[111 3 ,816,920 June 18, 1974 NOVEL CU'I'IING EDGES AND PROCESSES FOR MAKING THEM [75] Inventor: Aiyaswami Suryanarayan Sastri,

Stow, Mass.

[73] Assignee: The Gillette Company, Boston,

Mass.

[22] Filed: Nov. 30, 1972 [21] Appl. No.: 310,931

[51] Int. Cl B26b 21/54 [58] Field of Search 30/346.53, 346.54, 350; 148/1 1.5 F, 162; 29/5275 [56] References Cited UNITED STATES PATENTS 4/1913 Haynes 30/350 UX 12/1967 Smith 29/5275 X 11/1971 Wagner et a1. 148/162 X 2/1972 Owczarski..... 148/162 X 1,103,421 2/1968 Great Britain 30/346.54

Primary Examiner-Charles W. Lanhan Assistant Examiner-D. C. Reiley, Ill

Attorney, Agent, or Firm--William M. Anderson; Oistein .1. Bratlie; Scott R. Foster [5 7] ABSTRACT Novel cutting edges and especially razor blades which have substantially better corrosion resistance, edge hardness, temper resistance, strength and ductility than those heretofore made from stainless steel and processes for making such cutting edges. Generally the cutting edges are formed from alloys comprising 30 to 60 percent cobalt, 10 to 40 percent nickel, 15 to 25 percent chromium and 5 to 12 percent molybdenum by (a) heating strips of such alloys under conditions which will result in said strips having a face centered cubic structure when cooled to room temperature, (b) cold working the strips, (0) age hardening the strips and (d) at some time during or subsequent to the cold-working step and before or after the age hardening step forming the cutting edge therein.

10 Claims, N0 Drawings 1 NOVEL CUTTING EDGES AND PROCESSES FOR MAKING THEM Although cutting edges such as razor blades at first glance appear to be fairly simple instruments, they are in reality delicate and complex. With razor blades the ultimate edge is generally in the order of 250 angstroms thick and because of such dimensions they are extremely sensitive to the slightest amounts of corrosion. Further the edges are hardened to the highest extent achievable but yet it is necessary that they retain sufficient strength and ductility to withstand the stresses and strains such a narrow edge is subjected to during the source of its use. Further in addition to all this, it is necessary that they have good temper resistance to withstand the high temperatures which they are usually subjected to when the polytetrafluoroethylene coatings which are generally applied to them are sintered thereon. Although stainless steels have filled some of these requirements to a fair degree there is substantial room for improvement.

One object of the present invention is to provide novel cutting edges and especially razor blades which have hardnesses, stress corrosion resistances, ductilities, strengths and temper resistances which are sub-.

stantially better than those of stainless steel.

Another object of the present invention is to provide processes for making such edges.

Other objects should be obvious from the following description and claims.

In general, the aforementioned objects are achieved by: (a) heating an alloy comprising nickel, cobalt, chromium and molybdenum in the ranges specified below under conditions which will result in the alloy having a well annealed single phase face centered cubic structure when it is cooled to room temperature; (b) cold working the single phase alloy; age hardening the alloy and at some time during or subsequent to cold working step and before or after the age hardening step forming the cutting edge. In a preferred mode of making cutting instruments such as razor blades, the cutting edge is formed; e.g., by grinding subsequent to the age hardening step.

Generally the blades of the present invention are made from alloys which comprise by weight about to 40 percent nickel, 30 to 60 percent cobalt, to 25 percent chromium, 5 to 12 percent molybdenum, and 0 to percent iron. In preferred embodiments, the al loys comprise 20 to 35 percent nickel, 20 to 45 percent cobalt, 15 to percent chromium, 5 to 12 percent molybdenum and 0 to 5 percent iron. If desired, the alloys may contain other alloying elements which enhance the properties of the alloy but do not interfere with the processes. As examples of such other alloying elements and their preferred ranges mention may be made of the following:

