sheet metal parts 2 and 3 which are shaped like hat sections and are connected to each other with the aid of integral flanges 4 by spotweldcd areas 5.
  • the sheet metal part 2 which is arranged in the interior of the vehicle, is coated on both sides with a corrosion-resistant layer 5 cosisting of a coating compound with a high metal content, which has been rolled on and stoved.
  • the sheet metal part 3 on the other hand, which forms which a part 3 of its surface part of the skin of the vehicle, i.e., the door threshold provided with a door groove 3", is provided with the corrosion-resistant layer 6 only on its internal surface.
  • the corrosion-resistant layer 6 extends to the adjacent connecting surface 4 of the flanges 4 and since the spot-welded areas 5 penetrate the corrosionresistant layer 6 only locally. the protection from corrosion in the hollow space 7 of the hollow frame 1 is uninterrupted.
  • the surface of the sheet metal part 3 forming part of the skin with its part 3' can be provided with a multi-layer outer varnish coat after the whole floor group and the superstructure have been assembled.
  • the electrically conductive corrosion-resistant layer 6 can also be provided with an additional coating by electrophoresis, the protection from corrosion being thus further increased.
  • coating material is selected from the group consisting of synthetic resin paints and varnishes.
  • the coating material contains at least percent by weight of at least one material selected from the group comprising aluminium powder, zinc powder and graphite powder.
  • the hardenable bonding agent comprises from to percent by weight of an epoxy resin having free hydroxyl groups and having an OH number of from 0.35 to 0.50 mol OI-I/ g resin and of from 40 to 5 per cent by weight of polyfunctional compound selected from the group comprising poly-isocyanates,' thioplasts and fully blocked aminoplasts.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Transportation (AREA)
  • Body Structure For Vehicles (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Prevention Of Electric Corrosion (AREA)
US00237637A 1971-03-26 1972-03-24 Method of forming closed sheet metal structures with an internal corrosion-resistant coating Expired - Lifetime US3838495A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19712114615 DE2114615B2 (de) 1971-03-26 1971-03-26 Blechhohlkoerper, insbesondere fuer karosserien von kraftfahrzeugen

Publications (1)

Publication Number Publication Date
US3838495A true US3838495A (en) 1974-10-01

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Family Applications (1)

Application Number Title Priority Date Filing Date
US00237637A Expired - Lifetime US3838495A (en) 1971-03-26 1972-03-24 Method of forming closed sheet metal structures with an internal corrosion-resistant coating

Country Status (10)

Country Link
US (1) US3838495A (https=)
JP (1) JPS545565B1 (https=)
BE (1) BE781211A (https=)
DE (1) DE2114615B2 (https=)
ES (1) ES401153A1 (https=)
FR (1) FR2133418A5 (https=)
GB (1) GB1352962A (https=)
IT (1) IT959573B (https=)
NL (1) NL7204059A (https=)
SE (1) SE388637B (https=)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3972111A (en) * 1975-03-13 1976-08-03 Mcdonnell Douglas Corporation Surface preparation method
US4102041A (en) * 1977-03-28 1978-07-25 Amana Refrigeration, Inc. Method of making microwave oven seal structure
US4497876A (en) * 1983-03-16 1985-02-05 Kidon William E Corrosion resistant metal composite with zinc and chromium coating
US4930678A (en) * 1988-11-25 1990-06-05 Cyb Frederick F Heat-resistant exhaust manifold and method of preparing same
US5014903A (en) * 1988-11-25 1991-05-14 Cyb Frederick F Heat-retaining exhaust components and method of preparing same
US5018661A (en) * 1988-11-25 1991-05-28 Cyb Frederick F Heat-resistant exhaust manifold and method of preparing same
WO1997032936A1 (en) * 1996-03-08 1997-09-12 Hunting Industrial Coatings Anti-corrosive coating compositions
US6209884B1 (en) * 1996-11-26 2001-04-03 Robert Bosch Gmbh Radial sealing ring and method for producing it
US20010042393A1 (en) * 2000-04-07 2001-11-22 Ronald Kefferstein Process for the manufacture of a part with very high mechanical properties, formed by stamping of a strip of rolled steel sheet and more particularly hot rolled and coated
US20050266264A1 (en) * 2004-05-27 2005-12-01 Wolfgang Becker Assembly comprised of joined conductive components having cataphoretic paint layer and process for manufacture thereof
CN103511825A (zh) * 2012-06-15 2014-01-15 上海汇众汽车制造有限公司 车架用衬套套管及其成型方法
US9555462B2 (en) 2014-07-14 2017-01-31 GM Global Technology Operations LLC Sheet metal component and manufacturing method therefor
CN110369242A (zh) * 2019-07-26 2019-10-25 马鞍山钢铁股份有限公司 一种防氧化烧损基材的制造工艺及防氧化烧损钢坯制品
CN115464334A (zh) * 2022-07-19 2022-12-13 佑达光电科技(苏州)有限公司 一种电脑外壳及其冲压成型方法
EP4219271A1 (en) * 2022-01-31 2023-08-02 Toyota Jidosha Kabushiki Kaisha Vehicle floor structure and method for manufacturing vehicle
US12239188B2 (en) 2022-07-08 2025-03-04 Puma SE Article of footwear having a textile display system
US12364307B2 (en) 2022-08-01 2025-07-22 Puma SE Article of footwear having a display system

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4805795A (en) * 1986-12-27 1989-02-21 Toyo Seikan Kaisha Ltd. Butt-welded cans and process for manufacturing the same
FR2973262B1 (fr) * 2011-04-04 2013-04-05 Peugeot Citroen Automobiles Sa Procede de protection anticorrosion d'elements de structure d'un vehicule automobile
DE102014226242A1 (de) * 2014-12-17 2016-06-23 Volkswagen Aktiengesellschaft Stahlblechkonstruktion, Fahrzeug mit einer derartigen Stahlblechkonstruktion sowie Verfahren zur Herstellung der besagten Stahlblechkonstruktion