Carbon 0 to 0.3% Manganese 0 to 5% Tungsten 0 to 3% Copper 0 to 5% rial having a face centered cubic crystal structure when a it is cooled to room temperature, e.g., by air cooling or quenching. The temperature and the period of time the alloy has to be held at such temperature in order to provide such a structure on cooling will vary depending upon the specific composition of the alloy. Metallurgists are quite familiar with this phenomena and will have little trouble ascertaining the best time and temperature for each particular material. Generally for most alloys within the scope of this disclosure, such a structure may be achieved by heating the alloy to a temperature of between 800C to 1,200C and holding it there for periods from at least 1 minute to 1 hour. It will be understood that the longer times will be used for lower temperatures and vice versa. In preferred em bodiments, temperatures between 800C and 1,050C are employed. Particularly useful results were obtained by heatingalloys to a temperature of l,O00C for about one half hour.

The cold working step which converts the face cen' tered cubic structure of the alloys to a close packed hexagonal structure and which imparts a substantial in crease in hardness to the alloy, may be carried out by any of the well-known methods; e.g., rolling, stamping, pressing, drawing, etc. In preferred embodiments of the invention, the cold working is carried out by cold roll ing. Generally a reduction in thickness between about 60 to 95 percent will provide the maximum hardening. It is to be understood that reductions somewhat below 60 percent and about 95 percent can be made, but the results will not be as dramatic as when the reduction is between 60 percent and 95 percent. The preferred reduction is between to percent. Preferably the cold working step is carried out under ambient conditions. However if desired it may be performed at temperatures below ambient temperature, e.g., down to that of liquid nitrogen or at elevated temperatures below the transition temperature of the alloy. Usually the transition temperature will vary with the amount of cobalt in the alloy. Generally with alloys comprising about 30 percent cobalt the cold working may be carried out at temperatures up to 250C and with alloys comprising 60 percent cobalt it may be carried out at temperatures up to 650C.

In using the processes of the present invention for producing cutting edges such as razor blades, the cold working may be provided at least in part by the grinding operation normally used in forming the cutting edge. Of course, it will be understood that if desired, substantially all the cold working may be carried out, for example, by cold rolling and the grinding step would contribute little additional hardening. In such event if desired, electro-sharpening methods may be employed in forming the cutting edge. The cutting edge may be formed prior to the age hardening step when the alloy is not as hard but in preferred embodiments, it is formed subsequent to the age hardening step when the alloy is appreciably harder. Generally, the methods which may be employed for forming the cutting edge are well known to the art and the specifics thereof form no part of this invention.

The age hardening step which is carried out subsequent to the cold working step is a time-temperature dependent reaction in which a further substantial increase in hardness is achieved. Generally the optimum hardeness will be achieved by heating the alloy at temperatures between about 300C and 700C for periods. for example, of at least from about 1 minute to about 1 week. As will be appreciated, the shorter times will be more applicable to the higher temperatures and the longer times to lower temperatures. With the alloy containing 35 percent nickel, 35 percent cobalt, 20 percent chromium and percent molybdenum, optimum hardness was achieved by heating at 450C for 3 hours and with the alloy containing 42.5 percent cobalt, l3 nickel, percent chromium, 18 percent iron, 1.6 percent manganese, 2.8 percent tungsten, and 0.2 percent carbon, optimum hardness was achieved by heating at 450C for 10 hours.

The following non-limiting examples illustrate the processes of the present invention as it relates to the preparation of a razor blade.

EXAMPLE 1 A sheet of alloy containing 35 percent nickel, 35 percent cobalt, 20 percent chromium, 10 percent molybdenum (weight percentages), and the usual trace of impurities found therein, was made to have a face'centered cubic structure by heating it at 1,000C for one half hour and thereafter air cooling it to room temperature. The sheet had a hardness of 200 DPHN. Part of the sheet was then cold rolled to a thickness of 0.004 inch with a reduction of 93 percent in the thickness of the alloy. The hardness after cold rolling was 540 DPHN. The strip was then sharpened to produce an edge through conventional razor blade sharpening techniques. Subsequent to sharpening, the blade was heated at 450C for 3 hours and the body hardness rose to 725 DPHN. A polytetrafluoroethylene telomer coating was applied to the cutting edge and it was cured thereon at 343C for 10 minutes. The following table illustrates the temper resistance of the blade of the present invention during the sintering step as compared with typical carbon and stainless steel blades.

Body Body hardness Sintering hardness before Time after Blade sintering & Temp. sintering Blades of Example 1 725 DPHN 343-10 min. 725

Carbon Steel Blades 825-880 DPHN do. 510-560 Stainless Steel Blades (double edge type) 750 do. 580-595 Stainless Steel Blades (ribbon type) 750 do. 520-550 EXAMPLE 2 An alloy strip containing 42.5 percent cobalt, 13 percent nickel, 20 percent chromium, 2 percent molybdenum, 1.6 percent manganese, 2.8 percent tungsten, 18 percent iron, and 0.2 percent carbon and the usual impurities found therein was heated to 1,000C for one half hour and thereafter cooled to room temperature to make it a single phase material having a face centered cubic structure. The strip with a hardness of around 220 DPHN was cold rolled until a reduction of 84 percent in thickness had been made and the strip had a thickness of 0.003 inch. The hardness was 521 DPHN. The strip was sharpened to produce an edge through conventional razor blade sharpening techniques. Subsequent to sharpening, the blade was heated to 450C for 10 hours and the body hardness rose to 757 DPHN. A polytetrafluoroethylene coating was applied to the cutting edge and it was cured thereon at 343C for ten minutes. Subsequent to the cure, the blade had a body hardness of 757 DPHN which is much better than that of a typical carbon or stainless steel blade set forth in example 1.

In addition to the hardnesses and temper resistances set forth above, the blades of Examples 1 and 2 had strengths of approximately 300,000 pounds per square inch and sufficient ductility that they could be bent back on themselves 180) without fracture. In a corrosion test at F in a hydrochloric acid solution containing 10 percent sodium chloride, open crevice samples of the alloy of Example 1 corroded at the rate of 0.1 mil per year, whereas, 316 stainless steel corroded at the rate of 5 mils per year. in a 10 percent ferric chloride solution the results were even better in that the alloy of Example 1 remained intact while the 316 stainless steel corroded at the rate of over 50 mils per year. The corrosion resistance of the alloy of Example 2 was not as good as that of Example 1, but it was far superior to the stainless steel.

Having described the invention what is claimed is:

1. A process for making a cutting edge, said process comprising heat-treating a strip of an alloy consisting essentially of 30 to 60 percent cobalt, 10 to 40 percent nickel, 15 to 25 percent chromium and 5 to 12 molybdenum under conditions such that said strip will have a face centered cubic structure when it is cooled to room temperature, cold working the strip to convert the face centered cubic structure to a close packed hexagonal structure, age hardening the strip and at some time during or subsequent to the cold working step forming the cutting edge thereon.

2. A process as defined in claim 1 wherein said cutting edge is a razor blade.

3. A process as defined in claim 1 wherein said strip is cold worked so that there is a reduction in thickness of between 60 to percent.

4. A process as defined in claim 1 wherein said heat treatment is carried out at a temperature of 800C to 1,200C for a period between 1 minute to 1 hour.

5. A process as defined in claim 1 wherein said age hardening is carried out at a temperature of 300C to 700C for periods of from 1 minute to 1 week.

6. A process as defined in claim 1 wherein said alloy is heat-treated at a temperature between 800C to 1,200C for a period of 1 minute to 1 hour, cold worked until there is a reduction in thickness of between 60 and 95 percent and age hardened at a temperature of 300 to 700C for a period of 1 minute to 1 week.

7. A process as defined in claim 6 wherein said cutting edge is a razor blade.

8. A cutting edge of an alloy consisting essentially of 30 to 60 percent cobalt, 10 to 40percent nickel, 15 to 25 percent chromium, and 5 to 12 percent molybdenum, said alloy being in cold worked and age hardened condition and having a close packed hexagonal structure.

9. A cutting edge as defined in claim 8 which is a razor blade.

10. A razor blade as defined in claim 9 in which a polytetrafluoroethylene coating is on the cutting edge.