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US181356A (en) * 1876-08-22 Improvement in the processes of making zinc cartridge-cases
US1548514A (en) * 1923-02-26 1925-08-04 Dudzeele Gaston De Treatment of metals to be drawn, wiredrawn, or rolled
US2140131A (en) * 1936-06-27 1938-12-13 Western Electric Co Manufacture of formed articles
US3153990A (en) * 1962-01-26 1964-10-27 Gen Motors Corp Internal combustion engine
US3252215A (en) * 1961-12-06 1966-05-24 Dow Chemical Co Method of coating a magnesium metal article
US3293896A (en) * 1963-06-28 1966-12-27 Teleflex Inc Coated metal article and method of making same
US3689941A (en) * 1969-06-30 1972-09-12 Chausson Usines Sa Method of fabricating and soldering stainless steel parts

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US181356A (en) * 1876-08-22 Improvement in the processes of making zinc cartridge-cases
US1548514A (en) * 1923-02-26 1925-08-04 Dudzeele Gaston De Treatment of metals to be drawn, wiredrawn, or rolled
US2140131A (en) * 1936-06-27 1938-12-13 Western Electric Co Manufacture of formed articles
US3252215A (en) * 1961-12-06 1966-05-24 Dow Chemical Co Method of coating a magnesium metal article
US3153990A (en) * 1962-01-26 1964-10-27 Gen Motors Corp Internal combustion engine
US3293896A (en) * 1963-06-28 1966-12-27 Teleflex Inc Coated metal article and method of making same
US3689941A (en) * 1969-06-30 1972-09-12 Chausson Usines Sa Method of fabricating and soldering stainless steel parts

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3972111A (en) * 1975-03-13 1976-08-03 Mcdonnell Douglas Corporation Surface preparation method
US4102041A (en) * 1977-03-28 1978-07-25 Amana Refrigeration, Inc. Method of making microwave oven seal structure
US4497876A (en) * 1983-03-16 1985-02-05 Kidon William E Corrosion resistant metal composite with zinc and chromium coating
US4930678A (en) * 1988-11-25 1990-06-05 Cyb Frederick F Heat-resistant exhaust manifold and method of preparing same
WO1990006207A1 (en) * 1988-11-25 1990-06-14 Cyb Frederick F Heat-resistant exhaust manifold and method of preparing same
US5014903A (en) * 1988-11-25 1991-05-14 Cyb Frederick F Heat-retaining exhaust components and method of preparing same
US5018661A (en) * 1988-11-25 1991-05-28 Cyb Frederick F Heat-resistant exhaust manifold and method of preparing same
US5677367A (en) * 1995-08-15 1997-10-14 Savin; Ronald R. Graphite-containing compositions
WO1997032936A1 (en) * 1996-03-08 1997-09-12 Hunting Industrial Coatings Anti-corrosive coating compositions
US6209884B1 (en) * 1996-11-26 2001-04-03 Robert Bosch Gmbh Radial sealing ring and method for producing it
US20010042393A1 (en) * 2000-04-07 2001-11-22 Ronald Kefferstein Process for the manufacture of a part with very high mechanical properties, formed by stamping of a strip of rolled steel sheet and more particularly hot rolled and coated
US6564604B2 (en) * 2000-04-07 2003-05-20 Unisor Process for the manufacture of a part with very high mechanical properties, formed by stamping of a strip of rolled steel sheet and more particularly hot rolled and coated
US20050266264A1 (en) * 2004-05-27 2005-12-01 Wolfgang Becker Assembly comprised of joined conductive components having cataphoretic paint layer and process for manufacture thereof
US7144492B2 (en) * 2004-05-27 2006-12-05 Daimlerchrysler Ag Assembly comprised of joined conductive components having cataphoretic paint layer and process for manufacture thereof
CN103511825A (zh) * 2012-06-15 2014-01-15 上海汇众汽车制造有限公司 车架用衬套套管及其成型方法
CN103511825B (zh) * 2012-06-15 2016-03-16 上海汇众汽车制造有限公司 车架用衬套套管及其成型方法
US9555462B2 (en) 2014-07-14 2017-01-31 GM Global Technology Operations LLC Sheet metal component and manufacturing method therefor
CN110369242A (zh) * 2019-07-26 2019-10-25 马鞍山钢铁股份有限公司 一种防氧化烧损基材的制造工艺及防氧化烧损钢坯制品
EP4219271A1 (en) * 2022-01-31 2023-08-02 Toyota Jidosha Kabushiki Kaisha Vehicle floor structure and method for manufacturing vehicle
US12239188B2 (en) 2022-07-08 2025-03-04 Puma SE Article of footwear having a textile display system
CN115464334A (zh) * 2022-07-19 2022-12-13 佑达光电科技(苏州)有限公司 一种电脑外壳及其冲压成型方法
US12364307B2 (en) 2022-08-01 2025-07-22 Puma SE Article of footwear having a display system

Also Published As

Publication number Publication date
DE2114615B2 (de) 1977-10-27
BE781211A (fr) 1972-07-17
JPS545565B1 (https=) 1979-03-19
GB1352962A (en) 1974-05-15
NL7204059A (https=) 1972-09-28
DE2114615A1 (de) 1972-10-05
FR2133418A5 (https=) 1972-11-24
SE388637B (sv) 1976-10-11
ES401153A1 (es) 1975-02-01
IT959573B (it) 1973-11-10

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